JP5601861B2 - Manufacturing method of boron steel rolled annealed steel sheet - Google Patents

Manufacturing method of boron steel rolled annealed steel sheet Download PDF

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JP5601861B2
JP5601861B2 JP2010073842A JP2010073842A JP5601861B2 JP 5601861 B2 JP5601861 B2 JP 5601861B2 JP 2010073842 A JP2010073842 A JP 2010073842A JP 2010073842 A JP2010073842 A JP 2010073842A JP 5601861 B2 JP5601861 B2 JP 5601861B2
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幸男 片桐
誠 秋月
恒年 洲▲崎▼
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Nippon Steel Nisshin Co Ltd
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本発明は、良好な加工性、焼入れ性および溶接性を兼備し、かつ局部延性にも優れた、自動車部品をはじめとする各種機械部品に好適なボロン鋼の鋼板およびその製造法に関する。   The present invention relates to a steel plate made of boron steel suitable for various machine parts including automobile parts, which has good workability, hardenability and weldability, and excellent in local ductility, and a method for producing the same.

少量のBを添加した炭素鋼(ボロン鋼)は焼入れ性に優れることから、板厚中心部まで十分に焼きが入る(マルテンサイト組織となる)ことが要求される種々の部品用途において、低コスト材として使用されている。ボロン鋼の圧延焼鈍鋼板(焼鈍された熱延鋼板または冷延鋼板)は、打抜き、曲げなどのプレス成形や、鍛造、切削などの工程により所定の部品形状に加工されたのち、焼入れ・焼戻し、高周波焼入れ、浸炭焼入れ等の熱処理を施して使用される。また、このような焼入れ品に対し溶接が施されることもある。したがって、素材であるボロン鋼圧延焼鈍鋼板には加工性、焼入れ性、さらには焼入れ後の溶接性など、用途に応じた特性が要求される。   Since carbon steel (boron steel) with a small amount of B is excellent in hardenability, it is low cost in various parts applications that require sufficient quenching to the center of the plate thickness (becomes a martensite structure). Used as a material. Rolled and annealed steel sheet of boron steel (annealed hot-rolled steel sheet or cold-rolled steel sheet) is processed into a predetermined part shape by press forming such as punching and bending, and forging and cutting, and then quenched and tempered. Used after heat treatment such as induction hardening and carburizing and quenching. Moreover, welding may be performed with respect to such a hardened product. Therefore, the boron steel rolled annealed steel sheet, which is a raw material, is required to have characteristics corresponding to applications such as workability, hardenability, and weldability after quenching.

しかしながら、ボロン鋼鋼板には以下のような問題が生じている。
(i)鋼板の製造段階、あるいは部品成形後の焼入れ時に施される高温加熱によって、鋼材表層部の固溶Bが減少する(脱B)。
(ii)脱Bによって表層部の焼入れ性が低下し、焼入れ品の表面硬さが低下することがある。
(iii)特に板厚が大きい場合、焼入れ時の冷却速度が低下するため、表面硬さの低下が助長されやすい。場合によっては板厚中心部付近の断面硬さも低下して素材そのものの強度が不足することもある。
However, the following problems occur in the boron steel sheet.
(I) The solid solution B of the steel surface layer portion is reduced by high-temperature heating performed at the time of manufacturing the steel sheet or at the time of quenching after forming the part (de-B).
(Ii) The hardenability of the surface layer portion may decrease due to removal B, and the surface hardness of the quenched product may decrease.
(Iii) Particularly when the plate thickness is large, the cooling rate at the time of quenching is lowered, so that the reduction in surface hardness is easily promoted. In some cases, the cross-sectional hardness in the vicinity of the central portion of the plate thickness is also reduced, and the strength of the material itself may be insufficient.

表面硬さの低下について、これまでにも対応策が提案されている。例えば特許文献1には、C含有量が0.15〜0.35重量%のボロン鋼を使用し、保護雰囲気中で雰囲気ガスのカーボンポテンシャルを素材炭素量より0.04〜0.25%高く設定し、部品表面を微浸炭させた後、焼入れすることにより、脱Bによる表面部の焼入れ性低下を補う手法が開示されている。しかし、この方法では浸炭処理のための設備が必要となる。また、高周波焼入れ、電子ビーム焼入れなど、短時間加熱の局部焼入れにはこの手法は適用できない。   Countermeasures have been proposed for the reduction in surface hardness. For example, in Patent Document 1, boron steel having a C content of 0.15 to 0.35 wt% is used, and the carbon potential of the atmospheric gas in the protective atmosphere is 0.04 to 0.25% higher than the material carbon content. A method is disclosed that compensates for the hardenability deterioration of the surface portion due to de-B by setting and finely carburizing the surface of the component and then quenching. However, this method requires equipment for carburizing treatment. Further, this method cannot be applied to local quenching such as induction quenching and electron beam quenching for a short time.

また、特許文献2には、C含有量が0.1〜0.3質量%のボロン鋼を使用し、Ti、Nbの炭窒化物を微細析出させることによって浸炭時における粗大粒の発生を防止し、さらにCr、Moを添加して脱Bによる焼入れ性低下を補い、表面から深さ0.2〜0.7mmに生成する不完全焼入れ組織の生成を防止している。しかし、この方法ではTi、Nbの炭窒化物を微細析出させるために800〜500℃の温度範囲を1℃/sec以下の冷却速度で徐冷する必要があり、製造性に劣る。また、浸炭を施さない焼入れ時に問題となる表面硬さの低下については考慮されていない。   Patent Document 2 uses boron steel having a C content of 0.1 to 0.3% by mass, and prevents the formation of coarse grains during carburization by fine precipitation of carbonitrides of Ti and Nb. Further, Cr and Mo are added to compensate for the hardenability deterioration due to de-B, and the generation of an incompletely hardened structure formed to a depth of 0.2 to 0.7 mm from the surface is prevented. However, in this method, in order to finely precipitate carbonitrides of Ti and Nb, it is necessary to gradually cool the temperature range of 800 to 500 ° C. at a cooling rate of 1 ° C./sec or less, resulting in poor productivity. Further, no consideration is given to the decrease in surface hardness, which is a problem during quenching without carburizing.

特開昭57−94516号公報JP-A-57-94516 特開2001−303172号公報JP 2001-303172 A

上記のように、ボロン鋼の焼入れ時における表面硬さ低下に対しては、浸炭処理を施して対応することができる。しかし、浸炭処理は設備投資、処理時間、処理コストにおいて問題があり、安価な部品が要求される用途では必ずしも容易に採用できるものではない。また、焼入れ前の部品加工においてはできるだけ寸法精度の高い加工品を得ることが望まれる。特にファインブランキング打抜き加工を行う場合には「局部伸び」の良好な材料を使用することが寸法精度を高める上で極めて有利となる。しかしながら、焼入れ部材用の鋼板において、一般的な延性とともに局部伸びを十分に改善することは容易ではなく、現状の材料においては昨今の加工ニーズに必ずしも対応できているとは言えない。   As described above, the carburization treatment can be applied to the reduction in surface hardness during quenching of boron steel. However, the carburizing process has problems in capital investment, processing time, and processing cost, and is not always easily adopted in applications that require inexpensive parts. In addition, it is desired to obtain a processed product with as high a dimensional accuracy as possible in parts processing before quenching. In particular, when performing fine blanking punching, it is extremely advantageous to increase the dimensional accuracy by using a material having good “local elongation”. However, it is not easy to sufficiently improve local elongation as well as general ductility in a steel sheet for a quenched member, and it cannot be said that current materials necessarily meet the recent processing needs.

