JPH0411855A - Preparation of artificial honey - Google Patents
Preparation of artificial honeyInfo
- Publication number
- JPH0411855A JPH0411855A JP2113169A JP11316990A JPH0411855A JP H0411855 A JPH0411855 A JP H0411855A JP 2113169 A JP2113169 A JP 2113169A JP 11316990 A JP11316990 A JP 11316990A JP H0411855 A JPH0411855 A JP H0411855A
- Authority
- JP
- Japan
- Prior art keywords
- honey
- activated carbon
- sucrose
- colored
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000012907 honey Nutrition 0.000 title claims abstract description 41
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 69
- 108090000790 Enzymes Proteins 0.000 claims abstract description 18
- 102000004190 Enzymes Human genes 0.000 claims abstract description 18
- 229930006000 Sucrose Natural products 0.000 claims abstract description 15
- 239000005720 sucrose Substances 0.000 claims abstract description 15
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims abstract description 14
- 239000007864 aqueous solution Substances 0.000 claims abstract description 10
- 238000001914 filtration Methods 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 241000256844 Apis mellifera Species 0.000 claims description 4
- 208000024780 Urticaria Diseases 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 108010051210 beta-Fructofuranosidase Proteins 0.000 abstract description 6
- 235000011073 invertase Nutrition 0.000 abstract description 6
- 239000001573 invertase Substances 0.000 abstract description 5
- 238000000354 decomposition reaction Methods 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- 238000007865 diluting Methods 0.000 abstract 1
- 125000000185 sucrose group Chemical group 0.000 abstract 1
- 229940088598 enzyme Drugs 0.000 description 13
- 239000000243 solution Substances 0.000 description 4
- 241000256837 Apidae Species 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229930091371 Fructose Natural products 0.000 description 2
- 239000005715 Fructose Substances 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000028327 secretion Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- CHUGKEQJSLOLHL-UHFFFAOYSA-N 2,2-Bis(bromomethyl)propane-1,3-diol Chemical compound OCC(CO)(CBr)CBr CHUGKEQJSLOLHL-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010053835 Catalase Proteins 0.000 description 1
- 102000016938 Catalase Human genes 0.000 description 1
- 108010015776 Glucose oxidase Proteins 0.000 description 1
- 239000004366 Glucose oxidase Substances 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 102100024295 Maltase-glucoamylase Human genes 0.000 description 1
- NBGXQZRRLOGAJF-UHFFFAOYSA-N Maltulose Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)(CO)OCC1O NBGXQZRRLOGAJF-UHFFFAOYSA-N 0.000 description 1
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 1
- 108010028144 alpha-Glucosidases Proteins 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229940105657 catalase Drugs 0.000 description 1
- 239000006103 coloring component Substances 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 235000019420 glucose oxidase Nutrition 0.000 description 1
- 229940116332 glucose oxidase Drugs 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- JCQLYHFGKNRPGE-HFZVAGMNSA-N maltulose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JCQLYHFGKNRPGE-HFZVAGMNSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000012629 purifying agent Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000005918 transglycosylation reaction Methods 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
Landscapes
- Jellies, Jams, And Syrups (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は蜂蜜を人工的に提供する人工蜂蜜の製造法に関
するものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for producing artificial honey, which provides honey artificially.
（従来の技術）
蜂蜜はミツバチが主として花の電線から多ｖａ類の正電
を胃（宏量）中に吸いとって巣に戻り、多数のミツバチ
仲間に分配したり、吐き出すことを反復してそのときミ
ツバチの咽頭腺からの酵素を含有した分泌物を混合する
ことにより正電の多糖類を主として単ａＳのブドウ糖と
果糖に分解して巣房に蓄えたものであって、この多ＩＩ
類を単Ｗ頬に分解する酵素はミツバチの前記分泌物に含
まれるインベルターゼのほか正電や混入した花粉に含ま
れるインベルターゼによるものとされている。(Prior art) Honey is produced by honey bees, who suck up positive electrolytes of various va species into their stomachs (volumes) mainly from flower wires, return to the hive, and repeatedly distribute and spit out the honey. At that time, by mixing secretions containing enzymes from the pharyngeal glands of bees, positive polysaccharides were broken down into mainly monoaS glucose and fructose, which were stored in the hive.
