JP5565928B2 - Cosmetic composition for spray and makeup method to correct facial expression into youthful physical shape - Google Patents
Cosmetic composition for spray and makeup method to correct facial expression into youthful physical shape Download PDFInfo
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- JP5565928B2 JP5565928B2 JP2009166324A JP2009166324A JP5565928B2 JP 5565928 B2 JP5565928 B2 JP 5565928B2 JP 2009166324 A JP2009166324 A JP 2009166324A JP 2009166324 A JP2009166324 A JP 2009166324A JP 5565928 B2 JP5565928 B2 JP 5565928B2
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- cosmetic composition
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Landscapes
- Cosmetics (AREA)
Description
本発明は、顔全体を引き締めて皮膚のたるみや顔の輪郭の緩みを物理的に収縮させて、長時間(約6時間〜8時間)表情を若々しい物理的な形状に補正することが出来るスプレー用化粧組成物とこれを利用したメイクアップ方法に関する。 According to the present invention, the entire face is tightened to physically contract the slack of the skin and the looseness of the outline of the face, thereby correcting the expression for a long time (about 6 to 8 hours) into a youthful physical shape. The present invention relates to a cosmetic composition for spraying and a makeup method using the composition.
従来より、メイクアップ方法あるいはメイクアップに使用する化粧組成物には、皮膚のたるみや顔の輪郭の緩みを目立たなくして若々しい表情を作る技術が求められていた。 Conventionally, a makeup method or a cosmetic composition used for makeup has been required to have a technique for making a youthful expression without making the sagging skin or looseness of the facial contours inconspicuous.
従来のメイクアップ技術には、ファンデーションの色調の変化で顔に陰影を付けることにより、シミやそばかす等の皮膚に生じる色調トラブルを見えなくする特許文献1のメイクアップ方法(特開平9−208428号)がある。一方、従来のメイクアップ技術には、粘土鉱物とマンネンタケ抽出物を含有する複合粉体を顔に使用し、真皮構成成分であるコラーゲン等の生成を促進することにより、たるみ等の原因となるコラーゲンの減少を防止する特許文献2のメイクアップ化粧料(特開2005−89303号)がある。 The conventional makeup technique includes a makeup method disclosed in Japanese Patent Application Laid-Open No. Hei 9-208428, in which color tone troubles occurring on the skin such as spots and freckles are made invisible by shading the face with a change in the color tone of the foundation. ) On the other hand, the conventional makeup technology uses a composite powder containing clay mineral and Mannentake extract on the face, and promotes the production of collagen, etc., which is a constituent component of the dermis, thereby causing collagen such as sagging There is a makeup cosmetic (Japanese Patent Application Laid-Open No. 2005-89303) disclosed in Patent Document 2 that prevents the decrease of the above.
しかし、特許文献1のメイクアップ方法は、視覚的な錯覚を利用することによってシミ、そばかすなどの皮膚に生じる色調トラブルを見えないようにすることが出来るものの、皮膚形状を物理的に変化させるものではない。従って、加齢によって生じた皮膚のたるみ等、皮膚に発生した比較的大きな形状変化を物理的に元に戻すような補正が出来ない点で問題があった。また、顔の造りや印象は、人によって異なるため、特許文献1に示す従来のメイクアップ方法は、熟練した知識と化粧技術が必要であり、誰もが簡便に利用できないという点で問題があった。 However, the make-up method of Patent Document 1 can make the skin shape physically change by using a visual illusion, although it can hide color troubles occurring on the skin such as spots and freckles. is not. Therefore, there has been a problem in that it is not possible to perform correction to physically restore a relatively large shape change generated in the skin, such as sagging skin caused by aging. In addition, since the structure and impression of the face vary from person to person, the conventional makeup method shown in Patent Document 1 requires skilled knowledge and makeup techniques, and there is a problem in that no one can use it easily. It was.
