JPH04122797A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPH04122797A JPH04122797A JP24518290A JP24518290A JPH04122797A JP H04122797 A JPH04122797 A JP H04122797A JP 24518290 A JP24518290 A JP 24518290A JP 24518290 A JP24518290 A JP 24518290A JP H04122797 A JPH04122797 A JP H04122797A
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- present
- surfactants
- acid ester
- formulas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- 239000003599 detergent Substances 0.000 title abstract description 10
- -1 fatty acid ester Chemical class 0.000 claims abstract description 36
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 20
- 239000000194 fatty acid Substances 0.000 claims abstract description 20
- 229930195729 fatty acid Natural products 0.000 claims abstract description 20
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 18
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 14
- 239000004359 castor oil Substances 0.000 claims abstract description 11
- 235000019438 castor oil Nutrition 0.000 claims abstract description 11
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 5
- 238000004140 cleaning Methods 0.000 claims description 21
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 11
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 13
- 239000004094 surface-active agent Substances 0.000 abstract description 7
- 125000000129 anionic group Chemical group 0.000 abstract 2
- 210000004400 mucous membrane Anatomy 0.000 abstract 2
- 229940126062 Compound A Drugs 0.000 abstract 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 abstract 1
- 230000007794 irritation Effects 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 5
- 206010040880 Skin irritation Diseases 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- 230000036556 skin irritation Effects 0.000 description 4
- 231100000475 skin irritation Toxicity 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 241000283973 Oryctolagus cuniculus Species 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 206010040914 Skin reaction Diseases 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003889 eye drop Substances 0.000 description 2
- 229940012356 eye drops Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 231100000017 mucous membrane irritation Toxicity 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000035483 skin reaction Effects 0.000 description 2
- 231100000430 skin reaction Toxicity 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 241000283977 Oryctolagus Species 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical class C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- 210000000795 conjunctiva Anatomy 0.000 description 1
- 210000004087 cornea Anatomy 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000011597 hartley guinea pig Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 210000000554 iris Anatomy 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は皮膚刺激性、眼粘膜刺激性の極めて少ない洗浄
剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a detergent composition with extremely low skin irritation and eye mucosal irritation.
［従来の技術］
洗浄用界面活性剤としては、アニオン性界面活性剤、ノ
ニオン性界面活性剤、そして両性界面活性剤等がある。[Prior Art] Examples of cleaning surfactants include anionic surfactants, nonionic surfactants, and amphoteric surfactants.
アニオン性界面活性剤の代表例としては、アルキルサル
フェート、アルキルエーテルサルフェート等がある。こ
れらは、洗浄力に優れていることから、洗顔用やシャン
プー剤等の洗浄剤に配合使用されている。しかしこれら
は皮膚刺激性が強く、手荒れ等の皮膚障害を起こしやす
い欠点がある。Typical examples of anionic surfactants include alkyl sulfates and alkyl ether sulfates. Since these have excellent detergency, they are used in detergents such as face washes and shampoos. However, these have the drawback of being highly irritating to the skin and easily causing skin disorders such as rough hands.
又毛髪に対しても吸着しやすく洗浄性も強いことから毛
髪のなめらかき、櫛通り等を悪化させていてその改善が
強く望まれている。Furthermore, since it easily adsorbs to the hair and has a strong detergency, it impairs the smoothness and combability of the hair, and there is a strong desire to improve this problem.
皮膚刺激剤の少ない界面活性剤としてはノニオン性界面
活性剤がある。代表例としはグリセリン高級脂肪酸エス
テル、ショ糖高級脂肪酸エステル、ソルビタン高級脂肪
酸エステルなどがあげられる。Nonionic surfactants are examples of surfactants that are less irritating to the skin. Representative examples include glycerin higher fatty acid ester, sucrose higher fatty acid ester, and sorbitan higher fatty acid ester.
これらのノニオン性界面活性剤はアニオン性界面活性剤
に比べて低刺激性ではあるものの、泡立ちが悪く、シャ
ンプー、洗顔料、ボディ洗浄料や台所洗剤の要求を満足
することはできない。Although these nonionic surfactants are less irritating than anionic surfactants, they do not foam well and cannot satisfy the requirements for shampoos, face washes, body washes, and kitchen detergents.
