JP7246107B2 - Method for producing environment-friendly low-carbon degradable antibacterial material - Google Patents

Method for producing environment-friendly low-carbon degradable antibacterial material Download PDF

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JP7246107B2
JP7246107B2 JP2021525723A JP2021525723A JP7246107B2 JP 7246107 B2 JP7246107 B2 JP 7246107B2 JP 2021525723 A JP2021525723 A JP 2021525723A JP 2021525723 A JP2021525723 A JP 2021525723A JP 7246107 B2 JP7246107 B2 JP 7246107B2
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ヨン イ,キョン
ギ キム,ヒョン
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ダンジン ネイチャー ワールド クーパレイティブ
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/10Solid or semi-solid fertilisers, e.g. powders
    • C05G5/12Granules or flakes
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • C05F11/08Organic fertilisers containing added bacterial cultures, mycelia or the like
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F3/00Fertilisers from human or animal excrements, e.g. manure
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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Description

本発明は,環境にやさしい低炭素分解性抗菌素材の製造方法(以下,単に、「本発明」とも言う。)に係り,さらに詳しくは,家畜の糞尿をもって製造した堆肥粒子を合成樹脂と混合して多種多様な成形製品の原料となるペレットを準備し,農水畜産用品や産業用品,自動車部品又は各種の産業容器の射出成形又は押出成形などの素材,すなわち,家畜の糞尿の活用で大気汚染,土壌汚染及び水質汚染を解消し,家畜の糞尿と共に合成樹脂と混合体とすることによって,焼却するに際して低炭素であることを可能にする環境にやさしい低炭素分解性抗菌素材の製造方法に関する。 The present invention relates to a method for producing an environmentally friendly low-carbon decomposable antibacterial material (hereinafter simply referred to as the "present invention"). We prepare pellets that are raw materials for a wide variety of molded products, and use materials such as injection molding or extrusion molding for agricultural and livestock products, industrial products, automobile parts, and various industrial containers. The present invention relates to a method for producing an environment-friendly low-carbon decomposable antibacterial material that eliminates soil contamination and water contamination and enables low-carbon incineration by mixing it with livestock manure and synthetic resin.

一般に,家畜の糞尿としては,牛糞,豚糞,鶏糞などが挙げられるが,このような家畜の糞尿は,大気中に異臭を放つばかりではなく,土壌汚染はもとより,地下水までも汚染させる環境汚染の主犯となっている。 In general, livestock manure includes cow manure, pig manure, chicken manure, etc. Such manure not only emits a foul odor into the atmosphere, but also pollutes the soil and even groundwater, causing environmental pollution. is the main culprit.

本発明の出願人は,家畜の糞尿の処理の問題に苦慮していたところ,2016年12月21日付けで「牛糞を活かした植木鉢の製造方法」という名称の発明を大韓民国特許庁に特許出願して,2018年11月01日付けで大韓民国特許第1916213号(以下,先行技術文献と称する。)をもって登録を受けた。 The applicant of the present invention filed a patent application with the Korean Intellectual Property Office on December 21, 2016, titled ``Method for producing flower pots using cow dung'', while struggling with the problem of treating livestock manure. As a result, it was registered as Korean Patent No. 1916213 (hereinafter referred to as prior art document) dated November 01, 2018.

先行技術文献に開示されている牛糞を活かした植木鉢の製造方法は,牛糞を乾燥機を用いて150℃で140~150分間乾燥するステップ(ステップ1)と,前記乾燥された牛糞を成形して成形物を製造するステップ(ステップ2)と,前記成形物の内部を100℃で60分間乾燥するステップ(ステップ3)と,前記内部が乾燥させられた成形物の外部を150℃で140~150分間乾燥して植木鉢を製造するステップ(ステップ4)と,を含み,前記ステップ1における前記乾燥後の牛糞の水分含有量は,50~55重量%であり,前記ステップ4における前記乾燥後の前記植木鉢の内部の水分含有量は,35重量%であり,前記植木鉢の外部の水分含有量は20重量%とするものである。 A method for manufacturing a flowerpot using cow dung disclosed in the prior art documents includes steps of drying cow dung using a dryer at 150° C. for 140 to 150 minutes (step 1), and molding the dried cow dung. A step of manufacturing a molded product (step 2), a step of drying the inside of the molded product at 100 ° C. for 60 minutes (step 3), and the outside of the molded product whose inside is dried at 150 ° C. at 140 to 150 a step of drying for minutes to produce a flowerpot (step 4), wherein the water content of the dried cow dung in step 1 is 50 to 55% by weight, and the dried cow dung in step 4 has a water content of 50 to 55% by weight; The water content inside the flowerpot is 35% by weight, and the water content outside the flowerpot is 20% by weight.

先行技術文献には,牛糞を乾燥させた成形物をもって植木鉢を製造することが記載されているが,このような先行技術文献に開示されている牛糞を活かした植木鉢の製造方法は,水分に弱いだけではなく,外部の衝撃に破損し易いため長寿命を保証することができないという限界を有している。 Prior art documents describe the production of flowerpots using molded articles obtained by drying cow dung. In addition, it has a limitation that it cannot guarantee a long life because it is easily damaged by an external impact.

本発明の目的は,家畜の糞尿をもって製造した堆肥粒子を合成樹脂と混合して多種多様な成形製品の原料となるペレットとして準備し,農水畜産用品や産業用品,自動車部品又は各種の容器などの射出成形,押出成形などの素材,すなわち,家畜の糞尿の活用で大気汚染,土壌汚染及び水質汚染を解消し,家畜の糞尿とともに合成樹脂の混合体をもって,焼却するに際して発生する炭素を低炭素に可能にする環境にやさしい低炭素分解性抗菌素材の製造方法を提供することにある。 The object of the present invention is to mix compost particles produced from livestock excrement with synthetic resin and prepare them as pellets that are raw materials for a wide variety of molded products, and use them for agricultural and livestock products, industrial products, automobile parts, various containers, etc. Eliminate air pollution, soil pollution, and water pollution by using materials such as injection molding and extrusion molding, that is, livestock manure, and reduce the carbon generated when incinerating with a mixture of livestock manure and synthetic resin. To provide a method for producing an environment-friendly, low-carbon decomposable antibacterial material .

本発明の他の目的は,水分及び衝撃に強く,長寿命を保証することができるだけではなく,焼却ないしは分解に際しての環境汚染までも極小化できるようにする環境にやさしい低炭素分解性抗菌素材の製造方法を提供するところにある。 Another object of the present invention is to provide an eco-friendly, low-carbon decomposable antibacterial material that is resistant to moisture and shock, can guarantee a long life, and can minimize environmental pollution during incineration or decomposition. It is to provide a manufacturing method.

本発明のさらに他の目的は,家畜の糞尿を大鋸屑,微生物培地及び堆肥腐熟用微生物とともに混合,攪拌,発酵,後熟及び乾燥させた後,細かく砕いて堆肥粒子を準備し,大鋸屑による水分の吸収を可能にし,大鋸屑及び家畜の糞尿を微生物培地及び堆肥腐熟用微生物とともに攪拌及び発酵させて家畜の糞尿の積極的な分解を実現しながら,後熟及び乾燥をもってさらなる発酵及び分解を行うとともに,水分までも取り除いて合成樹脂との結合しやすさを実現できるようにする環境にやさしい低炭素分解性抗菌素材の製造方法を提供するところにある。 Still another object of the present invention is to prepare compost particles by mixing, stirring, fermenting, after-ripening and drying livestock manure with sawdust, microbial culture medium and compost-ripening microorganisms, and then finely crushing to prepare compost particles. Allowing for absorption, stirring and fermenting sawdust and livestock manure with microbial media and compost-fermenting microorganisms to achieve active decomposition of livestock manure, while further fermentation and decomposition with after-ripening and drying, The object of the present invention is to provide a method for producing an environment-friendly low-carbon decomposable antibacterial material that can be easily combined with a synthetic resin by removing even moisture.

