JP6768429B2 - Beverage containing heat-treated activated carbon - Google Patents
Beverage containing heat-treated activated carbon Download PDFInfo
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- JP6768429B2 JP6768429B2 JP2016182215A JP2016182215A JP6768429B2 JP 6768429 B2 JP6768429 B2 JP 6768429B2 JP 2016182215 A JP2016182215 A JP 2016182215A JP 2016182215 A JP2016182215 A JP 2016182215A JP 6768429 B2 JP6768429 B2 JP 6768429B2
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims description 146
- 235000013361 beverage Nutrition 0.000 title claims description 64
- 238000010438 heat treatment Methods 0.000 claims description 37
- 239000007788 liquid Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 244000060011 Cocos nucifera Species 0.000 claims description 6
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 6
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 5
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 5
- 240000007594 Oryza sativa Species 0.000 claims description 5
- 235000007164 Oryza sativa Nutrition 0.000 claims description 5
- 244000082204 Phyllostachys viridis Species 0.000 claims description 5
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 5
- 239000011425 bamboo Substances 0.000 claims description 5
- 239000010903 husk Substances 0.000 claims description 5
- 235000009566 rice Nutrition 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 3
- 235000019645 odor Nutrition 0.000 description 23
- 230000001877 deodorizing effect Effects 0.000 description 15
- 230000000694 effects Effects 0.000 description 14
- 235000013353 coffee beverage Nutrition 0.000 description 10
- 235000013616 tea Nutrition 0.000 description 10
- 244000269722 Thea sinensis Species 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 230000037406 food intake Effects 0.000 description 8
- 240000002234 Allium sativum Species 0.000 description 7
- 235000004611 garlic Nutrition 0.000 description 7
- 206010006326 Breath odour Diseases 0.000 description 6
- 239000002781 deodorant agent Substances 0.000 description 6
- 230000035622 drinking Effects 0.000 description 5
- 235000006468 Thea sinensis Nutrition 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 230000007937 eating Effects 0.000 description 4
- 208000032139 Halitosis Diseases 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 208000035985 Body Odor Diseases 0.000 description 2
- 206010040904 Skin odour abnormal Diseases 0.000 description 2
- RYYVLZVUVIJVGH-UHFFFAOYSA-N caffeine Chemical compound CN1C(=O)N(C)C(=O)C2=C1N=CN2C RYYVLZVUVIJVGH-UHFFFAOYSA-N 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 235000015203 fruit juice Nutrition 0.000 description 2
- 210000001035 gastrointestinal tract Anatomy 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000020124 milk-based beverage Nutrition 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000015067 sauces Nutrition 0.000 description 2
- 235000014214 soft drink Nutrition 0.000 description 2
- 239000008247 solid mixture Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 235000016795 Cola Nutrition 0.000 description 1
- 235000011824 Cola pachycarpa Nutrition 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000003368 Ilex paraguariensis Nutrition 0.000 description 1
- LPHGQDQBBGAPDZ-UHFFFAOYSA-N Isocaffeine Natural products CN1C(=O)N(C)C(=O)C2=C1N(C)C=N2 LPHGQDQBBGAPDZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 235000013334 alcoholic beverage Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000020279 black tea Nutrition 0.000 description 1
- 229960001948 caffeine Drugs 0.000 description 1
- VJEONQKOZGKCAK-UHFFFAOYSA-N caffeine Natural products CN1C(=O)N(C)C(=O)C2=C1C=CN2C VJEONQKOZGKCAK-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000019987 cider Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000021458 diet cola Nutrition 0.000 description 1
- 238000001647 drug administration Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000014080 ginger ale Nutrition 0.000 description 1
- 235000009569 green tea Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 208000017169 kidney disease Diseases 0.000 description 1
- 210000002429 large intestine Anatomy 0.000 description 1
- 235000020331 mate tea Nutrition 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000019520 non-alcoholic beverage Nutrition 0.000 description 1
- 235000020333 oolong tea Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000011496 sports drink Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
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- Non-Alcoholic Beverages (AREA)
- Cosmetics (AREA)
Description
本発明は、加熱処理活性炭含有飲料、及びその製造方法に関する。 The present invention relates to a heat-treated activated carbon-containing beverage and a method for producing the same.
活性炭は、比表面積が大きく高い吸着能を有するため、吸着剤として利用されている。一方で、活性炭は、ザラツキ感、味、色の点で経口投与に用いることは敬遠されてきた。そのため、その経口投与は積極的に行われておらず、毒性物質を吸着させる腎疾患治療又は予防剤（特許文献１）などの限定的な利用例があるだけである。 Activated carbon is used as an adsorbent because it has a large specific surface area and high adsorptive capacity. On the other hand, activated carbon has been avoided for oral administration in terms of graininess, taste and color. Therefore, the oral administration is not positively performed, and there are only limited use cases such as a renal disease treatment or preventive agent (Patent Document 1) that adsorbs a toxic substance.