そして通常よく使用されているノニオン性界面活性剤と
しては、脂肪酸とアミンの縮合物であるアマイド類があ
り、アニオン性界面活性剤との併用で利用されることが
多い。そのために皮膚刺激性の改善どころかその作用を
さらに強めているのが現状である。Commonly used nonionic surfactants include amides, which are condensates of fatty acids and amines, and are often used in combination with anionic surfactants. Therefore, rather than improving skin irritation, the current situation is that the effect is further strengthened.
両性界面活性剤には比較的刺激の少ないといわれている
イミダシリン型ベタインやアニオン性界面活性剤と同程
度の強い刺激性をもつジメチルベタインやアミンオキサ
イドなどが挙げられる。これら両性界面活性剤は泡質、
洗浄力等の点で弱さをもつため、単独で使用することは
少なく近年アニオン性界面活性剤との併用が多い。そし
て特定のアニオン性界面活性剤との特定の比率の配合に
よって刺激性が改善されるという特性がみられる。Examples of amphoteric surfactants include imidacillin-type betaine, which is said to be relatively mild, and dimethyl betaine and amine oxide, which have strong irritation comparable to anionic surfactants. These amphoteric surfactants have foamy properties,
Due to its weak detergency, it is rarely used alone, and in recent years it has often been used in combination with anionic surfactants. It has been found that irritation can be improved by blending with a specific anionic surfactant in a specific ratio.
しかしその低減の程度は十分なものではなく大幅な改善
が望まれている。However, the degree of reduction is not sufficient and significant improvement is desired.
このような背景と生活水準の高度化に伴い人体に対する
安全な性質を有する低刺激界面活性剤や洗浄剤組成物の
開発が強く要望されるようになってきているのが現状で
ある。Against this background and with the advancement of living standards, there is currently a strong demand for the development of mild surfactants and detergent compositions that are safe for the human body.
［発明が解決しようとする課題］
本発明者らはこのような事情に鑑み、洗浄用として使用
されているアニオン性界面活性剤及び両性界面活性剤の
それぞれのもつ皮膚刺激性及び眼粘膜刺激性について鋭
意研究した結果、これらの界面活性剤と、特定の化合物
とを特定比率で配合することにより解決できることを見
出し本発明を完成するに至った。[Problems to be Solved by the Invention] In view of the above circumstances, the present inventors have investigated the skin irritation and ocular mucosal irritation properties of anionic surfactants and amphoteric surfactants used for cleaning. As a result of intensive research on the above, it was discovered that the problem could be solved by blending these surfactants with a specific compound in a specific ratio, and the present invention was completed.
［課題を解決するための手段］
すなわち本発明の第１項は、
（Ｉ）ポリオキシエチレン硬化ヒマシ油の脂肪酸エステ
ルと、（ＩＩ）アニオン性界面活性剤及び両性界面活性
剤からなる群から選ばれる１種又は２種以上とを含有し
、（Ｉ）／（ＩＩ）の重量比が９７１〜１／５であるこ
とを特徴とする洗浄剤組成物であり、本発明の第２項は
、（１，）ポリオキシエチレン硬化ヒマシ油の脂肪酸エ
ステルと、（ＩＩ ）下記一般式［Ａ］乃至［Ｄ］で表
される化合物より選ばれたポリオキシアルキレン変性オ
ルガノポリシロキサンの１種又は２種以上と、（ＩＩＩ
）アニオン性界面活性剤及び両性界面活性剤からなる
群から選ばれるの１種又は２種以上とを含有し、（■）
＋（ＩＩ）／（ＩＩＩ）の重量比が９７１〜１／５であ
ることを特徴とする洗浄剤組成物である。[Means for Solving the Problems] That is, the first aspect of the present invention is to provide a polyoxyethylene hydrogenated castor oil fatty acid ester, and (II) an anionic surfactant and an amphoteric surfactant. The second aspect of the present invention is a cleaning composition, characterized in that the weight ratio of (I)/(II) is 971 to 1/5. (1,) fatty acid ester of polyoxyethylene hydrogenated castor oil; and (II) one or two polyoxyalkylene-modified organopolysiloxanes selected from compounds represented by the following general formulas [A] to [D]. Above, (III
) Contains one or more selected from the group consisting of anionic surfactants and amphoteric surfactants, (■)
A cleaning composition characterized in that the weight ratio of +(II)/(III) is 971 to 1/5.
