JP6938086B2 - Sliding member - Google Patents

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JP6938086B2
JP6938086B2 JP2017177190A JP2017177190A JP6938086B2 JP 6938086 B2 JP6938086 B2 JP 6938086B2 JP 2017177190 A JP2017177190 A JP 2017177190A JP 2017177190 A JP2017177190 A JP 2017177190A JP 6938086 B2 JP6938086 B2 JP 6938086B2
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sliding
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solid lubricant
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alloy
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JP2019052352A (en
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中井 雅博
雅博 中井
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Daido Metal Co Ltd
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Description

本発明は、裏金層と、合金および固体潤滑剤からなる摺動層とを備えた摺動部材に関する。 The present invention relates to a sliding member including a back metal layer and a sliding layer made of an alloy and a solid lubricant.

従来、鉄道の分岐器に用いられる分岐器用床板として、レールを載置固定する床板本体と、この床板本体に設けられ、レールに接離されるトングレールが摺動される平板形状の摺動部材とを備えたものが知られている。このような分岐器用床板等の摺動部材としては、裏金層上に含油焼結合金層を形成した摺動部材が用いられている(例えば、特許文献1,2参照)。しかしながら、分岐器用床板として含油焼結合金層を形成した摺動部材を用いた場合、その含油焼結合金層に定期的に潤滑油を注油する必要があり、使用には非常な労力を要するという問題がある。 Conventionally, as a floor board for a turnout used for a railway turnout, a floor board main body on which a rail is placed and fixed, and a flat plate-shaped sliding member provided on the floor board main body and on which a tongue rail attached to and detached from the rail is slid. The one with is known. As a sliding member such as a floor plate for a branching device, a sliding member having an oil-impregnated sintered alloy layer formed on a back metal layer is used (see, for example, Patent Documents 1 and 2). However, when a sliding member having an oil-impregnated sintered alloy layer formed as a floor plate for a branching device is used, it is necessary to periodically lubricate the oil-impregnated sintered alloy layer with lubricating oil, which requires a great deal of labor. There's a problem.

また、分岐器用床板の摺動部材としては、摺動部材への注油作業の廃止あるいは注油作業回数の低減のため、裏金層と、金属中に黒鉛等の固体潤滑剤を分散させた摺動層からなるものが提案されている(例えば、特許文献3参照)。 Further, as the sliding member of the floor plate for the branching device, in order to abolish the lubrication work to the sliding member or reduce the number of lubrication work, the back metal layer and the sliding layer in which a solid lubricant such as graphite is dispersed in the metal. (See, for example, Patent Document 3).

特開平5−255905号公報Japanese Unexamined Patent Publication No. 5-255905 特開2014−136899号公報Japanese Unexamined Patent Publication No. 2014-136899 特開2000−309807号公報Japanese Unexamined Patent Publication No. 2000-309807

ところで、鉄道の分岐器に用いられる分岐器用床板は、常に、摺動部材の摺動面と相手部材であるトングレールの摺動面とが直接接触している。このため、摺動部材が用いられる軸受装置の起動時等においては、相手部材の摺動面と摺動部材の摺動面とが直接接触した状態での摺動が起こる。そして、このような状態での摺動が起こると、相手部材に接する摺動部材の摺動面付近の合金は、相手部材に引きずられて、相手部材の移動方向(摺動方向)への弾性変形が生じることになる。このような状況では、特許文献3のように、分岐器用床板の摺動部材として、摺動層の合金中に固体潤滑剤の粒子を均一に分散させたものを用いた場合、摺動面付近の合金の弾性変形量が大きくなり、摺動層の表面に割れ等の損傷が発生する虞が大きくなる。 By the way, in the turnout floor plate used for a railway turnout, the sliding surface of the sliding member and the sliding surface of the mating member, Tongrail, are always in direct contact with each other. Therefore, when the bearing device in which the sliding member is used is started, sliding occurs in a state where the sliding surface of the mating member and the sliding surface of the sliding member are in direct contact with each other. When sliding occurs in such a state, the alloy near the sliding surface of the sliding member in contact with the mating member is dragged by the mating member and elastic in the moving direction (sliding direction) of the mating member. Deformation will occur. In such a situation, as in Patent Document 3, when a sliding member of the floor plate for a branching device in which particles of a solid lubricant are uniformly dispersed in an alloy of a sliding layer is used, the vicinity of the sliding surface is used. The amount of elastic deformation of the alloy is increased, and the risk of damage such as cracking on the surface of the sliding layer is increased.

本発明は、上記した事情に鑑みなされたものであり、その目的とするところは、軸受装置の起動時に摺動層の表面に割れ等の損傷が発生することを防止することが可能な摺動部材を提供することにある。 The present invention has been made in view of the above circumstances, and an object of the present invention is sliding that can prevent damage such as cracks from occurring on the surface of the sliding layer when the bearing device is started. The purpose is to provide members.

上記した目的を達成するために、請求項1に係る発明においては、 裏金層上に摺動層が設けられた摺動部材において、前記摺動層は、1〜15質量%の錫、残部が銅および不可避不純物からなる合金と、該合金中に分散した固体潤滑剤とからなり、該固体潤滑剤は、前記摺動層の10〜35%の体積割合を有し、前記摺動層の摺動面に垂直である断面組織において、前記摺動面から前記裏金層との界面に向かって前記摺動層の厚さの50%の領域を摺動面側領域としたとき、前記摺動層中の前記固体潤滑剤の全体積に対する前記摺動面側領域に分散した固体潤滑剤の体積割合が20〜40%であることを特徴とする。 In order to achieve the above object, in the invention according to claim 1, in the sliding member provided with the sliding layer on the back alloy layer, the sliding layer is composed of 1 to 15% by mass of tin and the balance. an alloy consisting of copper and unavoidable impurities, consists of a dispersed solid lubricant to the alloy, the solid lubricant has a 10% to 35% of the volume fraction of the sliding layer, sliding of the sliding layer In a cross-sectional structure perpendicular to the moving surface, when a region of 50% of the thickness of the sliding layer is defined as a sliding surface side region from the sliding surface toward the interface with the back alloy layer, the sliding layer The volume ratio of the solid lubricant dispersed in the sliding surface side region to the total volume of the solid lubricant in the solid lubricant is 20 to 40%.

請求項2に係る発明においては、請求項1記載の摺動部材において、前記合金は、さらに、0.1〜1質量%のP、15〜60質量%のNi、0.1〜30質量%のPb、0.1〜16質量%のBi、0.1〜10質量%のAg、0.1〜10質量%のFeから選択される1種以上を含むことを特徴とする。 In the invention according to claim 2, in the sliding member according to claim 1, the alloy further contains 0.1 to 1% by mass of P, 15 to 60% by mass of Ni, and 0.1 to 30% by mass. It is characterized by containing one or more selected from Pb, 0.1 to 16% by mass of Bi, 0.1 to 10% by mass of Ag, and 0.1 to 10% by mass of Fe.

請求項3に係る発明においては、請求項1または請求項2記載の摺動部材において、前記固体潤滑剤は、黒鉛、二硫化モリブデン、二硫化タングステン、窒化硼素から選択される1種以上であることを特徴とする。 In the invention according to claim 3, in the sliding member according to claim 1 or 2, the solid lubricant is one or more selected from graphite, molybdenum disulfide, tungsten disulfide, and boron nitride. It is characterized by that.

