JPH04100518A - Apparatus for treating exhaust gas from engine - Google Patents
Apparatus for treating exhaust gas from engineInfo
- Publication number
- JPH04100518A JPH04100518A JP2064631A JP6463190A JPH04100518A JP H04100518 A JPH04100518 A JP H04100518A JP 2064631 A JP2064631 A JP 2064631A JP 6463190 A JP6463190 A JP 6463190A JP H04100518 A JPH04100518 A JP H04100518A
- Authority
- JP
- Japan
- Prior art keywords
- magnetite
- exhaust gas
- hydrogen
- oxygen
- engine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000007789 gas Substances 0.000 claims abstract description 45
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 33
- 239000001257 hydrogen Substances 0.000 claims abstract description 31
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 27
- 239000001301 oxygen Substances 0.000 claims abstract description 25
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000000354 decomposition reaction Methods 0.000 claims description 12
- 208000028659 discharge Diseases 0.000 claims description 5
- 230000003213 activating effect Effects 0.000 claims description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 31
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 15
- 239000001569 carbon dioxide Substances 0.000 abstract description 12
- 238000006243 chemical reaction Methods 0.000 abstract description 12
- 230000002950 deficient Effects 0.000 abstract description 12
- 150000002431 hydrogen Chemical class 0.000 abstract description 11
- 238000010438 heat treatment Methods 0.000 abstract description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 27
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- 150000002926 oxygen Chemical class 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- -1 oxygen ions Chemical class 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 1
- ICTAZHZJEOVXOW-UHFFFAOYSA-N platinum vanadium Chemical compound [V].[Pt].[Pt].[Pt] ICTAZHZJEOVXOW-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Catalysts (AREA)
- Exhaust Gas After Treatment (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
この発明は、ガソリンエンジンやヂーゼルエンジンの排
気ガスを浄化して炭酸ガスの排気を抑えたり、窒素酸化
物の排気を無くす排気ガスの処理装置に関するものであ
る。[Detailed Description of the Invention] (Field of Industrial Application) This invention is an exhaust gas treatment device that purifies the exhaust gas of a gasoline engine or diesel engine to suppress carbon dioxide emissions and eliminate nitrogen oxide emissions. It is related to.
（従来技術）
従来、エンジンからの排気ガスを浄化する方法はいろい
ろと多数の研究者によって開発されてきたが、そのなか
でも、白金バナジュウムや白金ロジュウム等の複数の触
媒を排気ガス通路に直列的に並べて一酸化炭素を酸化し
て炭酸ガスしたり、窒素酸化物ＮＯｘを窒素ガスＮ７に
するものがあった。これは、特開昭６３−１１３１１２
号公報で代表される技術として既に公開されている。(Prior art) Various methods for purifying exhaust gas from engines have been developed by many researchers, but one of them is a method in which multiple catalysts such as platinum vanadium and platinum rhodium are connected in series in the exhaust gas passage. There were some that oxidized carbon monoxide to carbon dioxide gas or converted nitrogen oxide NOx to nitrogen gas N7. This is JP-A-63-113112
This technology has already been published as typified by the publication No.
（発明が解決しようとする問題点）
従来装置は、コストが高くなると共に、−酸化炭素を炭
酸ガスとして排気させてしまい、現在、世界中で温暖化
の要因になっている炭酸ガスの放出は抑えなければなら
ないにも拘らずこの従来装置は一酸化炭素を炭酸ガスに
して排出するために完全な浄化対策になっていない。(Problems to be solved by the invention) Conventional devices are expensive and emit carbon oxide as carbon dioxide gas, which is currently a cause of global warming. Despite the need to suppress carbon monoxide, this conventional device does not provide a complete purification measure because it converts carbon monoxide into carbon dioxide gas and exhausts it.
更に、複数箇所の各別な触媒中を排気ガスは通過しなけ
ればならないために、エンジンの出力が糺トしてそれだ
け多くの燃料が必要になり、このために更に多くの排気
ガスが発生して本質的な排気ガスの浄化にならないとい
う問題点があった。Furthermore, since the exhaust gases have to pass through different catalysts at multiple locations, the engine's output increases, requiring more fuel, which in turn generates more exhaust gases. However, there was a problem in that the exhaust gas was not essentially purified.
そこで、この従来技術の欠点を解消するために。Therefore, in order to eliminate the drawbacks of this conventional technology.
