JPH0155289B2 - - Google Patents
Info
- Publication number
- JPH0155289B2 JPH0155289B2 JP56046828A JP4682881A JPH0155289B2 JP H0155289 B2 JPH0155289 B2 JP H0155289B2 JP 56046828 A JP56046828 A JP 56046828A JP 4682881 A JP4682881 A JP 4682881A JP H0155289 B2 JPH0155289 B2 JP H0155289B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- acid
- epoxy
- bis
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003822 epoxy resin Substances 0.000 claims description 52
- 229920000647 polyepoxide Polymers 0.000 claims description 52
- 150000001875 compounds Chemical class 0.000 claims description 39
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 18
- 239000004593 Epoxy Substances 0.000 claims description 15
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 12
- 229920005862 polyol Polymers 0.000 claims description 12
- 150000003077 polyols Chemical class 0.000 claims description 11
- 125000003700 epoxy group Chemical group 0.000 claims description 6
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 5
- 239000005056 polyisocyanate Substances 0.000 claims description 5
- 229920001228 polyisocyanate Polymers 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 2
- WDGCBNTXZHJTHJ-UHFFFAOYSA-N 2h-1,3-oxazol-2-id-4-one Chemical group O=C1CO[C-]=N1 WDGCBNTXZHJTHJ-UHFFFAOYSA-N 0.000 claims 1
- -1 acrylonitrile butadiene compound Chemical class 0.000 description 41
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 39
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 37
- 125000002947 alkylene group Chemical group 0.000 description 22
- 125000003118 aryl group Chemical group 0.000 description 19
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 12
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 150000002989 phenols Chemical class 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 9
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 125000001118 alkylidene group Chemical group 0.000 description 7
- 150000007514 bases Chemical class 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 239000004721 Polyphenylene oxide Substances 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 150000001299 aldehydes Chemical class 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 229920000570 polyether Polymers 0.000 description 6
- 150000005846 sugar alcohols Polymers 0.000 description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical group C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 239000011976 maleic acid Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- IZXIZTKNFFYFOF-UHFFFAOYSA-N 2-Oxazolidone Chemical group O=C1NCCO1 IZXIZTKNFFYFOF-UHFFFAOYSA-N 0.000 description 4
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 4
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 125000003277 amino group Chemical group 0.000 description 4
- IMHDGJOMLMDPJN-UHFFFAOYSA-N biphenyl-2,2'-diol Chemical group OC1=CC=CC=C1C1=CC=CC=C1O IMHDGJOMLMDPJN-UHFFFAOYSA-N 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 238000006482 condensation reaction Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- DDFYFBUWEBINLX-UHFFFAOYSA-M tetramethylammonium bromide Chemical compound [Br-].C[N+](C)(C)C DDFYFBUWEBINLX-UHFFFAOYSA-M 0.000 description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 4
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 150000004982 aromatic amines Chemical class 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 229920005906 polyester polyol Polymers 0.000 description 3
- 235000013824 polyphenols Nutrition 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- LVLNPXCISNPHLE-UHFFFAOYSA-N 2-[(4-hydroxyphenyl)methyl]phenol Chemical compound C1=CC(O)=CC=C1CC1=CC=CC=C1O LVLNPXCISNPHLE-UHFFFAOYSA-N 0.000 description 2
- URFNSYWAGGETFK-UHFFFAOYSA-N 4,4'-Dihydroxybibenzyl Chemical compound C1=CC(O)=CC=C1CCC1=CC=C(O)C=C1 URFNSYWAGGETFK-UHFFFAOYSA-N 0.000 description 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 2
- RBHIUNHSNSQJNG-UHFFFAOYSA-N 6-methyl-3-(2-methyloxiran-2-yl)-7-oxabicyclo[4.1.0]heptane Chemical compound C1CC2(C)OC2CC1C1(C)CO1 RBHIUNHSNSQJNG-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- 229910015900 BF3 Inorganic materials 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- OJGMBLNIHDZDGS-UHFFFAOYSA-N N-Ethylaniline Chemical compound CCNC1=CC=CC=C1 OJGMBLNIHDZDGS-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- 238000007259 addition reaction Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- HFACYLZERDEVSX-UHFFFAOYSA-N benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 2
- 230000001588 bifunctional effect Effects 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical group OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 2
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 238000006266 etherification reaction Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 125000004957 naphthylene group Chemical group 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 150000008442 polyphenolic compounds Chemical class 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 2
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- NIDNOXCRFUCAKQ-UMRXKNAASA-N (1s,2r,3s,4r)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1[C@H]2C=C[C@@H]1[C@H](C(=O)O)[C@@H]2C(O)=O NIDNOXCRFUCAKQ-UMRXKNAASA-N 0.000 description 1
- PNNFEYPWPCDLOC-UPHRSURJSA-N (z)-2,3-dichlorobut-2-enedioic acid Chemical compound OC(=O)C(\Cl)=C(\Cl)C(O)=O PNNFEYPWPCDLOC-UPHRSURJSA-N 0.000 description 1
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- SQFQIHCPTTUZCP-UHFFFAOYSA-N 1,2-bis(chloromethyl)-3,4-dimethylbenzene Chemical group CC1=CC=C(CCl)C(CCl)=C1C SQFQIHCPTTUZCP-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 1
- ZXHZWRZAWJVPIC-UHFFFAOYSA-N 1,2-diisocyanatonaphthalene Chemical compound C1=CC=CC2=C(N=C=O)C(N=C=O)=CC=C21 ZXHZWRZAWJVPIC-UHFFFAOYSA-N 0.000 description 1
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 description 1
- 125000005655 1,3-cyclohexylene group Chemical group [H]C1([H])C([H])([H])C([H])([*:1])C([H])([H])C([H])([*:2])C1([H])[H] 0.000 description 1
- VDFVNEFVBPFDSB-UHFFFAOYSA-N 1,3-dioxane Chemical compound C1COCOC1 VDFVNEFVBPFDSB-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- 125000004955 1,4-cyclohexylene group Chemical group [H]C1([H])C([H])([H])C([H])([*:1])C([H])([H])C([H])([H])C1([H])[*:2] 0.000 description 1
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-dioxonaphthalene Natural products C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 description 1
- IZYSCLLIDVWMGO-UHFFFAOYSA-N 1-[2,3-bis[(dimethylamino)methyl]phenyl]-n,n-dimethylmethanamine Chemical compound CN(C)CC1=CC=CC(CN(C)C)=C1CN(C)C IZYSCLLIDVWMGO-UHFFFAOYSA-N 0.000 description 1
- UUKHFGSOCZLVJO-UHFFFAOYSA-N 1-fluoro-4-(4-fluorophenoxy)benzene Chemical compound C1=CC(F)=CC=C1OC1=CC=C(F)C=C1 UUKHFGSOCZLVJO-UHFFFAOYSA-N 0.000 description 1
- PMUPSYZVABJEKC-UHFFFAOYSA-N 1-methylcyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1(C)CCCCC1C(O)=O PMUPSYZVABJEKC-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- MQCPOLNSJCWPGT-UHFFFAOYSA-N 2,2'-Bisphenol F Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1O MQCPOLNSJCWPGT-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- FJJYYMJJQCQPAT-UHFFFAOYSA-N 2,3,5,6-tetrachloro-4-(2,3,5,6-tetrachloro-4-hydroxyphenyl)phenol Chemical group ClC1=C(Cl)C(O)=C(Cl)C(Cl)=C1C1=C(Cl)C(Cl)=C(O)C(Cl)=C1Cl FJJYYMJJQCQPAT-UHFFFAOYSA-N 0.000 description 1
- CDULGHZNHURECF-UHFFFAOYSA-N 2,3-dimethylaniline 2,4-dimethylaniline 2,5-dimethylaniline 2,6-dimethylaniline 3,4-dimethylaniline 3,5-dimethylaniline Chemical group CC1=CC=C(N)C(C)=C1.CC1=CC=C(C)C(N)=C1.CC1=CC(C)=CC(N)=C1.CC1=CC=C(N)C=C1C.CC1=CC=CC(N)=C1C.CC1=CC=CC(C)=C1N CDULGHZNHURECF-UHFFFAOYSA-N 0.000 description 1
- PQXKWPLDPFFDJP-UHFFFAOYSA-N 2,3-dimethyloxirane Chemical compound CC1OC1C PQXKWPLDPFFDJP-UHFFFAOYSA-N 0.000 description 1
- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- JHOPNNNTBHXSHY-UHFFFAOYSA-N 2-(4-hydroxyphenyl)phenol Chemical group C1=CC(O)=CC=C1C1=CC=CC=C1O JHOPNNNTBHXSHY-UHFFFAOYSA-N 0.000 description 1
- LROZSPADHSXFJA-UHFFFAOYSA-N 2-(4-hydroxyphenyl)sulfonylphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=CC=C1O LROZSPADHSXFJA-UHFFFAOYSA-N 0.000 description 1
- VVHFXJOCUKBZFS-UHFFFAOYSA-N 2-(chloromethyl)-2-methyloxirane Chemical compound ClCC1(C)CO1 VVHFXJOCUKBZFS-UHFFFAOYSA-N 0.000 description 1
- LKMJVFRMDSNFRT-UHFFFAOYSA-N 2-(methoxymethyl)oxirane Chemical compound COCC1CO1 LKMJVFRMDSNFRT-UHFFFAOYSA-N 0.000 description 1
- QDCPNGVVOWVKJG-VAWYXSNFSA-N 2-[(e)-dodec-1-enyl]butanedioic acid Chemical compound CCCCCCCCCC\C=C\C(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-VAWYXSNFSA-N 0.000 description 1
- HVOBSBRYQIYZNY-UHFFFAOYSA-N 2-[2-(2-aminoethylamino)ethylamino]ethanol Chemical compound NCCNCCNCCO HVOBSBRYQIYZNY-UHFFFAOYSA-N 0.000 description 1
- AVNFUVHTTAGFJM-UHFFFAOYSA-N 2-bromo-4-(3-bromo-4-hydroxyphenoxy)phenol Chemical compound C1=C(Br)C(O)=CC=C1OC1=CC=C(O)C(Br)=C1 AVNFUVHTTAGFJM-UHFFFAOYSA-N 0.000 description 1