請求項1に係る発明においては、摺動層中の固体潤滑剤の全体積に対する摺動面側領域に分散した固体潤滑剤の体積割合が20〜40%であり、界面側領域(界面から摺動面に向かって摺動層の厚さの50%までの領域)に比べて、摺動面側領域の強度(変形抵抗)が大きくなる。このため、摺動部材が用いられる軸受装置の起動時には、相手部材の表面と摺動層の摺動面が直接接触した状態での摺動が起こっても、界面側領域に弾性変形が生じることになる。したがって、摺動面側領域の摺動面付近の合金が摺動方向に過度に弾性変形することが抑制され、摺動面に割れ等の損傷が発生することを防止することができる。 In the invention according to claim 1, the volume ratio of the solid lubricant dispersed in the sliding surface side region to the total volume of the solid lubricant in the sliding layer is 20 to 40%, and the interface side region (sliding from the interface). The strength (deformation resistance) of the sliding surface side region is larger than that of the region (up to 50% of the thickness of the sliding layer toward the moving surface). Therefore, when the bearing device in which the sliding member is used is started, elastic deformation occurs in the interface side region even if the sliding surface of the mating member and the sliding surface of the sliding layer are in direct contact with each other. become. Therefore, it is possible to prevent the alloy near the sliding surface in the sliding surface side region from being excessively elastically deformed in the sliding direction, and to prevent damage such as cracks from occurring on the sliding surface.

また、合金には、強度を高めるために1〜15質量%の錫を含有しているが、錫の含有量が1質量%未満の場合には、合金の強度を高める効果が不十分となる。一方、錫の含有量が15質量%を超えると、合金が脆くなりすぎる。 Further, the alloy contains 1 to 15% by mass of tin in order to increase the strength, but when the tin content is less than 1% by mass, the effect of increasing the strength of the alloy becomes insufficient. .. On the other hand, if the tin content exceeds 15% by mass, the alloy becomes too brittle.

また、摺動層中の固体潤滑剤の体積割合は、10〜35%としているが、固体潤滑剤の体積割合が10%未満の場合には、摺動層の摺動面側領域中の固体潤滑剤の体積割合が少なくなりすぎて、摺動層の摺動特性(低摩擦化)を高める効果が不十分となる。一方、固体潤滑剤の体積割合が35%を超えると、摺動層の界面側領域中の固体潤滑剤の体積割合が多くなりすぎて、摺動層の強度が低くなりすぎる。 The volume ratio of the solid lubricant in the sliding layer is 10 to 35%, but when the volume ratio of the solid lubricant is less than 10%, the solid in the sliding surface side region of the sliding layer. The volume ratio of the lubricant becomes too small, and the effect of enhancing the sliding characteristics (low friction) of the sliding layer becomes insufficient. On the other hand, when the volume ratio of the solid lubricant exceeds 35%, the volume ratio of the solid lubricant in the interface side region of the sliding layer becomes too large, and the strength of the sliding layer becomes too low.

また、摺動層中の固体潤滑剤の全体積に対する摺動面側領域に分散した固体潤滑剤の体積割合が20%未満の場合には、摺動面側領域と界面側領域の強度(変形抵抗)の差が大きすぎて、摺動層が負荷を受けたときに、界面側領域が過度に弾性変形してしまい、界面側領域の内部で割れが発生することがある。一方、摺動層中の固体潤滑剤の全体積に対する摺動面側領域に分散した固体潤滑剤の体積割合が40%を超えると、摺動面側領域と界面側領域の強度(変形抵抗)の差が小さすぎて、上記の効果が得られない。 When the volume ratio of the solid lubricant dispersed in the sliding surface side region to the total volume of the solid lubricant in the sliding layer is less than 20%, the strength (deformation) of the sliding surface side region and the interface side region When the difference in resistance) is too large and the sliding layer is loaded, the interface side region may be excessively elastically deformed, and cracks may occur inside the interface side region. On the other hand, when the volume ratio of the solid lubricant dispersed in the sliding surface side region to the total volume of the solid lubricant in the sliding layer exceeds 40%, the strength (deformation resistance) of the sliding surface side region and the interface side region The difference is too small to obtain the above effect.

また、請求項2に係る発明のように、合金は、さらに、0.1〜1質量%のP、15〜60質量%のNi、0.1〜30質量%のPb、0.1〜16質量%のBi、0.1〜10質量%のAg、0.1〜10質量%のFeから選択される1種以上を含むことが好ましい。合金にP、Ni、Ag、Feのいずれか1種以上を含有した場合には、摺動層を強化することができ、合金Bi、Pbのいずれか1種以上を含有した場合には、摺動層の焼付き性を向上させることができる。 Further, as in the invention of claim 2, the alloy further contains 0.1 to 1% by mass of P, 15 to 60% by mass of Ni, 0.1 to 30% by mass of Pb, and 0.1 to 16% by mass. It is preferable to contain one or more selected from 1% by mass Bi, 0.1 to 10% by mass Ag, and 0.1 to 10% by mass Fe. When the alloy contains one or more of P, Ni, Ag, and Fe, the sliding layer can be strengthened, and when the alloy contains one or more of Bi and Pb, the sliding layer can be strengthened. The seizure property of the sliding layer can be improved.

また、請求項3に係る発明のように、固体潤滑剤は、黒鉛、二硫化モリブデン、二硫化タングステン、窒化硼素から選択される1種以上であることが好ましい。このような固体潤滑剤を用いることで、摺動層の摺動特性(低摩擦化)を高めることができる。 Further, as in the invention of claim 3, the solid lubricant is preferably one or more selected from graphite, molybdenum disulfide, tungsten disulfide, and boron nitride. By using such a solid lubricant, the sliding characteristics (low friction) of the sliding layer can be improved.

摺動部材の摺動面に垂直方向の断面を示す模式図である。It is a schematic diagram which shows the cross section in the direction perpendicular to the sliding surface of a sliding member. 表面部を有する裏金層を用いた場合における摺動部材の摺動面に垂直方向の断面を示す模式図である。It is a schematic diagram which shows the cross section in the direction perpendicular to the sliding surface of a sliding member when the back metal layer which has a surface part is used. 摺動部材の製造手順を説明するための図である。It is a figure for demonstrating the manufacturing procedure of a sliding member. 摺動部材の製造時の原材料粉の流れを説明するための図である。It is a figure for demonstrating the flow of the raw material powder at the time of manufacturing a sliding member. 摺動部材の製造時の原材料粉に固体潤滑剤が分散した状態を示す図である。It is a figure which shows the state which the solid lubricant was dispersed in the raw material powder at the time of manufacturing a sliding member. 裏金層の表面の凹凸を小さくした場合における摺動部材の製造時の原材料粉の流れを説明するための図である。It is a figure for demonstrating the flow of the raw material powder at the time of manufacturing a sliding member when the unevenness of the surface of a back metal layer is made small. 裏金層の表面の凹凸を大きくした場合における摺動部材の製造時の原材料粉の流れを説明するための図である。It is a figure for demonstrating the flow of the raw material powder at the time of manufacturing a sliding member when the unevenness of the surface of a back metal layer is made large.

