JPH04128041A - Decorative sheet and manufacture thereof - Google Patents
Decorative sheet and manufacture thereofInfo
- Publication number
- JPH04128041A JPH04128041A JP2249192A JP24919290A JPH04128041A JP H04128041 A JPH04128041 A JP H04128041A JP 2249192 A JP2249192 A JP 2249192A JP 24919290 A JP24919290 A JP 24919290A JP H04128041 A JPH04128041 A JP H04128041A
- Authority
- JP
- Japan
- Prior art keywords
- transparent
- resin film
- thermoplastic resin
- film
- translucent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 24
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 46
- 229920005989 resin Polymers 0.000 claims abstract description 33
- 239000011347 resin Substances 0.000 claims abstract description 33
- 238000000034 method Methods 0.000 claims abstract description 18
- 238000010030 laminating Methods 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 68
- 230000000694 effects Effects 0.000 abstract description 14
- 238000004049 embossing Methods 0.000 abstract description 9
- -1 polyethylene Polymers 0.000 abstract description 9
- 238000007731 hot pressing Methods 0.000 abstract description 4
- 229920001169 thermoplastic Polymers 0.000 abstract description 4
- 239000004416 thermosoftening plastic Substances 0.000 abstract description 4
- 239000004698 Polyethylene Substances 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 229920000573 polyethylene Polymers 0.000 abstract description 3
- 239000004743 Polypropylene Substances 0.000 abstract description 2
- 229920005668 polycarbonate resin Polymers 0.000 abstract description 2
- 239000004431 polycarbonate resin Substances 0.000 abstract description 2
- 229920001155 polypropylene Polymers 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 13
- 238000000465 moulding Methods 0.000 description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 239000004800 polyvinyl chloride Substances 0.000 description 7
- 229920000915 polyvinyl chloride Polymers 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000011049 pearl Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 description 1
- JJBFVQSGPLGDNX-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)COC(=O)C(C)=C JJBFVQSGPLGDNX-UHFFFAOYSA-N 0.000 description 1
- KGPXEVIKDFHEEZ-UHFFFAOYSA-N 2-(dibenzylamino)ethyl prop-2-enoate Chemical compound C=1C=CC=CC=1CN(CCOC(=O)C=C)CC1=CC=CC=C1 KGPXEVIKDFHEEZ-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- PTJDGKYFJYEAOK-UHFFFAOYSA-N 2-butoxyethyl prop-2-enoate Chemical compound CCCCOCCOC(=O)C=C PTJDGKYFJYEAOK-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- YXYJVFYWCLAXHO-UHFFFAOYSA-N 2-methoxyethyl 2-methylprop-2-enoate Chemical compound COCCOC(=O)C(C)=C YXYJVFYWCLAXHO-UHFFFAOYSA-N 0.000 description 1
- HFCUBKYHMMPGBY-UHFFFAOYSA-N 2-methoxyethyl prop-2-enoate Chemical compound COCCOC(=O)C=C HFCUBKYHMMPGBY-UHFFFAOYSA-N 0.000 description 1
- NIAGUSHJWAMKBZ-UHFFFAOYSA-N 2-methylprop-2-enoic acid;1,3,5-triazine-2,4,6-triamine Chemical class CC(=C)C(O)=O.NC1=NC(N)=NC(N)=N1 NIAGUSHJWAMKBZ-UHFFFAOYSA-N 0.000 description 1
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 description 1
- GAKWESOCALHOKH-UHFFFAOYSA-N 4-methoxybutyl prop-2-enoate Chemical compound COCCCCOC(=O)C=C GAKWESOCALHOKH-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- WMAFNLQQGPUKCM-UHFFFAOYSA-N ethoxymethyl 2-methylprop-2-enoate Chemical compound CCOCOC(=O)C(C)=C WMAFNLQQGPUKCM-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 229920006248 expandable polystyrene Polymers 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- DMEKUKDWAIXWSL-UHFFFAOYSA-N n,n-dimethyl-7-nitro-9h-fluoren-2-amine Chemical compound [O-][N+](=O)C1=CC=C2C3=CC=C(N(C)C)C=C3CC2=C1 DMEKUKDWAIXWSL-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- QCTJRYGLPAFRMS-UHFFFAOYSA-N prop-2-enoic acid;1,3,5-triazine-2,4,6-triamine Chemical compound OC(=O)C=C.NC1=NC(N)=NC(N)=N1 QCTJRYGLPAFRMS-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical class C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、内部に、凹凸のエンボス模様を有する立体感
に富む化粧材シート及びその化粧材シートの製造方法に
関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a decorative material sheet having a rich three-dimensional effect and having an uneven embossed pattern therein, and a method for manufacturing the decorative material sheet.
口従来の技術〕
立体感のある化粧材シートを得る目的で、化粧材シート
の表面に凹凸のエンボス模様を賦形させたものが利用さ
れており、例えば、エンボスロールによる凹凸模様が表
面に付されている化粧材シートが使用されている。[Conventional technology] In order to obtain a decorative material sheet with a three-dimensional effect, a decorative material sheet with an embossed pattern formed on its surface is used. A decorative sheet is used.