- GMVRBNZMOQKAPI-UHFFFAOYSA-N 2-chloro-4-(3-chloro-4-hydroxyphenoxy)phenol Chemical compound C1=C(Cl)C(O)=CC=C1OC1=CC=C(O)C(Cl)=C1 GMVRBNZMOQKAPI-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- VFIUGIUVIMSJBF-UHFFFAOYSA-N 2-fluoro-4-(3-fluoro-4-hydroxyphenoxy)phenol Chemical compound C1=C(F)C(O)=CC=C1OC1=CC=C(O)C(F)=C1 VFIUGIUVIMSJBF-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- ODGCZQFTJDEYNI-UHFFFAOYSA-N 2-methylcyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1(C)C=CCCC1C(O)=O ODGCZQFTJDEYNI-UHFFFAOYSA-N 0.000 description 1
- FZIIBDOXPQOKBP-UHFFFAOYSA-N 2-methyloxetane Chemical compound CC1CCO1 FZIIBDOXPQOKBP-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- JRBJSXQPQWSCCF-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine Chemical group C1=C(N)C(OC)=CC(C=2C=C(OC)C(N)=CC=2)=C1 JRBJSXQPQWSCCF-UHFFFAOYSA-N 0.000 description 1
- NUIURNJTPRWVAP-UHFFFAOYSA-N 3,3'-Dimethylbenzidine Chemical group C1=C(N)C(C)=CC(C=2C=C(C)C(N)=CC=2)=C1 NUIURNJTPRWVAP-UHFFFAOYSA-N 0.000 description 1
- RKSBPFMNOJWYSB-UHFFFAOYSA-N 3,3-Bis(4-hydroxyphenyl)pentane Chemical compound C=1C=C(O)C=CC=1C(CC)(CC)C1=CC=C(O)C=C1 RKSBPFMNOJWYSB-UHFFFAOYSA-N 0.000 description 1
- WZHHYIOUKQNLQM-UHFFFAOYSA-N 3,4,5,6-tetrachlorophthalic acid Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(O)=O WZHHYIOUKQNLQM-UHFFFAOYSA-N 0.000 description 1
- GRWFFFOEIHGUBG-UHFFFAOYSA-N 3,4-Epoxy-6-methylcyclohexylmethyl-3,4-epoxy-6-methylcyclo-hexanecarboxylate Chemical compound C1C2OC2CC(C)C1C(=O)OCC1CC2OC2CC1C GRWFFFOEIHGUBG-UHFFFAOYSA-N 0.000 description 1
- MRTGZAHZKQIISW-UHFFFAOYSA-N 3,6-dioxatetracyclo[6.3.0.02,4.05,7]undecane Chemical compound C12OC2C2CCCC2C2C1O2 MRTGZAHZKQIISW-UHFFFAOYSA-N 0.000 description 1
- ITNADJKYRCCJNX-UHFFFAOYSA-N 3-(2,3-diaminophenyl)sulfonylbenzene-1,2-diamine Chemical compound NC1=CC=CC(S(=O)(=O)C=2C(=C(N)C=CC=2)N)=C1N ITNADJKYRCCJNX-UHFFFAOYSA-N 0.000 description 1
- TUJHKTMBIVIOOV-UHFFFAOYSA-N 3-(4-hydroxyphenyl)-1,1,3-trimethyl-2h-inden-5-ol Chemical compound C12=CC(O)=CC=C2C(C)(C)CC1(C)C1=CC=C(O)C=C1 TUJHKTMBIVIOOV-UHFFFAOYSA-N 0.000 description 1
- CGFCKPWPXHKFPU-UHFFFAOYSA-N 3-chloro-4-[1-(2-chloro-4-hydroxyphenyl)ethyl]phenol Chemical compound C=1C=C(O)C=C(Cl)C=1C(C)C1=CC=C(O)C=C1Cl CGFCKPWPXHKFPU-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- XJBDGYMLLCHIMB-UHFFFAOYSA-N 4-(4-hydroxy-3-propan-2-ylphenoxy)-2-propan-2-ylphenol Chemical compound C1=C(O)C(C(C)C)=CC(OC=2C=C(C(O)=CC=2)C(C)C)=C1 XJBDGYMLLCHIMB-UHFFFAOYSA-N 0.000 description 1
- HAXZAKSZTJVNIS-UHFFFAOYSA-N 4-(4-hydroxynaphthalen-1-yl)oxynaphthalen-1-ol Chemical compound C12=CC=CC=C2C(O)=CC=C1OC1=CC=C(O)C2=CC=CC=C12 HAXZAKSZTJVNIS-UHFFFAOYSA-N 0.000 description 1
- NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 description 1
- HLBLWEWZXPIGSM-UHFFFAOYSA-N 4-Aminophenyl ether Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1 HLBLWEWZXPIGSM-UHFFFAOYSA-N 0.000 description 1
- ACEMPBSQAVZNEJ-UHFFFAOYSA-N 4-[(4-hydroxy-3-methoxy-2,6-dimethylphenyl)methyl]-2-methoxy-3,5-dimethylphenol Chemical compound C1=C(O)C(OC)=C(C)C(CC=2C(=C(OC)C(O)=CC=2C)C)=C1C ACEMPBSQAVZNEJ-UHFFFAOYSA-N 0.000 description 1
- WZDLEYNMGWZAEJ-UHFFFAOYSA-N 4-[1-(4-hydroxy-3,5-dimethylphenyl)ethyl]-2,6-dimethylphenol Chemical compound C=1C(C)=C(O)C(C)=CC=1C(C)C1=CC(C)=C(O)C(C)=C1 WZDLEYNMGWZAEJ-UHFFFAOYSA-N 0.000 description 1
- YXVSYZRICGNXIH-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-2-phenylethyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)CC1=CC=CC=C1 YXVSYZRICGNXIH-UHFFFAOYSA-N 0.000 description 1
- ZYEDGEXYGKWJPB-UHFFFAOYSA-N 4-[2-(4-aminophenyl)propan-2-yl]aniline Chemical compound C=1C=C(N)C=CC=1C(C)(C)C1=CC=C(N)C=C1 ZYEDGEXYGKWJPB-UHFFFAOYSA-N 0.000 description 1
- KCAPNGLKHXOABM-UHFFFAOYSA-N 4-[2-(4-hydroxy-2-propan-2-ylphenyl)propan-2-yl]-3-propan-2-ylphenol Chemical compound CC(C)C1=CC(O)=CC=C1C(C)(C)C1=CC=C(O)C=C1C(C)C KCAPNGLKHXOABM-UHFFFAOYSA-N 0.000 description 1
- BKTRENAPTCBBFA-UHFFFAOYSA-N 4-[2-(4-hydroxy-3-phenylphenyl)propan-2-yl]-2-phenylphenol Chemical compound C=1C=C(O)C(C=2C=CC=CC=2)=CC=1C(C)(C)C(C=1)=CC=C(O)C=1C1=CC=CC=C1 BKTRENAPTCBBFA-UHFFFAOYSA-N 0.000 description 1
- IJWIRZQYWANBMP-UHFFFAOYSA-N 4-[2-(4-hydroxy-3-propan-2-ylphenyl)propan-2-yl]-2-propan-2-ylphenol Chemical compound C1=C(O)C(C(C)C)=CC(C(C)(C)C=2C=C(C(O)=CC=2)C(C)C)=C1 IJWIRZQYWANBMP-UHFFFAOYSA-N 0.000 description 1
- LCYRQNBSGYQLKY-UHFFFAOYSA-N 4-[2-(4-hydroxynaphthalen-1-yl)propan-2-yl]naphthalen-1-ol Chemical compound C1=CC=C2C(C(C)(C=3C4=CC=CC=C4C(O)=CC=3)C)=CC=C(O)C2=C1 LCYRQNBSGYQLKY-UHFFFAOYSA-N 0.000 description 1
- DUKMWXLEZOCRSO-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)-1-phenylpropan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)CC1=CC=CC=C1 DUKMWXLEZOCRSO-UHFFFAOYSA-N 0.000 description 1
- XHQYAMKBTLODDV-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)heptan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(CCCCC)C1=CC=C(O)C=C1 XHQYAMKBTLODDV-UHFFFAOYSA-N 0.000 description 1
- WCUDAIJOADOKAW-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)pentan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(CCC)C1=CC=C(O)C=C1 WCUDAIJOADOKAW-UHFFFAOYSA-N 0.000 description 1
- PVFQHGDIOXNKIC-UHFFFAOYSA-N 4-[2-[3-[2-(4-hydroxyphenyl)propan-2-yl]phenyl]propan-2-yl]phenol Chemical compound C=1C=CC(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 PVFQHGDIOXNKIC-UHFFFAOYSA-N 0.000 description 1
- KWQRQJQLSQOJFN-UHFFFAOYSA-N 4-[4-(4-hydroxyphenyl)-4-methylpentan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)CC(C)(C)C1=CC=C(O)C=C1 KWQRQJQLSQOJFN-UHFFFAOYSA-N 0.000 description 1
- DRFCYJSCXJNNSS-UHFFFAOYSA-N 4-[4-hydroxy-3-(2-methylpropyl)phenoxy]-2-(2-methylpropyl)phenol Chemical compound C1=C(O)C(CC(C)C)=CC(OC=2C=C(CC(C)C)C(O)=CC=2)=C1 DRFCYJSCXJNNSS-UHFFFAOYSA-N 0.000 description 1
- HIRQBSLKWNGWRZ-UHFFFAOYSA-N 4-[[2,3,5,6-tetraethyl-4-[(4-hydroxyphenyl)methyl]phenyl]methyl]phenol Chemical compound CCC=1C(CC)=C(CC=2C=CC(O)=CC=2)C(CC)=C(CC)C=1CC1=CC=C(O)C=C1 HIRQBSLKWNGWRZ-UHFFFAOYSA-N 0.000 description 1
- IQIQZPUFQOLLKG-UHFFFAOYSA-N 4-[[4-[(4-hydroxyphenyl)methyl]-2,3,5,6-tetramethylphenyl]methyl]phenol Chemical compound CC=1C(C)=C(CC=2C=CC(O)=CC=2)C(C)=C(C)C=1CC1=CC=C(O)C=C1 IQIQZPUFQOLLKG-UHFFFAOYSA-N 0.000 description 1
- UHJYHYMHMYSURX-UHFFFAOYSA-N 4-[[4-[(4-hydroxyphenyl)methyl]phenyl]methyl]phenol Chemical compound C1=CC(O)=CC=C1CC(C=C1)=CC=C1CC1=CC=C(O)C=C1 UHJYHYMHMYSURX-UHFFFAOYSA-N 0.000 description 1
- YZYGDZRBLOLVDY-UHFFFAOYSA-N 4-[cyclohexyl-(4-hydroxyphenyl)methyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)C1CCCCC1 YZYGDZRBLOLVDY-UHFFFAOYSA-N 0.000 description 1
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 description 1
- IZSHZLKNFQAAKX-UHFFFAOYSA-N 5-cyclopenta-2,4-dien-1-ylcyclopenta-1,3-diene Chemical group C1=CC=CC1C1C=CC=C1 IZSHZLKNFQAAKX-UHFFFAOYSA-N 0.000 description 1
- JPKVIAIUBLGJQH-UHFFFAOYSA-N 6-methylidenecyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1C=CCC(=C)C1C(O)=O JPKVIAIUBLGJQH-UHFFFAOYSA-N 0.000 description 1
- NHJIDZUQMHKGRE-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-yl 2-(7-oxabicyclo[4.1.0]heptan-4-yl)acetate Chemical compound C1CC2OC2CC1OC(=O)CC1CC2OC2CC1 NHJIDZUQMHKGRE-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229920003319 Araldite® Polymers 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- GIXXQTYGFOHYPT-UHFFFAOYSA-N Bisphenol P Chemical compound C=1C=C(C(C)(C)C=2C=CC(O)=CC=2)C=CC=1C(C)(C)C1=CC=C(O)C=C1 GIXXQTYGFOHYPT-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical group NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- KYPYTERUKNKOLP-UHFFFAOYSA-N Tetrachlorobisphenol A Chemical compound C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 KYPYTERUKNKOLP-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 229920001893 acrylonitrile styrene Polymers 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- FNYYWLDEYHKLEG-UHFFFAOYSA-N aniline;formaldehyde;phenol Chemical compound O=C.NC1=CC=CC=C1.OC1=CC=CC=C1 FNYYWLDEYHKLEG-UHFFFAOYSA-N 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- CREXVNNSNOKDHW-UHFFFAOYSA-N azaniumylideneazanide Chemical group N[N] CREXVNNSNOKDHW-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- ZLSMCQSGRWNEGX-UHFFFAOYSA-N bis(4-aminophenyl)methanone Chemical compound C1=CC(N)=CC=C1C(=O)C1=CC=C(N)C=C1 ZLSMCQSGRWNEGX-UHFFFAOYSA-N 0.000 description 1
- LMMDJMWIHPEQSJ-UHFFFAOYSA-N bis[(3-methyl-7-oxabicyclo[4.1.0]heptan-4-yl)methyl] hexanedioate Chemical compound C1C2OC2CC(C)C1COC(=O)CCCCC(=O)OCC1CC2OC2CC1C LMMDJMWIHPEQSJ-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- VSSAZBXXNIABDN-UHFFFAOYSA-N cyclohexylmethanol Chemical compound OCC1CCCCC1 VSSAZBXXNIABDN-UHFFFAOYSA-N 0.000 description 1
