JP7294803B2 - Stretch fabrics and their textile products - Google Patents

Stretch fabrics and their textile products Download PDF

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JP7294803B2
JP7294803B2 JP2018242132A JP2018242132A JP7294803B2 JP 7294803 B2 JP7294803 B2 JP 7294803B2 JP 2018242132 A JP2018242132 A JP 2018242132A JP 2018242132 A JP2018242132 A JP 2018242132A JP 7294803 B2 JP7294803 B2 JP 7294803B2
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博樹 島田
憲二 岩下
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Description

本発明は、難燃性、伸縮性及び高い制電性を有するストレッチ布帛、および該ストレッチ布帛を用いてなる繊維製品に関する。 TECHNICAL FIELD The present invention relates to a stretch fabric having flame retardancy, stretchability and high antistatic properties, and a textile product using the stretch fabric.

従来、消防、電力、化学会社など火炎に晒される可能性のある作業に従事する人々が着用する作業服として難燃布帛が用いられている。この難燃布帛は、メタ系アラミド繊維やパラ系アラミド繊維をはじめとする難燃性繊維を主体として使用しており、一般的には伸縮性の付与は難しいとされている。 BACKGROUND ART Conventionally, flame-retardant fabrics have been used as work clothes worn by people engaged in work that may be exposed to fire, such as firefighting, electric power, and chemical companies. This flame-retardant fabric mainly uses flame-retardant fibers such as meta-aramid fibers and para-aramid fibers, and it is generally considered difficult to impart stretchability to the fabric.

従来のアラミド繊維を用いたストレッチ布帛として、特許文献1には、アラミド繊維とその他の繊維と制電繊維とが混紡された紡績糸と、伸縮繊維とを合撚した合撚糸を用いた難燃ストレッチ織物が提案されている。しかしながら、従来のストレッチ布帛では伸縮性やピリング性は改善されたものの、市場の要求に対して難燃性や制電性等、更なる性能向上する余地があった。 As a stretch fabric using conventional aramid fibers, Patent Document 1 discloses a flame-retardant fabric using a spun yarn in which aramid fibers, other fibers, and antistatic fibers are blended, and a plied yarn in which stretchable fibers are fused and twisted. Stretch fabrics have been proposed. However, although stretchability and pilling resistance have been improved in conventional stretch fabrics, there is still room for further performance improvements, such as flame retardancy and antistatic properties, to meet market demands.

特開2014-208930号公報JP 2014-208930 A

本発明は上記の背景に鑑みなされたものであり、難燃性と伸縮性に加えて優れた制電性を有するストレッチ布帛およびそれを用いてなる繊維製品を提供することにある。 The present invention has been made in view of the above background, and it is an object of the present invention to provide a stretch fabric having excellent antistatic properties in addition to flame retardance and stretchability, and a textile product using the stretch fabric.

本発明者らは上記の課題を達成するため鋭意検討した結果、難燃性繊維を含む紡績糸と、導電糸と、伸縮糸とを用いることによって難燃性、伸縮性および制電性に優れる布帛が得られることを見出し、さらに鋭意検討を重ねることにより本発明を完成するに至った。 As a result of intensive studies by the present inventors in order to achieve the above problems, the use of a spun yarn containing a flame-retardant fiber, a conductive yarn, and a stretch yarn has excellent flame retardancy, stretchability, and antistatic properties. The present inventors have found that a fabric can be obtained, and have completed the present invention through extensive research.

本発明によれば、JISK7201により測定される限界酸素指数が25以上の難燃性繊維を含む紡績糸と、導電糸と、伸縮糸とを用いた布帛であって、当該布帛は、JISL1096法により測定される伸び率が5~40%であり、かつ、JISL1094法に規定される帯電電荷量が6.0マイクロクーロン以下であるストレッチ布帛が提供される。 According to the present invention, a fabric using a spun yarn containing a flame-retardant fiber having a limiting oxygen index of 25 or more as measured by JIS K7201, a conductive yarn, and a stretch yarn, wherein the fabric is prepared according to the JIS L1096 method. Provided is a stretch fabric having a measured elongation of 5 to 40% and a charge amount of 6.0 microcoulombs or less as defined by JISL1094.

その際、難燃性繊維を含む紡績糸と、難燃性繊維を含む紡績糸と導電糸を用いた導電性難燃複合糸とを経糸とし、難燃性繊維を含む紡績糸と伸縮繊維を用いた伸縮性難複合糸とを緯糸とすることが好ましく、難燃性繊維と導電繊維を含む紡績糸と、難燃性繊維を含む紡績糸と導電糸を用いた導電性難燃複合糸とを経糸とし、難燃性繊維と導電繊維を含む紡績糸と伸縮繊維を用いた伸縮性難燃複合糸を緯糸とすることも好ましい、前記導電性複合糸は、布帛伸縮時5~50mmのピッチで経糸中に配設されることも好ましい、JISL1094法に規定される帯電電荷量が4.0マイクロクーロン以下であることも好ましい、難燃性繊維の重量比が布帛重量に対して40重量%以上であり、伸縮繊維の重量比が布帛重量に対して0.1~5重量%であり、導電糸及び/または導電繊維の重量比が布帛重量に対して0.1~5重量%であることも好ましい、JISL1091A-4-1992法で規定される炭化長が100mm以下、かつ、残炎及び残塵が2秒以下であることも好ましい、紡績糸の撚係数が2.5~4.5であることも好ましい、難燃性繊維が、メタ系アラミド繊維、パラ系アラミド繊維、ポリパラフェニレンベンズオキサゾール繊維、ポリベンゾイミダゾール繊維、ポリイミド繊維、ポリエーテルイミド繊維、ポリアミドイミド繊維、炭素繊維、ポリフェニレンサルファイド繊維、ポリ塩化ビニル繊維、難燃レーヨン、モダアクリル繊維、難燃アクリル繊維、難燃ポリエステル繊維、難燃ビニロン繊維、メラミン繊維、フッ素繊維、難燃ウール、難燃コットンの群から選ばれた1種類以上の繊維であることも好ましい、伸縮繊維が、エーテル系ポリウレタンを含むことも好ましい、難燃性繊維に難燃剤が練りこまれていることも好ましい、JISL1096B法で規定される経方向および/または緯方向の伸長率が5~20%であることも好ましい。 At that time, the spun yarn containing the flame-retardant fiber and the spun yarn containing the flame-retardant fiber and the conductive flame-retardant composite yarn using the conductive yarn are used as warp yarns, and the spun yarn containing the flame-retardant fiber and the stretchable fiber are used. The stretchable flame-retardant composite yarn used is preferably used as weft yarn, and a spun yarn containing a flame-retardant fiber and a conductive fiber, and a conductive flame-retardant composite yarn using a spun yarn containing a flame-retardant fiber and a conductive yarn. It is also preferable to use a stretchable flame-retardant composite yarn using a spun yarn containing a flame-retardant fiber and a conductive fiber and a stretchable fiber as a weft yarn, and the conductive composite yarn has a pitch of 5 to 50 mm when the fabric is stretched. It is also preferable that the warp is arranged in the warp, and it is also preferable that the charge amount specified in the JISL1094 method is 4.0 microcoulombs or less. The weight ratio of the flame-retardant fiber is 40% by weight with respect to the fabric weight. The weight ratio of the stretchable fiber is 0.1 to 5% by weight with respect to the weight of the fabric, and the weight ratio of the conductive yarn and/or conductive fiber is 0.1 to 5% by weight based on the weight of the fabric. It is also preferable that the char length defined by the JISL1091A-4-1992 method is 100 mm or less, and the afterflame and dust are 2 seconds or less, and the twist factor of the spun yarn is 2.5 to 4.5. It is also preferable that the flame-retardant fiber is meta-aramid fiber, para-aramid fiber, polyparaphenylene benzoxazole fiber, polybenzimidazole fiber, polyimide fiber, polyetherimide fiber, polyamideimide fiber, carbon fiber, polyphenylene 1 selected from the group of sulfide fiber, polyvinyl chloride fiber, flame-retardant rayon, modacrylic fiber, flame-retardant acrylic fiber, flame-retardant polyester fiber, flame-retardant vinylon fiber, melamine fiber, fluorine fiber, flame-retardant wool, flame-retardant cotton It is also preferable that the fibers are more than one type, it is preferable that the stretchable fibers contain ether-based polyurethane, it is also preferable that the flame-retardant fiber is kneaded with a flame retardant, and the warp direction and / Alternatively, it is also preferable that the elongation rate in the weft direction is 5 to 20%.