本発明のさらに他の目的は,堆肥粒子を合成樹脂と混合しつつ結合剤で結合するとともに,抗菌剤で細菌を根絶しつつ分散剤で製品を成形するときの収縮率を最小化させ,かつ,スリップ剤をもって製品を成形するときの脱型が行われ易いように熱混合及び押出ししつつカットして形成されたペレットを用意することにより,農水畜産用品や産業用品,自動車部品又は各種の容器及び部品などの射出成形,押出成形などの成形素材,すなわち,環境にやさしい低炭素分解性抗菌素材として活用することを可能にして,水分及び衝撃に強く,寿命を保証することができるだけではなく,焼却ないしは分解に際しての環境汚染までも極小化させることのできる環境にやさしい低炭素分解性抗菌素材の製造方法を提供するところにある。 It is a further object of the present invention to mix compost particles with a synthetic resin and combine them with a binder, eradicate bacteria with an antibacterial agent, and minimize shrinkage when molding products with a dispersant, and , By preparing pellets formed by cutting while heat mixing and extruding so that it is easy to demold when molding products with a slip agent, agricultural and livestock products, industrial products, automobile parts or various containers And it can be used as a molding material for injection molding, extrusion molding, etc. of parts, that is, as an environmentally friendly, low-carbon decomposable antibacterial material. The object of the present invention is to provide a method for producing an environmentally friendly low-carbon decomposable antibacterial material that can minimize environmental pollution when incinerated or decomposed.

本発明は,家畜の糞尿をもって製造した堆肥粒子を合成樹脂と混合して多種多様な成形製品の原料となるペレットを準備して,農水畜産用品や産業用品,自動車部品又は各種の容器などの射出成形,押出成形などの素材とし,すなわち,家畜の糞尿の活用で大気汚染,土壌汚染及び水質汚染を解消し,家畜の糞尿とともに合成樹脂の混合体をもって,焼却するに際して低炭素化を可能にするという効果を奏する。 The present invention mixes compost particles produced from livestock excrement with synthetic resin to prepare pellets that are raw materials for a wide variety of molded products. Using materials such as molding and extrusion molding, that is, using livestock manure to eliminate air pollution, soil pollution, and water pollution, and using a mixture of livestock manure and synthetic resin to make it possible to reduce carbon emissions when incinerating. It has the effect of

また,本発明による環境にやさしい低炭素分解性抗菌素材は,水分及び衝撃に強く,寿命を保証することができるだけではなく,焼却ないしは分解に際しての環境汚染までも極小化できるようにするという効果を奏する。 In addition, the environmentally friendly low-carbon decomposable antibacterial material according to the present invention is resistant to moisture and shock, and not only can guarantee a long life, but also has the effect of minimizing environmental pollution during incineration or decomposition. Play.

さらに,本発明は,家畜の糞尿を大鋸屑,微生物培地及び堆肥腐熟用微生物とともに混合,攪拌,発酵,後熟及び乾燥させた後,細かく砕いて堆肥粒子を用意して,大鋸屑による水分の吸収を可能にし,大鋸屑及び家畜の糞尿を微生物培地及び堆肥腐熟用微生物とともに攪拌及び発酵させて家畜の糞尿の積極的な分解を実現しながら,後熟及び乾燥をもってさらなる発酵及び分解を行うと共に,水分までも取り除いて合成樹脂との容易な結合を実現できるようにするという効果を奏する。 Furthermore, the present invention mixes, agitates, ferments, after-ripens, and dries livestock excrement with sawdust, a microbial culture medium, and microorganisms for compost rot, and then finely crushes to prepare compost particles, which absorbs moisture by sawdust. Sawdust and livestock manure are agitated and fermented with microbial media and compost-humidifying microorganisms to achieve active decomposition of livestock manure, while further fermentation and decomposition are performed by after-ripening and drying, and moisture is reached. is also removed to achieve an effect of realizing easy bonding with the synthetic resin.

さらにまた,本発明は,堆肥粒子を合成樹脂と共に混合しつつ結合剤で結合すると共に,抗菌剤で細菌を根絶しつつ分散剤で製品を成形するときの収縮率を最小化させ,かつ,スリップ剤をもって製品を成形するときの脱型が行われ易いように熱混合及び押出ししつつカットして形成されたペレットを用意することにより,農水畜産用品や産業用品,自動車部品又は各種の容器及び部品などの射出,押出又は成形などの素材,すなわち,環境にやさしい低炭素分解性抗菌素材として活用することを可能にして,水分及び衝撃に強く,寿命を保証することができるだけではなく,焼却ないしは分解に際しての環境汚染までも極小化させることができるという効果を奏する。 Furthermore, the present invention combines compost particles with a synthetic resin and binds them with a binder, eradicates bacteria with an antibacterial agent, and minimizes shrinkage when molding products with a dispersant, and prevents slippage. By preparing pellets formed by cutting while heat mixing and extruding so that it is easy to demold when molding products with agents, agricultural and livestock products, industrial products, automobile parts or various containers and parts It can be used as a material such as injection, extrusion or molding, that is, as an environmentally friendly low carbon degradable antibacterial material. There is an effect that even the environmental pollution at the time can be minimized.

本発明は,大鋸屑の中に混合されている家畜の糞尿を発酵及び分解させると共に,家畜の糞尿の発酵をさらに促してより分解させ易くすることができるという効果を奏する。 ADVANTAGE OF THE INVENTION This invention is effective in fermenting and decomposing livestock manure mixed in sawdust, and further promoting fermentation of livestock manure to make it easier to decompose.

本発明は,合成樹脂の成分に類似の性質をもって堆肥粒子と結合し易くし,ひいては,堆肥粒子及び合成樹脂をもってペレットに仕上げられるときにコーティング層をなして長期にわたって保管するときに水分に弱いという現象を克服できるようにするという効果を奏する。 The present invention makes it easy to combine with compost particles with properties similar to the components of synthetic resin, and when pellets are finished with compost particles and synthetic resin, the present invention forms a coating layer and is susceptible to moisture when stored for a long period of time. It has the effect of making it possible to overcome the phenomenon.

本発明に係る環境にやさしい低炭素分解性抗菌素材の製造方法を示す工程図である。BRIEF DESCRIPTION OF THE DRAWINGS It is process drawing which shows the manufacturing method of the environment-friendly low-carbon degradable antibacterial material which concerns on this invention. 本発明に係る環境にやさしい低炭素分解性抗菌素材の製造方法に適用される家畜の糞尿を堆肥粒子にする過程を示すフローチャートである。Fig. 2 is a flow chart showing a process of converting livestock manure into compost particles, which is applied to the production method of the environment-friendly low-carbon decomposable antibacterial material according to the present invention.

