JP6090984B2 - Soft magnetic sheet - Google Patents

Soft magnetic sheet Download PDF

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JP6090984B2
JP6090984B2 JP2012287749A JP2012287749A JP6090984B2 JP 6090984 B2 JP6090984 B2 JP 6090984B2 JP 2012287749 A JP2012287749 A JP 2012287749A JP 2012287749 A JP2012287749 A JP 2012287749A JP 6090984 B2 JP6090984 B2 JP 6090984B2
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soft magnetic
foil layer
base fabric
magnetic sheet
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JP2014129681A (en
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清 前橋
清 前橋
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Nichilaymagnet Co Ltd
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Description

本発明は、磁着効果のない壁等の平滑面に貼着することによって,マグネット部材を該壁等に磁着できるようにする軟質磁性体シートに関する。   The present invention relates to a soft magnetic sheet that allows a magnet member to be magnetically attached to a wall or the like by sticking to a smooth surface such as a wall that does not have a magnetic attachment effect.

従来、軟質磁性体である鉄箔層を有し表面に筆記面を有する書板の筆記面交換用表面材が提案されている(特許文献1)。該筆記面交換用表面材は,筆記面と,該筆記面の下側に設けた厚さ50〜100μmの鉄箔層と,該鉄箔層の下側に設けた施工時に接着剤による接着が可能な材質の可撓性基材層とから成る構造を持つことを特徴とする磁気性能を持った軽量かつシート状の書板の筆記面交換用表面材である。   Conventionally, a writing surface replacement surface material for a writing board having an iron foil layer which is a soft magnetic material and having a writing surface on the surface has been proposed (Patent Document 1). The writing surface replacement surface material has a writing surface, an iron foil layer having a thickness of 50 to 100 μm provided on the lower side of the writing surface, and adhesion by an adhesive during construction provided on the lower side of the iron foil layer. A surface material for replacing the writing surface of a lightweight and sheet-like writing board having magnetic performance, characterized by having a structure comprising a flexible base material layer made of a possible material.

特開平7−132697号公報JP-A-7-13297

しかしながら、特許文献1記載の筆記面交換用表面材の可撓性基材層は,該文献の明細書段落0015に記載のように難燃紙等の可撓性に優れた基材で構成されているため,該筆記面交換用表面材の鉄箔層に局部的な変形応力が加わると,この応力を分散させることが難しく,容易に鉄箔層が局部的に折り曲げられて跡が残る場合があるという課題がある。   However, the flexible base material layer of the writing surface replacement surface material described in Patent Document 1 is composed of a base material having excellent flexibility, such as flame retardant paper, as described in paragraph 0015 of the specification of this document. Therefore, when a local deformation stress is applied to the iron foil layer of the writing surface replacement surface material, it is difficult to disperse this stress, and the iron foil layer is easily bent locally to leave a mark. There is a problem that there is.

本発明が解決しようとする課題は、軟質磁性金属箔層である鉄箔層や鋼箔層に局部的な変形応力が加わっても,該応力を分散させて,軟質磁性金属箔層である鉄箔層や鋼箔層に局部的な折り曲げ跡が残ることがない軟質磁性体シートを提供することにある。   The problem to be solved by the present invention is that even if a local deformation stress is applied to the iron foil layer or the steel foil layer, which is a soft magnetic metal foil layer, the stress is dispersed and the iron which is the soft magnetic metal foil layer. An object of the present invention is to provide a soft magnetic sheet in which a local bending trace does not remain in a foil layer or a steel foil layer.

請求項1記載の発明は、軟質磁性金属箔層の上に表面層を設け、軟質磁性金属箔層の下に基布層を設け、軟質磁性金属箔層は鋼箔層であり、基布層は編み物地から成り、基布層の下に粘着層を設け、表面層は塗工紙、樹脂フィルムまたは壁用装飾紙のいずれかから成り、鋼箔層の厚みは50〜300μmであり、基布層の厚みは0.2〜0.7mmであり、基布層は両面メリヤス編み物地であり、10cm当たりのループ数は90〜100であることを特徴とする軟質磁性体シートを提供する。
According to the first aspect of the present invention, a surface layer is provided on the soft magnetic metal foil layer, a base fabric layer is provided below the soft magnetic metal foil layer, and the soft magnetic metal foil layer is a steel foil layer, Is made of knitted fabric, an adhesive layer is provided under the base fabric layer, the surface layer is made of either coated paper, resin film or wall decorative paper, and the thickness of the steel foil layer is 50 to 300 μm. the thickness of the fabric layer Ri 0.2~0.7mm der, the base fabric layer is a double-sided knitted fabric area, number of loops per 10cm offer soft magnetic sheet, wherein 90-100 der Rukoto To do.

