JP7590848B2 - Gel-type cleansing cosmetics - Google Patents

Gel-type cleansing cosmetics Download PDF

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JP7590848B2
JP7590848B2 JP2020168639A JP2020168639A JP7590848B2 JP 7590848 B2 JP7590848 B2 JP 7590848B2 JP 2020168639 A JP2020168639 A JP 2020168639A JP 2020168639 A JP2020168639 A JP 2020168639A JP 7590848 B2 JP7590848 B2 JP 7590848B2
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由紀夫 長谷部
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Almado Inc
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本発明はジェル状クレンジング化粧料に関する。より詳細には、水性のジェル状クレンジング化粧料に関する。 The present invention relates to a gel-type cleansing cosmetic preparation. More specifically, the present invention relates to a water-based gel-type cleansing cosmetic preparation.

メイクアップ化粧料や紫外線防止化粧料は、肌を美しく見せ外界の刺激から肌を保護する効果を有し、現代社会の生活においては欠かせないものである。しかし、これらの化粧料は油性成分や無機顔料を多量に含んでいるため、皮膚の毛穴を塞ぎ、新陳代謝を妨げ、また化粧料自体が徐々に酸化されることから、長時間の使用は肌トラブルの原因となる場合がある。このため、1日1回はクレンジング料を用いてこれらの化粧料を除去する必要がある。 Makeup cosmetics and UV protection cosmetics are indispensable in modern society, as they make the skin look beautiful and protect it from external stimuli. However, these cosmetics contain large amounts of oily ingredients and inorganic pigments, which can clog the skin's pores and hinder metabolism. In addition, the cosmetics themselves gradually oxidize, so prolonged use can cause skin problems. For this reason, it is necessary to remove these cosmetics using a cleansing product once a day.

クレンジング化粧料として、近年はゲルの特性であるみずみずしい使用感が好まれ、クレンジング用ジェルが大きなシェアを占めている。水を主成分とする水性ジェル(特許文献1参照)と油性ジェルが知られている。水性ジェルには少量の油分を分散させて配合することもあるが、これらは、水で洗い流すことができ、ダブル洗顔を必要とせずさっぱりした使用感があるものの、洗浄効果に劣るものや洗顔後にべたつくものがある。 In recent years, the fresh feel that is characteristic of gels has become popular as a cleansing cosmetic, and cleansing gels account for a large share of the market. Water-based gels (see Patent Document 1), which contain water as the main component, and oil-based gels are known. Water-based gels may contain a small amount of dispersed oil, and although these can be washed off with water and have a refreshing feel without the need for double cleansing, some have poor cleansing effects and leave a sticky feeling after washing the face.

油性ジェルは、メイクアップ化粧料との馴染みがよく、オイルジェルやW/O乳化型またはO/W乳化型の乳化タイプのものがある。オイルジェルやW/O乳化型のものは、クレンジング力が大きいが、油相を連続相とするために水洗できず、使用後にコットン等により拭き取り後、更に洗顔料などにより洗浄するダブル顔が必要である。O/W乳化型のもの(特許文献2参照)は水で洗い流すことが可能であるが、近年のメイクアップ化粧料の除去には必ずしも満足のいくものではなく、このため、近年のメイクアップ化粧料に適合したクレンジング化粧料の開発が望まれていた。 Oil-based gels blend well with makeup cosmetics, and come in emulsion types such as oil gels, W/O emulsion types, or O/W emulsion types. Oil gels and W/O emulsion types have strong cleansing power, but because the oil phase is the continuous phase, they cannot be washed with water, and so after use, the face must be wiped off with cotton or the like, and then washed with a facial cleanser or the like. O/W emulsion types (see Patent Document 2) can be washed off with water, but are not necessarily satisfactory for removing modern makeup cosmetics, and for this reason, there has been a demand for the development of cleansing cosmetics that are compatible with modern makeup cosmetics.

特開2012-6862号公報JP 2012-6862 A 特開2000-26238号公報JP 2000-26238 A 特許第5253483号公報Patent No. 5253483 特開2001-191076号公報JP 2001-191076 A 特開2015-16441号公報JP 2015-16441 A

美肌作りは洗顔からと言われている。美肌を保つためのクレンジング化粧料においては、化粧を落とす際にこすらないで、いかに肌のダメージを少なくするかが最も重要である。
本発明は、泡の立たない、即ち、こする必要がなく肌のダメージが少ないにもかかわらず、メイク除去効果に優れ、ダブル洗顔不要のジェル状クレンジング化粧料を提供することをその課題とする。
It is said that beautiful skin starts with washing your face. When using cleansing cosmetics to maintain beautiful skin, the most important thing is to avoid rubbing when removing makeup and to minimize damage to the skin.
To provide a gel-type cleansing cosmetic composition which does not produce foam, i.e., does not require rubbing and causes little damage to the skin, yet has an excellent makeup removing effect and does not require double face washing.

本発明者は種々検討を重ねた結果、水性のジェル状クレンジングの主原料となる水として、ジェル状クレンジングで従来広く用いられていた精製水の代わりに、3室型電解装置のカソード室に生成するアルカリ性の還元水を使用すると、オイルを添加しなくても、その還元力により酸化した化粧品を浮かして取り、泡が立たたずこすらずにメイクが落とせるために、肌へのダメージが少なく、しかもクレンジング後の保湿力に優れることを見出した。
併せて、加水分解卵殻膜成分を含有させると、電解還元水による保湿効果と相俟って洗顔後の保湿感がさらに高まり、洗顔後の乾燥が防止されて肌が潤うこと、そして、電解還元水が毛穴まで浸透して黒ずみがケアされた肌に、加水分解卵殻膜成分が保湿と同時に弾力とハリ、ツヤを与え美肌効果が増すことを見出し、本発明の完成に至った。
As a result of extensive research, the inventors have found that if alkaline reduced water generated in the cathode chamber of a three-chamber electrolysis device is used as the main water ingredient in aqueous gel cleansing products, instead of the purified water that has been widely used in gel cleansing products up until now, the reducing power of the water will float and remove oxidized cosmetics without the need for added oil, and makeup can be removed without creating foam or scrubbing, causing less damage to the skin and providing excellent moisturizing power after cleansing.
In addition, it was discovered that the inclusion of hydrolyzed eggshell membrane components, in combination with the moisturizing effect of electrolytically reduced water, further enhances the moisturizing feeling after washing the face, prevents dryness after washing and moisturizes the skin, and that the electrolytically reduced water penetrates into the pores and treats dark spots on the skin, while the hydrolyzed eggshell membrane components not only moisturize the skin but also impart elasticity, firmness and luster, thereby increasing the skin-beautifying effect, which led to the completion of the present invention.