本発明の技術的な解決方法としての環境にやさしい低炭素分解性抗菌素材の製造方法は,家畜の糞尿を大鋸屑,微生物培地及び堆肥腐熟用微生物と共に混合,攪拌,発酵,後熟及び乾燥させた後,細かく砕いて堆肥粒子を準備するステップ(S10)と,
前記堆肥粒子を合成樹脂,抗菌剤,結合剤,分散剤及びスリップ剤と共に熱混合及び押出ししつつカットしてペレットを形成するステップ(S20)と,
を含み,
前記ステップS10は,
前記家畜の糞尿を前記大鋸屑,微生物培地及び堆肥腐熟用微生物と共に混合して堆肥混合物を準備するステップ(S11)と,
前記堆肥混合物に空気を注入しつつ攪拌して堆肥発酵物を準備するステップ(S12)と,
前記堆肥発酵物を後熟させて堆肥後熟物を準備するステップ(S13)と,
前記堆肥後熟物を乾燥させて堆肥乾燥物を準備するステップ(S14)と,
前記堆肥乾燥物を細かく砕いて前記堆肥粒子を準備するステップ(S15)と,
を含むことをその技術的な構成上の基本的な特徴とする。
The technical solution of the present invention is a method for producing an environmentally friendly low-carbon degradable antibacterial material, which involves mixing, stirring, fermenting, after-ripening and drying livestock manure with sawdust, microbial culture medium and compost-fermenting microorganisms. Then, a step of finely crushing to prepare compost particles (S10);
a step of cutting the compost particles with synthetic resin, antibacterial agent, binder, dispersant and slip agent while thermally mixing and extruding to form pellets (S20);
including
The step S10 is
preparing a compost mixture by mixing the livestock manure with the sawdust, microbial culture medium and compost-ripening microorganisms (S11);
preparing a fermented compost by injecting and agitating the compost mixture (S12);
a step of post-ripening the fermented compost to prepare a post-ripened compost (S13);
a step of drying the ripened compost to prepare a dried compost (S14);
a step of finely pulverizing the dried compost to prepare the compost particles (S15);
The basic feature of its technical configuration is to include

本発明に係る環境にやさしい低炭素分解性抗菌素材の製造方法の好適な実施形態について図面を参照して説明し,その実施形態として多数が存在してもよく,このような実施形態を通して本発明の目的,特徴及びメリットなどについて理解することがなお一層容易になる。 Preferred embodiments of the method for producing an environment-friendly, low-carbon decomposable antibacterial material according to the present invention will be described with reference to the drawings. It becomes even easier to understand the purpose, characteristics and merits of

本発明は,家畜の糞尿を大鋸屑,微生物培地及び堆肥腐熟用微生物と共に混合,攪拌,発酵,後熟及び乾燥させた後,細かく砕いて準備された堆肥粒子を合成樹脂,抗菌剤,結合剤,分散剤及びスリップ剤と共に熱混合及び押出ししつつカットして形成されたペレットからなる。 The present invention mixes, agitates, ferments, after-ripens, and dries livestock excreta with sawdust, a microbial culture medium, and microorganisms for compost rot, and then finely crushes the prepared compost particles into a synthetic resin, an antibacterial agent, and a binder. , pellets formed by hot mixing and extruding with a dispersant and a slip agent.

家畜の糞尿は,大気汚染,土壌汚染及び水質汚染の主な要因となっており,これと同様に,合成樹脂もまた数十年乃至数百年経っても腐らないばかりではなく,焼却する際に二酸化炭素が飛散して大気を甚だしく汚染しながら,人体に致命的な環境汚染を引き起こす主因となっている。 Livestock manure is a major cause of air pollution, soil pollution and water pollution.Similarly, synthetic resin not only does not decompose even after tens or hundreds of years, but also when incinerated. It is the main cause of environmental pollution that is deadly to the human body as it pollutes the atmosphere severely by scattering carbon dioxide in the atmosphere.

このような事情に鑑みて,本発明は,家畜の糞尿をもって製造した堆肥粒子を合成樹脂と混合して多種多様な成形製品の原料となるペレットを準備し,農水畜産用品や産業用品,自動車部品又は各種の産業容器などの射出成形,押出成形などの素材とし,すなわち,家畜の糞尿の活用で大気汚染,土壌汚染及び水質汚染を解消し,家畜の糞尿と共に合成樹脂の混合体をもって,焼却するに際して低炭素で行うことを可能にした環境にやさしい低炭素分解性抗菌素材として活用するようにして,水分及び衝撃に強く,寿命を保証することができるだけではなく,焼却ないしは分解に際しての環境汚染までも極小化できるようにした発明である。 In view of such circumstances, the present invention prepares pellets that are raw materials for a wide variety of molded products by mixing compost particles produced from livestock excrement with synthetic resin, and prepares pellets that can be used as raw materials for agricultural and livestock products, industrial products, and automobile parts. Alternatively, it can be used as a material for injection molding, extrusion molding, etc. for various industrial containers, that is, by using livestock manure to eliminate air pollution, soil pollution, and water pollution, and incinerating a mixture of livestock manure and synthetic resin. By using it as an environmentally friendly low-carbon decomposable antibacterial material that makes it possible to perform low-carbon decomposing, it is resistant to moisture and shock, and not only can it guarantee a long life, but also environmental pollution during incineration or decomposition. It is an invention that enables the minimization of

特に,家畜の糞尿を大鋸屑,微生物培地及び堆肥腐熟用微生物と共に混合,攪拌,発酵,後熟及び乾燥させた後,粉砕して堆肥粒子を準備することにより,大鋸屑による水分の吸収を可能にし,大鋸屑及び家畜の糞尿を微生物培地及び堆肥腐熟用微生物と共に攪拌及び発酵させて家畜の糞尿の積極的な分解を実現しつつ,後熟及び乾燥をもってさらなる発酵及び分解を行うと共に,水分までも取り除いて合成樹脂との結合しやすさを実現できるようにする。 In particular, livestock manure is mixed, agitated, fermented, after-ripened and dried with sawdust, microbial media and compost-ripening microorganisms, and then ground to prepare compost particles, thereby allowing the sawdust to absorb moisture, Sawdust and livestock manure are agitated and fermented together with microbial culture medium and microorganisms for compost fermentation to actively decompose livestock manure. To enable easy bonding with a synthetic resin.

このように細かく砕かれて準備された堆肥粒子を合成樹脂と共に混合しつつ結合剤で結合すると共に,抗菌剤で細菌を根絶しつつ分散剤で製品を成形するときの収縮率を最小化させ,かつ,スリップ剤をもって製品を成形するときの脱型が行われ易いように熱混合及び押出ししつつカットして形成されたペレットを準備することにより,農水畜産用品や産業用品,自動車部品又は各種の産業容器及び産業部品などの射出成形,押出成形などの素材,すなわち,環境にやさしい低炭素分解性抗菌成形素材として活用することを可能にして,水分及び衝撃に強く,寿命を保証することができるだけではなく,焼却ないしは分解に際しての環境汚染までも極小化できるようにする。 The finely ground compost particles are mixed with a synthetic resin and bonded with a binder, and the antibacterial agent eradicates bacteria and the dispersant minimizes the shrinkage rate when molding the product, In addition, by preparing pellets formed by cutting while heat mixing and extruding so that it is easy to demold when molding products with a slip agent, agricultural and livestock products, industrial products, automobile parts or various It can be used as a material for injection molding, extrusion molding, etc. for industrial containers and industrial parts, that is, as an environment-friendly, low-carbon decomposable antibacterial molding material. Instead, the environmental pollution caused by incineration or decomposition can be minimized.