また、本発明によれば、前記のストレッチ布帛を用いてなる、防護服、消防防火服、消防活動服、救助服、ワークウェア、警察制服、自衛隊衣服、軍服等の繊維製品が提供される。 Further, according to the present invention, textile products such as protective clothing, firefighting clothing, firefighting clothing, rescue clothing, workwear, police uniforms, Self-Defense Forces clothing, and military uniforms are provided using the stretch fabric.

本発明によれば、難燃性と伸縮性に加えて優れた制電性を有するストレッチ布帛およびそれを用いてなる繊維製品を得ることができる。 INDUSTRIAL APPLICABILITY According to the present invention, it is possible to obtain a stretch fabric having excellent antistatic properties in addition to flame retardancy and stretchability, and a textile product using the stretch fabric.

以下、本発明の実施の形態について詳細に説明する。 BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, embodiments of the present invention will be described in detail.

本発明において、紡績糸は、JISK7201により測定される限界酸素指数が25以上の難燃性繊維を含む。かかる難燃性繊維としては、メタ系アラミド繊維、パラ系アラミド繊維、ポリパラフェニレンベンズオキサゾール繊維、ポリベンゾイミダゾール繊維、ポリイミド繊維、ポリエーテルイミド繊維、ポリアミドイミド繊維、炭素繊維、ポリフェニレンサルファイド繊維、ポリ塩化ビニル繊維、難燃レーヨン、モダアクリル繊維、難燃アクリル繊維、難燃ポリエステル繊維、難燃ビニロン繊維、メラミン繊維、フッ素繊維、難燃ウール、難燃コットンなどが例示される。これらの難燃性繊維を1種または2種以上用いることができる。 In the present invention, the spun yarn contains flame-retardant fibers having a limiting oxygen index of 25 or higher as measured by JISK7201. Such flame-retardant fibers include meta-aramid fibers, para-aramid fibers, polyparaphenylenebenzoxazole fibers, polybenzimidazole fibers, polyimide fibers, polyetherimide fibers, polyamideimide fibers, carbon fibers, polyphenylene sulfide fibers, poly Examples include vinyl chloride fiber, flame-retardant rayon, modacrylic fiber, flame-retardant acrylic fiber, flame-retardant polyester fiber, flame-retardant vinylon fiber, melamine fiber, fluorine fiber, flame-retardant wool, and flame-retardant cotton. One or more of these flame-retardant fibers can be used.

なかでも、優れた限界酸素指数を示しかつ優れた機械的物性の点から、メタ系アラミド繊維すなわちメタフェニレンイソフタルアミド繊維(市販品では、帝人株式会社製「テイジンコーネックス」「テイジンコーネックスネオ」(商標名)、デュポン社製「ノーメックス」(商標名)など)は有用である。さらには、パラ系アラミド繊維すなわちパラフェニレンテレフタルアミド繊維(市販品では、帝人株式会社製「トワロン」(商標名)、東レ・デュポン株式会社製「ケブラー」(商標名)など)、コパラフェニレン・3、4’オキシジフェニレンテレフタルアミド繊維(市販品では、帝人株式会社製「テクノーラ」(商標名)など)を混合させることも好ましい。 Among them, meta-aramid fibers, i.e., meta-phenylene isophthalamide fibers (commercially available products: Teijin Conex and Teijin Conex Neo, manufactured by Teijin Limited), have excellent limiting oxygen index and excellent mechanical properties. (trade name), DuPont "Nomex" (trade name), etc.) are useful. Furthermore, para-aramid fiber, that is, paraphenylene terephthalamide fiber (commercially available products, such as "Twaron" (trade name) manufactured by Teijin Limited, "Kevlar" (trade name) manufactured by Toray DuPont Co., Ltd.), coparaphenylene It is also preferable to mix 3,4′-oxydiphenylene terephthalamide fibers (commercially available products such as “Technora” (trade name) manufactured by Teijin Limited).

これらの難燃性繊維は、本発明の目的を損なわない範囲で、酸化防止剤、紫外線吸収剤、熱安定剤、難燃剤、酸化チタン、着色剤、不活性微粒子などの添加剤を含有してもよい。 These flame-retardant fibers contain additives such as antioxidants, ultraviolet absorbers, heat stabilizers, flame retardants, titanium oxide, colorants, and inert fine particles within the range that does not impair the purpose of the present invention. good too.

また、紡績糸は、前記の難燃性繊維のみからなることが好ましいが、非難燃性繊維(JIS K7201により測定される限界酸素指数が25未満の繊維)を含ませてもよい。その際、非難燃性繊維としては、ポリエステル繊維、ナイロン繊維、レーヨン繊維、ポリノジック繊維、リヨセル繊維、アクリル系繊維、ビニロン繊維、コットン、麻、ウールなどが例示される。これらの非難燃性繊維を1種または2種以上用いることができる。 The spun yarn preferably consists of only the above flame-retardant fibers, but may contain non-flame-retardant fibers (fibers having a limiting oxygen index of less than 25 as measured by JIS K7201). Examples of non-flame-retardant fibers include polyester fibers, nylon fibers, rayon fibers, polynosic fibers, lyocell fibers, acrylic fibers, vinylon fibers, cotton, hemp, and wool. One or more of these non-retardant fibers can be used.