また、3室型電解装置のカソード室に生成するアルカリ性の還元水に、3室型電解装置のアノード室に生成する酸性の酸化水を混合して用いることにより、pHを酸性方向に調整でき、しかも、酸化水による殺菌、除菌効果や肌再生効果も付加される。 In addition, by mixing the alkaline reduced water produced in the cathode chamber of a three-chamber electrolysis device with the acidic oxidized water produced in the anode chamber of the three-chamber electrolysis device, the pH can be adjusted toward the acidic side, and the oxidized water also has the added effect of sterilizing, disinfecting, and regenerating the skin.

ジェル状クレンジング化粧料の全重量に基づいて、3室型電解水の割合を40~90重量%、加水分解卵殻膜成分の割合を0.0001~2重量%とすること、加水分解卵殻膜成分が酵素分解卵殻膜成分および/またはアルカリ分解卵殻膜成分であることが好ましいこと、さらに、界面活性剤の含有量が少量でも皮膚の殺菌性を向上させることができる。 Based on the total weight of the gel-type cleansing cosmetic, the ratio of the three-chamber electrolyzed water is 40-90% by weight, the ratio of the hydrolyzed eggshell membrane component is 0.0001-2% by weight, the hydrolyzed eggshell membrane component is preferably an enzymatically decomposed eggshell membrane component and/or an alkaline decomposed eggshell membrane component, and further, even a small amount of surfactant content can improve the antibacterial properties of the skin.

本発明は、以下の(1)~()のジェル状クレンジング化粧料に関する。
(1)主成分としての3室型電解水と、加水分解卵殻膜成分とを含有し、3室型電解水がアルカリ性の3室型電解還元水と酸性の3室型電解酸化水の混合水である、ジェル状クレンジング化粧料。
(2)前記3室型電解水を40~90重量%、前記加水分解卵殻膜成分を0.0001~2重量%含有する、上記(1)に記載のジェル状クレンジング化粧料。
(3)前記3室型電解還元水が、アノード電極を備えるアノード室と、カソード電極を備えるカソード室と、アノード室とカソード室との間に設けられた中間室と、アノード室と中間室との間に配置された隔膜と、カソード室と中間室との間に配置された隔膜を備える3室型電解水生成装置を使用して、そのアノード室およびカソード室のそれぞれに水を供給し、中間室に塩化ナトリウム水溶液を供給して電気分解を行うことによってカソード室に生成させた還元水である、上記()または()に記載のジェル状クレンジング化粧料。
The present invention relates to the following gel-type cleansing cosmetic preparations (1) to ( 7 ).
(1) A gel-type cleansing cosmetic preparation containing three-compartment electrolyzed water and a hydrolyzed eggshell membrane component as main ingredients , the three-compartment electrolyzed water being a mixture of alkaline three-compartment electrolyzed reduced water and acidic three-compartment electrolyzed oxidized water.
(2) The gel-type cleansing cosmetic according to (1) above, containing 40 to 90% by weight of the three-compartment electrolyzed water and 0.0001 to 2% by weight of the hydrolyzed eggshell membrane component.
(3) The gel-type cleansing cosmetic preparation according to (1) or (2) above, wherein the three-chamber electrolytic reduced water is reduced water generated in the cathode chamber by using a three-chamber electrolytic water generating device including an anode chamber having an anode electrode, a cathode chamber having a cathode electrode, an intermediate chamber provided between the anode chamber and the cathode chamber, a diaphragm disposed between the anode chamber and the intermediate chamber, and a diaphragm disposed between the cathode chamber and the intermediate chamber, by supplying water to each of the anode chamber and the cathode chamber, and by supplying an aqueous sodium chloride solution to the intermediate chamber and performing electrolysis.

)前記加水分解卵殻膜成分が酵素分解卵殻膜成分および/またはアルカリ分解卵殻膜成分である、上記(1)ないし()のいずれかに記載のジェル状クレンジング化粧料。
)さらに界面活性剤を2~10重量%含有する、上記(1)ないし()のいずれかに記載のジェル状クレンジング化粧料。
)鉱物油と1価アルコールを含有しない、上記(1)ないし()のいずれかに記載のジェル状クレンジング化粧料。
)pHが5~7である、上記(1)ないし()のいずれかに記載のジェル状クレンジング化粧料。
( 4 ) The gel-type cleansing cosmetic according to any one of (1) to ( 3 ) above, wherein the hydrolyzed eggshell membrane component is an enzymatically decomposed eggshell membrane component and/or an alkali decomposed eggshell membrane component.
( 5 ) The gel-type cleansing cosmetic composition according to any one of (1) to ( 4 ) above, further comprising 2 to 10% by weight of a surfactant.
( 6 ) A gel-type cleansing cosmetic composition according to any one of (1) to ( 5 ) above, which does not contain mineral oil and monohydric alcohol.
( 7 ) The gel-type cleansing cosmetic preparation according to any one of (1) to ( 6 ) above, which has a pH of 5 to 7.

本発明のジェル状クレンジング化粧料は、主原料の水として、3室型電解水である3室型電解装置のカソード室に生成するアルカリ性の還元水を用いるため、その還元力によりオイルを含有しなくても化粧品を浮かせて取り、還元水が毛穴まで浸透して黒ずみをケアすることができる。
クレンジング化粧料が泡立つのはこするからであり、本発明のジェル状化粧料は、今までに存在しなかった泡が立たず、こすらずにメイクが落とせるノンオイルタイプであり、肌へのダメージが少ない。しかも洗浄力に優れ、油性、水性、ウオータプルーフ等の全てのタイブの化粧品がよく落ち、芸能人の使用するドーラン化粧品でもしっかり落とすことができる。
The gel-type cleansing cosmetic of the present invention uses alkaline reduced water, which is a three-chamber electrolytic water produced in the cathode chamber of a three-chamber electrolysis device, as its main raw material, and due to its reducing power, it can float and remove cosmetics even without containing oil, and the reduced water can penetrate into the pores to treat dark spots.
Cleansing cosmetics foam when rubbed, but the gel cosmetic of the present invention is a non-oil type that does not foam and can remove makeup without rubbing, which has never existed before, and causes less damage to the skin. Moreover, it has excellent cleansing power and can remove all types of cosmetics such as oil-based, water-based, and waterproof, and can even remove grease makeup used by celebrities.

また、水性ジェルであることからダブル洗顔が不要であり、敏感肌にも影響のない電解還元水の保湿力により、ジェル状クレンジングを拭き取り後、洗顔しなくても肌がしっとりする。また、洗顔すれば、すすぎ残しもなくさっぱりと仕上がる。さらに、電解水に加水分解卵殻膜成分を併用することで、保湿力が相乗的に高められるだけでなく、肌にハリとツヤを与え、弾力のあるみずみずしい肌に整えられる。 As it is a water-based gel, there is no need for double cleansing, and the moisturizing power of electrolytic reduced water, which is gentle on sensitive skin, means that after wiping off the gel cleanser, your skin will be moisturized even without washing your face. Also, if you wash your face, it will leave you feeling refreshed without leaving any residue behind. Furthermore, by combining electrolytic water with hydrolyzed eggshell membrane ingredients, not only is the moisturizing power increased synergistically, but it also gives the skin firmness and shine, leaving it looking elastic and moisturized.

