JPH04359094A - Azeotropy and azeotrope-like composition - Google Patents
Azeotropy and azeotrope-like compositionInfo
- Publication number
- JPH04359094A JPH04359094A JP16108291A JP16108291A JPH04359094A JP H04359094 A JPH04359094 A JP H04359094A JP 16108291 A JP16108291 A JP 16108291A JP 16108291 A JP16108291 A JP 16108291A JP H04359094 A JPH04359094 A JP H04359094A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- cyclohexane
- azeotrope
- r225cb
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims abstract description 19
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 claims 4
- UJIGKESMIPTWJH-UHFFFAOYSA-N 1,3-dichloro-1,1,2,2,3-pentafluoropropane Chemical compound FC(Cl)C(F)(F)C(F)(F)Cl UJIGKESMIPTWJH-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 description 8
- -1 chlorine radicals Chemical class 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000004821 distillation Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 239000010721 machine oil Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000013020 steam cleaning Methods 0.000 description 3
- GXDHCNNESPLIKD-UHFFFAOYSA-N 2-methylhexane Natural products CCCCC(C)C GXDHCNNESPLIKD-UHFFFAOYSA-N 0.000 description 2
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- JXMGZLBGSDLPKN-UHFFFAOYSA-N 1,1-dichloro-1,2,2,3,3-pentafluoropropane Chemical compound FC(F)C(F)(F)C(F)(Cl)Cl JXMGZLBGSDLPKN-UHFFFAOYSA-N 0.000 description 1
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- GDSQRBLILFKERU-UHFFFAOYSA-N 1,2-dichloro-1,1,2,3,3-pentafluoropropane Chemical compound FC(F)C(F)(Cl)C(F)(F)Cl GDSQRBLILFKERU-UHFFFAOYSA-N 0.000 description 1
- XAHBEACGJQDUPF-UHFFFAOYSA-N 1,2-dichloro-1,1,3,3,3-pentafluoropropane Chemical compound FC(F)(F)C(Cl)C(F)(F)Cl XAHBEACGJQDUPF-UHFFFAOYSA-N 0.000 description 1
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
- JEWUXLHWYRSHJK-UHFFFAOYSA-N 2,2-dichloro-1,1,1,3,3-pentafluoropropane Chemical compound FC(F)C(Cl)(Cl)C(F)(F)F JEWUXLHWYRSHJK-UHFFFAOYSA-N 0.000 description 1
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 description 1
- YGFIGGVCQHKDOL-UHFFFAOYSA-N 2,3-dichloro-1,1,1,2,3-pentafluoropropane Chemical compound FC(Cl)C(F)(Cl)C(F)(F)F YGFIGGVCQHKDOL-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- NAMYKGVDVNBCFQ-UHFFFAOYSA-N 2-bromopropane Chemical compound CC(C)Br NAMYKGVDVNBCFQ-UHFFFAOYSA-N 0.000 description 1
- JHUUPUMBZGWODW-UHFFFAOYSA-N 3,6-dihydro-1,2-dioxine Chemical compound C1OOCC=C1 JHUUPUMBZGWODW-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- QPAXMPYBNSHKAK-UHFFFAOYSA-N chloro(difluoro)methane Chemical compound F[C](F)Cl QPAXMPYBNSHKAK-UHFFFAOYSA-N 0.000 description 1
- KFUSEUYYWQURPO-UPHRSURJSA-N cis-1,2-dichloroethene Chemical group Cl\C=C/Cl KFUSEUYYWQURPO-UPHRSURJSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000005437 stratosphere Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000005436 troposphere Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
【0001】0001
【産業上の利用分野】本発明は、プリント基板、IC等
の電気・電子部品、精密機械部品等の油、グリース、ワ
ックス、フラックス等の洗浄等に用いられる共沸及び共
沸様組成物に関するものである。[Industrial Application Field] The present invention relates to azeotropic and azeotrope-like compositions used for cleaning oil, grease, wax, flux, etc. from printed circuit boards, electric/electronic parts such as ICs, precision mechanical parts, etc. It is something.