本実施形態に係る摺動部材1について、図1を参照して説明する。図1は、本実施形態に係る摺動部材1の摺動面30に垂直方向の断面を示す模式図である。 The sliding member 1 according to the present embodiment will be described with reference to FIG. FIG. 1 is a schematic view showing a cross section in a direction perpendicular to the sliding surface 30 of the sliding member 1 according to the present embodiment.

図1に示すように、摺動部材1は、裏金層2上に、摺動層3が設けられている。また、摺動層3は、合金4に10〜35体積%の固体潤滑剤5が分散されており、合金4は、1〜15質量%の錫と、残部が銅および不可避不純物からなる。 As shown in FIG. 1, the sliding member 1 is provided with a sliding layer 3 on a back metal layer 2. Moreover, the sliding layer 3 has a solid lubricant 5 of 10 to 35 vol% in the alloy 4 is dispersed, the alloy 4, and 1-15 wt% of tin, the balance being copper and inevitable impurities.

摺動層3の合金4には、強度を高めるために1〜15質量%の錫を含有させる。錫の含有量が1質量%未満の場合には、合金4の強度を高める効果が不十分となる。一方、錫の含有量が15質量%を超えると、合金4が脆くなりすぎる。 The alloy 4 of the sliding layer 3 contains 1 to 15% by mass of tin in order to increase the strength. When the tin content is less than 1% by mass, the effect of increasing the strength of the alloy 4 becomes insufficient. On the other hand, if the tin content exceeds 15% by mass, the alloy 4 becomes too brittle.

摺動層3の合金4は、さらに、15〜60質量のNi、0.1〜1質量%のP、0.1〜30質量%のPb、0.1〜16質量%のBi、0.1〜10質量%のAg、0.1〜10質量%のFeから選択される1種以上を含むようにすることができる。また、摺動層3の合金4は、さらに、セラミックスや、金属間化合物等の硬質粒子を含むようにすることもできる。 The alloy 4 of the sliding layer 3 further contains 15 to 60% by mass of Ni, 0.1 to 1% by mass of P, 0.1 to 30% by mass of Pb, and 0.1 to 16% by mass of Bi, 0. It can contain one or more selected from 1 to 10% by mass of Ag and 0.1 to 10% by mass of Fe. Further, the alloy 4 of the sliding layer 3 may further contain hard particles such as ceramics and intermetallic compounds.

摺動層3中の固体潤滑剤5の割合は、10〜35体積%としているが、固体潤滑剤5の割合が10体積%未満の場合には、摺動層3の後述する摺動面側領域31中の固体潤滑剤5の体積割合が少なくなりすぎて、摺動層3の摺動特性(低摩擦化)を高める効果が不十分となる。一方、固体潤滑剤5の割合が35体積%を超えると、摺動層3の後述する界面側領域32中の固体潤滑剤5の体積割合が多くなりすぎて、摺動層3の強度が低くなりすぎる。 The ratio of the solid lubricant 5 in the sliding layer 3 is 10 to 35% by volume, but when the ratio of the solid lubricant 5 is less than 10% by volume, the sliding surface side of the sliding layer 3 will be described later. The volume ratio of the solid lubricant 5 in the region 31 becomes too small, and the effect of enhancing the sliding characteristics (low friction) of the sliding layer 3 becomes insufficient. On the other hand, when the ratio of the solid lubricant 5 exceeds 35% by volume, the volume ratio of the solid lubricant 5 in the interface side region 32 described later of the sliding layer 3 becomes too large, and the strength of the sliding layer 3 becomes low. Too much.

固体潤滑剤5は、黒鉛、二硫化モリブデン、二硫化タングステン、窒化硼素から選択される1種以上であることが好ましい。 The solid lubricant 5 is preferably one or more selected from graphite, molybdenum disulfide, tungsten disulfide, and boron nitride.

摺動層3の厚さ(摺動面30から摺動層3と裏金層2との界面33までの間である摺動面30に垂直方向の距離)は、0.8〜3mmとすることが好ましい。 The thickness of the sliding layer 3 (distance in the direction perpendicular to the sliding surface 30 between the sliding surface 30 and the interface 33 between the sliding layer 3 and the back metal layer 2) shall be 0.8 to 3 mm. Is preferable.

摺動部材1の摺動面30に垂直である断面組織において、摺動層3の厚さをTとし、摺動層3の摺動面30から界面33に向かって厚さTの50%までの距離にある領域を「摺動面側領域31」、界面33から摺動面30に向かって厚さTの50%までの距離にある領域を「界面側領域32」、と区分すると、摺動層3中の固体潤滑剤5の全体積に対する摺動面側領域31に分散する固体潤滑剤5の体積割合は、20〜40%となっている。 In the cross-sectional structure perpendicular to the sliding surface 30 of the sliding member 1, the thickness of the sliding layer 3 is T, and the thickness is up to 50% of the thickness T from the sliding surface 30 of the sliding layer 3 toward the interface 33. The region at the distance of is classified as "sliding surface side region 31", and the region at a distance of up to 50% of the thickness T from the interface 33 toward the sliding surface 30 is classified as "interface side region 32". The volume ratio of the solid lubricant 5 dispersed in the sliding surface side region 31 to the total volume of the solid lubricant 5 in the moving layer 3 is 20 to 40%.

摺動層3の摺動面側領域31は、摺動層3中の固体潤滑剤5の全体積に対する固体潤滑剤5の体積割合が20〜40%であり、界面側領域32中に分散した固体潤滑剤5の体積割合である60〜80%に比べて小さいため、界面側領域32に比べて強度(変形抵抗)が大きくなる。これに対し、界面側領域32は、摺動面側領域31に比べて強度(変形抵抗)が小さくなり、変形を起こしやすくなる。 In the sliding surface side region 31 of the sliding layer 3, the volume ratio of the solid lubricant 5 to the total volume of the solid lubricant 5 in the sliding layer 3 was 20 to 40%, and the solid lubricant 5 was dispersed in the interface side region 32. Since it is smaller than the volume ratio of 60 to 80% of the solid lubricant 5, the strength (deformation resistance) is larger than that of the interface side region 32. On the other hand, the interface side region 32 has a smaller strength (deformation resistance) than the sliding surface side region 31, and is more likely to be deformed.

上記したように、摺動面側領域31の強度(変形抵抗)が界面側領域32に比べて大きいため、摺動部材1が用いられる軸受装置の起動時には、相手部材の表面と摺動層3の摺動面30が直接接触した状態での摺動が起こっても、界面側領域32に弾性変形が生じることになる。このため、摺動面側領域31の摺動面30付近の合金4が摺動方向に過度に弾性変形することが抑制され、摺動面30に割れ等の損傷が発生することを防止することができる。 As described above, since the strength (deformation resistance) of the sliding surface side region 31 is larger than that of the interface side region 32, when the bearing device in which the sliding member 1 is used is started, the surface of the mating member and the sliding layer 3 are started. Even if sliding occurs in a state where the sliding surfaces 30 of the above are in direct contact with each other, elastic deformation occurs in the interface side region 32. Therefore, it is possible to prevent the alloy 4 in the vicinity of the sliding surface 30 of the sliding surface side region 31 from being excessively elastically deformed in the sliding direction, and to prevent damage such as cracking from occurring in the sliding surface 30. Can be done.