マグネタイトを３００℃近辺におき、これに水素Ｈ，を
反応させてマグネタイト中の酸素Ｏトを水Ｈ，Ｏにして
除去し、１！ｆｔ素欠陥マグネタイトドｅ。Magnetite is placed at around 300°C, and hydrogen H, is reacted with it to remove oxygen O in magnetite by converting it into water H and O, and 1! ft elementary defect magnetite e.
○、−ｘとして活性化ならしめ、この酸素欠陥マグネタ
イトに今度は炭酸ガスや窒素酸化物等の酸素化合物であ
る排気ガスを接触反応させ、酸素を除去して炭素や窒素
に分解して排気させる技術手段を開発した。ところが、
この新らしい技術手段では、マグネタイトを水素で活性
化するために、水素ボンベを自動車に積み込んだり、あ
るいは、水を電解する従来の水の電気分解装置を装備し
なければならず、危険であったり、エネルギー損失の大
きい装置が必要になり実用化が非常に困難であった。This oxygen-deficient magnetite is activated as ○, -x, and this oxygen-deficient magnetite is then subjected to a contact reaction with exhaust gas, which is an oxygen compound such as carbon dioxide or nitrogen oxide, to remove oxygen and decompose it into carbon and nitrogen, which are then exhausted. Developed technical means. However,
With this new technology, in order to activate the magnetite with hydrogen, the car must either be loaded with hydrogen cylinders or equipped with a conventional water electrolyzer, which can be dangerous. However, it required a device with large energy loss, making it extremely difficult to put it into practical use.
（問題点を解決する手段）
前記の問題点を解決するために、この発明は次の技術手
段を請じた。(Means for Solving the Problems) In order to solve the above problems, the present invention requires the following technical means.
即ち、この発明は、排気ガス通路２の途中に概ね２５０
℃〜３５０℃近辺に保持される恒温部を設け、この恒温
部にマグネタイト７と排気ガスとが接触して通過する排
気ガス処理部を設け、このマグネタイト接触通路内に前
記排気ガスと水素とを交互に送り込むよう構成してなる
エンジン１の排気ガス分解手段を構成し、この排気ガス
分解手段に必要な前記水素の発生装置８に、マグネタイ
ト７を放電処理あるいは減圧処理で活性化してこの活性
化したマグネタイト７０に水を反応させて水素を得る手
段を採用してなるエンジンの排気ガス処理装置とした。That is, in the present invention, approximately 250
A constant temperature section maintained at around 350 degrees Celsius is provided, an exhaust gas treatment section is provided in this constant temperature section through which the magnetite 7 and exhaust gas pass through in contact with each other, and the exhaust gas and hydrogen are introduced into this magnetite contact passage. The exhaust gas decomposition means of the engine 1 is configured to alternately feed the hydrogen, and the magnetite 7 is activated by electric discharge treatment or depressurization treatment to the hydrogen generator 8 necessary for the exhaust gas decomposition means. This exhaust gas treatment device for an engine employs a means for obtaining hydrogen by reacting magnetite 70 with water.
（作用）
この発明の基本的な作用は、マグネタイト（フェライト
）の結晶構造が、２価の鉄（Ｆｅ”）が１個と３価の鉄
（Ｆ ｅ”″）が２個存在して計８価のプラス電荷であ
り、これが陰イオンを保有する酸素（０”−）４個と結
び付いてＦｅ、０４の安定したマグネタイトになってい
る。このマグネタイ１〜を３００Ｔ近ジノの雰囲気のも
と放電処理あるいは減圧処理にすることで、酸素を除去
させて、酸素が欠乏した活性のマグネタイトとして変身
させ、この活性化ならしめた＃素欠陥マグネタイト１−
’ ｅ ｉ Ｏａ−ｘに炭酸ガスを反応させると炭素と
不活性状態のマグネタイトになる６また。窒素酸化物を
反応させると窒素と不活性状態のマグネタイトになる。(Function) The basic function of this invention is that the crystal structure of magnetite (ferrite) is composed of one divalent iron (Fe") and two trivalent iron (Fe""). It has an octavalent positive charge, and this combines with four oxygen (0''-) atoms that have anions to form stable Fe, 04 magnetite. This magnetite 1~ is subjected to discharge treatment or depressurization treatment in an atmosphere of about 300 T to remove oxygen and transform it into active magnetite deficient in oxygen, and this activated # elemental defect magnetite 1-
' e i When Oa-x is reacted with carbon dioxide, it becomes carbon and magnetite in an inactive state6. When nitrogen oxides react with nitrogen, they form inactive magnetite.
