JPH04100995A - Softening agent composition for paper - Google Patents
Softening agent composition for paperInfo
- Publication number
- JPH04100995A JPH04100995A JP21017990A JP21017990A JPH04100995A JP H04100995 A JPH04100995 A JP H04100995A JP 21017990 A JP21017990 A JP 21017990A JP 21017990 A JP21017990 A JP 21017990A JP H04100995 A JPH04100995 A JP H04100995A
- Authority
- JP
- Japan
- Prior art keywords
- paper
- compound
- weight
- water
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 239000004902 Softening Agent Substances 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 10
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052740 iodine Inorganic materials 0.000 claims abstract description 8
- 239000011630 iodine Substances 0.000 claims abstract description 8
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims abstract description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 4
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical group COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 abstract 1
- 125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 abstract 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 9
- 230000007423 decrease Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- -1 Acrylic quaternary ammonium salt Chemical class 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- QSLPNSWXUQHVLP-UHFFFAOYSA-N $l^{1}-sulfanylmethane Chemical group [S]C QSLPNSWXUQHVLP-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は紙製品、特にティッシュペーパー、トイレット
ペーパー、紙タオルなどいわゆる薄葉紙に柔軟性を付与
する紙用柔軟剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a paper softener composition that imparts flexibility to paper products, particularly so-called thin paper such as tissue paper, toilet paper, and paper towels.
［従来の技術］ 紙用の柔軟剤として、多くの化合物が開示されている。[Conventional technology] Many compounds have been disclosed as softeners for paper.
たとえば、ジアルキルジメチルアンモニウムクロリド（
特開昭６３−１６５５９７号公報）、イミダシリン型第
四アンモニウム塩と非イオン界面活性剤（特開昭５８−
１８６６７３号公報、特開昭５９−３０９６５号公報）
、ポリアルキレンイミン誘導体（特開昭５８−１２０８
７９号公報、特開昭５６−９６９６０号公報、特開昭５
９−１７３３７８号公報、特開昭５４−８８３９５号公
報、特開昭６０−３９４７６号公報）、ラノリンおよび
ラノリン誘導体（特開昭５３−１４７８０３号公報）、
アクリル系第四アンモニウム塩（特開昭５９−１００７
７６号公報）、ウレタンアルコールまたはその４級化物
（特開昭６０−１３９８９７号公報）、カチオン性オリ
ゴマー（特開昭６３−２５１４０９号公報）、ポリアミ
ド誘導体（特開昭５１−３８６００号公報）などがある
。For example, dialkyldimethylammonium chloride (
JP-A-63-165597), imidacillin-type quaternary ammonium salt and nonionic surfactant (JP-A-58-1989)
186673, Japanese Patent Application Laid-Open No. 59-30965)
, polyalkyleneimine derivative (JP-A-58-1208
No. 79, JP-A-56-96960, JP-A-Sho 5
9-173378, JP 54-88395, JP 60-39476), lanolin and lanolin derivatives (JP 53-147803),
Acrylic quaternary ammonium salt (JP-A-59-1007
76), urethane alcohol or its quaternized product (JP-A-60-139897), cationic oligomers (JP-A-63-251409), polyamide derivatives (JP-A-51-38600), etc. There is.
［発明が解決しようとする課題］
従来用いられてきた紙用柔軟剤（以下、単に柔軟剤とい
う。）は紙に柔軟性を付与する反面、吸水性を低下させ
る欠点があった。[Problems to be Solved by the Invention] Conventionally used paper softeners (hereinafter simply referred to as softeners) impart flexibility to paper, but have the drawback of reducing water absorption.
柔軟剤は紙製品に優れた柔軟性を付与するだけでなく、
紙製品の吸水性を低下させないことが要求される。また
、柔軟剤は保存安定性に優れ、その取り扱い性が容易で
あることが望ましい。Softeners not only provide excellent flexibility to paper products, but also
It is required not to reduce the water absorbency of paper products. Further, it is desirable that the softener has excellent storage stability and is easy to handle.
本発明はこれらの条件を満たす柔軟剤を提供するもので
ある。The present invention provides a softener that satisfies these conditions.