以上の機構により、本発明に係る摺動部材1は、その摺動部材1が用いられる軸受装置の起動直後に、摺動面30と相手部材の表面が直接接触した状況であっても、摺動層3の表面に割れ等の損傷が発生することを防止することができる。 With the above mechanism, the sliding member 1 according to the present invention slides even when the sliding surface 30 and the surface of the mating member are in direct contact immediately after the start of the bearing device in which the sliding member 1 is used. It is possible to prevent damage such as cracks from occurring on the surface of the moving layer 3.

以上の本発明の構成とは異なり、摺動層全体を通じて固体潤滑剤の割合が同じになるように分散、すなわち均一に分散させた従来の摺動部材を用いた場合、軸受装置の起動直後に、摺動部材の摺動面と相手部材が直接接触するような状況では、相手部材に接する摺動層の表面付近の合金は、相手部材の表面に引きずられて、相手部材の移動方向(摺動方向)への弾性変形量が大きくなり、摺動層の表面に割れ等の損傷が発生し、摩耗が起こりやすい。 Unlike the above configuration of the present invention, when a conventional sliding member dispersed so that the proportion of the solid lubricant is the same throughout the sliding layer, that is, uniformly dispersed, is used immediately after the bearing device is started. In a situation where the sliding surface of the sliding member and the mating member are in direct contact with each other, the alloy near the surface of the sliding layer in contact with the mating member is dragged by the surface of the mating member and the moving direction of the mating member (sliding). The amount of elastic deformation in the moving direction) becomes large, damage such as cracks occurs on the surface of the sliding layer, and wear is likely to occur.

また、上記したように、摺動層3の摺動面側領域31は、摺動層3中の固体潤滑剤5の全体積に対する固体潤滑剤5の体積割合が20〜40%であることが好ましいが、その固体潤滑剤5の体積割合が30〜40%であることがより好ましい。 Further, as described above, in the sliding surface side region 31 of the sliding layer 3, the volume ratio of the solid lubricant 5 to the total volume of the solid lubricant 5 in the sliding layer 3 is 20 to 40%. It is preferable, but it is more preferable that the volume ratio of the solid lubricant 5 is 30 to 40%.

また、本発明の構成とは異なり、摺動層3の摺動面側領域31において、摺動層3中の固体潤滑剤5の全体積に対する固体潤滑剤5の体積割合が20%未満の場合には、摺動面側領域31と界面側領域32の強度(変形抵抗)の差が大きすぎて、摺動層3が負荷を受けたときに、界面側領域32が過度に弾性変形してしまい、界面側領域32の内部で割れが発生することがある。一方、摺動層3の摺動面側領域31において、摺動層3中の固体潤滑剤5の全体積に対する固体潤滑剤5の体積割合が40%を超える場合には、摺動面側領域31と界面側領域32の強度(変形抵抗)の差が小さすぎて、上記の効果が得られない。 Further, unlike the configuration of the present invention, in the sliding interface side region 31 of the sliding layer 3, the volume ratio of the solid lubricant 5 to the total volume of the solid lubricant 5 in the sliding layer 3 is less than 20%. The difference in strength (deformation resistance) between the sliding surface side region 31 and the interface side region 32 is too large, and when the sliding layer 3 is loaded, the interface side region 32 is excessively elastically deformed. Therefore, cracks may occur inside the interface side region 32. On the other hand, in the sliding surface side region 31 of the sliding layer 3, when the volume ratio of the solid lubricant 5 to the total volume of the solid lubricant 5 in the sliding layer 3 exceeds 40%, the sliding surface side region The difference in strength (deformation resistance) between 31 and the interface side region 32 is too small to obtain the above effect.

なお、図2に示すように、裏金層2は、摺動層3との界面となる表面において、焼結法や電気メッキ法等によりニッケルまたは銅、あるいは、ニッケルと銅からなる合金による表面部6を有してもよい。図2は、表面部6を有する裏金層2を用いた場合における摺動部材1の摺動面30に垂直方向の断面を示す模式図である。このように、裏金層2の表面に表面部6を設けることにより、摺動層3と裏金層2の接合強度を高めることができる。 As shown in FIG. 2, the back metal layer 2 has a surface portion made of nickel or copper or an alloy composed of nickel and copper on the surface of the interface with the sliding layer 3 by a sintering method, an electroplating method, or the like. May have 6. FIG. 2 is a schematic view showing a cross section in a direction perpendicular to the sliding surface 30 of the sliding member 1 when the back metal layer 2 having the surface portion 6 is used. By providing the surface portion 6 on the surface of the back metal layer 2 in this way, the joint strength between the sliding layer 3 and the back metal layer 2 can be increased.

上記に説明した摺動部材1について、製造工程に沿って以下に詳細に説明する。
(1)合金原材料の準備
合金4の原材料としては、アトマイズ法により作成した組成が1〜15質量%の錫、残部が銅である合金粉を用いることができる。また、組成が1〜15質量%の錫、残部が銅となるように調整されたアトマイズ法または電解法等により作成した銅粉と錫粉の混合合金粉を用いてもよい。また、合金粉や混合合金粉は、さらに、0.1〜1質量%のP、15〜60質量%のNi、0.1〜30質量%のPb、0.1〜16質量%のBi、0.1〜10質量%のAg、0.1〜10質量%のFeから選択される1種以上を含む組成であってもよい。
The sliding member 1 described above will be described in detail below along with the manufacturing process.
(1) Preparation of alloy raw materials
As the raw material of the alloy 4, an alloy powder prepared by an atomizing method having a composition of 1 to 15% by mass of tin and the balance being copper can be used. Further, a mixed alloy powder of copper powder and tin powder prepared by an atomizing method or an electrolysis method adjusted so that the composition is 1 to 15% by mass of tin and the balance is copper may be used. Further, the alloy powder and the mixed alloy powder further include 0.1 to 1% by mass of P, 15 to 60% by mass of Ni, 0.1 to 30% by mass of Pb, and 0.1 to 16% by mass of Bi. The composition may contain one or more selected from 0.1 to 10% by mass of Ag and 0.1 to 10% by mass of Fe.

(2)固体潤滑剤原材料の準備
固体潤滑剤5の原材料としては、黒鉛、二硫化モリブデン、二硫化タングステン、窒化硼素から選択される1種以上を用いることができる。また、固体潤滑剤5の原材料は、平均粒径が100〜350μmであることが好ましい。
(2) Preparation of Solid Lubricant Raw Material As the raw material of the solid lubricant 5, one or more selected from graphite, molybdenum disulfide, tungsten disulfide, and boron nitride can be used. The raw material of the solid lubricant 5 preferably has an average particle size of 100 to 350 μm.