一方、メイクアップ技術における従来の「引き締め」は、従来より収斂剤などの化学成分の薬効を訴求するものが主流である。従って、特許文献2のメイクアップ化粧料は、複合粉体の薬効成分によって、加齢によって生じる皮膚のたるみ等の発生を未然に防止する点では有効と言える。しかし、特許文献2のメイクアップ化粧料は、皮膚のたるみなどを発生させない、即ち肌の老化防止的なものであって、実際に発生したたるみを物理的に補正するものではなかった。即ち、加齢によって生じる皮膚のたるみや顔の輪郭の緩み、あるいは皮膚のたるみを伴って現れる比較的大きなシワ等に代表される物理的な皮膚の形状変化が実際に発生してしまった場合には、変化前の皮膚形状に物理的に戻すという補正が出来ないという点で問題があった。 On the other hand, the conventional “tightening” in the makeup technology has mainly been used to appeal for the efficacy of chemical components such as astringents. Therefore, it can be said that the makeup cosmetic of Patent Document 2 is effective in preventing the occurrence of sagging of the skin caused by aging by the medicinal component of the composite powder. However, the makeup cosmetic of Patent Document 2 does not cause sagging of the skin, that is, prevents skin aging, and does not physically correct the sagging actually generated. In other words, when physical changes in the shape of the skin such as sagging of the skin and facial contours caused by aging, or relatively large wrinkles that appear with sagging of the skin, have actually occurred. However, there is a problem in that it cannot be corrected to physically return to the skin shape before the change.
本願発明は、上記問題に鑑み、物理的な収縮力により、顔に生じた皮膚のたるみや輪郭の緩みを物理的に収縮変化させてたるみ前の状態に補正し、かつその状態を長時間(約6時間〜8時間)持続させることができる組成物であって、スプレーに使用しても目詰まりが無い、スプレー用化粧組成物を提供すると共に、この化粧組成物をスプレーを介して利用することにより、誰もが容易に若々しい表情を長時間演出することが出来るメイクアップ方法を提供するものである。 In view of the above problems, the present invention corrects the sagging of the skin and the looseness of the contour caused on the face by physical contraction force to the state before sagging by physically contracting, and the state is corrected for a long time ( Provided is a cosmetic composition for spraying that can be sustained for about 6 hours to 8 hours and is not clogged when used in a spray, and the cosmetic composition is utilized via a spray Therefore, it is an object of the present invention to provide a makeup method in which anyone can easily produce a youthful facial expression for a long time.
請求項1のスプレー用化粧組成物においては、天然高分子であるガゼインNaをスプレー用化粧組成物全体に対して0.5〜3.0質量%含有し、前記スプレー用化粧組成物全体に対して水膨潤性無機高分子であるヘクトライト及びシリカを合計で0.5〜3.5質量%含有するスプレー用化粧組成物であって、ポリエーテル変性シリコンを前記スプレー用化粧組成物全体に対して0.5〜3.0質量%含有することにした。 In the cosmetic composition for spray of Claim 1, 0.5-3.0 mass% of casein Na which is a natural polymer is contained with respect to the whole cosmetic composition for spray, and with respect to the whole cosmetic composition for spray. Te a spray cosmetic composition containing 0.5 to 3.5 mass% of hectorite and silica in total a water-swellable inorganic polymer, a polyether-modified silicone to total said spray cosmetic composition And 0.5 to 3.0% by mass.