本発明者は、活性炭を含有する飲料が、口臭を含めた体から生じる臭いに対する消臭に非常に有効であることを見出している。しかしながら、その消臭効果をより高める要求もある。 The present inventor has found that a beverage containing activated carbon is very effective in deodorizing odors generated from the body including bad breath. However, there is also a demand to further enhance the deodorizing effect.
本発明の課題は、活性炭含有飲料の消臭効果を高めることである。 An object of the present invention is to enhance the deodorizing effect of an activated carbon-containing beverage.
本発明者らは、鋭意検討した結果、活性炭に特定条件下で加熱処理をすると、その消臭効果が高まることを見出した。
本発明は、以下のものに関するが、これらに限定されない。
［１］活性炭と水とを含有する液体を加熱することにより得られる、加熱処理活性炭含有飲料であって、加熱時間（分）をＸ、加熱温度（℃）をＹとしたとき、加熱の条件が以下の式（１）の条件：
式（１） Ｙ≧−０．２４Ｘ＋６６ （ただし、Ｘ＞０かつＹ＞６０）
を満たすものである、加熱処理活性炭含有飲料。
［２］前記の加熱工程により生成された加熱処理活性炭を０．１ｗ／ｖ％以上含有する、［１］に記載の飲料。
［３］ｐＨが３．０〜７．０である、［１］又は［２］に記載の飲料。
［４］加熱処理活性炭が、もみ殻由来の活性炭、やし殻由来の活性炭、及び竹由来の活性炭からなる群から選択される１つまたはそれ以上を含む、［１］〜［３］のいずれか１項に記載の飲料。
［５］活性炭と水とを含有する液体を加熱することを含む、加熱処理活性炭含有飲料の製造方法であって、加熱時間（分）をＸ、加熱温度（℃）をＹとしたとき、加熱の条件が以下の式（１）の条件：
式（１） Ｙ≧−０．２４Ｘ＋６６ （ただし、Ｘ＞０かつＹ＞６０）
を満たすものである、前記製造方法。
As a result of diligent studies, the present inventors have found that when activated carbon is heat-treated under specific conditions, its deodorizing effect is enhanced.
The present invention relates to, but is not limited to:
[1] A heat-treated activated carbon-containing beverage obtained by heating a liquid containing activated carbon and water, where the heating time (minutes) is X and the heating temperature (° C.) is Y, the heating conditions. Is the condition of the following equation (1):
Equation (1) Y ≧ −0.24X + 66 (where X> 0 and Y> 60)
A heat-treated activated carbon-containing beverage that satisfies the above conditions.
[2] The beverage according to [1], which contains 0.1 w / v% or more of the heat-treated activated carbon produced by the heating step.
[3] The beverage according to [1] or [2], which has a pH of 3.0 to 7.0.
[4] Any of [1] to [3], wherein the heat-treated activated carbon contains one or more selected from the group consisting of activated carbon derived from rice husks, activated carbon derived from coconut shells, and activated carbon derived from bamboo. The beverage according to item 1.
[5] A method for producing a heat-treated activated carbon-containing beverage, which comprises heating a liquid containing activated carbon and water. When the heating time (minutes) is X and the heating temperature (° C.) is Y, heating is performed. Condition of the following equation (1):
Equation (1) Y ≧ −0.24X + 66 (where X> 0 and Y> 60)
The production method that satisfies the above conditions.
本発明は、活性炭含有飲料の消臭効果、例えば、口臭、体臭、汗臭、又は便臭に対する消臭効果を高めることができる。 The present invention can enhance the deodorizing effect of activated carbon-containing beverages, for example, the deodorizing effect on halitosis, body odor, sweat odor, or stool odor.
本発明の加熱処理活性炭含有飲料、及びその製造方法に関して、以下に詳細に説明する。
（加熱処理活性炭）
活性炭とは、やし殻などの炭素物質から高温での活性化反応を経て製造される、多孔質の、炭素を主な成分とする物質である。
The heat-treated activated carbon-containing beverage of the present invention and a method for producing the same will be described in detail below.
(Heat-treated activated carbon)
Activated carbon is a porous, carbon-based substance produced from a carbon substance such as coconut shell through an activation reaction at a high temperature.