このとき,微生物培地は,キノコ培地であり,堆肥腐熟用微生物は,バシラス及び乳酸菌であってもよく,具体的には,キノコ培地は,大鋸屑の中に混合されている家畜の糞尿を容易に発酵及び分解させ,バシラス及び乳酸菌は,大鋸屑の中に混合されている家畜の糞尿の発酵を促してさらに分解させ易くする。 At this time, the microbial medium is a mushroom medium, and the microorganisms for composting may be Bacillus and lactic acid bacteria. Fermentation and decomposition, Bacillus and lactic acid bacteria promote fermentation of livestock manure mixed in sawdust to facilitate further decomposition.

好ましくは,堆肥粒子にアクリル粉末をさらに加えて,合成樹脂の成分に似た性質をもって堆肥粒子と結合し易くし,ひいては,堆肥粒子に流動パラフィンなどの油分をさらに加えてペレットに仕上げられるときにコーティング層をなして長期にわたって保管するときに水分に弱いという現象を克服できるようにする。 Preferably, acrylic powder is further added to the compost particles to make it easier to bond with the compost particles with properties similar to the components of synthetic resin. To overcome the phenomenon of being vulnerable to moisture when a coating layer is formed and stored for a long period of time.

好ましくは,堆肥粒子は,家畜の糞尿66~75wt%,大鋸屑10~17wt%,微生物培地11~17wt%,堆肥腐熟用微生物0.1~0.7wt%を含む。 Preferably, the compost particles comprise 66-75 wt% livestock manure, 10-17 wt% sawdust, 11-17 wt% microbial medium, and 0.1-0.7 wt% compost-ripening microorganisms.

家畜の糞尿は,66wt%以下である場合,ペレットを形成する上で環境汚染の防止に対する効率が低く,75wt%以上である場合,水分を過剰に含有してしまうため好ましくなく,大鋸屑は,10wt%以下である場合,家畜の糞尿の水分を低減し難く,17wt%以上である場合,相対的に家畜の糞尿の組成比が低くなるため,ペレットを形成する上で効率性が低く,微生物培地は,11wt%以下である場合に発酵率が低く,17wt%以上である場合,むしろ大鋸屑を腐敗させ過ぎるため好ましくなく,堆肥腐熟用微生物は,0.1wt%以下である場合,発酵率及び腐熟率が低く,0.7wt%以上である場合,大鋸屑を腐敗させ過ぎるため好ましくない。 If the amount of livestock manure is 66 wt% or less, the efficiency of preventing environmental pollution in forming pellets is low, and if it is 75 wt% or more, it is not preferable because it contains excessive moisture. % or less, it is difficult to reduce the water content of livestock manure, and if it is 17 wt% or more, the composition ratio of livestock manure is relatively low, so the efficiency in forming pellets is low, and the microbial culture medium is 11 wt% or less, the fermentation rate is low. If the ratio is low, 0.7 wt % or more, it is not preferable because the sawdust is spoiled too much.

因みに,家畜の糞尿は,牛糞50~58wt%,豚糞2~8wt%,鶏糞6~15wt%を含んでいてもよい。 Incidentally, livestock manure may contain 50 to 58 wt% of cow manure, 2 to 8 wt% of pig manure, and 6 to 15 wt% of chicken manure.

牛糞は,繊維質に富んでいるため,50wt%以下である場合,相対的に繊維質が少ない豚糞及び鶏糞の組成比が高くなるため好ましくなく,58wt%以上である場合,環境汚染の主犯である豚糞及び牛糞が占める組成比が低くなるため好ましくなく,豚糞は,水分の含有量が高いことを考慮して,最小2wt%,且つ,最大8wt%に限定し,ひいては,鶏糞もまた,豚糞よりは少ないものの,水分の含有量が高いため,最小6wt%,かつ,最大15wt%に限定する。 Cow dung is rich in fiber, so if it is less than 50 wt%, it is not preferable because the composition ratio of pig manure and chicken manure, which are relatively low in fiber, becomes high. It is not preferable because the composition ratio of pig manure and cow manure is low. Also, although it is less than pig feces, it has a high water content, so the minimum is 6 wt% and the maximum is 15 wt%.

一方,ペレットは,堆肥粒子30~50wt%,合成樹脂30~50wt%,抗菌剤5~10wt%,結合剤2~3wt%,分散剤10~20wt%,スリップ剤0.5~1wt%,アクリル粉末0.1~1wt%,油分0.5~1wt%を含む。 On the other hand, pellets consist of compost particles 30-50 wt%, synthetic resin 30-50 wt%, antibacterial agent 5-10 wt%, binder 2-3 wt%, dispersant 10-20 wt%, slip agent 0.5-1 wt%, acrylic Contains 0.1-1 wt% powder and 0.5-1 wt% oil.

環境汚染源である家畜の糞尿を大鋸屑,微生物培地及び堆肥腐熟用微生物と共に混合,攪拌,発酵,後熟及び乾燥させた後,細かく砕いて準備された堆肥粒子と,環境汚染源である合成樹脂を,堆肥粒子の割合と同じ割合である30~50wt%にして,堆肥粒子の弱い物性,すなわち,強度に弱い物性を合成樹脂をもって補う一方で,合成樹脂(ポリエチレン(PE),ポリプロピレン(PP)又はポリエチレンテレフタレート(PET))の弱い物性,すなわち,数十年乃至数百年経っても腐らない物性を堆肥粒子をもって補って,大気汚染,土壌汚染,水質汚染などの環境汚染を最小化できるようにする。 Compost particles prepared by mixing, stirring, fermenting, after-ripening, and drying livestock manure, which is the source of environmental pollution, with sawdust, microbial culture medium, and microorganisms for compost rot, and then finely crushed and prepared, and synthetic resin, which is the source of environmental pollution, At 30 to 50 wt%, which is the same ratio as the compost particles, the weak physical properties of the compost particles, that is, the weak physical properties of the compost particles are supplemented with a synthetic resin, while the synthetic resin (polyethylene (PE), polypropylene (PP) or polyethylene Compost particles compensate for the weak physical properties of terephthalate (PET), that is, the physical properties that do not rot even after tens to hundreds of years, so that environmental pollution such as air pollution, soil pollution, and water pollution can be minimized. .

抗菌剤としては,堆肥粒子の中に含有されている各種の菌を滅菌させるためにポゾランを適用することができ,このようなポゾラン(Pozzolan)は,遠赤外線の波長率が93~94%であり,かつ,ゲルマニウム3~4ppmのアルカリ成分を有していることから,空気の浄化,殺菌作用,重金属の浄化,悪臭の除去,脱臭,毒性の中和などの効能に優れており,その結果,牛糞,豚糞及び鶏糞の中に存在する各種の細菌を消滅させてなお一層安全に使用できるようにし,5wt%以下である場合,滅菌効果が低く,さらに,抗菌の最大値である10wt%以下に限定する。 As an antibacterial agent, pozzolans can be applied to sterilize various bacteria contained in compost particles. And since it has an alkaline component of 3 to 4 ppm germanium, it has excellent effects such as air purification, sterilization, heavy metal purification, odor removal, deodorization, and neutralization of toxicity. , cow manure, pig manure, and chicken manure to eliminate various bacteria and make them safer to use. Limited to:

結合剤としては,堆肥粒子及び合成樹脂の相互間の強固な結合のために無水マレイン酸(Maleic Anhydride)を適用することができ,このような無水マレイン酸は,熱混合及び熱攪拌に際して合成樹脂及び堆肥粒子の融合を可能にし,2wt%以下である場合,堆肥粒子及び合成樹脂の相互間の結合力を保つことができず,約3wt%である場合,堆肥粒子及び合成樹脂の相互間の結合力を最大限に保つことができるため好ましい。 As a binder, maleic anhydride can be applied for strong bonding between the compost particles and the synthetic resin. and enable the fusion of compost particles, and if it is 2 wt% or less, the bonding force between the compost particles and the synthetic resin cannot be maintained, and if it is about 3 wt%, the compost particles and the synthetic resin It is preferable because it can keep the binding strength to the maximum.