これらの非難燃性繊維は、本発明の目的を損なわない範囲で、酸化防止剤、紫外線吸収剤、熱安定剤、難燃剤、酸化チタン、着色剤、不活性微粒子、導電粒子などの添加剤を含有してもよい。 These non-retardant fibers contain additives such as antioxidants, ultraviolet absorbers, heat stabilizers, flame retardants, titanium oxide, coloring agents, inert fine particles, conductive particles, etc., to the extent that they do not impair the purpose of the present invention. may contain.

また、難燃性繊維、非難燃性繊維は、繊維長としては35~110mmの範囲が好ましい。 The fiber length of flame-retardant fibers and non-flame-retardant fibers is preferably in the range of 35 to 110 mm.

また、紡績糸の総繊度は、用途に応じて、表面外観、耐熱性、熱防護性、伸縮性、風合いなどを考慮して適宜選択すればよく、特に紡績糸の繊度は58dtex(英式綿番手100番単糸相当)~580dtex(英式綿番手10番手相当)の範囲が好ましい。 In addition, the total fineness of the spun yarn may be appropriately selected in consideration of the surface appearance, heat resistance, thermal protection, stretchability, texture, etc., depending on the application. It is preferably in the range of 580 dtex (corresponding to 10 count of British cotton) to 580 dtex (corresponding to 100 count single yarn).

また、紡績糸の単繊維繊度は、良好な紡績工程通過性、柔軟性の求められている衣料用途への使用の観点から、0.6~5.5dtexの範囲が好ましい。 In addition, the single fiber fineness of the spun yarn is preferably in the range of 0.6 to 5.5 dtex from the viewpoint of use in clothing applications that require good passing through the spinning process and flexibility.

また、紡績糸の撚係数Kは布帛の物性および柔軟性の点から2.5~4.5の範囲であることが好ましい。ただし、T=K√nであり、Tは1インチ(2.54cm)あたりの撚数、nは英式綿番手、Kは撚係数である。 The twist coefficient K of the spun yarn is preferably in the range of 2.5 to 4.5 from the viewpoint of the physical properties and flexibility of the fabric. where T=K√n, where T is the number of twists per inch (2.54 cm), n is the British cotton count, and K is the twist factor.

また、紡績糸は単糸であってもよいし双糸であってもよい。また、酸化防止剤、紫外線吸収剤、熱安定剤、難燃剤、酸化チタン、着色剤、不活性微粒子などの添加剤を含有してもよい。 Also, the spun yarn may be a single yarn or a two-ply yarn. Moreover, additives such as antioxidants, ultraviolet absorbers, heat stabilizers, flame retardants, titanium oxide, colorants, and inert fine particles may be contained.

本発明の伸縮糸は、繊維の形状は特に限定されず、長繊維(マルチフィラメント)でもよいし短繊維でもよいが、優れた伸縮性を得る上で長繊維(マルチフィラメント)が好ましい。伸縮糸は、伸縮性を持たせたナイロン繊維、ポリエステル繊維、ポリウレタン繊維、が好ましく、特にエーテル系ポリウレタンであることが好ましい。 The shape of the stretchable yarn of the present invention is not particularly limited, and may be long fibers (multifilaments) or short fibers, but long fibers (multifilaments) are preferred for obtaining excellent stretchability. Stretchable yarns are preferably stretchable nylon fibers, polyester fibers, or polyurethane fibers, and particularly preferably ether-based polyurethane.

本発明の導電糸は、繊維の形状は特に限定されず、長繊維(マルチフィラメント)でもよいし短繊維でもよいが、優れた伸縮性を得る上で長繊維(マルチフィラメント)が好ましい。導電糸は、導電性を持たせた繊維であればよく、例えば、炭素粒子/繊維や金属粒子/繊維を配合した繊維が挙げられる。
伸縮糸、導電糸の総繊度、単繊維繊度は用途に応じて適宜選定され、総繊度20~200dtex、単繊維繊度0.5~10.0dtexの範囲が好ましい。
The conductive yarn of the present invention is not particularly limited in fiber shape, and may be either long fibers (multifilament) or short fibers, but long fibers (multifilament) are preferred for obtaining excellent stretchability. The conductive thread may be a fiber having conductivity, and examples thereof include fibers containing carbon particles/fibers and metal particles/fibers.
The total fineness and single fiber fineness of the stretchable yarn and conductive yarn are appropriately selected according to the application, preferably in the range of 20 to 200 dtex for the total fineness and 0.5 to 10.0 dtex for the single fiber fineness.

本発明の複合糸として、難燃性繊維を含む紡績糸(導電繊維を含んでいてもよい)と、難燃性繊維を含む紡績糸と導電糸を用いた導電性難燃複合糸(導電性難燃合撚糸)や、難燃性繊維を含む紡績糸と伸縮繊維を用いた伸縮性難複合糸(伸縮性難燃合撚糸)等が挙げられる。 As the composite yarn of the present invention, a spun yarn containing a flame-retardant fiber (which may contain a conductive fiber) and a conductive flame-retardant composite yarn using a spun yarn containing a flame-retardant fiber and a conductive yarn (conductive flame-retardant plied yarn), stretchable flame-retardant composite yarn (stretchable flame-retardant plied yarn) using spun yarn containing flame-retardant fiber and stretchable fiber, and the like.

本発明の複合糸の複合方法は特に限定されないが、合撚糸条またはカバリング糸であることが好ましい。より具体的には、前記の紡績糸と複合繊維とを用いて、市販のアップツイスタ、カバリング機、イタリ式撚糸機、ダブルツイスタなどを使用して、合撚またはカバリングすることが好ましい。その際、撚り止めセットは要求される品質により実施しても良い。複合合撚糸の撚り止めセットは、通常の紡績糸のセットに用いられる真空スチームセットを用いる事ができる。複合合撚糸のセット時の温度は、50~80℃(より好ましくは65~75℃)の範囲が好ましい。複合合撚糸の撚り止めセット温度が高過ぎると、最終的に得られる布帛の伸縮性が損なわれるおそれがある。 Although the method of combining the composite yarn of the present invention is not particularly limited, it is preferably a plied yarn or a covering yarn. More specifically, the spun yarn and the composite fiber are preferably plied or covered using a commercially available up twister, covering machine, Italian twister, double twister, or the like. At that time, the twist setting may be performed according to the required quality. Vacuum steam setting, which is used for setting ordinary spun yarns, can be used for twist setting of the composite plied yarn. The temperature at which the composite plied yarn is set is preferably in the range of 50 to 80°C (more preferably 65 to 75°C). If the twist setting temperature of the composite plied yarn is too high, the stretchability of the finally obtained fabric may be impaired.