本発明に係る軟質磁性体シートは,軟質磁性金属箔層である鋼箔層に局部的な変形応力が加わっても,基布層に弾力性があるため該応力が効果的に分散されて鋼箔層が局部的に折り曲げられることが無く,このため鋼箔層に折り曲げ跡が残ることがないという効果がある。また鋼箔層は軟質磁性体であるため,マグネット部材を磁着させることができる効果がある。   In the soft magnetic sheet according to the present invention, even if a local deformation stress is applied to the steel foil layer, which is a soft magnetic metal foil layer, the base fabric layer is elastic, so that the stress is effectively dispersed and the steel sheet is steel. There is no effect that the foil layer is not locally bent, so that no folding marks remain on the steel foil layer. Moreover, since the steel foil layer is a soft magnetic material, there is an effect that a magnet member can be magnetized.

また本発明に係る軟質磁性体シートは、基布層が編み物地から成るため、基布層の柔軟性が高く、鋼箔層に局部的な変形応力が加わっても、より柔軟に該応力を分散させることができ、このため軟質磁性金属箔層である鋼箔層が局部的に折り曲げられることがなく、折り曲げ跡が残ることがないという効果がある。
In the soft magnetic sheet according to the present invention, since the base fabric layer is made of knitted fabric, the flexibility of the base fabric layer is high, and even when a local deformation stress is applied to the steel foil layer, the stress is more flexibly applied. Therefore, the steel foil layer, which is a soft magnetic metal foil layer, is not locally bent, and there is an effect that no trace of bending remains.

また本発明に係る軟質磁性体シートは、基布層の下に粘着層が設けられているため、壁等に該粘着層を介して軟質磁性体シートを貼着させることができ、あらためて接着剤を塗布する必要がなく、迅速に軟質磁性体シートを壁等に貼着することができるという効果がある。
In addition , since the soft magnetic sheet according to the present invention has an adhesive layer provided under the base fabric layer, the soft magnetic sheet can be attached to a wall or the like via the adhesive layer, The soft magnetic material sheet can be quickly adhered to a wall or the like.

また本発明に係る軟質磁性体シートは、表面層は塗工紙,樹脂フィルムまたは壁用装飾紙のいずれかから成るため、建造物の内装用として使用できる効果がある。
Further, the soft magnetic sheet according to the present invention has an effect that the surface layer is made of any one of coated paper, resin film, and wall decorative paper, and can be used for interior decoration of a building.

本発明に係る軟質磁性体シート(粘着層を省略)の断面状態図である。It is a sectional state figure of the soft magnetic material sheet (adhesion layer is omitted) concerning the present invention. 本発明に係る軟質磁性体シートの断面状態図である。The present invention is a cross-sectional state diagram of the engagement Ru soft quality magnetic sheet.

次に本発明に係る軟質磁性体シートを実施するための形態について説明する。
図1は本発明に係る軟質磁性体シート1の断面状態図であり,2は表面層である。該表面層2は塗工紙,樹脂フィルム,壁用装飾紙等いずれであってもよい。樹脂フィルムの場合は,水性マーカーで該表面層2に筆記をすることができる。
Next, a mode for carrying out the soft magnetic sheet according to the present invention will be described.
FIG. 1 is a sectional state diagram of a soft magnetic sheet 1 according to the present invention, and 2 is a surface layer. The surface layer 2 may be any of coated paper, resin film, wall decorative paper, and the like. In the case of a resin film, the surface layer 2 can be written with an aqueous marker.