(3)裏金
裏金層2(帯鋼9)としては、炭素の含有量が0.1〜0.6質量%の炭素を含む亜共析鋼、オーステナイト系ステンレス鋼、高張力鋼、マルエージング鋼等の鉄合金や銅合金を用いることができる。また、裏金層2の表面には、機械加工等で最大高さ(ISO4287―1997)がRz20〜100μmの凹凸を設けるようにする。なお、凹凸方向は、任意の方向とする。また、図2に示すように、裏金層2は、摺動層3との界面となる表面において、焼結法や電気メッキ法等によりニッケルまたは銅、あるいは、ニッケルと銅からなる合金による表面部6を有してもよい。このような構成では、表面部6の厚さは、1〜50μmとし、表面部6の形成後の表面にRz20〜100μmの凹凸を設けるようにする。
(3) Back metal The back metal layer 2 (strip steel 9) includes subeutectoid steel containing carbon with a carbon content of 0.1 to 0.6% by mass, austenite-based stainless steel, high-strength steel, and maraging steel. Such as iron alloys and copper alloys can be used. Further, the surface of the back metal layer 2 is provided with irregularities having a maximum height (ISO4287-197) of Rz20 to 100 μm by machining or the like. The uneven direction is an arbitrary direction. Further, as shown in FIG. 2, the back metal layer 2 has a surface portion made of nickel or copper or an alloy composed of nickel and copper on the surface of the interface with the sliding layer 3 by a sintering method, an electroplating method, or the like. May have 6. In such a configuration, the thickness of the surface portion 6 is set to 1 to 50 μm, and the surface after the formation of the surface portion 6 is provided with irregularities of Rz 20 to 100 μm.

(4)組織制御
図3には、本実施形態に係る摺動部材1の製造工程を概略的に示す。図3に示すように、アンコイラー7からコイラー13に向けて帯鋼9(裏金層2)を移動する過程で、まず、合金粉と固体潤滑剤5を混合した原材料粉8を帯鋼9(裏金層2)に散布する。そして、帯鋼9(裏金層2)に散布された原材料粉8は、帯鋼9(裏金層2)に対して所定の間隔に設定したライナー10との間で所定の厚みにライニングされ、1次焼結、1次圧延、2次焼結、2次圧延を順次行い、所定の厚さに仕上げる。
(4) Organizational Control FIG. 3 schematically shows a manufacturing process of the sliding member 1 according to the present embodiment. As shown in FIG. 3, in the process of moving the strip steel 9 (back metal layer 2) from the uncoiler 7 to the coiler 13, first, the raw material powder 8 in which the alloy powder and the solid lubricant 5 are mixed is mixed with the strip steel 9 (back metal). Spray on layer 2). Then, the raw material powder 8 sprayed on the strip steel 9 (back metal layer 2) is lined with the liner 10 set at a predetermined interval with respect to the strip steel 9 (back metal layer 2) to a predetermined thickness, and 1 Next sintering, primary rolling, secondary sintering, and secondary rolling are sequentially performed to finish to a predetermined thickness.

より詳細には、合金粉と固体潤滑剤5を混合した原材料粉8として、合金粉の平均粒径は、1〜63μmとし、固体潤滑剤5の平均粒径は、合金粉の平均粒径より大きくする必要がある。また、固体潤滑剤5の形状は、球状や塊状であってもよいが、鱗片状や偏平状のほうが好ましい。このような原材料粉8を、接着層を被着した裏金層2上に所定厚さに均一に散布する。 More specifically, as the raw material powder 8 in which the alloy powder and the solid lubricant 5 are mixed, the average particle size of the alloy powder is 1 to 63 μm, and the average particle size of the solid lubricant 5 is larger than the average particle size of the alloy powder. It needs to be large. The shape of the solid lubricant 5 may be spherical or lumpy, but is preferably scaly or flat. Such raw material powder 8 is uniformly sprayed on the back metal layer 2 coated with the adhesive layer to a predetermined thickness.

また、図4に示すように、原材料粉8がライナー10に接触したときには、裏金層2とライナー10との間で対流が発生する。そして、図5(a)に示すように、裏金層2の表面粗さがRz20〜100μmである場合、原材料粉8がライナー10を通過する前には、原材料粉8に固体潤滑剤5が均一に分散しているのに対し、図5(b)に示すように、原材料粉8がライナー10を通過した後には、対流した原材料粉8のうち粒径が大きい固体潤滑剤5が裏金層2の表面の凹凸に引っ掛かり、摺動面側領域31と比べて界面側領域32に密集している。その後、焼結工程や圧延工程が行われるが、焼結工程や圧延工程では、固体潤滑剤5が摺動側領域31に移動することがなく、焼結工程や圧延工程後の摺動層3にも、固体潤滑剤5が摺動面側領域31と比べて界面側領域32に多く分布することとなる。 Further, as shown in FIG. 4, when the raw material powder 8 comes into contact with the liner 10, convection occurs between the back metal layer 2 and the liner 10. Then, as shown in FIG. 5A, when the surface roughness of the back metal layer 2 is Rz20 to 100 μm, the solid lubricant 5 is uniform on the raw material powder 8 before the raw material powder 8 passes through the liner 10. However, as shown in FIG. 5 (b), after the raw material powder 8 has passed through the liner 10, the solid lubricant 5 having a large particle size among the confluent raw material powder 8 is added to the back metal layer 2. It is caught in the unevenness of the surface of the surface, and is denser in the interface side region 32 than in the sliding surface side region 31. After that, a sintering step and a rolling step are performed. In the sintering step and the rolling step, the solid lubricant 5 does not move to the sliding side region 31, and the sliding layer 3 after the sintering step and the rolling step. In addition, the solid lubricant 5 is distributed more in the interface side region 32 than in the sliding surface side region 31.

なお、図6に示すように、裏金層2の表面粗さがRz20μm未満である場合、原材料粉8がライナー10を通過する際に、固体潤滑剤5が裏金層2の表面の凹凸に引っ掛からず、摺動面側領域31と比べて界面側領域32での固体潤滑剤5の割合を大きくすることができない。一方、図7に示すように、裏金層2の表面粗さがRz100μmを超えると、原材料粉8がライナー10を通過する際に、裏金層2の表面の凹部に固体潤滑剤5と一緒に合金粉を巻き込んでしまい、摺動面側領域31と比べて界面側領域32での固体潤滑剤5の割合を大きくすることができない。 As shown in FIG. 6, when the surface roughness of the back metal layer 2 is less than Rz 20 μm, the solid lubricant 5 does not get caught in the unevenness of the surface of the back metal layer 2 when the raw material powder 8 passes through the liner 10. , The ratio of the solid lubricant 5 in the interface side region 32 cannot be increased as compared with the sliding surface side region 31. On the other hand, as shown in FIG. 7, when the surface roughness of the back metal layer 2 exceeds Rz 100 μm, when the raw material powder 8 passes through the liner 10, it is alloyed with the solid lubricant 5 in the recesses on the surface of the back metal layer 2. The powder is entrained, and the proportion of the solid lubricant 5 in the interface side region 32 cannot be increased as compared with the sliding surface side region 31.