次に、元の状態になったこの不活性なマグネタイトを再
度放電処理、あるいは減圧処理して活性化ならしめ繰返
し排気ガスを分解する。Next, this inactive magnetite, which has returned to its original state, is activated again by electric discharge treatment or depressurization treatment, and the exhaust gas is repeatedly decomposed.
これを化学反応式にすると、
Ｆｅ１０４−−一→Ｆｅ、０４−ｘ＋ １／２ Ｘ
○２ド ｅ 、０４− ｘ ＋ １ ／２ ＣＯ７
１／ ２ Ｃ＋ Ｆ ｅ ３０４
である。窒素酸化物の場合は、
Ｆ’ ｅ ＜ ０４− Ｘ 十Ｎ Ｏｘ −ｍ−→１／
２ Ｎ２＋Ｆｅ１０４
である。If we convert this into a chemical reaction formula, Fe104--1 → Fe, 04-x+ 1/2 X
○2 de e, 04- x + 1/2 CO7
1/2 C+ Fe 304. In the case of nitrogen oxides, F' e < 04- X 10N Ox -m-→1/
2N2+Fe104.
然るに、この発明では、不活性状態のマグネタイトを活
性化した酸素欠陥マグネタイトにするために、水素を反
応させないで放電により電ｆｅを与えることによって実
現し、更に、無尽蔵な水をこのＷ１素欠陥マグネタイト
に反応させて鈴屯に水素と酸素に分解させ、この水素を
利用するものである。However, in this invention, in order to turn inactive magnetite into activated oxygen-deficient magnetite, this is achieved by applying electric charge (Fe) by electric discharge without causing hydrogen to react, and furthermore, inexhaustible water is converted into activated oxygen-deficient magnetite. The reactor reacts with Suzuton to decompose it into hydrogen and oxygen, and this hydrogen is used.
（実施例）
この発明の一実施例について詳述すると、１はエンジン
で、２がその排気通路である。３は排気ガス分解室であ
る。この排気ガス分解室は、前記排気通路２の途中に配
置され、ヒータ４で概ね３００℃に加温されて保温状態
にし、送込側通路２ａと排出側通路２ｂには夫々開閉弁
５．６が設けられている。７はマグネタイト（Ｆｅ、０
．）で。(Embodiment) An embodiment of the present invention will be described in detail. Reference numeral 1 represents an engine, and 2 represents an exhaust passage thereof. 3 is an exhaust gas decomposition chamber. This exhaust gas decomposition chamber is disposed in the middle of the exhaust passage 2, and is heated to approximately 300°C by a heater 4 to keep it warm, and on-off valves 5 and 6 are provided in the feed-side passage 2a and the discharge-side passage 2b, respectively. is provided. 7 is magnetite (Fe, 0
．． )in.
該排気ガス分解室３内に消音作用を兼ねるように詰めら
れ、ガスが流通可能になっている。It is packed in the exhaust gas decomposition chamber 3 so as to have a noise-muffling effect, and the gas can flow therethrough.
８は水素発生装置で１本願発明では特に重要な部分であ
る。8 is a hydrogen generator, which is a particularly important part in the present invention.
この水素発生装置８は、マグネタイト（Ｆｅ。This hydrogen generator 8 is made of magnetite (Fe).
０、）７０を収容する室９内をヒータ等の加温装置４０
で３００℃近辺に保温し、このマグネタイドア０に適宜
手法で電子を供与して酸素イオン（０２−）を逃避なら
しめて酸素欠陥マグネタイト（Ｆｅ、０４−ｘ）として
活性化させ、この活性化したマグネタイトに水蒸気（Ｈ
２Ｏ）を吹き付けて、水の酸素分子を活性化マグネタイ
トに奪わせ、水素（Ｈ２）を発生ならしめる装置である
。0, ) 70 is heated by a heating device 40 such as a heater.
The temperature is maintained at around 300°C, and electrons are donated to this magnetide door 0 using an appropriate method to allow oxygen ions (02-) to escape and activate it as oxygen-deficient magnetite (Fe, 04-x). water vapor (H
This is a device that sprays hydrogen (H2) to make the activated magnetite absorb the oxygen molecules in the water and generate hydrogen (H2).
即ち、次の化学反応を行なう装置である。That is, it is an apparatus for carrying out the following chemical reaction.