しかし、前記従来のエンボスロールによる凹凸模様が表
面に付されている化粧材シートは、ある程度の立体感は
表現されているが、全体的に満足され得る程の立体感を
具備するものではなく、例えば、木目模様を印刷した化
粧材シートを天然木による化粧材と比較した場合に、そ
の立体感が充分ではなく、品質性において劣るという欠
点を有している。However, although the decorative material sheet whose surface is given a concavo-convex pattern by the conventional embossing roll has a certain degree of three-dimensional effect, it does not have a three-dimensional effect that can be satisfied overall. For example, when comparing a decorative material sheet printed with a wood grain pattern with a decorative material made of natural wood, it has the disadvantage that its three-dimensional effect is not sufficient and its quality is inferior.
また、前記化粧材シートに再び熱圧成型を施した場合、
凹凸のエンボス模様が二〇熱圧成型により消えてしまう
。したがって、前記化粧材シートに熱圧成型により、裏
打ち材を積層した場合、立体感のある化粧材シートを得
ることができない。また、前記化粧材シートの凹凸のエ
ンボス模様を有している面の反対側の面に新たに凹凸の
エンボス模様を、熱圧成型により設けた場合、最初の凹
凸模様が消失してしまい、両面にそれぞれ凹凸模様を有
する化粧材シートを得ることができない。In addition, when the decorative material sheet is subjected to heat-pressing molding again,
The uneven embossed pattern disappears after 20 years of heat pressure molding. Therefore, when a backing material is laminated onto the decorative sheet by hot pressure molding, a decorative sheet with a three-dimensional effect cannot be obtained. Furthermore, when a new uneven embossed pattern is formed on the surface of the decorative material sheet opposite to the surface having the uneven embossed pattern by hot pressure molding, the initial uneven pattern disappears, and both sides Therefore, it is not possible to obtain a decorative sheet having a concavo-convex pattern.
これに対して、本発明は、立体感に富み、多彩な意匠効
果を持つ、化粧材シート及びその製造方法を提供する。In contrast, the present invention provides a decorative material sheet that is rich in three-dimensional effect and has various design effects, and a method for manufacturing the same.
本発明は、上記の課題を解決するものであって、
「■ 着色されている熱可塑性樹脂フィルムの片面に凹
凸のエンボス模様が設けられ、このエンボス面側に、透
明ないし半透明の耐熱圧性のある樹脂、及び透明ないし
半透明の熱可塑性樹脂フィルムがこの順に積層されてい
ることを特徴とする化粧材シート」、
「■ 前記■の化粧材シートにおいて、前記透明ないし
半透明熱可塑性樹脂フィルム側に更に別の凹凸のエンボ
ス模様が形成されていることを特徴とする化粧材シート
」、
「■ 前記■又は■の化粧材シートにおいて、前記着色
熱可塑性樹脂フィルム側に裏打ち材が積層されているこ
とを特徴とする化粧材シート」 ）
「■ 着色されている熱可塑性樹脂フィルムの片面に凹
凸のエンボス模様を設け、このエンボス面側に、透明な
いし半透明の耐熱圧性のある樹脂、及び透明ないし半透
明の熱可塑性樹脂フィルムをこの順に積層することを特
徴とする化粧材シートの製造方法」、
「■ 前記■の化粧材シートの製造方法において、前記
透明ないし半透明熱可塑性樹脂フィルム側に更に別の凹
凸のエンボス模様を設けることを特徴とする化粧材シー
トの製造方法」、「■ 前記■の化粧材シートの製造方
法において、前記着色熱可塑性樹脂フィルム側に裏打ち
材を積層することを特徴とする化粧材シートの製造方法
」及び、
「■ 前記■の化粧材シートの製造方法において、前記
透明ないし半透明熱可塑性樹脂フィルム側に更に別の凹
凸のエンボス模様を設けながら、前記着色熱可塑性樹脂
フィルム側に裏打ち材を積層することを特徴とする化粧
材シートの製造方法」
を要旨とするものである。The present invention solves the above-mentioned problems, and has the following features: ``■ A colored thermoplastic resin film is provided with an uneven embossed pattern on one side, and a transparent or translucent heat-pressure resistant material is provided on the embossed side. A decorative material sheet characterized in that a certain resin and a transparent or translucent thermoplastic resin film are laminated in this order,""■ In the decorative material sheet of (■) above, the transparent or translucent thermoplastic resin film side ``a decorative material sheet characterized in that a further uneven embossed pattern is formed on the surface'', ``■ In the decorative material sheet of ■ or ■, a backing material is laminated on the colored thermoplastic resin film side. A decorative material sheet characterized by the following: ``■ A colored thermoplastic resin film is provided with an embossed pattern of unevenness on one side, and a transparent or translucent heat-pressure resistant resin is coated on the embossed surface side, and a transparent or A method for producing a decorative material sheet characterized by laminating translucent thermoplastic resin films in this order,""■ In the method for producing a decorative sheet according to (■) above, further comprising: A method for manufacturing a decorative sheet characterized by providing another embossed pattern of unevenness", "■ In the method for manufacturing a decorative sheet according to (■) above, a backing material is laminated on the colored thermoplastic resin film side. ``method for manufacturing a decorative material sheet according to item 1 above,'' and ``■ In the method for manufacturing a decorative sheet according to item 1 above, while providing another uneven embossed pattern on the side of the transparent or translucent thermoplastic resin film, the colored thermoplastic A method for manufacturing a decorative material sheet characterized by laminating a backing material on the resin film side."