そして、原材料粉8がライナー10を通過した後には、1次焼結として焼結炉11を用い、還元雰囲気中で800〜1000℃の温度で10〜30分間焼結し、粉末同士の焼結と裏金層2への接合を行って焼結合金層を形成する。その後、1次圧延として圧延機12を用い、ロールにより圧延して焼結合金層の緻密化と厚さ調整を行う。そして、緻密化と裏金層2への接合強度を高めるために、再度、還元雰囲気中で800〜1000℃の温度で10〜30分間焼結すること(2次焼結)とロールによる圧延(2次圧延)とを繰り返し行う。 Then, after the raw material powder 8 has passed through the liner 10, the sintering furnace 11 is used as the primary sintering, and the powders are sintered at a temperature of 800 to 1000 ° C. for 10 to 30 minutes in a reducing atmosphere. And the back metal layer 2 are joined to form a sintered alloy layer. After that, a rolling mill 12 is used as the primary rolling, and the rolled alloy layer is densified and the thickness is adjusted by rolling. Then, in order to increase the densification and the bonding strength to the back metal layer 2, it is again sintered in a reducing atmosphere at a temperature of 800 to 1000 ° C. for 10 to 30 minutes (secondary sintering) and rolled by a roll (2). Next rolling) is repeated.

従来の摺動部材1の製造工程では、摺動層3との界面となる表面が平滑である裏金層2が用いられている。このような平滑な裏金層2を用いると、その表面に凹凸がないため、原材料粉8がライナー10を通過する際に、固体潤滑剤5が裏金層2の表面に引っ掛からず、摺動面側領域31と比べて界面側領域32での固体潤滑剤5の割合を大きくすることができない。また、摺動層3との界面となる裏金層2の表面に固体潤滑剤5を含まない多孔質金属部を有している場合には、その多孔質金属部の凹凸が100μmを超えるため、原材料粉8がライナー10を通過する際に、固体潤滑剤5と一緒に合金粉を巻き込んでしまい、摺動面側領域31と比べて界面側領域32での固体潤滑剤5の割合を大きくすることができない。 In the conventional manufacturing process of the sliding member 1, a back metal layer 2 having a smooth surface as an interface with the sliding layer 3 is used. When such a smooth back metal layer 2 is used, the surface thereof is not uneven, so that when the raw material powder 8 passes through the liner 10, the solid lubricant 5 does not get caught on the surface of the back metal layer 2 and is on the sliding surface side. The proportion of the solid lubricant 5 in the interface side region 32 cannot be increased as compared with the region 31. Further, when the surface of the back metal layer 2 which is the interface with the sliding layer 3 has a porous metal portion which does not contain the solid lubricant 5, the unevenness of the porous metal portion exceeds 100 μm. When the raw material powder 8 passes through the liner 10, the alloy powder is involved together with the solid lubricant 5, and the ratio of the solid lubricant 5 in the interface side region 32 is increased as compared with the sliding surface side region 31. Can't.

次に、摺動層3における摺動面側領域31と、界面側領域32との区分方法について説明する。まず、電子顕微鏡を用いて摺動部材1の摺動面30に垂直方向である断面の複数箇所(例えば5箇所)の電子像を200倍で撮影する。なお、電子像の撮影倍率は200倍に限定されないで、他の倍率に変更してもよい。この撮影画像を用い、摺動層1の摺動面30に垂直となる方向の厚さTを求める。また、摺動面30の任意の位置から裏金層2側へ向かって厚さTの50%の長さ(1/2×T)となる位置に、摺動面30に対し平行な仮想線CLを描く。そして、摺動層3の摺動面30から仮想線CLまでの間を摺動面側領域31とし、摺動層3の裏金層2との界面33から仮想線CLまでの間を界面側領域32とする。 Next, a method of separating the sliding surface side region 31 and the interface side region 32 in the sliding layer 3 will be described. First, using an electron microscope, electron images of a plurality of locations (for example, five locations) in a cross section perpendicular to the sliding surface 30 of the sliding member 1 are photographed at a magnification of 200. The photographing magnification of the electronic image is not limited to 200 times, and may be changed to another magnification. Using this photographed image, the thickness T in the direction perpendicular to the sliding surface 30 of the sliding layer 1 is obtained. Further, a virtual line CL parallel to the sliding surface 30 is located at a position that is 50% of the thickness T (1/2 × T) toward the back metal layer 2 side from an arbitrary position of the sliding surface 30. Draw. The area between the sliding surface 30 of the sliding layer 3 and the virtual line CL is the sliding surface side region 31, and the area between the interface 33 of the sliding layer 3 with the back metal layer 2 and the virtual line CL is the interface side region. It is set to 32.

また、摺動層3中の固体潤滑剤5の全体積に対する摺動面側領域31に分散した固体潤滑剤5の体積割合の測定方法について説明する。上記の手法で得られた電子像の撮影画像を用い、一般的な画像解析手法(例えば、解析ソフト:Image−Pro Plus(Version4.5);(株)プラネトロン製)を用いて、撮影画像における摺動層3中の固体潤滑剤5の合計面積、及び摺動面側領域31に分散した固体潤滑剤5の合計面積を測定し、それらの測定値から、摺動層3中の固体潤滑剤5の全面積に対する摺動面側領域31に分散した固体潤滑剤5の面積割合を算出する。なお、この面積割合は、体積割合に相当する。 Further, a method for measuring the volume ratio of the solid lubricant 5 dispersed in the sliding surface side region 31 with respect to the total volume of the solid lubricant 5 in the sliding layer 3 will be described. Using the captured image of the electronic image obtained by the above method, a general image analysis method (for example, analysis software: Image-Pro Plus (Version 4.5); manufactured by Planetron Co., Ltd.) is used in the captured image. The total area of the solid lubricant 5 in the sliding layer 3 and the total area of the solid lubricant 5 dispersed in the sliding surface side region 31 were measured, and from those measured values, the solid lubricant in the sliding layer 3 was measured. The area ratio of the solid lubricant 5 dispersed in the sliding surface side region 31 to the total area of 5 is calculated. This area ratio corresponds to the volume ratio.

次に、本実施形態に係る裏金層2および摺動層3を有する摺動部材1について、実施例1〜16および比較例17〜21を以下に示すとおり作製した。実施例1〜16および比較例17〜21の摺動部材1の摺動層3の組成は、表1に示すとおりである。実施例1〜16では、アトマイズ法にて製作した合金粉と固体潤滑剤5を一般的な混合機を用いて混合し、表1の成分比率となるようにして、表1の「裏金層表面粗さRz(μm)」欄に示す凹凸を表面に設けた裏金層2に散布し、焼結、圧延を繰り返して摺動部材1を製造した。また、この摺動材料1を板状に加工し、試験片を作製した。 Next, with respect to the sliding member 1 having the back metal layer 2 and the sliding layer 3 according to the present embodiment, Examples 1 to 16 and Comparative Examples 17 to 21 were produced as shown below. The composition of the sliding layer 3 of the sliding members 1 of Examples 1 to 16 and Comparative Examples 17 to 21 is as shown in Table 1. In Examples 1 to 16, the alloy powder produced by the atomizing method and the solid lubricant 5 were mixed using a general mixer to obtain the component ratios shown in Table 1, and the "back metal layer surface" in Table 1 was obtained. The unevenness shown in the "Roughness Rz (μm)" column was sprayed on the back metal layer 2 provided on the surface, and sintering and rolling were repeated to manufacture the sliding member 1. Further, the sliding material 1 was processed into a plate shape to prepare a test piece.