本発明のストレッチ布帛はかかる複合糸を用いてなる布帛である。その際、優れた難燃性を得る上で、前記難燃性繊維の重量比率が布帛重量に対して40重量%以上(好ましくは70~95重量%)の範囲であることが肝要である。前記難燃性繊維の重量比率が40重量%未満の場合、難燃性が低下するおそれがあり好ましくない。 The stretch fabric of the present invention is a fabric using such a composite yarn. At that time, in order to obtain excellent flame retardancy, it is essential that the weight ratio of the flame-retardant fiber is in the range of 40% by weight or more (preferably 70 to 95% by weight) with respect to the weight of the fabric. If the weight ratio of the flame-retardant fiber is less than 40% by weight, the flame retardancy may be lowered, which is not preferable.

また、前記伸縮糸の繊維が重量比率で布帛重量に対して5~15重量%の範囲であることが肝要である。前記伸縮糸の繊維が重量比率で布帛重量に対して15重量%を越える場合、炎が複合繊維に沿って伝わりやすく燃焼しやすくなるため好ましくない。また、逆に、前記伸縮糸の繊維が重量比率で5重量%未満の場合、布帛の伸縮性が低下するおそれがあり好ましくない。 Also, it is essential that the weight ratio of the fibers of the stretch yarn is in the range of 5 to 15% by weight with respect to the weight of the fabric. If the weight ratio of the fibers of the stretchable yarn exceeds 15% by weight with respect to the weight of the fabric, the flame tends to propagate along the composite fiber, which is not preferable because it tends to burn. Conversely, if the weight ratio of the fibers in the stretch yarn is less than 5% by weight, the stretchability of the fabric may decrease, which is not preferable.

布帛の布帛組織としては特に限定されないが、織物または編物であることが好ましい。織物であれば、平組織、綾組織、朱子組織および各組織のリップストップ化などが例示される。また、編物であれば、機械編、かぎ針編、棒針編、アフガン編、レース編などが例示される。 Although the fabric structure of the fabric is not particularly limited, it is preferably woven or knitted. In the case of woven fabrics, plain weave, twill weave, satin weave, and ripstop of each weave are exemplified. Knitted fabrics include machine knitting, crochet knitting, needle knitting, Afghan knitting, and lace knitting.

例えば、織物であれば、経方向および/または緯方向に、前記の複合糸を全量配してもよいし、前記の紡績と前記複合糸とを、例えば1:1、2:1、3:1、1:2、1:3の配列比で配列させてもよいが、難燃性繊維を含む紡績糸と導電糸とを合撚した導電性難燃合撚糸が、布帛の伸縮時に経糸中に5~50mmのピッチ(好ましくは5~30mm)で配置されることが好ましい。なお、製編織の方法は特に限定されず、通常の編機や織機を用いた方法でよい。このように導電性難燃合撚糸を配置することで高い制電性を得ることができる。ピッチが50mmを超えると制電性が低下するため好ましくない。 For example, in the case of a woven fabric, the entire amount of the composite yarn may be distributed in the warp direction and/or the weft direction, or the spun and the composite yarn may be mixed, for example, 1:1, 2:1, 3: It may be arranged at an arrangement ratio of 1, 1:2, or 1:3, but the conductive flame-retardant plied yarn obtained by twisting the spun yarn containing the flame-retardant fiber and the conductive yarn is placed in the warp when the fabric is stretched. are preferably arranged at a pitch of 5 to 50 mm (preferably 5 to 30 mm). The knitting and weaving method is not particularly limited, and a method using a normal knitting machine or loom may be used. By arranging the conductive flame-retardant plied yarn in this manner, high antistatic properties can be obtained. If the pitch exceeds 50 mm, the antistatic property is lowered, which is not preferable.

布帛は、毛焼、精錬、リラックス、染色処理、セットなどの熱処理を施す。布帛には、吸水加工、撥水加工、起毛加工、難燃加工、紫外線遮蔽あるいは抗菌剤、消臭剤、防虫剤、蓄光剤、再帰反射剤、マイナスイオン発生剤等の機能を付与する各種加工を付加適用してもよい。 The fabric is subjected to heat treatment such as singeing, refining, relaxing, dyeing, and setting. Fabrics are treated with various functions such as water absorption, water repellent, raised, flame retardant, UV shielding, antibacterial agents, deodorants, insect repellents, phosphorescent agents, retroreflective agents, negative ion generators, etc. may additionally be applied.

布帛の伸縮性は、経方向および/または緯方向の伸長率が5~40%(より好ましくは5~20%)の範囲であることが好ましい。また、布帛の伸長回復率としては、経方向および/または緯方向の伸長回復率が70%以上(より好ましくは73~99%)であることが好ましい。 The stretchability of the fabric is preferably in the range of 5 to 40% (more preferably 5 to 20%) in the warp and/or weft direction. In addition, as for the elongation recovery rate of the fabric, it is preferable that the elongation recovery rate in the warp direction and/or weft direction is 70% or more (more preferably 73 to 99%).

布帛の難燃性は、JIS K7201により測定される限界酸素指数が25以上(より好ましくは25~40)であることが好ましい。 The flame retardancy of the fabric is preferably such that the limit oxygen index measured according to JIS K7201 is 25 or more (more preferably 25 to 40).

布帛のピリングは、JIS L1076 A法(ICI 10hr)で規定される等級が3.0以上(より好ましくは3.5以上)であることが好ましい。 The pilling of the fabric preferably has a grade of 3.0 or higher (more preferably 3.5 or higher) as defined by JIS L1076 A method (ICI 10 hr).

布帛の制電性(帯電電荷量)は、JISL1094 C法により規定される帯電電荷量が6マイクロクーロン以下(より好ましくは4.0マイクロクーロン以下、特に好ましくは3.0マイクロクーロン以下)であることが好ましい。 The antistatic property (charge amount) of the fabric is 6 microcoulombs or less (more preferably 4.0 microcoulombs or less, particularly preferably 3.0 microcoulombs or less) as defined by JISL1094 C method. is preferred.

