JPH02209230A - Insect-resistant heat insulating board - Google Patents

Insect-resistant heat insulating board

Info

Publication number
JPH02209230A
JPH02209230A JP1032320A JP3232089A JPH02209230A JP H02209230 A JPH02209230 A JP H02209230A JP 1032320 A JP1032320 A JP 1032320A JP 3232089 A JP3232089 A JP 3232089A JP H02209230 A JPH02209230 A JP H02209230A
Authority
JP
Japan
Prior art keywords
heat insulating
synthetic resin
resin foam
plate
foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1032320A
Other languages
Japanese (ja)
Inventor
Seiji Ishino
政治 石野
Osamu Tarue
樽栄 修
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyo Tire Corp
Original Assignee
Toyo Tire and Rubber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Tire and Rubber Co Ltd filed Critical Toyo Tire and Rubber Co Ltd
Priority to JP1032320A priority Critical patent/JPH02209230A/en
Publication of JPH02209230A publication Critical patent/JPH02209230A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To keep perfect insect-resistant effect for a long period of time by coating the surface of the foamed resin constituting a heat insulating board with a microencapsulated insecticide. CONSTITUTION:As the synthetic resin foam used as a heat insulating material 1, thermosetting resin foam such as polyurethane foam, phenol resin foam, urea resin foam or melamine resin foam is pref. used and, as a surface material 2, any one of surface materials used as the surface material of a known laminated heat insulating panel such as a metal plate such as a steel plate, a zinc plated steel plate or an aluminum plate, a metal foil such as an aluminum foil, a synthetic resin plate, a glass fiber reinforced synthetic resin plate, a synthetic resin film, paper or fire-retardant cardboard can be used. In order to form a film containing a microencapsulated insecticide to the end surface of the heat insulating material, for example, an aqueous microcapsule suspension is mixed with paint based on an aqueous acrylic emulsion or an aqueous vinyl acetate emulsion before coating.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は害虫の食害を防止した建材用断熱ボードに関し
、特に畜舎等の断熱材として用いられる防虫断熱ボード
に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a heat insulation board for building materials that prevents insect damage, and particularly to an insect-proof heat insulation board used as a heat insulator for livestock barns and the like.

〔従来の技術〕[Conventional technology]

硬質ウレタ)フオーム板の両面に紙又は合成樹脂よりな
る表覚材を積層してなる断熱ボードが、る。
A heat insulating board is made by laminating a surface material made of paper or synthetic resin on both sides of a hard urethane foam board.

これらの断熱ボードをの端面にウレタンフオームが露出
していると、その断熱ボードを畜舎や鶏舎の断熱材とし
て使用した場合に、その端面より、ガイマイゴミムシダ
マシの幼虫等の害虫が侵入して、発泡樹脂よりなる断熱
材が食害され、大量に繁殖して断熱材の内部が殆ど空洞
化し、断熱性が低下するという問題がある。
If the urethane foam is exposed on the edges of these insulation boards, when the insulation boards are used as insulation for livestock or poultry houses, pests such as the larvae of the snail beetle can invade through the edges. There is a problem in that the heat insulating material made of foamed resin is eaten away and propagated in large quantities, and the inside of the heat insulating material becomes almost hollow, resulting in a decrease in heat insulation properties.

これを防ぐために、その端面にアルミニウム箔等よりな
る粘着テープを貼着する方法、断熱ボードの製造時に断
熱ボードの端面に被覆材を配置して一体に発泡接合する
方法、該端面に合成樹脂塗料等を塗装、被覆する方法等
が試みられている。
To prevent this, methods include attaching adhesive tape made of aluminum foil or the like to the end surfaces, placing a covering material on the end surfaces of the insulation boards and foaming them together when manufacturing the insulation boards, and applying synthetic resin paint to the end surfaces. Attempts have been made to paint or cover such materials.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

上記従来の断熱ボードの害虫による食害を防止する方法
のうち、断熱ボードの端面に粘着テープを貼着する方法
は耐久性に乏しく、長期間使用する間に粘着テープの粘
着力が低下して剥離してしまうという欠点がある。
Among the conventional methods for preventing insect damage to insulation boards, the method of pasting adhesive tape to the edges of insulation boards is not durable, and the adhesive strength of the adhesive tape decreases and peels off after long periods of use. There is a drawback that it does.

