JPH031337B2 - - Google Patents
Info
- Publication number
- JPH031337B2 JPH031337B2 JP58104669A JP10466983A JPH031337B2 JP H031337 B2 JPH031337 B2 JP H031337B2 JP 58104669 A JP58104669 A JP 58104669A JP 10466983 A JP10466983 A JP 10466983A JP H031337 B2 JPH031337 B2 JP H031337B2
- Authority
- JP
- Japan
- Prior art keywords
- golf ball
- rubber
- unsaturated carboxylic
- rubber component
- carboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001735 carboxylic acids Chemical class 0.000 claims description 9
- 229920001971 elastomer Polymers 0.000 claims description 9
- 239000005060 rubber Substances 0.000 claims description 9
- 229910052751 metal Chemical class 0.000 claims description 7
- 239000002184 metal Chemical class 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- CPGFMWPQXUXQRX-UHFFFAOYSA-N 3-amino-3-(4-fluorophenyl)propanoic acid Chemical compound OC(=O)CC(N)C1=CC=C(F)C=C1 CPGFMWPQXUXQRX-UHFFFAOYSA-N 0.000 claims description 5
- 239000003828 free initiator Substances 0.000 claims description 3
- 229920002857 polybutadiene Polymers 0.000 claims description 3
- 239000007787 solid Substances 0.000 description 10
- 239000000178 monomer Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- -1 etc. Chemical class 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 150000003751 zinc Chemical class 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- 229920003311 DuPont™ Surlyn® 1601 Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Description
本発明は新規なソリツドゴルフボールに関す
る。ソリツドゴルフボールには1つの構成物から
なるワンピースゴルフボールとソリツドコアをカ
バーで被覆したツーピースゴルフボールおよびソ
リツドコアとカバーとの間に適当な1ないし複数
の中間層を有する多層構造のゴルフボールがあ
る。これらのソリツドゴルフボールとして、その
反発係数を向上させ、かつ耐衝撃性を向上させる
ために、α,β−モノエチレン系不飽和カルボン
酸の金属塩等の不飽和結合を有するモノマーを共
架橋剤として配合したものが知られている。これ
らのソリツドゴルフボールは、それ自体かなり優
れた性能を有しているが、より優れた反発係数お
よび耐久性を有するゴルフボールが要請されてい
る。
従来、ソリツドゴルフボールの組成物に添加さ
れるα,β−エチレン系不飽和カルボン酸金属塩
モノマーを添加したソリツドゴルフボールは、こ
れらのモノマーが遊離開始剤によつてポリブタジ
エン主鎖にグラフトされ、共架橋剤として働き、
これによりボールに適度の硬さ(コンプレツシヨ
ン 圧縮比)と耐久性を与えるものと考えられて
いた。然しながら、この共架橋された際に生ずる
グラフト鎖が長くなると、ポリブタジエンゴムに
他のポリマーを配合したのと同様の結果、即ちゴ
ルフボールの反発性能の低下をきたす事となる。
本発明者らは前記α,β−エチレン系不飽和カ
ルボン酸の共架橋に際して生ずるグラフト鎖の長
さを調節する事により、適度の硬さと耐久性を付
与しながら、同時に反発性能を著しく向上させる
事を試みる内、ジペンタメチレンチウラムテトラ
スルフイド及び/又はその誘導体がグラフト鎖の
分子量調整剤として非常に優れた性能を有する事
を見出し、本発明を完成した。即ち、本発明は
α,β−エチレン系不飽和カルボン酸またはその
金属塩、遊離開始剤およびジペンタメチレンチウ
ラムテトラスルフイド及び/又はその誘導体を含
有するゴム組成物から形成したゴルフボールを提
供する。
本発明に於て使用するα,β−モノエチレン系
不飽和カルボン酸、例えば特公昭55−19615号公
報に記載されている様な、アクリル酸又はメタク
リル酸等であり、特にアクリル酸が好ましい。勿
論アクリル酸とメタクリル酸とを併用してもよ
い。上記のα,β−モノエチレン系不飽和カルボ
ン酸の金属塩は2価の金属塩、例えば亜鉛塩、カ
ルシウム塩、マグネシウム塩、ジルコニウム塩等
であるが、特に亜鉛塩が好ましい。
ジペンタメチレンチウラムテトラスルフイド及
び/又はその誘導体の使用量はゴム成分100重量
部に対し約0.1〜約5重量部であり、0.1重量部よ
り少量の場合は添加した効果が充分に発揮されな
い。
本発明の実施に用いられるゴム成分としてはポ
リブタタジエンを単独又は天然ゴム、合成ポリイ
ソプレンゴム等をゴム成分の約10重量%以下混合
して用いる。合成ポリイソプレンや天然ゴムが10
%以上配合されると、得られたボールの反発係数
が著しく低下する。
本発明のソリツドゴルフボールには、さらに
α,β−エチレン系不飽和カルボン酸を重合させ
る為の遊離基開始剤、例えばジクミルパーオキシ
ド等、老化防止剤、酸化亜鉛等の充填剤を適当量
配合する。
本発明で得られるソリツドゴルフボールは、前
述の如く、ワンピースゴルフボール、ツーピース
ゴルフボール及び多層構造のゴルフボールであつ
てもよく、いずれに於てもα,β−エチレン系不
飽和カルボン酸金属塩等のモノマーを単独で使用
した場合に比べ、著しく優れた反発性能、耐久性
およびフライトキヤリー特性を示す。
以下、実施例を挙げて本発明を説明する。
実施例 1〜3及び比較例 1〜4
表−1に示す処方で直径約39mmのゴルフボール
用コアを製造し、その反発係数と耐久性指数を常
法により測定した。さらにこのゴルフボール用コ
ア表面に厚み約2mmのカバー(サーリン1601)を
被覆し、そのフライトキヤリーを測定した。結果
を表−1、表−2に示す。