尚、請求項1のスプレー用化粧組成物においては、組成物全体に対する天然高分子であるガゼインNaの含有量が0.5質量%未満の場合、皮膜が弱くなり、たるみなど引き締め効果が期待できず、3.0質量%を超える場合、スプレー噴射口が目詰りを起こして使用できなくなる。一方、組成物全体に対する水膨潤性無機高分子であるヘクトライト及びシリカの合計含有量は、0.5質量%未満の場合、皮膜に収縮力が弱くなって皮膚を補正する固着力が弱くなり、3.5質量%を超える場合、スプレー噴射口が目詰りを起こして使用できなくなる。また、組成物全体に対するポリエーテル変性シリコンの含有量は、0.5質量%未満の場合、皮膜に柔軟性が不足し、持続力がなく途中で破断することに加え、スプレー噴射口に目詰りが発生する。また、3.0質量%を超える場合、柔軟性があるものの固着皮膜の収縮力が弱くなるため、たるみなどの引き締め効果が極めて低くなる。
請求項2のスプレー用化粧組成物は、天然高分子であるガゼインNaをスプレー用化粧組成物全体に対して1.5〜3.0質量%含有し、前記スプレー用化粧組成物全体に対して水膨潤性無機高分子であるヘクトライト及びシリカを合計で1.0〜3.0質量%含有し、前記ポリエーテル変性シリコンを前記スプレー用化粧組成物全体に対して0.5〜1.0質量%含有し、請求項3のスプレー用化粧組成物は、1.3BG(ブチレングリコール)を前記スプレー用化粧組成物全体に対して1.0質量%含有する。
In the cosmetic composition for spray according to claim 1, when the content of gazein Na , which is a natural polymer based on the whole composition, is less than 0.5% by mass, the film becomes weak and a tightening effect such as sagging can be expected. If it exceeds 3.0% by mass, the spray nozzle is clogged and cannot be used. On the other hand, if the total content of hectorite and silica, which are water-swellable inorganic polymers , with respect to the entire composition is less than 0.5% by mass, the shrinkage force is weakened on the film and the fixing force for correcting the skin is weakened. If it exceeds 3.5% by mass, the spray nozzle is clogged and cannot be used. In addition, when the content of the polyether-modified silicon in the whole composition is less than 0.5% by mass, the coating is insufficiently flexible, has no sustainability and breaks in the middle, and clogs the spray injection port. Will occur. On the other hand, if it exceeds 3.0% by mass, the shrinkage force of the fixing film is weak although it is flexible, and the tightening effect such as sagging becomes extremely low.
The cosmetic composition for spray according to claim 2 contains 1.5 to 3.0% by mass of gazein Na, which is a natural polymer, based on the entire cosmetic composition for spraying, and based on the entire cosmetic composition for spraying. The water-swellable inorganic polymer hectorite and silica are contained in a total amount of 1.0 to 3.0% by mass, and the polyether-modified silicone is added to the spray cosmetic composition in an amount of 0.5 to 1.0. The cosmetic composition for spraying according to claim 3 contains 1.0 mass% of 1.3BG (butylene glycol) with respect to the entire cosmetic composition for spraying.
請求項4のスプレー用化粧組成物は、請求項1に記載のスプレー用化粧組成物であって、天然高分子であるガゼインNaの含有量が0〜3.0質量%である。天然高分子は、含有量が増すごとに皮膚への接着力が強くなる傾向にある。しかし、目の回り等のデリケートな部分に本願組成物を使用する場合、形成される被膜には、皮膚の引き締め力だけでなく柔軟性が求められる。したがって、この場合には、天然高分子の含有量を減じるか又は含有しないようにして被膜の柔軟性を確保する。 The cosmetic composition for spray of Claim 4 is the cosmetic composition for spray of Claim 1, Comprising: Content of the casein Na which is a natural polymer is 0-3.0 mass%. Natural polymers tend to have stronger adhesion to the skin as their content increases. However, when the composition of the present application is used in a delicate part such as around the eyes, the formed film is required not only to tighten the skin but also to have flexibility. Therefore, in this case, the flexibility of the coating is ensured by reducing or not containing the content of the natural polymer .
また、水膨潤性無機高分子であるヘクトライト及びシリカの合計含有量は、組成物全体に対して0.5〜6.0質量%である。組成物全体における天然高分子であるガゼインNaを0.5質量%未満に減じたり、または天然高分子を含まないようにした場合には、皮膜の収縮力や皮膚を補正する固着力が弱くなるが、皮膚の収縮力や固着力の強さは、水膨潤性無機高分子の含有量を増加させることで補完される。従って、その場合における水膨潤性無機高分子であるヘクトライト及びシリカの合計含有量は、3.0質量%以上とすることが望ましい。しかし、通常は、水膨潤性無機高分子であるヘクトライト及びシリカの合計含有量が組成物全体の3.5質量%を超えると粘度が急激に上昇して撹拌分散することが困難となり、スプレー噴射口の目詰まり等の原因になる。 The total content of hectorite and silica, which are water-swellable inorganic polymers , is 0.5 to 6.0% by mass with respect to the entire composition. When the casein Na , which is a natural polymer in the whole composition , is reduced to less than 0.5% by mass or does not contain a natural polymer, the contraction force of the film and the fixing force for correcting the skin are weakened. However, the strength of the skin contraction force and adhesion force is complemented by increasing the content of the water-swellable inorganic polymer. Accordingly, in this case, the total content of hectorite and silica, which are water-swellable inorganic polymers , is preferably 3.0% by mass or more. However, normally, when the total content of hectorite and silica, which are water-swellable inorganic polymers , exceeds 3.5% by mass of the entire composition, the viscosity rapidly increases and it becomes difficult to stir and disperse. This may cause clogging of the injection port.