［課題を解決するための手段］ 本発明はつぎの三成分からなる柔軟剤組成物である。[Means to solve the problem] The present invention is a softener composition comprising the following three components.
（ａ）下記一般式（１）で示され、そのヨウ素価が１２
〜１１０である化合物
４０〜９５重量％
（ｂ）グリセリン ３〜５０重量％（Ｃ）水
または炭素数４以下の脂肪族アルコール２〜３０重量％
（式中、Ｒ”およびＲ′は炭素数１２〜２４の飽和また
は不飽和の炭化水素基、ＡＯはＣ２Ｈ４０またはＣ３Ｈ
６０、ｎは２〜２５、Ｘはハロゲン原子またはＣＨ３Ｓ
Ｏ４である。）
一般式（１）で示される化合物において、Ｒ゛とＲ２で
示される飽和または不飽和の炭素数１２〜２４を有する
炭化水素基としては、ラウリル基、ミリスチル基、パル
ミチル基、ステアリル基、パルミトオレイル基、オレイ
ル基、リルイル基、リルニル基、インミリスチル基、イ
ソパルミチル基、イソステアリル基などがあり、またこ
れらの混合物である牛脂アルキル基、豚脂アルキル基、
大豆油アルキル基、パーム油アルキル基、ナタネ油アル
キル基、アマニ油アルキル基などがある。(a) It is represented by the following general formula (1), and its iodine value is 12
-110 (b) Glycerin 3-50% by weight (C) Water or aliphatic alcohol having 4 or less carbon atoms 2-30% by weight (wherein R'' and R' are carbon atoms ~24 saturated or unsaturated hydrocarbon groups, AO is C2H40 or C3H
60, n is 2 to 25, X is a halogen atom or CH3S
It is O4. ) In the compound represented by general formula (1), the saturated or unsaturated hydrocarbon groups having 12 to 24 carbon atoms represented by R' and R2 include lauryl group, myristyl group, palmityl group, stearyl group, palmitooleyl group. group, oleyl group, lylyl group, lylunyl group, inmyristyl group, isopalmityl group, isostearyl group, etc., and mixtures thereof such as beef tallow alkyl group, lard alkyl group,
Examples include soybean oil alkyl groups, palm oil alkyl groups, rapeseed oil alkyl groups, and linseed oil alkyl groups.
一般式（１）で示される化合物のヨウ素価は１２〜１１
０の範囲にあることが必要である。一般式（１）の化合
物において、Ｒ１とＲ２で示される飽和または不飽和の
炭化水素基の炭素数が１２未満であると紙製品の皮膚へ
の刺激性が強く、また２４を超えると紙製品の吸水性が
低下する。ヨウ素価が１２未満であると紙製品の吸水性
が低下し、１１０を超えると十分な柔軟効果が得られな
い。The iodine value of the compound represented by general formula (1) is 12 to 11
It must be in the range of 0. In the compound of general formula (1), if the number of carbon atoms in the saturated or unsaturated hydrocarbon group represented by R1 and R2 is less than 12, the paper product will be highly irritating to the skin, and if it exceeds 24, the paper product will be water absorption is reduced. If the iodine value is less than 12, the water absorbency of the paper product will decrease, and if it exceeds 110, a sufficient softening effect will not be obtained.
ＡＯが炭素数４以上のオキシアルキレン基であると紙製
品の吸水性が低下する。ｎが２未満であると紙製品の吸
水性が低下し、２５を超えると一般式（１）の化合物の
融点と粘度が高くなり、取り扱い性が悪くなる。When AO is an oxyalkylene group having 4 or more carbon atoms, the water absorbency of the paper product decreases. When n is less than 2, the water absorbency of the paper product decreases, and when n exceeds 25, the melting point and viscosity of the compound of general formula (1) increase, resulting in poor handling properties.