表面層2の下には鋼箔層3が設けられ、鋼箔層3の下には編み物地である基布層4が形成され、鋼箔層3の厚みは50〜300μmが適している。50μm未満ではマグネット部材の磁着力が不十分であり、300μm超では鋼箔層3の可撓性が不足し、取り扱いが不便となる。本実施例では軟質磁性金属箔層には鉄箔を使用したが、マグネットが磁着するSUS430等の他の軟質磁性金属箔を使用してもよい。
A steel foil layer 3 is provided under the surface layer 2, and a base fabric layer 4 that is a knitted fabric is formed under the steel foil layer 3. The thickness of the steel foil layer 3 is preferably 50 to 300 μm. If it is less than 50 μm, the magnetizing force of the magnet member is insufficient, and if it exceeds 300 μm, the flexibility of the steel foil layer 3 is insufficient and handling becomes inconvenient. In this embodiment, an iron foil is used for the soft magnetic metal foil layer, but other soft magnetic metal foil such as SUS430 on which a magnet is magnetically attached may be used.

基布層4は編み物地であることが望ましい。編み物地であることにより,一般的な紙等より柔軟性が高く,ニット服地と同様に局部的に皴や折り曲げ跡が残ることがなく,結果として鋼箔層3に局部的な折り曲げ応力が加わっても,該鋼箔層3と隣接し一体化している基布層4が,該応力を分散させ,鋼箔層3に折り曲げ跡が残ることがない。   The base fabric layer 4 is preferably a knitted fabric. Because it is knitted fabric, it is more flexible than ordinary paper, and there is no wrinkle or bending trace left as in knitted clothing. As a result, local bending stress is applied to the steel foil layer 3. However, the base fabric layer 4 which is adjacent to and integrated with the steel foil layer 3 disperses the stress, so that no folding marks remain on the steel foil layer 3.

また基布層4は0.2mm〜0.7mmが効果的な上記応力分散の点で好ましく,0.2mm未満では応力分散が不十分となり,鋼箔層3に折り曲げ跡が残る場合がある。0.7mm超では重量が重くなり,壁等に貼着する際の施工性が低下する。   Further, the base fabric layer 4 is preferably 0.2 mm to 0.7 mm from the viewpoint of effective stress dispersion, and if it is less than 0.2 mm, the stress dispersion is insufficient, and the steel foil layer 3 may be left with a folding mark. If it exceeds 0.7 mm, the weight becomes heavy, and the workability when sticking to a wall or the like is lowered.

基布層4を両面メリヤス編み物地とした場合の10cm当たりのループ数としては,90〜100が好ましく,90未満では応力分散能力が低下する場合があるなど好ましくなく,100超では柔軟性が低下する場合があるなど好ましくない。またこの際の編み物に使用する糸の材質はレーヨン/ポリエステル(混紡)が好ましく,該糸の太さとしては,20〜40番手が好ましい。20番手未満では強度過多となり可撓性が低下する場合があるなど好ましくなく,40番手番手超では強度不足となり応力分散能力が低下する場合があるなど好ましくない。   When the base fabric layer 4 is a double-sided knitted fabric, the number of loops per 10 cm is preferably 90 to 100. If it is less than 90, the stress dispersion capability may be lowered, and if it exceeds 100, the flexibility is lowered. It may not be preferable. Moreover, the material of the yarn used for the knitting is preferably rayon / polyester (blend), and the thickness of the yarn is preferably 20 to 40. If it is less than 20th, it is not preferable because the strength is excessive and flexibility may be lowered, and if it is more than 40th, it is not preferable because the strength is insufficient and stress dispersion ability may be lowered.

図2は本発明に係る軟質磁性体シート10の断面状態図である。12は表面層であり、表面層12の下には軟質磁性体金属箔層である鋼箔層13が設けられ、該鋼箔層13の下には編み物地である基布層14が形成されている。基布層14の下にはアクリル樹脂、ウレタン樹脂またはシリコーン樹脂から成る粘着層15が設けられている。通常は粘着層15を覆う剥離紙(図示せず)がさらに設けられ、壁等に粘着層15を介して軟質磁性体シート10を貼着させる直前に、該剥離紙を取り除く。
Figure 2 is a sectional phase diagram of the engagement Ru soft quality magnetic sheet 10 to the present invention. 12 is a surface layer, and a steel foil layer 13 which is a soft magnetic metal foil layer is provided under the surface layer 12, and a base fabric layer 14 which is a knitted fabric is formed under the steel foil layer 13. ing. Under the base fabric layer 14, an adhesive layer 15 made of acrylic resin, urethane resin, or silicone resin is provided. Usually, a release paper (not shown) covering the adhesive layer 15 is further provided, and the release paper is removed immediately before the soft magnetic sheet 10 is attached to the wall or the like via the adhesive layer 15.

