JPH0421438A - Laminated sheet for electrical use - Google Patents
Laminated sheet for electrical useInfo
- Publication number
- JPH0421438A JPH0421438A JP12784290A JP12784290A JPH0421438A JP H0421438 A JPH0421438 A JP H0421438A JP 12784290 A JP12784290 A JP 12784290A JP 12784290 A JP12784290 A JP 12784290A JP H0421438 A JPH0421438 A JP H0421438A
- Authority
- JP
- Japan
- Prior art keywords
- base material
- polyphenylene oxide
- metal foil
- necessary
- pressing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 12
- 229920006380 polyphenylene oxide Polymers 0.000 claims abstract description 12
- 239000011888 foil Substances 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 229920001187 thermosetting polymer Polymers 0.000 claims description 9
- -1 and if necessary Substances 0.000 claims description 6
- 239000010410 layer Substances 0.000 abstract description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004744 fabric Substances 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 3
- 239000012790 adhesive layer Substances 0.000 abstract description 2
- 239000000956 alloy Substances 0.000 abstract description 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 2
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 abstract description 2
- 229910052802 copper Inorganic materials 0.000 abstract description 2
- 239000010949 copper Substances 0.000 abstract description 2
- 239000012765 fibrous filler Substances 0.000 abstract description 2
- 239000012784 inorganic fiber Substances 0.000 abstract description 2
- 239000011256 inorganic filler Substances 0.000 abstract description 2
- 229910003475 inorganic filler Inorganic materials 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- 239000003505 polymerization initiator Substances 0.000 abstract description 2
- 238000003825 pressing Methods 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 abstract 1
- 239000011521 glass Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical group C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は電子機器、電気機器、コンピューター、通信機
器等に用いられる電気用積層板に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an electrical laminate used in electronic equipment, electrical equipment, computers, communication equipment, etc.
従来の熱硬化性ポリフェニレンオキサイド樹脂からなる
電気用積層板は、熱硬化性ポリフェニレンオキサイド樹
脂ワニスを基材に含浸、乾燥して得られるものであるが
、基材への樹脂含浸性が悪く電気性能のバラツキ、反り
が大きくなる問題があった。Conventional electrical laminates made of thermosetting polyphenylene oxide resin are obtained by impregnating a base material with thermosetting polyphenylene oxide resin varnish and drying it, but the resin impregnation into the base material is poor and the electrical performance is poor. There was a problem of large variations in the temperature and warpage.
従来の技術で述べたように熱硬化性ポリフェニレン樹脂
ワニスを基材に含浸してなるプリプレグを用いた電気用
積層板は電気性能のバラツキ、反りが大きくなる問題点
がある。本発明は従来の技術における上述の問題点に鑑
みてなされたもので、その目的とするところは電気性能
のバラツキ及び反りの少ない電気用積層板を提供するこ
とにある。As described in the section on the prior art, electrical laminates using prepregs formed by impregnating thermosetting polyphenylene resin varnish into a base material have problems such as large variations in electrical performance and large warping. The present invention has been made in view of the above-mentioned problems in the prior art, and its purpose is to provide an electrical laminate with less variation in electrical performance and less warpage.