本発明の柔軟剤組成物は、（ａ）（ｂ）および（ｃ）の
３成分からなるが、（ａ）成分が４０重量％未満である
と紙製品に十分な柔軟性が付与できず、また９５重量％
を超えると疎水性が強くなりすぎて紙製品の吸水性が低
下する。（ｂ）成分が３重量％未満であると紙製品の吸
水性が低下し、５０重量％を超えると紙製品に十分な柔
軟性が付与できない。（ｃ）成分が２重量％未満である
と均一な柔軟剤組成物が得られず、３０重量％を超える
と長期保存に際し柔軟剤組成物の分離が起こる。The softener composition of the present invention consists of three components (a), (b), and (c), but if the content of component (a) is less than 40% by weight, sufficient flexibility cannot be imparted to paper products. Also 95% by weight
If it exceeds 100%, the hydrophobicity becomes too strong and the water absorbency of the paper product decreases. When component (b) is less than 3% by weight, the water absorbency of the paper product decreases, and when it exceeds 50% by weight, sufficient flexibility cannot be imparted to the paper product. When component (c) is less than 2% by weight, a uniform softener composition cannot be obtained, and when it exceeds 30% by weight, separation of the softener composition occurs during long-term storage.
本発明の柔軟剤組成物の使用方法は、５〜１０００倍に
水で希釈して処理液を調整し、長網抄紙機あるいは円網
抄紙機により湿紙を得るワイヤーパート、この湿紙をプ
レスし脱水を行うプレスパート、引き続いて加熱乾燥を
行うドライパートあるいはトライパート後のいずれかの
工程において、含浸機により含浸することも、噴霧機に
よりスプレーすることも、塗工機により塗布することも
可能である。いずれの場合にも、柔軟剤組成物の添加量
を０．０１〜５重量％［（ａ）成分＋（ｂ）成分／紙の
気乾重量コの範囲内で使用すると十分な柔軟効果を付与
し、かつ吸水性を有した紙製品を得ることができる。The method of using the softener composition of the present invention is to prepare a treatment solution by diluting it 5 to 1000 times with water, and then use a fourdrinier paper machine or a cylinder paper machine to obtain a wet paper from a wire part, and then press this wet paper. In any process after the press part where dehydration is carried out, the dry part which is followed by heat drying, or the trip part, impregnation can be carried out using an impregnation machine, spraying with a spray machine, or coating with a coating machine. It is possible. In either case, if the amount of the softener composition added is within the range of 0.01 to 5% by weight [component (a) + component (b)/air-dry weight of paper, a sufficient softening effect will be imparted. It is possible to obtain a paper product that has water absorption properties.
柔軟剤組成物の添加量が０．０１重量％よりも少ない場
合には、紙製品への分布状態が不均一となり十分な柔軟
効果が発揮されない。また、５重量％を超えると紙製品
の皮膚への刺激性が強くなり家庭用薄葉紙に使用するに
は好ましくない。If the amount of the softener composition added is less than 0.01% by weight, the distribution to the paper product will be uneven and a sufficient softening effect will not be exhibited. Moreover, if it exceeds 5% by weight, the paper product becomes highly irritating to the skin, making it undesirable for use in household tissue paper.
［発明の効果］
本発明の柔軟剤組成物は紙製品に優れた柔軟性および十
分な吸水性を付与する優れた柔軟剤組成物である。また
本発明の柔軟剤組成物は均一な溶液または乳化液である
ので、長期間の保存に際し非常に安定であり、かつ処理
液の調整が容易であるなど取り扱い性においても非常に
優れた柔軟剤組成物である。[Effects of the Invention] The softener composition of the present invention is an excellent softener composition that imparts excellent flexibility and sufficient water absorption to paper products. Furthermore, since the softener composition of the present invention is a homogeneous solution or emulsion, it is very stable during long-term storage and is a softener with excellent handling properties, such as easy adjustment of the processing solution. It is a composition.
［実施例コ つぎに本発明を実施例により具体的に説明する。[Example code] Next, the present invention will be specifically explained with reference to Examples.
なお以下の記述において％は重量％を示す。In the following description, % indicates weight %.
実施例１ 第四アンモニウム塩として、つぎの化合物を用いた。Example 1 The following compound was used as the quaternary ammonium salt.