It is said that the enzyme that decomposes these into single W cheeks is invertase contained in the secretions of honey bees, as well as invertase contained in positive electrons and mixed pollen.
そして、この蜂蜜は消化吸収のよいブドウ糖と果糖を主
成分としてその他各種ビタミン、ミネラル成分などを含
有することによって栄養食品として高く評価され、その
需要は増加を続けており、近年は中国、ソ連、アルゼン
チンその他からも輸入されているが、電源である花の種
類も異なることによって輸入蜂蜜には色調を暗色とした
ものが多く、淡色の蜂蜜が多い国内産の蜂蜜と比較して
外観、風味の点で商品価値の低下は免れない、そこで、
このような暗色の蜂蜜は製糖工業における粗糖液の脱色
と同様に活性炭、イオン交換樹脂などの脱色精製剤をも
って脱色精製されているが、この脱色精製の工程は製品
蜂蜜の生産コストを著しく増大させるという問題があっ
た。This honey is highly valued as a nutritional food because it contains glucose and fructose, which are easily digested and absorbed, as well as various other vitamins and minerals, and the demand for it continues to increase. Honey is also imported from Argentina and other countries, but due to the different types of flowers used as a power source, imported honey is often dark in color and has a different appearance and flavor compared to domestically produced honey, which is often light in color. Therefore, a decline in product value is inevitable.
This kind of dark-colored honey is decolorized and purified using decolorizing and purifying agents such as activated carbon and ion exchange resin, similar to the decolorizing of crude sugar liquid in the sugar industry, but this decolorizing and purifying process significantly increases the production cost of the product honey. There was a problem.
（課題を解決するための手段）
本発明は前記のような暗色の蜂蜜の脱色精製に使用した
後の廃棄されるべき活性炭を有効に活用して問題とされ
た生産コストの増大を回避するためになされたもので、
ミツバチの巣房から採取された暗色の蜂蜜を稀釈して活
性炭の濾過層を通すことにより該活性炭に蜂蜜中の着色
成分を吸着させると同時に蜂蜜中に含有される酵素を吸
着させ、次に前記活性炭の濾過層に水を通して水洗した
うえこれにスクロースの水溶液を緩徐に通して該活性炭
に吸着された酵素の作用によりスクロースを分解するこ
とを特徴とするものである。(Means for Solving the Problems) The present invention aims to effectively utilize the activated carbon that should be discarded after being used for decolorizing and refining dark-colored honey as described above, thereby avoiding the problematic increase in production costs. It was done to
Dark-colored honey collected from honey bee hives is diluted and passed through a filter layer of activated carbon so that the activated carbon adsorbs the colored components in the honey and at the same time adsorbs the enzymes contained in the honey. This method is characterized by passing water through an activated carbon filtration layer, washing it with water, and then slowly passing an aqueous solution of sucrose therethrough to decompose sucrose by the action of enzymes adsorbed on the activated carbon.