断熱ボードの製造時に端面に被覆材を配置して一体に発
泡接合する方法は、工程が複雑で、製造コストが嵩むと
いう欠点があり、また断熱ボードの端面を塗装被覆する
だけでは、防虫効果が完全でない。
When manufacturing insulation boards, the method of placing a covering material on the end face and foaming them together has the drawbacks of a complicated process and increased production costs.Furthermore, simply coating the end face of the insulation board with paint does not have an insect repellent effect. Not perfect.

従って、本発明は害虫による食害を完全に防止すること
ができ、その防虫効果を長期間維持することができる断
熱ボードを提供することを目的とする。
Therefore, an object of the present invention is to provide a heat insulating board that can completely prevent feeding damage caused by pests and maintain its insect repellent effect for a long period of time.

〔間頚点を解決するための手段〕[Means for solving interjugular points]

上記目的を達成すべく、本発明者らは鋭意研究を重ねた
結果、マイクロカプセル化した殺虫剤を断熱ボードを構
成する発泡樹脂内部に分散または発泡樹脂表面に塗布す
ることにより完全な防虫効果を長期間維持しうろことを
見出し、本発明を完成するに至った。
In order to achieve the above object, the inventors of the present invention have conducted intensive research and found that a complete insect repellent effect can be achieved by dispersing microencapsulated insecticides inside the foamed resin that makes up the insulation board or by applying it to the foamed resin surface. They discovered that the scales can be maintained for a long period of time, and completed the present invention.

即ち、本発明は合成樹脂発泡体よりなる断熱ボードにお
いて、該合成樹脂発泡体の内部にマイクロカプセル化し
た殺虫剤を分散、または該合成樹脂発泡体表面にマイク
ロカプセル化した殺虫剤を含む塗膜を形成したことを特
徴とする防虫断熱ボードを要旨とする。
That is, the present invention provides an insulating board made of a synthetic resin foam, in which a microencapsulated insecticide is dispersed inside the synthetic resin foam, or a coating film containing a microencapsulated insecticide is coated on the surface of the synthetic resin foam. The gist of the present invention is an insect-proof and heat-insulating board characterized by forming the following.

次に本発明の内容を図面により詳細に説明する。Next, the content of the present invention will be explained in detail with reference to the drawings.

第1図及び第2図は本発明の防虫断熱ボードの一例の断
面図である。(1)はポリウレタン樹脂等の合成樹脂発
泡体よりなる板状の断熱材であり、(2)はその両面を
被覆する金属、合成樹脂又は紙よりなるシート状の表面
材である。
FIGS. 1 and 2 are cross-sectional views of an example of the insect-proof insulation board of the present invention. (1) is a plate-shaped heat insulating material made of synthetic resin foam such as polyurethane resin, and (2) is a sheet-like surface material made of metal, synthetic resin, or paper covering both sides of the heat insulating material.

断熱材(1)として用いられる合成樹脂発泡体は、ポリ
ウレタンフォーム、フェノール樹脂フオーム、尿素樹脂
フオーム、メラミン樹脂フオーム等の熱硬化性樹脂発泡
体が好ましく用いられ、硬質合成樹脂発泡体が特に好ま
しく用いられる。又ポリスチレンフオーム、ポリエチレ
ンフオームその他の熱可塑性合成樹脂発泡体も使用可能
である。
As the synthetic resin foam used as the heat insulating material (1), thermosetting resin foams such as polyurethane foam, phenol resin foam, urea resin foam, melamine resin foam are preferably used, and rigid synthetic resin foams are particularly preferably used. It will be done. Polystyrene foam, polyethylene foam and other thermoplastic synthetic resin foams can also be used.

合成樹脂発泡体の厚みはとくに制限はないが、10〜1
00mmの厚みが普通に用いられる。
There is no particular limit to the thickness of the synthetic resin foam, but it is between 10 and 1
A thickness of 0.00 mm is commonly used.

表面材(2)は断熱材(1)の両面を被覆してもよいし
、片面のみを被覆してもよい。また場合によっては、表
面材(2)を省略してもよい。
The surface material (2) may cover both sides of the heat insulating material (1), or may cover only one side. Further, depending on the case, the surface material (2) may be omitted.