さらに、主原料の水として、アルカリ性の電解還元水に、3室型電解装置のアノード室に生成する酸性の酸化水を混合して用いることにより、酸化水による殺菌、除菌効果や肌再生効果を付与することができ、界面活性剤の含有量が少量でも皮膚の殺菌性を向上させることができる。また、酸性の酸化水を混合することでpHを低下させることができるため、保存安定性が向上し、皮膚への刺激も少なくなる。
このように、本発明のジェル状クレンジング化粧料は、洗浄力と美容効果において画期的であり、鉱物油や1価アルコールを含有しないため、敏感肌にも悪影響を与えることがない。
Furthermore, by mixing alkaline electrolytic reduced water with acidic oxidized water generated in the anode chamber of a three-chamber electrolysis device as the main raw water, it is possible to impart the sterilizing and disinfecting effects and skin regeneration effects of the oxidized water, and it is possible to improve the sterilizing properties of the skin even with a small amount of surfactant content. In addition, since the pH can be lowered by mixing acidic oxidized water, the storage stability is improved and irritation to the skin is reduced.
As described above, the gel-type cleansing cosmetic composition of the present invention is revolutionary in terms of its cleansing power and cosmetic effects, and since it does not contain mineral oil or monohydric alcohol, it does not adversely affect sensitive skin.

本発明のジェル状クレンジング化粧料は、水性ジェルの主原料の水として、3室型電解水であるアルカリ性の3室型電解還元水を用い、加水分解卵殻膜成分を含有することを特徴とする。
本発明におけるアルカリ性の3室型電解還元水とは、3室型電解水生成装置のカソード室(陰極室)で生成するアルカリ性の還元水を意味する。
The gel-type cleansing cosmetic of the present invention is characterized in that it uses alkaline three-compartment electrolyzed reduced water, which is three-compartment electrolyzed water, as the main raw water of the aqueous gel, and contains a hydrolyzed eggshell membrane component.
The alkaline three-compartment electrolytic reduced water in the present invention means alkaline reduced water generated in the cathode chamber (negative electrode chamber) of a three-compartment electrolytic water generating device.

3室型電解水生成装置は従来から知られており(例えば特許文献3~5を参照)、その基本的な構造は、精製水や純水である原水と、この原水に溶け込んだ塩化ナトリウム等の支持電解質が循環して流出入する中間室と、この中間室との間にイオン交換膜と陰極が仕切りとして配設され、中間室で電気分解を行うことにより、供給された原水にプラスイオンが溶け込み還元水が生成されるカソード室と、中間室との間にイオン交換膜と陽極が仕切りとして配設され、中間室に支持電解質を供給して電気分解を行うことにより、供給された原水にマイナスイオンが溶け込み酸化水が生成されるアノード室とから構成される。 Three-chamber electrolytic water generators have been known for some time (see, for example, Patent Documents 3 to 5), and their basic structure consists of an intermediate chamber where purified water or pure water and supporting electrolytes such as sodium chloride dissolved in the raw water circulate and flow in and out, a cathode chamber where an ion exchange membrane and a cathode are arranged as partitions between the intermediate chamber and the cathode chamber, where positive ions are dissolved in the supplied raw water by electrolysis in the intermediate chamber to produce reduced water, and an anode chamber where an ion exchange membrane and an anode are arranged as partitions between the intermediate chamber and the anode chamber, where a supporting electrolyte is supplied to the intermediate chamber and electrolysis is performed in which negative ions are dissolved in the supplied raw water to produce oxidized water.

3室型電解水生成装置は、中間室に用途に応じたイオン種を含んだ電解質を添加し、中間室で電解されたイオンだけが、プラスイオンは陰極側のカソード室に、マイナスイオンは陽極側のアノード室に引き込まれる。カソード室とアノード室には純粋な水だけが供給され、中間室に添加された電解質の電解により生じたイオンがカソード室とアノード室で溶け込んで、それぞれで機能的電解水である還元水と酸化水が生成される。
3室型電解水生成装置では電解効率が高まることにより、水の結合が切れて表面張力が下がり浸透性が上がるため、電解質として塩化ナトリウムを添加した場合には、カソード側の還元水は高い洗浄効果をもたらし、アノード側の酸化水は低濃度で殺菌効果をもたらし、この効果は、pHやイオン種、水温などの条件により変わる。
In a three-chamber electrolytic water generator, an electrolyte containing ion species appropriate for the purpose is added to the intermediate chamber, and only the ions electrolyzed in the intermediate chamber are drawn into the cathode chamber on the negative side for positive ions and the anode chamber on the positive side for negative ions. Only pure water is supplied to the cathode chamber and the anode chamber, and the ions generated by electrolysis of the electrolyte added to the intermediate chamber dissolve in the cathode chamber and the anode chamber, producing reduced water and oxidized water, which are functional electrolytic water, respectively.
In a three-chamber electrolyzed water generator, the increased electrolysis efficiency breaks the bonds in the water, lowers the surface tension, and increases permeability. Therefore, when sodium chloride is added as an electrolyte, the reduced water on the cathode side provides a high cleaning effect, while the oxidized water on the anode side provides a sterilizing effect at a low concentration. This effect varies depending on conditions such as pH, ion species, and water temperature.

本発明のジェル状クレンジング化粧料では、水性ジェルの主原料の水として、アルカリ性の3室型電解還元水に、3室型電解装置のアノード室に生成するまたは酸性の酸化水を混合して用いることが好ましい。酸化水による殺菌、除菌効果や肌再生効果が付与されるだけでなく、全体のpHを低下させることでジェル状クレンジング化粧料の保存安定性が高くなり、皮膚への刺激も少なくなる。還元水に混合する酸化水の重量比は、還元水100重量部に対して0~30重量部であり、5~30重量部が好ましく、10~30重量部がより好ましく、20~30重量部がさらに好ましい。 In the gel-type cleansing cosmetic of the present invention, it is preferable to use alkaline three-chamber electrolytic reduced water mixed with acidic oxidized water generated in the anode chamber of a three-chamber electrolytic device as the main water raw material of the aqueous gel. Not only does the oxidized water impart bactericidal, disinfecting and skin regenerating effects, but the storage stability of the gel-type cleansing cosmetic is improved and irritation to the skin is reduced by lowering the overall pH. The weight ratio of oxidized water to be mixed with reduced water is 0 to 30 parts by weight per 100 parts by weight of reduced water, preferably 5 to 30 parts by weight, more preferably 10 to 30 parts by weight, and even more preferably 20 to 30 parts by weight.