次に、本発明の繊維製品は前記の布帛を用いてなるものである。かかる繊維製品は前記の布帛を用いているので、伸縮性および難燃性に優れる。かかる繊維製品には、消防服、防火服、執務服、モータースポーツ用レーシングスーツ、作業服、手袋、帽子、ベスト、各種産業資材(シート、テント、膜材、幌、建築資材、住宅材、車両内装材など)などが含まれる。また、前記作業服には、製鉄所や鉄鋼工場の作業用作業服、溶接作業用作業服、防爆エリアにおける作業服などが含まれる。また、前記手袋には、精密部品を取り扱う航空機産業、情報機器産業、精密機器産業などで使用される作業手袋などが含まれる。 Next, the textile product of the present invention is made by using the above fabric. Since such a textile product uses the above fabric, it is excellent in stretchability and flame retardancy. Such textile products include firefighting clothing, fire protection clothing, office clothing, racing suits for motor sports, work clothing, gloves, hats, vests, various industrial materials (sheets, tents, membrane materials, hoods, construction materials, housing materials, vehicles interior materials, etc.). Further, the work clothes include work clothes for working in ironworks and steel factories, work clothes for welding work, work clothes for explosion-proof areas, and the like. Further, the gloves include work gloves used in the aircraft industry, the information equipment industry, the precision equipment industry, etc., which handle precision parts.

次に本発明の実施例及び比較例を詳述するが、本発明はこれらによって限定されるもの
ではない。なお、実施例中の各測定項目は下記の方法で測定した。
(1)難燃性
JIS K7201:1999(酸素指数法による高分子材料の燃焼試験法)により限
界酸素指数(LOI)を測定し、難燃性の指標とした。
(2)伸縮性
JIS L1096:2011(B法、定荷重法)にしたがって、伸長率及び伸長回復
率を測定した。
(3)燃焼性
JIS L1091 A-4法付属書8にしたがって、残炎時間、残じん時間、炭化長
を測定し、燃焼性の指標とした。
(4)ピリング測定
JIS L1076 A法(ICI 10hr)にしたがって、ピリング測定を行った。
(5)帯電電荷量(制電性)
20℃±2℃、40±2%RHの環境下で、JISL1094 C法 摩擦帯電電荷量測定法試験片(250mm×350mm)にしたがって測定した。
Examples and comparative examples of the present invention will now be described in detail, but the present invention is not limited to these. Each measurement item in the examples was measured by the following method.
(1) Flame retardancy Limiting oxygen index (LOI) was measured according to JIS K7201:1999 (combustion test method for polymer materials by oxygen index method) and used as an index of flame retardancy.
(2) Elasticity The elongation rate and elongation recovery rate were measured according to JIS L1096:2011 (B method, constant load method).
(3) Combustibility In accordance with JIS L1091 A-4 method appendix 8, afterflame time, afterburning time, and carbonization length were measured and used as indicators of combustibility.
(4) Pilling measurement Pilling measurement was performed according to JIS L1076 A method (ICI 10hr).
(5) Charge amount (antistatic property)
Measured in accordance with JISL1094 C method triboelectrification charge amount measurement test piece (250 mm x 350 mm) under an environment of 20°C ± 2°C and 40 ± 2% RH.

[実施例1]
紡績糸として、紡績工程において、単繊維繊度1.7dtex、カット長(繊維長)51mm、LOIが32であるポリメタフェニレンイソフタルアミド繊維(帝人株式会社製「テイジンコーネックス」(商標名))からなる短繊維と、単繊維繊度1.7dtex、カット長(繊維長)51mm、LOIが25であるコパラフェニレン・3、4’オキシジフェニレンテレフタルアミド繊維(帝人株式会社製「テクノーラ」(商標名))からなる短繊維を重量割合(テイジンコーネックス:テクノーラ)93:7の割合で混紡し、撚数24T/inch(撚係数=3.4)、英式綿番手で40番単糸を得た。
[Example 1]
As a spun yarn, polymetaphenylene isophthalamide fiber ("Teijin Conex" (trade name) manufactured by Teijin Limited) having a single fiber fineness of 1.7 dtex, a cut length (fiber length) of 51 mm, and an LOI of 32 is used in the spinning process. and a coparaphenylene 3,4′ oxydiphenylene terephthalamide fiber with a single fiber fineness of 1.7 dtex, a cut length (fiber length) of 51 mm, and an LOI of 25 (manufactured by Teijin Ltd., “Technora” (trade name )) are blended at a weight ratio (Teijinconex: Technora) of 93:7 to obtain a single yarn with a twist number of 24 T / inch (twist coefficient = 3.4) and a British cotton count of 40. rice field.

前記紡績糸2本を合糸し、ダブルツイスタ―にて上撚数20.9T/inchにて交撚した後、真空スチームセット機にてセット温度120℃、セット時間20分の条件で撚り止めセットし、難燃合撚糸を得た。 The two spun yarns are combined and twisted with a double twister at a ply twist number of 20.9 T / inch, and then twisted with a vacuum steam set machine under the conditions of a set temperature of 120 ° C. and a set time of 20 minutes. A flame-retardant plied yarn was obtained by setting.

次いで、前記紡績糸2本と導電糸(帝人(株)B-TCF(U300HX31T5))1本を合糸し、ダブルツイスタ―にて上撚数20.9T/inchにて交撚した後、真空スチームセット機にてセット温度120℃、セット時間20分の条件で撚り止めセットし、難燃導電合撚糸を得た。 Next, two spun yarns and one conductive yarn (B-TCF (U300HX31T5) manufactured by Teijin Limited) are combined, twisted with a double twister at a ply twist number of 20.9 T / inch, and then vacuumed. A flame-retardant conductive plied yarn was obtained by twisting and setting under the conditions of a setting temperature of 120° C. and a setting time of 20 minutes using a steam setting machine.

一方、伸縮繊維として、ポリウレタンフィラメント(長繊維)を用意した。(22T/inch)
次いで、前記紡績糸2本とポリウレタンフィラメント1本とを合糸し、ダブルツイスタ―にて上撚数19.8T/inchにて撚糸した後、真空スチームセット機にてセット温度70℃、セット時間20分の条件で撚り止めセットし、難燃伸縮合撚糸を得た。
On the other hand, polyurethane filaments (long fibers) were prepared as elastic fibers. (22T/inch)
Next, two spun yarns and one polyurethane filament are combined, twisted with a double twister at a final twist number of 19.8 T / inch, and then set at a temperature of 70 ° C. for a set time with a vacuum steam set machine. The twist was stopped and set for 20 minutes to obtain a flame-retardant stretch plied twisted yarn.