- 238000006704 dehydrohalogenation reaction Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- BQQUFAMSJAKLNB-UHFFFAOYSA-N dicyclopentadiene diepoxide Chemical compound C12C(C3OC33)CC3C2CC2C1O2 BQQUFAMSJAKLNB-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- GKIPXFAANLTWBM-UHFFFAOYSA-N epibromohydrin Chemical compound BrCC1CO1 GKIPXFAANLTWBM-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- NHOGGUYTANYCGQ-UHFFFAOYSA-N ethenoxybenzene Chemical group C=COC1=CC=CC=C1 NHOGGUYTANYCGQ-UHFFFAOYSA-N 0.000 description 1
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical group CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 150000003944 halohydrins Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 1
- 229940091173 hydantoin Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002462 imidazolines Chemical group 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 239000003049 inorganic solvent Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 1
- GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- QOHMWDJIBGVPIF-UHFFFAOYSA-N n',n'-diethylpropane-1,3-diamine Chemical compound CCN(CC)CCCN QOHMWDJIBGVPIF-UHFFFAOYSA-N 0.000 description 1
- ITZPOSYADVYECJ-UHFFFAOYSA-N n'-cyclohexylpropane-1,3-diamine Chemical compound NCCCNC1CCCCC1 ITZPOSYADVYECJ-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- MNZMMCVIXORAQL-UHFFFAOYSA-N naphthalene-2,6-diol Chemical compound C1=C(O)C=CC2=CC(O)=CC=C21 MNZMMCVIXORAQL-UHFFFAOYSA-N 0.000 description 1
- DFQICHCWIIJABH-UHFFFAOYSA-N naphthalene-2,7-diol Chemical compound C1=CC(O)=CC2=CC(O)=CC=C21 DFQICHCWIIJABH-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- MIVZUXGHPJSKRI-UHFFFAOYSA-N pentane-1,1,1,2-tetracarboxylic acid Chemical compound CCCC(C(O)=O)C(C(O)=O)(C(O)=O)C(O)=O MIVZUXGHPJSKRI-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 125000005415 substituted alkoxy group Chemical group 0.000 description 1
- 125000005156 substituted alkylene group Chemical group 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical group [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
- 125000003375 sulfoxide group Chemical group 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical class C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 150000004992 toluidines Chemical class 0.000 description 1
- HFFLGKNGCAIQMO-UHFFFAOYSA-N trichloroacetaldehyde Chemical compound ClC(Cl)(Cl)C=O HFFLGKNGCAIQMO-UHFFFAOYSA-N 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 150000003739 xylenols Chemical class 0.000 description 1
- 229940102001 zinc bromide Drugs 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Epoxy Resins (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
æ¬çºæã¯ãèç±å®å®æ§ãæ¥çæ§ãè¯å¥œãªãŠã¬ã¿
ã³å€æ§ã硬åæ§ãšããã·æš¹èçµæç©ã«é¢ãããã®
ã§ããã åŸæ¥ããšããã·æš¹èãæ¥çå€ãšããŠäœ¿çšããå Ž
ååŒåŒµãåªæ匷床ã¯å€§ã§ãããå¥é¢åŒ·åºŠãäœãã
å¥é¢åŒ·åºŠãæ¹è¯ããå Žåé«æž©äžã§ã®åŒ·åºŠãå£ããš
ããæ¬ ç¹ãããã ãããã«ãšããã·æš¹èãèªç©ºæ©ãèªåè»çã®å
éã«å¿çšããå Žåãæ§é çšæ¥çå€ãšããŠããã¯ãª
匷床ãé«æž©æ匷床ã®æ¹è¯ãæãŸããã ããããã¯ãªåŒ·åºŠãæ¹è¯ãããããããŸã§çš®ã
ã®è©Šã¿ããªãããŠãããäŸãã°ãšããã·æš¹èã®æ°Ž
é žåºããæ«ç«¯ã€ãœã·ã¢ããŒãåºãæãããŠã¬ã¿ã³
ãã¬ããªããŒãšåå¿ãããååå ã«ãŠã¬ã¿ã³çµå
ãå°å ¥ããæ¹æ³ãã€ãœã·ã¢ããŒãåºãã¢ã«ã³ãŒã«
é¡ãPPGé¡ãããšããŒã«é¡ãå°¿çŽ çã®å«ã¢ãã
åºååç©ã§å°éãããšããã·æš¹èäžã«å«æããã
æ¹æ³ãæã¯æ«ç«¯ã«ã«ããã·ã«åºå«æã¢ã¯ãªããã
ãªã«ãã¿ãžãšã³ç³»ååç©ããšããã·ååç©äžã«æ·»
å ä¹è³ã°ã©ãããããè©Šã¿ããªãããŠããããã
ãããã¯ãªåŒ·åºŠã®æ¹è¯ã¯èªãããããå åãšã¯ã
ããªãã ãããã«æ¬çºæã¯ãåŸæ¥ã®ãããã®æ¹æ³ã«æ¯ã¹
ç¹ã«ãã¯ãªåŒ·åºŠã®æ¹è¯ãæãããšåæã«é«æž©äžã§
ã®åŒ·åºŠãæ¹è¯ãããããŠã¬ã¿ã³å€æ§ãšããã·æš¹è
ãæäŸãããã®ã§ããã ããªãã¡æ¬çºæã¯ãå¹³åïŒåããå€ãã®ãšãã
ã·åºãååå ã«å«æãããšããã·ååç©ïŒâ
ïŒãšå¹³åååé300ã4000ãOHåœé100ã2000
ã®ããªãªãŒã«ãšããªã€ãœã·ã¢ããŒãããåŸããã
ã€ãœã·ã¢ããŒãåºå«æé0.1ã10ééïŒ ã®ãŠã¬ã¿
ã³ãã¬ããªããŒïŒâïŒã觊åªã®ååšäžã§é«æž©
ã§åå¿ãããããšã«ãã€ãŠåŸããããªããµãŸãªã
ã³ç°åã³ã€ãœã·ã¢ãã¬ãŒãç°ãå«æãããŠã¬ã¿ã³
å€æ§ãšããã·æš¹èïŒïŒãšããšããã·æš¹èçšç¡¬å
å€ïŒïŒãšãå«æããç±ç¡¬åå硬åæ§ãšããã·æš¹
èçµæç©ã«é¢ãããã®ã§ããã æ¬çºæã®ãŠã¬ã¿ã³å€æ§ãšããã·æš¹èïŒïŒã圢
æããããã®ãšããã·ååç©ïŒâïŒãšããŠã¯
以äžã«äŸç€ºããããããããšããã·ååç©äžã«å«
ãŸããæ°Žé žåºã®å«æéã¯ãšããã·ååç©å¹³åïŒå
ååœãïŒå以äžã§ããã®ãããã æ¬çºæã«çšãããããšããã·ååç©ïŒâïŒ
ãšããŠã¯ã åŒ ïŒããã«ïŒºã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºïŒã§
瀺ããã眮æåã¯é眮æã®ã°ãªã·ãžã«ãšãŒãã«åº
ãååå ã«å¹³åïŒåããå€ãæãããšããã·æš¹
èãåŒ ïŒããã«ïŒºã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºïŒã§
瀺ããã眮æåã¯é眮æã®ã°ãªã·ãžã«ãšã¹ãã«åº
ãååå ã«å¹³åïŒåããå€ãæãããšããã·æš¹
èãåŒ ïŒããã«ïŒºã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºïŒã§
瀺ããã眮æã®çœ®æåã¯é眮æïŒïŒïŒâãšãã
ã·ãããã«åºãååå ã«å¹³åïŒåããå€ãæãã
ãšããã·æš¹èçãå«ãŸããã äžèšçœ®æåã¯é眮æã®ã°ãªã·ãžã«ãšãŒãã«åºã
ååå ã«ïŒåããå€ãæãããšããã·æš¹èã¯ãã
ãšããŒã«æ§ããããã·ã«åºãã°ãªã·ãžã«ãšãŒãã«
åããŠåŸããããšããã·æš¹èåã³ã¢ã«ã³ãŒã«æ§ã
ãããã·ã«åºãã°ãªã·ãžã«ãšãŒãã«åããŠåŸãã
ããšããã·æš¹èçã§ãããããããšããã·æš¹èã®
奜ãŸããäŸãšããŠã¯ãïŒååã¯ïŒå以äžã®è³éŠæ
æ žãæããå€äŸ¡ããšããŒã«ã®ããªã°ãªã·ãžã«ãšãŒ
ãã«(ã€)ãïŒååã¯ïŒå以äžã®è³éŠææ žãæããå€
䟡ããšããŒã«ãšççŽ æ°ïŒãïŒåã®ã¢ã«ãã¬ã³ãªã
ãµã€ããšã®ä»å åå¿ã«ããèªå°ããããã¢ã«ã³ãŒ
ã«æ§ããªããããã·ã«ååç©ã®ããªã°ãªã·ãžã«ãš
ãŒãã«(ã)æãã¯æ žãå«ãŸãªãèèªæã®ããªããã
ãã·ã«ååç©ã®ããªã°ãªã·ãžã«ãšãŒãã«(ã)çãæ
ããããã ããããŠããªã°ãªã·ãžã«ãšãŒãã«(ã€)ãšã¯ãäŸã
ã°å°ãªããšãïŒåã®è³éŠææ žãæããå€äŸ¡ããšã
ãŒã«(A)ãšãšããããããªã³(b)ãšãæ°Žé žåãããªãŠ
ã ã®åŠãå¡©åºæ§è§Šåªä¹è³å¡©åºæ§ååç©ã®åå¿éã®
ååšäžã«åžžæ³ã«ããåå¿ããããŠåŸãããåŠãã
ãªã°ãªã·ãžã«ãšãŒãã«ãäž»åå¿çæç©ãšããŠå«ã
ãšããã·æš¹èæãã¯å°ãªããšãïŒåã®è³éŠææ žã
æããå€äŸ¡ããšããŒã«(A)ãšãšããããããªã³(b)ã
ããªãšãã«ã¢ãã³ã®åŠãå¡©åºæ§è§Šåªã®è§Šåªéã®å
åšäžã«åžžæ³ã«ããåå¿ããããŠåŸãããããªãã
ãªã³ãšãŒãã«ãšæ°Žé žåãããªãŠã ã®åŠãå¡©åºæ§å
åç©ãšãåå¿ããããŠåŸãããåŠããšããã·æš¹è
ã§ããã åæ§ããªã°ãªã·ãžã«ãšãŒãã«(ã)æãã¯ããªã°ãª
ã·ãžã«ãšãŒãã«(ã)ãšã¯ãäŸãã°å°ãªããšãïŒåã®
è³éŠææ žãæããå€äŸ¡ããšããŒã«ãšççŽ æ°ïŒãïŒ
åã®ã¢ã«ãã¬ã³ãªããµã€ããšã®ä»å åå¿ã«ããèª
å°ããããããªããããã·ã«ååç©(B)åã¯æ žãå«
ãŸãªãèèªæããªããããã·ååç©(C)ãšãšããã
ãããªã³(b)ãšãäžåŒåç¡ŒçŽ ã®åŠãé žæ§è§Šåªã®è§Šåª
éã®ååšäžã«åžžæ³ã«ããåå¿ããããããããªã
ããããªã³ãšãŒãã«ãšæ°Žé žåãããªãŠã ã®åŠãå¡©
åºæ§ååç©ãšãåå¿ããããŠåŸãããåŠãããªã°
ãªã·ãžã«ãšãŒãã«ãäž»åå¿çæç©ãšããŠå«ããšã
ãã·æš¹èã§ããã ããã«å°ãªããšãïŒåã®è³éŠææ žãæããå€äŸ¡
ããšããŒã«(A)ãšããŠã¯ãïŒåã®è³éŠææ žãæãã
åæ žå€äŸ¡ããšããŒã«ïŒïŒ¡âïŒïŒåã³ïŒå以äžã®è³
éŠææ žãæããå€æ žå€äŸ¡ããšããŒã«ïŒïŒ¡âïŒïŒã
ããã ãããåæ žå€äŸ¡ããšããŒã«ïŒïŒ¡âïŒïŒã®äŸãšã
ãŠã¯ãäŸãã°ã¬ãŸã«ã·ããŒã«ããã€ããããã³ã
ãã€ãã«ãã³ãŒã«ããããã°ã«ã·ããŒã«ãïŒïŒïŒ
âãžããããã·ããã¿ã¬ã³ãïŒïŒïŒâãžãããã
ã·ããã¿ã¬ã³ãïŒïŒïŒâãžããããã·ããã¿ã¬ã³
çãæããããã åãå€æ žå€äŸ¡ããšããŒã«ïŒïŒ¡âïŒïŒã®äŸãšããŠ
ã¯ãäžè¬åŒ ãåŒäžãArã¯ãããã¬ã³åºåã³ããšãã¬ã³åºã®
æ§ãªè³éŠæäºäŸ¡çåæ°ŽçŽ ã§æ¬çºæã®ç®çã«ã¯ããš
ãã¬ã³åºã奜ãŸãããYâ²åã³Y1ã¯åäžåã¯ç°ãª
ã€ãŠããŠããããã¡ãã«åºãïœâãããã«åºãïœ
âããã«åºãïœâããã·ã«åºãïœâãªã¯ãã«åºã®
ãããªã¢ã«ãã«åºãªãã¹ãã¯æé«ïŒåã®ççŽ åå
ãæã€ã¢ã«ãã«åºæãã¯ããã²ã³ååå³ã¡å¡©çŽ å
åãèçŽ ååãæ²çŽ åååã¯åŒçŽ ååæãã¯ã¡ã
ãã·åºãã¡ããã·ã¡ãã«åºããšããã·åºããšãã
ã·ãšãã«åºãïœâãããã·åºãã¢ãã«ãªãã·åºã®
æ§ãªã¢ã«ã³ãã·åºãªãã¹ãã¯æé«ïŒåã®ççŽ åå
ãæã€ã¢ã«ã³ãã·åºã§ãããåèšã®è³éŠæäºäŸ¡ç
åæ°ŽçŽ åºã®äœããåã¯äž¡æ¹ã«æ°Žé žåºä»¥å€ã«çœ®æåº
ãååšããå Žåã«ã¯ãããã®çœ®æåšã¯åäžã§ãç°
ãªããã®ã§ããããïœåã³ïœã¯çœ®æåºã«ãã€ãŠçœ®
æã§ããè³éŠç°ïŒArïŒã®æ°ŽçŽ ååã®æ°ã«å¯Ÿå¿ã
ãïŒïŒé¶ïŒããæ倧å€ãŸã§ã®å€ãæã€æŽæ°ã§ãå
äžåã¯ç°ãªãå€ã§ããããšãã§ãããR1ã¯äŸã
ã°
ã³å€æ§ã硬åæ§ãšããã·æš¹èçµæç©ã«é¢ãããã®
ã§ããã åŸæ¥ããšããã·æš¹èãæ¥çå€ãšããŠäœ¿çšããå Ž
ååŒåŒµãåªæ匷床ã¯å€§ã§ãããå¥é¢åŒ·åºŠãäœãã
å¥é¢åŒ·åºŠãæ¹è¯ããå Žåé«æž©äžã§ã®åŒ·åºŠãå£ããš
ããæ¬ ç¹ãããã ãããã«ãšããã·æš¹èãèªç©ºæ©ãèªåè»çã®å
éã«å¿çšããå Žåãæ§é çšæ¥çå€ãšããŠããã¯ãª
匷床ãé«æž©æ匷床ã®æ¹è¯ãæãŸããã ããããã¯ãªåŒ·åºŠãæ¹è¯ãããããããŸã§çš®ã
ã®è©Šã¿ããªãããŠãããäŸãã°ãšããã·æš¹èã®æ°Ž
é žåºããæ«ç«¯ã€ãœã·ã¢ããŒãåºãæãããŠã¬ã¿ã³
ãã¬ããªããŒãšåå¿ãããååå ã«ãŠã¬ã¿ã³çµå
ãå°å ¥ããæ¹æ³ãã€ãœã·ã¢ããŒãåºãã¢ã«ã³ãŒã«
é¡ãPPGé¡ãããšããŒã«é¡ãå°¿çŽ çã®å«ã¢ãã
åºååç©ã§å°éãããšããã·æš¹èäžã«å«æããã
æ¹æ³ãæã¯æ«ç«¯ã«ã«ããã·ã«åºå«æã¢ã¯ãªããã
ãªã«ãã¿ãžãšã³ç³»ååç©ããšããã·ååç©äžã«æ·»
å ä¹è³ã°ã©ãããããè©Šã¿ããªãããŠããããã
ãããã¯ãªåŒ·åºŠã®æ¹è¯ã¯èªãããããå åãšã¯ã
ããªãã ãããã«æ¬çºæã¯ãåŸæ¥ã®ãããã®æ¹æ³ã«æ¯ã¹
ç¹ã«ãã¯ãªåŒ·åºŠã®æ¹è¯ãæãããšåæã«é«æž©äžã§
ã®åŒ·åºŠãæ¹è¯ãããããŠã¬ã¿ã³å€æ§ãšããã·æš¹è
ãæäŸãããã®ã§ããã ããªãã¡æ¬çºæã¯ãå¹³åïŒåããå€ãã®ãšãã
ã·åºãååå ã«å«æãããšããã·ååç©ïŒâ
ïŒãšå¹³åååé300ã4000ãOHåœé100ã2000
ã®ããªãªãŒã«ãšããªã€ãœã·ã¢ããŒãããåŸããã
ã€ãœã·ã¢ããŒãåºå«æé0.1ã10ééïŒ ã®ãŠã¬ã¿
ã³ãã¬ããªããŒïŒâïŒã觊åªã®ååšäžã§é«æž©
ã§åå¿ãããããšã«ãã€ãŠåŸããããªããµãŸãªã
ã³ç°åã³ã€ãœã·ã¢ãã¬ãŒãç°ãå«æãããŠã¬ã¿ã³
å€æ§ãšããã·æš¹èïŒïŒãšããšããã·æš¹èçšç¡¬å
å€ïŒïŒãšãå«æããç±ç¡¬åå硬åæ§ãšããã·æš¹
èçµæç©ã«é¢ãããã®ã§ããã æ¬çºæã®ãŠã¬ã¿ã³å€æ§ãšããã·æš¹èïŒïŒã圢
æããããã®ãšããã·ååç©ïŒâïŒãšããŠã¯
以äžã«äŸç€ºããããããããšããã·ååç©äžã«å«
ãŸããæ°Žé žåºã®å«æéã¯ãšããã·ååç©å¹³åïŒå
ååœãïŒå以äžã§ããã®ãããã æ¬çºæã«çšãããããšããã·ååç©ïŒâïŒ
ãšããŠã¯ã åŒ ïŒããã«ïŒºã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºïŒã§
瀺ããã眮æåã¯é眮æã®ã°ãªã·ãžã«ãšãŒãã«åº
ãååå ã«å¹³åïŒåããå€ãæãããšããã·æš¹
èãåŒ ïŒããã«ïŒºã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºïŒã§
瀺ããã眮æåã¯é眮æã®ã°ãªã·ãžã«ãšã¹ãã«åº
ãååå ã«å¹³åïŒåããå€ãæãããšããã·æš¹
èãåŒ ïŒããã«ïŒºã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºïŒã§
瀺ããã眮æã®çœ®æåã¯é眮æïŒïŒïŒâãšãã
ã·ãããã«åºãååå ã«å¹³åïŒåããå€ãæãã
ãšããã·æš¹èçãå«ãŸããã äžèšçœ®æåã¯é眮æã®ã°ãªã·ãžã«ãšãŒãã«åºã
ååå ã«ïŒåããå€ãæãããšããã·æš¹èã¯ãã
ãšããŒã«æ§ããããã·ã«åºãã°ãªã·ãžã«ãšãŒãã«
åããŠåŸããããšããã·æš¹èåã³ã¢ã«ã³ãŒã«æ§ã
ãããã·ã«åºãã°ãªã·ãžã«ãšãŒãã«åããŠåŸãã
ããšããã·æš¹èçã§ãããããããšããã·æš¹èã®
奜ãŸããäŸãšããŠã¯ãïŒååã¯ïŒå以äžã®è³éŠæ
æ žãæããå€äŸ¡ããšããŒã«ã®ããªã°ãªã·ãžã«ãšãŒ
ãã«(ã€)ãïŒååã¯ïŒå以äžã®è³éŠææ žãæããå€