本発明のジェル状クレンジング化粧料に用いる3室型電解水の製造に当たっては、従来から知られている3室型電解水生成装置のいずれもが使用できる。限定されるものではないが、本発明では、特に使用可能な3室型電解水生成装置としては、例えば、株式会社レドックス製の3室型電解水生成システム、株式会社レドックス製の3室型ダブルイン電解システム[「kreski AQUA」(Type-α4000A,C,D)など]、株式会社レドックステクノロジー製「レドックスR25-15型」、株式会社ラシーヌ製の3室型電解水生成システムや3室型ダブルイン電解システム、株式会社アルマード社のマルチブル・ポールシステムなどが挙げられる。特に、株式会社アルマード社のマルチブル・ポールシステムでの3室型電解水が好ましい。 Any of the conventionally known three-chamber electrolyzed water generating devices can be used to produce the three-chamber electrolyzed water used in the gel-type cleansing cosmetic of the present invention. Although not limited thereto, examples of three-chamber electrolyzed water generating devices that can be particularly used in the present invention include a three-chamber electrolyzed water generating system manufactured by Redox Co., Ltd., a three-chamber double-in electrolysis system manufactured by Redox Co., Ltd. [such as "kreski AQUA" (Type-α4000A, C, D)], the "Redox R25-15" manufactured by Redox Technology Co., Ltd., a three-chamber electrolyzed water generating system and a three-chamber double-in electrolysis system manufactured by Racine Co., Ltd., and a Multiple Pole system manufactured by Almado Co., Ltd. In particular, a three-chamber electrolyzed water using a Multiple Pole system manufactured by Almado Co., Ltd. is preferred.

3室型電解水生成装置の中間室に供給する支持電解質である塩化ナトリウムの濃度は、3室型電解水生成装置の規模、電解水生成能力、構造、機種の種類などに応じて、それぞれの3室型電解水生成装置において推奨されている濃度を採用することが好ましい。
アノード室とカソード室への水の供給量および中間室への塩化ナトリウム水溶液の供給量も、3室型電解水生成装置の規模、電解水生成能力、構造、機種の種類などに応じて、それぞれの3室型電解水生成装置において推奨されている供給量を採用することが好ましい。
It is preferable to adopt the concentration of sodium chloride, which is the supporting electrolyte to be supplied to the intermediate chamber of a three-chamber electrolytic water generator, that recommended for each three-chamber electrolytic water generator, depending on the size, electrolytic water generation capacity, structure, model type, etc. of the three-chamber electrolytic water generator.
It is preferable to adopt the amounts of water supplied to the anode chamber and the cathode chamber and the amount of aqueous sodium chloride solution supplied to the intermediate chamber that are recommended for each three-chamber electrolytic water generator, depending on the size, electrolytic water generation capacity, structure, and type of model of the three-chamber electrolytic water generator.

それぞれの機種において推奨されている塩化ナトリウム濃度、アノード室とカソード室への純水の供給量および中間室への塩化ナトリウム水溶液の供給量を採用して電解を行うことによって、アノード室にpHが3~7、特に4~6.5程度の酸性の酸化作用を有する酸化水が生成し、カソード室にpHが10~12、特に11~12程度のアルカリ性の還元作用を有する還元水が生成する。 By performing electrolysis using the sodium chloride concentration recommended for each model, the amount of pure water supplied to the anode and cathode chambers, and the amount of aqueous sodium chloride solution supplied to the intermediate chamber, oxidized water with an acidic oxidizing effect and a pH of 3 to 7, especially 4 to 6.5, is generated in the anode chamber, and reduced water with an alkaline reducing effect and a pH of 10 to 12, especially 11 to 12, is generated in the cathode chamber.

また、本発明のジェル状クレンジング化粧料に用いる電解還元水として、3室型電解水生成装置による還元水の生成時の酸化還元電位が-500mV以下、更には-600mV以下、特に-750mV以下の還元水が、還元力が大きくて、洗浄効果に優れるジェル状化粧料が得られる点から好ましく用いられる。
たとえば、3室型電解水生成装置のアノード室およびカソード室に、電気伝導度が0.3μS/cm(20℃)の超純水を供給し、中間質に塩化ナトリウム水溶液を供給して電気分解を行うと、カソード室にpHが11.0以上で、生成時の酸化還元電位が-600mV以下の還元水を生成させることができる。
Furthermore, as the electrolytic reduced water used in the gel-type cleansing cosmetic of the present invention, reduced water having an oxidation-reduction potential of −500 mV or less, preferably −600 mV or less, and particularly −750 mV or less when generated by a three-chamber electrolytic water generator is preferably used, since it has a large reducing power and can produce a gel-type cosmetic with excellent cleansing effect.
For example, if ultrapure water with an electrical conductivity of 0.3 μS/cm (20°C) is supplied to the anode chamber and cathode chamber of a three-chamber electrolytic water generator, and an aqueous sodium chloride solution is supplied to the intermediate to perform electrolysis, reduced water with a pH of 11.0 or higher and an oxidation-reduction potential of -600 mV or lower during generation can be produced in the cathode chamber.

このpH10~12の還元水をpH調整することなくそのまま用いて、ジェル状クレンジング化粧料を製造してもよいが、本発明では、保存安定性に優れ、皮膚への刺激が少ないジェル状クレンジング化粧料が得られるなどの点から、還元水に酸性の酸化水を混合するか、および/またはpH調整剤を添加して、ジェル状クレンジング化粧料のpHを5~8にすることが好ましく、5~7にすることがより好ましく、5.5~6.5にすることが更に好ましい。 This reduced water with a pH of 10 to 12 may be used as is without adjusting the pH to produce a gel-type cleansing cosmetic; however, in the present invention, in order to obtain a gel-type cleansing cosmetic with excellent storage stability and low irritation to the skin, it is preferable to mix acidic oxidized water with the reduced water and/or add a pH adjuster to adjust the pH of the gel-type cleansing cosmetic to 5 to 8, more preferably 5 to 7, and even more preferably 5.5 to 6.5.

pH調整剤としては、例えば、クエン酸とクエン酸ナトリウムなどの有機酸とその塩、炭酸水素ナトリウム、水酸化カリウム、リン酸二水素ナトリウム、リン酸一水素ナトリウムなどを挙げることができ、本発明のジェル状クレンジング化粧料では必要に応じて、これらの1種または2種以上を用いることができる。特に、クエン酸とクエン酸ナトリウムが好ましく用いられる。 Examples of pH adjusters include organic acids and their salts, such as citric acid and sodium citrate, sodium bicarbonate, potassium hydroxide, sodium dihydrogen phosphate, and sodium monohydrogen phosphate. In the gel-type cleansing cosmetic composition of the present invention, one or more of these can be used as necessary. In particular, citric acid and sodium citrate are preferably used.