以下,実施例及び比較例にて本出願に係る軟質磁性体シートについて具体的に説明する。   Hereinafter, the soft magnetic material sheet according to the present application will be specifically described in Examples and Comparative Examples.

表1に示す仕様にて実施例1乃至実施例5及び比較例1乃至比較例3の軟質磁性体シートを作製した。表面層に使用した塗工紙には市販アート紙 特菱アート片面(商品名,三菱製紙社製,厚さ0.11mm),鋼箔には亜鉛メッキ鋼板(商品名,東洋鋼鈑社製),基布には,太さ30番手のレーヨン/ポリエステル混紡の糸を両面メリヤス編みしたもので,10cm当たりのループ数が,縦方向90〜95,横方向95〜100の編み物地(厚さ0.5mm)を用い,各層は市販の水性ビニルウレタン系接着剤スミカフレックス801HQ(商品名,住友化学社製)にて接着させ,23℃7日間養生後,以下に示す評価を行なった。比較例3の基布には, 太さ90番手のレーヨン/ポリエステル混紡の糸を両面メリヤス編みしたもので,10cm当たりのループ数が,縦方向250〜260,横方向270〜280の編み物地(厚さ0.15mm)を用いた。   Soft magnetic sheets of Examples 1 to 5 and Comparative Examples 1 to 3 were prepared according to the specifications shown in Table 1. The coated paper used for the surface layer is a commercial art paper, one side of the special art paper (trade name, manufactured by Mitsubishi Paper Industries, thickness 0.11 mm), and the steel foil is a galvanized steel sheet (trade name, manufactured by Toyo Kohan Co., Ltd.) The base fabric is a 30-thick rayon / polyester blend yarn knitted on both sides, and the number of loops per 10 cm is 90-95 in the vertical direction and 95-100 in the horizontal direction (thickness 0). Each layer was bonded with a commercially available aqueous vinyl urethane adhesive Sumikaflex 801HQ (trade name, manufactured by Sumitomo Chemical Co., Ltd.), cured at 23 ° C. for 7 days, and evaluated as follows. The base fabric of Comparative Example 3 is a knitted fabric in which a 90-thick rayon / polyester blend yarn is knitted on both sides and the number of loops per 10 cm is 250 to 260 in the longitudinal direction and 270 to 280 in the transverse direction ( Thickness 0.15 mm) was used.

Figure 0006090984
Figure 0006090984

〔評価項目及び評価方法〕 [Evaluation items and methods]

〔馬蹄形跡の付き易さ〕
実施例1乃至実施例5及び比較例1乃至比較例3の軟質磁性体シートを,人差し指と中指の上に載せて,親指にて強く載荷するようにして曲げ応力を加える。その後,軟質磁性体シートに馬蹄形跡が残るものを×,馬蹄形跡が残らないものを○と評価した。
[Ease of attaching horseshoe traces]
The soft magnetic sheets of Examples 1 to 5 and Comparative Examples 1 to 3 are placed on the index finger and the middle finger, and bending stress is applied so as to be strongly loaded with the thumb. After that, those with a horseshoe trace left on the soft magnetic sheet were evaluated as “X”, and those without a horseshoe trace left as “◯”.

〔柔軟性〕
実施例1乃至実施例5及び比較例1乃至比較例3の軟質磁性体シートを,ロール状に巻き,容易に巻けるものを○,反発力があって巻きにくいものを×と評価した。
[Flexibility]
The soft magnetic sheets of Examples 1 to 5 and Comparative Examples 1 to 3 were evaluated as ◯ when they were wound in a roll and easily wound, and X when they were repulsive and difficult to wind.