そこで、請求項4のスプレー用化粧組成物においては、解膠剤であるピロリン酸Naを含有させる。ピロリン酸ナトリウムを解膠剤として含有させた場合(好ましい含有量は、水膨潤性無機高分子の総量に対して0.01質量%〜5.0質量%)には、水膨潤性無機高分子であるヘクトライト及びシリカの合計含有量が3.5質量%を超えても粘度を低下させることができるため、水膨潤性無機高分子の含有量がより多くてもスプレー噴射口の目詰まり等を防止できる。 Therefore, in the cosmetic composition for spray according to claim 4 , Na pyrophosphate which is a peptizer is contained. When sodium pyrophosphate is included as a peptizer (preferably the content is 0.01% by mass to 5.0% by mass with respect to the total amount of the water-swellable inorganic polymer), the water-swellable inorganic polymer Since the viscosity can be lowered even if the total content of hectorite and silica exceeds 3.5% by mass, the spray nozzle is clogged even if the content of the water-swellable inorganic polymer is higher Can be prevented.
尚、請求項4における水膨潤性無機高分子の含有量は、0.5質量%未満の場合、皮膜の収縮力が弱くなって皮膚を補正する固着力が弱くなり、6.0質量%を超える場合、引き締め力は強靭になるが顔の表情の変化に追随できずに皮膜が破断して見栄えが悪くなる。また固形分濃度が高くなるためにスプレー噴射口が目詰りを起こして使用できなくなる。 In addition, when the content of the water-swellable inorganic polymer in claim 4 is less than 0.5% by mass, the shrinkage force of the film becomes weak and the fixing force for correcting the skin becomes weak, and 6.0% by mass is obtained. If it exceeds, the tightening force will be strong, but it will not be able to follow the change in facial expression, and the film will break and the appearance will deteriorate. Further, since the solid content concentration is high, the spray nozzle is clogged and cannot be used.
また、組成物全体に対するポリエーテル変性シリコンの含有量は、0.5〜5.0質量%である。また、ポリエーテル変性シリコンは、水膨潤性無機高分子の総量に比例して含有させ、水膨潤性無機高分子:ポリエーテル変性シリコンを80:20〜40:60質量比とすることが好ましく、更に、水膨潤性無機高分子:ポリエーテル変性シリコンを70:30〜60:40とすることがより好ましい。 Moreover, content of the polyether modified silicon with respect to the whole composition is 0.5-5.0 mass%. Further, the polyether-modified silicon is preferably contained in proportion to the total amount of the water-swellable inorganic polymer, and the water-swellable inorganic polymer: polyether-modified silicon is preferably 80:20 to 40:60 mass ratio, Furthermore, it is more preferable that the water-swellable inorganic polymer: polyether-modified silicon is 70:30 to 60:40.
ポリエーテル変性シリコンの含有量が0.5質量%未満の場合には、皮膜に柔軟性が不足し、持続力がなく途中で破断することに加え、スプレー噴射口に目詰りが発生する。また、ポリエーテル変性シリコンは、組成物に解膠剤を含有させて水膨潤性無機高分子の含有量を増加可能にしたことにより、含有量が3.0質量%を超えても固着皮膜の収縮力が低下しにくくなる。但し、ポリエーテル変性シリコンの含有量が5.0質量%を超える場合には、柔軟性があるものの固着皮膜の収縮力が弱くなるため、たるみなど引き締め効果が極めて低くなる。 When the content of the polyether-modified silicon is less than 0.5% by mass, the film is insufficiently flexible, has no sustainability and breaks in the middle, and clogging occurs in the spray nozzle. In addition, the polyether-modified silicon contains a deflocculant in the composition to increase the content of the water-swellable inorganic polymer, so that even if the content exceeds 3.0% by mass, The shrinkage force is difficult to decrease. However, when the content of the polyether-modified silicon exceeds 5.0% by mass, the shrinkage force of the fixing film is weakened although it is flexible, and the tightening effect such as sagging becomes extremely low.