本発明の飲料は、活性炭と水とを含有する液体を加熱処理して生成された加熱処理活性炭を含有する。当該飲料中の加熱処理活性炭の含有量は限定されないが、好ましくは０．１ｗ／ｖ％以上、より好ましくは０．２ｗ／ｖ以上、より好ましくは０．５ｗ／ｖ％以上、より好ましくは１．０ｗ／ｖ％以上である。消臭効果との関係では含有量の上限値は存在しないが、飲料の味や舌触りを考慮すると、加熱処理活性炭の含有量の上限値は、好ましくは２０ｗ／ｖ％、より好ましくは１０ｗ／ｖ％である。当該活性炭の含有量の好ましい範囲の例は、０．１ｗ／ｖ％〜２０ｗ／ｖ％、０．２ｗ／ｖ〜２０ｗ／ｖ％、０．５ｗ／ｖ〜２０ｗ／ｖ％、１．０ｗ／ｖ〜２０ｗ／ｖ％、０．１ｗ／ｖ％〜１０ｗ／ｖ％、０．２ｗ／ｖ〜１０ｗ／ｖ％、０．５ｗ／ｖ〜１０ｗ／ｖ％、又は１．０ｗ／ｖ〜１０ｗ／ｖ％である。 The beverage of the present invention contains heat-treated activated carbon produced by heat-treating a liquid containing activated carbon and water. The content of the heat-treated activated carbon in the beverage is not limited, but is preferably 0.1 w / v% or more, more preferably 0.2 w / v or more, more preferably 0.5 w / v% or more, and more preferably 1. It is 0.0 w / v% or more. There is no upper limit of the content in relation to the deodorant effect, but considering the taste and texture of the beverage, the upper limit of the content of the heat-treated activated carbon is preferably 20 w / v%, more preferably 10 w / v. %. Examples of the preferable range of the content of the activated carbon are 0.1 w / v% to 20 w / v%, 0.2 w / v to 20 w / v%, 0.5 w / v to 20 w / v%, 1.0 w /. v to 20w / v%, 0.1w / v% to 10w / v%, 0.2w / v to 10w / v%, 0.5w / v to 10w / v%, or 1.0w / v to 10w / It is v%.
加熱処理活性炭の形態は限定されないが、その摂取を容易にするために、粉末活性炭であることが好ましい。粒子サイズはレーザー回折式粒子径分布測定装置により測定することができるが、好ましくは全粒子の９０％以上が０．１〜３０μｍの粒子径を有し、摂取時の違和感を感じさせないために５０％粒径が７μｍ以下（全粒子の半分が７μｍ以下の粒子径を有する）であることがより好ましい。 The form of the heat-treated activated carbon is not limited, but it is preferably powdered activated carbon in order to facilitate its intake. The particle size can be measured by a laser diffraction type particle size distribution measuring device, but preferably 90% or more of all particles have a particle size of 0.1 to 30 μm, so that a feeling of strangeness during ingestion is not felt. It is more preferable that the% particle size is 7 μm or less (half of all particles have a particle size of 7 μm or less).
また本発明の目的で使用する活性炭粉末は臭気成分をより効率的に吸着するという観点から、重量あたりの比表面積（ｍ２／ｇ）が５００以上であることが好ましく、１０００以上であることがさらに好ましい。また、同じ観点から平均細孔径が０．３〜１０ｎｍであることが好ましく、０．５〜２．５ｎｍであることが好ましい。比表面積および平均細孔径は自動比表面積／細孔分布測定装置（島津製作所、トライスターII-３０２０）により測定することができる。 Further, the activated carbon powder used for the purpose of the present invention preferably has a specific surface area (m 2 / g) per weight of 500 or more, preferably 1000 or more, from the viewpoint of more efficiently adsorbing odorous components. More preferred. From the same viewpoint, the average pore diameter is preferably 0.3 to 10 nm, preferably 0.5 to 2.5 nm. The specific surface area and the average pore diameter can be measured by an automatic specific surface area / pore distribution measuring device (Shimadzu Corporation, Tristar II-3020).
加熱処理活性炭の由来は特に限定されず、例えば、やし殻由来活性炭、木由来活性炭、竹由来活性炭、もみ殻由来活性炭などから選択することができる。中でも、もみ殻由来活性炭、やし殻由来活性炭、又は竹由来活性炭が好ましい。一種類の活性炭だけを用いてもよいし、二種類以上を組み合わせて用いてもよい。 The origin of the heat-treated activated carbon is not particularly limited, and for example, it can be selected from coconut shell-derived activated carbon, wood-derived activated carbon, bamboo-derived activated carbon, rice husk-derived activated carbon, and the like. Of these, rice husk-derived activated carbon, coconut shell-derived activated carbon, or bamboo-derived activated carbon is preferable. Only one type of activated carbon may be used, or two or more types may be used in combination.