Ｆｅ１０４Ｘ＋ＸＨ２Ｏ−一→Ｆｅ、○、＋ＸＨ。Fe104X+XH2O-1→Fe, ○, +XH.
１０はマグネタイト７０を活性化させるための電子供与
装置で、回倒では高電圧を当該マグネタイト７０と他の
適宜な端子部材１１との間に掛けて電子をマグネタイト
７０に飛ばすようにしたものである。Reference numeral 10 denotes an electron donor device for activating the magnetite 70, in which a high voltage is applied between the magnetite 70 and another appropriate terminal member 11 during rotation, and electrons are sent to the magnetite 70. .
１２は水蒸気発生器で、開閉弁１３を介して間欠的に蒸
気を前記水素発生装置８内に送り込むように構成したも
のである。１４は酸素放出口、１５は水素供給通路、１
６は排気用の吸引機である。Reference numeral 12 denotes a steam generator, which is configured to intermittently send steam into the hydrogen generator 8 via an on-off valve 13. 14 is an oxygen discharge port, 15 is a hydrogen supply passage, 1
6 is a suction machine for exhaust.
上側の作用について詳述すると、第１図において、水素
発生装置８の室９内に収容されて３００℃近辺に保持さ
れているたマグネタイト（Ｆｅ。To explain the upper function in detail, in FIG. 1, magnetite (Fe) is housed in the chamber 9 of the hydrogen generator 8 and maintained at around 300°C.
０、）７０に高電圧をかけて電子を供与する。すると、
内部の酸素イオンが強制的に放出されて酸素欠陥マグネ
タイトＦｅ、０４−Ｘに脅わる。これは陰イオンを欲し
がっている活性マグネタイトである。0, ) 70 to donate electrons. Then,
Internal oxygen ions are forcibly released and threaten the oxygen-deficient magnetite Fe, 04-X. This is active magnetite that wants anions.
この反応は、 Ｆｅ３０ｓドｅ＊○ａ−ｘ＋ｘ／２０２である。This reaction is Fe30s do e*○a-x+x/202.
次に、水蒸気発生器１２から室９内に水蒸気を送り込む
と、水（Ｈ，Ｏ）の酸素が酸素欠陥マグネタイトと反応
して、次式反応式でわかる通り不活性な元のマグネタイ
トと水素になる。Next, when steam is sent into the chamber 9 from the steam generator 12, the oxygen in the water (H, O) reacts with the oxygen-deficient magnetite, and as can be seen from the following reaction formula, it is converted to the original inert magnetite and hydrogen. Become.
ｐｅ、ｏ４Ｘ＋ＸＨ２０−−−→Ｆｅ、ｏ、＋ＸＨ。pe, o4X+XH20---→Fe, o, +XH.
このようにして得られた水素（Ｈ９）を次に排気ガス分
解装置３の室内に通路１５を通して供給する。するとこ
の室内のマグネタイト（Ｆｅ１０４）この水素を受けと
って次の反応式により、Ｆｅ、○、＋ＸＨ，−−→Ｆｅ
、０４− ｘ ＋ Ｘ Ｈ７０活性マグネタイトに変わ
ると共に水が発生する。The hydrogen (H9) thus obtained is then fed into the chamber of the exhaust gas decomposition device 3 through the passage 15. Then, the magnetite (Fe104) in this chamber receives this hydrogen and according to the following reaction formula, Fe, ○, +XH, −-→Fe
, 04- x + X H70 is converted into active magnetite and water is generated.
次に、エンジン１から炭酸ガスＣＯ２，窒素酸化物ＮＯ
ｘの混合した排気ガスガス分解装置７の室内に送り込む
、すると、炭酸ガスＣ○、の酸素Ｏ，あるいはＮＯｘの
酸素○Ｘを該酸素欠陥マグネタイトが取り込み、炭ＳＣ
が析出したり、あるいは窒素ガスＮ３になって飛び出る
。Next, from the engine 1, carbon dioxide gas CO2, nitrogen oxide NO
When the mixed exhaust gas x is sent into the chamber of the gas decomposition device 7, the oxygen-deficient magnetite takes in the oxygen O of carbon dioxide C○, or the oxygen ○X of NOx, and converts it into carbon SC.
may precipitate or escape as nitrogen gas N3.
即ち、次の化学反応が行なわれる。That is, the following chemical reaction takes place.
ドｅ、○、ｘ＋１／２ＸＣｏ、一番 １／２ Ｘ Ｃ＋Ｆｅ、Ｏ４ あるいは。Do e, ○, x+1/2XCo, first 1/2 X C+Fe, O4 or.