䟡ããšããŒã«ãšççŽ æ°ïŒãïŒåã®ã¢ã«ãã¬ã³ãªã
ãµã€ããšã®ä»å åå¿ã«ããèªå°ããããã¢ã«ã³ãŒ
ã«æ§ããªããããã·ã«ååç©ã®ããªã°ãªã·ãžã«ãš
ãŒãã«(ã)æãã¯æ žãå«ãŸãªãèèªæã®ããªããã
ãã·ã«ååç©ã®ããªã°ãªã·ãžã«ãšãŒãã«(ã)çãæ
ããããã ããããŠããªã°ãªã·ãžã«ãšãŒãã«(ã€)ãšã¯ãäŸã
ã°å°ãªããšãïŒåã®è³éŠææ žãæããå€äŸ¡ããšã
ãŒã«(A)ãšãšããããããªã³(b)ãšãæ°Žé žåãããªãŠ
ã ã®åŠãå¡©åºæ§è§Šåªä¹è³å¡©åºæ§ååç©ã®åå¿éã®
ååšäžã«åžžæ³ã«ããåå¿ããããŠåŸãããåŠãã
ãªã°ãªã·ãžã«ãšãŒãã«ãäž»åå¿çæç©ãšããŠå«ã
ãšããã·æš¹èæãã¯å°ãªããšãïŒåã®è³éŠææ žã
æããå€äŸ¡ããšããŒã«(A)ãšãšããããããªã³(b)ã
ããªãšãã«ã¢ãã³ã®åŠãå¡©åºæ§è§Šåªã®è§Šåªéã®å
åšäžã«åžžæ³ã«ããåå¿ããããŠåŸãããããªãã
ãªã³ãšãŒãã«ãšæ°Žé žåãããªãŠã ã®åŠãå¡©åºæ§å
åç©ãšãåå¿ããããŠåŸãããåŠããšããã·æš¹è
ã§ããã åæ§ããªã°ãªã·ãžã«ãšãŒãã«(ã)æãã¯ããªã°ãª
ã·ãžã«ãšãŒãã«(ã)ãšã¯ãäŸãã°å°ãªããšãïŒåã®
è³éŠææ žãæããå€äŸ¡ããšããŒã«ãšççŽ æ°ïŒãïŒ
åã®ã¢ã«ãã¬ã³ãªããµã€ããšã®ä»å åå¿ã«ããèª
å°ããããããªããããã·ã«ååç©(B)åã¯æ žãå«
ãŸãªãèèªæããªããããã·ååç©(C)ãšãšããã
ãããªã³(b)ãšãäžåŒåç¡ŒçŽ ã®åŠãé žæ§è§Šåªã®è§Šåª
éã®ååšäžã«åžžæ³ã«ããåå¿ããããããããªã
ããããªã³ãšãŒãã«ãšæ°Žé žåãããªãŠã ã®åŠãå¡©
åºæ§ååç©ãšãåå¿ããããŠåŸãããåŠãããªã°
ãªã·ãžã«ãšãŒãã«ãäž»åå¿çæç©ãšããŠå«ããšã
ãã·æš¹èã§ããã ããã«å°ãªããšãïŒåã®è³éŠææ žãæããå€äŸ¡
ããšããŒã«(A)ãšããŠã¯ãïŒåã®è³éŠææ žãæãã
åæ žå€äŸ¡ããšããŒã«ïŒïŒ¡âïŒïŒåã³ïŒå以äžã®è³
éŠææ žãæããå€æ žå€äŸ¡ããšããŒã«ïŒïŒ¡âïŒïŒã
ããã ãããåæ žå€äŸ¡ããšããŒã«ïŒïŒ¡âïŒïŒã®äŸãšã
ãŠã¯ãäŸãã°ã¬ãŸã«ã·ããŒã«ããã€ããããã³ã
ãã€ãã«ãã³ãŒã«ããããã°ã«ã·ããŒã«ãïŒïŒïŒ
âãžããããã·ããã¿ã¬ã³ãïŒïŒïŒâãžãããã
ã·ããã¿ã¬ã³ãïŒïŒïŒâãžããããã·ããã¿ã¬ã³
çãæããããã åãå€æ žå€äŸ¡ããšããŒã«ïŒïŒ¡âïŒïŒã®äŸãšããŠ
ã¯ãäžè¬åŒ ãåŒäžãArã¯ãããã¬ã³åºåã³ããšãã¬ã³åºã®
æ§ãªè³éŠæäºäŸ¡çåæ°ŽçŽ ã§æ¬çºæã®ç®çã«ã¯ããš
ãã¬ã³åºã奜ãŸãããYâ²åã³Y1ã¯åäžåã¯ç°ãª
ã€ãŠããŠããããã¡ãã«åºãïœâãããã«åºãïœ
âããã«åºãïœâããã·ã«åºãïœâãªã¯ãã«åºã®
ãããªã¢ã«ãã«åºãªãã¹ãã¯æé«ïŒåã®ççŽ åå
ãæã€ã¢ã«ãã«åºæãã¯ããã²ã³ååå³ã¡å¡©çŽ å
åãèçŽ ååãæ²çŽ åååã¯åŒçŽ ååæãã¯ã¡ã
ãã·åºãã¡ããã·ã¡ãã«åºããšããã·åºããšãã
ã·ãšãã«åºãïœâãããã·åºãã¢ãã«ãªãã·åºã®
æ§ãªã¢ã«ã³ãã·åºãªãã¹ãã¯æé«ïŒåã®ççŽ åå
ãæã€ã¢ã«ã³ãã·åºã§ãããåèšã®è³éŠæäºäŸ¡ç
åæ°ŽçŽ åºã®äœããåã¯äž¡æ¹ã«æ°Žé žåºä»¥å€ã«çœ®æåº
ãååšããå Žåã«ã¯ãããã®çœ®æåšã¯åäžã§ãç°
ãªããã®ã§ããããïœåã³ïœã¯çœ®æåºã«ãã€ãŠçœ®
æã§ããè³éŠç°ïŒArïŒã®æ°ŽçŽ ååã®æ°ã«å¯Ÿå¿ã
ãïŒïŒé¶ïŒããæ倧å€ãŸã§ã®å€ãæã€æŽæ°ã§ãå
äžåã¯ç°ãªãå€ã§ããããšãã§ãããR1ã¯äŸã
ã°
ãåŒãââãââãâSOâãâSO2âãâ
ïŒïŒ³ïŒoâïŒïœã¯ïŒãïŒã®æŽæ°ïŒåã¯ã¢ã«ãã¬ã³åºäŸ
ãã°ã¡ãã¬ã³åºããšãã¬ã³åºãããªã¡ãã¬ã³åºã
ããã©ã¡ãã¬ã³åºããã³ã¿ã¡ãã¬ã³åºããããµã¡
ãã¬ã³åºãïŒâãšãã«ãããµã¡ãã¬ã³åºããªã¯ã¿
ã¡ãã¬ã³åºãããã¡ãã¬ã³åºããã«ã¡ãã¬ã³åºæ
ãã¯ã¢ã«ããªãã³åºäŸãã°ãšããªãã³åºãããã
ãªãã³åºãã€ãœããããªãã³åºãã€ãœãããªãã³
åºãã¢ããªãã³åºãã€ãœã¢ããªãã³åºãïŒâããš
ãã«ãšããªãã³åºãÏâïŒããã²ã³åãžã·ã¯ãã
ã³ã¿ãžãšãã«ïŒã¢ã«ããªãã³åºæãã¯ç°ç¶èèªæ
åºäŸãã°ïŒïŒïŒâã·ã¯ãããã·ã¬ã³åºãïŒïŒïŒâ
ã·ã¯ãããã·ã¬ã³åºãã·ã¯ãããã·ãªãã³åºæã
ã¯ããã²ã³åãããã¢ã«ãã¬ã³åºæãã¯ããã²ã³
åãããã¢ã«ããªãã³åºæãã¯ããã²ã³åããã
ç°ç¶èèªæåºæãã¯ã¢ã«ã³ãã·âåã³ã¢ãªãŒã«ãª
ãã·â眮æãããã¢ã«ããªãã³åºæãã¯ã¢ã«ã³ã
ã·âåã³ã¢ãªãŒã«ãªãã·â眮æãããã¢ã«ãã¬ã³
åºæãã¯ã¢ã«ã³ãã·âåã³ã¢ãªãŒã«ãªãã·â眮æ
ãããç°ç¶èèªæåºäŸãã°ã¡ããã·ã¡ãã¬ã³åºã
ãšããã·ã¡ãã¬ã³åºããšããã·ãšãã¬ã³åºãïŒâ
ãšããã·ããªã¡ãã¬ã³åºãïŒâãšããã·ãã³ã¿ã¡
ãã¬ã³åºãïŒïŒïŒâïŒïŒâã¡ããã·ã·ã¯ããããµ
ã³ïŒåºãããšããã·ãšãã¬ã³åºãïŒâããšããã·
ããªã¡ãã¬ã³åºãïŒïŒïŒâïŒïŒâããšããã·ã·ã¯
ããããµã³ïŒåºæãã¯ã¢ã«ãã¬ã³åºäŸãã°ããšã
ã«ãšãã¬ã³åºãïŒâããšãã«ããªã¡ãã¬ã³åºã
ïŒïŒïŒâããšãã«ãã³ã¿ã¡ãã¬ã³åºãïŒâããšã
ã«ãã«ã¡ãã¬ã³åºæãã¯è³éŠæåºäŸãã°ããšãã¬
ã³åºããããã¬ã³åºæãã¯ããã²ã³åãããè³éŠ
æåºäŸãã°ïŒïŒïŒâïŒïŒâã¯ãã«ããšãã¬ã³ïŒåºã
ïŒïŒïŒâïŒïŒâãã«ãªã«ããšãã¬ã³ïŒåºæãã¯ã¢
ã«ã³ãã·åã³ã¢ãªãŒã«ãªãã·çœ®æãããè³éŠæåº
äŸãã°ïŒïŒïŒâïŒïŒâã¡ããã·ããšãã¬ã³ïŒåºã
ïŒïŒïŒâïŒïŒâãšããã·ããšãã¬ã³ïŒåºãïŒïŒïŒ
âïŒïŒâïœâããããã·ããšãã¬ã³ïŒåºãïŒïŒïŒ
âïŒïŒâããšããã·ããšãã¬ã³ïŒåºæãã¯ã¢ã«ã
ã«çœ®æãããè³éŠæåºäŸãã°ïŒïŒïŒâïŒïŒâã¡ã
ã«ããšãã¬ã³ïŒåºãïŒïŒïŒâïŒïŒâãšãã«ããšã
ã¬ã³ïŒåºãïŒïŒïŒâïŒïŒâïœâãããã«ããšãã¬
ã³ïŒåºãïŒïŒïŒâïŒïŒâïœâããã«ããšãã¬ã³ïŒ
åºãïŒïŒïŒâïŒïŒâïœâããã·ã«ããšãã¬ã³ïŒåºã åŒ ïŒïŒ²ã¯æ°ŽçŽ ååãããã²ã³åååã¯ççŽ æ°ïŒãïŒ
ã®ã¢ã«ãã«åºïŒã§è¡šããããåºãåŒ åŒ ïŒåŒäžãR2ã¯æ°ŽçŽ åååã¯æ°Žé žåºåã¯ãšããã·
åºã§çœ®æãããŠãããçåæ°ŽçŽ åºïŒã®æ§ãªäºäŸ¡ç
åæ°ŽçŽ åºãªã©ã®äºäŸ¡ã®åºã§ãããæãã¯R1ã¯äŸ
ãã°åŒ ã§è¡šããããååç©ã®å Žåã®æ§ã«åèšAråºäžã€
ã«èçããŠããç°ã§ããããšãã§ããæãã¯R1
ã¯ããªãšããã·åºãããªããããã·åºãããªããª
ãšããã·åºãããªãããã·åºãããªããšãã«ãšã
ãã·åºã®æ§ãªããªã¢ã«ã³ãã·åºã§ããããšãã§
ããæãã¯R1ã¯äŸãã°ããªãžã¡ãã«ã·ããã·åºã
ããªãžããšãã«ã·ããã·åºãããªã¡ãã«ããšãã«
ã·ããã·åºã®æ§ãªçªçŽ ååãå«ãåºã§ããããšã
ã§ããæãã¯R1ã¯è³éŠæç°ã第ïŒã¢ããåºãšãŒ
ãã«çµåãã«ã«ããã«åºåã¯ç¡«é»åã¯ã¹ã«ããã·
ãã®æ§ãªç¡«é»ãå«ãçµåã«ãã€ãŠéãŠãããïŒå
åã¯ãã以äžã®ã¢ã«ãã¬ã³åºåã¯ã¢ã«ããªãã³åº
ã§ããããšãã§ãããã§è¡šããããå€æ žäºäŸ¡ããš
ããŒã«ãããã ãããå€æ žäºäŸ¡ããšããŒã«ã§ãã€ãŠç¹ã«å¥œãŸã
ãã®ã¯ãäžè¬åŒ ïŒåŒäžãYâ²åã³Y1ã¯åèšãšåãæå³ã§ãããïœ
åã³ïœã¯ïŒãïŒã®å€ã§ãããR1ã¯ãªãã¹ãã¯ïŒ
ãïŒåã®ççŽ ååãæã€ã¢ã«ãã¬ã³åºåã¯ã¢ã«ã
ãªãã³åºæãã¯åŒ å㯠ã§è¡šãããã飜ååºãã¯ïŒåã¯ïŒã§ããïŒã§è¡š
ããããå€æ žäºäŸ¡ããšããŒã«ã§ããã ãããäºäŸ¡ããšããŒã«ã®äŸã®äžã«ã¯æ®éååå
ãã¹ããšããŒã«(A)ãšç§°ããïŒïŒïŒâãã¹âïŒïŒâ
ããããã·ããšãã«ïŒãããã³ãïŒïŒ4â²âãžãã
ããã·ãžããšãã«ã¡ã¿ã³ããã¹ïŒïŒâããããã·
ããšãã«ïŒã¡ã¿ã³ããã¹ïŒïŒâããããã·ããšã
ã«ïŒã¡ã¿ã³ããã¹ïŒïŒâããããã·âïŒïŒïŒâãž
ã¡ãã«âïŒâã¡ããã·ããšãã«ïŒã¡ã¿ã³ãïŒïŒïŒ
âãã¹ïŒïŒâããããã·ããšãã«ïŒãšã¿ã³ãïŒïŒ
ïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒãšã¿ã³ã
ïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒâã¯ãã«ããš
ãã«ïŒãšã¿ã³ãïŒïŒïŒâãã¹ïŒïŒïŒïŒâãžã¡ãã«
âïŒâããããã·ããšãã«ïŒãšã¿ã³ãïŒïŒïŒâã
ã¹ïŒïŒâã¡ãã«âïŒâããããã·ããšãã«ïŒãã
ãã³ãïŒïŒïŒâãã¹ïŒïŒïŒïŒâãžã¯ããâïŒâã
ãããã·ããšãã«ïŒãããã³ãïŒïŒïŒâãã¹ïŒïŒ
âããšãã«âïŒâããããã·ããšãã«ïŒããã
ã³ãïŒïŒïŒâãã¹ïŒïŒâã€ãœãããã«âïŒâãã
ããã·ããšãã«ïŒãããã³ãïŒïŒïŒâãã¹ïŒïŒâ
ã€ãœãããã«âïŒâããããã·ããšãã«ïŒããã
ã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·ãããã«ïŒã
ããã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·ããšã
ã«ïŒãã³ã¿ã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·ã
ãšãã«ïŒãã³ã¿ã³ãïŒïŒïŒâãã¹ïŒïŒâãããã
ã·ããšãã«ïŒããã¿ã³ããã¹ïŒïŒâããããã·ã
ãšãã«ïŒã¡ã¿ã³ããã¹ïŒïŒâããããã·ããšã
ã«ïŒã·ã¯ãããã·ã«ã¡ã¿ã³ãïŒïŒïŒâãã¹ïŒïŒâ
ããããã·ããšãã«ïŒâïŒïŒïŒâãã¹ïŒããšãã«ïŒ
ãããã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·ããšã
ã«ïŒâïŒâããšãã«ãããã³ã®æ§ãªãã¹ïŒããã
ãã·ããšãã«ïŒã¢ã«ã«ã³æãã¯ïŒïŒ4â²âãžããã
ãã·ãããšãã«ãïŒïŒ4â²âãžããããã·ãªã¯ã¿ã¯
ãããããšãã«ãïŒïŒ2â²âãžããããã·ãããšã
ã«ãïŒïŒ4â²âãžããããã·ãããšãã«ã®æ§ãªãžã
ãããã·ãããšãã«æãã¯ãã¹âïŒïŒâãããã
ã·ããšãã«ïŒã¹ã«ãã³ãïŒïŒ4â²âãžããããã·ãž
ããšãã«ã¹ã«ãã³ãã¯ãã«âïŒïŒïŒâãžãããã
ã·ãžããšãã«ã¹ã«ãã³ãïŒâã¯ãã«âïŒïŒ4â²âãž
ããããã·ãžããšãã«ã¹ã«ãã³ã3â²âã¯ãã«â
ïŒïŒ4â²âãžããããã·ãžããšãã«ã¹ã«ãã³ã®æ§ãª
ãžïŒããããã·ããšãã«ïŒã¹ã«ãã³æãã¯ãã¹
ïŒïŒâããããã·ããšãã«ïŒãšãŒãã«ãïŒïŒ3â²â
ïŒåã¯ïŒïŒ2â²âåã¯ïŒïŒ2â²âãžããããã·ãžããš
ãã«ïŒãšãŒãã«ãïŒïŒ4â²âãžããããã·âïŒïŒïŒ
âãžã¡ãã«ãžããšãã«ãšãŒãã«ããã¹ïŒïŒâãã
ããã·âïŒâã€ãœããã«ããšãã«ïŒãšãŒãã«ãã
ã¹ïŒïŒâããããã·âïŒâã€ãœãããã«ããšã
ã«ïŒãšãŒãã«ããã¹ïŒïŒâããããã·âïŒâã¯ã
ã«ããšãã«ïŒãšãŒãã«ããã¹ïŒïŒâããããã·â
ïŒâãã«ãªã«ããšãã«ïŒãšãŒãã«ããã¹ïŒïŒâã
ãããã·âïŒâããã ããšãã«ïŒãšãŒãã«ããã¹
ïŒïŒâããããã·ãããã«ïŒãšãŒãã«ããã¹ïŒïŒ
âããããã·âïŒâã¯ãã«ãããã«ïŒãšãŒãã«ã
ãã¹ïŒïŒâããããã·ãããšãã«ïŒãšãŒãã«ã
ïŒïŒ4â²âãžããããã·âïŒïŒïŒâãžã¡ããã·ãžã
ãšãã«ãšãŒãã«ãïŒïŒ4â²âãžããããã·âïŒïŒïŒ
âãžãšããã·ãžããšãã«ãšãŒãã«ã®æ§ãªãžïŒãã
ããã·ããšãã«ïŒãšãŒãã«ãå«ãŸããåïŒïŒïŒâ
ãã¹ïŒïŒâããããã·ããšãã«ïŒâïŒâããšãã«
ãšã¿ã³ãïŒïŒïŒïŒïŒâããªã¡ãã«âïŒâïŒïŒâã
ãããã·ããšãã«ïŒâïŒâããããã·ã€ã³ãã³ã
ïŒïŒïŒâãã¹ïŒïœâããããã·ããšãã«ïŒâïŒâ
ã¡ãã«ãã³ã¿ã³ãé©åœã§ããã æŽã«åãããå€æ žäºäŸ¡ããšããŒã«ã§ãã€ãŠå¥œãŸ
ããä»ã®äžçŸ€ã®ãã®ã¯ãäžè¬åŒ ïŒããã«R3ã¯ã¡ãã«åã¯ãšãã«åºãR1åã³R2ã¯
ççŽ æ°ïŒãïŒåã®ã¢ã«ããªãã³åºåã¯ãã®ä»ã®ã¢
ã«ãã¬ã³åºãïœã¯ïŒãïŒïŒã§ç€ºããããã®ã§ãäŸ
ãã°ïŒïŒïŒâãã¹ïŒïŒâããããã·ãã³ãžã«ïŒã
ã³ãŒã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·ãã³ãž
ã«ïŒããã©ã¡ãã«ãã³ãŒã³ãïŒïŒïŒâãã¹ïŒïŒâ
ããããã·ãã³ãžã«ïŒããã©ãšãã«ãã³ãŒã³ã
ïŒïŒïŒâãã¹ïŒïœâããããã·ã¯ãã«ïŒãã³ãŒ
ã³ãïŒïŒïŒâãã¹ïŒïœâããããã·ã¯ãã«ïŒãã³
ãŒã³çãæããããã ãã®ä»ã®å€æ žå€äŸ¡ããšããŒã«ïŒïŒ¡âïŒïŒã«å«ãŸ
ãããã®ãšããŠã¯ãäŸãã°ïŒïŒïŒïŒïŒïŒïŒâãã
ã©ãã¹ïŒïŒâããããã·ããšãã«ïŒãšã¿ã³ããšã
ãŒã«é¡ãšã«ã«ããã«ååç©ãšã®åæçž®åç©é¡
ïŒäŸïŒããšããŒã«æš¹èåæçž®åç©ãããšããŒã«ãš
ã¢ã¯ãã¬ã€ã³ãšã®çž®ååå¿çæç©ãããšããŒã«ãš
ã°ãªãªãã¶ãŒã«ã®çž®ååå¿çæç©ãããšããŒã«ãš
ãã³ã¿ã³ãžã¢ãªã«ã®çž®ååå¿çæç©ãã¬ãŸã«ã·ã
ãŒã«ãšã¢ã»ãã³ã®çž®ååå¿çæç©ããã·ã¬ã³âã
ãšããŒã«âãã«ããªã³åæçž®åç©ïŒãããšããŒã«
é¡ãšããªã¯ãã«ã¡ãã«åè³éŠæååç©ã®çž®åçæ
ç©ïŒäŸïŒããšããŒã«ãšãã¹ã¯ãã«ã¡ãã«ãã·ã¬ã³
ãšã®çž®åçæç©ïŒçãæããããšãã§ããã èããŠãããã«ããªããããã·ã«ååç©(B)ãšã¯
äžèšã®å°ãªããšãïŒåã®è³éŠææ žãæããå€äŸ¡ã
ãšããŒã«(A)ãšã¢ã«ãã¬ã³ãªããµã€ããšãOHåºãš
ãšããã·åºãšã®åå¿ãä¿é²ããåŠã觊åªã®ååšäž
ã«åå¿ããããŠåŸããããšãŒãã«çµåã«ãã€ãŠè©²
ããšããŒã«æ®åºãšçµåãããŠããâROHïŒããã«
ã¯ã¢ã«ãã¬ã³ãªããµã€ãã«ç±æ¥ããã¢ã«ãã¬ã³
åºïŒæãã¯ïŒåã³ïŒâïŒROïŒoïŒããã«ïŒ²ã¯ã¢ã«ã
ã¬ã³ãªããµã€ãã«ç±æ¥ããã¢ã«ãã¬ã³åºã§äžã€ã®
ããªãªãã·ã¢ã«ãã¬ã³éã¯ç°ãªãã¢ã«ãã¬ã³åºã
å«ãã§ããŠããããïœã¯ãªãã·ã¢ã«ãã¬ã³åºã®é
åæ°ã瀺ãïŒåã¯ïŒä»¥äžã®æŽæ°ïŒãªãåå矀ãæ
ããååç©ã§ããããã®å Žåãåœè©²å€äŸ¡ããšããŒ
ã«(A)ãšã¢ã«ãã¬ã³ãªããµã€ããšã®å²åã¯ïŒïŒïŒ
ïŒã¢ã«ïŒã¢ã«ïŒä»¥äžãšããããã奜ãŸããã¯åœè©²
å€äŸ¡ããšããŒã«(A)ã®OHåºã«å¯Ÿããã¢ã«ãã¬ã³ãª
ããµã€ãã®å²åã¯ïŒïŒïŒã10ã奜ãŸããã¯ïŒïŒïŒ
ãïŒïŒåœéïŒåœéïŒã§ããã ããã«ã¢ã«ãã¬ã³ãªããµã€ããšããŠã¯ãäŸãã°
ãšãã¬ã³ãªããµã€ãããããã¬ã³ãªããµã€ããã
ãã¬ã³ãªããµã€ããªã©ããããããããã該å€äŸ¡
ããšããŒã«(A)ãšåå¿ããŠãšãŒãã«çµåããªãå Žå
åŽéãçãããã®ãç¹ã«å¥œãŸããããã®æ§ãªãã®
ãšããŠã¯ãããã¬ã³ãªããµã€ããïŒïŒïŒâããã¬
ã³ãªããµã€ããïŒïŒïŒâããã¬ã³ãªããµã€ãã
ïŒïŒïŒâããã¬ã³ãªããµã€ããããæ®ã«ãããã¬
ã³ãªããµã€ãã奜ãŸããã ãããããªããããã·ã«ååç©(B)ã§ãã€ãŠãç¹
ã«å¥œãŸããäžçŸ€ã®ãã®ã¯ãäžè¬åŒ ïŒåŒäžãYâ²ãY1ãïœãïœåã³R1ã¯åèšïŒïŒ¡âïŒ
âïŒâïŒïŒåŒã®ãããšåãã§ãããã¯ççŽ æ°ïŒ
ãïŒåã®ã¢ã«ãã¬ã³åºãn1åã³n2ã¯ïŒãïŒã®å€ã§
ããïŒã§è¡šããããããªããããã·ã«ååç©ã§ã
ãã æŽã«åããããããªããããã·ã«ååç©ã§ãã€