化合物Ａ
［（ｃ １ｅ Ｈｌ５） ２Ｎ ＋（ＣＨ３）＜Ｃ２Ｈ
４０）、ｏＨコ Ｂｒヨウ素価３７．８
化合物Ｂ
［Ｒ２Ｎ＋（ＣＨ３）（Ｃ３Ｈ６０）３Ｈ］ Ｃ１（Ｒ
：牛脂アルキル基）
ヨウ素価３１．４
化合物Ｃ
［Ｒ２Ｎ＋（ＣＨｌ）２１ Ｃ１−
（Ｒ：牛脂アルキル基）
ヨウ素価３９．７
これらの第四アンモニウム塩を用いて表１に示す柔軟剤
組成物を調整した。表１には柔軟剤組成物の室温におけ
る状態と室温に一月間静置した場合の保存安定性の結果
を示す。Compound A [(c 1e Hl5) 2N + (CH3)<C2H
40), oH Co Br iodine value 37.8 Compound B [R2N+(CH3)(C3H60)3H] C1(R
: tallow alkyl group) Iodine value 31.4 Compound C [R2N+(CHl)21 C1- (R: tallow alkyl group) Iodine value 39.7 Using these quaternary ammonium salts, the softener compositions shown in Table 1 were prepared. It was adjusted. Table 1 shows the state of the softener composition at room temperature and the storage stability results when it was left at room temperature for one month.
表１より、本発明の柔軟剤組成物は透明溶液または乳化
液であり、室温に一月間放置しても分離せずに安定であ
ることがわかる。From Table 1, it can be seen that the softener composition of the present invention is a transparent solution or emulsion, and is stable without separating even if left at room temperature for one month.
実施例２
被試験紙として市販のキムワイプワイパー５２００ （
十条キンバリー株式会社製）１枚を内径１２ｃｍのプラ
スッチク製の円形リングに固定した。Example 2 Commercially available Kimwipe Wiper 5200 (
(manufactured by Jujo Kimberly Co., Ltd.) was fixed to a plastic circular ring with an inner diameter of 12 cm.
この被試験紙に表１に記載の柔軟剤組成物を水で０．０
０１〜４％に希釈して、噴霧器（Ｃａｎｙｏｎ ２Ｌｉ
ｎｅ Ｓｙｓｔｅｍ Ｈｉｓｐｒａｙｅｒ ）を用いて
所定の添加量になるように噴震し、２４時間気乾したの
ちに、柔軟性および吸水性を調べた。表２にこれらの試
験結果を示す。なお、実験Ｎｏ、１２は水のみを噴霧し
たものである。Add the softener composition listed in Table 1 to this test paper at 0.00% with water.
Dilute to 01-4% and use a sprayer (Canyon 2Li
The mixture was shaken to a predetermined amount using a vacuum cleaner, and after being air-dried for 24 hours, the flexibility and water absorption were examined. Table 2 shows the results of these tests. In Experiment No. 12, only water was sprayed.
性能試験は下記の方法で行った。The performance test was conducted in the following manner.
（柔軟性）
被試験紙５枚を片手で握って、柔軟性に関する官能検査
を行った。評価基準はつぎの５段階とし、検査を５人で
行い、その平均値を求めた。(Flexibility) A sensory test regarding flexibility was conducted by holding five test papers in one hand. The evaluation criteria were set to the following five levels, and the tests were conducted by five people, and the average value was calculated.
１：柔らかくない。 ２：普通。1: Not soft. 2: Normal.
３：やや柔らかい。 ４：柔らかい。3: Slightly soft. 4: Soft.
５：非常に柔らかい。5: Very soft.
（吸水性）
ＪＩＳ Ｐ ８１４１ 紙のクレム法による吸水
度試験方法に従った。なお、測定時間は１０分間とした
。(Water Absorption) JIS P 8141 paper water absorption test method by Klemm's method was followed. Note that the measurement time was 10 minutes.
表２より、本発明の柔軟剤組成物は、紙製品の吸水性を
低下することなく、柔軟性を付与する優れた柔軟剤組成
物であることが明らかである。From Table 2, it is clear that the softener composition of the present invention is an excellent softener composition that imparts flexibility to paper products without reducing their water absorbency.