本発明はこのような現状に鑑み、焼入れ前の素材鋼板として、通常の加工性(延性)に加えて局部伸びにも優れ、焼入れに際しては板厚が厚い場合でも部品表層部の高い焼入れ硬さが確保され、さらに焼入れ後に良好な溶接性が得られる鋼板素材を提供しようというものである。   In view of the current situation, the present invention is excellent in local elongation in addition to normal workability (ductility) as a raw steel plate before quenching, and has a high quenching hardness in the surface part of the component even when the plate thickness is thick during quenching. Is intended to provide a steel plate material that can secure good weldability after quenching.

発明者らの研究によれば、上記目的に合致する鋼板は、成分組成を特定範囲に調整した上で、熱間圧延において巻取温度を規定し、巻取までの冷却速度を厳密にコントロールし、かつ、所定のヒートパターンを有する焼鈍を施すことによって実現できることがわかった。   According to the inventors' research, steel sheets that meet the above objectives are adjusted to a specific range of component composition, and then the coiling temperature is defined in hot rolling, and the cooling rate until coiling is strictly controlled. And it turned out that it can implement | achieve by giving the annealing which has a predetermined | prescribed heat pattern.

すなわち本発明では、質量%で、C:0.15〜0.35%、Si:0.50%以下、Mn:0.20〜1.00%、P:0.030%以下、S:0.020%以下、Cr:0.20〜1.00%、Al:0.005〜0.200%、Ti:0.01〜0.20%、B:0.0005〜0.0050%、N:0.0080%以下、残部Feおよび不可避的不純物、下記(1)式により定まるX値が17.00以上、下記(2)式により定まる炭素当量Ceqが0.500以下である化学組成を有し、圧延方向の全伸びT.Elが38.0%以上、圧延方向JIS5号引張試験片の平行部中央の両エッジに2mmVノッチを形成した切欠き引張試験片を用いた標点距離10mmの引張試験による局部伸びElvが43.0%以上となる延性を有するボロン鋼圧延焼鈍鋼板が提供される。
X値=5.5C1/2(1+0.6Si)(1+4.1Mn)(1+2.3Cr) …(1)
Ceq=C+Si/24+Mn/6+Cr/5 …(2)
That is, in the present invention, in mass%, C: 0.15 to 0.35%, Si: 0.50% or less, Mn: 0.20 to 1.00%, P: 0.030% or less, S: 0 0.020% or less, Cr: 0.20 to 1.00%, Al: 0.005 to 0.200%, Ti: 0.01 to 0.20%, B: 0.0005 to 0.0050%, N : A chemical composition having 0.0080% or less, the balance Fe and inevitable impurities, an X value determined by the following formula (1) of 17.00 or more, and a carbon equivalent Ceq determined by the following formula (2) of 0.500 or less. The total elongation T.E1 in the rolling direction is 38.0% or more, and the mark distance is 10 mm using notched tensile test pieces in which 2 mm V notches are formed at both edges in the center of the parallel part of the rolling direction JIS No. 5 tensile test piece. boron steel rolled annealed steel sheet local elongation Elv by tensile test ductile comprising 43.0% or more Hisage It is.
X value = 5.5C 1/2 (1 + 0.6Si) (1 + 4.1Mn) (1 + 2.3Cr) (1)
Ceq = C + Si / 24 + Mn / 6 + Cr / 5 (2)

上記(1)式、(2)式の元素記号の箇所には当該元素の質量%で表された含有量の値が代入される。全伸びT.Elは、長手方向が圧延方向となるように採取したJIS5号引張試験片を用いてJIS Z2241:1998に従い常温で破断するまで引張試験を行うことによって、標点距離50mmの部分について記録される破断時点での伸び率(%)の値が採用される。また、局部伸びElvは、長手方向が圧延方向となるように採取したJIS5号引張試験片の平行部中央の両エッジに2mmVノッチを形成した切欠き引張試験片を用いること、および標点距離を10mmとすることを除き、T.Elと同様の手法で測定される。2mmVノッチは、シャルピー衝撃試験片においてJISに規定されているVノッチ形状を採用することができる(JIS G0202−1987の番号1311の図7(b))。
本発明のボロン鋼圧延焼鈍鋼板の板厚は例えば1.0〜12.0mmである。
The value of the content expressed in mass% of the element is substituted for the element symbol in the above formulas (1) and (2). The total elongation T.E1 is measured for a portion with a gauge distance of 50 mm by performing a tensile test using a JIS No. 5 tensile test piece collected so that the longitudinal direction is the rolling direction until it breaks at room temperature according to JIS Z2241: 1998. The value of elongation (%) at the time of breaking recorded is adopted. Further, the local elongation Elv is determined by using notched tensile test pieces in which 2 mmV notches are formed at both edges in the center of the parallel part of a JIS No. 5 tensile test specimen taken so that the longitudinal direction is the rolling direction, and the gauge distance is It is measured by the same method as T.El except for 10 mm. The 2 mm V notch can adopt the V notch shape defined by JIS in the Charpy impact test piece (FIG. 7B of number 1311 of JIS G0202-1987).
The thickness of the boron steel rolled annealed steel sheet of the present invention is, for example, 1.0 to 12.0 mm.

また、上記のボロン鋼圧延焼鈍鋼板の製造方法として、
スラブ加熱温度:1100〜1300℃、仕上温度:800〜900℃、仕上圧延パス終了時点から巻取までの平均冷却速度:30〜45℃/sec、巻取温度:500〜650℃の条件で熱間圧延を行い熱延板を得る工程、
必要に応じて、上記熱延板に対して、圧延率60%以下の冷間圧延を施し冷延板を得る工程、
上記熱延板または冷延板に対して、下記条件A、Bのいずれかのヒートパターンで熱処理を施す工程、
を有するボロン鋼圧延焼鈍鋼板の製造法が提供される。
Moreover, as a manufacturing method of said boron steel rolling annealing steel plate,
Slab heating temperature: 1100 to 1300 ° C., finishing temperature: 800 to 900 ° C., average cooling rate from the end of finishing rolling pass to winding: 30 to 45 ° C./sec, winding temperature: 500 to 650 ° C. A step of hot rolling to perform hot rolling,
If necessary, with respect to the hot-rolled sheet, a step of performing cold rolling with a rolling rate of 60% or less to obtain a cold-rolled sheet,
A step of heat-treating the hot-rolled plate or the cold-rolled plate with a heat pattern of any one of the following conditions A and B,
A method of manufacturing a boron steel rolled annealed steel sheet having the following is provided.

〔条件A〕
(A1−30℃)以上A1未満のオーステナイト相未生成温度域で0.5h以上均熱保持し、昇温してA1以上(A1+50℃)以下のオーステナイト相生成温度域で0.5〜20h均熱保持し、その後、前記保持温度から少なくとも(A1−10℃)までを冷却速度5〜30℃/hで徐冷するヒートパターン。
〔条件B〕
(A1−30℃)以上A1未満のオーステナイト相未生成温度域で0.5h以上均熱保持した後、冷却するヒートパターン。
[Condition A]
(A 1 −30 ° C.) or more and less than A 1 in the austenite phase non-generation temperature range, 0.5 h or more soaking is maintained, and the temperature is raised to A 1 or more (A 1 + 50 ° C.) or less in the austenite phase generation temperature range Heat pattern in which soaking is maintained for 5 to 20 hours, and then gradually cooled from the holding temperature to at least (A 1 -10 ° C.) at a cooling rate of 5 to 30 ° C./h.
[Condition B]
(A 1 -30 ° C.) A heat pattern that cools after holding soaking for 0.5 h or more in the austenite phase non-generation temperature range of A 1 or more and less than A 1 .