（加熱処理）
本発明の飲料を製造するための方法は限定されないが、好ましくは、活性炭と水とを含有する液体を、以下の式（１）：
式（１）Ｙ≧−０．２４Ｘ＋６６ （ただし、Ｘ＞０かつＹ＞６０）
を満たす条件で加熱処理することにより得る。ここで、Ｘは加熱時間（分）であり、Ｙは加熱温度（℃）である。本明細書において加熱処理に関して記載される温度は液温を意味する。
(Heat treatment)
The method for producing the beverage of the present invention is not limited, but preferably, a liquid containing activated carbon and water is used in the following formula (1):
Equation (1) Y ≧ −0.24X + 66 (where X> 0 and Y> 60)
Obtained by heat treatment under the conditions satisfying. Here, X is the heating time (minutes), and Y is the heating temperature (° C.). The temperature described for heat treatment herein means liquid temperature.
加熱温度は、式（１）を満たす条件であれば特に限定されないが、６０℃を上回り、より好ましくは６５℃以上、より好ましくは８０℃以上、より好ましくは９０℃以上である。６０℃以下の温度では消臭効果の向上が明確に現れない。本発明の効果との関係では加熱温度の上限値は存在しないが、加熱温度は好ましくは１４０℃以下である。水の蒸発が著しいと処理が困難となること、１００℃以上で加熱する場合は高圧になること、などから、加熱温度はより好ましくは１００℃未満である。 The heating temperature is not particularly limited as long as it satisfies the condition of the formula (1), but is higher than 60 ° C., more preferably 65 ° C. or higher, more preferably 80 ° C. or higher, and more preferably 90 ° C. or higher. At a temperature of 60 ° C. or lower, the improvement of the deodorizing effect does not appear clearly. Although there is no upper limit of the heating temperature in relation to the effect of the present invention, the heating temperature is preferably 140 ° C. or lower. The heating temperature is more preferably less than 100 ° C. because the treatment becomes difficult when the water evaporates significantly, and the pressure becomes high when the water is heated at 100 ° C. or higher.
加熱時間は式（１）を満たす条件であれば限定されないが、好ましくは１分以上である。加熱時間の上限値は存在しないが、加熱時間は好ましくは１時間以下、より好ましくは３０分未満、より好ましくは１５分以下である。 The heating time is not limited as long as the conditions satisfy the formula (1), but is preferably 1 minute or more. There is no upper limit for the heating time, but the heating time is preferably 1 hour or less, more preferably less than 30 minutes, more preferably 15 minutes or less.
本発明では、活性炭と水とを含有する液体を加熱処理して得られる液体をそのまま飲料として利用する。 In the present invention, the liquid obtained by heat-treating a liquid containing activated carbon and water is used as it is as a beverage .
本明細書における「活性炭と水とを含有する液体」とは、それらの成分を含有するあらゆる液体を意味する。当該液体は、本発明の効果を損なわない限り、活性炭と水以外の成分を含んでいてよい。当該液体の種類は限定されないが、本明細書の後の部分で例示される飲料のいずれかであってもよい。 As used herein, the term "liquid containing activated carbon and water" means any liquid containing those components. The liquid may contain components other than activated carbon and water as long as the effects of the present invention are not impaired. The type of liquid is not limited, but may be any of the beverages exemplified later in this specification.
加熱処理の際には撹拌をしてもよいし、撹拌をしなくてもよいが、撹拌をする場合には、当該液体は、粘性が低いことが好ましい。このため、当該液体中に溶存している不揮発性の溶質濃度は、好ましくは４０ｗ／ｖ％以下、より好ましくは３０ｗ／ｖ％以下、より好ましくは２０ｗ／ｖ％以下、より好ましくは１０ｗ／ｖ％以下である。 Stirring may or may not be performed during the heat treatment, but in the case of stirring, the liquid preferably has a low viscosity. Therefore, the concentration of the non-volatile solute dissolved in the liquid is preferably 40 w / v% or less, more preferably 30 w / v% or less, more preferably 20 w / v% or less, and more preferably 10 w / v. % Or less.