図面を引用して、本発明を説明する。 The present invention will be explained with reference to the drawings.
第１図は、本発明の化粧材シートの一例を示すものであ
って、着色熱可塑性樹脂フィルム２の上側の面に凹凸の
エンボス模様５ａが設けられ、このエンボス面側に、透
明ないし半透明の耐熱圧性樹脂３が凹凸を埋めて積層さ
れ、その上に透明ないし半透明熱可塑性樹脂フィルム１
が積層されている。 第１図に示す化粧材シートを製造
するには、着色熱可塑性フィルム２の片面に適当なエン
ボス版、エンボスロールを用いたエンボス法により、凹
凸のエンボス模様５ａを設けた後、エンボス面側に透明
ないし半透明の耐熱圧性樹脂層３を塗装などにより、少
なくとも凹凸を埋約るようにして積層し、その上に透明
ないし半透明熱可塑性樹脂フィルム１を積層する。フィ
ルムｌの層３上への積層は層３を形成する組成物を塗布
し、塗布層を接着剤層として利用する接着法によっても
よいし、他の方法によってでもよい。FIG. 1 shows an example of a decorative material sheet of the present invention, in which an uneven embossed pattern 5a is provided on the upper surface of a colored thermoplastic resin film 2, and the embossed surface side is transparent or translucent. A heat-resistant and pressure-resistant resin 3 is laminated to fill the unevenness, and a transparent or translucent thermoplastic resin film 1 is placed on top of it.
are layered. In order to manufacture the decorative material sheet shown in FIG. 1, an uneven embossed pattern 5a is provided on one side of the colored thermoplastic film 2 by an embossing method using an appropriate embossing plate and an embossing roll, and then an uneven embossed pattern 5a is provided on one side of the colored thermoplastic film 2. A transparent or translucent heat-pressure resistant resin layer 3 is laminated by painting or the like so as to at least fill in the irregularities, and a transparent or translucent thermoplastic resin film 1 is laminated thereon. The film 1 may be laminated onto the layer 3 by an adhesive method in which a composition forming the layer 3 is applied and the applied layer is used as an adhesive layer, or by other methods.
また、必要に応じ、エンボス模様５ａ上に、絵柄層を設
けてもよい。Further, if necessary, a pattern layer may be provided on the embossed pattern 5a.
透明ないし半透明熱可塑性樹脂フィルム１としては、例
えば、ポリエチレン、ポリプロピレン等のポリオレフィ
ン系樹脂、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリ
ビニルアルコール、エチレン−酢酸ビニル共重合体、エ
チレン−ビニルアルコール共重合体、ポリ酢酸ビニル−
塩化ビニル共重合体、ポリフッ化ビニル、ポリビニルブ
チラール、ポリフッ化ビニリデン、ビニロン等のビニル
重合体樹脂、ポリスチレン、アクリルスチレン、ＡＢＳ
等のスチレン系樹脂、ポリメタクリル酸エチル、ポリメ
タクリル酸メチル、ポリアクリル酸ブチル、ポリアクリ
ロニトリルなどのアクリル系樹脂、ポリエチレンテレフ
タレート樹脂、ポリカーボネート樹脂等による厚さ２０
〜５００μ程度のフィルムで、塩化ビニル樹脂フィルム
で言えば、０〜１００ｐｈｒ、の可塑剤添加に相当する
硬度のフィルムが使用される。Examples of the transparent or translucent thermoplastic resin film 1 include polyolefin resins such as polyethylene and polypropylene, polyvinyl chloride, polyvinylidene chloride, polyvinyl alcohol, ethylene-vinyl acetate copolymer, ethylene-vinyl alcohol copolymer, polyvinyl acetate
Vinyl polymer resins such as vinyl chloride copolymer, polyvinyl fluoride, polyvinyl butyral, polyvinylidene fluoride, vinylon, polystyrene, acrylic styrene, ABS
Styrene resins such as polyethyl methacrylate, polymethyl methacrylate, polybutyl acrylate, acrylic resins such as polyacrylonitrile, polyethylene terephthalate resin, polycarbonate resin, etc. with a thickness of 20 mm.
A film with a hardness of about 500 μm and a vinyl chloride resin film, which corresponds to 0 to 100 phr of plasticizer addition, is used.
なお、透明ないし半透明熱可塑性樹脂フィルム１は、例
えば、パールクリヤー、カラークリヤー、無色クリヤー
等のフィルムであってもよく、下の層が透視できるもの
であればよい。The transparent or translucent thermoplastic resin film 1 may be, for example, a pearl clear film, a color clear film, a colorless clear film, etc., as long as the underlying layer can be seen through.
また、必要に応じ、透明ないし半透明熱可塑性樹脂フィ
ルム１の図中、上側もしくは下側の面に絵柄層６を設け
てもよい。Further, if necessary, a pattern layer 6 may be provided on the upper or lower surface of the transparent or translucent thermoplastic resin film 1 in the drawing.