Figure 0006938086
Figure 0006938086

比較例17,18では、裏金層2の表面における凹凸の大きさを変更した後、上述した実施例の作製方法と同手法にて、表1の成分比率となるように摺動材料1を製造した。また、この摺動材料1を板状に加工し、試験片を作製した。 In Comparative Examples 17 and 18, after changing the size of the unevenness on the surface of the back metal layer 2, the sliding material 1 was manufactured so as to have the component ratios shown in Table 1 by the same method as the manufacturing method of the above-mentioned Examples. bottom. Further, the sliding material 1 was processed into a plate shape to prepare a test piece.

比較例19では、合金粉をアトマイズ法にて、表1の成分となるように作製した。そして、作製した合金粉と固体潤滑剤5を一般的な混合機を用いて混合し、表1の成分比率となるようにして、表面に凹凸を設けた裏金層2に散布し、焼結、圧延を繰り返して摺動部材1を製造した。また、この摺動材料1を板状に加工し、試験片を作製した。 In Comparative Example 19, the alloy powder was prepared by an atomizing method so as to have the components shown in Table 1. Then, the produced alloy powder and the solid lubricant 5 are mixed using a general mixer, sprayed on the back metal layer 2 having irregularities on the surface so as to have the component ratios shown in Table 1, and sintered. The sliding member 1 was manufactured by repeating rolling. Further, the sliding material 1 was processed into a plate shape to prepare a test piece.

比較例20,21では、合金粉と固体潤滑剤5の混合比を表1の成分となるように混合し、上述した実施例の作製方法と同手法にて、表1の成分比率となるように摺動材料1を製造した。また、この摺動材料1を板状に加工し、試験片を作製した。 In Comparative Examples 20 and 21, the mixing ratios of the alloy powder and the solid lubricant 5 were mixed so as to be the components of Table 1, and the component ratios of Table 1 were obtained by the same method as the production method of the above-mentioned Examples. Sliding material 1 was manufactured. Further, the sliding material 1 was processed into a plate shape to prepare a test piece.

また、実施例1〜16および比較例17〜21について、表2の条件で往復摺動試験を行った。その結果を表1に示す。また、割れ発生の有無は、往復摺動試験後の摺動層3の外観より判別した。 In addition, a reciprocating sliding test was conducted on Examples 1 to 16 and Comparative Examples 17 to 21 under the conditions shown in Table 2. The results are shown in Table 1. Further, the presence or absence of cracks was determined from the appearance of the sliding layer 3 after the reciprocating sliding test.

Figure 0006938086
Figure 0006938086

実施例1〜16は、摺動層3の表面に割れが発生していない。また、摺動層3の表面での割れの発生を抑制した結果、摩耗量も小さくなっている。これは、摺動層3中の固体潤滑剤5の体積割合が10〜35%であり、且つ、摺動層3中の固体潤滑剤5の全体積に対する摺動面側領域31に分散した固体潤滑剤5の体積割合が20〜40%であることで、摺動面側領域31の強度(変形抵抗)が界面側領域32に比べて大きく、摺動面側領域31の摺動面30付近の合金4が摺動方向に過度に弾性変形することが抑制されるためである。 In Examples 1 to 16, the surface of the sliding layer 3 is not cracked. Further, as a result of suppressing the occurrence of cracks on the surface of the sliding layer 3, the amount of wear is also reduced. This is a solid in which the volume ratio of the solid lubricant 5 in the sliding layer 3 is 10 to 35% and is dispersed in the sliding surface side region 31 with respect to the total volume of the solid lubricant 5 in the sliding layer 3. Since the volume ratio of the lubricant 5 is 20 to 40%, the strength (deformation resistance) of the sliding surface side region 31 is larger than that of the interface side region 32, and the vicinity of the sliding surface 30 of the sliding surface side region 31 This is because the alloy 4 of the above is suppressed from being excessively elastically deformed in the sliding direction.

実施例6は、実施例1と比較し、裏金層2の表面粗さをRz20μmと小さくしたが、実施例1と同様、摺動層3の表面に割れが発生していない。また、実施例7は、実施例1と比較し、裏金層2の表面粗さをRz100μmと大きくしたが、実施例1と同様、摺動層3の表面に割れが発生していない。 In Example 6, the surface roughness of the back metal layer 2 was reduced to Rz 20 μm as compared with Example 1, but the surface of the sliding layer 3 was not cracked as in Example 1. Further, in Example 7, the surface roughness of the back metal layer 2 was increased to Rz 100 μm as compared with Example 1, but the surface of the sliding layer 3 was not cracked as in Example 1.

実施例8は、固体潤滑剤5として黒鉛を含有した実施例1と比較し、固体潤滑剤5としてMoSを含有しているが、実施例1と同様、摺動層3の表面に割れが発生していない。 Example 8 contains MoS 2 as the solid lubricant 5 as compared with Example 1 which contains graphite as the solid lubricant 5, but the surface of the sliding layer 3 is cracked as in Example 1. It has not occurred.

実施例9は、実施例1と比較し、合金を強化させるSnを15質量%と多く含有しているが、実施例1と同様、摺動層3の表面に割れが発生していない。また、摺動層3が強化されることで、実施例1よりも摩耗量が低下している。 Compared with Example 1, Example 9 contains as much as 15% by mass of Sn for strengthening the alloy , but as in Example 1, cracks are not generated on the surface of the sliding layer 3. Further, by strengthening the sliding layer 3, the amount of wear is lower than that of the first embodiment.

実施例10〜13,16は、実施例1と比較し、合金を強化させるP、Ni、Fe、Agから選択される1種以上を含有しているが、実施例1と同様、摺動層3の表面に割れが発生していない。また、摺動層3が強化されることで、実施例1よりも摩耗量が低下している。 Examples 10 to 13 and 16 contain one or more selected from P, Ni, Fe, and Ag that strengthen the alloy as compared with Example 1, but the sliding layer is the same as in Example 1. No cracks have occurred on the surface of 3. Further, by strengthening the sliding layer 3, the amount of wear is lower than that of the first embodiment.

実施例14,15は、実施例1と比較し、焼付き性を向上させるPb、Biをそれぞれ含有しているが、実施例1と同様、摺動層3の表面に割れが発生していない。 Examples 14 and 15 contain Pb and Bi, respectively, which improve seizure property as compared with Example 1, but the surface of the sliding layer 3 is not cracked as in Example 1. ..

比較例17は、実施例1と比較し、裏金層2の表面粗さをRz20μm未満と小さくしたため、上述したように、原材料粉がライナー10を通過する際に、固体潤滑剤5が裏金層2の表面の凹凸に引っ掛からず、摺動面側領域31と比べて界面側領域32での固体潤滑剤5の割合を大きくすることができない。このため、摺動試験時において、摺動面側領域31の摺動面30付近の合金4が摺動方向に過度に弾性変形してしまい、摺動層3の表面に割れが発生している。また、摺動層3の表面に割れが発生した結果、摩耗量も大きくなっている。 In Comparative Example 17, the surface roughness of the back metal layer 2 was reduced to less than Rz 20 μm as compared with Example 1. Therefore, as described above, when the raw material powder passed through the liner 10, the solid lubricant 5 was applied to the back metal layer 2. The proportion of the solid lubricant 5 in the interface side region 32 cannot be increased as compared with the sliding surface side region 31 without being caught by the unevenness of the surface of the surface. Therefore, during the sliding test, the alloy 4 near the sliding surface 30 in the sliding surface side region 31 is excessively elastically deformed in the sliding direction, and the surface of the sliding layer 3 is cracked. .. Further, as a result of cracks occurring on the surface of the sliding layer 3, the amount of wear is also large.