比較に用いた組成物Ｎｏ、５ ［ジ（牛脂アルキル）ジ
メチルアンモニウムクロリトコで処理した場合（実験Ｎ
００９）、柔軟性はすぐれているが、吸水性が著しく劣
っていて紙用の柔軟剤には適していない。一般式（１）
の化合物の少ない組成物Ｎｏ、６ （実験Ｎｏ、１０）
と本発明の組成物でも添加量の少ない実験Ｎｏ、１１は
吸水性は十分であるが、柔軟性が低く、柔軟剤として用
いるには不適当である。Composition No. 5 used for comparison [When treated with di(tallow alkyl)dimethylammonium chloritco (Experiment N
009) has excellent flexibility, but has extremely poor water absorption and is not suitable as a paper softener. General formula (1)
Composition No. 6 with less compound (Experiment No. 10)
Experiment No. 11, in which the composition of the present invention was added in a small amount, had sufficient water absorption, but had low flexibility and was unsuitable for use as a softener.
Claims (1)
〜１１０である化合物 ４０〜９５重量％ （ｂ）グリセリン３〜５０重量％ （ｃ）水または炭素数４以下の脂肪族アルコール２〜３
０重量％ ▲数式、化学式、表等があります▼ （式中、Ｒ＾１およびＲ＾２は炭素数１２〜２４の飽和
または不飽和の炭化水素基、ＡＯはＣ＿２Ｈ＿４Ｏまた
はＣ＿３Ｈ＿６Ｏ、ｎは２〜２５、Ｘはハロゲン原子ま
たはＣＨ＿３ＳＯ＿４である。）[Claims] A paper softener composition comprising the following three components. (a) It is represented by the following general formula (1), and its iodine value is 12
~110 (b) 3-50% by weight of glycerin (c) Water or aliphatic alcohol having 4 or less carbon atoms 2-3
0% by weight ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R^1 and R^2 are saturated or unsaturated hydrocarbon groups having 12 to 24 carbon atoms, AO is C_2H_4O or C_3H_6O, and n is 2 to 25, X is a halogen atom or CH_3SO_4.)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21017990A JPH04100995A (en) | 1990-08-10 | 1990-08-10 | Softening agent composition for paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21017990A JPH04100995A (en) | 1990-08-10 | 1990-08-10 | Softening agent composition for paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04100995A true JPH04100995A (en) | 1992-04-02 |
Family
ID=16585089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21017990A Pending JPH04100995A (en) | 1990-08-10 | 1990-08-10 | Softening agent composition for paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04100995A (en) |
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1994010381A1 (en) * | 1992-10-27 | 1994-05-11 | The Procter & Gamble Company | Paper products containing a chemical softening composition |
| US5312522A (en) * | 1993-01-14 | 1994-05-17 | Procter & Gamble Company | Paper products containing a biodegradable chemical softening composition |
| US5397435A (en) * | 1993-10-22 | 1995-03-14 | Procter & Gamble Company | Multi-ply facial tissue paper product comprising chemical softening compositions and binder materials |
| US5405501A (en) * | 1993-06-30 | 1995-04-11 | The Procter & Gamble Company | Multi-layered tissue paper web comprising chemical softening compositions and binder materials and process for making the same |
| US5415737A (en) * | 1994-09-20 | 1995-05-16 | The Procter & Gamble Company | Paper products containing a biodegradable vegetable oil based chemical softening composition |
| US5437766A (en) * | 1993-10-22 | 1995-08-01 | The Procter & Gamble Company | Multi-ply facial tissue paper product comprising biodegradable chemical softening compositions and binder materials |
| US5487813A (en) * | 1994-12-02 | 1996-01-30 | The Procter & Gamble Company | Strong and soft creped tissue paper and process for making the same by use of biodegradable crepe facilitating compositions |
| US5510000A (en) * | 1994-09-20 | 1996-04-23 | The Procter & Gamble Company | Paper products containing a vegetable oil based chemical softening composition |
| EP0711870A1 (en) * | 1991-11-01 | 1996-05-15 | The Procter & Gamble Company | Soft absorbent tissue paper comprising a biodegradable quaternized di-methylated amine-ester compound and a temporary wet strength resin |