【0002】0002
【従来の技術】油、グリース、ワックス、フラックス等
の洗浄等には、不燃性、低毒性、安定性に優れる等の特
徴を有する1,1,2−トリクロロ−1,2,2− ト
リフルオロエタン( 以下 R113 という) が広
く使用されている。さらに、R113は金属、プラスチ
ック、エラストマー等の基材を侵さず、各種の汚れを選
択的に溶解する特徴を有するため、金属、プラスチック
、エラストマー等からなる各種電気・電子部品、プリン
ト基板、精密機械部品等の洗浄には最適であった。[Prior Art] 1,1,2-trichloro-1,2,2-trifluoro, which has characteristics such as nonflammability, low toxicity, and excellent stability, is used for cleaning oil, grease, wax, flux, etc. Ethane (hereinafter referred to as R113) is widely used. Furthermore, R113 does not attack base materials such as metals, plastics, and elastomers, and has the characteristic of selectively dissolving various types of dirt. It was perfect for cleaning parts, etc.
【0003】0003
【発明が解決しようとする課題】従来使用されていたR
113は、種々の利点を有するにもかかわらず、化学的
に特に安定なため、対流圏内での寿命が長く、拡散して
成層圏に達し、ここで太陽光線により分解して発生する
塩素ラジカルがオゾンと連鎖反応を起こし、オゾン層を
破壊するとのことから、その使用規制が実施されること
となった。このため、従来のR113に替わり、オゾン
層を破壊しにくい代替溶剤の探索が活発に行なわれてい
る。[Problem to be solved by the invention] Conventionally used R
Despite its various advantages, 113 is chemically particularly stable, has a long lifetime in the troposphere, and diffuses into the stratosphere, where it is decomposed by sunlight and generates chlorine radicals, which are absorbed into the ozone. Since it is said that it causes a chain reaction and destroys the ozone layer, restrictions on its use have been implemented. Therefore, in place of the conventional R113, an active search is being made for alternative solvents that are less likely to destroy the ozone layer.
【0004】本発明は、従来のR113が有している優
れた特性を満足しながら代替溶剤として使用できる新規
なフッ素化塩素化炭化水素系共沸及び共沸様組成物を提
供することを目的とするものである。The object of the present invention is to provide a novel fluorinated chlorinated hydrocarbon azeotropic and azeotrope-like composition that can be used as a substitute solvent while satisfying the excellent properties of conventional R113. That is.
【0005】[0005]
【課題を解決するための手段】本発明は前述の目的を達
成すべくなされたものであり、炭素数が3である特定の
フッ素化塩素化炭化水素 1,3− ジクロロ−1,1
,2,2,3− ペンタフルオロプロパン(CClF2
CF2CHClF:以下 R225cb という) と
シクロヘキサンからなる共沸及び共沸様組成物を提供す
るものである。[Means for Solving the Problems] The present invention has been made to achieve the above-mentioned object, and is directed to a specific fluorinated chlorinated hydrocarbon having 3 carbon atoms, 1,3-dichloro-1,1
,2,2,3-pentafluoropropane (CClF2
The present invention provides azeotropic and azeotrope-like compositions consisting of CF2CHClF (hereinafter referred to as R225cb) and cyclohexane.
【0006】本発明の組成物の共沸様特性を示す混合組
成比は、R225cb70 〜99.5重量%及びシク
ロヘキサン 0.5〜30重量%であり、さらに共沸組
成はR225cb 97 重量%及びシクロヘキサン
3重量%である。なお、本発明の組成比は、用いるR2
25cb及びシクロヘキサンの純度や測定誤差等の影響
により、約±0.5 重量%程度の範囲で変動するもの
である。The composition of the present invention exhibits azeotrope-like characteristics at a mixing ratio of 70 to 99.5% by weight of R225cb and 0.5 to 30% by weight of cyclohexane, and further has an azeotropic composition of 97% by weight of R225cb and cyclohexane.
It is 3% by weight. Note that the composition ratio of the present invention is based on R2 used.
It fluctuates within a range of approximately ±0.5% by weight due to the purity of 25cb and cyclohexane, measurement errors, etc.