ただし、上記A1は下記(3)式により定まる値を採用する。
1(℃)=723+29.1Si−10.7Mn+16.9Cr…(3)
However, the value determined by the following equation (3) is adopted as A 1 .
A 1 (° C.) = 723 + 29.1 Si−10.7 Mn + 16.9 Cr (3)

上記(3)式の元素記号の箇所には当該元素の質量%で表された含有量の値が代入される。ここでいう「熱延板」とは、熱延鋼板において巻取後に未だ熱処理を受けていない状態のものを意味する。熱間圧延後に酸洗されたものであっても構わない。「冷延板」とは冷延鋼板において未だ熱処理を受けていない状態のものを意味する。   The value of the content expressed in mass% of the element is substituted for the element symbol in the above formula (3). The term “hot rolled sheet” as used herein means a sheet in a hot rolled steel sheet that has not yet undergone heat treatment after winding. It may be pickled after hot rolling. “Cold-rolled sheet” means a cold-rolled steel sheet that has not yet been heat-treated.

本発明のボロン鋼圧延焼鈍鋼板は、従来のボロン鋼圧延焼鈍鋼板に比べ表層部の焼入れ性に優れ、かつ焼入れ前の加工性(全伸び・局部伸び)も良好であり、寸法精度の高い加工品を得るうえで有利である。さらに良好な溶接性を兼備する。素材鋼板の製造段階および部品製造段階において新たな製造工程の追加を伴うこともない。したがって本発明は、自動車部品をはじめとする各種機械部品の用途において、強度向上、寸法精度向上および製造コストの低減に寄与するものである。   The boron steel rolled annealed steel sheet of the present invention is superior in the hardenability of the surface layer compared to the conventional boron steel rolled annealed steel sheet, and also has good workability (total elongation and local elongation) before quenching, and has high dimensional accuracy. It is advantageous in obtaining a product. It also has good weldability. There is no need to add a new manufacturing process at the manufacturing stage and the part manufacturing stage of the material steel plate. Therefore, the present invention contributes to improvement in strength, improvement in dimensional accuracy, and reduction in manufacturing cost in applications of various machine parts including automobile parts.

〔化学組成〕
以下、本明細書において鋼の化学組成における「%」は特に断らない限り「質量%」を意味する。
Cは、機械構造用部品としての芯部強度を確保するために必要な元素である。十分な強度を確保するためには0.15%以上のC含有量が必要となる。ただし、C含有量が多くなると焼鈍後の加工性が低下し、焼入れ焼戻し後の溶接性も低下する。本発明では、自動車部品をはじめとする各種機械部品に幅広く適用できる加工性および溶接性を持たせることを考慮して、C含有量は0.35%以下の範囲とする。
[Chemical composition]
Hereinafter, “%” in the chemical composition of steel in this specification means “% by mass” unless otherwise specified.
C is an element necessary for securing the core strength as a machine structural component. In order to ensure sufficient strength, a C content of 0.15% or more is required. However, if the C content increases, the workability after annealing decreases, and the weldability after quenching and tempering also decreases. In the present invention, in consideration of providing workability and weldability that can be widely applied to various machine parts including automobile parts, the C content is set to a range of 0.35% or less.

Siは、鋼の脱酸および焼入れ性の向上に有効である。しかし、過剰に添加すると加工性が低下する。また焼鈍時に粒界酸化層の形成を助長し、調質熱処理(焼入れ、焼戻し)後の部材の疲労特性低下を招く要因となる。そのためSi含有量は0.50%以下とする。   Si is effective in deoxidizing steel and improving hardenability. However, if it is added excessively, the workability decreases. Further, it promotes the formation of a grain boundary oxide layer during annealing, and causes a reduction in fatigue characteristics of the member after tempering heat treatment (quenching and tempering). Therefore, the Si content is set to 0.50% or less.

Mnは、脱酸・脱硫、および焼入れ性の向上に有効であり、これらの作用を十分に発揮させるために0.20%以上のMn含有量を確保する。ただし、過剰のMn含有は、焼鈍材を硬質化させ加工性低下を招き、また焼入れ焼戻し後の溶接割れを助長する要因となる。種々検討の結果、Mn含有量は1.0%以下の範囲に制限される。   Mn is effective in improving deoxidation / desulfurization and hardenability, and a Mn content of 0.20% or more is ensured in order to sufficiently exhibit these functions. However, the excessive Mn content causes the annealed material to harden, causing a decrease in workability, and promotes weld cracking after quenching and tempering. As a result of various studies, the Mn content is limited to a range of 1.0% or less.

PおよびSは、鋼の靭性に悪影響を与える元素であり、含有量は少ないほうが望ましい。検討の結果、本発明の成分系においてPは0.030%まで、Sは0.020まで許容される。   P and S are elements that adversely affect the toughness of steel, and it is desirable that the content is small. As a result of the examination, in the component system of the present invention, P is allowed up to 0.030% and S is allowed up to 0.020.

Crは、焼入れ性を向上させ、強度や耐摩耗性を向上させる作用を有する。ただし0.20%未満ではその作用は十分に発揮されない。一方、過剰のCr添加は、焼鈍材を硬質化させ加工性低下の要因となり、また焼入れ焼戻し後における溶接割れ発生の要因となる。Cr含有量は1.00%以下の範囲に制限される。   Cr has effects of improving hardenability and improving strength and wear resistance. However, if it is less than 0.20%, the effect is not sufficiently exhibited. On the other hand, the excessive addition of Cr hardens the annealed material and causes a decrease in workability, and also causes a weld crack after quenching and tempering. The Cr content is limited to a range of 1.00% or less.

Alは、鋼の脱酸材として含有される成分であるが、その他AlNを生成し焼入れ時のオーステナイト粒の異常成長を抑制する作用を有する。また、このN固着効果によりBNの生成を抑制して固溶ボロンによる焼入れ性向上を促進する働きがある。これらの作用を十分に発揮させるために、0.005%以上のトータルAl含有量を確保する必要がある。ただし、過剰なAl含有は鋼板の表面欠陥の原因となりやすく、またコスト高となる。種々検討の結果、Al含有量は0.200%以下の範囲とする必要があり、0.100%以下とすることがより好ましい。   Al is a component contained as a deoxidizing material for steel, but has the effect of suppressing other abnormal growth of austenite grains during quenching by generating other AlN. In addition, this N fixing effect serves to suppress the formation of BN and promote the improvement of hardenability by solid solution boron. In order to fully exhibit these actions, it is necessary to ensure a total Al content of 0.005% or more. However, excessive Al content tends to cause a surface defect of the steel sheet and increases the cost. As a result of various studies, the Al content needs to be in the range of 0.200% or less, more preferably 0.100% or less.

Tiは、鋼中のNと結合してTiNとして析出する。本発明ではTi添加によりBNの析出を防止し、焼入れ性の向上に有効な固溶ボロンを確保する。またTiは焼入れ時のオーステナイト結晶粒径を微細化させる作用を有する。これらの作用を十分に発揮させるためには0.01%以上のTi含有が必要である。ただし、Ti含有量が多くなるとTiCが過剰に析出し、加工性を低下させる。Ti含有量は0.20%以下の範囲とする。   Ti combines with N in the steel and precipitates as TiN. In the present invention, precipitation of BN is prevented by addition of Ti, and solid solution boron effective in improving hardenability is secured. Ti also has the effect of refining the austenite grain size during quenching. In order to fully exhibit these actions, it is necessary to contain 0.01% or more of Ti. However, when the Ti content is increased, TiC is excessively precipitated and the workability is lowered. The Ti content is in the range of 0.20% or less.

