JP5656343B2 - 精製ペンタメチレンジアミンの製造方法 - Google Patents
精製ペンタメチレンジアミンの製造方法 Download PDFInfo
- Publication number
- JP5656343B2 JP5656343B2 JP2007336609A JP2007336609A JP5656343B2 JP 5656343 B2 JP5656343 B2 JP 5656343B2 JP 2007336609 A JP2007336609 A JP 2007336609A JP 2007336609 A JP2007336609 A JP 2007336609A JP 5656343 B2 JP5656343 B2 JP 5656343B2
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- Japan
- Prior art keywords
- pentamethylenediamine
- phase
- alkali
- solution
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 title claims description 446
- 238000000034 method Methods 0.000 title claims description 62
- 230000008569 process Effects 0.000 title description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 117
- 239000000243 solution Substances 0.000 claims description 86
- 150000003839 salts Chemical class 0.000 claims description 51
- 108010048581 Lysine decarboxylase Proteins 0.000 claims description 50
- 239000003513 alkali Substances 0.000 claims description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- 239000007864 aqueous solution Substances 0.000 claims description 37
- 238000004519 manufacturing process Methods 0.000 claims description 31
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- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 claims description 29
- 238000004821 distillation Methods 0.000 claims description 29
- 229920006122 polyamide resin Polymers 0.000 claims description 28
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- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
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- FGNLEIGUMSBZQP-UHFFFAOYSA-N cadaverine dihydrochloride Chemical compound Cl.Cl.NCCCCCN FGNLEIGUMSBZQP-UHFFFAOYSA-N 0.000 claims 1
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- OACUNRCVXCMTJN-UHFFFAOYSA-N CADAVERINE SULFATE Chemical compound [O-]S([O-])(=O)=O.[NH3+]CCCCC[NH3+] OACUNRCVXCMTJN-UHFFFAOYSA-N 0.000 description 8
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- 239000000126 substance Substances 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
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| JP5630286B2 (ja) * | 2010-01-29 | 2014-11-26 | 東レ株式会社 | ポリアミド樹脂の製造方法 |
| JP5623310B2 (ja) * | 2010-03-01 | 2014-11-12 | 三井化学株式会社 | ペンタメチレンジアミンまたはその塩、および、その製造方法 |
| JP2011201863A (ja) * | 2010-03-01 | 2011-10-13 | Mitsui Chemicals Inc | ペンタメチレンジイソシアネート、ポリイソシアネート組成物、ペンタメチレンジイソシアネートの製造方法、および、ポリウレタン樹脂 |
| JP5729085B2 (ja) * | 2010-03-31 | 2015-06-03 | 三菱化学株式会社 | ペンタメチレンジアミンの製造方法及びポリアミド樹脂の製造方法 |
| MY163292A (en) | 2011-03-09 | 2017-09-15 | Mitsui Chemicals Inc | Pentamethylenediisocyanate, method for producing pentamethylenediisocyanate, polyisocyanate composition, polyurethane resin, and polyurea resin |
| JP6147475B2 (ja) * | 2012-07-02 | 2017-06-14 | 御木本製薬株式会社 | 蛋白質の加水分解の方法および蛋白質加水分解物 |
| CN104968640B (zh) | 2013-02-08 | 2017-11-10 | 味之素株式会社 | 保存1，5‑戊二胺或其盐的方法、防止其变色的方法、和包装的1，5‑戊二胺或其盐 |
| KR20150115533A (ko) * | 2014-04-04 | 2015-10-14 | 씨제이제일제당 (주) | 1,5-디아미노펜탄의 정제방법 |
| KR101802343B1 (ko) * | 2017-03-31 | 2017-11-28 | 씨제이제일제당 주식회사 | 1,5-디아미노펜탄의 정제방법 |
| CN114315601A (zh) * | 2020-10-09 | 2022-04-12 | 上海凯赛生物技术股份有限公司 | 一种1,5-戊二胺的提取方法、所得的1,5-戊二胺产品及聚酰胺 |
| CN117986134A (zh) * | 2022-10-28 | 2024-05-07 | 中国科学院过程工程研究所 | 一种高纯度1,5-戊二胺的提纯方法 |
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