【0007】本発明の組成物には、必要に応じてその他
の成分を更に添加混合することができる。例えば、溶剤
としての用途においては、ペンタン、イソペンタン、ヘ
キサン、イソヘキサン、ヘプタン、イソヘプタン、2,
3−ジメチルブタン、シクロペンタン、メチルシクロペ
ンタン等の炭化水素類、ニトロメタン、ニトロエタン、
ニトロプロパン等のニトロアルカン類、ジエチルアミン
、トリエチルアミン、イソプロピルアミン、ブチルアミ
ン、イソブチルアミン等のアミン類、メタノール、エタ
ノール、n−プロピルアルコール、イソプロピルアルコ
ール、n−ブチルアルコール、i−ブチルアルコール、
s−ブチルアルコール、t−ブチルアルコール等のアル
コール類、メチルセロソルブ、テトラヒドロフラン、1
,4−ジオキサン等のエーテル類、アセトン、メチルエ
チルケトン、メチルブチルケトン等のケトン類、酢酸エ
チル、酢酸プロピル、酢酸ブチル等のエステル類、ジク
ロロメタン、cis−1,2−ジクロロエチレン、tr
ans−1,2−ジクロロエチレン、2−ブロモプロパ
ン等のハロゲン化炭化水素類、その他、1,1−ジクロ
ロ−1− フルオロエタン、2,2−ジクロロ−1,1
,1− トリフルオロエタン、1,1−ジクロロ−1,
2,2,3,3− ペンタフルオロプロパン、1,2−
ジクロロ−1,1,3,3,3− ペンタフルオロプロ
パン、1,2−ジクロロ−1,1,2,3,3−ペンタ
フルオロプロパン、2,3−ジクロロ−1,1,1,2
,3− ペンタフルオロプロパン、2,2−ジクロロ−
1,1,1,3,3− ペンタフルオロプロパン、1,
1−ジクロロ−2,3,3,3− テトラフルオロプロ
ペン−1、trans−3−クロロ−1,1,1,2,
4,4,5,5,5−ノナフルオロペンテン−2、ci
s−3−クロロ−1,1,1,2,4,4,5,5,5
− ノナフルオロペンテン−2、1,1,1,2,2,
5,5,6,6,6−デカフルオロヘキサン等のR22
5cb以外のフッ素化塩素化炭化水素類等を適宜添加す
ることができる。[0007] Other components may be further added and mixed into the composition of the present invention, if necessary. For example, in applications as a solvent, pentane, isopentane, hexane, isohexane, heptane, isoheptane, 2,
Hydrocarbons such as 3-dimethylbutane, cyclopentane, methylcyclopentane, nitromethane, nitroethane,
Nitroalkanes such as nitropropane, amines such as diethylamine, triethylamine, isopropylamine, butylamine, isobutylamine, methanol, ethanol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, i-butyl alcohol,
Alcohols such as s-butyl alcohol and t-butyl alcohol, methyl cellosolve, tetrahydrofuran, 1
, ethers such as 4-dioxane, ketones such as acetone, methyl ethyl ketone, methyl butyl ketone, esters such as ethyl acetate, propyl acetate, butyl acetate, dichloromethane, cis-1,2-dichloroethylene, tr
ans-1,2-dichloroethylene, halogenated hydrocarbons such as 2-bromopropane, others, 1,1-dichloro-1-fluoroethane, 2,2-dichloro-1,1
, 1-trifluoroethane, 1,1-dichloro-1,
2,2,3,3-pentafluoropropane, 1,2-
Dichloro-1,1,3,3,3-pentafluoropropane, 1,2-dichloro-1,1,2,3,3-pentafluoropropane, 2,3-dichloro-1,1,1,2
, 3-pentafluoropropane, 2,2-dichloro-
1,1,1,3,3-pentafluoropropane, 1,
1-dichloro-2,3,3,3-tetrafluoropropene-1, trans-3-chloro-1,1,1,2,
4,4,5,5,5-nonafluoropentene-2, ci
s-3-chloro-1,1,1,2,4,4,5,5,5
- nonafluoropentene-2,1,1,1,2,2,
R22 such as 5,5,6,6,6-decafluorohexane
Fluorinated chlorinated hydrocarbons other than 5cb can be added as appropriate.
【0008】これらの化合物の添加量は、安定化の目的
のためには、0.01〜10重量%、溶解力向上または
調節等の目的のためには 0.1〜30重量%である。The amount of these compounds added is 0.01 to 10% by weight for the purpose of stabilization, and 0.1 to 30% by weight for the purpose of improving or controlling the dissolving power.
【0009】R225cbとシクロヘキサンとからなる
本発明の組成物は、共沸組成または共沸様特性を有する
ため、蒸気洗浄等においても、組成変化がない、または
極めて小さいため、単一の溶剤と同様に用いることがで
きる。
また、プロペラントやフェノール樹脂等の発泡剤として
使うこともできる。Since the composition of the present invention consisting of R225cb and cyclohexane has an azeotropic composition or azeotrope-like characteristics, there is no or extremely small change in the composition even during steam cleaning, so it is similar to a single solvent. It can be used for. It can also be used as a foaming agent for propellants, phenolic resins, and the like.
