JP7582823B2 - Li超イオン伝導体としてのリチウムカリウム元素酸化物化合物、固体電解質、ならびにリチウム金属電池およびリチウムイオン電池のための被覆層 - Google Patents

Li超イオン伝導体としてのリチウムカリウム元素酸化物化合物、固体電解質、ならびにリチウム金属電池およびリチウムイオン電池のための被覆層 Download PDF

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JP7582823B2
JP7582823B2 JP2020153091A JP2020153091A JP7582823B2 JP 7582823 B2 JP7582823 B2 JP 7582823B2 JP 2020153091 A JP2020153091 A JP 2020153091A JP 2020153091 A JP2020153091 A JP 2020153091A JP 7582823 B2 JP7582823 B2 JP 7582823B2
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lithium ion
lithium
ion electrolyte
battery
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ムォ・イーフェイ
バイ・チィアン
ホー・シンフェン
リン・チェン
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トヨタ モーター エンジニアリング アンド マニュファクチャリング ノース アメリカ,インコーポレイティド
ユニバーシティ オブ メリーランド, カレッジ パーク
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    • C01G55/00Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
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    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562Solid materials
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    • H01M4/02Electrodes composed of, or comprising, active material
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    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
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    • H01M4/36Selection of substances as active materials, active masses, active liquids
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    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
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    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
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JP2020153091A 2019-09-13 2020-09-11 Li超イオン伝導体としてのリチウムカリウム元素酸化物化合物、固体電解質、ならびにリチウム金属電池およびリチウムイオン電池のための被覆層 Active JP7582823B2 (ja)

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Application Number Priority Date Filing Date Title
US16/570,888 US11018375B2 (en) 2019-09-13 2019-09-13 Lithium potassium element oxide compounds as Li super-ionic conductor, solid electrolyte and coating layer for lithium metal battery and lithium-ion battery
US16/570,888 2019-09-13

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JP2021048127A JP2021048127A (ja) 2021-03-25
JP2021048127A5 JP2021048127A5 (https=) 2022-08-01
JP7582823B2 true JP7582823B2 (ja) 2024-11-13

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CN112186242B (zh) * 2020-09-29 2022-04-15 清华大学深圳国际研究生院 无机氧化物固态电解质材料、制备方法、锂离子电池及电子装置
JP2023080494A (ja) * 2021-11-30 2023-06-09 国立大学法人信州大学 イリジウム固溶マンガン酸化物

Citations (1)

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Publication number Priority date Publication date Assignee Title
WO2013137224A1 (ja) 2012-03-15 2013-09-19 株式会社 村田製作所 全固体電池およびその製造方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4668593A (en) 1986-08-29 1987-05-26 Eltron Research, Inc. Solvated electron lithium electrode for high energy density battery
DE102004010892B3 (de) 2004-03-06 2005-11-24 Christian-Albrechts-Universität Zu Kiel Chemisch stabiler fester Lithiumionenleiter
US7300722B2 (en) * 2005-04-11 2007-11-27 The Gillette Company Lithium battery containing bismuth metal oxide
US8784512B2 (en) 2007-08-13 2014-07-22 University Of Virginia Patent Foundation Thin film battery synthesis by directed vapor deposition
JP5298558B2 (ja) * 2007-08-30 2013-09-25 ソニー株式会社 二次電池用負極およびその製造方法、二次電池およびその製造方法、ならびに電子機器
JP5525388B2 (ja) 2009-09-03 2014-06-18 日本碍子株式会社 セラミックス材料及びその製造方法
DE102011013018B3 (de) 2011-03-04 2012-03-22 Schott Ag Lithiumionen leitende Glaskeramik und Verwendung der Glaskeramik
CN103000934B (zh) * 2011-09-16 2016-03-30 苏州宝时得电动工具有限公司 锂硫电池
US9070950B2 (en) 2012-03-26 2015-06-30 Semiconductor Energy Laboratory Co., Ltd. Power storage element, manufacturing method thereof, and power storage device
CN104078647B (zh) * 2013-03-27 2016-04-27 比亚迪股份有限公司 一种锂离子电池负极及其制备方法和锂离子电池
JP2016091995A (ja) 2014-10-30 2016-05-23 株式会社デンソー リチウム空気電池及びリチウム空気電池装置
US10446872B2 (en) * 2015-08-04 2019-10-15 Samsung Electronics Co., Ltd. Solid electrolyte and lithium battery including the same
DE102015217749A1 (de) * 2015-09-16 2017-03-16 Robert Bosch Gmbh Beschichtetes Kathodenaktivmaterial für eine Batteriezelle
FR3046498B1 (fr) 2015-12-31 2019-11-29 I-Ten Batterie entierement solide comprenant un electrolyte solide et une couche de materiau conducteur ionique
CN106229447A (zh) * 2016-08-10 2016-12-14 东莞永蓝电子科技有限公司 一种锂离子电池
CN208489305U (zh) * 2018-06-27 2019-02-12 江西星盈科技有限公司 一种由复合型固态电解质组成的全固态锂电池

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013137224A1 (ja) 2012-03-15 2013-09-19 株式会社 村田製作所 全固体電池およびその製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
BAI, Qiang,First Principles Computational Design of Solid Ionic Conductors through Ion Substitution,Digital Repositry at the University of Maryland,2019年01月01日

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JP2021048127A (ja) 2021-03-25
CN112510252B (zh) 2024-05-24
CN112510252A (zh) 2021-03-16
US20210083319A1 (en) 2021-03-18
DE102020123739A1 (de) 2021-03-18
US11018375B2 (en) 2021-05-25

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