（以下余白） 以下、本発明の構成について詳述する。(Margin below) Hereinafter, the configuration of the present invention will be explained in detail.
本発明に用いられるポリオキシエチレン硬化ヒマシ油の
脂肪酸エステルは、下記一般式［Ｅ］〜［Ｇ］で表され
、長鎖の酸化エチレン基を有するものであるが、硬化ヒ
マシ油の脂肪酸エステルに対する酸化エチレンの付加モ
ル数は２０〜３００重量％のものが適当である。中でも
脂肪酸としては、ラウリン酸、ミリスチン酸及びイソス
テアリン酸が好ましい。特に好ましくはこれら脂肪酸の
モノ又はトリエステルである。また酸化エチレン付加モ
ル数は、好ましくは４０〜２００であるが、特に好まし
くは５０〜１５０である。該付加モル数が２０未満では
、均一な混合系ができにくり、３００を超えると増粘し
すぎて好ましくない。The fatty acid ester of polyoxyethylene hydrogenated castor oil used in the present invention is represented by the following general formulas [E] to [G] and has a long chain ethylene oxide group. The appropriate number of moles of ethylene oxide added is 20 to 300% by weight. Among the fatty acids, lauric acid, myristic acid and isostearic acid are preferred. Particularly preferred are mono- or tri-esters of these fatty acids. The number of moles of ethylene oxide added is preferably 40 to 200, particularly preferably 50 to 150. If the number of moles added is less than 20, a homogeneous mixed system cannot be obtained, and if it exceeds 300, the viscosity increases too much, which is not preferable.
（以下余白）
（ＯＣＨ２ＣＨ２）−０Ｃｏ Ｃ，−ＬＨ２ｎ［Ｅ］
（ＯＣＨ２ＣＨ２）、 ＯＣｏ Ｃｎ−ＬＨ２゜［
Ｆ］
（ＯＣＨ２ＣＨ２）−０ＣＯＣｎ−ＩＨ２ｏ−１［Ｇ］
（式中、ａ）ｂ）ｃはポリオキシエチレン基の付加モル
数で、ａ ＋ ｂ ＋ ｃ ＝２０−３００で、ｎはＣ
Ｉ２〜Ｃ２２である。）
本発明に用いられるアニオン性界面活性剤としては、脂
肪酸石鹸、アルカンジオール酢酸エーテル塩、エーテル
カルボン酸塩、α−アシルスルフォン酸塩、アルキルス
ルホン酸塩、アルキルスルホコハク酸塩、脂肪酸エステ
ルの硫酸エステル塩、アルキル硫酸塩、アルキルアミド
硫酸エステル塩、アルキルアミドのスルフォン酸塩、ア
ルキルリン酸塩、アルキルアミドリン酸塩等が挙げられ
る。(Left below) (OCH2CH2)-0Co C,-LH2n[E] (OCH2CH2), OCo Cn-LH2゜[
F] (OCH2CH2)-0COCn-IH2o-1[G] (In the formula, a) b) c are the number of added moles of polyoxyethylene group, a + b + c = 20-300, and n is C
They are I2 to C22. ) The anionic surfactants used in the present invention include fatty acid soaps, acetic acid ether salts of alkanediols, ether carboxylates, α-acyl sulfonates, alkyl sulfonates, alkyl sulfosuccinates, and sulfuric acid esters of fatty acid esters. Examples include salts, alkyl sulfates, alkylamide sulfate ester salts, alkylamide sulfonates, alkyl phosphates, and alkylamide phosphates.