請求項5のスプレー用化粧組成物は、水膨潤性無機高分子であるヘクトライトをスプレー用化粧組成物全体に対して3.0質量%含有し、水膨潤性無機高分子であるシリカを前記スプレー用化粧組成物全体に対して2.5質量%含有し、解膠剤であるピロリン酸Naをヘクトライト及びシリカからなる水膨潤性無機高分子の総量に対して0.1質量%含有し、ポリエーテル変性シリコンを前記スプレー用化粧組成物全体に対して3.0質量%含有する。The spray cosmetic composition according to claim 5 contains 3.0% by mass of hectorite, which is a water-swellable inorganic polymer, based on the entire spray cosmetic composition, and the silica, which is a water-swellable inorganic polymer, Containing 2.5% by mass with respect to the entire cosmetic composition for spraying, and 0.1% by mass of sodium pyrophosphate, a peptizer, with respect to the total amount of the water-swellable inorganic polymer composed of hectorite and silica. The polyether-modified silicon is contained in an amount of 3.0% by mass with respect to the entire spray cosmetic composition.
請求項6のスプレー用化粧組成物は、1.3BGを請求項4または5のスプレー用化粧組成物全体に対して3.0質量%含有する。 The cosmetic composition for spray according to claim 6 contains 3.0% by mass of 1.3BG with respect to the entire cosmetic composition for spray according to claim 4 or 5.
請求項7のスプレー用化粧組成物は、請求項1から6のうちいずれかに記載のスプレー用化粧組成物であって、前記ポリエーテル変性シリコンは、HLB値(親水性と親油性のバランス値)が5以上ものを採用した。 The spray cosmetic composition according to claim 7 is the spray cosmetic composition according to any one of claims 1 to 6 , wherein the polyether-modified silicone has an HLB value (balance between hydrophilicity and lipophilicity). ) Used 5 or more.
請求項8の表情を若々しい物理的な形状に補正するメイクアップ方法は、請求項1から7のうちいずれかに記載のスプレー用化粧組成物をスプレーで顔に吹き付けて皮膜を形成し、前記皮膜の物理的かつ強力な収縮力を利用して、顔全体の皮膚のたるみや顔の輪郭の緩みを物理的に収縮させて補正し、かつ皮膜の柔軟性によって前記補正後の状態を持続させることにより、表情を皮膚のたるみ等が発生する前の若々しい状態に長時間(約6時間〜8時間)保つ。 A makeup method for correcting the facial expression of claim 8 to a youthful physical shape forms a film by spraying the cosmetic composition for spray according to any one of claims 1 to 7 on the face with a spray, Using the physical and strong contraction force of the film, the skin sagging of the entire face and the looseness of the facial contour are corrected by physically contracting, and the corrected state is maintained by the flexibility of the film. By doing so, the facial expression is kept in a youthful state before the occurrence of sagging skin etc. for a long time (about 6 to 8 hours).
ここで、請求項1から7に示すスプレー用化粧組成物(皮膜)の収縮力と柔軟性の発現メカニズムを説明する。本発明で使用される水膨潤性無機高分子の粒子は、比表面積が大きく、水中で三次元構造に分散する超微細粒子であるため、粒子間の空隙は小さく毛管作用が大きくなる。これによって、水分が離脱する際には、粒子間の空隙が微細に狭まり、強い収縮力が発生し、超微粒子どうしが引き寄せられて徐々に固着する。しかし、水膨潤性無機高分子の塗膜は、一般に単独で連続皮膜化はせず、固くて砂のように脆い塊となる。水膨潤性無機高分子であるヘクトライト(合成ラポナイト)などは、単独で乾燥皮膜化するが、やはり柔軟性のある皮膚上ではすぐ破断して粉状になる点で問題がある。 Here, the mechanism of expression of the shrinkage force and flexibility of the cosmetic composition for spraying (film) according to claims 1 to 7 will be described. Since the water-swellable inorganic polymer particles used in the present invention are ultrafine particles having a large specific surface area and dispersed in a three-dimensional structure in water, the voids between the particles are small and the capillary action is large. As a result, when moisture is released, the voids between the particles are finely narrowed, a strong contraction force is generated, and the ultrafine particles are attracted and gradually fixed. However, a coating film of a water-swellable inorganic polymer generally does not form a continuous film by itself, but becomes a hard and brittle mass like sand. Hectorite (synthetic laponite), which is a water-swellable inorganic polymer, forms a dry film by itself, but still has a problem in that it breaks immediately on flexible skin and becomes powdery.