本発明は所要枚数の基材の各上面及び又は下線に熱硬化
性ポリフェニレンオキサイド樹脂フィルムを配し、更に
必要に応じて最外層に金属箔を配設した積層体を一体化
してなることを特徴とする電気用積層板のため、基材に
溶融樹脂が圧入されるので基材への樹脂の含浸が均一と
なり電気性能のバラツキ、反りを少くすることができた
もので以下本発明の詳細な説明するー；゛
本発明に用いる基材としてはガラス、アスベスト等の無
機繊維やポリエステル、ポリアクリル、ポリビニルアル
コール、ポリアミド、ポリイミド、ポリフェニレンサル
ファイド、ポリウレタン等の有機合成繊維や木綿等の天
然繊維からなる織布、不織布、マット或は紙又はこれ等
の組合せ基材である。基材は予じめカップリング剤等で
処理しておくこともできる。熱硬化性ポリフェニレンオ
キサイド樹脂フィルムとしては、ポリ（２・６ジメチル
ト４フェニレンオキサイド）等のポリフェニレンオキサ
イドに対し、１・２ポリブタジエン、１・４ポリブタジ
エン、スチレンブタジェンコポリマー、変性１・２ポリ
ブタジエン（マレイン変性、アクリル変性、エポキシ変
性等）、トリアリルイソシアヌレート、ゴム類等の架橋
性ポリマー、ヘイシイルバーオキサイド、２・５ジメチ
ル２・５ジヘンゾイルパーオキシヘキサン、ターシャリ
−ブチルパーオキシベンゾエート、ジクミルパーオキサ
イド等の重合開始側等からなる熱硬化ポリフェニレンオ
キサイド樹脂を厚さ０．００５〜０．５閣のフィルムに
したものである。なお必要ニ応じて熱硬化性ポリフェニ
レンオキサイド樹脂には水酸化アルミニウム、タルク、
シリカ、アルミナ、炭酸カルシウム、炭酸マグネシウム
等の無機充填剤やガラス繊維チップ、アスベスト、木粉
、パルプ、綿粉等の繊維質充填剤を添加することもでき
る。金属箔としては銅、アルミニウム、鉄、ニッケル、
亜鉛等の単独、合金、複合箔が用いられ、必要に応じて
金属箔の片面に接着側層を設けておき、より接着性を向
上させることもできる一体化手段としてはプレス多段プ
レス、マルチロール等が用いられる。The present invention is characterized by integrating a laminate in which a thermosetting polyphenylene oxide resin film is arranged on the upper surface and/or the underline of each of the required number of base materials, and further, if necessary, a metal foil is arranged on the outermost layer. For electrical laminates, the molten resin is press-fitted into the base material, so that the resin impregnation into the base material is uniform, reducing variations in electrical performance and warping.Details of the present invention are described below. Explain: The base material used in the present invention is made of inorganic fibers such as glass and asbestos, organic synthetic fibers such as polyester, polyacrylic, polyvinyl alcohol, polyamide, polyimide, polyphenylene sulfide, polyurethane, and natural fibers such as cotton. The base material is woven fabric, non-woven fabric, mat, paper, or a combination thereof. The base material can also be treated with a coupling agent or the like in advance. As a thermosetting polyphenylene oxide resin film, 1,2 polybutadiene, 1,4 polybutadiene, styrene butadiene copolymer, modified 1,2 polybutadiene (malein modified , acrylic modified, epoxy modified, etc.), triallyl isocyanurate, crosslinkable polymers such as rubbers, heysil peroxide, 2,5 dimethyl 2,5 dihenzoyl peroxyhexane, tert-butyl peroxybenzoate, dicumyl A thermosetting polyphenylene oxide resin consisting of a polymerization initiator such as peroxide is made into a film with a thickness of 0.005 to 0.5 mm. If necessary, aluminum hydroxide, talc,
Inorganic fillers such as silica, alumina, calcium carbonate, and magnesium carbonate, and fibrous fillers such as glass fiber chips, asbestos, wood flour, pulp, and cotton powder may also be added. Metal foils include copper, aluminum, iron, nickel,
Single, alloy, or composite foils such as zinc are used, and if necessary, an adhesive layer is provided on one side of the metal foil to further improve adhesion. Multi-stage presses and multi-roll presses are used as an integration method. etc. are used.
以下本発明を実施例にもとづいて説明する。The present invention will be explained below based on examples.