Bは、微量の添加によって焼入れ性を顕著に向上させる元素である。鋼中に存在するBのうち、焼入れ性の向上に有効な固溶ボロン量を十分に確保するためには、0.0005%以上のBを含有させる必要がある。ただし、過剰のB含有は鋼の靭性を阻害する要因となるので、B含有量は0.0050%以下の範囲に制限される。   B is an element that significantly improves the hardenability by adding a small amount. Of the B present in the steel, in order to ensure a sufficient amount of solid solution boron effective for improving hardenability, it is necessary to contain 0.0005% or more of B. However, since excessive B content becomes a factor which inhibits the toughness of steel, B content is restrict | limited to the range below 0.0050%.

下記(1)式で定義されるX値は、本発明の成分系において、固溶ボロン量が減少したことを前提とした場合の、表層部の焼入れ性を評価する指標である。
X値=5.5C1/2(1+0.6Si)(1+4.1Mn)(1+2.3Cr) …(1)
発明者らは詳細な検討の結果、このX値が17.00以上となる成分組成に調整したとき、通常の焼入れ処理を行って得られる焼入れ材において、表面硬さの低下が顕著に抑制できることを見出した。
The X value defined by the following formula (1) is an index for evaluating the hardenability of the surface layer part on the premise that the amount of dissolved boron is reduced in the component system of the present invention.
X value = 5.5C 1/2 (1 + 0.6Si) (1 + 4.1Mn) (1 + 2.3Cr) (1)
As a result of detailed studies, the inventors have been able to significantly suppress a decrease in surface hardness in a quenching material obtained by performing a normal quenching treatment when the X value is adjusted to a component composition of 17.00 or more. I found.

Nは、上記の固溶Bを十分に確保するためにできるだけ少ないことが望ましい。種々検討の結果、Nの混入は0.0080%まで許容される。   N is desirably as small as possible in order to sufficiently secure the above-mentioned solid solution B. As a result of various studies, N contamination is allowed up to 0.0008%.

下記(2)式で定義される炭素当量Ceqは、焼入れ後の溶接性を評価する指標である。
Ceq=C+Si/24+Mn/6+Cr/5 …(2)
種々検討を行った結果、このCeqが0.500を超えると焼入れ後の材料において溶接割れの発生が認められる場合がある。したがって、溶接に供する焼入れ部品用途においては、Ceqが0.500以下に調整された化学組成とすることが重要となる。
以上の化学組成に調整された本発明対象鋼は、通常の焼入れ処理によって350HV以上の表面硬さが得られるものである。
The carbon equivalent Ceq defined by the following formula (2) is an index for evaluating the weldability after quenching.
Ceq = C + Si / 24 + Mn / 6 + Cr / 5 (2)
As a result of various studies, when this Ceq exceeds 0.500, occurrence of weld cracks may be observed in the material after quenching. Therefore, in the use of quenched parts used for welding, it is important to have a chemical composition in which Ceq is adjusted to 0.500 or less.
The steel according to the present invention adjusted to the above chemical composition has a surface hardness of 350 HV or higher by a normal quenching process.

〔延性〕
本発明の圧延鋼板は、350HV以上の表面硬さが得られる優れた焼入れ性を有しているとともに、種々の焼入れ部品形状への加工に対応できる良好な延性を有しているという特長を有する。具体的には、一般的な延性の指標である全伸びT.Elが38.0%以上であり、且つ局所的な延性を評価しうる局部伸びElv(前述)が43.0%以上であるという特性を有する。これら2種類の延性指標を同時に高い値に維持することは必ずしも容易ではない。局部伸びElvはファインブランキング打抜き加工などにおける寸法精度に大きく影響する指標である。本出願人は焼入れ後の表面硬さと板厚中心部硬さの差が少ないボロン鋼鋼板を製造する技術を特願2009−063921号に開示した。しかし、表面硬さが350HVとなるような成分系のボロン鋼において、全伸びT.Elと局部伸びElvを上記のような高い値に維持した鋼板は実現されていなかった。T.Elが38.0%以上、且つElvが43.0%以上という延性を有する本発明のボロン鋼圧延鋼板は、従来の材料と比べ、ファインブランキング打抜き加工などに供した場合の寸法精度の向上をもたらすものである。T.ElとElvは、主として上述した化学組成の限定と、熱間圧延条件の限定によってコントロールすることができる。
[Ductility]
The rolled steel sheet of the present invention has excellent hardenability capable of obtaining a surface hardness of 350 HV or more, and has good ductility that can be applied to various hardened part shapes. . Specifically, the total elongation T.El, which is a general ductility index, is 38.0% or more, and the local elongation Elv (previously described) that can evaluate local ductility is 43.0% or more. It has the characteristic. It is not always easy to maintain these two types of ductility indices at a high value at the same time. The local elongation Elv is an index that greatly affects the dimensional accuracy in fine blanking punching and the like. The present applicant disclosed in Japanese Patent Application No. 2009-063921 a technique for producing a boron steel sheet having a small difference between the surface hardness after quenching and the center thickness hardness. However, in a component-based boron steel having a surface hardness of 350 HV, a steel sheet in which the total elongation T.El and the local elongation Elv are maintained at the above high values has not been realized. The boron steel rolled steel sheet of the present invention having a ductility of T.El of 38.0% or more and Elv of 43.0% or more is dimensional accuracy when subjected to fine blanking punching processing, etc., compared with conventional materials. It will bring about improvement. T.El and Elv can be controlled mainly by the above-described chemical composition limitation and hot rolling condition limitation.

本発明のボロン鋼圧延焼鈍鋼板は以下のような方法により製造することができる。
〔熱間圧延〕
熱延前のスラブ加熱温度は、一般的な炭素鋼と同様に1100〜1300℃とすればよい。仕上温度(熱延最終パスの温度)は800〜900℃とする。800℃を下回ると変形抵抗が大きくなり通板性が低下し、また後述の巻取温度を確保することが難しくなる。900℃を超えるとオーステナイト粒径が粗大化して熱延材の靱性が低下する。巻取温度は500〜650℃とする。500℃を下回ると熱延材が硬くなり製造性が低下する。650℃を上回ると初析フェライトの量が増加し、焼鈍後の炭化物の分布が不均一になることに加え、パーライトのラメラー間隔が大きくなるため焼鈍による炭化物の球状化が困難になり、焼鈍後の加工性が低下する。
The boron steel rolled annealed steel sheet of the present invention can be manufactured by the following method.
(Hot rolling)
The slab heating temperature before hot rolling may be set to 1100 to 1300 ° C. similarly to general carbon steel. The finishing temperature (temperature of the hot rolling final pass) is 800 to 900 ° C. If it is below 800 ° C., the deformation resistance is increased, the sheet passing property is lowered, and it is difficult to secure a winding temperature described later. When it exceeds 900 degreeC, an austenite particle size will coarsen and the toughness of a hot rolled material will fall. The winding temperature is 500 to 650 ° C. If it is below 500 ° C., the hot-rolled material becomes hard and the productivity is lowered. If the temperature exceeds 650 ° C, the amount of pro-eutectoid ferrite increases, the distribution of carbide after annealing becomes non-uniform, and the lamellar spacing of pearlite increases, making it difficult to spheroidize carbide by annealing, and after annealing The workability of is reduced.