本発明の効果を害しない限り、活性炭の加熱処理の前又は後に、追加的な工程を実施してもよい。例えば、活性炭の加熱処理の前には、活性炭と水とを含有する液体を製造するための追加的な工程を行うことができる。例えば、当該液体に活性炭と水以外の種々の成分を混合してもよいし、当該液体を容器に充填してもよい。 Additional steps may be performed before or after the heat treatment of the activated carbon as long as the effects of the present invention are not impaired. For example, prior to the heat treatment of the activated carbon, an additional step can be performed to produce a liquid containing the activated carbon and water. For example, the liquid may be mixed with various components other than activated carbon and water, or the liquid may be filled in a container.
上記した加熱処理工程を含む加熱処理活性炭含有飲料の製造方法は、活性炭含有飲料の消臭効果を高めることができるため、別の側面では、活性炭含有飲料の消臭効果を高める方法でもある。 Since the method for producing a heat-treated activated carbon-containing beverage including the above-mentioned heat treatment step can enhance the deodorizing effect of the activated carbon-containing beverage, another aspect is also a method of enhancing the deodorizing effect of the activated carbon-containing beverage.
（他の成分）
本発明の飲料には、上記した各種成分に加えて、通常の経口組成物に用いられる香料、酸化防止剤、保存料、ｐＨ調整剤、品質安定剤などの成分を、本発明の効果を損なわない範囲で添加することができる。
(Other ingredients)
In the beverage of the present invention, in addition to the above-mentioned various components, components such as flavors, antioxidants, preservatives, pH adjusters, and quality stabilizers used in ordinary oral compositions impair the effects of the present invention. It can be added in a range that does not exist.
（飲料の種類など）
本発明の飲料の種類は特に限定されないが、例えば、清涼飲料のような非アルコール飲料や、アルコール飲料等が挙げられる。本発明の飲料は、炭酸ガスを含んでいても、含まなくてもよい。炭酸ガスを含まない飲料として、例えば、コーヒー飲料や茶飲料が挙げられる。
(Type of beverage, etc.)
The type of the beverage of the present invention is not particularly limited, and examples thereof include non-alcoholic beverages such as soft drinks and alcoholic beverages. The beverage of the present invention may or may not contain carbon dioxide. Examples of beverages that do not contain carbon dioxide include coffee beverages and tea beverages.
ここで、コーヒー飲料とは、コーヒー分を原料として使用し、加熱殺菌工程を経て製造される飲料製品のことをいう。製品の種類は特に限定されないが、１９７７年に認定された「コーヒー飲料等の表示に関する公正競争規約」の定義である「コーヒー」、「コーヒー飲料」、「コーヒー入り清涼飲料」が主に挙げられる。また、コーヒー分を原料とした飲料においても、乳固形分が３．０重量％以上のものは「飲用乳の表示に関する公正競争規約」の適用を受け、「乳飲料」として取り扱われるが、これも、本明細書においてはコーヒー飲料である。 Here, the coffee beverage refers to a beverage product produced by using coffee as a raw material and undergoing a heat sterilization process. The type of product is not particularly limited, but mainly includes "coffee", "coffee beverage", and "soft drink with coffee", which are defined in the "Fair Competition Code for Labeling Coffee Beverages" approved in 1977. .. In addition, even among beverages made from coffee, those with a milk solid content of 3.0% by weight or more are treated as "milk beverages" under the application of the "Fair Competition Code for Labeling of Drinking Milk". Also, in the present specification, it is a coffee beverage.
また、茶飲料は、典型的には、茶樹（学名：Ｃａｍｅｌｌｉａ ｓｉｎｅｎｓｉｓ）の主に葉や茎などのカフェインを含む茶原料を用いて製造された茶飲料であり、例えば、緑茶、紅茶、ウーロン茶、及びマテ茶であるが、ブレンド茶、穀物茶、ハーブティー、麦茶等も好適な茶飲料である。 The tea beverage is typically a tea beverage produced using a tea raw material containing caffeine such as leaves and stems of a tea plant (scientific name: Camellia sinensis), and is, for example, green tea, black tea, or oolong tea. , And mate tea, but blended tea, grain tea, herb tea, barley tea and the like are also suitable tea beverages.
炭酸ガスを含まない本発明の飲料の他の態様としては、コーヒー飲料でない飲料や、茶飲料でない飲料、例えば、果汁飲料、乳飲料、スポーツドリンク等が挙げられるが、これらに限定されない。 Other aspects of the beverage of the present invention that do not contain carbon dioxide include, but are not limited to, non-coffee beverages and non-tea beverages such as fruit juice beverages, milk beverages, sports drinks and the like.
また、本発明の炭酸ガスを含む飲料として、例えば、コーラ、ダイエットコーラ、ジンジャーエール、サイダー、及び果汁風味が付与された炭酸水等が挙げられるが、これらに限定されるものではない。 Further, examples of the beverage containing carbon dioxide gas of the present invention include, but are not limited to, cola, diet cola, ginger ale, cider, and carbonated water to which a fruit juice flavor is imparted.