本発明の断熱ボードにおいて、表面材(2)としては、
鋼板、亜鉛メツキ鋼板、アルミニウム板等の金属板、ア
ルミニウム箔等の金属箔、合成樹脂板、ガラス繊維補強
合成樹脂板、合成樹脂フィルム、紙、難燃性板紙等公知
の積層断熱板の表面材として使用される表面材はいずれ
も使用可能であり、これらを積層したシート材も用いら
れる。表面材は平面状だけでなく、断面が波形形状であ
ってもよい。
In the heat insulation board of the present invention, the surface material (2) includes:
Metal plates such as steel plates, galvanized steel plates, and aluminum plates, metal foils such as aluminum foil, synthetic resin plates, glass fiber-reinforced synthetic resin plates, synthetic resin films, paper, flame-retardant paperboard, and other known surface materials for laminated insulation boards. Any of the surface materials used as such can be used, and sheet materials made by laminating these materials can also be used. The surface material may not only be planar, but may also have a wavy cross section.

断熱材(1)の内部に殺虫剤を内包したマイクロカプセ
ルを分散するか又は断熱材(1)の端面(3)に殺虫剤
を内包したマイクロカプセルを含む塗膜(4)を形成す
る。
Microcapsules containing an insecticide are dispersed inside the heat insulating material (1), or a coating film (4) containing microcapsules containing the pesticide is formed on the end surface (3) of the heat insulating material (1).

マイクロカプセルに内包する殺虫剤は公知のあらゆる種
類の殺虫剤が使用可能であるが、例えばダイアジノン等
の人体または哺乳動物に対する毒性の比較的小さいもの
が望ましい。
All kinds of known insecticides can be used as the insecticide to be encapsulated in the microcapsules, but it is preferable to use one that has relatively low toxicity to the human body or mammals, such as diazinon.

マイクロカプセルの皮膜の材質は特に制限はなく、ポリ
アミド樹脂、ポリエチレンスルホン酸樹脂、ビニル化合
物と無水フタル酸の共重合体、ゼラチン、カゼイン、ア
ルブミン等の水溶性蛋白質、アラビヤゴム、寒天、アル
ギン酸ナトリウム、セルロース誘導体等の炭水化物等の
公知のマイクロカプセル皮膜が用いられる。これらの皮
膜の種類に応じて、公知の方法により殺虫剤を内包した
マイクロカプセルを製造する。
The material of the microcapsule film is not particularly limited, and may include polyamide resin, polyethylene sulfonic acid resin, copolymer of vinyl compound and phthalic anhydride, water-soluble proteins such as gelatin, casein, and albumin, gum arabic, agar, sodium alginate, and cellulose. Known microcapsule coatings such as carbohydrates such as derivatives can be used. Microcapsules encapsulating insecticides are manufactured by known methods depending on the type of these films.

マイクロカプセルの粒径は特に制限はなく、数μ乃至数
百μのも・のが使用可能であり、製造及び取扱いの容易
さを考慮して、例えば5〜30μのものが用いられる。
There is no particular restriction on the particle size of the microcapsules, and those from several microns to several hundred microns can be used, and in consideration of ease of production and handling, for example, those from 5 to 30 microns are used.

ポリウレタン樹脂発泡体等よりなる断熱材(1)の内部
にマイクロカプセルを分散する場合には、発泡体を発泡
成型する際に、ポリウレタンの原料であるポリイソシア
ネートとポリオールに水性マイクロカプセル懸濁液を添
加、均一に混合して表面材(2〕の間で発泡させ、断熱
材(1)と表面材(2)を一体に成型することができる
When microcapsules are dispersed inside a heat insulating material (1) made of polyurethane resin foam, etc., an aqueous microcapsule suspension is added to polyisocyanate and polyol, which are raw materials for polyurethane, when foam-molding the foam. The heat insulating material (1) and the surface material (2) can be integrally molded by adding and uniformly mixing and foaming between the surface materials (2).

この場合のマイクロカプセルの添加量は特に制限はない
が、発泡体に対してマイクロカプセルを0.1〜10重
量%、好ましくは0.2〜1重量%添加することができ
る。
Although there is no particular restriction on the amount of microcapsules added in this case, the microcapsules can be added in an amount of 0.1 to 10% by weight, preferably 0.2 to 1% by weight, based on the foam.

断熱材(1)の端面(3)にマイクロカプセル化した殺
虫剤を含む塗膜を形成する場合は、例えば水性アクリル
エマルジョン、水性酢酸ビニルエマルジョン等を主成分
とする塗料中に水性マイクロカプセル懸濁液を混合して
塗布することができる。
When forming a coating film containing a microencapsulated insecticide on the end face (3) of the heat insulating material (1), for example, water-based microcapsules are suspended in a paint whose main component is an aqueous acrylic emulsion, an aqueous vinyl acetate emulsion, etc. Liquids can be mixed and applied.