本発明のジェル状クレンジング化粧料に用いる加水分解卵殻膜成分は、卵殻膜あるいは卵殻膜含有粉末を、酸水溶液、アルカリ水溶液、アルカリ性有機溶媒溶液、およびタンパク質分解酵素含有液などのタンパク質の分解作用を有する液中で加水分解することによって得られる。加水分解卵殻膜成分の製造に用いられる卵殻膜含有粉末は、少なくとも卵殻膜を含む粉末であれば特に制限はなく、粉末とは粒子サイズにかかわらず、あらゆる粉体をいう。剥離された卵殻膜または卵殻に卵殻膜が付着した状態の原料を使用して、公知のいずれの方法で粉末化してもよい。また、市販の卵殻膜含有粉末を用いてもよい。 The hydrolyzed eggshell membrane component used in the gel-type cleansing cosmetic of the present invention is obtained by hydrolyzing eggshell membrane or an eggshell membrane-containing powder in a liquid having a protein decomposing action, such as an acid aqueous solution, an alkaline aqueous solution, an alkaline organic solvent solution, or a liquid containing a protease. The eggshell membrane-containing powder used in the production of the hydrolyzed eggshell membrane component is not particularly limited as long as it is a powder containing at least eggshell membrane, and the term "powder" refers to any powder regardless of particle size. A raw material in the form of peeled eggshell membrane or eggshell with eggshell membrane attached thereto may be powdered by any known method. A commercially available eggshell membrane-containing powder may also be used.

本発明で使用される加水分解卵殻膜成分は,いずれの方法によって製造された加水分解卵殻膜成分を用いることができるが、pHが中性付近の酵素分解卵殻膜成分やアルカリ性付近のアルカリ分解卵殻膜成分が好ましく、また、酵素分解卵殻膜成分とアルカリ分解卵殻膜成分を混合したものも好ましい。 The hydrolyzed eggshell membrane component used in the present invention may be a hydrolyzed eggshell membrane component produced by any method, but an enzymatically decomposed eggshell membrane component with a pH close to neutral or an alkali-decomposed eggshell membrane component with a pH close to alkaline is preferred, and a mixture of an enzymatically decomposed eggshell membrane component and an alkali-decomposed eggshell membrane component is also preferred.

本発明のジェル状クレンジング化粧料は、化粧品を浮かせて取り、毛穴まで浸透して黒ずみをケアすることができる洗浄力と保湿力と、肌にハリとツヤを与える効果を高めるために、ジェル状クレンジング化粧料の全重量に基づいて、3室型電解水を40~90重量%、加水分解卵殻膜成分を0.0001~2重量%の割合で含有することが好ましく、より好ましくは3室型電解水を60~75重量%、加水分解卵殻膜成分を0.001~1重量%の割合で含有し、さらに好ましくは3室型電解水を70重量%前後の割合で含有させる。 The gel-type cleansing cosmetic of the present invention preferably contains 40 to 90% by weight of three-chamber electrolyzed water and 0.0001 to 2% by weight of hydrolyzed eggshell membrane components based on the total weight of the gel-type cleansing cosmetic, more preferably 60 to 75% by weight of three-chamber electrolyzed water and 0.001 to 1% by weight of hydrolyzed eggshell membrane components, and even more preferably contains around 70% by weight of three-chamber electrolyzed water, based on the total weight of the gel-type cleansing cosmetic, in order to enhance the cleansing and moisturizing power that can lift and remove cosmetics and penetrate into pores to treat dark spots, as well as the effect of giving firmness and luster to the skin.

本発明のジェル状クレンジング化粧料は、上記した成分と共に、ジェル状クレンジング化粧料や美容液において従来から用いられている他の成分を必要に応じて含有することができる。必要に応じて含有し得る他の成分としては、保湿剤、粘結剤、界面活性剤、医薬美容成分、精油、果実エキス、果汁等を挙げることができる。
本発明のジェル状クレンジング化粧料は、敏感肌にも影響を与えないため、鉱物油や1価アルコールを含まないことが好ましく、殺菌性を有する界面活性剤も、最低限の2~10重量%とすることが好ましい。
The gel-type cleansing cosmetic of the present invention may contain, in addition to the above-mentioned components, other components that have been conventionally used in gel-type cleansing cosmetic compositions and beauty serums, as necessary. Examples of other components that may be contained as necessary include moisturizers, binders, surfactants, medicinal and cosmetic ingredients, essential oils, fruit extracts, fruit juices, etc.
The gel-type cleansing cosmetic composition of the present invention preferably does not contain mineral oil or monohydric alcohol so as not to affect sensitive skin, and the content of a surfactant having bactericidal properties is preferably kept to a minimum of 2 to 10% by weight.

保湿剤、粘結剤としては、アラニン、セリン、ロイシン、イソロイシン、スレオニン、グリシン、プロリン、ヒドロキシプロリン、グルコサミン、テアニンなどのアミノ酸及びその誘導体;コラーゲン、コラーゲンペプチド、ゼラチン等のペプチド;グリセリン、1,3-ブチレングリコール、ジプロピレングリコール、ジプロピレングリコール-14ポリグリセリン-2エーテル、ペンチレングリコール、ポリエチレングリコールなどの多価アルコール;ソルビトール、グリセリルグルコシドなどの糖アルコール;ヒアルロン酸プロピレングリコール、ヘパリン、コンドロイチン等のムコ多糖;乳酸、ピロリドンカルボン酸ナトリウム、ポリクオタニウム-51などの成分等が挙げられる。 Moisturizing agents and binders include amino acids and derivatives thereof such as alanine, serine, leucine, isoleucine, threonine, glycine, proline, hydroxyproline, glucosamine, and theanine; peptides such as collagen, collagen peptides, and gelatin; polyhydric alcohols such as glycerin, 1,3-butylene glycol, dipropylene glycol, dipropylene glycol-14 polyglycerin-2 ether, pentylene glycol, and polyethylene glycol; sugar alcohols such as sorbitol and glyceryl glucoside; mucopolysaccharides such as propylene glycol hyaluronate, heparin, and chondroitin; and ingredients such as lactic acid, sodium pyrrolidone carboxylate, and polyquaternium-51.

