JPH03267558A - Engine - Google Patents
EngineInfo
- Publication number
- JPH03267558A JPH03267558A JP2066263A JP6626390A JPH03267558A JP H03267558 A JPH03267558 A JP H03267558A JP 2066263 A JP2066263 A JP 2066263A JP 6626390 A JP6626390 A JP 6626390A JP H03267558 A JPH03267558 A JP H03267558A
- Authority
- JP
- Japan
- Prior art keywords
- magnetite
- hydrogen
- oxygen
- water
- activated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims abstract description 41
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 39
- 239000001257 hydrogen Substances 0.000 claims abstract description 38
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000001301 oxygen Substances 0.000 claims abstract description 20
- 239000000446 fuel Substances 0.000 claims description 15
- 150000002431 hydrogen Chemical class 0.000 claims description 9
- 150000002926 oxygen Chemical class 0.000 claims description 3
- 230000007547 defect Effects 0.000 claims 1
- 208000028659 discharge Diseases 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 14
- 238000006243 chemical reaction Methods 0.000 abstract description 8
- -1 oxygen ion Chemical class 0.000 abstract description 7
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 230000004308 accommodation Effects 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 238000002485 combustion reaction Methods 0.000 description 12
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 11
- 230000002950 deficient Effects 0.000 description 9
- 239000003502 gasoline Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001450 anions Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/30—Use of alternative fuels, e.g. biofuels
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
この発明は、燃料の一部あるいは全部に水素を使用した
水素エンジンに関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application This invention relates to a hydrogen engine that uses hydrogen as part or all of its fuel.
従来技術とその問題点
従来、水素エンジンについてはいろいろ考えられたいた
が、その燃料になる水素は予め化学工場でナフサ分解し
て得た水素を使用するものであり、危険な水素ボンベを
容易する必要があった。また、水を電気分解して水素を
得ることも考えられたが、電気分解するためのエネルギ
ーが過大になり、実用化が図れない欠点があった。Conventional technology and its problems In the past, various ideas have been made about hydrogen engines, but the hydrogen used as fuel is obtained by cracking naphtha in advance at a chemical factory, making it easy to use dangerous hydrogen cylinders. There was a need. It was also considered to obtain hydrogen by electrolyzing water, but this had the drawback that the energy required for electrolysis would be too much, making it impractical.
問題点を解決する手段
前記の問題点を解決するために、この発明は次の技術手
段を講じた。Means for Solving the Problems In order to solve the above problems, the present invention takes the following technical means.
即ち、この発明は、概ね２５０℃〜３５０℃近辺に保持
される恒温部にマグネタイトを収容する室を設け、この
室内のマグネタイトを畠電圧化あるいは減圧化等による
酸素イオン放出機構で該マグネタイトを活性化し、この
活性化した酸素欠陥マグネタイトに水を反応させて水素
を生成し、この水素をエンジンの燃料に使用したエンジ
ンとした。That is, the present invention provides a chamber containing magnetite in a constant temperature section maintained at approximately 250° C. to 350° C., and activates the magnetite in this chamber by an oxygen ion release mechanism such as by converting the magnetite into a field voltage or by reducing the pressure. This activated oxygen-deficient magnetite was reacted with water to produce hydrogen, and this hydrogen was used as fuel for the engine.
作用
この発明の基本的な作用は、マグネタイト（フェライト
）の分子構造が、２価の鉄（Ｆ ｅ２″″）が１個と３
価の鉄（Ｆ’ｅ”）が２個存在して計８価のプラス電荷
であり、これが陰イオンを保有する酸素（０”） ４個
と結び付いてＦｅ、０４の安定したマグネタイトになっ
ている。このマグネタイトを３００℃近辺の雰囲気のも
と高電圧あるいは減圧にすることで、酸素を除去させて
、酸素が欠乏した活性のマグネタイトとして変身させ、
この活性化ならしめた酸素欠陥マグネタイトＦｅ。Function The basic function of this invention is that the molecular structure of magnetite (ferrite) is composed of one divalent iron (Fe2'') and three
There are two valent irons (F'e") with a total of 8 positive charges, which combine with four anion-bearing oxygens (0") to form Fe, 04, a stable magnetite. There is. By subjecting this magnetite to high voltage or reduced pressure in an atmosphere around 300 degrees Celsius, oxygen is removed and it transforms into oxygen-deficient active magnetite.
This activated oxygen-deficient magnetite Fe.
○、−ｘに無尽蔵な水を反応させて簡単に水素と酸素に
分解させ、この水素を燃料に使用する。○, -x is reacted with inexhaustible water to easily decompose into hydrogen and oxygen, and this hydrogen is used as fuel.