本発明で用いられる両性界面活性剤としては、ベタイン
型（カルボキシベタイン、スルホベタイン）、アミノカ
ルボン酸塩型、イミダシリン誘導体型等が挙げられ、特
にイミダプリン誘導体型が好ましい。Examples of the amphoteric surfactant used in the present invention include betaine type (carboxybetaine, sulfobetaine), aminocarboxylate type, imidacillin derivative type, etc., and imidapurine derivative type is particularly preferred.
本発明の請求項２に用いられるポリオキシアルキレン変
性オルガノポリシロキサンは、上記一般式［Ａ］〜［Ｄ
］で表きれる化合物である。平均分子量は３０００以上
を有するものが好ましく、更に好ましくは５０００以上
である。また、ポリオキシアルキレン変性オルガノポリ
シロキサン分子中にポリオキシアルキレン基を２〜４０
重量％含有するものが好ましく、効果発現の面から更に
好ましくは、２〜２９重量％である。The polyoxyalkylene-modified organopolysiloxane used in claim 2 of the present invention has the above general formulas [A] to [D
] It is a compound that can be expressed as follows. The average molecular weight is preferably 3,000 or more, more preferably 5,000 or more. In addition, 2 to 40 polyoxyalkylene groups are added to the polyoxyalkylene-modified organopolysiloxane molecule.
The content is preferably 2% to 29% by weight, and more preferably 2 to 29% by weight from the viewpoint of achieving effects.
本発明の請求項１の洗浄剤組成物においては、ポリオキ
シエチレン硬化ヒマシ油の脂肪酸エステルと、アニオン
性界面活性剤及び両性界面活性剤の一種又は二種以上と
の配合比は９７１〜１／５の範囲にある必要があり、特
に好ましくは、９７１〜３１５である。上記の配合比の
範囲外では本発明の効果を得ることはできない。In the cleaning composition according to claim 1 of the present invention, the blending ratio of the fatty acid ester of polyoxyethylene hydrogenated castor oil and one or more of anionic surfactants and amphoteric surfactants is 971 to 1/2. It needs to be in the range of 5, particularly preferably 971-315. The effects of the present invention cannot be obtained outside the above blending ratio range.
本発明の請求項２の洗浄剤組成物においては、ポリオキ
シエチレン硬化ヒマシ油の脂肪酸エステルとポリオキシ
アルキレン変性オルガノポリシロキサンとの合計量と、
アニオン性界面活性剤び両性界面活性剤の一種又は二種
以上との配合比は９７１〜１／５の範囲にある必要があ
り、特に好ましくは、９７１〜３１５である。上記の配
合比の範囲外では本発明の効果を得ることはできない。In the cleaning composition according to claim 2 of the present invention, the total amount of fatty acid ester of polyoxyethylene hydrogenated castor oil and polyoxyalkylene-modified organopolysiloxane;
The blending ratio of one or more anionic surfactants and amphoteric surfactants must be in the range of 971 to 1/5, particularly preferably 971 to 315. The effects of the present invention cannot be obtained outside the above blending ratio range.
本発明においては、洗浄剤組成物を調製する際、エタノ
ールを適量配合すると特に好ましい。調製方法としては
例えば、アニオン性界面活性剤及ヒ両性界面活性剤の１
種又は２種以上を少量の水に溶解せしめた後、ポリオキ
シエチレン硬化ヒマシ油の脂肪酸エステルまたは、ポリ
オキシエチレン硬化しマシ油の脂肪酸エステルとポリオ
キシアルキレン変性オルガノポリシロキサンとを添加し
、加熱混合撹拌し、同温度の水で稀釈することにょって
得られる。特に好ましい調製法としては、この両成分を
混合撹拌する際適量のエタノールを添加する方法で、容
易に目的とする組成物を得ることができる。In the present invention, when preparing the cleaning composition, it is particularly preferable to add an appropriate amount of ethanol. The preparation method includes, for example, one of anionic surfactants and amphoteric surfactants.
After dissolving the seeds or two or more in a small amount of water, a fatty acid ester of polyoxyethylene hydrogenated castor oil or a fatty acid ester of polyoxyethylene hydrogenated mustard oil and a polyoxyalkylene-modified organopolysiloxane are added and heated. It is obtained by mixing and stirring and diluting with water at the same temperature. A particularly preferred preparation method is a method in which an appropriate amount of ethanol is added when mixing and stirring these two components, whereby the desired composition can be easily obtained.