ãŠå¥œãŸããä»ã®äžçŸ€ã®ãã®ã¯ãäžè¬åŒ ïŒåŒäžãR1ãR2ãR3åã³ïœã¯åèšïŒïŒ¡âïŒâïŒ
âïŒïŒåŒã®ãããšåãã§ãããã¯ççŽ æ°ïŒãïŒ
åã®ã¢ã«ãã¬ã³åºãn1åã³n2ã¯ïŒãïŒã®å€ã§ã
ãïŒã§è¡šããããããªããããã·ã«ååç©ã§ã
ãã ãã®ä»æ žãå«ãããªããããã·ã«ååç©(B)ãšã
ãŠã¯ããªããããã·ã«ååç©(A)ã®è³éŠææ žãæ°ŽçŽ
æ·»å ããŠåŸãããèç°æããªãªãŒã«ãå«ãŸããã åãããã«æ žãå«ãŸãªãèèªæããªããããã·
ã«ååç©(C)ãšããŠã¯ãäŸãã°ãšãã¬ã³ã°ãªã³ãŒ
ã«ããããã¬ã³ã°ãªã³ãŒã«ãããã¬ã³ã°ãªã³ãŒ
ã«ããžãšãã¬ã³ã°ãªã³ãŒã«ããžãããã¬ã³ã°ãªã³
ãŒã«ããžããã¬ã³ã°ãªã³ãŒã«ãã°ãªã»ãªã³ããã³
ã¿ãšãªã¹ãªããŒã«çã®å€äŸ¡ã¢ã«ã³ãŒã«åã³ããã
ã®å€äŸ¡ã¢ã«ã³ãŒã«åã¯ãã®ä»ã®æŽ»æ§æ°ŽçŽ å«æåå
ç©ïŒäŸãã°ã¢ããåºãã«ã«ããã·ã«åºãããªãã
ããã·ã«åºçã®åºãæã€ååç©ïŒã«ã¢ã«ãã¬ã³ãª
ããµã€ããä»å ããããå€äŸ¡ããªããããã·ã«å
åç©ãããªãšãŒãã«ããªãªãŒã«çã®ããªãããã
ã·ã«ååç©ãæããããã åãããã«åèšãšããããããªã³(b)ãšã¯ãäžè¬
åŒ ïŒããã«ïŒºã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºã
Xâ²ã¯ããã²ã³ååã§ããïŒã§è¡šãããããã®ã§
ãããããããšããããããªã³(b)ã®äŸãšããŠã¯ã
äŸãã°ãšãã¯ãã«ãããªã³ããšãããã ãããª
ã³ãïŒïŒïŒâãšããã·âïŒâã¡ãã«âïŒâã¯ãã«
ãããã³ãïŒïŒïŒâãšããã·âïŒâãšãã«âïŒâ
ã¯ãã«ãããã³ãªã©ãæããããã äžèšãšããããããªã³(b)ãšããªããããã·ã«å
åç©(B)æãã¯ããªããããã·ã«ååç©(C)ãšã®åå¿
ãä¿é²ããé žæ§è§ŠåªãšããŠã¯ãäžåŒåç¡ŒçŽ ãå¡©å
第äºé«ãå¡©åäºéãå¡©å第äºéã®åŠãã«ã€ã¹é žã
ãããã®æŽ»æ§ã瀺ãèªå°äœïŒäŸïŒäžåŒåç¡ŒçŽ âãš
ãŒãã«é¯ååç©ïŒæãã¯ãããã®æ··åç©çãçšã
ãããšãã§ããã åãåæ§ãšããããããªã³(b)ãšå€äŸ¡ããšããŒã«
(A)ãšã®åå¿ãä¿é²ããå¡©åºæ§è§ŠåªãšããŠã¯ãã¢ã«
ã«ãªéå±æ°Žé žåç©ïŒäŸïŒæ°Žé žåãããªãŠã ïŒãã¢
ã«ã«ãªéå±ã¢ã«ã³ã©ãŒãïŒäŸïŒãããªãŠã ãšãã©
ãŒãïŒã第äžçŽã¢ãã³ååç©ïŒäŸïŒããªãšãã«ã¢
ãã³ãããªãšã¿ããŒã«ã¢ãã³ïŒã第åçŽã¢ã³ã¢ã
ãŠã ååç©ïŒäŸïŒããã©ã¡ãã«ã¢ã³ã¢ããŠã åå
ç©ïŒäŸïŒããã©ã¡ãã«ã¢ã³ã¢ããŠã ãããã€ãïŒ
æãã¯ãããã®æ··åç©ãçšããããšãã§ãããã
ããŠæ¯ãåå¿ãšåæã«ã°ãªã·ãžã«ãšãŒãã«ãçæ
ããããããæãã¯åå¿ã®çµæçæãããããã
ãªã³ãšãŒãã«ãè±ããã²ã³åæ°ŽçŽ åå¿ã«ãã€ãŠé
ç°ããããŠã°ãªã·ãžã«ãšãŒãã«ãçæããããå¡©
åºæ§ååç©ãšããŠã¯ã¢ã«ã«ãªéå±æ°Žé žåç©ïŒäŸïŒ
æ°Žé žåãããªãŠã ãã¢ã«ãã³é žã¢ã«ã«ãªéå±å¡©
ïŒäŸïŒã¢ã«ãã³é žãããªãŠã ïŒçãéœåããçšã
ãããã ããããŠããããã®è§Šåªä¹è³å¡©åºæ§ååç©ã¯ã
ã®ãŸãŸæãã¯é©åœãªç¡æ©æãã¯ïŒåã³ïŒææ©æº¶åª
溶液ãšããŠäœ¿çšããããšãã§ããã®ã¯å¿è«ã§ã
ãã åã眮æåã¯é眮æã®ã°ãªã·ãžã«ãšã¹ãã«åºã
ååå ã«å¹³åïŒå以äžæãããšããã·æš¹èã«ã¯ã
èèªæããªã«ã«ãã³é žæãã¯è³éŠæããªã«ã«ãã³
é žïŒäŸãã°ãã¿ã«é žãã€ãœãã¿ã«é žããã¬ãã¿ã«
é žãããã©ããããã¿ã«é žãã¡ãã«ããã©ããã
ãã¿ã«é žããããµããããã¿ã«é žãã¡ãã«ãããµ
ããããã¿ã«é žããšã³ãã¡ãã¬ã³ããã©ãããã
ã¿ã«é žãã¡ãã«ãšã³ãã¡ãã¬ã³ããã©ããããã¿
ã«é žããã¬ã€ã³é žããã¿ã«é žãã€ã¿ã³ã³é žãã³ã
ã¯é žãã°ã«ã¿ã«é žãã¢ãžãã³é žããã¡ãªã³é žãã¹
ããªã³é žãã¢ãŒã©ã€ã³é žãã»ãã·ã³é žãäºéäœè
èªé žãããªã¡ãªããé žãããªã¡ã·ã³é žãããã¡ãª
ããé žãã·ã¯ããã³ã¿ã³ããã©ã«ã«ãã³é žããã
ãã®ããã²ã³çœ®æååç©ã®ã»ãããããå€äŸ¡ã«ã«
ãã³é žãšå€äŸ¡ã¢ã«ã³ãŒã«ãšããåŸãããæ«ç«¯ã«ã«
ããã·ã«ããªãšã¹ãã«ãªãªãŽããŒãªã©ãå«ãŸãåŸ
ãïŒã®ããªã°ãªã·ãžã«ãšã¹ãã«çããããäŸãã°
åèšäžè¬åŒã§ç€ºããããšããããããªã³(b)ãšã¡ã¿
ã¯ãªã«é žãšããåæãããã°ãªã·ãžã«ã¡ã¿ã¢ã¯ãª
ã¬ãŒããéåããããŠåŸãããåŠããšããã·æš¹è
ãå«ãŸããã åã眮æã®çœ®æåã¯é眮æïŒïŒïŒâãšããã·
ãããã«åºãååå ã«å¹³åïŒåããå€ãæãããš
ããã·æš¹èã®äŸãšããŠã¯ãè³éŠæã¢ãã³ïŒäŸãã°
ã¢ããªã³åã¯æ žã«ã¢ã«ãã«çœ®æåºãæããã¢ããª
ã³ïŒãšäžèšäžè¬åŒã§ç€ºããããšããããããªã³(b)
ãšããåŸããããšããã·æš¹èãè³éŠæã¢ãã³ãšã¢
ã«ããããšã®åæçž®åç©ïŒäŸãã°ã¢ããªã³ãâã
ã«ã ã¢ã«ãããåæçž®åäœãã¢ããªã³âããšããŒ
ã«âãã«ã ã¢ã«ãããåæçž®åäœïŒãšãšãããã
ããªã³(b)ãšããåŸããããšããã·æš¹èããžã°ãªã·
ãžã«ããã³ãã€ã³çãæããããã ãã®ä»ã®ãšããã·æš¹èãšããŠã¯ããšããã·åæ²¹
ïŒäŸãã°ãšããã·åããŸã«æ²¹ããšããã·å倧è±æ²¹ã
ãšããã·åãµãã©ã¯ãŒæ²¹ããšããã·åæ¡æ²¹ããšã
ãã·åãšãæ²¹ããšããã·åè±æ°Žã²ãŸãæ²¹ããšãã
ã·åãªã€ãã·ã«æ²¹ããšããã·åããŒã«æ²¹ãªã©ïŒã
ãšããã·åèèªé žããšããã·åç°ç¶ãªã¬ãã€ã³å
åç©ïŒäŸãã°ããã«ã·ã¯ãããã»ã³ãžãªããµã€
ããïŒâïŒïŒâã¡ãã«âïŒïŒïŒâãšããã·ãšãã«ïŒ
âïŒïŒïŒâãšããã·âïŒâã¡ãã«ã·ã¯ããããµ
ã³ãïŒïŒïŒâãšããã·ã·ã¯ãããã·ã«ã¡ãã«â
ïŒïŒïŒâãšããã·ã·ã¯ããããµã³ã«ã«ããã·ã¬ãŒ
ããïŒïŒïŒâãšããã·âïŒâã¡ãã«ã·ã¯ãããã·
ã«ã¡ãã«âïŒïŒïŒâãšããã·âïŒâã¡ãã«ã·ã¯ã
ãããµã³ã«ã«ããã·ã¬ãŒãããã¹ïŒïŒïŒïŒâãšã
ãã·âïŒâã¡ãã«ã·ã¯ãããã·ã«ã¡ãã«ïŒã¢ãžã
ãŒãããžã·ã¯ããã³ã¿ãžãšã³ãžãªããµã€ãããžã
ã³ãã³ãžãªããµã€ããããã©ãããã€ã³ãã³ãžãª
ããµã€ããæãã¯ãããã®ç°ãå ã«äžè¬åŒïŒïŒ¡â
ïŒâïŒïŒã§R1ãšããŠç€ºããããããªåºã§çµåã
ããååç©ããã®ä»Araldite CYâ175ïŒãã瀟補
ååååïŒãªã©ïœãå ±åœ¹ãžãšã³éåäœã®ãšããã·
åç©ïŒäŸãã°ãšããã·åããªãã¿ãžãšã³ããšãã
ã·åãããã¹ãã¬ã³âãã¿ãžãšã³å ±éåäœããšã
ãã·åãããã¢ã¯ãªããããªã«âã¹ãã¬ã³å ±éå
äœïŒãäžé£œåçµåãå«ãéåäœã®ãšããã·åç©
ïŒäŸãã°ããªãããã¬ã³ã®ãšããã·åç©ãããªã€
ãœããã³ã®ãšããã·åç©ïŒãããªã·ãããµã³ã®ã
ãªã°ãªã·ãžã«ãšãŒãã«ãåè€çŽ ç°ãå«ããšããã·
æš¹èãšããŠã¯ããªããµãŸãªãžãã³ç°ã«ççŽ ååã
ä»ããŠãšããã·åºãçµåãããšããã·æš¹èããã©
ã³ã®ãžã°ãªã·ãžã«ãšãŒãã«åç©ããžãªããµã³ã®ãž
ã°ãªã·ãžã«ãšãŒãã«åç©ãã¹ãããïŒïœâãžãªã
ãµã³ïŒã®ãžã°ãªã·ãžã«ãšãŒãã«åç©ãïŒã®äœçœ®ã«
å€äžé£œåã®ã¢ã«ã±ãã«åºã眮æããã€ãããŸãªã³
ããåŸãããããªãšããã·ååç©ãããªã°ãªã·ãž
ã«ã€ãœã·ã¢ãã¬ãŒãçãæããããããã®ä»ããš
ããã·æš¹èã®è£œé ãšå¿çšãïŒå£å åŒç·šïŒã«èšèŒã
ããŠããåŠãçš®ã ã®ãšããã·æš¹èçã®åŸæ¥å ¬ç¥ã®
ãšããã·æš¹èã䜿çšãããã æ¬çºæã«çšãããããŠã¬ã¿ã³ãã¬ããªããŒïŒ
âïŒãšããŠã¯ããªã€ãœã·ã¢ããŒããšããªãªãŒã«
é¡ãšãå ¬ç¥ã®åå¿æ¹æ³ã«åŸã€ãŠåå¿ãããããšã«
ãã€ãŠåŸããããã®ã§ããªã€ãœã·ã¢ããŒããšããŠ
ã¯ãžã€ãœã·ã¢ããŒããè¯ãããšãã°ããªã¬ã³â
ïŒïŒïŒâãžã€ãœã·ã¢ããŒããããªã¬ã³âïŒïŒïŒâ
ãžã€ãœã·ã¢ããŒããïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãž
ã€ãœã·ã¢ããŒããããšãã¬ã³ãžã€ãœã·ã¢ããŒãã
ããã¿ã¬ã³ãžã€ãœã·ã¢ããŒãããã·ãªã¬ã³ãžã€ãœ
ã·ã¢ããŒããã€ãœããã³ãžã€ãœã·ã¢ããŒãããã
ãµã¡ãã¬ã³ãžã€ãœã·ã¢ããŒãçãæãããããã
ãšãã«å¥œé©ãªãã®ã¯ããªã¬ã³ãžã€ãœã·ã¢ããŒãã
ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€ãœã·ã¢ããŒãçã§
ããã ãŸããããªãªãŒã«ãšããŠã¯ããªãªãã·ãšãã¬ã³
ã°ãªã³ãŒã«ãããªãªãã·ãããã¬ã³ã°ãªã³ãŒã«ã
ããªãªãã·ããã©ã¡ãã¬ã³ã°ãªã³ãŒã«ããããã¯
ã°ãªã»ãªã³ãããªã¡ãããŒã«ãããã³çã®å€äŸ¡ã¢
ã«ã³ãŒã«é¡ãããã¯ã¢ãã³é¡ã®ãšãã¬ã³ãªããµã€
ãããããã¬ã³ãªããµã€ãçã®ã¢ã«ãã¬ã³ãªããµ
ã€ãä»å ç©ãªã©ã®å¹³åååéã300ã4000ãOH
åœé100ã2000ã®ç¯å²ã«ããããªãšãŒãã«ããªãª
ãŒã«ïŒèé žãã³ãã¯é žãã¢ãžãã³é žããã¡ãªã³
é žãã¢ãŒã©ã€ã³é žãã»ãã·ã³é žããã¿ã«é žãã€ãœ
ãã¿ã«é žããã¬ãã¿ã«é žããã¬ã€ã³é žãããã«é ž
çã®å€äŸ¡ã«ã«ãã³é žãšãšãã¬ã³ã°ãªã³ãŒã«ããã
ãã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâãã¿ã³ãžãªãŒã«ã
ïŒïŒïŒâãããµã³ãžãªãŒã«ããžãšãã¬ã³ã°ãªã³ãŒ
ã«ãããªã¡ãããŒã«ãããã³ãã°ãªã»ãªã³ãããª
ãã³ãã«ã°ãªã³ãŒã«ããã¹ïŒããããã·ã¡ãã«ã·
ã¯ããããµã³ïŒçã®å€äŸ¡ã¢ã«ã³ãŒã«ãšãã«ã«ãã
ã·ã«åºã«å¯Ÿããæ°Žé žåºã®ã¢ã«æ¯ãïŒãã倧ã®æ¡ä»¶
äžã§çž®åããŠåŸãããããããã¯ã«ããã©ã¯ãã³
ã®ãããªã©ã¯ãã³é¡ãå€äŸ¡ã¢ã«ã³ãŒã«ã®ååšäžé
ç°éåããŠåŸãããå¹³åååéã300ã4000ã
OHåœé100ã2000ã®ç¯å²ã«ããããªãšã¹ãã«ã
ãªãªãŒã«ãã®ä»ãããã·æ²¹ãããªãã¿ãžãšã³ã°ãª
ã³ãŒã«é¡çãæããããã ããªã€ãœã·ã¢ããŒãããªãšãŒãã«ããªãªãŒã«ã
ããªãšã¹ãã«ããªãªãŒã«çã®ããªãªãŒã«ãšã®åå¿
ã¯æ®éæ°Žé žåºã«å¯ŸããNCOåºã®ã¢ã«æ¯ãïŒãã
倧ã奜ãŸããã¯1.05ãïŒã®æ¡ä»¶äžã§ãåžžæž©ãªãã
æé«90âãŸã§ã®æž©åºŠã§å®æœãããããã®ããã«ã
ãŠåŸããããŠã¬ã¿ã³ãã¬ããªããŒã¯NCOåºå«é
ã0.1ã10ééïŒ ãååéã600ã16000ã®ç¯å²ã«
ããããšã奜ãŸããããŠã¬ã¿ã³ãã¬ããªããŒã®
NCOåºå«éåã³ååéã¯åæçµæãããªãã¡æ°Ž
é žåºã«å¯ŸããNCOåºã®ã¢ã«æ¯ããããããšã«ã
ãå¶åŸ¡ããããšãã§ããã æ¬çºæã®ã€ãœã·ã¢ããŒãåºïŒãšããã·åºã®åå¿
ã«ãããªããµãŸãªãã³ç°ãã€ãœã·ã¢ãã¬ãŒãç°ã®
çæã«ã¯ãå ¬ç¥ã®ãããç°çæ觊åªã䜿çšããã
ãããã®äŸãšããŠã¯äŸãã°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©
é¡ãïŒçŽã¢ãã³é¡ãªã©ã®å¡©åºæ§ååç©ããªããŠã
ãããããèåäºéããã¹ãããŠã å¡©é¡ãªã©ãæ
ããããåå¿æž©åºŠã¯100ã220â奜ãŸããã¯ã140
ã180âã§ãåå¿æéã¯ïŒã10æéã奜ãŸããã¯
ïŒãïŒæéã§ããã 次ã«æ¬çºæã®çµæç©ã®ããäžã€ã®å¿ é ã®æ§ææ
åã§ãããšããã·æš¹èçšç¡¬åå€ïŒïŒãšã¯ããšã
ãã·æš¹èã®åå¿ãä¿é²ããäœçšãæããååç©ä¹
è³ç©è³ªããšããã·æš¹èãšåå¿æ§ãæããååç©ä¹
è³ç©è³ªããšããã·æš¹èãšåå¿æ§ãæããååç©ä¹
è³ç©è³ªãšããçã®åå¿ãä¿é²ããååç©ä¹è³ç©
質ããããç©è³ªã®å¹Ÿã€ããéããŠæããååç©ä¹
è³ç©è³ªãæãã¯ãããã®æ··åç©ãæå³ãåäžã®å
åç©ä¹è³ç©è³ªæãã¯ïŒçš®ä»¥äžã®ååç©ä¹è³ç©è³ªã®
æ··åä¹è³äœµçšç©ãæå³ãã該硬åå€ã¯æ¥µãäœåå
éã®ãã®ããé«ååéã®ãã®ãŸã§å«ãŸããåäžèš
ã®åŠãã¢ããåºãã«ã«ããã·ã«åºãã«ã«ãã³æ®ç¡
æ°Žç©åºïŒâCOââCOâïŒãããããã·ã«åºãâ
SHåºãâNCOåºãâNCSåºãâCONHâåºãæã
ãåŠãææ©ååç©æãã¯ãã¬ãŒãæ§é ãæããæ
æ©éå±ååç©ãå«ãŸããã ããããšããã·æš¹èçšç¡¬åå€ïŒïŒã®ãã¡å¥œãŸ
ãããã®ã¯ãäŸãã°ãšãã¬ã³ãžã¢ãã³ããžãšãã¬
ã³ããªã¢ãã³ãããªãšãã¬ã³ããã©ãã³ããžãã
ãã¬ã³ããªã¢ãã³ããžã¡ãã«ã¢ãããããã«ã¢ã
ã³ããžãšãã«ã¢ãããããã«ã¢ãã³ãã·ã¯ããã
ã·ã«ã¢ãããããã«ã¢ãã³çã®åŠãèèªæããªã¢
ãã³ãã¢ããšã¿ããŒã«ã¢ãã³ããžãšã¿ããŒã«ã¢ã
ã³ããããããŒã«ã¢ãã³ãâã¡ãã«ãšã¿ããŒã«
ã¢ãã³çã®åŠãèèªæããããã·ã¢ãã¢ãã³ïŒã¢
ãããšãã«ãšã¿ããŒã«ã¢ãã³ãã¢ãããããã·ãš
ãã«ãžãšãã¬ã³ããªã¢ãã³ããã¹ããããã·ãšã
ã¬ã³ããªã¢ãã³ãïŒïŒâããããã·ãããã«ïŒ
ãšãã¬ã³ãžã¢ãã³çã®åŠãèèªæããããã·ããª
ã¢ãã³ïŒãã€ããŒé žãšãžã¢ãã³ïŒäŸãã°ãšãã¬ã³
ãžã¢ãã³ïŒãšã®çž®åã«ãã€ãŠåŸãããããªã¢ã
ãïŒãããã®äœãããšååŠéè«çã«äžè¶³éã®åå
äžã«å¹³åïŒåæªæºã®ïŒïŒïŒâãšããã·åºãæãã
ãšããã·ååç©ïŒäŸãã°ãšãã¬ã³ãªããµã€ããã
ããã¬ã³ãªããµã€ãããšãã¯ãã«ãããªã³ãã¹ã
ã¬ã³ãªããµã€ããã¡ãã«ã°ãªã·ãžã«ãšãŒãã«ãã
ãšãã«ã°ãªã·ãžã«ãšãŒãã«ãã°ãªã·ãžã«ã¡ã¿ã¯ãª
ã¬ãŒãçïŒãšã®åå¿ã«ãã€ãŠåŸãããæè¬å€æ§è
èªæã¢ãã³ç³»ç¡¬åå€ïŒã¢ããªã³ããã«ã€ãžã³ããš
ãã«ã¢ããªã³ããã·ãªãžã³ããã³ãžãžã³ãïŒïŒ
4â²âãžã¢ãããžããšãã«ã¡ã¿ã³ãïŒïŒïŒïŒïŒâã
ãªïŒãžã¡ãã«ã¢ããã¡ãã«ïŒããšããŒã«ãïŒïŒïŒ
âãã¹ïŒïŒâã¢ããããšãã«ïŒãããã³ãïŒïŒ
4â²âãžã¢ãããžããšãã«ãšãŒãã«ãïŒïŒ4â²âãžã¢
ãããžããšãã«ã¹ã«ãã³ãïŒïŒ4â²âãžã¢ãããã³
ãŸããšãã³ãïŒïŒ2â²âãžã¡ãã«âïŒïŒ4â²âãžã¢ã
ããžããšãã«ã¡ã¿ã³ãïŒïŒ4â²âãžã¢ãããããšã
ã«ãïŒïŒ3â²âãžã¡ãã«âïŒïŒ4â²âãžã¢ãããããš
ãã«ãïŒïŒ3â²âãžã¡ããã·âïŒïŒ4â²âãžã¢ããã
ããšãã«ã§äŸç€ºããããããªè³éŠæã¢ãã³ããã
ãè³éŠæã¢ãã³ãšã¢ã«ãããæãã¯ã¢ã«ãããã®
åå¿æ§èªå°äœïŒäŸãã°ãã«ã ã¢ã«ãããããã©ã
ã«ã ã¢ã«ããããã¢ã»ãã¢ã«ããããã¯ãã©ãŒã«
çã®èèªæäœçŽã¢ã«ããããæããããç¹ã«ãã«
ã ã¢ã«ãããæãã¯ãã®åå¿æ§èªå°äœã奜ãŸã
ãïŒãšã®åæçž®åç©ããããè³éŠæã¢ãã³ãšããš
ããŒã«é¡ïŒäŸãã°ããšããŒã«ãã¯ã¬ãŸãŒã«ããã·
ã¬ããŒã«ããšãã«ããšããŒã«ãã¯ãã«ããšããŒ
ã«ãã¢ããœãŒã«ïŒãšäžèšã®åŠãã¢ã«ãããæãã¯
ã¢ã«ãããã®åå¿æ§èªå°äœãšã®åæçž®åç©æãã¯
ãããã®äœãããšååŠéè«çã«äžè¶³éã®ååå ã«
å¹³åïŒä»¥äžïŒæªæºã®ïŒïŒïŒâãšããã·åºãæãã
ãšããã·ååç©ãšã®åå¿ã«ãã€ãŠåŸãããã¢ãã³
ä»å ç©ïŒå€æ§ã¢ãã³ïŒãªã©ã§ããã åããšããã·æš¹èçšç¡¬åå€ïŒïŒã«å«ãŸããã
ã®ä»ã®ã¢ããåºãæãã硬åå€ïŒããã硬åå€ãš
ããŠã¯ã¢ãæ çªçŽ ååãšçµåãããšããã®æŽ»æ§æ°Ž