次いで、経糸に前記難燃合撚糸と、10mmピッチの間隔で難燃導電合撚糸を配設し、緯糸は前記難燃伸縮合撚糸のみを配して、織物密度が経54本/inch、緯63本/inchで織物組織が2/1綾織にて織り成した。
織り成した織物を毛焼-精練-セット(温度160℃×時間30秒)-リラックス(温度120℃×時間30分)工程した。
Next, the flame-retardant plied yarn and the flame-retardant conductive plied yarn are arranged at intervals of 10 mm in the warp, and only the flame-retardant stretch plied yarn is arranged in the weft, and the fabric density is 54 warps/inch and the weft. The fabric was woven with a 2/1 twill weave at 63 threads/inch.
The woven fabric was subjected to the steps of singeing-scouring-setting (temperature 160° C.×time 30 seconds)-relaxing (temperature 120° C.×time 30 minutes).

得られた伸縮性難燃織物において、織物密度が経68本/inch、緯64本/inch、非難燃性繊維の重量割合は11.0wt%、限界酸素指数は32.0、緯伸長率は10.0%と良好な伸縮性が得られ、伸長回復率は85%であった。また、帯電電荷量は2.3μCと良好な制電性が得られた。評価結果を表1に示す。 In the resulting stretchable flame-retardant fabric, the fabric density is 68 warp/inch, weft 64/inch, the weight ratio of non-flame-retardant fiber is 11.0 wt%, the limiting oxygen index is 32.0, and the weft elongation rate is A good stretchability of 10.0% was obtained, and the elongation recovery rate was 85%. Also, the charge amount was 2.3 μC, and good antistatic properties were obtained. Table 1 shows the evaluation results.

次いで、該伸縮性難燃織物を用いて作業服を得たところ、伸縮性と難燃性に優れるものであった。 Next, when work clothes were obtained using the stretchable flame-retardant fabric, they were excellent in stretchability and flame retardancy.

[実施例2]
紡績糸として、紡績工程において、単繊維繊度1.7dtex、カット長(繊維長)51mm、LOIが26であるポリメタフェニレンイソフタルアミド繊維(帝人株式会社製「帝人コーネックスネオ」(商標名))からなる短繊維と、単繊維繊度1.7dtex、カット長(繊維長)51mm、LOIが25であるポリパラフェニレンテレフタラミド(PPTA)繊維(帝人株式会社製「トワロン」(商標名))と短繊維繊度3.3dtex、カット長(繊維長)38mmである導電繊維(三菱ケミカル製「コアブリットET10」(商標名))からなる短繊維を重量割合93:5:2(帝人コーネックスネオ:トワロン:コアブリットET10)の割合で混紡し、撚数24T/inch(撚係数=3.4)、英式綿番手で40番単糸を得た以外は実施例1と同様にした。
[Example 2]
As a spun yarn, a polymetaphenylene isophthalamide fiber (“Teijin Conex Neo” (trade name) manufactured by Teijin Limited) having a single fiber fineness of 1.7 dtex, a cut length (fiber length) of 51 mm, and an LOI of 26 was used in the spinning process. and a polyparaphenylene terephthalamide (PPTA) fiber ("Twaron" (trade name) manufactured by Teijin Limited) having a single fiber fineness of 1.7 dtex, a cut length (fiber length) of 51 mm, and an LOI of 25. Short fibers made of conductive fibers (“Corebrit ET10” (trade name) manufactured by Mitsubishi Chemical) having a short fiber fineness of 3.3 dtex and a cut length (fiber length) of 38 mm were mixed at a weight ratio of 93:5:2 (Teijin Conex Neo: The procedure was the same as in Example 1, except that the yarn was blended at a ratio of Twaron: Corebrit ET10), and a single yarn with a twist number of 24 T/inch (twist coefficient = 3.4) and an English cotton count of 40 was obtained.

得られた伸縮性難燃織物において、織物密度が経68本/inch、緯64本/inch、非難燃性繊維の重量割合は11.0wt%、限界酸素指数は29.0、緯伸長率は10.0%と良好な伸縮性が得られ、伸長回復率は85%であった。また、帯電電荷量は2.1μCと良好な制電性が得られた。評価結果を表1に示す。 In the resulting elastic flame-retardant fabric, the fabric density is 68 warp/inch, weft 64/inch, the weight ratio of non-flame-retardant fiber is 11.0 wt%, the limiting oxygen index is 29.0, and the weft elongation rate is A good stretchability of 10.0% was obtained, and the elongation recovery rate was 85%. Also, the charge amount was 2.1 μC, and good antistatic properties were obtained. Table 1 shows the evaluation results.

[実施例3]
紡績糸として、紡績工程において、単繊維繊度1.7dtex、カット長(繊維長)51mm、LOIが32であるポリメタフェニレンイソフタルアミド繊維(帝人株式会社製「テイジンコーネックス」(商標名))からなる短繊維と、単繊維繊度1.7dtex、カット長(繊維長)51mm、LOIが25であるコパラフェニレン・3、4’オキシジフェニレンテレフタルアミド繊維(帝人株式会社製「テクノーラ」(商標名))からなる短繊維と単繊維繊度1.7dtex、カット長(繊維長)51mm、ポリエステル繊維(帝人(株)製eco-PET(RA02)単繊維繊度2.2dtex、繊維長38mmからなる短繊維を75:5:20の割合で混紡し、撚数20.87T/inch(撚係数=3.3)、英式綿番手で40番単糸を得た以外は実施例1と同様にした。また、帯電電荷量は2.5μCと良好な制電性が得られた。評価結果を表1に示す。
[Example 3]
As a spun yarn, polymetaphenylene isophthalamide fiber ("Teijin Conex" (trade name) manufactured by Teijin Limited) having a single fiber fineness of 1.7 dtex, a cut length (fiber length) of 51 mm, and an LOI of 32 is used in the spinning process. and a coparaphenylene 3,4′ oxydiphenylene terephthalamide fiber with a single fiber fineness of 1.7 dtex, a cut length (fiber length) of 51 mm, and an LOI of 25 (manufactured by Teijin Ltd., “Technora” (trade name ))) and a short fiber consisting of a single fiber fineness of 1.7 dtex, a cut length (fiber length) of 51 mm, a polyester fiber (eco-PET (RA02) manufactured by Teijin Limited), a single fiber fineness of 2.2 dtex, and a fiber length of 38 mm were blended at a ratio of 75:5:20 to obtain a single yarn with a twist number of 20.87 T/inch (twist coefficient = 3.3) and a British cotton count of No. 40. In addition, the charge amount was 2.5 μC, indicating good antistatic properties.The evaluation results are shown in Table 1.

得られた伸縮性難燃織物において、織物密度が経68本/inch、緯64本/inch、非難燃性繊維の重量割合は20wt%、限界酸素指数は33.0、緯伸長率は12.0%と良好な伸縮性が得られ、伸長回復率は86%であった。評価結果を表1に示す。 In the obtained stretchable flame-retardant fabric, the density of the fabric was 68 warp/inch, 64 weft/inch, the weight ratio of the non-flame-retardant fiber was 20 wt%, the limiting oxygen index was 33.0, and the weft elongation rate was 12.0%. A good stretchability of 0% was obtained, and the elongation recovery rate was 86%. Table 1 shows the evaluation results.