また、着色熱可塑性樹脂フィルム２としては、透明ない
し半透明熱可塑性樹脂フィルム１となる熱可塑性樹脂フ
ィルムについて説明したものと同様の熱可塑性樹脂によ
る、厚さ２０〜１００μ程度の着色フィルムで、塩化ビ
ニル樹脂で言えば、０〜１００ ｐｈｒ、の可塑剤添加
に相当する硬度のものが使用される。In addition, the colored thermoplastic resin film 2 is a colored film of about 20 to 100 μm in thickness made of the same thermoplastic resin as that described for the thermoplastic resin film that becomes the transparent or translucent thermoplastic resin film 1. In terms of vinyl resin, those having a hardness corresponding to the addition of a plasticizer of 0 to 100 phr are used.
なお、着色熱可塑性樹脂フィルム２は、着色剤が含有さ
れている着色フィルムであっても、着色剤が含有されて
いるインクを用いた印刷もしくは塗装による着色フィル
ムであってもよく、着色剤としては普通のもの以外に、
アルミニウム、銅、真鍮等による金属を利用して得られ
る金属粉、金属箔片、金属蒸着合成フィルムの裁断等に
よる金属光沢を有する顔料をはじめ、酸化チタンで被覆
されている雲母、魚鱗箔、酸塩化ビスマス等による真珠
光沢〜干渉光沢を発する顔料などによる光輝性顔料など
のメタリック調ないしパール調のものであってもよい。The colored thermoplastic resin film 2 may be a colored film containing a colorant, or may be a colored film printed or painted using an ink containing a colorant. In addition to the ordinary ones,
Metal powder obtained using metals such as aluminum, copper, and brass, metal foil pieces, pigments with metallic luster obtained by cutting metallized synthetic films, mica coated with titanium oxide, fish scale foil, and acids. Metallic or pearlescent pigments such as bright pigments such as pigments such as bismuth chloride that produce pearlescent to interference luster may also be used.
また、透明ないし半透明の耐熱圧性樹脂３としては、Ｕ
Ｖ、ＥＢ等による電離放射線硬化性樹脂が良く、最も耐
熱圧性に優れている。この電離放射線硬化性樹脂として
は、分子中に重合性不飽和結合もしくはエポキシ基を有
するプレポリマー、オリゴマー又は単量体を用いる。ま
た、上記プレポリマー、オリゴマー及び単量体を必要に
応じ、１種もしくは２種以上混合して用いてもよい。In addition, as the transparent or semitransparent heat and pressure resistant resin 3, U
Ionizing radiation curable resins such as V and EB are good and have the best heat and pressure resistance. As this ionizing radiation-curable resin, a prepolymer, oligomer or monomer having a polymerizable unsaturated bond or an epoxy group in the molecule is used. Further, the above prepolymers, oligomers and monomers may be used alone or in combination of two or more, if necessary.
前記プレポリマー及びオリゴマーとしては、不飽和カル
ボン酸と多価アルコールの縮合物等の不飽和ポリエステ
ル類、ポリエステルメタクリレート、ポリエーテルメタ
クリレート、ポリオールメタクリレート、メラミンメタ
クリレート等のメタクリレート類、ポリエステルアクリ
レート、エポキシアクリレート、ウレタンアクリレート
、ポリエーテルアクリレート、ポリオールアクリレート
、メラミンアクリレート等のアクリレート類等がある。The prepolymers and oligomers include unsaturated polyesters such as condensates of unsaturated carboxylic acids and polyhydric alcohols, methacrylates such as polyester methacrylates, polyether methacrylates, polyol methacrylates, and melamine methacrylates, polyester acrylates, epoxy acrylates, and urethanes. There are acrylates such as acrylate, polyether acrylate, polyol acrylate, and melamine acrylate.
また、前記単量体としては、スチレン、αメチルスチレ
ン等のスチレン系単量体、アクリル酸メチル、アクリル
酸−２−エチルヘキシル、アクリル酸メトキシエチル、
アクリル酸ブトキシエチル、アクリル酸ブチル、アクリ
ル酸メトキシブチル、アクリル酸フェニル等のアクリル
酸エステル類、メタクリル酸メチル、メタクリル酸エチ
ル、メタクリル酸プロピル、メタクリル酸メトキシエチ
ル、メタクリル酸エトキシメチル、メタクリル酸フェニ
ル、メタクリル酸ラウリル等のメタクリル酸エステル類
、アクリル酸−２−（Ｎ、Ｎ−ジメチルアミノ）エチル
、アクリル酸−２−（Ｎ、Ｎ−ジベンジルアミノ）エチ
ル、メタクリル酸−２−（Ｎ％Ｎ−ジメチルアミノ）メ
チル、アクリル酸−２−（Ｎ。In addition, examples of the monomer include styrene monomers such as styrene and α-methylstyrene, methyl acrylate, 2-ethylhexyl acrylate, methoxyethyl acrylate,
Acrylic acid esters such as butoxyethyl acrylate, butyl acrylate, methoxybutyl acrylate, phenyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, methoxyethyl methacrylate, ethoxymethyl methacrylate, phenyl methacrylate, Methacrylic acid esters such as lauryl methacrylate, 2-(N,N-dimethylamino)ethyl acrylate, 2-(N,N-dibenzylamino)ethyl acrylate, 2-(N%N) methacrylate -dimethylamino)methyl, acrylic acid-2-(N.