本発明の洗浄剤組成物は透明又は不透明均一系で、さら
にこの組成物に水添加したものも透明又は不透明均一系
で有用である。The cleaning composition of the present invention is a transparent or opaque homogeneous type, and a composition containing water added thereto is also useful as a transparent or opaque homogeneous type.
又本発明の洗浄剤組成物に必要に応じて疎水性シリコー
ン、分枝高級アルコール、液状炭化水素、液状エステル
油分等の油性物質を配合することができる。Further, oily substances such as hydrophobic silicones, branched higher alcohols, liquid hydrocarbons, and liquid ester oils can be blended into the cleaning composition of the present invention, if necessary.
本発明の洗浄剤組成物には、更に必要に応じて保湿剤、
香料、防腐剤等を配合することができる。The cleaning composition of the present invention may further include a moisturizer, if necessary.
Flavors, preservatives, etc. can be added.
なお、これらは本発明の目的を損なわない質的、量的条
件下で使用されなければならない。In addition, these must be used under qualitative and quantitative conditions that do not impair the purpose of the present invention.
本発明の洗浄剤組成物は、シャンプー剤、ボディ用洗浄
剤、洗顔料、メイク落し用洗浄剤、乳児用シャンプー、
台所用液体洗剤、医療用洗浄剤等、その他各種の用途に
利用できる。The cleaning composition of the present invention can be applied to shampoos, body cleansers, facial cleansers, make-up removers, infant shampoos,
It can be used for a variety of other purposes, including kitchen liquid detergents and medical cleaning agents.
［発明の効果］
本発明は、ポリオキシエチレン硬化ヒマシ油の脂肪酸エ
ステルまたは、ポリオキシエチレン硬化ヒマシ油の脂肪
酸エステルとポリオキシアルキレン変性オルガノポリシ
ロキサンと、アニオン性界面活性剤及び両性界面活性剤
の１種又は２種以上とを特定比率で配合することにより
無刺激性の洗浄剤組成物を捷供するものである。[Effects of the Invention] The present invention provides a combination of a fatty acid ester of polyoxyethylene hydrogenated castor oil or a fatty acid ester of polyoxyethylene hydrogenated castor oil, a polyoxyalkylene-modified organopolysiloxane, an anionic surfactant, and an amphoteric surfactant. By blending one type or two or more types in a specific ratio, a non-irritating cleaning composition can be prepared.
［実施例］
次に実施例及び比較例をあげて本発明を具体的に説明す
る。本発明はこれ゛により限定されるものではない。配
合量は重量％である。実施例に先立ち評価法を以下に示
す。[Example] Next, the present invention will be specifically explained with reference to Examples and Comparative Examples. The present invention is not limited thereby. The blending amount is in weight%. Prior to Examples, evaluation methods are shown below.
、 ゛テスト
体重３００〜５００ｇの健常なハートレイ系モルモット
の皮膚に試料０ 、３ ＊ｔを塗布して２４時間放置す
る。Samples 0 and 3*t were applied to the skin of a healthy Hartley guinea pig weighing 300 to 500 g and left for 24 hours.
２４時間後に皮膚反応を判定し、その後２回目の塗布を
行う。そして２４時間後判定。その後３回目の塗布を行
い、２４時間後判定する。この３回の塗布に基づく皮膚
反応の平均値を算出し、皮膚累積刺激性を評価した。Skin reaction is determined after 24 hours, followed by a second application. Judgment will be made 24 hours later. Thereafter, a third application is performed and a judgment is made 24 hours later. The average value of the skin reactions based on these three applications was calculated to evaluate cumulative skin irritation.