çŽ ååãæããç矩ã®ç¡¬åå€ãšã¢ããæ çªçŽ ãšçµ
åããæ°ŽçŽ ååãæããªãæè¬è§Šåªã«å±ãããã®
çãå«ãŸããããããã«ãããŠã¯ããçãç·ãŠç¡¬
åå€ãšããŠç·ç§°ãããã®ã¯äžèšã®éãã§ããïŒãš
ããŠã¯ããã©ãžã³ãâã¢ãããšãã«ããã©ãž
ã³ãããªãšãã¬ã³ãžã¢ãã³ã®åŠãç°ç¶æ§é ãæã
ãèèªæã¢ãã³ïŒã¡ã¿ããšãã¬ã³ãžã¢ãã³ãã¡ã¿
ãã·ã¬ã³ãžã¢ãã³ããã©ãã·ã¬ã³ãžã¢ãã³ãïœïŒ
pâ²âãžã¢ãããžããšãã«ã¡ã¿ã³ããžã¢ããããšã
ã«ã¹ã«ãã³ã®åŠãè³éŠæïŒçŽã¢ãã³ïŒãã³ãžã«ãž
ã¡ãã«ã¢ãã³ãïŒâã¡ãã«ãžã¡ãã«ã¢ãã³ãããª
ïŒãžã¡ãã«ã¢ããã¡ãã«ïŒãã³ãŒã³ã®åŠãè³éŠæ
ïŒçŽã¢ãã³ãBF3ã»C2H5NH2ãBF3ã»ããã©ãž
ã³ãããªã¢ã«ã«ããŒã«ã¢ãã³ç¡Œé žå¡©ïŒãã¿ã³é žã¢
ãã³å¡©ïŒã·ã¢ããšãã«åããªã¢ãã³ïŒã¡ã©ãã³æš¹
èåæçž®åç©ãã¢ããæš¹èåæçž®åç©ãäŸç€ºãåŸ
ãã åãäŸãã°ã«ã«ããã·ã«åºãæãã硬åå€åã¯
ã«ã«ãã³é žç¡æ°Žç©ã«å±ãã硬åå€ãšããŠã¯ãã¿ã«
é žããã¬ã€ã³é žãããªã¡ãªããé žãããã¡ãªãã
é žãããã©ããããã¿ã«é žããããµããããã¿ã«
é žãããã©ã¯ãã«ãã¿ã«é žãããã»ãã«ç¥çé žã
ãšã³ãã¡ãã¬ã³ãã¿ã«é žãã¡ãã«ãšã³ãã¡ãã¬ã³
ãã¿ã«é žããããµã¯ããã¡ãã¬ã³ããã©ãããã
ã¿ã«é žããžã¯ãããã¬ã€ã³é žåã¯ãããã®é žç¡æ°Ž
ç©ãé žæ§ããªãšã¹ãã«æš¹èããã¬ã€ã³é žæãã¯ç¡
æ°Žãã¬ã€ã³é žãšãã®ä»ã®éåæ§ããã«ååç©
ïŒäŸïŒã¹ãã¬ã³ïŒãšã®éåïŒå ±éåãäžéåçïŒ
äœããã®éšåãšã¹ãã«åç©ããã¬ã€ã³é žãšã¹ãã«
ãšéåæ§ããã«ååç©ãšã®éåäœçãäŸç€ºããã
ãšãã§ããã åãäŸãã°ãã®ä»ã®çªçŽ ååå«æ硬åå€ãšããŠ
ã¯ãžã·ã¢ã³ãžã¢ãããã°ã¢ããžã³ãå°¿çŽ æš¹èåæ
çž®åç©çãäŸç€ºããããšãã§ããåäŸãã°ORåº
ãæãã硬åå€ãšããŠã¯å€äŸ¡ããšããŒã«é¡ãããš
ããŒã«æš¹èåæçž®åç©ãããªãµã«ãã¢ã€ãæš¹èç
ãäŸç€ºããããšãã§ããã ãããã®ãšããã·æš¹èçšç¡¬åå€ïŒïŒã®ãã¡ã¢
ãã³ç³»ãé žç¡æ°Žç©ç³»ã奜ãŸãããäžã§ãåæ±ãã®
䟿çã«ããç¹ã«å¥œãŸãããã®ã¯æœåšæ§ç¡¬åå€ã§ã
äŸãã°ãžã·ã¢ã³ãžã¢ãããããªã«ã«ãã³é žãžãã
ã©ãžãçãæããããã åããšããã·æš¹èçšç¡¬åå€ïŒïŒã®é åéã¯ãš
ããã·æš¹èïŒïŒã«å«ãŸããåå¿ã«äžããåºã«ã€
ããŠã®åœéããçžäºã®åœéãç®åºããããšãã§ã
ããããšããã·æš¹èã®ç¡¬åç©ãç®çãšããã«éã
ãŠã¯ãããåœéå€ã®ååŸã«äºãæ¯èŒçåºãå·Ÿã®å²
åããšãããšãå¯èœã§ãããçµå±ãããå²åã¯ãš
ããã·æš¹èã®ç¡¬åã«ãããåŸæ¥å ¬ç¥ã®æè¡ãé©å®
å¿çšããããšã«ãã€ãŠå®ããããšãã§ããã æ¬çºæã¯ãããã®å¿ é æåã®ã»ãã«ãŠã¬ã¿ã³å€
æ§ããŠããªããšããã·æš¹èãåå¿æ§åã¯éåå¿æ§
åžéå€ãã·ãªã«ãã¿ã«ã¯ãã¯ã¬ãŒãçé žã«ã«ã·ãŠ
ã ãé žåãã¿ã³ãã¢ã«ãç²ãã¢ã«ããçã®å å¡«
å€ããã®ä»ãé¡æãæºå€å€ãçãå«æããŠãè¯
ãã 以äžã«è£œé äŸåã³å®æœäŸã瀺ããæ¬çºæãæŽã«
詳述ããã 補é äŸ ïŒ ïŒå®èœã°ãªã»ãªã³ããŒã¹ã®ååé4000ã®ããªãª
ãã·ãããã¬ã³ã°ãªã³ãŒã«700éšïŒéééšã以äž
åãïŒãïŒå®èœååé2000ã®ããªãªãã·ãããã¬
ã³ã°ãªã³ãŒã«200éšããã«ãšã³ãžã€ãœã·ã¢ããŒã
123éšãçªçŽ 眮æãããã©ã¹ã³äžã§æ··åããN2ã¬
ã¹äž80ã90âã§çŽïŒæéåå¿ããNCOåºå«æé
3.1ïŒ ã®ç²çš ãªãŠã¬ã¿ã³ãã¬ããªããŒãåŸãã 次ãã§äžèšãŠã¬ã¿ã³ãã¬ããªããŒ140éšãã¢
ãã«ã¬ãžã³Epâ4100ïŒãšããã·åœé190ãç²åºŠ
ïŒ25âïŒã11000cpsã®ãã¹ããšããŒã«(A)ã®ãžã°ãªã·
ãžã«ãšãŒãã«ãæé»åå·¥æ¥è£œïŒ200éšãããã©ã¡
ãã«ã¢ã³ã¢ããŠã ãããã0.12éšãæ··åãã160
âã§ïŒæéåå¿ããã宀枩ã§ç²çš ãªãšããã·åœé
321ã®ãªããµãŸãªãã³ç°åã³ã€ãœã·ã¢ãã¬ãŒãç°
å«æïŒèµ€å€ã¹ãã¯ãã«ã§ç¢ºèªïŒãšããã·æš¹èâã€ã
åŸãã 補é äŸ ïŒ ååé2000ã®ã¢ãžãã³é žãšãžãšãã¬ã³ã°ãªã³ãŒ
ã«ãšã®åå¿ã«ãã€ãŠåŸãããããªãšã¹ãã«ããªãª
ãŒã«ïŒæé»å補ãã¢ãã«ããŠãŒãšãŒã¹ïŒŠâ15â
22ïŒ100éšã«ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€ãœã·
ã¢ããŒã20éšãçªçŽ 眮æãããã©ã¹ã³äžã«ãŠæ··å
ããN2ã¬ã¹äžã90âã§ïŒæéåå¿ãNCOåºå«æ
é2.0ïŒ ããŠã¬ã¿ã³ãã¬ããªããŒãåŸãã äžèšãŠã¬ã¿ã³ãã¬ããªããŒ100éšãã¢ãã«ã¬
ãžã³Epâ4100 200éšãããã©ã¡ãã«ã¢ã³ã¢ããŠ
ã ãããã0.15éšãæ··åã160âã§ïŒæéåå¿ã
ã宀枩ã§ç²çš ãªãšããã·åœéïŒ290ã®ãªããµãŸãª
ãã³ç°åã³ã€ãœã·ã¢ãã¬ãŒãç°å«æïŒèµ€å€ã¹ãã¯
ãã«ã«ãŠç¢ºèªïŒã®ãšããã·æš¹èâããåŸãã 補é äŸ ïŒ ïŒå®èœã°ãªã»ãªã³ããŒã¹ååé3000ã®ããªãšãŒ
ãã«ããªãªãŒã«150éšããã«ãšã³ãžã€ãœã·ã¢ããŒ
ã268éšãïŒå®èœååé1000ã®ããªãšãŒãã«ããª
ãªãŒã«165éšãïŒå®èœããªã¡ãããŒã«ãããã³ã
ãŒã¹ååé1500ã®ããªãšãŒãã«ããªãªãŒã«400éš
ãçªçŽ 眮æãããã©ã¹ã³äžã«ãŠæ··åãN2ã¬ã¹äž
90âã§ïŒæéåå¿ãNCOåºå«æé7.0ïŒ ã®ãŠã¬ã¿
ã³ãã¬ããªããŒãåŸãã äžèšãŠã¬ã¿ã³ãã¬ããªããŒ140éšãã¢ãã«ã¬
ãžã³Epâ4000ïŒãšããã·åœéïŒ320ãç²åºŠïŒ25âïŒ
35ãã€ãºãæé»å補åŽéåãšããã·æš¹èïŒ140éšã
ããã©ã¡ãã«ã¢ã³ã¢ããŠã ãããã0.15éšãæ··å
ã160âã§ïŒæéåå¿ãã宀枩ã§ç²çš ãªãšããã·
åœé630ã®ãŠã¬ã¿ã³å€æ§ãšããã·æš¹èâããåŸãã å®æœäŸ ïŒ è¡šïŒã«ç€ºãçµæãæãããšããã·æš¹èçµæç©ã
硬åããããã®ç©æ§ãè©äŸ¡ãããçµæãè¡šïŒã«ç€º
ãã
ãã°ã¡ãã¬ã³åºããšãã¬ã³åºãããªã¡ãã¬ã³åºã
ããã©ã¡ãã¬ã³åºããã³ã¿ã¡ãã¬ã³åºããããµã¡
ãã¬ã³åºãïŒâãšãã«ãããµã¡ãã¬ã³åºããªã¯ã¿
ã¡ãã¬ã³åºãããã¡ãã¬ã³åºããã«ã¡ãã¬ã³åºæ
ãã¯ã¢ã«ããªãã³åºäŸãã°ãšããªãã³åºãããã
ãªãã³åºãã€ãœããããªãã³åºãã€ãœãããªãã³
åºãã¢ããªãã³åºãã€ãœã¢ããªãã³åºãïŒâããš
ãã«ãšããªãã³åºãÏâïŒããã²ã³åãžã·ã¯ãã
ã³ã¿ãžãšãã«ïŒã¢ã«ããªãã³åºæãã¯ç°ç¶èèªæ
åºäŸãã°ïŒïŒïŒâã·ã¯ãããã·ã¬ã³åºãïŒïŒïŒâ
ã·ã¯ãããã·ã¬ã³åºãã·ã¯ãããã·ãªãã³åºæã
ã¯ããã²ã³åãããã¢ã«ãã¬ã³åºæãã¯ããã²ã³
åãããã¢ã«ããªãã³åºæãã¯ããã²ã³åããã
ç°ç¶èèªæåºæãã¯ã¢ã«ã³ãã·âåã³ã¢ãªãŒã«ãª
ãã·â眮æãããã¢ã«ããªãã³åºæãã¯ã¢ã«ã³ã
ã·âåã³ã¢ãªãŒã«ãªãã·â眮æãããã¢ã«ãã¬ã³
åºæãã¯ã¢ã«ã³ãã·âåã³ã¢ãªãŒã«ãªãã·â眮æ
ãããç°ç¶èèªæåºäŸãã°ã¡ããã·ã¡ãã¬ã³åºã
ãšããã·ã¡ãã¬ã³åºããšããã·ãšãã¬ã³åºãïŒâ
ãšããã·ããªã¡ãã¬ã³åºãïŒâãšããã·ãã³ã¿ã¡
ãã¬ã³åºãïŒïŒïŒâïŒïŒâã¡ããã·ã·ã¯ããããµ
ã³ïŒåºãããšããã·ãšãã¬ã³åºãïŒâããšããã·
ããªã¡ãã¬ã³åºãïŒïŒïŒâïŒïŒâããšããã·ã·ã¯
ããããµã³ïŒåºæãã¯ã¢ã«ãã¬ã³åºäŸãã°ããšã
ã«ãšãã¬ã³åºãïŒâããšãã«ããªã¡ãã¬ã³åºã
ïŒïŒïŒâããšãã«ãã³ã¿ã¡ãã¬ã³åºãïŒâããšã
ã«ãã«ã¡ãã¬ã³åºæãã¯è³éŠæåºäŸãã°ããšãã¬
ã³åºããããã¬ã³åºæãã¯ããã²ã³åãããè³éŠ
æåºäŸãã°ïŒïŒïŒâïŒïŒâã¯ãã«ããšãã¬ã³ïŒåºã
ïŒïŒïŒâïŒïŒâãã«ãªã«ããšãã¬ã³ïŒåºæãã¯ã¢
ã«ã³ãã·åã³ã¢ãªãŒã«ãªãã·çœ®æãããè³éŠæåº
äŸãã°ïŒïŒïŒâïŒïŒâã¡ããã·ããšãã¬ã³ïŒåºã
ïŒïŒïŒâïŒïŒâãšããã·ããšãã¬ã³ïŒåºãïŒïŒïŒ
âïŒïŒâïœâããããã·ããšãã¬ã³ïŒåºãïŒïŒïŒ
âïŒïŒâããšããã·ããšãã¬ã³ïŒåºæãã¯ã¢ã«ã
ã«çœ®æãããè³éŠæåºäŸãã°ïŒïŒïŒâïŒïŒâã¡ã
ã«ããšãã¬ã³ïŒåºãïŒïŒïŒâïŒïŒâãšãã«ããšã
ã¬ã³ïŒåºãïŒïŒïŒâïŒïŒâïœâãããã«ããšãã¬
ã³ïŒåºãïŒïŒïŒâïŒïŒâïœâããã«ããšãã¬ã³ïŒ
åºãïŒïŒïŒâïŒïŒâïœâããã·ã«ããšãã¬ã³ïŒåºã åŒ ïŒïŒ²ã¯æ°ŽçŽ ååãããã²ã³åååã¯ççŽ æ°ïŒãïŒ
ã®ã¢ã«ãã«åºïŒã§è¡šããããåºãåŒ åŒ ïŒåŒäžãR2ã¯æ°ŽçŽ åååã¯æ°Žé žåºåã¯ãšããã·
åºã§çœ®æãããŠãããçåæ°ŽçŽ åºïŒã®æ§ãªäºäŸ¡ç
åæ°ŽçŽ åºãªã©ã®äºäŸ¡ã®åºã§ãããæãã¯R1ã¯äŸ
ãã°åŒ ã§è¡šããããååç©ã®å Žåã®æ§ã«åèšAråºäžã€
ã«èçããŠããç°ã§ããããšãã§ããæãã¯R1
ã¯ããªãšããã·åºãããªããããã·åºãããªããª
ãšããã·åºãããªãããã·åºãããªããšãã«ãšã
ãã·åºã®æ§ãªããªã¢ã«ã³ãã·åºã§ããããšãã§
ããæãã¯R1ã¯äŸãã°ããªãžã¡ãã«ã·ããã·åºã
ããªãžããšãã«ã·ããã·åºãããªã¡ãã«ããšãã«
ã·ããã·åºã®æ§ãªçªçŽ ååãå«ãåºã§ããããšã
ã§ããæãã¯R1ã¯è³éŠæç°ã第ïŒã¢ããåºãšãŒ
ãã«çµåãã«ã«ããã«åºåã¯ç¡«é»åã¯ã¹ã«ããã·
ãã®æ§ãªç¡«é»ãå«ãçµåã«ãã€ãŠéãŠãããïŒå
åã¯ãã以äžã®ã¢ã«ãã¬ã³åºåã¯ã¢ã«ããªãã³åº
ã§ããããšãã§ãããã§è¡šããããå€æ žäºäŸ¡ããš
ããŒã«ãããã ãããå€æ žäºäŸ¡ããšããŒã«ã§ãã€ãŠç¹ã«å¥œãŸã
ãã®ã¯ãäžè¬åŒ ïŒåŒäžãYâ²åã³Y1ã¯åèšãšåãæå³ã§ãããïœ
åã³ïœã¯ïŒãïŒã®å€ã§ãããR1ã¯ãªãã¹ãã¯ïŒ
ãïŒåã®ççŽ ååãæã€ã¢ã«ãã¬ã³åºåã¯ã¢ã«ã
ãªãã³åºæãã¯åŒ å㯠ã§è¡šãããã飜ååºãã¯ïŒåã¯ïŒã§ããïŒã§è¡š
ããããå€æ žäºäŸ¡ããšããŒã«ã§ããã ãããäºäŸ¡ããšããŒã«ã®äŸã®äžã«ã¯æ®éååå
ãã¹ããšããŒã«(A)ãšç§°ããïŒïŒïŒâãã¹âïŒïŒâ
ããããã·ããšãã«ïŒãããã³ãïŒïŒ4â²âãžãã
ããã·ãžããšãã«ã¡ã¿ã³ããã¹ïŒïŒâããããã·
ããšãã«ïŒã¡ã¿ã³ããã¹ïŒïŒâããããã·ããšã
ã«ïŒã¡ã¿ã³ããã¹ïŒïŒâããããã·âïŒïŒïŒâãž
ã¡ãã«âïŒâã¡ããã·ããšãã«ïŒã¡ã¿ã³ãïŒïŒïŒ
âãã¹ïŒïŒâããããã·ããšãã«ïŒãšã¿ã³ãïŒïŒ
ïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒãšã¿ã³ã
ïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒâã¯ãã«ããš
ãã«ïŒãšã¿ã³ãïŒïŒïŒâãã¹ïŒïŒïŒïŒâãžã¡ãã«
âïŒâããããã·ããšãã«ïŒãšã¿ã³ãïŒïŒïŒâã
ã¹ïŒïŒâã¡ãã«âïŒâããããã·ããšãã«ïŒãã
ãã³ãïŒïŒïŒâãã¹ïŒïŒïŒïŒâãžã¯ããâïŒâã
ãããã·ããšãã«ïŒãããã³ãïŒïŒïŒâãã¹ïŒïŒ
âããšãã«âïŒâããããã·ããšãã«ïŒããã
ã³ãïŒïŒïŒâãã¹ïŒïŒâã€ãœãããã«âïŒâãã
ããã·ããšãã«ïŒãããã³ãïŒïŒïŒâãã¹ïŒïŒâ
ã€ãœãããã«âïŒâããããã·ããšãã«ïŒããã
ã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·ãããã«ïŒã
ããã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·ããšã
ã«ïŒãã³ã¿ã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·ã
ãšãã«ïŒãã³ã¿ã³ãïŒïŒïŒâãã¹ïŒïŒâãããã
ã·ããšãã«ïŒããã¿ã³ããã¹ïŒïŒâããããã·ã
ãšãã«ïŒã¡ã¿ã³ããã¹ïŒïŒâããããã·ããšã
ã«ïŒã·ã¯ãããã·ã«ã¡ã¿ã³ãïŒïŒïŒâãã¹ïŒïŒâ
ããããã·ããšãã«ïŒâïŒïŒïŒâãã¹ïŒããšãã«ïŒ
ãããã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·ããšã
ã«ïŒâïŒâããšãã«ãããã³ã®æ§ãªãã¹ïŒããã
ãã·ããšãã«ïŒã¢ã«ã«ã³æãã¯ïŒïŒ4â²âãžããã
ãã·ãããšãã«ãïŒïŒ4â²âãžããããã·ãªã¯ã¿ã¯
ãããããšãã«ãïŒïŒ2â²âãžããããã·ãããšã
ã«ãïŒïŒ4â²âãžããããã·ãããšãã«ã®æ§ãªãžã
ãããã·ãããšãã«æãã¯ãã¹âïŒïŒâãããã
ã·ããšãã«ïŒã¹ã«ãã³ãïŒïŒ4â²âãžããããã·ãž
ããšãã«ã¹ã«ãã³ãã¯ãã«âïŒïŒïŒâãžãããã
ã·ãžããšãã«ã¹ã«ãã³ãïŒâã¯ãã«âïŒïŒ4â²âãž
ããããã·ãžããšãã«ã¹ã«ãã³ã3â²âã¯ãã«â
ïŒïŒ4â²âãžããããã·ãžããšãã«ã¹ã«ãã³ã®æ§ãª
ãžïŒããããã·ããšãã«ïŒã¹ã«ãã³æãã¯ãã¹
ïŒïŒâããããã·ããšãã«ïŒãšãŒãã«ãïŒïŒ3â²â
ïŒåã¯ïŒïŒ2â²âåã¯ïŒïŒ2â²âãžããããã·ãžããš
ãã«ïŒãšãŒãã«ãïŒïŒ4â²âãžããããã·âïŒïŒïŒ
âãžã¡ãã«ãžããšãã«ãšãŒãã«ããã¹ïŒïŒâãã
ããã·âïŒâã€ãœããã«ããšãã«ïŒãšãŒãã«ãã
ã¹ïŒïŒâããããã·âïŒâã€ãœãããã«ããšã
ã«ïŒãšãŒãã«ããã¹ïŒïŒâããããã·âïŒâã¯ã
ã«ããšãã«ïŒãšãŒãã«ããã¹ïŒïŒâããããã·â
ïŒâãã«ãªã«ããšãã«ïŒãšãŒãã«ããã¹ïŒïŒâã
ãããã·âïŒâããã ããšãã«ïŒãšãŒãã«ããã¹
ïŒïŒâããããã·ãããã«ïŒãšãŒãã«ããã¹ïŒïŒ
âããããã·âïŒâã¯ãã«ãããã«ïŒãšãŒãã«ã
ãã¹ïŒïŒâããããã·ãããšãã«ïŒãšãŒãã«ã
ïŒïŒ4â²âãžããããã·âïŒïŒïŒâãžã¡ããã·ãžã
ãšãã«ãšãŒãã«ãïŒïŒ4â²âãžããããã·âïŒïŒïŒ
âãžãšããã·ãžããšãã«ãšãŒãã«ã®æ§ãªãžïŒãã
ããã·ããšãã«ïŒãšãŒãã«ãå«ãŸããåïŒïŒïŒâ
ãã¹ïŒïŒâããããã·ããšãã«ïŒâïŒâããšãã«
ãšã¿ã³ãïŒïŒïŒïŒïŒâããªã¡ãã«âïŒâïŒïŒâã
ãããã·ããšãã«ïŒâïŒâããããã·ã€ã³ãã³ã
ïŒïŒïŒâãã¹ïŒïœâããããã·ããšãã«ïŒâïŒâ
ã¡ãã«ãã³ã¿ã³ãé©åœã§ããã æŽã«åãããå€æ žäºäŸ¡ããšããŒã«ã§ãã€ãŠå¥œãŸ
ããä»ã®äžçŸ€ã®ãã®ã¯ãäžè¬åŒ ïŒããã«R3ã¯ã¡ãã«åã¯ãšãã«åºãR1åã³R2ã¯
ççŽ æ°ïŒãïŒåã®ã¢ã«ããªãã³åºåã¯ãã®ä»ã®ã¢
ã«ãã¬ã³åºãïœã¯ïŒãïŒïŒã§ç€ºããããã®ã§ãäŸ
ãã°ïŒïŒïŒâãã¹ïŒïŒâããããã·ãã³ãžã«ïŒã
ã³ãŒã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·ãã³ãž
ã«ïŒããã©ã¡ãã«ãã³ãŒã³ãïŒïŒïŒâãã¹ïŒïŒâ
ããããã·ãã³ãžã«ïŒããã©ãšãã«ãã³ãŒã³ã
ïŒïŒïŒâãã¹ïŒïœâããããã·ã¯ãã«ïŒãã³ãŒ
ã³ãïŒïŒïŒâãã¹ïŒïœâããããã·ã¯ãã«ïŒãã³
ãŒã³çãæããããã ãã®ä»ã®å€æ žå€äŸ¡ããšããŒã«ïŒïŒ¡âïŒïŒã«å«ãŸ
ãããã®ãšããŠã¯ãäŸãã°ïŒïŒïŒïŒïŒïŒïŒâãã
ã©ãã¹ïŒïŒâããããã·ããšãã«ïŒãšã¿ã³ããšã
ãŒã«é¡ãšã«ã«ããã«ååç©ãšã®åæçž®åç©é¡
ïŒäŸïŒããšããŒã«æš¹èåæçž®åç©ãããšããŒã«ãš
ã¢ã¯ãã¬ã€ã³ãšã®çž®ååå¿çæç©ãããšããŒã«ãš
ã°ãªãªãã¶ãŒã«ã®çž®ååå¿çæç©ãããšããŒã«ãš