Ｆｅ、０４ ｘ＋Ｎ０ｘ−−一→ １／２ Ｎ、＋
Ｆ ｅ、○の化学反応を起こして浄化される。Fe, 04 x+N0x--1 → 1/2 N, +
It is purified by causing a chemical reaction of Fe and ○.
尚、窒素酸化物ＮＯｘについては、極めて速い反応にな
り、窒素酸化物の浄化は相当速く行なわれるが、炭酸ガ
スＣＯ２については、反応が遅く。It should be noted that the reaction with nitrogen oxides NOx is extremely fast and purification of nitrogen oxides is carried out fairly quickly, but the reaction with carbon dioxide gas CO2 is slow.
排気ガス処理部を加圧状態にすることが望ましい。It is desirable that the exhaust gas treatment section be in a pressurized state.
尚、図中記号１７は加圧装置で反応速度を速める為に分
解室を高圧化するよう設けたものである。Note that the symbol 17 in the figure is a pressurizing device installed to increase the pressure in the decomposition chamber in order to speed up the reaction rate.
（作用効果）
この発明によると、エンジンからの排気ガスがマグネタ
イトによってによって浄化でき、窒素酸化物ＮＯｘがｆ
＃Ｊｔ１８．に窒素ガスＮ２になって排気される。また
、幾分かの炭酸ガスＣ○２は炭ＪＣになって析出して９
％され、炭酸ガスＣＯ２の排気を少なくできる。然も、
マグネタイトを活性化する水素を得るに、マグネタイト
に電子を供与して活性化し、これに水を作用させてＳ単
に水素を得る構成にしたから効率的に排気ガス分解装置
に必要な水素を得ることができ、エンジンに特別な水素
ボンベや非効率的な水の電気分解装置を装備することが
必要でなくなる。(Operation and Effect) According to this invention, exhaust gas from an engine can be purified by magnetite, and nitrogen oxides NOx are
#Jt18. Then, it becomes nitrogen gas N2 and is exhausted. In addition, some carbon dioxide gas C○2 becomes charcoal JC and precipitates, resulting in 9
%, reducing emissions of carbon dioxide gas CO2. Of course,
To obtain hydrogen that activates magnetite, electrons are donated to magnetite to activate it, and then water is applied to it to simply obtain hydrogen.This structure enables efficient hydrogen production for the exhaust gas decomposition equipment. This eliminates the need to equip the engine with special hydrogen cylinders or inefficient water electrolyzers.
図は、この発明の一実施例であって、第１図は一部断面
の要部の側面図。
図中の記号
１はエンジン、２は排気通路、３は徘訊ガス分解室、４
はヒータ、５，６は開閉弁、７，７０はマグネタイト（
Ｆｅ、０４）、８は水素発生装置、９室 １０は電子供
与装置、１１は端子部材、１２は水蒸気発生器、１３は
開閉弁を示す。The figure shows one embodiment of the present invention, and FIG. 1 is a side view of the main part, partially in section. In the diagram, symbol 1 is the engine, 2 is the exhaust passage, 3 is the wandering gas decomposition chamber, and 4
is a heater, 5 and 6 are on-off valves, and 7 and 70 are magnetite (
8 is a hydrogen generator, 9 chambers, 10 is an electron donor, 11 is a terminal member, 12 is a steam generator, and 13 is an on-off valve.