比較例18は、実施例1と比較し、裏金層2の表面粗さがRz100μmを超えるため、上述したように、原材料粉がライナー10を通過する際に、裏金層2の表面の凹部に固体潤滑剤5と一緒に合金粉を巻き込んでしまい、摺動面側領域31と比べて界面側領域32での固体潤滑剤5の割合を大きくすることができない。このため、摺動試験時において、摺動面側領域31の摺動面30付近の合金4が摺動方向に過度に弾性変形してしまい、摺動層3の表面に割れが発生している。また、摺動層3の表面に割れが発生した結果、摩耗量も大きくなっている。 In Comparative Example 18, the surface roughness of the back metal layer 2 exceeds Rz 100 μm as compared with Example 1. Therefore, as described above, when the raw material powder passes through the liner 10, it is solid in the recess on the surface of the back metal layer 2. Since the alloy powder is involved together with the lubricant 5, the proportion of the solid lubricant 5 in the interface side region 32 cannot be increased as compared with the sliding surface side region 31. Therefore, during the sliding test, the alloy 4 near the sliding surface 30 in the sliding surface side region 31 is excessively elastically deformed in the sliding direction, and the surface of the sliding layer 3 is cracked. .. Further, as a result of cracks occurring on the surface of the sliding layer 3, the amount of wear is also large.

比較例19は、実施例1と比較し、合金を強化させるSnを含有していないため、摺動層3の強度が低くなり、摺動層3の表面に割れが発生している。また、摺動層3の表面に割れが発生した結果、摩耗量も大きくなっている。 Compared with Example 1, Comparative Example 19 does not contain Sn that reinforces the alloy , so that the strength of the sliding layer 3 is low and the surface of the sliding layer 3 is cracked. Further, as a result of cracks occurring on the surface of the sliding layer 3, the amount of wear is also large.

比較例20は、実施例1と比較し、摺動層3中の固体潤滑剤5の体積割合を10%未満と少なくしたため、摺動層3の摺動特性(低摩擦化)を高める効果が不十分となり、摺動層3の表面に割れが発生している。一方、比較例21は、実施例1と比較し、摺動層3中の固体潤滑剤5の体積割合が35%を超えるため、摺動層3の界面側領域32中の固体潤滑剤5の体積割合が多くなりすぎて、摺動層3の強度が低くなりすぎ、摺動層3の表面に割れが発生している。また、摺動層3の表面に割れが発生した結果、摩耗量も大きくなっている。 In Comparative Example 20, since the volume ratio of the solid lubricant 5 in the sliding layer 3 was reduced to less than 10% as compared with Example 1, the effect of improving the sliding characteristics (low friction) of the sliding layer 3 was obtained. It becomes insufficient and cracks are generated on the surface of the sliding layer 3. On the other hand, in Comparative Example 21, since the volume ratio of the solid lubricant 5 in the sliding layer 3 exceeds 35% as compared with Example 1, the solid lubricant 5 in the interface side region 32 of the sliding layer 3 The volume ratio becomes too large, the strength of the sliding layer 3 becomes too low, and the surface of the sliding layer 3 is cracked. Further, as a result of cracks occurring on the surface of the sliding layer 3, the amount of wear is also large.

本発明の摺動部材1は、鉄道の分岐器に用いられる分岐器用床板等の平板形状の摺動部材に限定されないで、各種軸受の回転軸のラジアル方向負荷を支承する円筒形状のジャーナル軸受や、回転軸の軸線方向負荷を支承する任意の形状のスラスト軸受に適用することができる。 The sliding member 1 of the present invention is not limited to a flat plate-shaped sliding member such as a floor plate for a branching device used in a railway branching device, and is not limited to a cylindrical journal bearing that supports a radial load on the rotating shaft of various bearings. It can be applied to thrust bearings of any shape that support the axial load of the rotating shaft.

1 摺動部材
2 裏金層
3 摺動層
合金
5 固体潤滑剤
6 表面部
7 アンコイラー
8 原材料粉
9 帯鋼
10 ライナー
11 焼結炉
12 圧延機
13 コイラー
30 摺動面
31 摺動面側領域
32 界面側領域
33 界面
1 Sliding member 2 Back metal layer 3 Sliding layer 4 Alloy 5 Solid lubricant 6 Surface part 7 Uncoiler 8 Raw material powder 9 Stripped steel 10 Liner 11 Sintering furnace 12 Roller 13 Koyler 30 Sliding surface 31 Sliding surface side area 32 Interface side region 33 Interface

Claims (3)

裏金層上に摺動層が設けられた摺動部材において、
前記摺動層は、1〜15質量%の錫、残部が銅および不可避不純物からなる合金と、該合金中に分散した固体潤滑剤とからなり、該固体潤滑剤は、前記摺動層の10〜35%の体積割合を有し、
前記摺動層の摺動面に垂直である断面組織において、前記摺動面から前記裏金層との界面に向かって前記摺動層の厚さの50%の領域を摺動面側領域としたとき、前記摺動層中の前記固体潤滑剤の全体積に対する前記摺動面側領域に分散した固体潤滑剤の体積割合が20〜40%であることを特徴とする摺動部材。
In a sliding member provided with a sliding layer on the back metal layer,
The sliding layer is composed of a alloy 1-15 wt% of tin, the balance being copper and inevitable impurities, and dispersed solid lubricant to the alloy, the solid lubricant, 10 of the sliding layer Has a volume ratio of ~ 35%,
In the cross-sectional structure perpendicular to the sliding surface of the sliding layer, a region of 50% of the thickness of the sliding layer from the sliding surface toward the interface with the back metal layer is defined as a sliding surface side region. When, the sliding member is characterized in that the volume ratio of the solid lubricant dispersed in the sliding surface side region to the total volume of the solid lubricant in the sliding layer is 20 to 40%.
前記合金は、さらに、0.1〜1質量%のP、15〜60質量%のNi、0.1〜30質量%のPb、0.1〜16質量%のBi、0.1〜10質量%のAg、0.1〜10質量%のFeから選択される1種以上を含むことを特徴とする請求項1記載の摺動部材。 The alloy further contains 0.1 to 1% by mass of P, 15 to 60% by mass of Ni, 0.1 to 30% by mass of Pb, 0.1 to 16% by mass of Bi, and 0.1 to 10% by mass. The sliding member according to claim 1, further comprising one or more selected from% Ag and 0.1 to 10% by mass Fe. 前記固体潤滑剤は、黒鉛、二硫化モリブデン、二硫化タングステン、窒化硼素から選択される1種以上であることを特徴とする請求項1又は請求項2記載の摺動部材。
The sliding member according to claim 1 or 2, wherein the solid lubricant is one or more selected from graphite, molybdenum disulfide, tungsten disulfide, and boron nitride.
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