Ｎ−ジエチルアミノ）プロピル等の不飽和酸の置換アミ
ノアルコールエステル類、アクリルアミド、メタクリル
アミド等の不飽和カルボン酸アミド、エチレングリコー
ルジアクリレート、プロピレングリコールジアクリレー
ト、ネオペンチルグリコールジアクリレート、１．６−
ヘキサンジオールジアクリレート、ジエチレングリコー
ルジアクリレート、トリエチレングリコールジアクリレ
ート等の化合物、ジブロブレンゲリコールジアクリレー
ト、エチレングリコールジアクリレート、プロピレング
リコールジメタクリレート、ジエチレングリコールジメ
タクリレート等の多官能性化合物、分子中に２個以上の
チオール基を有するポリチオール化合物等がある。Substituted amino alcohol esters of unsaturated acids such as N-diethylamino)propyl, unsaturated carboxylic acid amides such as acrylamide and methacrylamide, ethylene glycol diacrylate, propylene glycol diacrylate, neopentyl glycol diacrylate, 1.6-
Compounds such as hexanediol diacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, etc., polyfunctional compounds such as dibroblene gelicol diacrylate, ethylene glycol diacrylate, propylene glycol dimethacrylate, diethylene glycol dimethacrylate, etc., 2 in the molecule There are polythiol compounds having the above thiol groups.
なお、透明ないし半透明の耐熱圧性樹脂３として、ウレ
タン系樹脂、アクリル系樹脂等の２液硬化性樹脂、ある
いは酢酸セルロース系樹脂等の溶剤乾燥硬化性樹脂を用
いてもよく、上記電離放射線硬化性樹脂よりも耐熱圧性
は劣るが、加工適性はよく、コストは安くつく。Note that as the transparent or translucent heat-resistant and pressure-resistant resin 3, a two-component curable resin such as a urethane resin or an acrylic resin, or a solvent dry curable resin such as a cellulose acetate resin may be used. Although its heat and pressure resistance is inferior to plastic resins, it has good processability and is inexpensive.
耐熱圧性樹脂３をエンボス面側に積層するには、ワイピ
ング塗装やその他の塗装によって行う。The heat and pressure resistant resin 3 is laminated on the embossed surface side by wiping coating or other coating.
第２図に示す化粧材シートは、第１図に示す化粧材シー
トの透明ないし半透明熱可塑性樹脂フィルム１の上側に
熱圧成型により、別の凹凸のエンボス模様５ｂを設けた
ものである。The decorative material sheet shown in FIG. 2 is obtained by providing another uneven embossed pattern 5b on the upper side of the transparent or translucent thermoplastic resin film 1 of the decorative material sheet shown in FIG. 1 by hot pressure molding.
第２図に示す化粧材シートを製造するには、第１図に示
す化粧材シートを製造した後に、エンボス法により最上
面にエンボスするか、フィルムｌの積層と同時にエンボ
スすることによって行う。To manufacture the decorative material sheet shown in FIG. 2, after manufacturing the decorative material sheet shown in FIG. 1, the uppermost surface is embossed by an embossing method, or by embossing at the same time as the film 1 is laminated.
第３図に示す化粧材シートは、第１図に示す化粧材シー
トの着色熱可塑性樹脂フィルム２側に、裏打ち材４を熱
圧成型により積層したものである。The decorative material sheet shown in FIG. 3 is obtained by laminating a backing material 4 on the colored thermoplastic resin film 2 side of the decorative material sheet shown in FIG. 1 by hot pressure molding.
第３図に示す化粧材シートを製造するには、第１図に示
す化粧材シートを製造する過程に於いて、あるいはその
後に、着色熱可塑性樹脂フィルム２の下側に適当な方法
により裏打ち材４を積層することにより行う。In order to manufacture the decorative material sheet shown in FIG. 3, a backing material is applied to the underside of the colored thermoplastic resin film 2 by an appropriate method during or after the process of manufacturing the decorative material sheet shown in FIG. This is done by laminating 4.
裏打ち材４としては、化粧板の基板として通常に用いる
ものであるかぎり、どのようなものでもよく、例えば、
合板、パーティクルボードハードボード、インシュレー
ションボード等の木質系の基板、石膏ボード、石綿パー
ライト板、ケイ酸カルシウム板、グラスウール、ロック
ウール等の無機質基材、鉄板、亜鉛板、アルミニウム板
、鉛板、銅板等の金属系基板、発泡ポリエチレン板、発
泡ポリスチレン板、ウレタンフオーム、フェノールフオ
ーム等の発泡プラスチック板（フオーム基板）、フェノ
ール樹脂板、メラミン樹脂板、ポリエステル樹脂板、ア
クリル樹脂板、塩化ビニル樹脂板等の合成樹脂板等があ
る。前記したような基板は、同じもの同士、あるいは違
うもの同士を貼り合わせて複合し、複合板として使用し
てもよい。The backing material 4 may be of any material as long as it is commonly used as a substrate for decorative laminates; for example,
Wooden substrates such as plywood, particle board hardboard, insulation board, inorganic substrates such as gypsum board, asbestos perlite board, calcium silicate board, glass wool, rock wool, iron plate, zinc plate, aluminum plate, lead plate, Metal substrates such as copper plates, foamed polyethylene plates, foamed polystyrene plates, foamed plastic plates (foam substrates) such as urethane foam, phenol foam, phenolic resin plates, melamine resin plates, polyester resin plates, acrylic resin plates, vinyl chloride resin plates There are synthetic resin plates such as The above-mentioned substrates may be used as a composite board by bonding the same or different substrates together.