分散剤としては,堆肥粒子及び合成樹脂の相互間の結合により準備されたペレットを活用して,各種の農水畜産用品や産業部品を射出,押出又は成形した後に硬化させるときに収縮による誤差を最小化させるために,すなわち,収縮率を最小化させるために,白雲石パウダーを適用することができ,このような白雲石パウダーは,その固有の成分である酸化カルシウム(CaO)及び酸化マグネシウム(MgO)を通して堆肥粒子及び合成樹脂の中に含有されてペレットとして準備された後,産業部品を製作するときにその収縮率を最小化させる作用をするものであって,10wt%以下である場合,収縮率が低く,20wt%までである場合に,収縮率を最適にすることができるため好ましい。 As a dispersant, pellets prepared by bonding between compost particles and synthetic resin are used to minimize errors due to shrinkage when curing after injection, extrusion or molding of various agricultural and livestock products and industrial parts. Dolomite powders can be applied to minimize shrinkage, i.e., to minimize shrinkage, such dolomite powders containing their inherent constituents calcium oxide (CaO) and magnesium oxide (MgO). ) to minimize the shrinkage rate when manufacturing industrial parts after being contained in compost particles and synthetic resin and prepared as pellets. A low modulus, up to 20 wt%, is preferred as this allows for optimum shrinkage.

スリップ剤としては,堆肥粒子及び合成樹脂の相互間の結合により準備されたペレットを活用して,各種の農水畜産用品や産業部品を射出,押出又は成形した後に硬化させるときに表面の摺動性(滑り性)を向上させて脱型が行われ易いように,アミド系スリップ剤を適用することができ,このようなアミド系スリップ剤としては,脂肪酸から合成されたアミド系の高い融点を有し,ヒドロキシル(Hydroxyl)基がアミノ(Amino)構造に置換されて中性的な構造を有している化合物を用いることができる。 As a slip agent, pellets prepared by bonding between compost particles and synthetic resin are used to improve surface slidability when hardening after injection, extrusion or molding of various agricultural and livestock products and industrial parts. An amide-based slip agent can be applied to improve slipperiness (slipperiness) and make demolding easier. However, a compound having a neutral structure in which the hydroxyl group is substituted with an amino structure can be used.

アミド系スリップ剤の例としては,エルカミド(erucamide),オレアミド(Oleamide),ベヘンアミド(behenamide),ステアラミド(stearamide),ステアリルステアラミド(stearyl stearamidel),ステアリルエルカミド(stearyl erucamide),オレイルパルミチルアミド(oleylpalmityl amide)が挙げられ,これらのアミド系スリップ剤は,堆肥粒子及び合成樹脂の中に含有されてペレットとして準備された後,産業部品を製作するときに金型から脱型され易くするものであって,0.5wt%以下である場合,脱型し難く,1wt%までである場合,最適に脱型することができるため好ましい。 Examples of amide slip agents include erucamide, oleamide, behenamide, stearamide, stearyl stearamide, stearyl erucamide, oleyl palmitylamide ( oleylpalmityl amide), and these amide-based slip agents are contained in compost particles and synthetic resins, and after being prepared as pellets, are made easier to release from molds when manufacturing industrial parts. When the content is 0.5 wt % or less, it is difficult to release the mold.

アクリル粉末は,合成樹脂の成分に似た性質をもって堆肥粒子と結合し易くするものであって,0.1wt%以下である場合,合成樹脂及び堆肥粒子の相互間の結合力に影響を及ぼすことができず,1wt%までである場合,堆肥粒子及び合成樹脂の相互間の結合力を最適にすることができるため好ましい。 Acrylic powder has properties similar to the components of synthetic resin and facilitates bonding with compost particles. If the amount is 0.1 wt% or less, it will affect the bonding force between the synthetic resin and compost particles. is not possible and the content is up to 1 wt %, the bonding strength between the compost particles and the synthetic resin can be optimized, which is preferable.

油分は,ペレットに仕上げられるときにコーティング層をなして長期にわたって保管するときに水分に弱いという現象を克服できるようにするものであって,油分として流動パラフィンを適用することができ,このような流動パラフィンは,0.5wt%以下である場合にコーティング力を発揮することができず,1wt%までである場合,ペレットのコーティング力を最適にすることができるため好ましい。 The oil makes it possible to overcome the phenomenon of being vulnerable to moisture when it is stored for a long time by forming a coating layer when it is finished into pellets, and liquid paraffin can be applied as the oil. If the liquid paraffin content is less than 0.5 wt %, the coating power cannot be exhibited.

図1は,本発明の製造方法を示す工程図であり,図2は,本発明に係る環境にやさしい低炭素分解性抗菌素材の製造方法に適用された家畜の糞尿を堆肥粒子にする過程を示すフローチャートである。
FIG. 1 is a process diagram showing the production method of the present invention , and FIG. 2 shows the process of converting livestock manure into compost particles applied to the production method of the environmentally friendly low-carbon degradable antibacterial material according to the present invention. It is a flow chart showing.

本発明に係る環境にやさしい低炭素分解性抗菌素材の製造方法は,図1に示すように,家畜の糞尿を大鋸屑,微生物培地及び堆肥腐熟用微生物と共に混合,攪拌,発酵,後熟及び乾燥させた後,細かく砕いて堆肥粒子を準備し(S10),堆肥粒子に合成樹脂,抗菌剤,結合剤,分散剤及びスリップ剤と共に熱混合及び押出ししつつカットしてペレットを形成する工程(S20)からなる。 As shown in FIG. 1, the method for producing an environment-friendly low-carbon decomposable antibacterial material according to the present invention involves mixing, stirring, fermenting, after-ripening, and drying livestock manure with sawdust, a microbial culture medium, and microorganisms for compost rot. After that, the compost particles are finely ground to prepare compost particles (S10), and the compost particles are thermally mixed with a synthetic resin, an antibacterial agent, a binder, a dispersant and a slip agent, extruded and cut to form pellets (S20). consists of