The present invention relates to a novel solid golf ball. Solid golf balls include one-piece golf balls consisting of one composition, two-piece golf balls having a solid core covered with a cover, and multilayer golf balls having one or more suitable intermediate layers between the solid core and the cover. . In order to improve the coefficient of restitution and impact resistance of these solid golf balls, we co-crosslink monomers with unsaturated bonds such as metal salts of α,β-monoethylenically unsaturated carboxylic acids. It is known that it is formulated as an agent. Although these solid golf balls themselves have fairly good performance, there is a need for golf balls that have better coefficients of restitution and durability. Conventionally, solid golf balls containing α,β-ethylenically unsaturated carboxylic acid metal salt monomers, which are added to solid golf ball compositions, are produced by grafting these monomers onto the polybutadiene main chain using a free initiator. and acts as a co-crosslinking agent,
This was thought to give the ball appropriate hardness (compression ratio) and durability. However, if the graft chains produced during this co-crosslinking become longer, the result will be the same as when other polymers are blended with polybutadiene rubber, that is, the repulsion performance of the golf ball will be reduced. By adjusting the length of the graft chains generated during co-crosslinking of the α,β-ethylenically unsaturated carboxylic acids, the present inventors have achieved a method that significantly improves repulsion performance while imparting appropriate hardness and durability. While trying this, the inventors discovered that dipentamethylenethiuram tetrasulfide and/or its derivatives have very excellent performance as a molecular weight regulator for graft chains, and completed the present invention. That is, the present invention provides a golf ball formed from a rubber composition containing an α,β-ethylenically unsaturated carboxylic acid or a metal salt thereof, a free initiator, and dipentamethylenethiuram tetrasulfide and/or a derivative thereof. do. The α,β-monoethylenically unsaturated carboxylic acid used in the present invention is, for example, acrylic acid or methacrylic acid as described in Japanese Patent Publication No. 55-19615, with acrylic acid being particularly preferred. Of course, acrylic acid and methacrylic acid may be used together. The metal salt of the α,β-monoethylenically unsaturated carboxylic acid mentioned above is a divalent metal salt such as a zinc salt, a calcium salt, a magnesium salt, a zirconium salt, etc., and a zinc salt is particularly preferred. The amount of dipentamethylenethiuram tetrasulfide and/or its derivatives used is about 0.1 to about 5 parts by weight per 100 parts by weight of the rubber component, and if it is less than 0.1 part by weight, the added effect will not be fully exhibited. . As the rubber component used in the practice of the present invention, polybutatadiene is used alone, or natural rubber, synthetic polyisoprene rubber, etc. are used in a mixture of not more than about 10% by weight of the rubber component. Synthetic polyisoprene and natural rubber are 10