これらの条件に加え、仕上圧延パス終了時点から巻取までの平均冷却速度を30〜45℃/secの範囲にコントロールすることが高い全伸びT.Elと局部伸びElvを両立させるうえで重要である。上記の平均冷却速度が30℃/sec未満では初析フェライト量が多くなりすぎ、後工程の焼鈍を行った後のセメンタイトの分布が不均一になる。それに起因してり、全伸びT.Elと局部伸びElvを前述のよう高い値に両立させることが難しくなる。一方、上記の平均冷却速度が45℃/secを超えると熱延材が硬くなり製造性が低下する。巻取後には通常の手法にて酸洗を行うことができる。   In addition to these conditions, it is important to control the average cooling rate from the end of the finishing rolling pass to the winding in the range of 30 to 45 ° C./sec in order to achieve both high total elongation T.El and local elongation Elv. is there. When the average cooling rate is less than 30 ° C./sec, the amount of pro-eutectoid ferrite becomes too large, and the distribution of cementite after post-annealing becomes uneven. As a result, it becomes difficult to make the total elongation T.El and the local elongation Elv compatible with high values as described above. On the other hand, when the average cooling rate exceeds 45 ° C./sec, the hot-rolled material becomes hard and the productivity is lowered. After winding, pickling can be performed by a normal method.

〔冷間圧延〕
上記の条件で得られた熱延板に対して、必要に応じて冷間圧延を施して板厚を調整することができる。冷間圧延率は60%以下の範囲とすることが望ましい。それより冷間圧延率が高くなるとコスト高となる。冷間圧延率の下限は特に制限されないが、良好な板厚精度を得ることを重視する場合は20%以上の冷間圧延率を確保することが有利となる。
(Cold rolling)
The hot-rolled sheet obtained under the above conditions can be cold-rolled as necessary to adjust the sheet thickness. It is desirable that the cold rolling rate be in the range of 60% or less. If the cold rolling rate becomes higher than that, the cost increases. Although the lower limit of the cold rolling rate is not particularly limited, it is advantageous to secure a cold rolling rate of 20% or more when emphasizing obtaining good sheet thickness accuracy.

〔焼鈍〕
熱間圧延を終え、必要に応じて冷間圧延が施された圧延鋼板は、焼鈍に供される。
焼鈍は、(a)前工程で得られた鋼板を(A1−30℃)以上A1未満の温度範囲で0.5h以上均熱保持したのち、(b)A1以上(A1+50℃)の温度範囲で0.5〜20h均熱保持し、(c)その保持温度から少なくとも(A1−10℃)までを冷却速度5〜30℃/hで徐冷するヒートパターンを採用することができる。
[Annealing]
The rolled steel sheet that has been hot-rolled and cold-rolled as necessary is subjected to annealing.
In annealing, (a) the steel plate obtained in the previous step was soaked for 0.5 h or more in a temperature range of (A 1 -30 ° C.) or more and less than A 1 , and then (b) A 1 or more (A 1 + 50 ° C. ) In a temperature range of 0.5 to 20 h, and (c) adopt a heat pattern in which the temperature is gradually cooled from the holding temperature to at least (A 1 -10 ° C.) at a cooling rate of 5 to 30 ° C./h. Can do.

ここで、A1は、A1変態点にほぼ対応する温度(℃)であり、本発明の対象鋼種においては上記の(3)式により定まる値によって熱処理条件を管理することができる。 Here, A 1 is a temperature (° C.) substantially corresponding to the A 1 transformation point, and in the target steel type of the present invention, the heat treatment condition can be managed by the value determined by the above equation (3).

(a)の加熱保持は概ね24h以下とすればよい。(b)の工程は省略しても構わない。ただし、(a)のあとに(b)の加熱を行って微細な炭化物を溶解させると共に炭化物の一部を残存させ、その後(c)の徐冷過程で上記の残存した炭化物を核として炭化物を成長させることにより、球状かつ粗大な炭化物形態を得ることがより容易となる。(c)の徐冷は、変態が完了するまで実施することが望ましい。このため少なくとも(A1−10℃)までを上記所定の冷却速度に維持した徐冷とする。徐冷を終了する温度は、工業的には(A1−10℃)から(A1−80℃)までの間で設定すればよい。その後の冷却速度は任意に設定して構わない。(b)の加熱を省略する場合は(a)の保持温度から直接冷却することになるが、この場合の冷却速度は特に管理する必要はない。 The heating and holding in (a) may be approximately 24 h or less. The step (b) may be omitted. However, heating of (b) is performed after (a) to dissolve fine carbides and part of the carbides remain, and then the carbides are formed using the remaining carbides as a nucleus in the slow cooling process of (c). By making it grow, it becomes easier to obtain a spherical and coarse carbide form. It is desirable to carry out the slow cooling of (c) until the transformation is completed. For this reason, at least (A 1 −10 ° C.) is gradually cooled while maintaining the predetermined cooling rate. Temperature to end the slow cooling, for industrial may be set between the up from (A 1 -10 ℃) (A 1 -80 ℃). The subsequent cooling rate may be set arbitrarily. When the heating in (b) is omitted, the cooling is performed directly from the holding temperature in (a), but the cooling rate in this case does not need to be particularly managed.

このようにして得られる焼鈍鋼板の金属組織は、粗大な球状炭化物組織であるが、球状炭化物の分散が均一化されており、かつ通常の焼鈍材に比べ軟質となっている。すなわち、この焼鈍工程により、自動車部品をはじめとする各種機械部品の用途に好適な、優れた加工性を有する圧延焼鈍鋼板が得られる。
なお、この熱処理に供する前には、前述の熱延段階で適切な組織コントロールが行われている必要がある。
The metal structure of the annealed steel sheet thus obtained is a coarse spherical carbide structure, but the dispersion of the spherical carbide is made uniform and softer than a normal annealed material. That is, by this annealing process, a rolled annealed steel sheet having excellent workability suitable for various machine parts including automobile parts can be obtained.
In addition, before using for this heat processing, appropriate structure | tissue control needs to be performed at the above-mentioned hot rolling stage.

以上のようにして本発明のボロン鋼圧延焼鈍鋼板が得られる。
〔加工、焼入れ〕
上記のようにして得られた本発明の鋼板は、所定の機械部品に加工され、その後、焼入れ処理に供される。部品への加工に際しては良好な加工性を活かして、従来よりも厳しい加工条件を設定することも可能となりうる。焼入れ後には通常、焼戻し処理が行われる。このような調質熱処理を経た部品は、さらに必要に応じて溶接加工に供される。
As described above, the boron steel rolled annealed steel sheet of the present invention is obtained.
[Processing and quenching]
The steel plate of the present invention obtained as described above is processed into a predetermined machine part and then subjected to a quenching process. When processing parts, it is possible to set stricter processing conditions than before by utilizing good processability. A tempering process is usually performed after quenching. The parts that have undergone such tempering heat treatment are further subjected to welding as necessary.