０・・・・・・殆ど刺激性なし
Ｏ・・・・・・弱い刺激性
へ・・・・・・中程度の刺激性
×・・・・・・強い刺激性
ｉ ’ｉ
体重３〜３ 、５Ｋｇ０家兎を用い、１群６匹としてそ
の右眼に試料を夫々０ 、１ ｍＮ点眼し、６匹の内３
匹は点眼したまま洗眼を行なわずに放置し残り３匹は点
眼１０秒後に２０ｍ１の温水にて洗眼を行なった。0... Almost no irritation O... To weak irritation... Moderate irritation ×... Strong irritation i 'i Weight 3-3 Using 5kg0 domestic rabbits, 0 and 1 mN of the sample were instilled into the right eye of each group of 6 rabbits, and 3 of the 6 rabbits received 0 and 1 mN, respectively.
The animals were left with the eye drops in place without washing their eyes, and the remaining three animals were washed with 20 ml of warm water 10 seconds after the eye drops were instilled.
判定法としては、点眼後２４．４８．７２．９６および
１６８時間にわたりスリットランプを用い、左眼を対照
として刺激の程度を観察した。As a determination method, the degree of irritation was observed using a slit lamp for 24.48.72.96 and 168 hours after instillation, using the left eye as a control.
これらの判定については、結膜、角膜、虹彩等を対象と
した。なお、これらの各部の刺激反応については、すべ
てＤｒａ ｉｚｅ点数評価基準に準じた。For these determinations, the conjunctiva, cornea, iris, etc. were targeted. The stimulation responses of these parts were all based on the Draize score evaluation criteria.
０・・・・・・殆ど刺激性なし ○・・・・・・弱い刺激性 △・・・・・・中程度の刺激性 ×・・・・・・強い刺激性 実施例１〜９、 比較例１ 下記表− に示す洗浄剤組成物を調製し評価し た。0...Almost no irritation ○・・・・・・Weak irritation △・・・・・・Moderate irritation ×・・・strong irritation Examples 1 to 9, Comparative example 1 Table below- The cleaning composition shown in was prepared and evaluated. Ta.
ポリオキシアルキレン基２０重量％
表−１から明らかなように本発明の組成物は、刺激が極
めて少ない、洗浄剤組成物であることがわかる。20% by weight of polyoxyalkylene groups As is clear from Table 1, the composition of the present invention is a cleaning composition with extremely little irritation.
実施例１０〜１３、比較例２〜４ 下記表−２に示す洗浄剤組成物を調製し評価した。Examples 10-13, Comparative Examples 2-4 Cleaning compositions shown in Table 2 below were prepared and evaluated.
表−２から明らかなように本発明の組成物は、刺激が極
めて少ない、
洗浄剤組成物であることが
わかる。As is clear from Table 2, the composition of the present invention is a cleaning composition that causes very little irritation.
実施例１４〜１６、 比較例５〜？ 下記表−３に示す洗浄剤組成物を調製し評価した。Examples 14-16, Comparative example 5~? Cleaning compositions shown in Table 3 below were prepared and evaluated.
（以下余白）
ポリオキシアルキレン基２０１量％
表−３から明らかなように本発明の組成物は、刺激が極
めて少ない、
洗浄剤組成物であることが
わかる。(The following is a blank space) Polyoxyalkylene group 201% by weight As is clear from Table 3, the composition of the present invention is a cleaning composition with extremely little irritation.
実施例１７〜２０、 比較例８〜１０ 下記表−４に示す洗浄剤組成物を調製し評価した。Examples 17-20, Comparative examples 8-10 Cleaning compositions shown in Table 4 below were prepared and evaluated.
ネ１４
ドデシル硫酸ナトリウム
表−４から明らかなように本発明の組成物は、刺激が極
めて少ない、
洗浄剤組成物であることが
わかる。14 Sodium dodecyl sulfate As is clear from Table 4, the composition of the present invention is a detergent composition with extremely little irritation.
Claims (2)
酸エステルと、（II）アニオン性界面活性剤及び両性界
面活性剤からなる群から選ばれる１種又は２種以上とを
含有し、（ I ）／（II）の重量比が９／１〜１／５で
あることを特徴とする洗浄剤組成物。(1) Contains (I) fatty acid ester of polyoxyethylene hydrogenated castor oil and (II) one or more selected from the group consisting of anionic surfactants and amphoteric surfactants, (I) A cleaning composition characterized in that the weight ratio of /(II) is 9/1 to 1/5.