Figure 0007294803000001
Figure 0007294803000001

[比較例1]
導電繊維は含まず、経糸および緯糸に難燃合撚糸を配して織り成したこと以外は、実施例1と同様にした。得られた伸縮性難燃織物において、織物密度が経68本/inch、緯64本/inch、非難燃性繊維の重量割合は2wt%、限界酸素指数は26.0、緯伸長率は10.0%と良好な伸縮性が得られ、伸長回復率は90%であった。しかしながら、帯電電荷量は14.0μCであり制電性が不十分であった。評価結果を表2に示す。
[Comparative Example 1]
The same procedure as in Example 1 was carried out, except that no conductive fibers were included, and flame-retardant plied yarns were arranged in the warp and weft. In the obtained stretchable flame-retardant fabric, the fabric density was 68 warp/inch, weft 64/inch, the weight ratio of the non-flame-retardant fiber was 2 wt%, the limiting oxygen index was 26.0, and the weft elongation rate was 10.0. A good stretchability of 0% was obtained, and the elongation recovery rate was 90%. However, the charge amount was 14.0 μC and the antistatic property was insufficient. Table 2 shows the evaluation results.

[比較例2]
導電繊維は含まず、経糸および緯糸に難燃合撚糸を配して織り成したこと以外は、実施例2と同様にした。
[Comparative Example 2]
The same procedure as in Example 2 was carried out except that the conductive fiber was not included and the flame-retardant plied yarn was arranged in the warp and weft.

得られた伸縮性難燃織物において、織物密度が経68本/inch、緯64本/inch、非難燃性繊維の重量割合は4wt%、限界酸素指数は26.0、緯伸長率は10.0%と良好な伸縮性が得られ、伸長回復率は90%であった。しかしながら、帯電電荷量は7.0μCであり制電性は凡庸であった。評価結果を表2に示す。 In the obtained stretchable flame-retardant fabric, the density of the fabric was 68 warp/inch, 64 weft/inch, the weight ratio of the non-flame-retardant fiber was 4 wt%, the limiting oxygen index was 26.0, and the weft elongation rate was 10.0. A good stretchability of 0% was obtained, and the elongation recovery rate was 90%. However, the charge amount was 7.0 μC and the antistatic property was mediocre. Table 2 shows the evaluation results.

[比較例3]
紡績糸として、紡績工程において、単繊維繊度1.7dtex、カット長(繊維長)51mm、LOIが32であるポリメタフェニレンイソフタルアミド繊維(帝人株式会社製「テイジンコーネックス」(商標名))からなる短繊維と、単繊維繊度1.7dtex、カット長(繊維長)51mm、LOIが25であるコパラフェニレン・3、4’オキシジフェニレンテレフタルアミド繊維(帝人株式会社製「テクノーラ」(商標名))からなる短繊維と単繊維繊度1.7dtex、カット長(繊維長)51mm、ポリウレタン短繊維を47:3:10の割合で混紡し、撚数20.87T/inch(撚係数=3.3)、英式綿番手で40番単糸を得た以外は実施例1と同様にした。
[Comparative Example 3]
As a spun yarn, polymetaphenylene isophthalamide fiber ("Teijin Conex" (trade name) manufactured by Teijin Limited) having a single fiber fineness of 1.7 dtex, a cut length (fiber length) of 51 mm, and an LOI of 32 is used in the spinning process. and a coparaphenylene 3,4′ oxydiphenylene terephthalamide fiber with a single fiber fineness of 1.7 dtex, a cut length (fiber length) of 51 mm, and an LOI of 25 (manufactured by Teijin Ltd., “Technora” (trade name ))), a single fiber fineness of 1.7 dtex, a cut length (fiber length) of 51 mm, and polyurethane staple fibers were blended at a ratio of 47:3:10, and the twist number was 20.87 T/inch (twist coefficient = 3. 3) The procedure was the same as in Example 1, except that a No. 40 single yarn with an English cotton count was obtained.

得られた伸縮性難燃織物において、織物密度が経68本/inch、緯64本/inch、限界酸素指数は23.0、緯伸長率は20.0%と優れた伸縮性が得られ、伸長回復率は95%であった。しかしながら、燃焼性試験で布帛が全焼してしまったため、難燃性布帛としては不十分であった。また、帯電電荷量は15.0μCであり制電性も不十分であった。評価結果を表2に示す。 The resulting stretchable flame-retardant fabric has a fabric density of 68 warp/inch, a weft of 64/inch, a limiting oxygen index of 23.0, and a weft elongation rate of 20.0%. The elongation recovery rate was 95%. However, since the fabric burned down in the combustibility test, it was insufficient as a flame-retardant fabric. In addition, the charge amount was 15.0 μC, and the antistatic property was also insufficient. Table 2 shows the evaluation results.

Figure 0007294803000002
Figure 0007294803000002

Claims (7)