実施例
この発明の一実施例について詳述すると、１はエンジン
で、園側の場合には、４気筒のガソリンエンジンを示し
、この４気筒のうちの１気筒の燃料を水素にしている。Embodiment One embodiment of the present invention will be described in detail. Reference numeral 1 denotes an engine. In the case of the park, it is a four-cylinder gasoline engine, and one of the four cylinders is fueled with hydrogen.
即ち、ｌａ、ｌｂ、ｌｃの燃焼室はガソリンを燃料とし
、残る１ｄの燃焼室は水素を燃料としている。２はピス
トン、３は吸入弁、４は排気弁を示す。５は排気通路で
ある。That is, the combustion chambers la, lb, and lc use gasoline as fuel, and the remaining combustion chamber 1d uses hydrogen as fuel. 2 is a piston, 3 is an intake valve, and 4 is an exhaust valve. 5 is an exhaust passage.
前記１ａ、ｌｂ、ｌｃの燃焼室に吸入弁から吸入される
燃料は、周知の気化器６を介して燃料タンク７から気化
した燃料（ガソリン）がピストン２の引っ込みで吸入さ
れる。そして、圧縮行程の終端で点火プラグ８によって
点火爆発されてピストン２からロッド９を介して連設さ
れたクランク軸１０が回転される。The fuel sucked into the combustion chambers 1a, lb, and lc from the intake valve is vaporized fuel (gasoline) from a fuel tank 7 via a well-known carburetor 6, and is sucked in by retraction of the piston 2. At the end of the compression stroke, the spark plug 8 causes ignition and explosion, and the crankshaft 10, which is connected to the piston 2 via the rod 9, is rotated.
また、燃焼室１ｄに吸収される燃料は水素であり、この
水素は、水素発生装置１１から供給される。Further, the fuel absorbed into the combustion chamber 1d is hydrogen, and this hydrogen is supplied from the hydrogen generator 11.
即ち、水素発生装置１１は、マグネタイト（Ｆｅ３０４
）１２を収容する室１３内をヒータ等の加温装置１４で
３００℃近辺に保温し、このマグネタイト１２に高電圧
発生器１４で電圧をかけて電子を飛ばし、その電子を該
マグネタイトに供与して酸素イオン（０２）を逃避なら
しめて酸素欠陥マグネタイト（Ｆｅ、Ｏ，ｘ）として活
性化させ、この活性化したマグネタイトにエンジン冷却
用に設けた水タンク１５からの水蒸気（Ｈ，Ｏ）を弁１
６の間欠的な開閉によって吹き付けて、水の酸素分子を
活性化マグネタイトに称わせ、水素（Ｈ２）を発生なら
しめる装置である。即ち、次の化学反応を行なう装置で
ある。That is, the hydrogen generator 11 is made of magnetite (Fe304
) 12 is kept at around 300° C. with a heating device 14 such as a heater, a voltage is applied to this magnetite 12 with a high voltage generator 14, electrons are blown off, and the electrons are donated to the magnetite. The oxygen ions (02) are made to escape and activated as oxygen-deficient magnetite (Fe, O, 1
This is a device that blows water by opening and closing intermittently to make the oxygen molecules of water convert into activated magnetite, thereby generating hydrogen (H2). That is, it is an apparatus for carrying out the following chemical reaction.
Ｆｅ、、０４ｘ＋ＸＨ，Ｏ−＋Ｆｅ、、Ｏ，＋１／２Ｘ
Ｈ。Fe,,04x+XH,O-+Fe,,O,+1/2X
H.
このようにして、マグネタイトで水を分解して得た水素
Ｈ２を前記エンジン１の燃焼室１ｄへ送り込むようにな
っている。In this way, hydrogen H2 obtained by decomposing water with magnetite is sent into the combustion chamber 1d of the engine 1.
マグネタイトの活性化は、高電圧で電子を供与するのが
便利であるが、マグネタイトを減圧してもよく、あるい
は、水素を与えて酸素を水として逃す手段も考えられる
。尚、図中１７は高電圧器用の端子を示す。For activation of magnetite, it is convenient to donate electrons at high voltage, but magnetite may be depressurized, or hydrogen may be supplied to release oxygen as water. In addition, numeral 17 in the figure indicates a terminal for a high voltage device.