〔マグネット吸着性〕
実施例1乃至実施例5及び比較例1乃至比較例3の軟質磁性体シートを垂直状に保持し,多極着磁(極間3.0mm)を施した軟鉄との磁気吸着力96gf/cmの異方性マグネットシート(3cm×3cm)を非磁性体に積層してなる自重150gfのマグネット部品を試験体表面に磁着させる。該マグネット部品が落下しないものを○と評価し,落下するものを×評価した。
[Magnet adsorption]
Magnetic attraction force of 96 gf / cm with soft iron obtained by holding the soft magnetic sheets of Examples 1 to 5 and Comparative Examples 1 to 3 vertically and applying multipolar magnetization (3.0 mm between poles) A magnet component having a self-weight of 150 gf obtained by laminating two anisotropic magnet sheets (3 cm × 3 cm) on a nonmagnetic material is magnetically attached to the surface of the test body. A case where the magnet part did not fall was evaluated as “good”, and a case where the magnetic part was dropped was evaluated as “x”.

〔総合評価〕
すべての評価項目が○評価のものを○とし,これ以外を×とした。
〔Comprehensive evaluation〕
All evaluation items were evaluated as ○, and other items were evaluated as ×.

〔評価結果〕
評価結果を表2に示す。
表2に示すように,実施例1乃至実施例5は総合評価が○であったが,比較例は×であった。
〔Evaluation results〕
The evaluation results are shown in Table 2.
As shown in Table 2, the overall evaluation of Examples 1 to 5 was “good”, but the comparative example was “poor”.

Figure 0006090984
Figure 0006090984

1 軟質磁性体シート
2 表面層
3 鋼箔層
4 基布層
10 軟質磁性体シート
12 表面層
13 鋼箔層
14 基布層
15 粘着層
DESCRIPTION OF SYMBOLS 1 Soft magnetic sheet 2 Surface layer 3 Steel foil layer 4 Base cloth layer 10 Soft magnetic sheet 12 Surface layer 13 Steel foil layer 14 Base cloth layer 15 Adhesive layer

Claims (1)

軟質磁性金属箔層の上に表面層を設け、軟質磁性金属箔層の下に基布層を設け、軟質磁性金属箔層は鋼箔層であり、基布層は編み物地から成り、基布層の下に粘着層を設け、表面層は塗工紙、樹脂フィルムまたは壁用装飾紙のいずれかから成り、鋼箔層の厚みは50〜300μmであり、基布層の厚みは0.2〜0.7mmであり、基布層は両面メリヤス編み物地であり、10cm当たりのループ数は90〜100であることを特徴とする軟質磁性体シート。
A surface layer is provided on the soft magnetic metal foil layer, a base fabric layer is provided below the soft magnetic metal foil layer, the soft magnetic metal foil layer is a steel foil layer, and the base fabric layer is made of knitted fabric. An adhesive layer is provided under the layer, the surface layer is composed of any one of coated paper, resin film, or wall decorative paper, the thickness of the steel foil layer is 50 to 300 μm, and the thickness of the base fabric layer is 0.2. ~0.7mm der is, the base fabric layer is a double-sided knitted fabric area, the soft magnetic sheet loops per 10cm is characterized by 90-100 der Rukoto.
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US20170037567A1 (en) 2015-08-05 2017-02-09 Milliken & Company Washable Multi-Component Magnetic Floor Mat
US20170037568A1 (en) 2015-08-05 2017-02-09 Milliken & Company Installation of Multi-Component Floor Mat
US20180055266A1 (en) 2016-08-24 2018-03-01 Milliken & Company Floor Mat with Hidden Base Component

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JPS58131076U (en) * 1982-02-27 1983-09-05 日本ゼオン株式会社 Bulletin board sheet
JPH0633177U (en) * 1992-09-22 1994-04-28 大洋株式会社 Surface sheet material
JPH07132697A (en) * 1993-11-10 1995-05-23 Nagoya Kokuban Kk Surface material for replacement of writing surface of writing plate
JP2882566B2 (en) * 1994-05-18 1999-04-12 巴紙工株式会社 Surface sheet material and method of attaching the same
JP2001166719A (en) * 1999-12-10 2001-06-22 Keiwa Inc Magnet chip-attachable notice sheet
JP4979010B2 (en) * 2007-07-10 2012-07-18 株式会社アサヒペン Adhesive wallpaper
JP3170964U (en) * 2011-07-28 2011-10-06 株式会社夢創舎 Magnetized wallpaper
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