厚さ０．１５ｍｍのガラス布７枚の各層間及び最外層に
厚さ０．１閣の熱硬化性ポリフェニレンオキサイド樹脂
フィルム（ポリフェニレンオキサイド４０重量部に対し
スチレンブタジェンコポリマ−４０重量部トリアリルイ
ソシアヌレート１２０重量部、２・５ジメチル２・５ジ
ターシャリ−ブチルパーオキシヘキシン３を６重量部か
らなる樹脂のフィルム）を配し、更に最外層ニこ厚さ０
．０３５ｍｍの接着剤付銅箔の接着剤側をフィルムと対
向させて夫々配設した積層体を成形圧力５０ｋｇ／ｄ、
２２０°Ｃで６０分間プレスで積層成形して厚さ１．２
閣の電気用積層板を得た。A thermosetting polyphenylene oxide resin film with a thickness of 0.1 mm is placed between each layer of seven glass cloths with a thickness of 0.15 mm and as the outermost layer (40 parts by weight of styrene-butadiene copolymer - 40 parts by weight of triallyl isocyanate per 40 parts by weight of polyphenylene oxide). A resin film consisting of 120 parts by weight of Nurate and 6 parts by weight of 2.5 dimethyl 2.5 ditert-butyl peroxyhexine 3 was disposed, and the outermost layer had a thickness of 0.
．． A laminate of 0.35 mm adhesive-coated copper foil with the adhesive side facing the film was formed at a molding pressure of 50 kg/d.
Laminated with a press at 220°C for 60 minutes to a thickness of 1.2
Obtained electrical laminates for the cabinet.
実施例と同し熱硬化性ポリフェニレンオキサイド樹脂を
樹脂量が３０重量％になるように、厚さ０．１５ｍｍの
ガラス布に含浸、乾燥したプリプレグ７枚を重ね、更に
その最外層に実施例と同し銅箔を夫々配設した積層体を
実施例と同様に処理して厚さ１．２ｍａ＋の電気用積層
板を得た。Seven prepregs impregnated with a glass cloth having a thickness of 0.15 mm and dried were layered with the same thermosetting polyphenylene oxide resin as in the example so that the resin amount was 30% by weight. A laminate having the same copper foils disposed thereon was treated in the same manner as in the example to obtain an electrical laminate having a thickness of 1.2 ma+.
実施例及び比較例の電気用積層板の性能は第１表のよう
である。The performance of the electrical laminates of Examples and Comparative Examples is shown in Table 1.
第 １ 表
〔発明の効果〕
本発明は上述した如く構成されている。特許請求の範囲
に記載した構成を有する電気用積層板においては電気性
能のバラツキ、反りか少なくなる効果がある。Table 1 [Effects of the Invention] The present invention is constructed as described above. The electrical laminate having the structure described in the claims has the effect of reducing variations in electrical performance and warping.
Claims (1)
ポリフェニレンオキサイド樹脂フイルムを配し、更に必
要に応じて最外層に金属箔を配設した積層体を一体化し
てなることを特徴とする電気用積層板。(1) It is characterized by an integrated laminate in which thermosetting polyphenylene oxide resin films are arranged on the upper and/or lower surfaces of each of the required number of base materials, and if necessary, metal foil is arranged on the outermost layer. Electrical laminates.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12784290A JPH0421438A (en) | 1990-05-16 | 1990-05-16 | Laminated sheet for electrical use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12784290A JPH0421438A (en) | 1990-05-16 | 1990-05-16 | Laminated sheet for electrical use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0421438A true JPH0421438A (en) | 1992-01-24 |
Family
ID=14970017
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12784290A Pending JPH0421438A (en) | 1990-05-16 | 1990-05-16 | Laminated sheet for electrical use |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0421438A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9051465B1 (en) | 2012-02-21 | 2015-06-09 | Park Electrochemical Corporation | Thermosetting resin composition containing a polyphenylene ether and a brominated fire retardant compound |
| US9243164B1 (en) | 2012-02-21 | 2016-01-26 | Park Electrochemical Corporation | Thermosetting resin composition containing a polyphenylene ether and a brominated fire retardant compound |
-
1990
- 1990-05-16 JP JP12784290A patent/JPH0421438A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9051465B1 (en) | 2012-02-21 | 2015-06-09 | Park Electrochemical Corporation | Thermosetting resin composition containing a polyphenylene ether and a brominated fire retardant compound |
| US9243164B1 (en) | 2012-02-21 | 2016-01-26 | Park Electrochemical Corporation | Thermosetting resin composition containing a polyphenylene ether and a brominated fire retardant compound |
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