JP7629655B2 - ピリジン－ピロール－ルテニウム錯体とその生成方法、及びアンモニア酸化に対し電極触媒作用を発揮してヒドラジンを生成する触媒としての応用 - Google Patents

ピリジン－ピロール－ルテニウム錯体とその生成方法、及びアンモニア酸化に対し電極触媒作用を発揮してヒドラジンを生成する触媒としての応用 Download PDF

Info

Publication number
JP7629655B2
JP7629655B2 JP2023524432A JP2023524432A JP7629655B2 JP 7629655 B2 JP7629655 B2 JP 7629655B2 JP 2023524432 A JP2023524432 A JP 2023524432A JP 2023524432 A JP2023524432 A JP 2023524432A JP 7629655 B2 JP7629655 B2 JP 7629655B2
Authority
JP
Japan
Prior art keywords
pyrrole
pyridine
ruthenium complex
ruthenium
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2023524432A
Other languages
English (en)
Japanese (ja)
Other versions
JP2024504897A (ja
JP2024504897A5 (https=
JPWO2023116540A5 (https=
Inventor
易小藝
陳果
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Central South University
Original Assignee
Central South University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Central South University filed Critical Central South University
Publication of JP2024504897A publication Critical patent/JP2024504897A/ja
Publication of JP2024504897A5 publication Critical patent/JP2024504897A5/ja
Publication of JPWO2023116540A5 publication Critical patent/JPWO2023116540A5/ja
Application granted granted Critical
Publication of JP7629655B2 publication Critical patent/JP7629655B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/50—Processes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • C25B11/085—Organic compound
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/09—Nitrogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/23—Oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/13—Crystalline forms, e.g. polymorphs
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Pyridine Compounds (AREA)
JP2023524432A 2021-12-22 2022-12-15 ピリジン－ピロール－ルテニウム錯体とその生成方法、及びアンモニア酸化に対し電極触媒作用を発揮してヒドラジンを生成する触媒としての応用 Active JP7629655B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN202111584527.X 2021-12-22
CN202111584527.XA CN114478648B (zh) 2021-12-22 2021-12-22 一种类吡啶吡咯钌配合物及其制备方法和作为电催化氨氧化催化剂的应用
PCT/CN2022/139184 WO2023116540A1 (zh) 2021-12-22 2022-12-15 一种吡啶吡咯钌配合物及其制备方法和作为电催化氨氧化制备肼的催化剂的应用

Publications (4)

Publication Number Publication Date
JP2024504897A JP2024504897A (ja) 2024-02-02
JP2024504897A5 JP2024504897A5 (https=) 2024-10-30
JPWO2023116540A5 JPWO2023116540A5 (https=) 2024-10-30
JP7629655B2 true JP7629655B2 (ja) 2025-02-14

Family

ID=81493812

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2023524432A Active JP7629655B2 (ja) 2021-12-22 2022-12-15 ピリジン－ピロール－ルテニウム錯体とその生成方法、及びアンモニア酸化に対し電極触媒作用を発揮してヒドラジンを生成する触媒としての応用

Country Status (6)

Country Link
US (1) US20240101586A1 (https=)
EP (1) EP4261216A4 (https=)
JP (1) JP7629655B2 (https=)
KR (1) KR20230119704A (https=)
CN (1) CN114478648B (https=)
WO (1) WO2023116540A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114478648B (zh) * 2021-12-22 2024-01-30 中南大学 一种类吡啶吡咯钌配合物及其制备方法和作为电催化氨氧化催化剂的应用
CN114853798B (zh) * 2022-06-07 2024-07-02 海南贝欧亿科技有限公司 一种吡咯环三齿金属配合物及其应用
JPWO2024225204A1 (https=) * 2023-04-24 2024-10-31

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150073143A1 (en) 2009-08-24 2015-03-12 The University Of North Carolina At Chapel Hill Ruthenium or Osmium Complexes and Their Uses as Catalysts for Water Oxidation
CN108997435A (zh) 2018-05-29 2018-12-14 中南大学 一种二吡啶基吡咯-钌(i)配合物及其制备方法和作为电化学还原催化剂的应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060122055A1 (en) * 2004-12-06 2006-06-08 Gaffney Anne M (Amm)oxidation catalyst and catalytic (amm)oxidation process for conversion of lower alkanes
JP5913222B2 (ja) * 2012-09-28 2016-04-27 富士フイルム株式会社 光電変換素子および色素増感太陽電池
US11465136B2 (en) * 2019-10-23 2022-10-11 Wisconsin Alumni Research Foundation Metal-metal bonded ammonia oxidation catalysts
CN114478648B (zh) * 2021-12-22 2024-01-30 中南大学 一种类吡啶吡咯钌配合物及其制备方法和作为电催化氨氧化催化剂的应用