JISK7201により測定される限界酸素指数が25以上の難燃性繊維を含む紡績糸と導電糸及び/または長繊維からなる伸縮糸との複合糸を用いた布帛であって、当該布帛は、JISL1096法により測定される伸び率が5~40%であり、かつ、JISL1094法に規定される帯電電荷量が6.0マイクロクーロン以下であることを特徴とするストレッチ布帛であって、
難燃性繊維を含む紡績糸と、難燃性繊維を含む紡績糸と導電糸を用いた導電性難燃複合糸とを経糸とし、難燃性繊維を含む紡績糸と伸縮糸を用いた伸縮性難燃複合糸を緯糸とし、
前記導電糸が、炭素粒子を配合した導電糸であり、JISL1094法に規定される帯電電荷量が4.0マイクロクーロン以下、前記難燃性繊維の重量比が布帛重量に対して40重量%以上であり、前記伸縮糸の重量比が布帛重量に対して0.1~5重量%であり、前記導電糸の重量比が布帛重量に対して0.1~5重量%であり、JISL1091A-4-1992法で規定される炭化長が100mm以下、かつ、残炎及び残塵が2秒以下であり、JISL1096B法で規定される経方向および/または緯方向の伸長率が5~20%であるストレッチ布帛。
A fabric using a composite yarn of a spun yarn containing a flame-retardant fiber having a limiting oxygen index of 25 or more as measured by JIS K7201 and a conductive yarn and / or a stretch yarn made of long fibers, and the fabric conforms to the JISL1096 method. A stretch fabric characterized by having an elongation rate of 5 to 40% as measured by the method and having a charge amount of 6.0 microcoulombs or less as defined by the JISL1094 method,
Spun yarn containing flame-retardant fiber and conductive flame-retardant composite yarn using spun yarn containing flame-retardant fiber and conductive yarn are used as warps, and stretch using spun yarn containing flame-retardant fiber and stretch yarn Using flame retardant composite yarn as weft yarn,
The conductive yarn is a conductive yarn containing carbon particles, has a charge amount of 4.0 microcoulombs or less as defined in JISL1094, and a weight ratio of the flame-retardant fiber to the fabric weight of 40% by weight or more. The weight ratio of the stretchable yarn is 0.1 to 5% by weight with respect to the weight of the fabric, and the weight ratio of the conductive yarn is 0.1 to 5% by weight with respect to the weight of the fabric, JISL1091A-4 -The carbonization length specified by the 1992 method is 100 mm or less, and the afterflame and afterglow are 2 seconds or less, and the elongation rate in the warp and / or weft direction specified by the JISL1096B method is 5 to 20%. stretch fabric.
JISK7201により測定される限界酸素指数が25以上の難燃性繊維を含む紡績糸と導電糸及び/または長繊維からなる伸縮糸との複合糸を用いた布帛であって、当該布帛は、JISL1096法により測定される伸び率が5~40%であり、かつ、JISL1094法に規定される帯電電荷量が6.0マイクロクーロン以下であることを特徴とするストレッチ布帛であって、
難燃性繊維と導電繊維を含む紡績糸と、難燃性繊維を含む紡績糸と導電糸を用いた導電性難燃複合糸とを経糸とし、難燃性繊維と導電繊維を含む紡績糸と伸縮糸を用いた伸縮性難燃複合糸を緯糸とし、
前記導電糸が、炭素粒子を配合した導電糸であり、JISL1094法に規定される帯電電荷量が4.0マイクロクーロン以下、前記難燃性繊維の重量比が布帛重量に対して40重量%以上であり、前記伸縮糸の重量比が布帛重量に対して0.1~5重量%であり、前記導電糸及び/または前記導電繊維の重量比が布帛重量に対して0.1~5重量%であり、JISL1091A-4-1992法で規定される炭化長が100mm以下、かつ、残炎及び残塵が2秒以下であり、JISL1096B法で規定される経方向および/または緯方向の伸長率が5~20%であるストレッチ布帛。
A fabric using a composite yarn of a spun yarn containing a flame-retardant fiber having a limiting oxygen index of 25 or more as measured by JIS K7201 and a conductive yarn and / or a stretch yarn made of long fibers, and the fabric conforms to the JISL1096 method. A stretch fabric characterized by having an elongation rate of 5 to 40% as measured by the method and having a charge amount of 6.0 microcoulombs or less as defined by the JISL1094 method,
A spun yarn containing a flame-retardant fiber and a conductive fiber, and a conductive flame-retardant composite yarn using the spun yarn containing the flame-retardant fiber and the conductive yarn as warps, and a spun yarn containing the flame-retardant fiber and the conductive fiber. Stretchable flame-retardant composite yarn using elastic yarn is used as weft yarn,
The conductive yarn is a conductive yarn containing carbon particles, has a charge amount of 4.0 microcoulombs or less as defined in JISL1094, and a weight ratio of the flame-retardant fiber to the fabric weight of 40% by weight or more. wherein the weight ratio of the stretchable yarn is 0.1 to 5% by weight relative to the weight of the fabric, and the weight ratio of the conductive yarn and/or the conductive fiber is 0.1 to 5% by weight relative to the weight of the fabric. , the char length specified by the JISL1091A-4-1992 method is 100 mm or less, and the afterflame and residual dust are 2 seconds or less, and the elongation rate in the warp and / or weft directions specified by the JISL1096B method is A stretch fabric that is between 5 and 20% .
前記紡績糸の撚係数が2.5~4.5である請求項1または2に記載のストレッチ布帛。 The stretch fabric according to claim 1 or 2, wherein the twist factor of said spun yarn is 2.5 to 4.5. 前記難燃性繊維が、メタ系アラミド繊維、パラ系アラミド繊維、ポリパラフェニレンベンズオキサゾール繊維、ポリベンゾイミダゾール繊維、ポリイミド繊維、ポリエーテルイミド繊維、ポリアミドイミド繊維、炭素繊維、ポリフェニレンサルファイド繊維、ポリ塩化ビニル繊維、難燃レーヨン、モダアクリル繊維、難燃アクリル繊維、難燃ポリエステル繊維、難燃ビニロン繊維、メラミン繊維、フッ素繊維、難燃ウール、難燃コットンの群から選ばれた1種類以上の繊維である、請求項1~3のいずれか1つに記載のストレッチ布帛。 The flame-retardant fiber is meta-aramid fiber, para-aramid fiber, polyparaphenylenebenzoxazole fiber, polybenzimidazole fiber, polyimide fiber, polyetherimide fiber, polyamideimide fiber, carbon fiber, polyphenylene sulfide fiber, polychlorinated One or more fibers selected from the group consisting of vinyl fiber, flame-retardant rayon, modacrylic fiber, flame-retardant acrylic fiber, flame-retardant polyester fiber, flame-retardant vinylon fiber, melamine fiber, fluorine fiber, flame-retardant wool, and flame-retardant cotton. The stretch fabric according to any one of claims 1 to 3, wherein the stretch fabric is 前記伸縮糸が、エーテル系ポリウレタンを含む請求項1~4のいずれか1つに記載のストレッチ布帛。 The stretch fabric according to any one of claims 1 to 4, wherein the stretch yarn comprises ether-based polyurethane. 前記難燃性繊維に難燃剤が練りこまれている請求項1~5のいずれか1つに記載のストレッチ布帛。 The stretch fabric according to any one of claims 1 to 5, wherein a flame retardant is kneaded into the flame-retardant fibers. 請求項1~6のいずれか1つに記載されたストレッチ布帛を用いてなる、防護服、消防防火服、消防活動服、救助服、ワークウェア、警察制服、自衛隊衣服、および軍服からなる群より選択されるいずれかの繊維製品。
From the group consisting of protective clothing, firefighting clothing, firefighting clothing, rescue clothing, workwear, police uniforms, self-defense force clothing, and military clothing, using the stretch fabric according to any one of claims 1 to 6 Any textile product selected.
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JP2014240532A (en) 2013-06-11 2014-12-25 帝人株式会社 Stretchable flame-retardant fabric and textile product
JP2015059290A (en) 2013-09-20 2015-03-30 帝人株式会社 Fabric for protection product and method for producing the same, and protection product

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JP2009523194A (en) 2005-10-21 2009-06-18 ダウ グローバル テクノロジーズ インコーポレイティド Flame and heat resistant stretch fabric with improved chemical resistance and durability
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