一方、水膨潤性無機高分子に加えて天然高分子を含有させた場合には、連続被膜化する一方、これらの含有濃度に比例して固着皮膜が厚くなり、強い収縮力を発生して皮膚を収縮させる。しかし、天然高分子と水膨潤性無機高分子からなる厚い被膜は、皮膚に対する違和感を強く感じさせ、柔軟性の不足から顔の表情の動きに追随できずに破断や剥離するなど、皮膚面で長時間(約6時間〜8時間)皮膜を持続させる上で無理がある。 On the other hand, when a natural polymer is contained in addition to a water-swellable inorganic polymer, a continuous film is formed. On the other hand, the fixed film becomes thicker in proportion to the concentration of these, and a strong contraction force is generated to cause the skin. Shrink. However, a thick film made of natural polymer and water-swellable inorganic polymer gives a strong sense of discomfort to the skin, and due to lack of flexibility, it can not follow the facial expression movement and breaks or peels off. It is impossible to maintain the film for a long time (about 6 to 8 hours).
そこで、発明者が研究を重ねた結果、天然高分子と水膨潤性無機高分子に加えてポリエーテル変性シリコンを請求項1に記載した割合で含有させた場合、得られるスプレー用化粧用組成物は、保水性能が著しく向上することにより、柔軟性のある皮膜を長時間保つことが判った。即ち、ポリエーテル変性シリコンを含有させた組成物は、ポリエーテル変性シリコンを含有させない場合と比べて、皮膚上での濡れ性や広がり、皮膚との密着性など、水膨潤性無機高分子と肌の親和性、固着皮膜の弾性などに優れ、スプレー塗着で皮膚上に柔軟性のある収縮皮膜を形成できることが判った。 Therefore, as a result of repeated research by the inventors, when a polyether-modified silicon is contained in the proportion described in claim 1 in addition to the natural polymer and the water-swellable inorganic polymer, the resulting cosmetic composition for spraying is obtained. Has been found to maintain a flexible film for a long time by significantly improving the water retention performance. That is, the composition containing the polyether-modified silicon has a water-swellable inorganic polymer and skin such as wettability and spread on the skin, adhesion to the skin, etc., compared to the case where the polyether-modified silicon is not contained. It has been found that it is excellent in the affinity of the resin and the elasticity of the fixed film, and a flexible shrink film can be formed on the skin by spray coating.
一方、発明者が更に研究を重ねた結果、請求項4に示すように組成物に解膠剤を含有させた場合には、天然高分子、水膨潤性無機高分子及びポリエーテル変性シリコンを請求項4に記載した幅広い割合で含有させたとしても、得られるスプレー用化粧用組成物が、請求項1と同様の作用効果を奏する被膜を形成するものと判明した。 On the other hand, as a result of further research by the inventor, when a peptizer is included in the composition as shown in claim 4 , a natural polymer, a water-swellable inorganic polymer and a polyether-modified silicon are claimed. even is contained in a wide range of proportions described in claim 4, cosmetic compositions for the resulting spray, were found as forming a coating film achieves the same effects as claim 1.
従って、請求項1から請求項7の化粧用組成物によって顔に形成された皮膜は、天然高分子と水膨潤性無機高分子の組み合わせ、または水膨潤性無機高分子の組み合わせによって物理的な収縮力を発生し、その収縮力によって顔に生じた皮膚のたるみや輪郭の緩みを物理的に収縮変化させてたるみ前の状態に補正する。また、請求項1から請求項7の皮膜は、ポリエーテル変性シリコンによって柔軟性を発揮し、顔の表情の動きに追随して破断や剥離をすることなく、前記補正後の状態を長時間(約6時間〜8時間)持続させる。 Therefore, the film formed on the face by the cosmetic composition of claims 1 to 7 is physically contracted by a combination of a natural polymer and a water-swellable inorganic polymer, or a combination of a water-swellable inorganic polymer. A force is generated, and the sagging of the skin and the looseness of the contour caused by the contraction force are physically contracted to correct the state before sagging. In addition, the film according to claims 1 to 7 exhibits flexibility by the polyether-modified silicon, and maintains the state after correction for a long time without breaking or peeling following the movement of the facial expression. Last for about 6-8 hours).