本発明の飲料のｐＨは特に限定されないが、３．０〜８．０であってもよいし、３．０〜７．０であってもよいし、３．０以上４．５未満、又は４．５〜７．０であってもよい。本発明の典型的な酸性飲料は、３．０以上４．５未満のｐＨを有し、加熱処理活性炭を０．１ｗ／ｖ％以上、０．２ｗ／ｖ以上、０．５ｗ／ｖ％以上、又は１．０ｗ／ｖ％以上含有する。本発明の典型的な中性飲料は、４．５〜７．０のｐＨを有し、加熱処理活性炭を０．１ｗ／ｖ％以上、０．２ｗ／ｖ以上、０．５ｗ／ｖ％以上、又は１．０ｗ／ｖ％以上含有する。 The pH of the beverage of the present invention is not particularly limited, but may be 3.0 to 8.0, 3.0 to 7.0, 3.0 or more and less than 4.5, or It may be 4.5 to 7.0. The typical acidic beverage of the present invention has a pH of 3.0 or more and less than 4.5, and heat-treated activated carbon is 0.1 w / v% or more, 0.2 w / v or more, 0.5 w / v% or more. , Or 1.0 w / v% or more. The typical neutral beverage of the present invention has a pH of 4.5 to 7.0, and heat-treated activated carbon is 0.1 w / v% or more, 0.2 w / v or more, 0.5 w / v% or more. , Or 1.0 w / v% or more.
本発明の飲料は、好ましくは容器詰めの形態で提供される。容器の形態には、缶等の金属容器、ペット（ＰＥＴ）ボトル、紙パック、瓶、パウチなどが含まれるが、これらに限定されない。本発明の飲料は、経口摂取した直後にカプセルが溶解して速やかに内溶液が放出される易溶性カプセルの形態で提供されてもよいが、これは容器詰飲料の一種と考えることができる。 The beverage of the present invention is preferably provided in the form of a container. The form of the container includes, but is not limited to, a metal container such as a can, a PET bottle, a paper pack, a bottle, and a pouch. The beverage of the present invention may be provided in the form of an easily soluble capsule in which the capsule dissolves immediately after ingestion and the internal solution is rapidly released, which can be considered as a kind of packaged beverage.
容器に充填される飲料の容量は１回摂取量であってもよいし、複数回、例えば１０回分が充填されていてもよい。そのような場合は摂取時に、期待する消臭効果の程度に応じて容量を任意に変えて摂取量を調整することができる。 The volume of the beverage filled in the container may be a single intake amount, or may be filled in a plurality of times, for example, 10 times. In such a case, the amount of intake can be adjusted by arbitrarily changing the volume according to the degree of the expected deodorant effect at the time of intake.
（消臭）
飲料は、活性炭の胃腸への迅速な送達を容易にするため、経口投与による消臭作用の発揮に好適である。臭いが胃腸に存在する物質に由来する場合には、飲料の形態で活性炭を使用すると、固形組成物の形態で摂取する場合に比べて迅速に効果が発現することが期待される。すなわち、飲料の形態で摂取することにより、固形組成物の形態で摂取する場合に比べて活性炭が大腸まで迅速に送達されるため、既に臭いが生じている場合に摂取しても体内の悪臭元に速やかに接触することにより早期に効果が得られることが期待される。したがって、例えば、飲食など臭いを発生させる行為の前だけでなく、その行為中、又はその後に摂取しても、消臭効果が得られることが期待される。
(deodorize)
Beverages are suitable for exerting a deodorant effect by oral administration because they facilitate the rapid delivery of activated carbon to the gastrointestinal tract. When the odor is derived from a substance present in the gastrointestinal tract, it is expected that the use of activated carbon in the form of a beverage will have a faster effect than ingestion in the form of a solid composition. That is, when ingested in the form of a beverage, the activated carbon is delivered to the large intestine more quickly than in the case of ingesting in the form of a solid composition. It is expected that the effect will be obtained at an early stage by promptly contacting. Therefore, for example, it is expected that the deodorant effect can be obtained not only before the act of generating an odor such as eating and drinking, but also during or after the act.