| AU670415B2 (en) * | 1991-11-01 | 1996-07-18 | Procter & Gamble Company, The | Soft absorbent tissue paper with high permanent wet strength |
| US5538595A (en) * | 1995-05-17 | 1996-07-23 | The Proctor & Gamble Company | Chemically softened tissue paper products containing a ploysiloxane and an ester-functional ammonium compound |
| US5573637A (en) * | 1994-12-19 | 1996-11-12 | The Procter & Gamble Company | Tissue paper product comprising a quaternary ammonium compound, a polysiloxane compound and binder materials |
| US5575891A (en) * | 1995-01-31 | 1996-11-19 | The Procter & Gamble Company | Soft tissue paper containing an oil and a polyhydroxy compound |
| US5624532A (en) * | 1995-02-15 | 1997-04-29 | The Procter & Gamble Company | Method for enhancing the bulk softness of tissue paper and product therefrom |
| US5635028A (en) * | 1995-04-19 | 1997-06-03 | The Procter & Gamble Company | Process for making soft creped tissue paper and product therefrom |
| US5698076A (en) * | 1996-08-21 | 1997-12-16 | The Procter & Gamble Company | Tissue paper containing a vegetable oil based quaternary ammonium compound |
| US5846380A (en) * | 1995-06-28 | 1998-12-08 | The Procter & Gamble Company | Creped tissue paper exhibiting unique combination of physical attributes |
| JPH11269799A (en) * | 1998-01-13 | 1999-10-05 | Kao Corp | Bulking agent for paper |
| US5981044A (en) * | 1993-06-30 | 1999-11-09 | The Procter & Gamble Company | Multi-layered tissue paper web comprising biodegradable chemical softening compositions and binder materials and process for making the same |
| JP2006028670A (en) * | 2004-07-14 | 2006-02-02 | Nof Corp | Paper softener |
| JP2006083479A (en) * | 2004-09-15 | 2006-03-30 | Miyoshi Oil & Fat Co Ltd | Paper strength-reducing agent |
| US7344621B2 (en) | 2003-03-24 | 2008-03-18 | Nof Corporation | Paper additive composition and method for producing paper using the same |
| US7947151B2 (en) | 2006-02-15 | 2011-05-24 | Nof Corporation | Softening agent for paper and method for making paper by using same |
-
1990
- 1990-08-10 JP JP21017990A patent/JPH04100995A/en active Pending
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0711870A1 (en) * | 1991-11-01 | 1996-05-15 | The Procter & Gamble Company | Soft absorbent tissue paper comprising a biodegradable quaternized di-methylated amine-ester compound and a temporary wet strength resin |
| AU670415B2 (en) * | 1991-11-01 | 1996-07-18 | Procter & Gamble Company, The | Soft absorbent tissue paper with high permanent wet strength |
| WO1994010381A1 (en) * | 1992-10-27 | 1994-05-11 | The Procter & Gamble Company | Paper products containing a chemical softening composition |
| KR100317578B1 (en) * | 1992-10-27 | 2002-04-24 | 데이비드 엠 모이어 | Paper products containing chemical flexible formulations |
| US5312522A (en) * | 1993-01-14 | 1994-05-17 | Procter & Gamble Company | Paper products containing a biodegradable chemical softening composition |
| US5981044A (en) * | 1993-06-30 | 1999-11-09 | The Procter & Gamble Company | Multi-layered tissue paper web comprising biodegradable chemical softening compositions and binder materials and process for making the same |
| US5405501A (en) * | 1993-06-30 | 1995-04-11 | The Procter & Gamble Company | Multi-layered tissue paper web comprising chemical softening compositions and binder materials and process for making the same |
| US5397435A (en) * | 1993-10-22 | 1995-03-14 | Procter & Gamble Company | Multi-ply facial tissue paper product comprising chemical softening compositions and binder materials |
| US5437766A (en) * | 1993-10-22 | 1995-08-01 | The Procter & Gamble Company | Multi-ply facial tissue paper product comprising biodegradable chemical softening compositions and binder materials |