第４図に示す化粧材シートは、第１図に示す化粧材シー
トの透明ないし半透明熱可塑性樹脂フィルム１の上側に
、熱圧成型により、凹凸のエンボス模様５ｂを設け、か
つ着色熱可塑性樹脂フィルム２の下側に裏打ち材４を積
層したものである。The decorative material sheet shown in FIG. 4 has an uneven embossed pattern 5b formed by hot pressure molding on the upper side of the transparent or semitransparent thermoplastic resin film 1 of the decorative material sheet shown in FIG. 1, and is made of colored thermoplastic resin. A backing material 4 is laminated on the underside of the film 2.
第４図に示す化粧材シートを製造するには、第１図の化
粧材シートを製造する過程において、あるいはその後に
、透明ないし半透明熱可塑性樹脂フィルム１の上側にエ
ンボス法によりエンボス模様５ｂを設けること、及び着
色熱可塑性樹脂フィルム２の下側に裏打ち材４を積層す
ることによす行うが、エンボスすることと裏打ち材を積
層することを同時に行うと、いずれも加熱・加圧を伴う
のが普通であるので効率的である。In order to manufacture the decorative material sheet shown in FIG. 4, an embossed pattern 5b is formed on the upper side of the transparent or translucent thermoplastic resin film 1 by an embossing method during or after the manufacturing process of the decorative material sheet shown in FIG. However, if embossing and laminating the backing material are performed at the same time, heating and pressurization are involved. It is efficient because it is common.
前記構成の本番発明において、透明ないし半透明熱可塑
性樹脂フィルムｌと着色熱可塑性樹脂フィルム２との間
に、必要に応じ、１層以上の熱可塑性樹脂フィルムによ
る中間樹脂層を設けてもよく、また、この中間樹脂層に
絵柄層を設けてもよい。In the actual invention having the above structure, an intermediate resin layer of one or more thermoplastic resin films may be provided between the transparent or translucent thermoplastic resin film 1 and the colored thermoplastic resin film 2, if necessary. Further, a pattern layer may be provided on this intermediate resin layer.
次に、本発明の化粧材シート及びその製造方法の具体的
な構成を、図面実施例に基づいて説明する。Next, the specific structure of the decorative material sheet and the manufacturing method thereof of the present invention will be explained based on drawing examples.
実施例１
第２図において、透明ポリ塩化ビニルフイルムエ （理
研ビニル工業ｍ！Ｉｌ＞の裏面に絵柄層６を設けた。別
に厚さ８０μのパール練つ込みポリ塩化ビニルフィルム
２ （理研ビニル工業■製）の片面に凹凸のエンボス模
様５ａを設けた後、このエンボス面に透明ないし半透明
の耐熱圧性のある樹脂３をフローコーターにより、厚さ
６０μになるように塗布した。耐熱圧性樹脂３としては
ウレタンアクリル系の紫外線硬化性樹脂 （日本ペイン
ト側腹ンを用い、紫外線を照射することにより完全に硬
化させた後、この上に透明ポリ塩化ビニルフィルム１を
、絵柄層６側を接着面としてロールで押さえながら積層
した。更に透明ポリ塩化ビニルフィルム１の表面に熱圧
成型により、凹凸のエンボス模様５ｂを設けた。Example 1 In Fig. 2, a pattern layer 6 was provided on the back side of a transparent polyvinyl chloride film (RIKEN VINYL INDUSTRIAL M!Il). After providing an uneven embossed pattern 5a on one side of the embossed surface (manufactured by ■), a transparent or translucent heat-pressure resistant resin 3 was applied to the embossed surface using a flow coater to a thickness of 60 μm.Heat-pressure resistant resin 3 After completely curing the urethane acrylic UV-curable resin by irradiating it with ultraviolet rays (using Nippon Paint), place the transparent polyvinyl chloride film 1 on top of it, and place the pattern layer 6 side on the adhesive surface. The transparent polyvinyl chloride film 1 was further laminated with an uneven embossed pattern 5b on its surface by hot pressure molding.
得られた化粧材シートは、表面と内部の両方に凹凸模様
を有する、立体感のあるシートであった。The obtained decorative material sheet had an uneven pattern on both the surface and inside, and had a three-dimensional appearance.
実施例２
実施例１と同様にした後、ポリ塩化ビニルタイル４をパ
ール練り込み塩化ビニルフィルム２側に熱圧成型により
、積層した。Example 2 After carrying out the same procedure as in Example 1, a polyvinyl chloride tile 4 was layered on the pearl-kneaded vinyl chloride film 2 side by hot pressure molding.