尚、本願発明の化粧組成物は、例えば、素肌や化粧下地の状態で使用する場合において、手塗りやスポンジ、不織布、綿布、綿棒などに含浸させて塗布することができる。しかし、ファンデーションの上から手塗りなどで塗布した場合には、均一な皮膜を得ることが出来ないばかりか、ファンデーションの仕上がりを崩壊してしまうなどの問題がある。従って、ファンデーションの仕上げ後に使用する場合には、スプレーによる塗着方法が優れている。 The cosmetic composition of the present invention can be applied, for example, by hand coating, sponge, non-woven fabric, cotton cloth, cotton swab or the like when used in the state of bare skin or makeup base. However, when it is applied by hand or the like from above the foundation, there is a problem that not only a uniform film cannot be obtained but also the finish of the foundation is destroyed. Therefore, when used after finishing the foundation, the spray coating method is excellent.
しかし、通常スプレーで使用される化粧水やヘアーセット剤などのスプレー用化粧品組成物は、スプレーの噴射口が詰まらないように濃度が低く抑えられ、通常500cps/25℃以下の低粘度のものが使用される。本願のスプレー用化粧組成物は、皮膚上に固着皮膜を形成する必要があるため、天然高分子と水膨潤性無機高分子、または水膨潤性無機高分子の組み合わせからなる化粧用組成物は、比較的固形分濃度が高く、1000cps/25℃以上の高粘度になる。従って、本願のスプレー用化粧組成物は、高粘度であっても吹き付けによって皮膚へ均一に広がるようにする必要があった。一方、天然高分子は、接着剤の主成分として使用されることが多く、化粧用組成物の収縮力に寄与する反面、乾燥が早く、収縮固着しやすいため、スプレーに使用すると噴射口が詰まりやすくなる問題があった。従って、本願のスプレー用化粧組成物に天然高分子を使用する場合には、スプレー噴射口が詰まらないようにしなければならなかった。 However, cosmetic compositions for sprays such as lotions and hair setting agents that are usually used in sprays have a low viscosity so that the spray nozzles are not clogged, and usually have a low viscosity of 500 cps / 25 ° C or lower. used. Since the spray cosmetic composition of the present application needs to form a fixed film on the skin, the cosmetic composition comprising a combination of a natural polymer and a water-swellable inorganic polymer, or a water-swellable inorganic polymer, The solid content concentration is relatively high, and the viscosity becomes 1000 cps / 25 ° C. or higher. Therefore, the spray cosmetic composition of the present application needs to spread evenly on the skin by spraying even if it has a high viscosity. On the other hand, natural polymers are often used as the main component of adhesives, and contribute to the shrinkage of cosmetic compositions, but they dry quickly and tend to shrink and stick, so when used in sprays, the injection ports are clogged. There was a problem that made it easier. Therefore, when a natural polymer is used in the spray cosmetic composition of the present application, it has been necessary to prevent the spray nozzle from clogging.
請求項1から請求項7のスプレー用化粧組成物は、ポリエーテル変性シリコンを組成物全体に対して所定の質量%で配合することによって天然高分子と水膨潤性無機高分子、または水膨潤性無機高分子の組み合わせにより、ゾル、ゲル構造のコロイド状態が更に強くなるが、軽く振る上下運動、あるいはスプレー噴霧する際の蓄圧で瞬時に低粘度の液体に変化して噴射される一方、圧力から開放されると瞬時にまた元のゾル、ゲルの状態に戻る性質を見出すことができた。この性質は、組成物に配合される種々の粉黛などの沈降防止に役立つことはもちろん、皮膚上に塗着された瞬間にスプレー組成物が増粘されるため、重ね塗りをしても液ダレの防止になる。従って、請求項1から請求項7のスプレー用化粧組成物は、塗布量を多くして強い皮膜を作ることができる。 The cosmetic composition for spray according to any one of claims 1 to 7, wherein a natural polymer and a water-swellable inorganic polymer, or a water-swelling property is obtained by blending polyether-modified silicon in a predetermined mass% with respect to the entire composition. By combining inorganic polymers, the colloidal state of the sol and gel structure is further strengthened. When released, it was possible to find the property of returning to the original sol and gel state instantly. This property not only helps prevent settling of various powders and the like blended in the composition, but also increases the viscosity of the spray composition as soon as it is applied on the skin. It becomes prevention of. Therefore, the cosmetic composition for spray according to claims 1 to 7 can make a strong film by increasing the coating amount.