Claims (1)
に保持される恒温部を設け、この恒温部にマグネタイト
７と排気ガスとが接触して通過する排気ガス処理部を設
け、このマグネタイト接触通路内に前記排気ガスと水素
とを交互に送り込むよう構成してなるエンジン１の排気
ガス分解手段を構成し、この排気ガス分解手段に必要な
前記水素の発生装置８に、マグネタイト７を放電処理あ
るいは減圧処理で酸素欠陥化させ活性化し、この活性化
したマグネタイト７０に水を反応させて水素を得る手段
を採用してなるエンジンの排気ガス処理装置。A constant temperature section maintained at approximately 250 to 350 degrees Celsius is provided in the middle of the exhaust gas passage 2, an exhaust gas treatment section is provided in this constant temperature section through which the magnetite 7 and the exhaust gas come into contact with each other, and this magnetite contact passage The exhaust gas decomposition means of the engine 1 is configured to alternately feed the exhaust gas and hydrogen into the exhaust gas decomposition means, and the magnetite 7 is subjected to electric discharge treatment or An exhaust gas treatment device for an engine employing means for obtaining hydrogen by activating oxygen by depressurizing it and reacting the activated magnetite 70 with water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2064631A JPH04100518A (en) | 1990-03-14 | 1990-03-14 | Apparatus for treating exhaust gas from engine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2064631A JPH04100518A (en) | 1990-03-14 | 1990-03-14 | Apparatus for treating exhaust gas from engine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04100518A true JPH04100518A (en) | 1992-04-02 |
Family
ID=13263809
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2064631A Pending JPH04100518A (en) | 1990-03-14 | 1990-03-14 | Apparatus for treating exhaust gas from engine |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04100518A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06185348A (en) * | 1992-12-08 | 1994-07-05 | Taketoshi Tokumura | Exhaust emission control device |
| WO2002081368A1 (en) * | 2001-04-02 | 2002-10-17 | Uchiya Thermostat Co., Ltd. | Method for producing hydrogen and apparatus for supplying hydrogen |
| WO2004002881A1 (en) * | 2002-06-26 | 2004-01-08 | Uchiya Thermostat Co.,Ltd. | Method for producing hydrogen and apparatus for supplying hydrogen |
| JP2020008001A (en) * | 2018-07-11 | 2020-01-16 | 日本碍子株式会社 | Exhaust gas heating system and exhaust gas heating method |
-
1990
- 1990-03-14 JP JP2064631A patent/JPH04100518A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06185348A (en) * | 1992-12-08 | 1994-07-05 | Taketoshi Tokumura | Exhaust emission control device |
| WO2002081368A1 (en) * | 2001-04-02 | 2002-10-17 | Uchiya Thermostat Co., Ltd. | Method for producing hydrogen and apparatus for supplying hydrogen |
| US7300643B2 (en) | 2001-04-02 | 2007-11-27 | Uchiya Thermostat Co., Ltd. | Method for producing hydrogen and apparatus for supplying hydrogen |
| WO2004002881A1 (en) * | 2002-06-26 | 2004-01-08 | Uchiya Thermostat Co.,Ltd. | Method for producing hydrogen and apparatus for supplying hydrogen |
| JP2020008001A (en) * | 2018-07-11 | 2020-01-16 | 日本碍子株式会社 | Exhaust gas heating system and exhaust gas heating method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US7655204B2 (en) | Heat-treated active carbons for use in denitration, processes for producing same, denitration method using same, and denitration system using same | |
| KR20070072535A (en) | Plasma-assisted nox reduction | |
| JPH03502426A (en) | Photo-enhanced method for decomposing nitrogen oxides into environmentally compatible products | |
| JPH0268404A (en) | Method and device for reducing nitrogen oxide (nox) from combustion exhaust gas | |
| US7468171B2 (en) | Process using microwave energy and a catalyst to decompose nitrogen oxides | |
| JPH04100518A (en) | Apparatus for treating exhaust gas from engine | |
| JPH03195305A (en) | Vehicle driven through diesel engine and motor | |
| CN216841896U (en) | Engine exhaust treatment system | |
| JPH04171022A (en) | Waste gas cleaning method | |
| JP3863610B2 (en) | Ammonia detoxification method and apparatus | |
| JPH038412A (en) | Method for removing nox in exhaust gas by electric discharge | |
| JP2986830B2 (en) | Engine exhaust gas treatment device | |
| CN216866824U (en) | Denitration treatment device for engine exhaust gas and engine exhaust gas treatment system | |
| JPH02214524A (en) | Method for removing nitrogen oxide | |
| JP3713634B2 (en) | Nitrogen oxide removal method and flue gas denitration equipment in exhaust gas | |
| JPS5995922A (en) | Denitration method of gas containing nox | |
| JP3574008B2 (en) | Carbon dioxide fixation device | |
| JPH03170316A (en) | Decomposition of carbon dioxide gas | |
| Cooper et al. | Apparatus and method for treating pollutants in a gas using hydrogen peroxide and UV light | |
| JPH03267558A (en) | Engine | |
| JPH065303A (en) | Ammonia synthesizing device utilizing fuel cell reaction | |
| JPH0656706A (en) | Production of carbonaceous fuel and method for regenerating gaseous carbon dioxide into resource | |
| JPH0929062A (en) | Exhaust gas treatment method and apparatus therefor | |
| JPS5910244B2 (en) | Nitrogen oxide decomposition method | |
| JPH045417A (en) | Exhaust gas treating device for engine |