本発明において、ミツバチの巣房から採取された暗色の
蜂蜜は先ず活性炭の濾過層を円滑に通過させるために水
で稀釈して粉状または粒状の活性炭の濾過層を通すもの
であるが、この活性炭の濾過層を緩徐に通す間に該活性
炭には暗色の蜂蜜中の着色成分が吸着され、脱色された
蜂蜜水溶液が濾過層を出ることとなり、また、この着色
成分の吸着と同時に蜂蜜中に含有されたインベルターゼ
、アミラーゼ、グルコースオキシダーゼ、カタラーゼ、
フォスファターゼなどの酵素も該活性炭に吸着されるも
のである０次に、前記着色成分の吸着によって活性炭の
脱色力が低下した時において蜂蜜の供給を止めて活性炭
の濾過層に水を通して水洗すれば、活性炭に吸着されて
いる着色成分は容易に洗除されるから、続いてスクロー
スの水溶液を緩徐に通してゆけば、活性炭に吸着された
前記酵素のうち特に正賓、花粉を起源とするインへルタ
ーゼ（β−フラクトフラノシダーゼ）とミツバチを起源
とするインベルターゼ（α−グルコシダーゼ）などの酵
素の作用によって前記スクロースの多くは加水分解や糖
転移反応を生起し、単糖類のほかエルロース、マルチュ
ロース、１−ケスドースなどに分解されるものである。In the present invention, dark-colored honey collected from honey bee hives is first diluted with water in order to pass through the activated carbon filtration layer smoothly, and then passed through the powdered or granular activated carbon filtration layer. While passing slowly through the activated carbon filtration layer, the activated carbon adsorbs the dark colored components in the honey, and the decolored honey aqueous solution exits the filtration layer. Contained invertase, amylase, glucose oxidase, catalase,
Enzymes such as phosphatase are also adsorbed on the activated carbon.Next, when the decolorizing power of the activated carbon decreases due to the adsorption of the colored components, the honey supply is stopped and water is passed through the activated carbon filter layer to wash it with water. The colored components adsorbed on the activated carbon are easily washed away, so if the aqueous sucrose solution is then passed slowly, the enzymes adsorbed on the activated carbon, especially the enzymes originating from the guest of honor and pollen, can be removed. Due to the action of enzymes such as lutease (β-fructofuranosidase) and invertase (α-glucosidase), which originates from honey bees, most of the sucrose undergoes hydrolysis and transglycosylation reactions, and in addition to monosaccharides, erulose, maltulose, - It is decomposed into kesdose, etc.
なお、前記活性炭に吸着された酵素は本来活性炭がコロ
イドである酵素に対し強力な吸着能をもっているため、
前記着色成分を洗除するための通水によっても洗除され
ることは少ないものである。しかして、前記のようにし
て活性炭の濾過層を出るスクロースの分解水溶液は濃縮
することによって通常の蜂蜜に近位の各種Ｉｉ類を成分
組成とした淡色の人工蜂蜜の製品とすることができ、一
方、最初の工程において着色成分を活性炭に吸着させて
濾過層を出た蜂蜜水溶液は同様濃縮することによって通
常の蜂蜜とすることができるものである。Note that the enzyme adsorbed on the activated carbon originally has a strong adsorption ability for colloidal enzymes.
Even when water is passed through to wash away the coloring components, they are rarely washed away. Therefore, by concentrating the decomposed aqueous solution of sucrose that exits the activated carbon filtration layer as described above, it is possible to produce a light-colored artificial honey product whose composition is composed of various types of class Ii that are close to ordinary honey. On the other hand, the aqueous honey solution that leaves the filtration layer after the colored components are adsorbed on activated carbon in the first step can be converted into regular honey by concentrating in the same way.
実施例
ミツバチの巣房から採取された暗色の蜂蜜の稀釈液（Ｂ
ｒｉｘ ４５）を空間速度２、温度５０°Ｃの下に粒
状活性炭を充填した濾過層を約３０時間かけて通過させ
ることにより脱色率３５％前後の淡色の蜂蜜水溶液を得
ると同時に蜂蜜中の酵素を粒状の活性炭に吸着させた０
次に、前記活性炭はこれに吸着されている着色成分を水
洗によって洗除したうえこれにスクロースの水溶液（Ｂ
ｒｉに ４０〜６５）を空間速度０．３５、温度５０°
Ｃの下に約２４時間かけて通過させて該活性炭に吸着さ
れた酵素の作用によりスクロースを分解させ、後このス
クロースの分解水溶液を濃縮して製品とした。Example A diluted solution of dark honey collected from honey bee hives (B
rix 45) at a space velocity of 2 and a temperature of 50°C for about 30 hours to obtain a light-colored honey aqueous solution with a decolorization rate of about 35%, while simultaneously removing the enzymes in the honey. 0 adsorbed on granular activated carbon
Next, the colored components adsorbed on the activated carbon are washed with water, and then an aqueous solution of sucrose (B
40 to 65) at a space velocity of 0.35 and a temperature of 50°.