【0010】さらにまた、R225cbとシクロヘキサ
ンとからなる本発明の共沸及び共沸様組成物は、従来の
R113と同程度の溶解力を有するため、溶剤の各種用
途に好適に使用でる。この具体的な用途としては、油、
グリース、ワックス、フラックス、インキ等の洗浄・除
去剤、塗料用溶剤、抽出剤、ガラス、セラミックス、プ
ラスチック、ゴム、金属製各種物品、特にIC部品、電
気機器、精密機械、光学レンズ等の洗浄剤や水切り剤等
を挙げることができる。洗浄方法としては、手拭き、浸
漬、スプレー、揺動、超音波洗浄、蒸気洗浄等を採用す
ればよい。Furthermore, the azeotropic and azeotrope-like compositions of the present invention comprising R225cb and cyclohexane have a solvency power comparable to that of conventional R113, and therefore can be suitably used in various solvent applications. Specific uses include oil,
Cleaning and removing agents for grease, wax, flux, ink, etc., paint solvents, extractants, glass, ceramics, plastics, rubber, various metal articles, especially IC parts, electrical equipment, precision machinery, optical lenses, etc. and draining agents. As the cleaning method, hand wiping, dipping, spraying, shaking, ultrasonic cleaning, steam cleaning, etc. may be employed.
【0011】[0011]
[実施例1]下記の組成からなる組成物1000gを蒸
留フラスコに入れ、理論段数20段の精留塔を用い、大
気圧下で蒸留を行なった。
(組成) (
重量%)R225cb(沸点56.1℃)
95シクロヘキサン(沸点80.7℃
) 5[Example 1] 1000 g of a composition having the following composition was placed in a distillation flask and distilled under atmospheric pressure using a rectification column with 20 theoretical plates. (composition) (
Weight%) R225cb (boiling point 56.1°C)
95 cyclohexane (boiling point 80.7℃
) 5
【0012】その結果、55.9℃
において留分 430gを得た。このものをガスクロマ
トグラフで測定した結果、次の組成であった。
(組成) (
重量%)R225cb
97シクロヘキサン
3[0012] As a result, the temperature was 55.9°C.
430 g of fraction was obtained. As a result of measuring this product with a gas chromatograph, it had the following composition. (composition) (
Weight%) R225cb
97 cyclohexane
3
【0013】
[実施例2]下記の組成からなる組成物1000gを蒸
留フラスコに入れ、理論段数5段の精留塔を用い、大気
圧下で蒸留を行なった。
(組成) (
重量%)R225cb(沸点56.1℃)
90シクロヘキサン(沸点80.7℃
) 10[0013]
[Example 2] 1000 g of a composition having the composition shown below was placed in a distillation flask and distilled under atmospheric pressure using a rectification column with 5 theoretical plates. (composition) (
Weight%) R225cb (boiling point 56.1°C)
90 cyclohexane (boiling point 80.7℃
) 10
【0014】その結果、4時間後、
8時間後、12時間後において留分100gを各々採取
した。このものをガスクロマトグラフで測定した結果、
次の組成であった。As a result, after 4 hours,
After 8 hours and 12 hours, 100 g of fractions were each collected. As a result of measuring this with a gas chromatograph,
It had the following composition.
【0015】[実施例3]下記の組成からなる組成物1
000gを蒸留フラスコに入れ、理論段数5段の精留塔
を用い、大気圧下で蒸留を行なった。
(組成) (
重量%)R225cb(沸点56.1℃)
80シクロヘキサン(沸点80.7℃
) 20[Example 3] Composition 1 consisting of the following composition
000 g was placed in a distillation flask and distilled under atmospheric pressure using a rectification column with 5 theoretical plates. (composition) (
Weight%) R225cb (boiling point 56.1°C)
80 cyclohexane (boiling point 80.7℃
) 20
【0016】その結果、4時間後、
8時間後、12時間後において留分100gを各々採取
した。このものをガスクロマトグラフで測定した結果、
次の組成であった。As a result, after 4 hours,
After 8 hours and 12 hours, 100 g of fractions were each collected. As a result of measuring this with a gas chromatograph,
It had the following composition.