表1に示す組成の鋼を溶製し、本発明で規定する条件で熱間圧延を施し、酸洗し、厚さ6mmの熱延板とした。熱間圧延条件は、加熱温度1150〜1270℃、仕上温度815〜880℃、巻取温度550〜610℃、仕上温度から巻取温度までの平均冷却速度33〜39℃/secの範囲であった。得られた酸洗済みの熱延板に対して、本発明で規定を満たす下記(A)のヒートパターンにて焼鈍を施して供試材とした。
(A)715℃で均熱保持20h→760℃で均熱保持10h→650℃まで10℃/hで冷却→炉冷
Steel having the composition shown in Table 1 was melted, hot-rolled under the conditions specified in the present invention, pickled, and a hot-rolled sheet having a thickness of 6 mm was obtained. The hot rolling conditions were a heating temperature of 1150 to 1270 ° C, a finishing temperature of 815 to 880 ° C, a winding temperature of 550 to 610 ° C, and an average cooling rate from the finishing temperature to the winding temperature of 33 to 39 ° C / sec. . The pickled hot-rolled sheet obtained was annealed with a heat pattern of the following (A) that satisfies the regulations of the present invention to obtain a test material.
(A) Soaking soak at 715 ° C. 20h → Soaking soaking at 760 ° C. 10h → Cooling to 650 ° C. at 10 ° C./h→Cooling furnace

Figure 0005601861
Figure 0005601861

焼鈍後の供試材を用いて以下の試験を行った。
〔加工性評価〕
加工性の指標として、全伸びT.Elと局部伸びElvの2つを求めた。局部伸びElvの値が大きい材料ほど、ファインブランキング打抜き加工に好適な材料と考えてよい。
全伸びT.Elは、圧延方向のJIS5号試験片を用いて引張試験を行うことによって求めた。標点距離は50mmとした。
局部伸びElvは、前述のように圧延方向のJIS5号試験片に2mmのVノッチを平行部中央の両エッジに形成した切り欠き引張試験片を用いて引張試験を行うことにより求めた。この場合の標点距離は10mmである。
全伸びT.Elは38.0%以上を合格、局部伸びElvは43.0%以上を合格と判定した。
The following tests were performed using the specimens after annealing.
[Processability evaluation]
Two indices, total elongation T.El and local elongation Elv, were obtained as indices of workability. A material having a larger value of the local elongation Elv may be considered as a material suitable for fine blanking punching.
The total elongation T.E1 was obtained by conducting a tensile test using a JIS No. 5 test piece in the rolling direction. The gauge distance was 50 mm.
The local elongation Elv was determined by conducting a tensile test using notched tensile test pieces in which 2 mm V-notches were formed on both edges at the center of the parallel part on a JIS No. 5 test piece in the rolling direction as described above. In this case, the gauge distance is 10 mm.
The total elongation T.El was determined to be 38.0% or more, and the local elongation Elv was determined to be 43.0% or more.

〔焼入れ後の硬さ評価〕
各供試材について900℃で15min均熱後、油浴中に焼き入れる焼入れ処理を施した。焼入れ材の表面硬さおよび板厚中心部の断面硬さをビッカース硬度計により荷重10kgにて測定した。表面硬さが350HV以上のものを焼入れ性良好と判定した。
[Evaluation of hardness after quenching]
Each specimen was soaked at 900 ° C. for 15 minutes and then quenched in an oil bath. The surface hardness of the quenched material and the cross-sectional hardness at the center of the plate thickness were measured with a Vickers hardness meter at a load of 10 kg. Those having a surface hardness of 350 HV or higher were judged to have good hardenability.

〔溶接性〕
上記焼入れ材について、JIS Z3158−1993に規定されるy形溶接割れ試験を実施した。溶接条件は、y形の試験片形状とし、電流:150A、電圧:20V、速度:20cm/minとした。溶接割れの検出は10倍のルーペを用い、割れ発生の有無により良否判定を行った。
これらの結果を表2に示す。
(Weldability)
About the said hardening material, the y-type weld crack test prescribed | regulated to JISZ3158-1993 was implemented. The welding conditions were a y-shaped test piece, current: 150 A, voltage: 20 V, and speed: 20 cm / min. Weld cracks were detected using a 10-fold magnifier, and the quality was determined by the presence or absence of cracks.
These results are shown in Table 2.

Figure 0005601861
Figure 0005601861

本発明例のものはいずれも、T.El:38.0%以上、局部伸びElv:43.0%以上の優れた加工性を呈し、焼入れ後には350HV以上の表面硬さが得られ、溶接性も良好であった。   All of the examples of the present invention exhibit excellent workability of T.El: 38.0% or more and local elongation Elv: 43.0% or more, and surface hardness of 350 HV or more is obtained after quenching. The property was also good.

これに対し、No.1はC量が少ないため焼入れ後の表面硬さが350HVを満足しない。No.3およびNo.8はMn、Cr量が比較的少ないためX値の規定を満足できず焼入れ後の表面硬さに劣った。No.6はCr量が高すぎたことにより局部伸びElvが低かった。No.9は炭素当量Ceqが高すぎるものであり、加工性(T.El、Elv)が悪く、溶接割れも発生した。No.11はMn量が本発明の範囲を超えるため加工性(T.El、Elv)に劣った。No.16およびNo.19は炭素当量Ceqが高いために溶接割れが発生した。No.21はC量が高いため加工性(T.El、Elv)が悪く、さらにX値の規定を満たさないため焼入れ後の表面硬さも低かった。No.22はMn量が高いため全伸びT.Elが低かった。   On the other hand, since No. 1 has a small amount of C, the surface hardness after quenching does not satisfy 350 HV. No. 3 and No. 8 were inferior in surface hardness after quenching because the amounts of Mn and Cr were relatively small and the X value was not satisfied. In No. 6, the local elongation Elv was low because the amount of Cr was too high. No. 9 has a carbon equivalent Ceq that is too high, the workability (T.El, Elv) is poor, and weld cracks also occur. No. 11 was inferior in workability (T.El, Elv) because the amount of Mn exceeded the range of the present invention. Since No. 16 and No. 19 had high carbon equivalent Ceq, weld cracks occurred. Since No. 21 had a high C content, workability (T.El, Elv) was poor, and further, the surface hardness after quenching was low because it did not satisfy the definition of the X value. In No. 22, the total elongation T.E1 was low because of the high Mn content.

表1のNo.12鋼を用いて、熱延、冷延、焼鈍条件による影響を調べた結果を例示する。熱延の仕上温度、巻取温度、仕上圧延パス終了時点から巻取までの平均冷却速度を種々変えて熱延を行い、その後、酸洗し、一部のものについては冷間圧延を行い、焼鈍を行い、板厚6.0mmの供試材を作製した。焼鈍条件は実施例1と同じ(A)の条件、または下記(B)の条件を採用した。焼鈍後の供試材について実施例1と同様の手法でT.El、Elvを求めた。
(A)715℃で均熱保持20h→760℃で均熱保持10h→650℃まで10℃/hで冷却→炉冷
(B)710℃で均熱保持20h→650℃まで10℃/hで冷却→炉冷
結果を表3に示す。
The result of having investigated the influence by hot rolling, cold rolling, and annealing conditions using No. 12 steel of Table 1 is illustrated. Hot rolling finish temperature, coiling temperature, hot rolling with various changes in the average cooling rate from the end of the finishing rolling pass to winding, and then pickling, and some parts are cold rolled, Annealing was performed to prepare a specimen having a thickness of 6.0 mm. As the annealing conditions, the same conditions (A) as in Example 1 or the following conditions (B) were adopted. T.El and Elv were determined for the test material after annealing by the same method as in Example 1.
(A) Soaking soak at 715 ° C. 20 h → Soaking soak at 760 ° C. 10 h → Cooling at 10 ° C./h until 650 ° C. → Bool cooling (B) Soaking soak at 710 ° C. 20 h → 10 ° C./h until 650 ° C. Cooling → furnace cooling Table 3 shows the results.

Figure 0005601861
Figure 0005601861

本発明例のものはいずれも良好な加工性(T.El、Elv)を呈した。
これに対し、試験No.(3)は仕上温度、巻取温度は本発明の範囲内であるが、仕上圧延パス終了時点から巻取までの平均冷却速度が小さいことに起因して焼鈍後の炭化物の分布が不均一で球状化率が低くなり、その結果、加工性に劣った。試験No.(7)は巻取温度が本発明の範囲より高いことに起因して焼鈍後の炭化物の分布が不均一で球状化率が低くなり、その結果、加工性に劣った。
All of the inventive examples exhibited good processability (T.El, Elv).
On the other hand, although test No. (3) has a finishing temperature and a coiling temperature within the scope of the present invention, the average cooling rate from the end of the finishing rolling pass to the coiling is small, so that after annealing. The distribution of carbides was uneven and the spheroidization rate was low, resulting in poor processability. In Test No. (7), the coiling temperature was higher than the range of the present invention, so the distribution of carbides after annealing was non-uniform and the spheroidization rate was low, resulting in poor workability.