The activated carbon was passed through carbon for about 24 hours to decompose sucrose by the action of the enzyme adsorbed on the activated carbon, and the aqueous solution of sucrose decomposition was then concentrated to produce a product.
（発明の効果）
本発明は自然界においてミツバチが行っている酵素を利
用しての蜂蜜の生産を商品価値の低い暗色の蜂蜜を脱色
精製するために用いた濾過層の活性炭に吸着されている
酵素を利用することによってスクロースから蜂蜜に近位
の各種ｗＮ類を成分組成とした淡色の人工蜂蜜を安直に
提供できるものであって、暗色の蜂蜜の脱色精製に使用
した後の廃棄されるべき活性炭を有効に活用できるばか
りでなく最初の工程において得られる脱色精製された蜂
蜜水溶液は通常の蜂蜜とすることができるものであるか
ら、−石二鳥の効果を奏する工業的価値きわめて大なも
のである。(Effects of the Invention) The present invention utilizes enzymes adsorbed on activated carbon in a filtration layer used to decolorize and purify dark-colored honey with low commercial value. By using activated carbon that should be discarded after being used for decolorizing and purifying dark-colored honey, it is possible to easily provide light-colored artificial honey with a composition of various wNs close to honey from sucrose. Not only can it be used effectively, but also the decolorized and purified aqueous honey solution obtained in the first process can be used as regular honey, so it has an extremely large industrial value and has the effect of killing two birds. be.
Claims (1)
性炭の濾過層を通すことにより該活性炭に蜂蜜中の着色
成分を吸着させると同時に蜂蜜中に含有される酵素を吸
着させ、次に前記活性炭の濾過層に水を通して水洗した
うえこれにスクロースの水溶液を緩徐に通して該活性炭
に吸着された酵素の作用によりスクロースを分解するこ
とを特徴とする人工蜂蜜の製造法。Dark-colored honey collected from honey bee hives is diluted and passed through a filter layer of activated carbon so that the activated carbon adsorbs the colored components in the honey and at the same time adsorbs the enzymes contained in the honey. A method for producing artificial honey, which comprises passing water through an activated carbon filtration layer to wash it, and then slowly passing an aqueous solution of sucrose therethrough to decompose sucrose by the action of enzymes adsorbed on the activated carbon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2113169A JPH0411855A (en) | 1990-04-27 | 1990-04-27 | Preparation of artificial honey |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2113169A JPH0411855A (en) | 1990-04-27 | 1990-04-27 | Preparation of artificial honey |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0411855A true JPH0411855A (en) | 1992-01-16 |
| JPH0543337B2 JPH0543337B2 (en) | 1993-07-01 |
Family
ID=14605304
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2113169A Granted JPH0411855A (en) | 1990-04-27 | 1990-04-27 | Preparation of artificial honey |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0411855A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6427366A (en) * | 1988-05-30 | 1989-01-30 | Dainippon Printing Co Ltd | Process layout device |
| KR100872510B1 (en) * | 2007-06-28 | 2008-12-08 | 한국식품연구원 | Honey treatment system capable of removing protein and germs |
-
1990
- 1990-04-27 JP JP2113169A patent/JPH0411855A/en active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6427366A (en) * | 1988-05-30 | 1989-01-30 | Dainippon Printing Co Ltd | Process layout device |
| JPH0411855B2 (en) * | 1988-05-30 | 1992-03-02 | Dainippon Printing Co Ltd | |
| KR100872510B1 (en) * | 2007-06-28 | 2008-12-08 | 한국식품연구원 | Honey treatment system capable of removing protein and germs |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0543337B2 (en) | 1993-07-01 |
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