本明細書における「消臭」とは、臭いを完全に消すことだけでなく、その臭いを低減すること、及び、臭いの発生を防止することも意味する。
消臭の対象となる臭いは、主に、体から生じる好ましくない臭いであり、例えば、口臭、体臭（これは、体、主に体表面から生じる臭いである）、汗臭、及び便臭からなる群から選択される少なくとも一つである。臭いには種々の原因が存在する。典型的には、飲食、喫煙、医薬品投与、疾患などの原因が存在する。本発明の飲料は、それらの内のいずれの原因による臭いにも有効であるが、特に、飲食を原因とする臭いに好適である。飲食により生じる臭いの例は、ニンニクなどに由来する硫黄含有化合物の臭いである。
The term "deodorant" as used herein means not only completely eliminating the odor, but also reducing the odor and preventing the generation of the odor.
The odors to be deodorized are mainly unpleasant odors originating from the body, such as halitosis, body odor (which is the odor originating from the body, mainly from the body surface), sweat odor, and stool odor. At least one selected from the group of There are various causes for odor. Typically, there are causes such as eating and drinking, smoking, drug administration, and illness. The beverage of the present invention is effective against odors caused by any of them, but is particularly suitable for odors caused by eating and drinking. An example of the odor generated by eating and drinking is the odor of a sulfur-containing compound derived from garlic or the like.
（数値範囲）
明確化のために記載すると、本明細書において下限値と上限値によって表されている数値範囲、即ち「下限値〜上限値」は、それら下限値及び上限値を含む。例えば、「１〜２
」により表される範囲は、１及び２を含む。
(Numerical range)
For the sake of clarity, the numerical range represented by the lower and upper limits in the present specification, that is, "lower limit to upper limit" includes those lower limit and upper limit. For example, "1-2
The range represented by "includes 1 and 2.
以下に実施例に基づいて本発明の説明をするが、本発明はこれらの実施例に限定されるものではない。
（実施例１）
竹由来の粉末活性炭（全粒子の９０％以上の粒子径が０．１〜３０μｍ）を水に懸濁し、０．２、０．５又は１．０ｇ／１００ｍｌの活性炭含有量の未加熱活性炭飲料（容量１００ｍｌ）を調製した。また、これらの飲料と同じものを調製し、それらを８５℃で１０分間加熱し、加熱処理活性炭飲料（容量１００ｍｌ）を調製した。
The present invention will be described below based on examples, but the present invention is not limited to these examples.
(Example 1)
Bamboo-derived powdered activated carbon (90% or more of the total particles have a particle size of 0.1 to 30 μm) is suspended in water, and an unheated activated carbon beverage having an activated carbon content of 0.2, 0.5 or 1.0 g / 100 ml. (Volume 100 ml) was prepared. In addition, the same beverages as these beverages were prepared and heated at 85 ° C. for 10 minutes to prepare heat-treated activated carbon beverages (capacity 100 ml).
訓練されたパネラーが、昼食時に、すりおろされたニンニク１ｇを含むタレ（１０ｍｌ）に１２個（３００ｇ）の餃子を、摂取後にタレが残らないようにつけて摂取した。摂取時間は２０分とした。各パネラーは、餃子の摂取完了後直ちに口臭の程度を評価し、速やかに上記飲料（いずれかの活性炭含有量のものを１本）を摂取した。飲料摂取直後、１０分後、３０分後、１時間後、６時間後、および翌朝に口臭の程度を評価した。 A trained panelist ingested 12 (300 g) dumplings in a sauce (10 ml) containing 1 g of grated garlic at lunch so that no sauce remained after ingestion. The intake time was 20 minutes. Each panelist evaluated the degree of bad breath immediately after the completion of ingestion of dumplings, and promptly ingested the above-mentioned beverage (one bottle having one of the activated carbon contents). The degree of halitosis was evaluated immediately after ingestion of the beverage, 10 minutes, 30 minutes, 1 hour, 6 hours, and the next morning.
口臭の程度は、パネラーごとに、以下の基準に基づいてスコアで評価し、その平均点を求めた。結果を表１に示す。いずれの濃度の活性炭飲料の消臭作用も、加熱処理によって向上していた。 The degree of bad breath was evaluated by a score for each panelist based on the following criteria, and the average score was calculated. The results are shown in Table 1. The deodorant effect of the activated carbon beverage at any concentration was improved by the heat treatment.
５点：ニンニク特有の嫌な臭いを自分でとても強く感じ、人目がとても気になる。
４点：ニンニク特有の嫌な臭いを自分で強く感じ、人目がとても気になる。
３点：ニンニク特有の嫌な臭いを自分で感じ、人目が気になる。
２点：ニンニク特有の嫌な臭いを自分で少し感じるが、人目が気にならない。
１点：ニンニク特有の嫌な臭いを自分で感じず、人目が気にならない。
5 points: I feel the unpleasant odor peculiar to garlic very strongly, and I am very worried about the eyes.