ãã³ã¿ã³ãžã¢ãªã«ã®çž®ååå¿çæç©ãã¬ãŸã«ã·ã
ãŒã«ãšã¢ã»ãã³ã®çž®ååå¿çæç©ããã·ã¬ã³âã
ãšããŒã«âãã«ããªã³åæçž®åç©ïŒãããšããŒã«
é¡ãšããªã¯ãã«ã¡ãã«åè³éŠæååç©ã®çž®åçæ
ç©ïŒäŸïŒããšããŒã«ãšãã¹ã¯ãã«ã¡ãã«ãã·ã¬ã³
ãšã®çž®åçæç©ïŒçãæããããšãã§ããã èããŠãããã«ããªããããã·ã«ååç©(B)ãšã¯
äžèšã®å°ãªããšãïŒåã®è³éŠææ žãæããå€äŸ¡ã
ãšããŒã«(A)ãšã¢ã«ãã¬ã³ãªããµã€ããšãOHåºãš
ãšããã·åºãšã®åå¿ãä¿é²ããåŠã觊åªã®ååšäž
ã«åå¿ããããŠåŸããããšãŒãã«çµåã«ãã€ãŠè©²
ããšããŒã«æ®åºãšçµåãããŠããâROHïŒããã«
ã¯ã¢ã«ãã¬ã³ãªããµã€ãã«ç±æ¥ããã¢ã«ãã¬ã³
åºïŒæãã¯ïŒåã³ïŒâïŒROïŒoïŒããã«ïŒ²ã¯ã¢ã«ã
ã¬ã³ãªããµã€ãã«ç±æ¥ããã¢ã«ãã¬ã³åºã§äžã€ã®
ããªãªãã·ã¢ã«ãã¬ã³éã¯ç°ãªãã¢ã«ãã¬ã³åºã
å«ãã§ããŠããããïœã¯ãªãã·ã¢ã«ãã¬ã³åºã®é
åæ°ã瀺ãïŒåã¯ïŒä»¥äžã®æŽæ°ïŒãªãåå矀ãæ
ããååç©ã§ããããã®å Žåãåœè©²å€äŸ¡ããšããŒ
ã«(A)ãšã¢ã«ãã¬ã³ãªããµã€ããšã®å²åã¯ïŒïŒïŒ
ïŒã¢ã«ïŒã¢ã«ïŒä»¥äžãšããããã奜ãŸããã¯åœè©²
å€äŸ¡ããšããŒã«(A)ã®OHåºã«å¯Ÿããã¢ã«ãã¬ã³ãª
ããµã€ãã®å²åã¯ïŒïŒïŒã10ã奜ãŸããã¯ïŒïŒïŒ
ãïŒïŒåœéïŒåœéïŒã§ããã ããã«ã¢ã«ãã¬ã³ãªããµã€ããšããŠã¯ãäŸãã°
ãšãã¬ã³ãªããµã€ãããããã¬ã³ãªããµã€ããã
ãã¬ã³ãªããµã€ããªã©ããããããããã該å€äŸ¡
ããšããŒã«(A)ãšåå¿ããŠãšãŒãã«çµåããªãå Žå
åŽéãçãããã®ãç¹ã«å¥œãŸããããã®æ§ãªãã®
ãšããŠã¯ãããã¬ã³ãªããµã€ããïŒïŒïŒâããã¬
ã³ãªããµã€ããïŒïŒïŒâããã¬ã³ãªããµã€ãã
ïŒïŒïŒâããã¬ã³ãªããµã€ããããæ®ã«ãããã¬
ã³ãªããµã€ãã奜ãŸããã ãããããªããããã·ã«ååç©(B)ã§ãã€ãŠãç¹
ã«å¥œãŸããäžçŸ€ã®ãã®ã¯ãäžè¬åŒ ïŒåŒäžãYâ²ãY1ãïœãïœåã³R1ã¯åèšïŒïŒ¡âïŒ
âïŒâïŒïŒåŒã®ãããšåãã§ãããã¯ççŽ æ°ïŒ
ãïŒåã®ã¢ã«ãã¬ã³åºãn1åã³n2ã¯ïŒãïŒã®å€ã§
ããïŒã§è¡šããããããªããããã·ã«ååç©ã§ã
ãã æŽã«åããããããªããããã·ã«ååç©ã§ãã€
ãŠå¥œãŸããä»ã®äžçŸ€ã®ãã®ã¯ãäžè¬åŒ ïŒåŒäžãR1ãR2ãR3åã³ïœã¯åèšïŒïŒ¡âïŒâïŒ
âïŒïŒåŒã®ãããšåãã§ãããã¯ççŽ æ°ïŒãïŒ
åã®ã¢ã«ãã¬ã³åºãn1åã³n2ã¯ïŒãïŒã®å€ã§ã
ãïŒã§è¡šããããããªããããã·ã«ååç©ã§ã
ãã ãã®ä»æ žãå«ãããªããããã·ã«ååç©(B)ãšã
ãŠã¯ããªããããã·ã«ååç©(A)ã®è³éŠææ žãæ°ŽçŽ
æ·»å ããŠåŸãããèç°æããªãªãŒã«ãå«ãŸããã åãããã«æ žãå«ãŸãªãèèªæããªããããã·
ã«ååç©(C)ãšããŠã¯ãäŸãã°ãšãã¬ã³ã°ãªã³ãŒ
ã«ããããã¬ã³ã°ãªã³ãŒã«ãããã¬ã³ã°ãªã³ãŒ
ã«ããžãšãã¬ã³ã°ãªã³ãŒã«ããžãããã¬ã³ã°ãªã³
ãŒã«ããžããã¬ã³ã°ãªã³ãŒã«ãã°ãªã»ãªã³ããã³
ã¿ãšãªã¹ãªããŒã«çã®å€äŸ¡ã¢ã«ã³ãŒã«åã³ããã
ã®å€äŸ¡ã¢ã«ã³ãŒã«åã¯ãã®ä»ã®æŽ»æ§æ°ŽçŽ å«æåå
ç©ïŒäŸãã°ã¢ããåºãã«ã«ããã·ã«åºãããªãã
ããã·ã«åºçã®åºãæã€ååç©ïŒã«ã¢ã«ãã¬ã³ãª
ããµã€ããä»å ããããå€äŸ¡ããªããããã·ã«å
åç©ãããªãšãŒãã«ããªãªãŒã«çã®ããªãããã
ã·ã«ååç©ãæããããã åãããã«åèšãšããããããªã³(b)ãšã¯ãäžè¬
åŒ ïŒããã«ïŒºã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºã
Xâ²ã¯ããã²ã³ååã§ããïŒã§è¡šãããããã®ã§
ãããããããšããããããªã³(b)ã®äŸãšããŠã¯ã
äŸãã°ãšãã¯ãã«ãããªã³ããšãããã ãããª
ã³ãïŒïŒïŒâãšããã·âïŒâã¡ãã«âïŒâã¯ãã«
ãããã³ãïŒïŒïŒâãšããã·âïŒâãšãã«âïŒâ
ã¯ãã«ãããã³ãªã©ãæããããã äžèšãšããããããªã³(b)ãšããªããããã·ã«å
åç©(B)æãã¯ããªããããã·ã«ååç©(C)ãšã®åå¿
ãä¿é²ããé žæ§è§ŠåªãšããŠã¯ãäžåŒåç¡ŒçŽ ãå¡©å
第äºé«ãå¡©åäºéãå¡©å第äºéã®åŠãã«ã€ã¹é žã
ãããã®æŽ»æ§ã瀺ãèªå°äœïŒäŸïŒäžåŒåç¡ŒçŽ âãš
ãŒãã«é¯ååç©ïŒæãã¯ãããã®æ··åç©çãçšã
ãããšãã§ããã åãåæ§ãšããããããªã³(b)ãšå€äŸ¡ããšããŒã«
(A)ãšã®åå¿ãä¿é²ããå¡©åºæ§è§ŠåªãšããŠã¯ãã¢ã«
ã«ãªéå±æ°Žé žåç©ïŒäŸïŒæ°Žé žåãããªãŠã ïŒãã¢
ã«ã«ãªéå±ã¢ã«ã³ã©ãŒãïŒäŸïŒãããªãŠã ãšãã©
ãŒãïŒã第äžçŽã¢ãã³ååç©ïŒäŸïŒããªãšãã«ã¢
ãã³ãããªãšã¿ããŒã«ã¢ãã³ïŒã第åçŽã¢ã³ã¢ã
ãŠã ååç©ïŒäŸïŒããã©ã¡ãã«ã¢ã³ã¢ããŠã åå
ç©ïŒäŸïŒããã©ã¡ãã«ã¢ã³ã¢ããŠã ãããã€ãïŒ
æãã¯ãããã®æ··åç©ãçšããããšãã§ãããã
ããŠæ¯ãåå¿ãšåæã«ã°ãªã·ãžã«ãšãŒãã«ãçæ
ããããããæãã¯åå¿ã®çµæçæãããããã
ãªã³ãšãŒãã«ãè±ããã²ã³åæ°ŽçŽ åå¿ã«ãã€ãŠé
ç°ããããŠã°ãªã·ãžã«ãšãŒãã«ãçæããããå¡©
åºæ§ååç©ãšããŠã¯ã¢ã«ã«ãªéå±æ°Žé žåç©ïŒäŸïŒ
æ°Žé žåãããªãŠã ãã¢ã«ãã³é žã¢ã«ã«ãªéå±å¡©
ïŒäŸïŒã¢ã«ãã³é žãããªãŠã ïŒçãéœåããçšã
ãããã ããããŠããããã®è§Šåªä¹è³å¡©åºæ§ååç©ã¯ã
ã®ãŸãŸæãã¯é©åœãªç¡æ©æãã¯ïŒåã³ïŒææ©æº¶åª
溶液ãšããŠäœ¿çšããããšãã§ããã®ã¯å¿è«ã§ã
ãã åã眮æåã¯é眮æã®ã°ãªã·ãžã«ãšã¹ãã«åºã
ååå ã«å¹³åïŒå以äžæãããšããã·æš¹èã«ã¯ã
èèªæããªã«ã«ãã³é žæãã¯è³éŠæããªã«ã«ãã³
é žïŒäŸãã°ãã¿ã«é žãã€ãœãã¿ã«é žããã¬ãã¿ã«
é žãããã©ããããã¿ã«é žãã¡ãã«ããã©ããã
ãã¿ã«é žããããµããããã¿ã«é žãã¡ãã«ãããµ
ããããã¿ã«é žããšã³ãã¡ãã¬ã³ããã©ãããã
ã¿ã«é žãã¡ãã«ãšã³ãã¡ãã¬ã³ããã©ããããã¿
ã«é žããã¬ã€ã³é žããã¿ã«é žãã€ã¿ã³ã³é žãã³ã
ã¯é žãã°ã«ã¿ã«é žãã¢ãžãã³é žããã¡ãªã³é žãã¹
ããªã³é žãã¢ãŒã©ã€ã³é žãã»ãã·ã³é žãäºéäœè
èªé žãããªã¡ãªããé žãããªã¡ã·ã³é žãããã¡ãª
ããé žãã·ã¯ããã³ã¿ã³ããã©ã«ã«ãã³é žããã
ãã®ããã²ã³çœ®æååç©ã®ã»ãããããå€äŸ¡ã«ã«
ãã³é žãšå€äŸ¡ã¢ã«ã³ãŒã«ãšããåŸãããæ«ç«¯ã«ã«
ããã·ã«ããªãšã¹ãã«ãªãªãŽããŒãªã©ãå«ãŸãåŸ
ãïŒã®ããªã°ãªã·ãžã«ãšã¹ãã«çããããäŸãã°
åèšäžè¬åŒã§ç€ºããããšããããããªã³(b)ãšã¡ã¿
ã¯ãªã«é žãšããåæãããã°ãªã·ãžã«ã¡ã¿ã¢ã¯ãª
ã¬ãŒããéåããããŠåŸãããåŠããšããã·æš¹è
ãå«ãŸããã åã眮æã®çœ®æåã¯é眮æïŒïŒïŒâãšããã·
ãããã«åºãååå ã«å¹³åïŒåããå€ãæãããš
ããã·æš¹èã®äŸãšããŠã¯ãè³éŠæã¢ãã³ïŒäŸãã°
ã¢ããªã³åã¯æ žã«ã¢ã«ãã«çœ®æåºãæããã¢ããª
ã³ïŒãšäžèšäžè¬åŒã§ç€ºããããšããããããªã³(b)
ãšããåŸããããšããã·æš¹èãè³éŠæã¢ãã³ãšã¢
ã«ããããšã®åæçž®åç©ïŒäŸãã°ã¢ããªã³ãâã
ã«ã ã¢ã«ãããåæçž®åäœãã¢ããªã³âããšããŒ
ã«âãã«ã ã¢ã«ãããåæçž®åäœïŒãšãšãããã
ããªã³(b)ãšããåŸããããšããã·æš¹èããžã°ãªã·
ãžã«ããã³ãã€ã³çãæããããã ãã®ä»ã®ãšããã·æš¹èãšããŠã¯ããšããã·åæ²¹
ïŒäŸãã°ãšããã·åããŸã«æ²¹ããšããã·å倧è±æ²¹ã
ãšããã·åãµãã©ã¯ãŒæ²¹ããšããã·åæ¡æ²¹ããšã
ãã·åãšãæ²¹ããšããã·åè±æ°Žã²ãŸãæ²¹ããšãã
ã·åãªã€ãã·ã«æ²¹ããšããã·åããŒã«æ²¹ãªã©ïŒã
ãšããã·åèèªé žããšããã·åç°ç¶ãªã¬ãã€ã³å
åç©ïŒäŸãã°ããã«ã·ã¯ãããã»ã³ãžãªããµã€
ããïŒâïŒïŒâã¡ãã«âïŒïŒïŒâãšããã·ãšãã«ïŒ
âïŒïŒïŒâãšããã·âïŒâã¡ãã«ã·ã¯ããããµ
ã³ãïŒïŒïŒâãšããã·ã·ã¯ãããã·ã«ã¡ãã«â
ïŒïŒïŒâãšããã·ã·ã¯ããããµã³ã«ã«ããã·ã¬ãŒ
ããïŒïŒïŒâãšããã·âïŒâã¡ãã«ã·ã¯ãããã·
ã«ã¡ãã«âïŒïŒïŒâãšããã·âïŒâã¡ãã«ã·ã¯ã
ãããµã³ã«ã«ããã·ã¬ãŒãããã¹ïŒïŒïŒïŒâãšã
ãã·âïŒâã¡ãã«ã·ã¯ãããã·ã«ã¡ãã«ïŒã¢ãžã
ãŒãããžã·ã¯ããã³ã¿ãžãšã³ãžãªããµã€ãããžã
ã³ãã³ãžãªããµã€ããããã©ãããã€ã³ãã³ãžãª
ããµã€ããæãã¯ãããã®ç°ãå ã«äžè¬åŒïŒïŒ¡â
ïŒâïŒïŒã§R1ãšããŠç€ºããããããªåºã§çµåã
ããååç©ããã®ä»Araldite CYâ175ïŒãã瀟補
ååååïŒãªã©ïœãå ±åœ¹ãžãšã³éåäœã®ãšããã·
åç©ïŒäŸãã°ãšããã·åããªãã¿ãžãšã³ããšãã
ã·åãããã¹ãã¬ã³âãã¿ãžãšã³å ±éåäœããšã
ãã·åãããã¢ã¯ãªããããªã«âã¹ãã¬ã³å ±éå
äœïŒãäžé£œåçµåãå«ãéåäœã®ãšããã·åç©
ïŒäŸãã°ããªãããã¬ã³ã®ãšããã·åç©ãããªã€
ãœããã³ã®ãšããã·åç©ïŒãããªã·ãããµã³ã®ã
ãªã°ãªã·ãžã«ãšãŒãã«ãåè€çŽ ç°ãå«ããšããã·
æš¹èãšããŠã¯ããªããµãŸãªãžãã³ç°ã«ççŽ ååã
ä»ããŠãšããã·åºãçµåãããšããã·æš¹èããã©
ã³ã®ãžã°ãªã·ãžã«ãšãŒãã«åç©ããžãªããµã³ã®ãž
ã°ãªã·ãžã«ãšãŒãã«åç©ãã¹ãããïŒïœâãžãªã
ãµã³ïŒã®ãžã°ãªã·ãžã«ãšãŒãã«åç©ãïŒã®äœçœ®ã«
å€äžé£œåã®ã¢ã«ã±ãã«åºã眮æããã€ãããŸãªã³
ããåŸãããããªãšããã·ååç©ãããªã°ãªã·ãž
ã«ã€ãœã·ã¢ãã¬ãŒãçãæããããããã®ä»ããš
ããã·æš¹èã®è£œé ãšå¿çšãïŒå£å åŒç·šïŒã«èšèŒã
ããŠããåŠãçš®ã ã®ãšããã·æš¹èçã®åŸæ¥å ¬ç¥ã®
ãšããã·æš¹èã䜿çšãããã æ¬çºæã«çšãããããŠã¬ã¿ã³ãã¬ããªããŒïŒ
âïŒãšããŠã¯ããªã€ãœã·ã¢ããŒããšããªãªãŒã«
é¡ãšãå ¬ç¥ã®åå¿æ¹æ³ã«åŸã€ãŠåå¿ãããããšã«
ãã€ãŠåŸããããã®ã§ããªã€ãœã·ã¢ããŒããšããŠ
ã¯ãžã€ãœã·ã¢ããŒããè¯ãããšãã°ããªã¬ã³â
ïŒïŒïŒâãžã€ãœã·ã¢ããŒããããªã¬ã³âïŒïŒïŒâ
ãžã€ãœã·ã¢ããŒããïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãž
ã€ãœã·ã¢ããŒããããšãã¬ã³ãžã€ãœã·ã¢ããŒãã
ããã¿ã¬ã³ãžã€ãœã·ã¢ããŒãããã·ãªã¬ã³ãžã€ãœ
ã·ã¢ããŒããã€ãœããã³ãžã€ãœã·ã¢ããŒãããã
ãµã¡ãã¬ã³ãžã€ãœã·ã¢ããŒãçãæãããããã
ãšãã«å¥œé©ãªãã®ã¯ããªã¬ã³ãžã€ãœã·ã¢ããŒãã
ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€ãœã·ã¢ããŒãçã§
ããã ãŸããããªãªãŒã«ãšããŠã¯ããªãªãã·ãšãã¬ã³
ã°ãªã³ãŒã«ãããªãªãã·ãããã¬ã³ã°ãªã³ãŒã«ã
ããªãªãã·ããã©ã¡ãã¬ã³ã°ãªã³ãŒã«ããããã¯
ã°ãªã»ãªã³ãããªã¡ãããŒã«ãããã³çã®å€äŸ¡ã¢
ã«ã³ãŒã«é¡ãããã¯ã¢ãã³é¡ã®ãšãã¬ã³ãªããµã€
ãããããã¬ã³ãªããµã€ãçã®ã¢ã«ãã¬ã³ãªããµ
ã€ãä»å ç©ãªã©ã®å¹³åååéã300ã4000ãOH
åœé100ã2000ã®ç¯å²ã«ããããªãšãŒãã«ããªãª
ãŒã«ïŒèé žãã³ãã¯é žãã¢ãžãã³é žããã¡ãªã³
é žãã¢ãŒã©ã€ã³é žãã»ãã·ã³é žããã¿ã«é žãã€ãœ
ãã¿ã«é žããã¬ãã¿ã«é žããã¬ã€ã³é žãããã«é ž
çã®å€äŸ¡ã«ã«ãã³é žãšãšãã¬ã³ã°ãªã³ãŒã«ããã
ãã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâãã¿ã³ãžãªãŒã«ã
ïŒïŒïŒâãããµã³ãžãªãŒã«ããžãšãã¬ã³ã°ãªã³ãŒ
ã«ãããªã¡ãããŒã«ãããã³ãã°ãªã»ãªã³ãããª
ãã³ãã«ã°ãªã³ãŒã«ããã¹ïŒããããã·ã¡ãã«ã·
ã¯ããããµã³ïŒçã®å€äŸ¡ã¢ã«ã³ãŒã«ãšãã«ã«ãã
ã·ã«åºã«å¯Ÿããæ°Žé žåºã®ã¢ã«æ¯ãïŒãã倧ã®æ¡ä»¶
äžã§çž®åããŠåŸãããããããã¯ã«ããã©ã¯ãã³
ã®ãããªã©ã¯ãã³é¡ãå€äŸ¡ã¢ã«ã³ãŒã«ã®ååšäžé
ç°éåããŠåŸãããå¹³åååéã300ã4000ã
OHåœé100ã2000ã®ç¯å²ã«ããããªãšã¹ãã«ã
ãªãªãŒã«ãã®ä»ãããã·æ²¹ãããªãã¿ãžãšã³ã°ãª
ã³ãŒã«é¡çãæããããã ããªã€ãœã·ã¢ããŒãããªãšãŒãã«ããªãªãŒã«ã
ããªãšã¹ãã«ããªãªãŒã«çã®ããªãªãŒã«ãšã®åå¿
ã¯æ®éæ°Žé žåºã«å¯ŸããNCOåºã®ã¢ã«æ¯ãïŒãã
倧ã奜ãŸããã¯1.05ãïŒã®æ¡ä»¶äžã§ãåžžæž©ãªãã
æé«90âãŸã§ã®æž©åºŠã§å®æœãããããã®ããã«ã
ãŠåŸããããŠã¬ã¿ã³ãã¬ããªããŒã¯NCOåºå«é
ã0.1ã10ééïŒ ãååéã600ã16000ã®ç¯å²ã«
ããããšã奜ãŸããããŠã¬ã¿ã³ãã¬ããªããŒã®
NCOåºå«éåã³ååéã¯åæçµæãããªãã¡æ°Ž
é žåºã«å¯ŸããNCOåºã®ã¢ã«æ¯ããããããšã«ã
ãå¶åŸ¡ããããšãã§ããã æ¬çºæã®ã€ãœã·ã¢ããŒãåºïŒãšããã·åºã®åå¿
ã«ãããªããµãŸãªãã³ç°ãã€ãœã·ã¢ãã¬ãŒãç°ã®
çæã«ã¯ãå ¬ç¥ã®ãããç°çæ觊åªã䜿çšããã
ãããã®äŸãšããŠã¯äŸãã°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©
é¡ãïŒçŽã¢ãã³é¡ãªã©ã®å¡©åºæ§ååç©ããªããŠã
ãããããèåäºéããã¹ãããŠã å¡©é¡ãªã©ãæ
ããããåå¿æž©åºŠã¯100ã220â奜ãŸããã¯ã140
ã180âã§ãåå¿æéã¯ïŒã10æéã奜ãŸããã¯
ïŒãïŒæéã§ããã 次ã«æ¬çºæã®çµæç©ã®ããäžã€ã®å¿ é ã®æ§ææ
åã§ãããšããã·æš¹èçšç¡¬åå€ïŒïŒãšã¯ããšã
ãã·æš¹èã®åå¿ãä¿é²ããäœçšãæããååç©ä¹
è³ç©è³ªããšããã·æš¹èãšåå¿æ§ãæããååç©ä¹
è³ç©è³ªããšããã·æš¹èãšåå¿æ§ãæããååç©ä¹
è³ç©è³ªãšããçã®åå¿ãä¿é²ããååç©ä¹è³ç©
質ããããç©è³ªã®å¹Ÿã€ããéããŠæããååç©ä¹
è³ç©è³ªãæãã¯ãããã®æ··åç©ãæå³ãåäžã®å
åç©ä¹è³ç©è³ªæãã¯ïŒçš®ä»¥äžã®ååç©ä¹è³ç©è³ªã®
æ··åä¹è³äœµçšç©ãæå³ãã該硬åå€ã¯æ¥µãäœåå
éã®ãã®ããé«ååéã®ãã®ãŸã§å«ãŸããåäžèš
ã®åŠãã¢ããåºãã«ã«ããã·ã«åºãã«ã«ãã³æ®ç¡
æ°Žç©åºïŒâCOââCOâïŒãããããã·ã«åºãâ
SHåºãâNCOåºãâNCSåºãâCONHâåºãæã
ãåŠãææ©ååç©æãã¯ãã¬ãŒãæ§é ãæããæ
æ©éå±ååç©ãå«ãŸããã ããããšããã·æš¹èçšç¡¬åå€ïŒïŒã®ãã¡å¥œãŸ
ãããã®ã¯ãäŸãã°ãšãã¬ã³ãžã¢ãã³ããžãšãã¬
ã³ããªã¢ãã³ãããªãšãã¬ã³ããã©ãã³ããžãã
ãã¬ã³ããªã¢ãã³ããžã¡ãã«ã¢ãããããã«ã¢ã
ã³ããžãšãã«ã¢ãããããã«ã¢ãã³ãã·ã¯ããã
ã·ã«ã¢ãããããã«ã¢ãã³çã®åŠãèèªæããªã¢
ãã³ãã¢ããšã¿ããŒã«ã¢ãã³ããžãšã¿ããŒã«ã¢ã
ã³ããããããŒã«ã¢ãã³ãâã¡ãã«ãšã¿ããŒã«
ã¢ãã³çã®åŠãèèªæããããã·ã¢ãã¢ãã³ïŒã¢
ãããšãã«ãšã¿ããŒã«ã¢ãã³ãã¢ãããããã·ãš