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150073143A1 (en) 2009-08-24 2015-03-12 The University Of North Carolina At Chapel Hill Ruthenium or Osmium Complexes and Their Uses as Catalysts for Water Oxidation
CN108997435A (zh) 2018-05-29 2018-12-14 中南大学 一种二吡啶基吡咯-钌(i)配合物及其制备方法和作为电化学还原催化剂的应用

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Alex MCSKIMMING et al.，"An Easy One‐Pot Synthesis of Diverse 2,5‐Di(2‐pyridyl)pyrroles: A Versatile Entry Point to Metal Complexes of Functionalised, Meridial and Tridentate 2,5‐Di(2‐pyridyl)pyrrolato Ligands"，Chemistry - A European Journal，2014年07月23日，Vol. 20, No. 36，p.11445-11456，DOI: 10.1002/chem.201402157

Also Published As

Publication number Publication date
EP4261216A4 (en) 2025-07-09
JP2024504897A (ja) 2024-02-02
US20240101586A1 (en) 2024-03-28
EP4261216A1 (en) 2023-10-18
KR20230119704A (ko) 2023-08-16
WO2023116540A1 (zh) 2023-06-29
CN114478648A (zh) 2022-05-13
CN114478648B (zh) 2024-01-30

Similar Documents

Publication Publication Date Title
JP7629655B2 (ja) ピリジン－ピロール－ルテニウム錯体とその生成方法、及びアンモニア酸化に対し電極触媒作用を発揮してヒドラジンを生成する触媒としての応用
Ma et al. Boosting activity of molecular oxygen by pyridinium-based photocatalysts for metal-free alcohol oxidation
CN112811392B (zh) 氘气制备方法及以其作为氘源参与的氘代反应
CN107540660B (zh) 一种以三联吡啶衍生物为配体的铁配合物及其合成方法和应用
Soni et al. Sustainable photoredox chemistry of a transient ternary complex: an unconventional approach toward trifluoromethylated hydroquinones
CN115785122A (zh) 一种吲哚衍生哌啶类化合物及其合成方法
JPWO2023116540A5 (https=)
JP2014062038A (ja) 一酸化炭素および／または水素の製造方法
CN113957461A (zh) 一种1,1′-联萘类化合物的电化学合成方法
CN112694489B (zh) N-杂环卡宾铜催化剂的制备方法
CN111788001B (zh) 氨的分解方法及钌配位化合物
CN108276261B (zh) 一种水相中催化分子氧氧化制备2-溴芴酮的方法
Pratap et al. Synthesis and characterization of In (iii) S-thiobenzoylthioglycolate complexes and their catalytic applications in CO 2 fixation and multicomponent synthetic reactions
CN117822001A (zh) 一种电化学催化制备苄醇及其衍生物的方法
CN112570025B (zh) 一种巴比妥酸改性多金属氧簇杂化物及其制备方法
Li et al. Green synthesis of furan di-Schiff bases via a one-pot tandem amination-oxidation-amination process under room temperature
CN114560761A (zh) 一种水相中一次性合成2,3-二取代的茚酮衍生物的方法
CN116410126B (zh) 一种配体、钌配合物及其制备方法和在催化炔烃半氢化反应中的应用
CN114950554B (zh) 一种用于含氧气体氧化制备2-烷基蒽醌的催化剂及其应用
CN117126043B (zh) 一种绿色氧化安息香或其衍生物合成苯偶酰或其衍生物的方法
CN119350376B (zh) 一种具有协同双催化位点的Cu4团簇催化材料及其在硼氢化反应中的应用
JP6146860B2 (ja) 金属錯体およびこれを含む燃料電池用カソード
CN111362796B (zh) 三级烷基醇还原加氢的方法
CN110407884B (zh) 一种水溶性单核钌配合物的制备方法
Li et al. Synthesis, crystal structure and properties of binuclear manganese complex [(bipy) 2Mn2 (μ-O)(μ-Ac) 2 (H2O) 2](ClO4) 2

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20230511

A871 Explanation of circumstances concerning accelerated examination

Free format text: JAPANESE INTERMEDIATE CODE: A871

Effective date: 20230519

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20240730

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20241021

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20250114

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20250127

R150 Certificate of patent or registration of utility model

Ref document number: 7629655

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150