界面活性剤は、化粧料に通常用いられるものであれば特に制限されないが、ヤシ油脂肪酸PEG-7グリセリル、PPG-14ジグリセリル、ベタイン、レシチン、水素添加レシチン等が好ましく、他医薬美容成分としては、例えば、ビタミンC、コラーゲン、スクワラン、ヒアルロン酸、ヒアルロン酸誘導体、ナイアシン、プラセンタエキス、キチン、キトサン、カンゾウ根エキス、アロエベラ液汁等の種々の植物抽出物が挙げられる。 The surfactant is not particularly limited as long as it is one that is commonly used in cosmetics, but preferred are PEG-7 glyceryl coconut oil fatty acid, PPG-14 diglyceryl, betaine, lecithin, hydrogenated lecithin, etc., and other medicinal beauty ingredients include, for example, various plant extracts such as vitamin C, collagen, squalane, hyaluronic acid, hyaluronic acid derivatives, niacin, placenta extract, chitin, chitosan, licorice root extract, and aloe vera juice.

精油としては、果実油、果皮油、花油、葉油、たとえばカニナバラ果実油、レモン果皮油、グレープフルーツ果皮油、ユズ果皮油、バラ花油、サルビア油、カミツレ花油、ビャクシン油、マヨラナ葉油等が挙げられ、保湿とキメを整える効果がある。
果実エキス、果汁としては、オレンジ、レモン、グレープフルーツ、ライム、リンゴ、ナツメ、サンザシ等を原料とするもの挙げられ、角質ケアの効果がある。
Examples of essential oils include fruit oils, peel oils, flower oils, and leaf oils, such as rosehip fruit oil, lemon peel oil, grapefruit peel oil, yuzu peel oil, rose flower oil, salvia oil, chamomile flower oil, juniper oil, and marjoram leaf oil, which have moisturizing and skin-texturizing effects.
Fruit extracts and juices include those made from orange, lemon, grapefruit, lime, apple, jujube, hawthorn, etc., and are effective in exfoliating skin.

本発明のジェル状クレンジング化粧料の製造方法は特に制限されない。加水分解卵殻膜成分とそれと共に必要に応じて更に配合される上記した成分の1種または2種以上が、3室型電解水生成装置のカソード室で生成したアルカリ性の還元水を基材とするジェル化物中に均一に混合されたジェル状化粧料を製造し得る方法であれば、いずれの方法で製造してもよい。一般的には、電解水と加水分解卵殻膜成分、保湿剤、粘結剤および必要に応じてその他の成分を同時にまたは任意の順序で配合して水性組成物を調製し、当該水性組成物中の各成分が均一に混合され且つジェル化するまで十分に攪拌混合することによって製造することができる。 The method for producing the gel-type cleansing cosmetic of the present invention is not particularly limited. Any method may be used as long as it is capable of producing a gel-type cosmetic in which the hydrolyzed eggshell membrane component and one or more of the above-mentioned components further blended therewith as necessary are uniformly mixed in a gelled product based on alkaline reduced water generated in the cathode chamber of a three-chamber electrolyzed water generator. In general, the gel-type cosmetic can be produced by blending electrolyzed water, the hydrolyzed eggshell membrane component, a moisturizing agent, a binder, and other components as necessary simultaneously or in any order to prepare an aqueous composition, and thoroughly stirring and mixing the components in the aqueous composition until they are uniformly mixed and gelled.

以下に本発明を実施例などにより具体的に説明するが、本発明は以下の例により何ら限定されない。
〔実施例1〕
株式会社アルマード社製の3室型電解装置マルチブル・ポールシステムのカソード室で生成した還元水(温度25℃でpH11)にアノード室で生成した酸化水(温度25℃でpH5)を8:2の割合で混合した電解水73.5重量%に対して、酵素加水分解卵殻膜成分(株式会社アルマード社製)0.012重量%と、下記の表1に記載した成分を、表1に記載した量で配合し、温度25℃で均一になるまで混合して、還元水を基材とするpH6のジェル状クレンジング化粧料を製造した。
The present invention will be described in detail below with reference to examples, but the present invention is not limited to the following examples in any way.
Example 1
Reduced water (pH 11 at 25° C.) produced in the cathode chamber of a three-chamber electrolysis device Multiple Pole System manufactured by Almado Co., Ltd. was mixed with oxidized water (pH 5 at 25° C.) produced in the anode chamber in a ratio of 8:2 to obtain 73.5% by weight of electrolyzed water. 0.012% by weight of an enzymatically hydrolyzed eggshell membrane component (manufactured by Almado Co., Ltd.) and the components shown in Table 1 below were blended in the amounts shown in Table 1 and mixed until uniform at 25° C. to produce a gel-type cleansing cosmetic product with a pH of 6 based on reduced water.

[表1] ジェル状クレンジング化粧料の配合
成分 配合量(重量%)
電解水 73.5
加水分解卵殻膜成分 0.012
ヤシ油脂肪酸PEG-7グリセリル 9.5
ジプロピレングリコール(DPG) 6.5
DPG-14ポリグリセリン-2エーテル 5.5
ペンチレングリコール 4.5
各種微量成分 計0.488
合計 100

(注:微量成分は、各種アミノ酸、果実エキス、果実油、植物抽出物、pH調整剤等であり、各種微量成分の全てが0.1重量%以下の配合である。)
[Table 1] Composition of gel-type cleansing cosmetic composition Component Amount (wt%)
Electrolyzed water 73.5
Hydrolyzed eggshell membrane component 0.012
Coconut oil fatty acid PEG-7 glyceryl 9.5
Dipropylene glycol (DPG) 6.5
DPG-14 Polyglycerin-2 Ether 5.5
Pentylene glycol 4.5
Various trace components total 0.488
Total 100

(Note: Trace ingredients include various amino acids, fruit extracts, fruit oils, plant extracts, pH adjusters, etc., and all trace ingredients are contained at less than 0.1% by weight.)

〔比較例1〕
実施例1において、電解水73.5重量%の代わりに精製水73.5重量%を用い、それ以外の配合は実施例1と同じに行って、加水分解卵殻膜成分を含有し精製水を基材とするジェル状クレンジング化粧料を製造した。
Comparative Example 1
In Example 1, 73.5 wt% purified water was used instead of 73.5 wt% electrolyzed water, and the other formulation was the same as in Example 1 to produce a gel-type cleansing cosmetic containing hydrolyzed eggshell membrane components and based on purified water.

〔評価方法1〕
メイクをした15名の女性をパネラーとし、実施例1と比較例1の各ジェル状クレンジング化粧料を、パネラーにはどちらのジェル状クレンジング化粧料であるかを知らせずに、パネラーの顔の左側と右側に別々に使用してもらった。下記の評価基準により、各ジェル状クレンジング化粧料を評価した。
下記の基準で評価した15名の合計点を求めて、結果を表2中に表示した。
[Evaluation Method 1]
Fifteen women wearing makeup were used as panelists, and the panelists were asked to apply the gel-type cleansing cosmetic compositions of Example 1 and Comparative Example 1 separately to the left and right sides of their faces, without being informed of which gel-type cleansing cosmetic composition they were using. Each gel-type cleansing cosmetic composition was evaluated according to the following evaluation criteria.
The total score of the 15 people who evaluated the product based on the following criteria was calculated, and the results are shown in Table 2.