Claims (4)

質量%で、C:0.15〜0.35%、Si:0.50%以下、Mn:0.20〜1.00%、P:0.030%以下、S:0.020%以下、Cr:0.20〜1.00%、Al:0.005〜0.200%、Ti:0.01〜0.20%、B:0.0005〜0.0050%、N:0.0080%以下、残部Feおよび不可避的不純物、下記(1)式により定まるX値が17.00以上、下記(2)式により定まる炭素当量Ceqが0.500以下である化学組成を有するスラブに対して、スラブ加熱温度:1100〜1300℃、仕上温度:800〜900℃、仕上圧延パス終了時点から巻取までの平均冷却速度:30〜45℃/sec、巻取温度:500〜650℃の条件で熱間圧延を行う工程、
熱延板に対して、(A1−30℃)以上A1未満のオーステナイト相未生成温度域で0.5h以上均熱保持し、昇温してA1以上(A1+50℃)以下のオーステナイト相生成温度域で0.5〜20h均熱保持し、その後、前記保持温度から少なくとも(A1−10℃)までを冷却速度5〜30℃/hで徐冷するヒートパターンで焼鈍を施す工程、
を有する、圧延方向の全伸びT.Elが38.0%以上、圧延方向JIS5号引張試験片の平行部中央の両エッジに2mmVノッチを形成した切欠き引張試験片を用いた標点距離10mmの引張試験による局部伸びElvが43.0%以上であるボロン鋼圧延焼鈍鋼板の製造法。
ただし、上記A1は下記(3)式により定まる値を採用する。
X値=5.5C1/2(1+0.6Si)(1+4.1Mn)(1+2.3Cr) …(1)
Ceq=C+Si/24+Mn/6+Cr/5 …(2)
1(℃)=723+29.1Si−10.7Mn+16.9Cr…(3)
In mass%, C: 0.15 to 0.35%, Si: 0.50% or less, Mn: 0.20 to 1.00%, P: 0.030% or less, S: 0.020% or less, Cr: 0.20 to 1.00%, Al: 0.005 to 0.200%, Ti: 0.01 to 0.20%, B: 0.0005 to 0.0050%, N: 0.0080% Hereinafter, with respect to the slab having a chemical composition in which the balance Fe and inevitable impurities, the X value determined by the following formula (1) is 17.00 or more, and the carbon equivalent Ceq determined by the following formula (2) is 0.500 or less. Slab heating temperature: 1100 to 1300 ° C., finishing temperature: 800 to 900 ° C., average cooling rate from the end of finishing rolling pass to winding: 30 to 45 ° C./sec, winding temperature: 500 to 650 ° C. A step of performing rolling,
With respect to the hot-rolled sheet, (A 1 -30 ° C.) or more and less than A 1 in the austenite phase non-generated temperature range, hold for 0.5 h or more, raise the temperature, and A 1 or more (A 1 + 50 ° C.) or less. Annealing is performed in a heat pattern in which the temperature is maintained for 0.5 to 20 hours in the austenite phase generation temperature range, and then gradually cooled from the holding temperature to at least (A 1 -10 ° C.) at a cooling rate of 5 to 30 ° C./h. Process,
The total distance T.E1 in the rolling direction is 38.0% or more, and the mark distance is 10 mm using notched tensile test pieces in which 2 mm V notches are formed at both edges in the center of the parallel part of the rolling direction JIS No. 5 tensile test piece. A method for producing a boron steel rolled annealed steel sheet having a local elongation Elv of 43.0% or more according to a tensile test.
However, the value determined by the following equation (3) is adopted as A 1 .
X value = 5.5C 1/2 (1 + 0.6Si) (1 + 4.1Mn) (1 + 2.3Cr) (1)
Ceq = C + Si / 24 + Mn / 6 + Cr / 5 (2)
A 1 (° C.) = 723 + 29.1 Si−10.7 Mn + 16.9 Cr (3)
質量%で、C:0.15〜0.35%、Si:0.50%以下、Mn:0.20〜1.00%、P:0.030%以下、S:0.020%以下、Cr:0.20〜1.00%、Al:0.005〜0.200%、Ti:0.01〜0.20%、B:0.0005〜0.0050%、N:0.0080%以下、残部Feおよび不可避的不純物、下記(1)式により定まるX値が17.00以上、下記(2)式により定まる炭素当量Ceqが0.500以下である化学組成を有するスラブに対して、スラブ加熱温度:1100〜1300℃、仕上温度:800〜900℃、仕上圧延パス終了時点から巻取までの平均冷却速度:30〜45℃/sec、巻取温度:500〜650℃の条件で熱間圧延を行う工程、
熱延板に対して、圧延率60%以下の冷間圧延を施す工程、
冷延板に対して、(A1−30℃)以上A1未満のオーステナイト相未生成温度域で0.5h以上均熱保持し、昇温してA1以上(A1+50℃)以下のオーステナイト相生成温度域で0.5〜20h均熱保持し、その後、前記保持温度から少なくとも(A1−10℃)までを冷却速度5〜30℃/hで徐冷するヒートパターンで焼鈍を施す工程、
を有する、圧延方向の全伸びT.Elが38.0%以上、圧延方向JIS5号引張試験片の平行部中央の両エッジに2mmVノッチを形成した切欠き引張試験片を用いた標点距離10mmの引張試験による局部伸びElvが43.0%以上であるボロン鋼圧延焼鈍鋼板の製造法。
ただし、上記A1は下記(3)式により定まる値を採用する。
X値=5.5C1/2(1+0.6Si)(1+4.1Mn)(1+2.3Cr) …(1)
Ceq=C+Si/24+Mn/6+Cr/5 …(2)
1(℃)=723+29.1Si−10.7Mn+16.9Cr…(3)
In mass%, C: 0.15 to 0.35%, Si: 0.50% or less, Mn: 0.20 to 1.00%, P: 0.030% or less, S: 0.020% or less, Cr: 0.20 to 1.00%, Al: 0.005 to 0.200%, Ti: 0.01 to 0.20%, B: 0.0005 to 0.0050%, N: 0.0080% Hereinafter, with respect to the slab having a chemical composition in which the balance Fe and inevitable impurities, the X value determined by the following formula (1) is 17.00 or more, and the carbon equivalent Ceq determined by the following formula (2) is 0.500 or less. Slab heating temperature: 1100 to 1300 ° C., finishing temperature: 800 to 900 ° C., average cooling rate from the end of finishing rolling pass to winding: 30 to 45 ° C./sec, winding temperature: 500 to 650 ° C. A step of performing rolling,
A step of subjecting the hot-rolled sheet to cold rolling at a rolling rate of 60% or less,
Keeping soaked for 0.5 h or more in the austenite phase non-generated temperature range of (A 1 -30 ° C.) or more and less than A 1 with respect to the cold-rolled sheet, raising the temperature to A 1 or more (A 1 + 50 ° C.) or less. Annealing is performed in a heat pattern in which the temperature is maintained for 0.5 to 20 hours in the austenite phase generation temperature range, and then gradually cooled from the holding temperature to at least (A 1 -10 ° C.) at a cooling rate of 5 to 30 ° C./h. Process,
The total distance T.E1 in the rolling direction is 38.0% or more, and the mark distance is 10 mm using notched tensile test pieces in which 2 mm V notches are formed at both edges in the center of the parallel part of the rolling direction JIS No. 5 tensile test piece. A method for producing a boron steel rolled annealed steel sheet having a local elongation Elv of 43.0% or more according to a tensile test.