家畜の糞尿を大鋸屑,微生物培地及び堆肥腐熟用微生物と共に混合,攪拌,発酵,後熟及び乾燥させた後,細かく砕いて堆肥粒子を準備するステップ(S10)により,大鋸屑による水分の吸収を可能にし,大鋸屑及び家畜の糞尿を微生物培地及び堆肥腐熟用微生物と共に攪拌及び発酵させて家畜の糞尿の積極的な分解を実現しながら,後熟及び乾燥をもってさらなる発酵及び分解を行うと共に,水分までも取り除いて合成樹脂との結合しやすさを実現できるようにし,ひいては,このように細かく砕かれて準備された堆肥粒子を合成樹脂と共に混合しつつ結合剤で結合すると共に,抗菌剤で細菌を根絶しつつ分散剤で製品を成形するときの収縮率を最小化させ,かつ,スリップ剤をもって製品を成形するときの脱型が行われ易いように熱混合及び押出しつつカットして形成されたペレットを形成するステップ(S20)により,環境にやさしい低炭素分解性抗菌素材を準備して,後続する農水畜産用品や産業用品,自動車部品又は各種の容器などの射出,押出又は成形などを可能にし,このような製品を通して,水分及び衝撃に強く,寿命を保証することができるだけではなく,焼却ないしは分解に際しての環境汚染までも極小化させることが可能になる。 After mixing, agitating, fermenting, after-ripening and drying livestock manure with sawdust, microbial culture medium and microorganisms for compost rot, the step of finely grinding to prepare compost particles (S10) enables the sawdust to absorb moisture. , Sawdust and livestock manure are agitated and fermented with microbial media and microorganisms for compost fermentation to actively decompose livestock manure, while further fermentation and decomposition are performed by after-ripening and drying, and even moisture is removed. In addition, the compost particles finely crushed and prepared in this way are mixed with the synthetic resin and bound with a binder, and the bacteria are eradicated with an antibacterial agent. In order to minimize shrinkage when molding a product with a dispersant and to facilitate demolding when molding a product with a slip agent, pellets are formed by cutting while hot mixing and extruding. By the step (S20) of preparing an environment-friendly low-carbon degradable antibacterial material to enable subsequent injection, extrusion or molding of agricultural and livestock products, industrial products, automobile parts, various containers, etc. Through such a product, it is possible not only to ensure a long service life by being resistant to moisture and shock, but also to minimize environmental pollution caused by incineration or decomposition.

より具体的に,前記ステップS10は,図2に示すように,家畜の糞尿を大鋸屑,微生物培地及び堆肥腐熟用微生物と共に混合して堆肥混合物を準備し(S11),堆肥混合物に空気を注入しつつ攪拌して堆肥発酵物を準備し(S12),堆肥発酵物を後熟させて堆肥後熟物を準備し(S13),堆肥後熟物を乾燥させて堆肥乾燥物を準備した後(S14),堆肥乾燥物を細かく砕いて堆肥粒子を準備するステップ(S15)からなる。 More specifically, the step S10 includes, as shown in FIG. 2, preparing a compost mixture by mixing livestock manure with sawdust, a microbial culture medium, and compost-fermenting microorganisms (S11), and injecting air into the compost mixture. A fermented compost is prepared by stirring while stirring (S12), the fermented compost is post-ripened to prepare a post-ripened compost (S13), and the post-ripened compost is dried to prepare a dried compost (S14). ) and a step of finely pulverizing the dried compost to prepare compost particles (S15).

家畜の糞尿を大鋸屑,微生物培地及び堆肥腐熟用微生物と共に混合して堆肥混合物を準備した後,この堆肥混合物に空気を注入しつつ攪拌して堆肥発酵物を準備することにより,攪拌に際して空気による堆肥混合物の均一な発酵が可能になり,このような堆肥発酵物を貯蔵庫において再び後熟させて,すなわち,再び熟成させて十分に発酵された堆肥後熟物を準備した後,乾燥させて堆肥乾燥物にし,次いで,これらの堆肥乾燥物を細かく砕いて堆肥粒子を準備した後,合成樹脂と結合し易くする。 After preparing a compost mixture by mixing livestock manure with sawdust, a microbial culture medium and microorganisms for compost rottenness, the compost mixture is agitated while injecting air into the compost mixture to prepare a fermented compost. Uniform fermentation of the mixture is enabled and such compost fermented product is re-ripened in storage, i.e. re-ripened to provide a fully fermented composted post-ripe product and then dried to compost dry. These compost granules are then finely ground to prepare compost particles, which are then facilitated to bond with the synthetic resin.

このとき,前記ステップS11において,堆肥混合物は,水分の含有量を50~70%にし,前記ステップS12において,堆肥発酵物は,堆肥混合物を2ヵ月間発酵させて,水分の含有量を40~45%にし,前記ステップS13において,堆肥後熟物は,堆肥発酵物を2ヵ月間後熟させて,水分の含有量を35~40%にし,前記ステップS14において,堆肥乾燥物は,堆肥後熟物を乾燥させて,水分の含有量を5~10%にし,前記ステップS15において,堆肥粒子は,堆肥乾燥物を砕いて,粒径を70~90meshにする。 At this time, in step S11, the compost mixture has a water content of 50 to 70%, and in step S12, the fermented compost mixture is fermented for two months to have a water content of 40 to 40%. In step S13, the post-compost ripening product is obtained by post-ripening the fermented compost for two months to make the water content 35 to 40%, and in step S14, the dried compost product is the post-composting product. The dried compost is dried to a moisture content of 5-10%, and in step S15, the compost particles are crushed to a particle size of 70-90 mesh.

具体的に,家畜の糞尿は,ほとんどが水分からなるが,本発明においては,大鋸屑を入れて水分の含有量を50~70%に調整し,このとき,水分の含有量が50%以下である場合,大鋸屑が多くなり過ぎて合成樹脂と結合され難く,水分の含有量が70%以上である場合,発酵及び後熟が行われ難いため好ましくない。 Specifically, livestock manure consists mostly of water. In the present invention, sawdust is added to adjust the water content to 50 to 70%. In some cases, sawdust is too much to be combined with the synthetic resin, and if the moisture content is more than 70%, fermentation and after-ripening are difficult, which is undesirable.

次いで,堆肥混合物を2ヵ月間十分に発酵させて水分の含有量を40~45%に低くして堆肥発酵物を準備し,再び堆肥発酵物を2ヵ月間貯蔵庫において十分に後熟させて水分の含有量が35~40%である堆肥後熟物を準備し,再び堆肥後熟物を乾燥させて水分の含有量が5~10%である堆肥乾燥物を準備した後,70~90meshに細かく砕いて合成樹脂と結合し易くする。 Then, the compost mixture is fully fermented for 2 months to reduce the moisture content to 40-45% to prepare a fermented compost, and the fermented compost is again fully after-ripened in the storage for 2 months to remove moisture. Prepare a compost-ripened product with a content of 35-40%, dry the compost-ripened product again to prepare a compost-dried product with a moisture content of 5-10%, and then divide it into 70-90 mesh. It is crushed finely to make it easier to bond with the synthetic resin.

一方,前記ステップS10において,微生物培地は,キノコ培地であり,前記ステップS10において,堆肥腐熟用微生物は,バシラス及び乳酸菌であってもよい。 On the other hand, in step S10, the microorganism medium may be a mushroom medium, and in step S10, the compost-fermenting microorganisms may be bacillus and lactic acid bacteria.

キノコ培地は,大鋸屑の中に混合されている家畜の糞尿を発酵及び分解させ,バシラス及び乳酸菌もまた,大鋸屑の中に混合されている家畜の糞尿の発酵を促してさらに分解され易くする。 The mushroom medium ferments and decomposes the livestock manure mixed in the sawdust, and Bacillus and lactic acid bacteria also promote fermentation of the livestock manure mixed in the sawdust to facilitate further decomposition.