ãã«ãžãšãã¬ã³ããªã¢ãã³ããã¹ããããã·ãšã
ã¬ã³ããªã¢ãã³ãïŒïŒâããããã·ãããã«ïŒ
ãšãã¬ã³ãžã¢ãã³çã®åŠãèèªæããããã·ããª
ã¢ãã³ïŒãã€ããŒé žãšãžã¢ãã³ïŒäŸãã°ãšãã¬ã³
ãžã¢ãã³ïŒãšã®çž®åã«ãã€ãŠåŸãããããªã¢ã
ãïŒãããã®äœãããšååŠéè«çã«äžè¶³éã®åå
äžã«å¹³åïŒåæªæºã®ïŒïŒïŒâãšããã·åºãæãã
ãšããã·ååç©ïŒäŸãã°ãšãã¬ã³ãªããµã€ããã
ããã¬ã³ãªããµã€ãããšãã¯ãã«ãããªã³ãã¹ã
ã¬ã³ãªããµã€ããã¡ãã«ã°ãªã·ãžã«ãšãŒãã«ãã
ãšãã«ã°ãªã·ãžã«ãšãŒãã«ãã°ãªã·ãžã«ã¡ã¿ã¯ãª
ã¬ãŒãçïŒãšã®åå¿ã«ãã€ãŠåŸãããæè¬å€æ§è
èªæã¢ãã³ç³»ç¡¬åå€ïŒã¢ããªã³ããã«ã€ãžã³ããš
ãã«ã¢ããªã³ããã·ãªãžã³ããã³ãžãžã³ãïŒïŒ
4â²âãžã¢ãããžããšãã«ã¡ã¿ã³ãïŒïŒïŒïŒïŒâã
ãªïŒãžã¡ãã«ã¢ããã¡ãã«ïŒããšããŒã«ãïŒïŒïŒ
âãã¹ïŒïŒâã¢ããããšãã«ïŒãããã³ãïŒïŒ
4â²âãžã¢ãããžããšãã«ãšãŒãã«ãïŒïŒ4â²âãžã¢
ãããžããšãã«ã¹ã«ãã³ãïŒïŒ4â²âãžã¢ãããã³
ãŸããšãã³ãïŒïŒ2â²âãžã¡ãã«âïŒïŒ4â²âãžã¢ã
ããžããšãã«ã¡ã¿ã³ãïŒïŒ4â²âãžã¢ãããããšã
ã«ãïŒïŒ3â²âãžã¡ãã«âïŒïŒ4â²âãžã¢ãããããš
ãã«ãïŒïŒ3â²âãžã¡ããã·âïŒïŒ4â²âãžã¢ããã
ããšãã«ã§äŸç€ºããããããªè³éŠæã¢ãã³ããã
ãè³éŠæã¢ãã³ãšã¢ã«ãããæãã¯ã¢ã«ãããã®
åå¿æ§èªå°äœïŒäŸãã°ãã«ã ã¢ã«ãããããã©ã
ã«ã ã¢ã«ããããã¢ã»ãã¢ã«ããããã¯ãã©ãŒã«
çã®èèªæäœçŽã¢ã«ããããæããããç¹ã«ãã«
ã ã¢ã«ãããæãã¯ãã®åå¿æ§èªå°äœã奜ãŸã
ãïŒãšã®åæçž®åç©ããããè³éŠæã¢ãã³ãšããš
ããŒã«é¡ïŒäŸãã°ããšããŒã«ãã¯ã¬ãŸãŒã«ããã·
ã¬ããŒã«ããšãã«ããšããŒã«ãã¯ãã«ããšããŒ
ã«ãã¢ããœãŒã«ïŒãšäžèšã®åŠãã¢ã«ãããæãã¯
ã¢ã«ãããã®åå¿æ§èªå°äœãšã®åæçž®åç©æãã¯
ãããã®äœãããšååŠéè«çã«äžè¶³éã®ååå ã«
å¹³åïŒä»¥äžïŒæªæºã®ïŒïŒïŒâãšããã·åºãæãã
ãšããã·ååç©ãšã®åå¿ã«ãã€ãŠåŸãããã¢ãã³
ä»å ç©ïŒå€æ§ã¢ãã³ïŒãªã©ã§ããã åããšããã·æš¹èçšç¡¬åå€ïŒïŒã«å«ãŸããã
ã®ä»ã®ã¢ããåºãæãã硬åå€ïŒããã硬åå€ãš
ããŠã¯ã¢ãæ çªçŽ ååãšçµåãããšããã®æŽ»æ§æ°Ž
çŽ ååãæããç矩ã®ç¡¬åå€ãšã¢ããæ çªçŽ ãšçµ
åããæ°ŽçŽ ååãæããªãæè¬è§Šåªã«å±ãããã®
çãå«ãŸããããããã«ãããŠã¯ããçãç·ãŠç¡¬
åå€ãšããŠç·ç§°ãããã®ã¯äžèšã®éãã§ããïŒãš
ããŠã¯ããã©ãžã³ãâã¢ãããšãã«ããã©ãž
ã³ãããªãšãã¬ã³ãžã¢ãã³ã®åŠãç°ç¶æ§é ãæã
ãèèªæã¢ãã³ïŒã¡ã¿ããšãã¬ã³ãžã¢ãã³ãã¡ã¿
ãã·ã¬ã³ãžã¢ãã³ããã©ãã·ã¬ã³ãžã¢ãã³ãïœïŒ
pâ²âãžã¢ãããžããšãã«ã¡ã¿ã³ããžã¢ããããšã
ã«ã¹ã«ãã³ã®åŠãè³éŠæïŒçŽã¢ãã³ïŒãã³ãžã«ãž
ã¡ãã«ã¢ãã³ãïŒâã¡ãã«ãžã¡ãã«ã¢ãã³ãããª
ïŒãžã¡ãã«ã¢ããã¡ãã«ïŒãã³ãŒã³ã®åŠãè³éŠæ
ïŒçŽã¢ãã³ãBF3ã»C2H5NH2ãBF3ã»ããã©ãž
ã³ãããªã¢ã«ã«ããŒã«ã¢ãã³ç¡Œé žå¡©ïŒãã¿ã³é žã¢
ãã³å¡©ïŒã·ã¢ããšãã«åããªã¢ãã³ïŒã¡ã©ãã³æš¹
èåæçž®åç©ãã¢ããæš¹èåæçž®åç©ãäŸç€ºãåŸ
ãã åãäŸãã°ã«ã«ããã·ã«åºãæãã硬åå€åã¯
ã«ã«ãã³é žç¡æ°Žç©ã«å±ãã硬åå€ãšããŠã¯ãã¿ã«
é žããã¬ã€ã³é žãããªã¡ãªããé žãããã¡ãªãã
é žãããã©ããããã¿ã«é žããããµããããã¿ã«
é žãããã©ã¯ãã«ãã¿ã«é žãããã»ãã«ç¥çé žã
ãšã³ãã¡ãã¬ã³ãã¿ã«é žãã¡ãã«ãšã³ãã¡ãã¬ã³
ãã¿ã«é žããããµã¯ããã¡ãã¬ã³ããã©ãããã
ã¿ã«é žããžã¯ãããã¬ã€ã³é žåã¯ãããã®é žç¡æ°Ž
ç©ãé žæ§ããªãšã¹ãã«æš¹èããã¬ã€ã³é žæãã¯ç¡
æ°Žãã¬ã€ã³é žãšãã®ä»ã®éåæ§ããã«ååç©
ïŒäŸïŒã¹ãã¬ã³ïŒãšã®éåïŒå ±éåãäžéåçïŒ
äœããã®éšåãšã¹ãã«åç©ããã¬ã€ã³é žãšã¹ãã«
ãšéåæ§ããã«ååç©ãšã®éåäœçãäŸç€ºããã
ãšãã§ããã åãäŸãã°ãã®ä»ã®çªçŽ ååå«æ硬åå€ãšããŠ
ã¯ãžã·ã¢ã³ãžã¢ãããã°ã¢ããžã³ãå°¿çŽ æš¹èåæ
çž®åç©çãäŸç€ºããããšãã§ããåäŸãã°ORåº
ãæãã硬åå€ãšããŠã¯å€äŸ¡ããšããŒã«é¡ãããš
ããŒã«æš¹èåæçž®åç©ãããªãµã«ãã¢ã€ãæš¹èç
ãäŸç€ºããããšãã§ããã ãããã®ãšããã·æš¹èçšç¡¬åå€ïŒïŒã®ãã¡ã¢
ãã³ç³»ãé žç¡æ°Žç©ç³»ã奜ãŸãããäžã§ãåæ±ãã®
䟿çã«ããç¹ã«å¥œãŸãããã®ã¯æœåšæ§ç¡¬åå€ã§ã
äŸãã°ãžã·ã¢ã³ãžã¢ãããããªã«ã«ãã³é žãžãã
ã©ãžãçãæããããã åããšããã·æš¹èçšç¡¬åå€ïŒïŒã®é åéã¯ãš
ããã·æš¹èïŒïŒã«å«ãŸããåå¿ã«äžããåºã«ã€
ããŠã®åœéããçžäºã®åœéãç®åºããããšãã§ã
ããããšããã·æš¹èã®ç¡¬åç©ãç®çãšããã«éã
ãŠã¯ãããåœéå€ã®ååŸã«äºãæ¯èŒçåºãå·Ÿã®å²
åããšãããšãå¯èœã§ãããçµå±ãããå²åã¯ãš
ããã·æš¹èã®ç¡¬åã«ãããåŸæ¥å ¬ç¥ã®æè¡ãé©å®
å¿çšããããšã«ãã€ãŠå®ããããšãã§ããã æ¬çºæã¯ãããã®å¿ é æåã®ã»ãã«ãŠã¬ã¿ã³å€
æ§ããŠããªããšããã·æš¹èãåå¿æ§åã¯éåå¿æ§
åžéå€ãã·ãªã«ãã¿ã«ã¯ãã¯ã¬ãŒãçé žã«ã«ã·ãŠ
ã ãé žåãã¿ã³ãã¢ã«ãç²ãã¢ã«ããçã®å å¡«
å€ããã®ä»ãé¡æãæºå€å€ãçãå«æããŠãè¯
ãã 以äžã«è£œé äŸåã³å®æœäŸã瀺ããæ¬çºæãæŽã«
詳述ããã 補é äŸ ïŒ ïŒå®èœã°ãªã»ãªã³ããŒã¹ã®ååé4000ã®ããªãª
ãã·ãããã¬ã³ã°ãªã³ãŒã«700éšïŒéééšã以äž
åãïŒãïŒå®èœååé2000ã®ããªãªãã·ãããã¬
ã³ã°ãªã³ãŒã«200éšããã«ãšã³ãžã€ãœã·ã¢ããŒã
123éšãçªçŽ 眮æãããã©ã¹ã³äžã§æ··åããN2ã¬
ã¹äž80ã90âã§çŽïŒæéåå¿ããNCOåºå«æé
3.1ïŒ ã®ç²çš ãªãŠã¬ã¿ã³ãã¬ããªããŒãåŸãã 次ãã§äžèšãŠã¬ã¿ã³ãã¬ããªããŒ140éšãã¢
ãã«ã¬ãžã³Epâ4100ïŒãšããã·åœé190ãç²åºŠ
ïŒ25âïŒã11000cpsã®ãã¹ããšããŒã«(A)ã®ãžã°ãªã·
ãžã«ãšãŒãã«ãæé»åå·¥æ¥è£œïŒ200éšãããã©ã¡
ãã«ã¢ã³ã¢ããŠã ãããã0.12éšãæ··åãã160
âã§ïŒæéåå¿ããã宀枩ã§ç²çš ãªãšããã·åœé
321ã®ãªããµãŸãªãã³ç°åã³ã€ãœã·ã¢ãã¬ãŒãç°
å«æïŒèµ€å€ã¹ãã¯ãã«ã§ç¢ºèªïŒãšããã·æš¹èâã€ã
åŸãã 補é äŸ ïŒ ååé2000ã®ã¢ãžãã³é žãšãžãšãã¬ã³ã°ãªã³ãŒ
ã«ãšã®åå¿ã«ãã€ãŠåŸãããããªãšã¹ãã«ããªãª
ãŒã«ïŒæé»å補ãã¢ãã«ããŠãŒãšãŒã¹ïŒŠâ15â
22ïŒ100éšã«ïŒïŒ4â²âãžããšãã«ã¡ã¿ã³ãžã€ãœã·
ã¢ããŒã20éšãçªçŽ 眮æãããã©ã¹ã³äžã«ãŠæ··å
ããN2ã¬ã¹äžã90âã§ïŒæéåå¿ãNCOåºå«æ
é2.0ïŒ ããŠã¬ã¿ã³ãã¬ããªããŒãåŸãã äžèšãŠã¬ã¿ã³ãã¬ããªããŒ100éšãã¢ãã«ã¬
ãžã³Epâ4100 200éšãããã©ã¡ãã«ã¢ã³ã¢ããŠ
ã ãããã0.15éšãæ··åã160âã§ïŒæéåå¿ã
ã宀枩ã§ç²çš ãªãšããã·åœéïŒ290ã®ãªããµãŸãª
ãã³ç°åã³ã€ãœã·ã¢ãã¬ãŒãç°å«æïŒèµ€å€ã¹ãã¯
ãã«ã«ãŠç¢ºèªïŒã®ãšããã·æš¹èâããåŸãã 補é äŸ ïŒ ïŒå®èœã°ãªã»ãªã³ããŒã¹ååé3000ã®ããªãšãŒ
ãã«ããªãªãŒã«150éšããã«ãšã³ãžã€ãœã·ã¢ããŒ
ã268éšãïŒå®èœååé1000ã®ããªãšãŒãã«ããª
ãªãŒã«165éšãïŒå®èœããªã¡ãããŒã«ãããã³ã
ãŒã¹ååé1500ã®ããªãšãŒãã«ããªãªãŒã«400éš
ãçªçŽ 眮æãããã©ã¹ã³äžã«ãŠæ··åãN2ã¬ã¹äž
90âã§ïŒæéåå¿ãNCOåºå«æé7.0ïŒ ã®ãŠã¬ã¿
ã³ãã¬ããªããŒãåŸãã äžèšãŠã¬ã¿ã³ãã¬ããªããŒ140éšãã¢ãã«ã¬
ãžã³Epâ4000ïŒãšããã·åœéïŒ320ãç²åºŠïŒ25âïŒ
35ãã€ãºãæé»å補åŽéåãšããã·æš¹èïŒ140éšã
ããã©ã¡ãã«ã¢ã³ã¢ããŠã ãããã0.15éšãæ··å
ã160âã§ïŒæéåå¿ãã宀枩ã§ç²çš ãªãšããã·
åœé630ã®ãŠã¬ã¿ã³å€æ§ãšããã·æš¹èâããåŸãã å®æœäŸ ïŒ è¡šïŒã«ç€ºãçµæãæãããšããã·æš¹èçµæç©ã
硬åããããã®ç©æ§ãè©äŸ¡ãããçµæãè¡šïŒã«ç€º
ãã
ãè¡šã
ãè¡šã
ãŒã«ãæºå»ãåŸãããçæç©ã
å®æœäŸ ïŒ è¡šïŒã«ç€ºãçµæãæãããšããã·æš¹èçµæç©ã
硬åãããã®ç©æ§ãè©äŸ¡ãããçµæãè¡šïŒã«ç€º
ãã
å®æœäŸ ïŒ è¡šïŒã«ç€ºãçµæãæãããšããã·æš¹èçµæç©ã
硬åãããã®ç©æ§ãè©äŸ¡ãããçµæãè¡šïŒã«ç€º
ãã
ãè¡šã
å®æœäŸ ïŒ
è¡šïŒã«ç€ºãçµæãæãããšããã·æš¹èçµæç©ã
硬åãããã®ç©æ§ãè©äŸ¡ãããçµæãè¡šïŒã«ç€º
ãã
硬åãããã®ç©æ§ãè©äŸ¡ãããçµæãè¡šïŒã«ç€º
ãã
ãè¡šã
ãè¡šã
å®æœäŸ ïŒ
è¡šïŒã«ç€ºãçµæãæãããšããã·æš¹èçµæç©ã
硬åãããã®ç©æ§ãè©äŸ¡ãããçµæãè¡šïŒã«ç€º
ãã
硬åãããã®ç©æ§ãè©äŸ¡ãããçµæãè¡šïŒã«ç€º
ãã
ãè¡šã
Claims (1)
- ïŒ å¹³åïŒåããå€ãã®ãšããã·åºãååå ã«æ
ãããšããã·ååç©ïŒâïŒãšãå¹³åååé
300ã4000ãOHåœé100ã2000ã®ããªãªãŒã«ãšã
ãªã€ãœã·ã¢ããŒãããåŸãããã€ãœã·ã¢ããŒãåº
å«æé0.1ã10ééïŒ ã®ãŠã¬ã¿ã³ãã¬ããªããŒ
ïŒâïŒãšãåå¿ãããŠåŸããããªããµãŸãªã
ã³ç°ãšã€ãœã·ã¢ãã¬ãŒãç°ãå«ããšããã·æš¹è
ïŒïŒãåã³ãšããã·æš¹èçšç¡¬åå€ïŒïŒãå«æã
ãç±ç¡¬åå硬åæ§ãšããã·æš¹èçµæç©ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4682881A JPS57159814A (en) | 1981-03-30 | 1981-03-30 | Curable epoxy resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4682881A JPS57159814A (en) | 1981-03-30 | 1981-03-30 | Curable epoxy resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57159814A JPS57159814A (en) | 1982-10-02 |
| JPH0155289B2 true JPH0155289B2 (ja) | 1989-11-24 |
Family
ID=12758183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4682881A Granted JPS57159814A (en) | 1981-03-30 | 1981-03-30 | Curable epoxy resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57159814A (ja) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59113023A (ja) * | 1982-12-17 | 1984-06-29 | Dainippon Ink & Chem Inc | ãšããã·æš¹èçµæç© |
| JPS59193918A (ja) * | 1983-04-20 | 1984-11-02 | Dainippon Ink & Chem Inc | ãšããã·æš¹èçµæç© |
| DE3323123A1 (de) * | 1983-06-27 | 1985-01-10 | Siemens AG, 1000 Berlin und 8000 MÃŒnchen | Hitzehaertbare reaktionsharzmischungen |
| JPS6011526A (ja) * | 1983-06-30 | 1985-01-21 | Dainippon Ink & Chem Inc | è£ é£Ÿæçšæš¹èçµæç© |
| JP6766323B2 (ja) * | 2015-06-05 | 2020-10-14 | Dicæ ªåŒäŒç€Ÿ | ããªãŠã¬ã¿ã³å€æ§ãšããã·æš¹èåã³æ¥çå€ |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5453197A (en) * | 1977-10-04 | 1979-04-26 | Mitsubishi Electric Corp | Thermosetting resin material |
| JPS55155012A (en) * | 1979-05-21 | 1980-12-03 | Mitsubishi Electric Corp | Photosetting type, heatresisting resin composition |
-
1981
- 1981-03-30 JP JP4682881A patent/JPS57159814A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5453197A (en) * | 1977-10-04 | 1979-04-26 | Mitsubishi Electric Corp | Thermosetting resin material |
| JPS55155012A (en) * | 1979-05-21 | 1980-12-03 | Mitsubishi Electric Corp | Photosetting type, heatresisting resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57159814A (en) | 1982-10-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9315664B2 (en) | High Tg epoxy systems for composite applications | |
| EP0197458B1 (en) | Curable epoxy resin composition | |
| US5508326A (en) | Emulsifying epoxy resin composition and curable composition | |
| EP0758661B1 (en) | Curable epoxy resin compositions | |
| JPS62265323A (ja) | 硬åæ§ãšããã·æš¹èçµæç© | |
| WO2003000798A1 (en) | Thermosetting resin composition, process for producing the same, and suspension-form mixture | |
| JP3375160B2 (ja) | æ°Žæ§ãšããã·æš¹è硬åæ§çµæç© | |
| JP4390478B2 (ja) | ãšããã·æš¹èçšç¡¬åå€çµæç© | |
| JPH0155289B2 (ja) | ||
| JPH09176292A (ja) | æ°Žæ§ãšããã·æš¹è硬åæ§çµæç© | |
| JPS5936928B2 (ja) | 硬åæ§ãšããã·æš¹èçµæç© | |
| JPH0694496B2 (ja) | 硬åæ§çµæç© | |
| JPS621613B2 (ja) | ||
| JP2786456B2 (ja) | 硬åæ§ãšããã·æš¹èçµæç© | |
| JPS5922727B2 (ja) | ãšããã·æš¹è硬åå€ã®è£œæ³ | |
| JP3121631B2 (ja) | 硬åæ§ãšããã·æš¹èçµæç© | |
| JP3024006B2 (ja) | æ°Žæ§ãšããã·æš¹è硬åæ§çµæç© | |
| JPS62146915A (ja) | 硬åæ§ãšããã·æš¹èçµæç© | |
| JPS6251304B2 (ja) | ||
| JPS5840570B2 (ja) | ã³ãŠã«ã»ã€ãžãŠã·ãœã»ã€ãã | |
| JPS6011729B2 (ja) | éæ¶åºæ§ãšããã·æš¹èçµæç© | |
| JPH0674319B2 (ja) | 硬åæ§çµæç© | |
| JPS5936930B2 (ja) | 硬åæ§ãšããã·æš¹èçµæç© | |
| JPS6312889B2 (ja) | ||
| JPS62195012A (ja) | æ°èŠç¡¬åæ§çµæç© |