However, the value determined by the following equation (3) is adopted as A 1 .
X value = 5.5C 1/2 (1 + 0.6Si) (1 + 4.1Mn) (1 + 2.3Cr) (1)
Ceq = C + Si / 24 + Mn / 6 + Cr / 5 (2)
A 1 (° C.) = 723 + 29.1 Si−10.7 Mn + 16.9 Cr (3)
質量%で、C:0.15〜0.35%、Si:0.50%以下、Mn:0.20〜1.00%、P:0.030%以下、S:0.020%以下、Cr:0.20〜1.00%、Al:0.005〜0.200%、Ti:0.01〜0.20%、B:0.0005〜0.0050%、N:0.0080%以下、残部Feおよび不可避的不純物、下記(1)式により定まるX値が17.00以上、下記(2)式により定まる炭素当量Ceqが0.500以下である化学組成を有するスラブに対して、スラブ加熱温度:1100〜1300℃、仕上温度:800〜900℃、仕上圧延パス終了時点から巻取までの平均冷却速度:30〜45℃/sec、巻取温度:500〜650℃の条件で熱間圧延を行う工程、
熱延板に対して、(A1−30℃)以上A1未満のオーステナイト相未生成温度域で0.5h以上均熱保持した後、冷却するヒートパターンで焼鈍を施す工程、
を有する、圧延方向の全伸びT.Elが38.0%以上、圧延方向JIS5号引張試験片の平行部中央の両エッジに2mmVノッチを形成した切欠き引張試験片を用いた標点距離10mmの引張試験による局部伸びElvが43.0%以上であるボロン鋼圧延焼鈍鋼板の製造法。
ただし、上記A1は下記(3)式により定まる値を採用する。
X値=5.5C1/2(1+0.6Si)(1+4.1Mn)(1+2.3Cr) …(1)
Ceq=C+Si/24+Mn/6+Cr/5 …(2)
1(℃)=723+29.1Si−10.7Mn+16.9Cr…(3)
In mass%, C: 0.15 to 0.35%, Si: 0.50% or less, Mn: 0.20 to 1.00%, P: 0.030% or less, S: 0.020% or less, Cr: 0.20 to 1.00%, Al: 0.005 to 0.200%, Ti: 0.01 to 0.20%, B: 0.0005 to 0.0050%, N: 0.0080% Hereinafter, with respect to the slab having a chemical composition in which the balance Fe and inevitable impurities, the X value determined by the following formula (1) is 17.00 or more, and the carbon equivalent Ceq determined by the following formula (2) is 0.500 or less. Slab heating temperature: 1100 to 1300 ° C., finishing temperature: 800 to 900 ° C., average cooling rate from the end of finishing rolling pass to winding: 30 to 45 ° C./sec, winding temperature: 500 to 650 ° C. A step of performing rolling,
A process of annealing with a heat pattern to cool after holding soaking for 0.5 h or more in an austenite phase non-generated temperature range of (A 1 -30 ° C.) or more and less than A 1 with respect to the hot rolled sheet,
The total distance T.E1 in the rolling direction is 38.0% or more, and the mark distance is 10 mm using notched tensile test pieces in which 2 mm V notches are formed at both edges in the center of the parallel part of the rolling direction JIS No. 5 tensile test piece. A method for producing a boron steel rolled annealed steel sheet having a local elongation Elv of 43.0% or more according to a tensile test.
However, the value determined by the following equation (3) is adopted as A 1 .
X value = 5.5C 1/2 (1 + 0.6Si) (1 + 4.1Mn) (1 + 2.3Cr) (1)
Ceq = C + Si / 24 + Mn / 6 + Cr / 5 (2)
A 1 (° C.) = 723 + 29.1 Si−10.7 Mn + 16.9 Cr (3)
質量%で、C:0.15〜0.35%、Si:0.50%以下、Mn:0.20〜1.00%、P:0.030%以下、S:0.020%以下、Cr:0.20〜1.00%、Al:0.005〜0.200%、Ti:0.01〜0.20%、B:0.0005〜0.0050%、N:0.0080%以下、残部Feおよび不可避的不純物、下記(1)式により定まるX値が17.00以上、下記(2)式により定まる炭素当量Ceqが0.500以下である化学組成を有するスラブに対して、スラブ加熱温度:1100〜1300℃、仕上温度:800〜900℃、仕上圧延パス終了時点から巻取までの平均冷却速度:30〜45℃/sec、巻取温度:500〜650℃の条件で熱間圧延を行う工程、
熱延板に対して、圧延率60%以下の冷間圧延を施す工程、
冷延板に対して、(A1−30℃)以上A1未満のオーステナイト相未生成温度域で0.5h以上均熱保持した後、冷却するヒートパターンで焼鈍を施す工程、
を有する、圧延方向の全伸びT.Elが38.0%以上、圧延方向JIS5号引張試験片の平行部中央の両エッジに2mmVノッチを形成した切欠き引張試験片を用いた標点距離10mmの引張試験による局部伸びElvが43.0%以上であるボロン鋼圧延焼鈍鋼板の製造法。
ただし、上記A1は下記(3)式により定まる値を採用する。
X値=5.5C1/2(1+0.6Si)(1+4.1Mn)(1+2.3Cr) …(1)
Ceq=C+Si/24+Mn/6+Cr/5 …(2)
1(℃)=723+29.1Si−10.7Mn+16.9Cr…(3)
In mass%, C: 0.15 to 0.35%, Si: 0.50% or less, Mn: 0.20 to 1.00%, P: 0.030% or less, S: 0.020% or less, Cr: 0.20 to 1.00%, Al: 0.005 to 0.200%, Ti: 0.01 to 0.20%, B: 0.0005 to 0.0050%, N: 0.0080% Hereinafter, with respect to the slab having a chemical composition in which the balance Fe and inevitable impurities, the X value determined by the following formula (1) is 17.00 or more, and the carbon equivalent Ceq determined by the following formula (2) is 0.500 or less. Slab heating temperature: 1100 to 1300 ° C., finishing temperature: 800 to 900 ° C., average cooling rate from the end of finishing rolling pass to winding: 30 to 45 ° C./sec, winding temperature: 500 to 650 ° C. A step of performing rolling,
A step of subjecting the hot-rolled sheet to cold rolling at a rolling rate of 60% or less,
A step of annealing the cold-rolled sheet with a heat pattern to cool after holding for 0.5 h or more in an austenite phase non-generated temperature range of (A 1 -30 ° C.) or more and less than A 1 ,
The total distance T.E1 in the rolling direction is 38.0% or more, and the mark distance is 10 mm using notched tensile test pieces in which 2 mm V notches are formed at both edges in the center of the parallel part of the rolling direction JIS No. 5 tensile test piece. A method for producing a boron steel rolled annealed steel sheet having a local elongation Elv of 43.0% or more according to a tensile test.
However, the value determined by the following equation (3) is adopted as A 1 .
X value = 5.5C 1/2 (1 + 0.6Si) (1 + 4.1Mn) (1 + 2.3Cr) (1)
Ceq = C + Si / 24 + Mn / 6 + Cr / 5 (2)
A 1 (° C.) = 723 + 29.1 Si−10.7 Mn + 16.9 Cr (3)
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