If more than % is added, the coefficient of restitution of the resulting ball will be significantly lowered. The solid golf ball of the present invention may further contain a free radical initiator for polymerizing the α,β-ethylenically unsaturated carboxylic acid, such as dicumyl peroxide, an antiaging agent, and a filler such as zinc oxide. Mix the amounts. As mentioned above, the solid golf ball obtained by the present invention may be a one-piece golf ball, a two-piece golf ball, or a golf ball with a multilayer structure, and in any of them, α,β-ethylenically unsaturated carboxylic acid metal It exhibits significantly superior repulsion performance, durability, and flight carry characteristics compared to when monomers such as salts are used alone. The present invention will be explained below with reference to Examples. Examples 1 to 3 and Comparative Examples 1 to 4 Golf ball cores having a diameter of about 39 mm were manufactured using the formulations shown in Table 1, and their coefficient of restitution and durability index were measured by conventional methods. Further, a cover (Surlyn 1601) having a thickness of approximately 2 mm was coated on the surface of this golf ball core, and its flight carry was measured. The results are shown in Table-1 and Table-2.
【表】【table】
【表】【table】
【表】【table】
Claims (1)
その金属塩、遊離開始剤およびジペンタメチレン
チウラムテトラスルフイド及び/又はその誘導体
を含有するゴム組成物から形成されるソリツドゴ
ルフボール。 2 ジペンタメチレンチウラムテトラスルフイド
及び/又はその誘導体をゴム成分の0.1〜5重量
%含有する第1項記載のゴルフボール。 3 ゴム成分がポリブタジエンゴムを全ゴム成分
の90重量%以上含有する第1項記載のゴルフボー
ル。[Scope of Claims] 1. A sol formed from a rubber composition containing an α,β-ethylenically unsaturated carboxylic acid or a metal salt thereof, a free initiator, and dipentamethylenethiuram tetrasulfide and/or a derivative thereof. Tsudo golf ball. 2. The golf ball according to item 1, which contains dipentamethylenethiuram tetrasulfide and/or its derivatives in an amount of 0.1 to 5% by weight based on the rubber component. 3. The golf ball according to item 1, wherein the rubber component contains polybutadiene rubber in an amount of 90% or more by weight of the total rubber component.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58104669A JPS59228868A (en) | 1983-06-10 | 1983-06-10 | Solid golf ball |
GB08414497A GB2142640B (en) | 1983-06-10 | 1984-06-07 | Solid golf balls |
US06/618,448 US4556220A (en) | 1983-06-10 | 1984-06-07 | Solid golf balls |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58104669A JPS59228868A (en) | 1983-06-10 | 1983-06-10 | Solid golf ball |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59228868A JPS59228868A (en) | 1984-12-22 |
JPH031337B2 true JPH031337B2 (en) | 1991-01-10 |
Family
ID=14386871
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58104669A Granted JPS59228868A (en) | 1983-06-10 | 1983-06-10 | Solid golf ball |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59228868A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2669051B2 (en) * | 1989-05-11 | 1997-10-27 | ブリヂストンスポーツ株式会社 | Solid golf ball |
US5919101A (en) * | 1995-08-25 | 1999-07-06 | Sumitomo Rubber Industries, Ltd. | Solid golf ball |
JP6379242B2 (en) * | 2016-03-24 | 2018-08-22 | キャスコ株式会社 | Rubber composition for golf ball and golf ball |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4881951A (en) * | 1972-01-17 | 1973-11-01 |
-
1983
- 1983-06-10 JP JP58104669A patent/JPS59228868A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4881951A (en) * | 1972-01-17 | 1973-11-01 |
Also Published As
Publication number | Publication date |
---|---|
JPS59228868A (en) | 1984-12-22 |
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