上側の作用について詳述すると、第１図において、最初
は、ガソリンを燃料とした１８〜ＩＣの燃焼室によるエ
ンジン作動でエンジン１を始動する。そして、このエン
ジンによる発電機で高電圧を起こさせ、この電気エネル
ギーで水素発生装置１１のマグネタイトに電子を供与す
る。To explain the upper operation in detail, in FIG. 1, the engine 1 is first started by operating the combustion chamber of 18 to IC using gasoline as fuel. Then, a high voltage is generated by a generator using this engine, and the electric energy is used to donate electrons to the magnetite of the hydrogen generator 11.
すると、マグネタイトの酸素イオンが強制的に放出して
酸素欠陥マグネタイトＦ ｅ ３０ ａ ｘに変わる。Then, the oxygen ions of magnetite are forcibly released and turned into oxygen-deficient magnetite F e 30 a x .
この反応は。This reaction is.
Ｆｅ、０４−ｍ−→Ｆｅ、ｏ、ｘ＋ｘ／２０゜である。Fe, 04-m-→Fe, o, x+x/20°.
次に、水蒸気をマグネタイト室内に送り込むと、水（Ｈ
，Ｏ）の酸素が酸素欠陥マグネタイトと反応して、次の
反応式の通り不活性な元のマグネタイトと水素になる。Next, when water vapor is sent into the magnetite chamber, water (H
, O) reacts with oxygen-deficient magnetite to become inert original magnetite and hydrogen as shown in the following reaction formula.
ド ｅｌｏ、 ｘ ＋ １ ／ ２ ＸＨ
，Ｏ−一一−−−−→Ｆｅ、ｏ、＋１／２ＸＨ。de elo, x + 1/2 XH
, O-11---→Fe, o, +1/2XH.
このようにして得られた水素（Ｈ２）をエンジン１の燃
焼室１ｄに吸入ならしめて爆発させ、エンジン動力源と
する。The hydrogen (H2) thus obtained is sucked into the combustion chamber 1d of the engine 1 and exploded to serve as a power source for the engine.
この場合の排気は、当然ながら水素が燃えるから水であ
り、この水は水蒸気として排出されるからこれを冷却し
て再び水素源としての水としてリサイクルされる。Naturally, the exhaust gas in this case is water because hydrogen burns, and this water is discharged as water vapor, which is then cooled and recycled as water as a hydrogen source.
尚、エンジン１の１ａ〜ＩＣの燃焼室で燃やされた排気
ガスの炭酸ガスや窒素酸化物（ヂーゼルエンジンの場合
に多く発生）は、第２図で示した通り、上記の高電圧器
１４ａによる電子供与でマグネタイト１２ａが活性化さ
れた酸素欠陥マグネタイトＦｅ１０４−ｘを利用して分
解できる。即ち、炭酸ガスＣＯ７の酸素０２あるいはＮ
Ｏｘの酸素ＯＸを該酸素欠陥マグネタイトが取り込み
、炭素Ｃが析出したり、あるいは窒素ガスＮ、、になっ
て飛び出る。Incidentally, as shown in Fig. 2, the carbon dioxide and nitrogen oxides in the exhaust gas burned in the combustion chambers of 1a to IC of the engine 1 (often generated in diesel engines) are removed by the high voltage generator 14a as shown in Fig. 2. Magnetite 12a can be decomposed using oxygen-deficient magnetite Fe104-x, which is activated by electron donation. That is, oxygen 02 or N of carbon dioxide gas CO7
The oxygen-deficient magnetite takes in the oxygen OX, and carbon C precipitates or escapes as nitrogen gas N.
即ち、次の化学反応が行なわれる。That is, the following chemical reaction takes place.
Ｆ ｅ、０．−ｘ ＋ １ ／ ２ ＸＣＯ２−一→１
／２ＸＣ＋Ｆ ｅ、Ｏ４
あるいは、
ト’ｅ、０４ ｘ 十ＮＯｘ −−一一−−−今１／
２Ｎ、＋Ｆｅ、０４
の化学反応を起こして浄化される。Fe, 0. -x + 1/2 XCO2-1 → 1
/2
It is purified by causing a chemical reaction of 2N, +Fe, 04.
尚、窒素酸化物ＮＯｘについては、極めて速い反応にな
り、窒素酸化物の浄化は相当速く行なわれるが、炭酸ガ
スＣ○２については、反応が遅く、排気ガス処理部を加
圧状態にすることが望ましい。Regarding nitrogen oxides (NOx), the reaction is extremely fast and purification of nitrogen oxides is carried out fairly quickly, but for carbon dioxide gas (C○2), the reaction is slow and it is necessary to pressurize the exhaust gas treatment section. is desirable.