断熱ボードが断熱材(1)の両面に表面材(2)を積層
してなる場合は、断熱材(1)の端面(3)にのみマイ
クロカプセル化した殺虫剤を含む塗膜を形成すればよく
、表面材(2)を両面に被覆しない場合は露出する断熱
材(1)の表面に上記塗膜を形成すればよい。
If the insulation board is made by laminating the surface material (2) on both sides of the insulation material (1), it is possible to form a coating film containing the microencapsulated insecticide only on the end surface (3) of the insulation material (1). If both surfaces are not coated with the surface material (2), the coating film may be formed on the exposed surface of the heat insulating material (1).

本発明で用いるマイクロカプセルに殺虫剤を内包する代
わりに、害虫が嫌う忌避剤を内包してもよい。また殺虫
剤の代わりに、殺鼠剤或いは鼠の忌避剤を用いれば、鼠
の食害を防止することができ、これらを殺虫剤と併用す
ることもできる。
Instead of encapsulating an insecticide in the microcapsules used in the present invention, a repellent that pests dislike may be encapsulated therein. Moreover, if a rat poison or a rat repellent is used instead of an insecticide, feeding damage by rats can be prevented, and these can also be used in combination with the insecticide.

〔作用〕[Effect]

本発明の防虫断熱ボードによれば、マイクロカプセル化
した殺虫剤が断熱材(1)の内部または断熱材(1)表
面に形成した塗膜中に分散されているため、マイクロカ
プセルに内包された殺虫剤は揮発性が極めて小さくなり
長期間安定に存在し、殺虫効果が長期間持続する。また
マイクロカプセルが防虫断熱ボードの表面に露出せず、
断熱材(1)の合成樹脂または塗膜に被覆されているた
め、更に安定性が増す。
According to the insect-proof and heat-insulating board of the present invention, the micro-encapsulated insecticide is dispersed inside the heat-insulating material (1) or in the coating film formed on the surface of the heat-insulating material (1). Insecticides have extremely low volatility and remain stable for long periods of time, resulting in long-lasting insecticidal effects. In addition, the microcapsules are not exposed on the surface of the insect-proof insulation board.
Since it is coated with the synthetic resin or coating of the heat insulating material (1), its stability is further increased.

〔発明の効果〕〔Effect of the invention〕

本発明の防虫断熱ボードによれば、害虫による断熱ボー
ドの食害を完全に防止することができ、その防虫効果を
長期間維持することができると共に、人体及び動物に対
する毒性を全くなくすることができ、環境を汚染する虞
もない。
According to the insect-proof insulation board of the present invention, it is possible to completely prevent pests from eating the insulation board, maintain its insect-proofing effect for a long period of time, and completely eliminate toxicity to humans and animals. , there is no risk of polluting the environment.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図及び第2図はは本発明の防虫断熱ボードの一例の
断面図である。 (1)断熱材、     (2)表面材、(3)端面、
      (4)塗膜。 特許出願人  東洋ゴム工業株式会社 代理人 弁理士 小  山  義  2第  図 1 断熱材 ク ツ 第  図 手続補正書働刻 平成元年 9月/7日 平成1年特許願第32320号 2、発明の名称 防虫断熱ボード 3、補正をする者 事件との関係 特許出願人 住所 大阪市西区江戸堀1丁目17番18号名称 (3
14)東洋ゴム工業株式会社代表者 香  取  健 4、代理人 平成1年5月15日 (平成1年5月30日発送) 8゜ 補正の内容 図面を別紙訂正図面のとおり補正する。 第、4図 以上 ! 断熱材 表面材 3−・端面 ゛・塗膜 手 続 補 正 書 (自発) 8゜ 補正の内容 明細書全文を別紙訂正明細書のとおり補正する。 ■。 事件の表示 以上 平成1年特許願第3 20号 2゜ 発明の名称 防虫断熱ボード 3゜ 補正をする者 事件との関係
FIGS. 1 and 2 are cross-sectional views of an example of the insect-proof insulation board of the present invention. (1) Heat insulating material, (2) Surface material, (3) End surface,
(4) Paint film. Patent applicant Toyo Tire & Rubber Industries Co., Ltd. Agent Patent attorney Yoshi Koyama 2nd Figure 1 Insulating shoes No. Drawing procedure amendment filed September/7th, 1989 Patent Application No. 32320, 1999 2, Title of the invention Insect-proof insulation board 3, relationship with the amended case Patent applicant address 1-17-18 Edobori, Nishi-ku, Osaka Name (3
14) Toyo Rubber Industries Co., Ltd. Representative Ken Katori 4, Agent May 15, 1999 (Shipped on May 30, 1999) 8゜Amendment Details The drawings will be amended as shown in the attached corrected drawings. Figure 4 and above! Insulating material surface material 3-/End face/Coating film procedure amendment (voluntary) 8゜The entire statement of contents of the amendment shall be amended as shown in the attached amendment statement. ■. Above the description of the case 1999 Patent Application No. 3 20 2゜Name of the invention Insect-proof insulation board 3゜Relationship with the case