| US5415737A (en) * | 1994-09-20 | 1995-05-16 | The Procter & Gamble Company | Paper products containing a biodegradable vegetable oil based chemical softening composition |
| US5510000A (en) * | 1994-09-20 | 1996-04-23 | The Procter & Gamble Company | Paper products containing a vegetable oil based chemical softening composition |
| US5487813A (en) * | 1994-12-02 | 1996-01-30 | The Procter & Gamble Company | Strong and soft creped tissue paper and process for making the same by use of biodegradable crepe facilitating compositions |
| US5573637A (en) * | 1994-12-19 | 1996-11-12 | The Procter & Gamble Company | Tissue paper product comprising a quaternary ammonium compound, a polysiloxane compound and binder materials |
| US5575891A (en) * | 1995-01-31 | 1996-11-19 | The Procter & Gamble Company | Soft tissue paper containing an oil and a polyhydroxy compound |
| US5624532A (en) * | 1995-02-15 | 1997-04-29 | The Procter & Gamble Company | Method for enhancing the bulk softness of tissue paper and product therefrom |
| US5635028A (en) * | 1995-04-19 | 1997-06-03 | The Procter & Gamble Company | Process for making soft creped tissue paper and product therefrom |
| US5538595A (en) * | 1995-05-17 | 1996-07-23 | The Proctor & Gamble Company | Chemically softened tissue paper products containing a ploysiloxane and an ester-functional ammonium compound |
| US5846380A (en) * | 1995-06-28 | 1998-12-08 | The Procter & Gamble Company | Creped tissue paper exhibiting unique combination of physical attributes |
| US5698076A (en) * | 1996-08-21 | 1997-12-16 | The Procter & Gamble Company | Tissue paper containing a vegetable oil based quaternary ammonium compound |
| JPH11269799A (en) * | 1998-01-13 | 1999-10-05 | Kao Corp | Bulking agent for paper |
| US7344621B2 (en) | 2003-03-24 | 2008-03-18 | Nof Corporation | Paper additive composition and method for producing paper using the same |
| JP2006028670A (en) * | 2004-07-14 | 2006-02-02 | Nof Corp | Paper softener |
| JP2006083479A (en) * | 2004-09-15 | 2006-03-30 | Miyoshi Oil & Fat Co Ltd | Paper strength-reducing agent |
| JP4683529B2 (en) * | 2004-09-15 | 2011-05-18 | ミヨシ油脂株式会社 | Paper strength reduction method |
| US7947151B2 (en) | 2006-02-15 | 2011-05-24 | Nof Corporation | Softening agent for paper and method for making paper by using same |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH04100995A (en) | Softening agent composition for paper | |
| FI92410C (en) | Product for use in the treatment of fabrics and the method of treatment of fabrics | |
| JPH02139480A (en) | Softening finishing agent | |
| JP5250860B2 (en) | Liquid softener composition | |
| JP3791117B2 (en) | Softener composition | |
| JPS58167700A (en) | Soap composition | |
| DK158318B (en) | LIQUID TEXTILE SOFT CONCENTRATE AND ITS APPLICATION | |
| JPH0742649B2 (en) | Softening agent | |
| JPS6014146B2 (en) | fiber softening composition | |
| JPH026795B2 (en) | ||
| JP4739074B2 (en) | Aqueous composition | |
| JP2005171399A (en) | Softener composition | |
| JP3235935B2 (en) | Liquid softener composition | |
| JP2647963B2 (en) | Composition for removing shine of fiber | |
| JPH03287868A (en) | Flexibilizing finish | |
| KR100561102B1 (en) | Fabric softener composition | |
| KR19980013609A (en) | Febric softener composition for house | |
| JP2006176918A (en) | Fiber product processing agent composition | |
| JP2672881B2 (en) | Liquid soft finish | |
| JPH0718576A (en) | Softening agent composition | |
| JP3212175B2 (en) | Softener composition | |
| JPS63312399A (en) | Softening and finishing agent | |
| JP2951776B2 (en) | Liquid soft finish | |
| JPH0723584B2 (en) | Softening agent | |
| JPS63126972A (en) | Softening finish agent |