【0017】[実施例4]下記の組成からなる組成物1
000gを蒸留フラスコに入れ、理論段数5段の精留塔
を用い、大気圧下で蒸留を行なった。
(組成) (
重量%)R225cb(沸点56.1℃)
75シクロヘキサン(沸点80.7℃
) 25[Example 4] Composition 1 consisting of the following composition
000 g was placed in a distillation flask and distilled under atmospheric pressure using a rectification column with 5 theoretical plates. (composition) (
Weight%) R225cb (boiling point 56.1°C)
75 cyclohexane (boiling point 80.7℃
) 25
【0018】その結果、4時間後、
8時間後、12時間後において留分100gを各々採取
した。このものをガスクロマトグラフで測定した結果、
次の組成であった。As a result, after 4 hours,
After 8 hours and 12 hours, 100 g of fractions were each collected. As a result of measuring this with a gas chromatograph,
It had the following composition.
【0019】[実施例5]実施例1の組成物(R225
cb/シクロヘキサン=97重量%/3 重量%)につ
いてタグ式引火点測定装置(JIS K 2265)を
用いて、引火点を測定した。その結果、この組成物は引
火点がなく、不燃であることが確認された。[Example 5] Composition of Example 1 (R225
cb/cyclohexane=97% by weight/3% by weight), the flash point was measured using a tag type flash point measuring device (JIS K 2265). As a result, it was confirmed that this composition had no flash point and was nonflammable.
【0020】[実施例6〜9]機械油の洗浄試験として
、SUS−304 のテストピース(25mm ×30
mm×2mm)を機械油(日本石油製CQ−30)中に
浸漬した後、表1の混合組成物中に5分浸漬した。機械
油の除去の度合を表1に示す。[Examples 6 to 9] As a machine oil cleaning test, a test piece of SUS-304 (25 mm x 30
mm x 2 mm) was immersed in machine oil (Nippon Oil Co., Ltd. CQ-30) and then immersed in the mixed composition shown in Table 1 for 5 minutes. Table 1 shows the degree of machine oil removal.
【0021】[0021]
【表1】[Table 1]
【0022】[0022]
【発明の効果】本発明のR225cbとシクロヘキサン
からなる共沸及び共沸様組成物は、従来のR113が有
している優れた特性を満足し、従来のR113と同じ使
い方でき、従来技術の大幅な変更を要しない等の利点が
あり、さらに蒸気洗浄等を行っても組成変化がない、ま
たは極めて小さいという利点もある。Effects of the Invention: The azeotropic and azeotrope-like compositions of R225cb and cyclohexane of the present invention satisfy the excellent properties of conventional R113, can be used in the same way as conventional R113, and are significantly superior to conventional R113. It has the advantage that it does not require any major changes, and it also has the advantage that even if steam cleaning or the like is performed, there is no change in the composition or it is extremely small.
Claims (4)
ペンタフルオロプロパンとシクロヘキサンとからなる
共沸組成物。Claim 1: 1,3-dichloro-1,1,2,2,3-
An azeotropic composition consisting of pentafluoropropane and cyclohexane.
ペンタフルオロプロパン97重量%とシクロヘキサン
3 重量%とからなる共沸組成物。Claim 2: 1,3-dichloro-1,1,2,2,3-
An azeotropic composition consisting of 97% by weight of pentafluoropropane and 3% by weight of cyclohexane.
ペンタフルオロプロパンとシクロヘキサンとからなる
共沸様組成物。Claim 3: 1,3-dichloro-1,1,2,2,3-
An azeotrope-like composition consisting of pentafluoropropane and cyclohexane.
ペンタフルオロプロパン70〜99.5重量%とシク
ロヘキサン 0.5〜30重量%とからなる共沸様組成
物。Claim 4: 1,3-dichloro-1,1,2,2,3-
An azeotrope-like composition comprising 70-99.5% by weight of pentafluoropropane and 0.5-30% by weight of cyclohexane.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16108291A JPH04359094A (en) | 1991-06-05 | 1991-06-05 | Azeotropy and azeotrope-like composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16108291A JPH04359094A (en) | 1991-06-05 | 1991-06-05 | Azeotropy and azeotrope-like composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04359094A true JPH04359094A (en) | 1992-12-11 |
Family
ID=15728282
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP16108291A Pending JPH04359094A (en) | 1991-06-05 | 1991-06-05 | Azeotropy and azeotrope-like composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04359094A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013224383A (en) * | 2012-04-23 | 2013-10-31 | Asahi Glass Co Ltd | Solvent composition for cleaning |
-
1991
- 1991-06-05 JP JP16108291A patent/JPH04359094A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013224383A (en) * | 2012-04-23 | 2013-10-31 | Asahi Glass Co Ltd | Solvent composition for cleaning |
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