Claims (2)

【特許請求の範囲】[Claims] (1)合成樹脂発泡体よりなる断熱ボードにおいて、該
合成樹脂発泡体の内部にマイクロカプセル化した殺虫剤
を分散、または該合成樹脂発泡体表面にマイクロカプセ
ル化した殺虫剤を含む塗膜を形成したことを特徴とする
防虫断熱ボード。
(1) In a heat insulation board made of synthetic resin foam, a microencapsulated insecticide is dispersed inside the synthetic resin foam, or a coating film containing the microencapsulated insecticide is formed on the surface of the synthetic resin foam. Insect-proof insulation board characterized by:
(2)板状の該合成樹脂発泡体の両面または片面にシー
ト状の表面材を積層してなる請求項1項記載の防虫断熱
ボード。
(2) The insect-proof insulation board according to claim 1, wherein a sheet-like surface material is laminated on both or one side of the plate-like synthetic resin foam.
JP1032320A 1989-02-10 1989-02-10 Insect-resistant heat insulating board Pending JPH02209230A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1032320A JPH02209230A (en) 1989-02-10 1989-02-10 Insect-resistant heat insulating board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1032320A JPH02209230A (en) 1989-02-10 1989-02-10 Insect-resistant heat insulating board

Publications (1)

Publication Number Publication Date
JPH02209230A true JPH02209230A (en) 1990-08-20

Family

ID=12355646

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1032320A Pending JPH02209230A (en) 1989-02-10 1989-02-10 Insect-resistant heat insulating board

Country Status (1)

Country Link
JP (1) JPH02209230A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010083657A (en) * 2000-02-17 2001-09-01 안민동 Resin-impregnated insecticide
KR100431574B1 (en) * 1996-12-11 2004-08-25 주식회사 엘지화학 Method of manufacturing a mothproofed melanin decoration panel
KR100449258B1 (en) * 2002-11-25 2004-09-18 오상택 Method of manufacturing the chamber for environment test
US6983571B2 (en) 2000-09-29 2006-01-10 Teel Plastics, Inc. Composite roofing panel
WO2006070183A1 (en) * 2004-12-30 2006-07-06 Syngenta Limited Aqueous coating compositions
WO2011012935A2 (en) * 2009-07-29 2011-02-03 Universidade Do Minho Photocatalytic coating for the controlled release of volatile agents
CN102364000A (en) * 2011-10-11 2012-02-29 常熟市华夏建筑节能材料有限公司 Thermal insulation floor
AU2012258505B2 (en) * 2004-12-30 2015-05-28 Syngenta Limited Aqueous coating compositions
WO2015164925A1 (en) * 2014-04-30 2015-11-05 The Wilpak Group Pty Ltd Pest repellent and/or recyclable multilayer sheet material and packaging made therefrom
WO2017104473A1 (en) * 2015-12-14 2017-06-22 吉野石膏株式会社 Gypsum board and process for producing gypsum board

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100431574B1 (en) * 1996-12-11 2004-08-25 주식회사 엘지화학 Method of manufacturing a mothproofed melanin decoration panel
KR20010083657A (en) * 2000-02-17 2001-09-01 안민동 Resin-impregnated insecticide
US6983571B2 (en) 2000-09-29 2006-01-10 Teel Plastics, Inc. Composite roofing panel
KR100449258B1 (en) * 2002-11-25 2004-09-18 오상택 Method of manufacturing the chamber for environment test
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