さらに,前記ステップS20において,堆肥粒子にアクリル粉末をさらに加えて,合成樹脂の成分に似た性質をもって堆肥粒子と結合し易くし,ひいては,前記ステップS20において,堆肥粒子に流動パラフィンなどの油分をさらに加えてペレットに仕上げられるときにコーティング層をなして長期にわたって保管するときに水分に弱いという現象を克服できるようにする。 Further, in step S20, acrylic powder is further added to the compost particles to facilitate binding with the compost particles with a property similar to the component of synthetic resin. In addition, when the pellets are finished, a coating layer is formed to overcome the phenomenon that the pellets are vulnerable to moisture when stored for a long period of time.

一方,前記ステップS10において,堆肥粒子は,家畜の糞尿66~75wt%,大鋸屑10~17wt%,微生物培地11~17wt%,堆肥腐熟用微生物0.1~0.7wt%を含んでいてもよい。 On the other hand, in step S10, the compost particles may contain 66 to 75 wt% of livestock manure, 10 to 17 wt% of sawdust, 11 to 17 wt% of microbial culture medium, and 0.1 to 0.7 wt% of microorganisms for compost ripening. .

家畜の糞尿は,66wt%以下である場合,ペレットを形成する上で効率性が低く,75wt%以上である場合,水分を過剰に含有してしまうため好ましくなく,大鋸屑は,10wt%以下である場合,家畜の糞尿の水分を希釈し難く,17wt%以上である場合,相対的に家畜の糞尿の組成比が低くなるため,ペレットを形成する上で効率性が低く,微生物培地は,11wt%以下である場合,発酵率が低く,17wt%以上である場合,むしろ大鋸屑を腐敗させ過ぎるため好ましくなく,堆肥腐熟用微生物は,0.1wt%以下である場合,発酵率及び腐熟率が低く,0.7wt%以上である場合,大鋸屑を腐敗させ過ぎるため好ましくない。 If the manure of livestock is less than 66 wt%, the efficiency in forming pellets is low, and if it is more than 75 wt%, it is not preferable because it contains excessive moisture. In this case, it is difficult to dilute the water content of livestock manure, and if it is 17 wt% or more, the composition ratio of livestock manure is relatively low, so the efficiency in forming pellets is low, and the microbial medium is 11 wt%. If it is 17 wt% or more, the fermentation rate is low, and if it is 17 wt% or more, it is not preferable because it causes the sawdust to rot excessively. If it is 0.7 wt % or more, it is not preferable because the sawdust is spoiled too much.

因みに,前記ステップS10において,家畜の糞尿は,牛糞50~58wt%,豚糞2~8wt%,鶏糞6~15wt%を含んでいてもよい。 Incidentally, in step S10, the manure of livestock may contain 50 to 58 wt% of cow manure, 2 to 8 wt% of pig manure, and 6 to 15 wt% of chicken manure.

牛糞は,繊維質に富んでいるため,50wt%以下である場合,相対的に繊維質が少ない豚糞及び鶏糞の組成比が高くなるため好ましくなく,58wt%以上である場合,環境汚染の主犯である豚糞及び牛糞が占める組成比が低くなるため好ましくなく,豚糞は,水分の含有量が高いことを考慮して,最小2wt%,かつ,最大8wt%に限定し,ひいては,鶏糞もまた,豚糞よりは少ないものの,水分の含有量が高いため,最小6wt%,かつ,最大15wt%に限定する。 Cow dung is rich in fiber, so if it is less than 50 wt%, it is not preferable because the composition ratio of pig manure and chicken manure, which are relatively low in fiber, becomes high. It is not preferable because the composition ratio of pig manure and cow manure, which is the Also, although it is less than pig feces, it has a high water content, so the minimum is 6 wt% and the maximum is 15 wt%.

前記ステップS20において,ペレットは,堆肥粒子30~50wt%,合成樹脂30~50wt%,抗菌剤5~10wt%,結合剤2~3wt%,分散剤10~20wt%,スリップ剤0.5~1wt%,アクリル粉末0.1~1wt%,油分0.5~1wt%を熱混合及び押出ししつつカットして形成される。 In step S20, the pellets are composed of 30-50 wt% compost particles, 30-50 wt% synthetic resin, 5-10 wt% antibacterial agent, 2-3 wt% binder, 10-20 wt% dispersant, and 0.5-1 wt% slip agent. %, acrylic powder 0.1-1 wt%, and oil content 0.5-1 wt% are cut while hot mixing and extruding.

環境汚染源である家畜の糞尿を大鋸屑,微生物培地及び堆肥腐熟用微生物と共に混合,攪拌,発酵,後熟及び乾燥させた後,細かく砕いて準備された堆肥粒子と,環境汚染源である合成樹脂を堆肥粒子の割合と同じ割合である30~50wt%にして,堆肥粒子の弱い物性,すなわち,強度に弱い物性を合成樹脂をもって補う一方で,合成樹脂(ポリエチレン(PE),ポリプロピレン(PP)又はポリエチレンテレフタレート(PET))の弱い物性,すなわち,数十年乃至数百年経っても腐らない物性を堆肥粒子をもって補って,大気汚染,土壌汚染,水質汚染などの環境汚染を最小化できるようにする。 Compost is prepared by mixing, agitating, fermenting, after-ripening, and drying livestock manure, which is a source of environmental pollution, with sawdust, a microbial culture medium, and microorganisms for compost rot, and then crushing it finely, and composting synthetic resin, which is a source of environmental pollution. The ratio of 30 to 50 wt%, which is the same as the ratio of particles, is used to compensate for the weak physical properties of compost particles, that is, the physical properties that are weak in strength, with synthetic resins (polyethylene (PE), polypropylene (PP), or polyethylene terephthalate). (PET)), which does not rot even after tens to hundreds of years, is supplemented with compost particles to minimize environmental pollution such as air pollution, soil pollution, and water pollution.

好ましくは,前記ステップS20において,熱混合は,70~80℃の温度で15~30分間行われて,堆肥粒子及び合成樹脂を混合し易くし,このとき,70℃以下及び18分以下である場合,堆肥粒子の中に合成樹脂が円滑に混合されないため好ましくなく,80℃以上及び30分以上である場合,堆肥粒子に合成樹脂が均一に混合される前に合成樹脂が溶融されてしまうという現象が生じるため好ましくない。 Preferably, in step S20, the thermal mixing is performed at a temperature of 70-80°C for 15-30 minutes to facilitate mixing of the compost particles and the synthetic resin, at which time is 70°C or less and 18 minutes or less. In this case, the synthetic resin is not mixed smoothly into the compost particles, and if the temperature is above 80°C and for more than 30 minutes, the synthetic resin will be melted before the synthetic resin is evenly mixed with the compost particles. It is not preferable because it causes a phenomenon.

さらに,前記ステップS20において,押出しは,160~190℃の温度で行われるようにして,堆肥粒子入り合成樹脂が160℃から190℃に至るまで容易に溶融されながら速やかに押出しできるようにする。 Further, in step S20, the extrusion is performed at a temperature of 160 to 190.degree.

本発明は,土壌汚染,地下水の汚染,大気汚染などの環境汚染を防ぐと共に,各種の農水畜産用品や産業部品を合成樹脂で製作しようとする産業分野において利用可能である。 INDUSTRIAL APPLICABILITY The present invention can be used in industrial fields to prevent environmental pollution such as soil pollution, groundwater pollution, air pollution, etc., and to produce various agricultural and livestock products and industrial parts from synthetic resin.