〔評価基準〕
(1)メイクとのなじみ
2点:メイクとのなじみが速い
1点:メイクとなじむまでやや時間がかかる
0点:メイクとなじむのが明らかに遅い
(2)メイクの浮き上がり
2点:メイクの浮き上がりがよい
1点:メイクが少し浮き上がる
0点:メイクが浮き上がる感じがしない
(3)洗浄効果
使用して30秒後にコットンで軽く拭き取り、メイクの落ちを評価した。
2点:メイクが十分に落ちた
1点:メイクが大体落ちた
0点:メイクの落ちが悪いと感じた
[Evaluation Criteria]
(1) Blending with makeup 2 points: Blends with makeup quickly 1 point: Takes some time to blend with makeup 0 point: Blends with makeup significantly slower (2) Makeup removal 2 points: Removes makeup well 1 point: Removes makeup a little 0 point: Does not feel like makeup is removed (3) Cleansing effect After 30 seconds of use, the product was lightly wiped off with cotton and the makeup removal was evaluated.
2 points: Makeup was removed sufficiently 1 point: Makeup was mostly removed 0 point: I felt that the makeup was not removed well

(4)洗い流し時のべたつき
使用して30秒後に洗い流し、その時のべたつき感を評価した。
2点:べたつきを感じない
1点:べたつきをやや感じる
0点:かなりべたつきを感じる
(5)使用直後の保湿感
使用して30秒後に洗い流し、タオルドライをした時の保湿感を評価した。
2点:保湿感がある
1点:保湿感がややある
0点:保湿感がない
(6)毛穴の黒ずみ
使用して30秒後に洗い流した後の、毛穴の黒ずみを比較した。
2点:実施例1のクレンジングの方が黒ずみが薄い
1点:どちらも変わらない
0点:比較例1のクレンジングの方が黒ずみが薄い
(7)翌朝の肌の状態(ハリとキメ)
使用して30秒後に洗い流し、タオルドライをした。化粧水や乳液等を使用するスキンケアは行わずに、翌朝の肌の状態について比較した。
2点:実施例1のクレンジングの方が肌の状態が良い
1点:どちらも変わらない
0点:比較例1のクレンジングの方が肌の状態が良い
(4) Stickiness upon rinsing The product was rinsed off 30 seconds after use, and the stickiness felt at that time was evaluated.
2 points: no stickiness felt 1 point: some stickiness felt 0 point: very sticky felt (5) Moisturizing sensation immediately after use The moisturizing sensation was evaluated after rinsing 30 seconds after use and drying with a towel.
2 points: Moisturizing feeling is felt 1 point: Slightly moisturizing feeling is felt 0 point: No moisturizing feeling is felt (6) Darkening of pores The degree of darkening of pores was compared after rinsing 30 seconds after application.
2 points: The cleansing product in Example 1 caused less dark spots. 1 point: No difference between the two.
0 points: The cleansing product of Comparative Example 1 caused less dark spots. (7) Skin condition the next morning (firmness and texture)
Thirty seconds after application, the skin was washed off and towel-dried. The skin condition the following morning was compared without any skin care using lotion or milky lotion.
2 points: The cleansing agent of Example 1 is in a better condition for the skin. 1 point: No difference between the two. 0 point: The cleansing agent of Comparative Example 1 is in a better condition for the skin.

表2の結果から、3室型電解還元水を主原料とする実施例1のジェル状クレンジング化粧料は、電解水による殺菌、除菌力、洗浄力により、全ての洗浄効果がアップすることがわかる。また、保湿効果のある還元水と加水分解卵殻膜成分の併用により、特に保湿力と肌の状態が相乗的に向上し、還元水が毛穴まで浸透して黒ずみをケアし、加水分解卵殻膜成分が毛穴まで作用して、肌の状態がより整えられることがわかった。 The results in Table 2 show that the gel-type cleansing cosmetic of Example 1, which uses three-chamber electrolytic reduced water as its main ingredient, improves all of the cleansing effects due to the bactericidal, disinfecting, and cleansing power of the electrolytic water. In addition, the combined use of reduced water, which has a moisturizing effect, and hydrolyzed eggshell membrane ingredients synergistically improves moisturizing power and skin condition in particular, with the reduced water penetrating into the pores to treat dark spots, and the hydrolyzed eggshell membrane ingredients acting on the pores to improve skin condition.

〔比較例2〕
実施例1において、加水分解卵殻膜成分を配合せず、それ以外の配合は実施例1と同じに行って、加水分解卵殻膜成分を含有しない電解水を基材とするジェル状クレンジング化粧料を製造した。
〔評価方法2〕
評価方法1を行なった3日後に、メイクをした評価方法1と同じ15名の女性をパネラーとし、実施例1と比較例2の各ジェル状クレンジング化粧料を、パネラーにはどちらのジェル状クレンジング化粧料であるかを知らせずに、パネラーの顔の左側と右側に別々に使用してもらった。評価方法1と同じ上記の評価基準(5)と、下記の評価基準(6)、(7)により、各ジェル状クレンジング化粧料を評価して15名の合計点を求めた。結果を表3中に示す。
Comparative Example 2
In Example 1, the hydrolyzed eggshell membrane component was not added, but the other components were the same as in Example 1, and a gel-type cleansing cosmetic was produced using electrolyzed water as a base that did not contain a hydrolyzed eggshell membrane component.
[Evaluation Method 2]
Three days after carrying out Evaluation Method 1, the same 15 female panelists as in Evaluation Method 1, who were wearing makeup, were asked to apply each of the gel-type cleansing cosmetics of Example 1 and Comparative Example 2 to the left and right sides of their faces, respectively, without informing the panelists which gel-type cleansing cosmetic they were using. Each gel-type cleansing cosmetic was evaluated according to the above-mentioned evaluation criteria (5) as in Evaluation Method 1, and the following evaluation criteria (6) and (7), and the total score of the 15 panelists was calculated. The results are shown in Table 3.

(6)毛穴の黒ずみ
使用して30秒後に洗い流した後の、毛穴の黒ずみを比較した。
2点:実施例1のクレンジングの方が黒ずみが薄い
1点:どちらも変わらない
0点:比較例2のクレンジングの方が黒ずみが薄い
(7)翌朝の肌の状態(ハリとキメ)
使用して30秒後に洗い流し、タオルドライをした。化粧水や乳液等を使用するスキンケアは行わずに、翌朝の肌の状態について比較した。
2点:実施例1のクレンジングの方が肌の状態が良い
1点:どちらも変わらない
0点:比較例2のクレンジングの方が肌の状態が良い
(6) Darkening of pores After rinsing 30 seconds after use, the degree of darkening of pores was compared.
2 points: The cleansing product in Example 1 caused less dark spots. 1 point: No difference between the two.
0 points: The cleansing product of Comparative Example 2 caused less dark spots. (7) Skin condition the next morning (firmness and texture)
Thirty seconds after application, the skin was washed off and towel-dried. The skin condition the following morning was compared without any skin care using lotion or milky lotion.
2 points: The cleansing agent of Example 1 is in a better condition for the skin. 1 point: No difference between the two. 0 point: The cleansing agent of Comparative Example 2 is in a better condition for the skin.