酸エステルと、（II）下記一般式［Ａ］乃至［Ｄ］で表
される化合物より選ばれたポリオキシアルキレン変性オ
ルガノポリシロキサンの１種又は２種以上と、（III）
アニオン性界面活性剤及び両性界面活性剤からなる群か
ら選ばれるの１種又は２種以上とを含有し、（ I ）＋
（II）／（III）の重量比が９／１〜１／５であること
を特徴とする洗浄剤組成物。 ▲数式、化学式、表等があります▼［Ａ］ ▲数式、化学式、表等があります▼［Ｂ］ ▲数式、化学式、表等があります▼［Ｃ］ ▲数式、化学式、表等があります▼［Ｄ］ （式中、Ｒは炭素数１乃至３のアルキル基、又はフエニ
ル基、Ｒ′は水素、又は炭素数１乃至１２のアルキル基
、ｐは１乃至５の整数、ｍは０乃至１００の整数、ｎお
よびｘは１乃至５０の整数、ｔおよびｙは０乃至５０の
整数である。）(2) (I) fatty acid ester of polyoxyethylene hydrogenated castor oil; and (II) one type of polyoxyalkylene-modified organopolysiloxane selected from compounds represented by the following general formulas [A] to [D]; or 2 or more types and (III)
(I)+
A cleaning composition characterized in that the weight ratio of (II)/(III) is 9/1 to 1/5. ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [A] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [B] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [C] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [ D] (wherein, R is an alkyl group having 1 to 3 carbon atoms or a phenyl group, R' is hydrogen or an alkyl group having 1 to 12 carbon atoms, p is an integer of 1 to 5, and m is an integer of 0 to 100. (Integers, n and x are integers from 1 to 50, and t and y are integers from 0 to 50.)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24518290A JPH04122797A (en) | 1990-09-14 | 1990-09-14 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24518290A JPH04122797A (en) | 1990-09-14 | 1990-09-14 | Detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04122797A true JPH04122797A (en) | 1992-04-23 |
Family
ID=17129835
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24518290A Pending JPH04122797A (en) | 1990-09-14 | 1990-09-14 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04122797A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997040125A1 (en) * | 1996-04-24 | 1997-10-30 | Unilever Plc | Liquid compositions comprising hydrophobically modified polyalkylene glycols as mildness actives |
| US6290944B1 (en) | 1999-02-16 | 2001-09-18 | L'oreal S.A. | Detergent compositions containing an hydroxylalkyl ether surfactant and a cationic guar gum |
| US6368584B1 (en) | 2000-02-15 | 2002-04-09 | L'oreal S.A. | Detergent cosmetic compositions comprising an anionic hydroxyalkyl ether surfactant and a silicone, and their uses |
| US6511669B1 (en) | 1999-02-16 | 2003-01-28 | L'oreal S.A. | Cosmetic compositions containing an anionic hydroxyalkyl ether surfactant and a cationic polymer, and uses thereof |
| JP2009062293A (en) * | 2007-09-05 | 2009-03-26 | Hoyu Co Ltd | Oxidizing agent composition |
-
1990
- 1990-09-14 JP JP24518290A patent/JPH04122797A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997040125A1 (en) * | 1996-04-24 | 1997-10-30 | Unilever Plc | Liquid compositions comprising hydrophobically modified polyalkylene glycols as mildness actives |
| US6290944B1 (en) | 1999-02-16 | 2001-09-18 | L'oreal S.A. | Detergent compositions containing an hydroxylalkyl ether surfactant and a cationic guar gum |
| US6511669B1 (en) | 1999-02-16 | 2003-01-28 | L'oreal S.A. | Cosmetic compositions containing an anionic hydroxyalkyl ether surfactant and a cationic polymer, and uses thereof |
| US6368584B1 (en) | 2000-02-15 | 2002-04-09 | L'oreal S.A. | Detergent cosmetic compositions comprising an anionic hydroxyalkyl ether surfactant and a silicone, and their uses |
| JP2009062293A (en) * | 2007-09-05 | 2009-03-26 | Hoyu Co Ltd | Oxidizing agent composition |
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