得られた化粧材シートは、内部の凹凸模様が熱圧成前と
同様の凹凸形状を保っており、内部立体感のあるシート
であった。The resulting decorative material sheet had an internal three-dimensional effect, with the internal uneven pattern maintaining the same uneven shape as before hot-pressing.
実施例３
実施例１と同様にした後、透明ポリ塩化ビールフィルム
１の表面に熱圧成型により、凹凸のエンボス模様５ｂを
設けながら、ポリ塩化ビニルタイル４をパール練り込み
塩化ビニルフィルム２側に積層した。Example 3 After carrying out the same procedure as in Example 1, a polyvinyl chloride tile 4 was kneaded with pearls on the polyvinyl chloride film 2 side while providing an uneven embossed pattern 5b on the surface of the transparent polychlorinated beer film 1 by hot pressure molding. Laminated.
得られた化粧材シートは、内部の凹凸模様が熱圧成型前
と同様の凹凸形状を保っており、表面と内部の両方に凹
凸模様を有する、立体感のあるシートであり、プラスチ
ックタイルとして使用するのに適したものであった。The obtained decorative material sheet retains the same uneven pattern on the inside as before hot-pressing molding, and has a three-dimensional effect with uneven patterns on both the surface and inside, and is used as a plastic tile. It was suitable for doing so.
本発明の請求項１記載の化粧材シートにおいて、耐熱圧
性のある樹脂３が、着色熱可塑性樹脂フィルム２の凹凸
面に少なくとも凹部を埋めて介在するので、化粧材シー
トを製造する際にもこのエンボス模様５ａが消失するこ
とがなく、また前記化粧材シートに再び熱圧成型を施し
ても、エンボス模様５ａが消失することがない。In the decorative material sheet according to claim 1 of the present invention, since the resin 3 having heat and pressure resistance is interposed in the uneven surface of the colored thermoplastic resin film 2 by filling at least the recesses, this resin 3 is also used when manufacturing the decorative material sheet. The embossed pattern 5a does not disappear, and even if the decorative material sheet is subjected to hot-pressure molding again, the embossed pattern 5a does not disappear.
したがって、本発明の化粧材シートにおいてはいずれも
内部の凹凸のエンボス模様により、内部立体に富んでい
る。Therefore, the decorative material sheet of the present invention is rich in internal three-dimensionality due to the embossed pattern of internal irregularities.
また、請求項２記載の化粧材シートにおいては、更に透
明ないし半透明熱可塑性樹脂フィルム１の表面にも別の
凹凸模様５ｂが設けられており、この表面の凹凸模様に
よる立体感が加わって、化粧材シートの立体感が更に優
れている。Further, in the decorative material sheet according to claim 2, another uneven pattern 5b is further provided on the surface of the transparent or translucent thermoplastic resin film 1, and the uneven pattern on the surface adds a three-dimensional effect. The three-dimensional effect of the decorative material sheet is even better.
また、請求項３記載の化粧材シートにおいては、裏面に
裏打ち材を有するので、厚みの必要なプラスチックタイ
ル等の用途に適している。Furthermore, since the decorative material sheet according to the third aspect has a backing material on the back surface, it is suitable for applications such as plastic tiles that require thickness.
請求項４もしくは５の発明によればそれぞれ請求項１も
しくは２記載の化粧材シートが、請求項６または７の発
明によれば請求項３ｇ己載の化粧材シートがそれぞれ効
率よく製造できる。According to the invention of claim 4 or 5, the decorative sheet according to claim 1 or 2, respectively, can be efficiently produced, and according to the invention according to claim 6 or 7, the decorative sheet according to claim 3g can be manufactured efficiently.
第１図〜第４図はいずれも本発明の化粧材−シートの断
面図である。
１ 透明ないし半透明熱可塑性樹脂フィルム
２ 着色熱可塑性樹脂フィルム
透明なシ）シ半透明の耐熱圧性樹脂
裏打ち材
エンボス模様ａ
エンボス模様す
絵柄層1 to 4 are all cross-sectional views of the decorative material sheet of the present invention. 1 Transparent or translucent thermoplastic resin film 2 Colored thermoplastic resin film Transparent resin backing material Embossed pattern a Embossed pattern pattern layer
Claims (7)
凸のエンボス模様が設けられ、このエンボス面側に、透
明ないし半透明の耐熱圧性のある樹脂、及び透明ないし
半透明の熱可塑性樹脂フィルムがこの順に積層されてい
ることを特徴とする化粧材シート。(1) An uneven embossed pattern is provided on one side of a colored thermoplastic resin film, and a transparent or translucent heat-pressure resistant resin and a transparent or translucent thermoplastic resin film are placed on the embossed side. A decorative material sheet characterized by being laminated in this order.
ないし半透明熱可塑性樹脂フィルム側に更に別の凹凸の
エンボス模様が形成されていることを特徴とする化粧材
シート。(2) The decorative material sheet according to claim 1, further comprising another embossed pattern of projections and depressions formed on the side of the transparent or translucent thermoplastic resin film.
記着色熱可塑性樹脂フィルム側に裏打ち材が積層されて
いることを特徴とする化粧材シート。(3) The decorative material sheet according to claim 1 or 2, wherein a backing material is laminated on the colored thermoplastic resin film side.