4 points: I strongly feel the unpleasant odor peculiar to garlic, and I am very worried about the eyes.
3 points: I feel the unpleasant odor peculiar to garlic by myself, and I am worried about the eyes.
2 points: I feel a little unpleasant odor peculiar to garlic, but I don't mind the eyes.
1 point: I don't feel the unpleasant odor peculiar to garlic, and I don't mind the eyes.
（実施例２）
活性炭含有量が１ｇ／１００ｍｌの飲料について加熱処理条件（温度・時間）のみを変えて実施例１と同様の試験を行った。その結果を表２に示す。評価結果は、餃子摂取完了直後（飲料摂取前）と、飲料摂取の１時間後のものだけを示している。比較のため、未加熱の飲料（活性炭含有量１ｇ／１００ｍｌ）を使用し、これは室温にて１８時間放置して得た。これらの結果を図１のグラフにも示した。図１では、飲料摂取の１時間後の効果が未加熱飲料と同程度であった飲料を×、未加熱のものより消臭効果が向上したものを○、向上したもののうち特に向上の程度が高かったものを●としてプロットした。６０℃、１８時間で加熱処理した場合の結果（消臭効果向上せず）は図１に示されていない。加熱処理による効果が有効である範囲は、加熱時間（分）をＸ、加熱温度（℃）をＹとすると、近似式Ｙ≧−０．２４Ｘ＋６６（ただし、Ｘ＞０かつＹ＞６０）で示すことができた。
(Example 2)
The same test as in Example 1 was carried out on a beverage having an activated carbon content of 1 g / 100 ml by changing only the heat treatment conditions (temperature and time). The results are shown in Table 2. The evaluation results show only those immediately after the completion of gyoza intake (before the intake of the beverage) and one hour after the intake of the beverage. For comparison, an unheated beverage (activated carbon content 1 g / 100 ml) was used, which was obtained by leaving it at room temperature for 18 hours. These results are also shown in the graph of FIG. In FIG. 1, a beverage whose effect after 1 hour of ingestion of the beverage was similar to that of an unheated beverage was ×, a beverage having an improved deodorizing effect compared to an unheated beverage was ○, and among those improved, the degree of improvement was particularly high. The ones that were high were plotted as ●. The results (without improving the deodorizing effect) of the heat treatment at 60 ° C. for 18 hours are not shown in FIG. The range in which the effect of the heat treatment is effective is shown by the approximate expression Y ≧ −0.24X + 66 (where X> 0 and Y> 60), where X is the heating time (minutes) and Y is the heating temperature (° C.). I was able to.
（実施例３）
実施例２の活性炭をやし殻由来活性炭、または、もみ殻由来活性炭に変えて実施例２と同様の試験を行った。結果を表３に示す。いずれの飲料においても、活性炭配合量は１ｇ／１００ｍｌであり、加熱飲料の加熱処理条件は８５℃、１分であった。その結果、いずれの活性炭でも加熱による消臭効果の向上が見られた。
(Example 3)
The same test as in Example 2 was carried out by changing the activated carbon of Example 2 to coconut shell-derived activated carbon or rice husk-derived activated carbon. The results are shown in Table 3. In each of the beverages, the amount of activated carbon blended was 1 g / 100 ml, and the heat treatment conditions for the heated beverage were 85 ° C. for 1 minute. As a result, the deodorizing effect of all activated carbons was improved by heating.
Claims (2)
０．１〜２０ｗ／ｖ％の活性炭と水とを含有する液体を加熱することを含み、
前記加熱の条件が、加熱時間（分）をＸ、加熱温度（℃）をＹとしたとき、以下の式（１）の条件：
式（１） Ｙ≧−０．２４Ｘ＋６６ （ただし、Ｘ＞０かつＹ＞６０）
を満たすものであり、
前記活性炭が、もみ殻由来の活性炭、やし殻由来の活性炭、及び竹由来の活性炭からなる群から選択される１つまたはそれ以上を含む、
前記製造方法。 It is a method for producing activated carbon-containing beverages.
It looks including heating the liquid containing the 0.1 to 20 / v% of activated carbon and water,
Assuming that the heating time (minutes) is X and the heating temperature (° C.) is Y, the conditions of the following formula (1) are:
Equation (1) Y ≧ −0.24X + 66 (where X> 0 and Y> 60)
Der to satisfy the is,
The activated carbon comprises one or more selected from the group consisting of rice husk-derived activated carbon, coconut shell-derived activated carbon, and bamboo-derived activated carbon.
The manufacturing method.
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