作用効果
この発明によると、エンジンの燃料として、酸素欠陥マ
グネタイトで水を分解した水素を利用でき、従来の電気
分解によって水がら水素を得る場合に比較して簡単に多
量の水素が小さいエネルギーで生成できて、無尽蔵な水
が燃料になり、効率的なエンジンが創作できる。Effects According to this invention, hydrogen obtained by decomposing water with oxygen-deficient magnetite can be used as engine fuel, and a large amount of hydrogen can be easily produced with less energy than when hydrogen is obtained from water by conventional electrolysis. The inexhaustible water can be used as fuel and an efficient engine can be created.
尚、実施例は、ガソリンエンジンの一部の燃焼室に水素
燃料を使用したが、水素燃料だけでエンジンを作動する
構成であってもよく、また、燃焼室にガソリンと水素と
を同時に混合させて供給する構成であっても差し支えな
い。また、ガソリンエンジンに限らず、ヂーゼルエンジ
ンにこの発明を応用して軽油と水素の燃料で作動させる
ものであってもよいことは勿論である。In the embodiment, hydrogen fuel was used in some combustion chambers of the gasoline engine, but the engine may be configured to operate only with hydrogen fuel, or gasoline and hydrogen may be mixed simultaneously in the combustion chamber. There is no problem even if the configuration is such that it is supplied by Furthermore, it goes without saying that the present invention is not limited to gasoline engines, but may also be applied to diesel engines to operate on diesel fuel and hydrogen.
図は、この発明の一実施例であって、第１図は一部断面
の要部の側面図、第２図は別個の要部の簡略斜面図であ
る。
図中の記号
１はエンジン、１８〜１ｂは燃焼室、２はピストン、３
は吸気弁、４は排気弁、５は排気通路、６は完化器、７
は燃焼タンク、８は点火プラグ、９はロンド、１０はク
ランク軸、１１は水素発生装置、１２はマグネタイト、
１３は室、１４は高電圧発生器、１５は水タンク、１６
は弁、１７は端子を示す。
第１図
第２図The drawings show an embodiment of the present invention, in which FIG. 1 is a partially sectional side view of the main parts, and FIG. 2 is a simplified perspective view of the main parts. In the figure, symbol 1 is the engine, 18 to 1b are the combustion chambers, 2 is the piston, and 3
is an intake valve, 4 is an exhaust valve, 5 is an exhaust passage, 6 is a completer, 7
is a combustion tank, 8 is a spark plug, 9 is a rond, 10 is a crankshaft, 11 is a hydrogen generator, 12 is a magnetite,
13 is a chamber, 14 is a high voltage generator, 15 is a water tank, 16
indicates a valve, and 17 indicates a terminal. Figure 1 Figure 2
Claims (1)
ネタイトを収容する室を設け、この室内のマグネタイト
を放電処理あるいは減圧処理による酸素イオン放出機構
で該マグネタイトを活性化し、この活性化した酸素欠陥
マグネタイトに水を反応させて水素を生成し、この水素
をエンジンの燃料に使用したエンジン。A chamber containing magnetite is provided in a constant temperature section maintained at approximately 250°C to 350°C, and the magnetite in this chamber is activated by an oxygen ion release mechanism using electric discharge treatment or reduced pressure treatment, and the activated oxygen defects are removed. An engine that generates hydrogen by reacting magnetite with water and uses this hydrogen as engine fuel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2066263A JPH03267558A (en) | 1990-03-15 | 1990-03-15 | Engine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2066263A JPH03267558A (en) | 1990-03-15 | 1990-03-15 | Engine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03267558A true JPH03267558A (en) | 1991-11-28 |
Family
ID=13310794
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2066263A Pending JPH03267558A (en) | 1990-03-15 | 1990-03-15 | Engine |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03267558A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002081368A1 (en) * | 2001-04-02 | 2002-10-17 | Uchiya Thermostat Co., Ltd. | Method for producing hydrogen and apparatus for supplying hydrogen |
| WO2004002881A1 (en) * | 2002-06-26 | 2004-01-08 | Uchiya Thermostat Co.,Ltd. | Method for producing hydrogen and apparatus for supplying hydrogen |
-
1990
- 1990-03-15 JP JP2066263A patent/JPH03267558A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002081368A1 (en) * | 2001-04-02 | 2002-10-17 | Uchiya Thermostat Co., Ltd. | Method for producing hydrogen and apparatus for supplying hydrogen |
| US7300643B2 (en) | 2001-04-02 | 2007-11-27 | Uchiya Thermostat Co., Ltd. | Method for producing hydrogen and apparatus for supplying hydrogen |
| WO2004002881A1 (en) * | 2002-06-26 | 2004-01-08 | Uchiya Thermostat Co.,Ltd. | Method for producing hydrogen and apparatus for supplying hydrogen |
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