Claims (12)

家畜の糞尿を大鋸屑,微生物培地及び堆肥腐熟用微生物と共に混合,攪拌,発酵,後熟及び乾燥させた後,細かく砕いて堆肥粒子を準備するステップ(S10)と,
前記堆肥粒子を合成樹脂,抗菌剤,結合剤,分散剤及びスリップ剤と共に熱混合及び押出ししつつカットしてペレットを形成するステップ(S20)と,
を含み,
前記ステップS10は,
前記家畜の糞尿を前記大鋸屑,微生物培地及び堆肥腐熟用微生物と共に混合して堆肥混合物を準備するステップ(S11)と,
前記堆肥混合物に空気を注入しつつ攪拌して堆肥発酵物を準備するステップ(S12)と,
前記堆肥発酵物を後熟させて堆肥後熟物を準備するステップ(S13)と,
前記堆肥後熟物を乾燥させて堆肥乾燥物を準備するステップ(S14)と,
前記堆肥乾燥物を細かく砕いて前記堆肥粒子を準備するステップ(S15)と,
を含むことを特徴とする環境にやさしい低炭素分解性抗菌素材の製造方法。
a step of mixing, stirring, fermenting, after-ripening and drying livestock manure with sawdust, microbial culture medium and compost-ripening microorganisms, and then finely grinding to prepare compost particles (S10);
a step of cutting the compost particles with synthetic resin, antibacterial agent, binder, dispersant and slip agent while thermally mixing and extruding to form pellets (S20);
including
The step S10 is
preparing a compost mixture by mixing the livestock manure with the sawdust, microbial culture medium and compost-ripening microorganisms (S11);
preparing a fermented compost by injecting and agitating the compost mixture (S12);
a step of post-ripening the fermented compost to prepare a post-ripened compost (S13);
a step of drying the ripened compost to prepare a dried compost (S14);
a step of finely pulverizing the dried compost to prepare the compost particles (S15);
A method for producing an environmentally friendly low-carbon decomposable antibacterial material, comprising:
前記ステップS11において,前記堆肥混合物は,水分の含有量を50~70%にし,
前記ステップS12において,前記堆肥発酵物は,前記堆肥混合物を2ヵ月間発酵させて,水分の含有量を40~45%にし,
前記ステップS13において,前記堆肥後熟物は,前記堆肥発酵物を2ヵ月間後熟させて,水分の含有量を35~40%にし,
前記ステップS14において,前記堆肥乾燥物は,前記堆肥後熟物を乾燥させて,水分の含有量を5~10%にし,
前記ステップS15において,前記堆肥粒子は,前記堆肥乾燥物を砕いて,粒径を70~90meshにすることを特徴とする請求項記載の環境にやさしい低炭素分解性抗菌素材の製造方法。
In step S11, the compost mixture has a water content of 50 to 70%,
In the step S12, the fermented compost is obtained by fermenting the compost mixture for two months to have a water content of 40 to 45%,
In step S13, the compost-ripened product is obtained by post-ripening the compost-fermented product for two months to have a water content of 35 to 40%,
In the step S14, the dried compost is obtained by drying the post-compost ripened product to have a water content of 5 to 10%,
2. The method for producing an environment-friendly low-carbon decomposable antibacterial material according to claim 1 , wherein in said step S15, said compost particles are produced by crushing said dried compost to a particle size of 70-90 mesh.
前記ステップS10において,前記微生物培地は,キノコ培地であることを特徴とする請求項記載の環境にやさしい低炭素分解性抗菌素材の製造方法。 2. The method of claim 1 , wherein in step S10, the microorganism culture medium is a mushroom culture medium. 前記ステップS10において,前記堆肥腐熟用微生物は,バシラス及び乳酸菌であることを特徴とする請求項記載の環境にやさしい低炭素分解性抗菌素材の製造方法。 2. The method for producing an environment-friendly low-carbon degradable antibacterial material according to claim 1, wherein in said step S10, said compost-fermenting microorganisms are bacillus and lactic acid bacteria. 前記ステップS20において,前記堆肥粒子にアクリル粉末をさらに加えることを特徴とする請求項乃至請求項いずれか一項に記載の環境にやさしい低炭素分解性抗菌素材の製造方法。 5. The method of claim 1 , wherein acrylic powder is further added to the compost particles in step S20. 前記ステップS20において,前記堆肥粒子に油分をさらに加えることを特徴とする請求項記載の環境にやさしい低炭素分解性抗菌素材の製造方法。 6. The method of claim 5 , wherein in step S20, oil is further added to the compost particles. 前記ステップS20において,前記油分は,流動パラフィンであることを特徴とする請求項記載の環境にやさしい低炭素分解性抗菌素材の製造方法。 7. The method for producing an environment-friendly low-carbon degradable antibacterial material according to claim 6 , wherein in said step S20, said oil is liquid paraffin. 前記ステップS10において,前記堆肥粒子は,前記家畜の糞尿66~75wt%,前記大鋸屑10~17wt%,前記微生物培地11~17wt%,前記堆肥腐熟用微生物0.1~0.7wt%を含むことを特徴とする請求項記載の環境にやさしい低炭素分解性抗菌素材の製造方法。 In step S10, the compost particles contain 66 to 75 wt% of the livestock manure, 10 to 17 wt% of the sawdust, 11 to 17 wt% of the microbial medium, and 0.1 to 0.7 wt% of the compost-fermenting microorganisms. The method for producing an environmentally friendly low-carbon decomposable antibacterial material according to claim 6 , characterized by: 前記ステップS10において,前記家畜の糞尿は,牛糞50~58wt%,豚糞2~8wt%,鶏糞6~15wt%を含むことを特徴とする請求項記載の環境にやさしい低炭素分解性抗菌素材の製造方法。 7. The environment-friendly low-carbon decomposable antibacterial material according to claim 6 , wherein in the step S10, the manure of livestock contains 50-58 wt% of cow manure, 2-8 wt% of pig manure, and 6-15 wt% of poultry manure. manufacturing method. 前記ステップS20において,前記ペレットは,前記堆肥粒子30~50wt%,前記合成樹脂30~50wt%,前記抗菌剤5~10wt%,前記結合剤2~3wt%,前記分散剤10~20wt%,前記スリップ剤0.5~1wt%,前記アクリル粉末0.1~1wt%,前記油分0.5~1wt%を熱混合及び押出ししつつカットして形成されることを特徴とする請求項記載の環境にやさしい低炭素分解性抗菌素材の製造方法。 In step S20, the pellets are composed of 30 to 50 wt% of the compost particles, 30 to 50 wt% of the synthetic resin, 5 to 10 wt% of the antibacterial agent, 2 to 3 wt% of the binder, 10 to 20 wt% of the dispersant, and the 7. The sheet according to claim 6 , wherein 0.5 to 1 wt% of the slip agent, 0.1 to 1 wt% of the acrylic powder, and 0.5 to 1 wt% of the oil are cut while being hot-mixed and extruded. A method for producing an environmentally friendly low-carbon degradable antibacterial material. 前記ステップS20において,熱混合は,70~80℃の温度で15~30分間行われることを特徴とする請求項10記載の環境にやさしい低炭素分解性抗菌素材の製造方法。 11. The method of claim 10 , wherein in step S20, the thermal mixing is performed at a temperature of 70-80° C. for 15-30 minutes. 前記ステップS20において,押出は,160~190℃の温度で行われることを特徴とする請求項10記載の環境にやさしい低炭素分解性抗菌素材の製造方法。 The method of claim 10 , wherein in step S20, the extrusion is performed at a temperature of 160-190°C.
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