表2により、実施例1のジェル状クレンジング化粧料が、電解水による殺菌、除菌力、洗浄力によって全ての洗浄効果において、効果がアップすることが確認された。ここでは、電解水と加水分解卵殻膜成分の相乗効果について検討した。還元水が毛穴に浸透して黒ずみをケアすることから、黒ずみについては実施例1と比較例2で、それ程変化はなかった。一方、保湿感と肌の状態については、実施例1と比較例1、2の結果から、電解水と加水分解卵殻膜成分の相乗効果が確認された。特に肌の状態について実施例1が優れており、還元水が毛穴まで浸透し、加水分解卵殻膜成分が毛穴まで作用して、肌の状態がより整えられるためと説明される。

From Table 2, it was confirmed that the gel-type cleansing cosmetic of Example 1 has improved cleaning effects in all respects due to the bactericidal, antibacterial, and cleaning power of electrolytic water. Here, the synergistic effect of electrolytic water and hydrolyzed eggshell membrane component was examined. Since reduced water penetrates into pores to care for dark spots, there was not much change in dark spots between Example 1 and Comparative Example 2. On the other hand, the results of Example 1 and Comparative Examples 1 and 2 confirmed the synergistic effect of electrolytic water and hydrolyzed eggshell membrane component in terms of moisturizing feeling and skin condition. In particular, Example 1 is superior in terms of skin condition, which is explained by the fact that reduced water penetrates into pores and hydrolyzed eggshell membrane component acts on pores to improve skin condition.

Claims (7)

主成分としての3室型電解水と、加水分解卵殻膜成分とを含有し、3室型電解水がアルカリ性の3室型電解還元水と酸性の3室型電解酸化水の混合水である、ジェル状クレンジング化粧料。 The gel-type cleansing cosmetic contains three-chamber electrolyzed water as main ingredients and a hydrolyzed eggshell membrane component, the three-chamber electrolyzed water being a mixture of alkaline three-chamber electrolyzed reduced water and acidic three-chamber electrolyzed oxidized water. 前記3室型電解水を40~90重量%、前記加水分解卵殻膜成分を0.0001~2重量%含有する、請求項1に記載のジェル状クレンジング化粧料。 The gel-type cleansing cosmetic according to claim 1 contains 40 to 90% by weight of the three-chamber electrolyzed water and 0.0001 to 2% by weight of the hydrolyzed eggshell membrane component. 前記3室型電解還元水が、アノード電極を備えるアノード室と、カソード電極を備えるカソード室と、アノード室とカソード室との間に設けられた中間室と、アノード室と中間室との間に配置された隔膜と、カソード室と中間室との間に配置された隔膜を備える3室型電解水生成装置を使用して、そのアノード室およびカソード室のそれぞれに水を供給し、中間室に塩化ナトリウム水溶液を供給して電気分解を行うことによってカソード室に生成させた還元水である、請求項またはに記載のジェル状クレンジング化粧料。 3. The gel-type cleansing cosmetic preparation according to claim 1 or 2, wherein the three-chamber electrolyzed reduced water is reduced water generated in the cathode chamber by using a three-chamber electrolyzed water generating device comprising an anode chamber having an anode electrode, a cathode chamber having a cathode electrode, an intermediate chamber provided between the anode chamber and the cathode chamber, a diaphragm disposed between the anode chamber and the intermediate chamber, and a diaphragm disposed between the cathode chamber and the intermediate chamber, supplying water to each of the anode chamber and the cathode chamber, and supplying an aqueous sodium chloride solution to the intermediate chamber to perform electrolysis. 前記加水分解卵殻膜成分が酵素分解卵殻膜成分および/またはアルカリ分解卵殻膜成分である、請求項1ないしのいずれかに記載のジェル状クレンジング化粧料。 4. The gel-type cleansing cosmetic preparation according to claim 1 , wherein the hydrolyzed eggshell membrane component is an enzymatically decomposed eggshell membrane component and/or an alkali decomposed eggshell membrane component. さらに界面活性剤を2~10重量%含有する、請求項1ないしのいずれかに記載のジェル状クレンジング化粧料。 5. The gel-type cleansing cosmetic composition according to claim 1, further comprising 2 to 10% by weight of a surfactant. 鉱物油と1価アルコールを含有しない、請求項1ないしのいずれかに記載のジェル状クレンジング化粧料。 6. The gel-type cleansing cosmetic preparation according to claim 1, which contains no mineral oil and no monohydric alcohol. pHが5~7である、請求項1ないしのいずれかに記載のジェル状クレンジング化粧料。 7. The gel-type cleansing cosmetic preparation according to claim 1, which has a pH of 5 to 7.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006225273A (en) 2005-02-15 2006-08-31 Natural:Kk Method for producing face washing agent using ionized alkaline water
JP5253483B2 (en) 2010-11-15 2013-07-31 株式会社レドックス Electrolyzer
JP2019137634A (en) 2018-02-09 2019-08-22 株式会社 アルマード Cosmetic liquid containing hydrolyzed eggshell membrane component
JP2019198260A (en) 2018-05-16 2019-11-21 株式会社モトイ Method for producing eggshell membrane protein soluble product, and composition containing eggshell membrane protein soluble product

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006225273A (en) 2005-02-15 2006-08-31 Natural:Kk Method for producing face washing agent using ionized alkaline water
JP5253483B2 (en) 2010-11-15 2013-07-31 株式会社レドックス Electrolyzer
JP2019137634A (en) 2018-02-09 2019-08-22 株式会社 アルマード Cosmetic liquid containing hydrolyzed eggshell membrane component
JP2019198260A (en) 2018-05-16 2019-11-21 株式会社モトイ Method for producing eggshell membrane protein soluble product, and composition containing eggshell membrane protein soluble product

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
アルマード,CELLULA(チェルラー)パーフェクトクレンジングジェル,Cosmetic-Info.jp,2019年09月02日,http://www.cosmetic-info.jp//prod/detail.php?=75041
卵殻膜×特許取得の電解水!?『チェルラーパーフェクトクレンジングジェル』はダブル洗顔不要の大人気クレンジング♪,[online],2016年06月30日,[令和6年7月16日検索],インターネット<URL:https://fanblogs.jp/biyoumonitor/archive/382/0#more>

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