凸のエンボス模様を設け、このエンボス面側に、透明な
いし半透明の耐熱圧性のある樹脂、及び透明ないし半透
明の熱可塑性樹脂フィルムをこの順に積層することを特
徴とする化粧材シートの製造方法。(4) An uneven embossed pattern is provided on one side of the colored thermoplastic resin film, and a transparent or translucent heat-pressure resistant resin and a transparent or translucent thermoplastic resin film are placed on the embossed side. A method for producing a decorative material sheet, the method comprising sequentially laminating layers.
、前記透明ないし半透明熱可塑性樹脂フィルム側に更に
別の凹凸のエンボス模様を設けることを特徴とする化粧
材シートの製造方法。(5) The method for producing a decorative material sheet according to claim 4, further comprising providing another embossed pattern of unevenness on the side of the transparent or translucent thermoplastic resin film.
、前記着色熱可塑性樹脂フィルム側に裏打ち材を積層す
ることを特徴とする化粧材シートの製造方法。(6) The method for manufacturing a decorative material sheet according to claim 4, wherein a backing material is laminated on the colored thermoplastic resin film side.
、前記透明ないし半透明熱可塑性樹脂フィルム側に更に
別の凹凸のエンボス模様を設けながら、前記着色熱可塑
性樹脂フィルム側に裏打ち材を積層することを特徴とす
る化粧材シートの製造方法。(7) In the method for producing a decorative material sheet according to claim 4, a backing material is laminated on the colored thermoplastic resin film side while providing another uneven embossed pattern on the transparent or translucent thermoplastic resin film side. A method for producing a decorative material sheet, characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2249192A JP3016034B2 (en) | 1990-09-19 | 1990-09-19 | Cosmetic material sheet and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2249192A JP3016034B2 (en) | 1990-09-19 | 1990-09-19 | Cosmetic material sheet and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04128041A true JPH04128041A (en) | 1992-04-28 |
| JP3016034B2 JP3016034B2 (en) | 2000-03-06 |
Family
ID=17189271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2249192A Expired - Lifetime JP3016034B2 (en) | 1990-09-19 | 1990-09-19 | Cosmetic material sheet and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3016034B2 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06115298A (en) * | 1992-09-01 | 1994-04-26 | Nankai Plywood Kk | Decorative board and manufacture thereof |
| JPH07125151A (en) * | 1993-10-29 | 1995-05-16 | Kyodo Printing Co Ltd | Mirror-finished decorative plate and manufacture thereof |
| JP2010234709A (en) * | 2009-03-31 | 2010-10-21 | C I Kasei Co Ltd | Decorative sheet and method for manufacturing the same |
| JP2010234708A (en) * | 2009-03-31 | 2010-10-21 | C I Kasei Co Ltd | Decorative sheet and method for manufacturing the same |
| WO2011013659A1 (en) * | 2009-07-31 | 2011-02-03 | 日本写真印刷株式会社 | Method for producing decorative sheet |
| WO2017102047A1 (en) * | 2015-12-15 | 2017-06-22 | Merck Patent Gmbh | Method for creating virtual three-dimensional patterns in molded bodies |
| JP2018058223A (en) * | 2016-09-30 | 2018-04-12 | 大日本印刷株式会社 | Decorative sheet, manufacturing method of decorative sheet, decorative resin molding and manufacturing method of decorative resin molding |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6387028U (en) * | 1986-11-26 | 1988-06-07 | ||
| JPH0292634A (en) * | 1988-09-30 | 1990-04-03 | Dainippon Printing Co Ltd | Stereoscopic decorative plate and manufacture thereof |
-
1990
- 1990-09-19 JP JP2249192A patent/JP3016034B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6387028U (en) * | 1986-11-26 | 1988-06-07 | ||
| JPH0292634A (en) * | 1988-09-30 | 1990-04-03 | Dainippon Printing Co Ltd | Stereoscopic decorative plate and manufacture thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06115298A (en) * | 1992-09-01 | 1994-04-26 | Nankai Plywood Kk | Decorative board and manufacture thereof |
| JPH07125151A (en) * | 1993-10-29 | 1995-05-16 | Kyodo Printing Co Ltd | Mirror-finished decorative plate and manufacture thereof |
| JP2010234709A (en) * | 2009-03-31 | 2010-10-21 | C I Kasei Co Ltd | Decorative sheet and method for manufacturing the same |
| JP2010234708A (en) * | 2009-03-31 | 2010-10-21 | C I Kasei Co Ltd | Decorative sheet and method for manufacturing the same |
| WO2011013659A1 (en) * | 2009-07-31 | 2011-02-03 | 日本写真印刷株式会社 | Method for producing decorative sheet |
| WO2017102047A1 (en) * | 2015-12-15 | 2017-06-22 | Merck Patent Gmbh | Method for creating virtual three-dimensional patterns in molded bodies |
| US10821640B2 (en) | 2015-12-15 | 2020-11-03 | Merck Patent Gmbh | Process for the production of virtual three-dimensional patterns in mouldings |
| JP2018058223A (en) * | 2016-09-30 | 2018-04-12 | 大日本印刷株式会社 | Decorative sheet, manufacturing method of decorative sheet, decorative resin molding and manufacturing method of decorative resin molding |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3016034B2 (en) | 2000-03-06 |
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