尚、上述した水膨潤性無機高分子である二酸化ケイ素(シリカ)と合成ケイ酸マグネシウム(ヘクトライト、即ち合成ラポナイト)の混合物は、化粧組成物全体に対する含有量が3.5質量%を超えると急激に増粘して化粧組成物の製造を困難にさせる。その場合には、化粧組成物に解膠剤であるピロリン酸ナトリウムを含有させる(好ましくは、水膨潤性無機高分子の総量に対して0.01質量%〜5.0質量%)ことで粘度を低下させることができる。 In addition, when the mixture of silicon dioxide (silica), which is the above-described water-swellable inorganic polymer , and synthetic magnesium silicate ( hectorite, ie, synthetic laponite) exceeds 3.5% by mass with respect to the entire cosmetic composition. It rapidly thickens, making it difficult to produce a cosmetic composition. In that case, the cosmetic composition contains sodium pyrophosphate as a peptizer (preferably, 0.01% by mass to 5.0% by mass with respect to the total amount of the water-swellable inorganic polymer). Can be reduced .
このように、構造粘性が外圧力で変化する本発明のスプレー組成物は、スプレー噴霧粒子の微細化、スプレーディスペンサーチューブなどの摩擦抵抗の低減化が図られる。その結果、本願のスプレー用化粧組成物は、噴射口の目詰まり無くスプレーに使用出来ると共に、形成される皮膜が皮膚に対して均一に拡がり、適度な密着力を発揮し、皮膚の引き締め持続性を向上させる。 As described above, the spray composition of the present invention in which the structural viscosity changes with the external pressure can reduce the atomization of spray spray particles and reduce the frictional resistance of a spray dispenser tube or the like. As a result, the cosmetic composition for spray of the present application can be used for spraying without clogging the injection port, the formed film spreads uniformly on the skin, exhibits appropriate adhesion, and tightening durability of the skin To improve.
従って、請求項8のメイクアップ方法は、請求項1から請求項7の化粧用組成物をスプレーで顔に吹き付けるだけで顔に生じた皮膚のたるみ等を物理的にたるみ前の若々しい状態に形状補正し、かつ補正後の状態を長時間(約6〜8時間)持続させることが出来る。 Therefore, the makeup method according to claim 8 is a youthful state before physically sagging the skin sagging generated on the face simply by spraying the cosmetic composition according to claims 1 to 7 on the face. The shape can be corrected and the corrected state can be maintained for a long time (about 6 to 8 hours).
請求項1から7のスプレー用化粧組成物は、強力かつ物理的な収縮力を発揮し、立体的な顔の皮膚の動きに追随する柔軟性を発揮しつつ、皮膚との接着性、ファンデーション粉体類との密着性に優れた強靭な固着皮膜を作る。従って、顔に使用した場合には、皮膜の強力な収縮力が、顔に生じた皮膚のたるみや輪郭の緩みを物理的に収縮変化させてたるみ前の状態に補正し、皮膜の柔軟性が、その状態を長時間(約6時間〜8時間)持続させるため、顔の皮膚にたるみのない若々しい表情が長時間(約6時間〜8時間)保たれる。また、請求項1から7のスプレー用化粧組成物は、スプレーに使用しても目詰まりが無いため、請求項8に示す誰にも容易なメイクアップ方法を可能にする。 The cosmetic composition for spray according to any one of claims 1 to 7 , which exhibits a strong and physical contraction force and exhibits flexibility to follow the movement of the three-dimensional facial skin, adhesion to the skin, foundation powder Creates a tough adhesive film with excellent adhesion to the body. Therefore, when used on the face, the strong contraction force of the film compensates for the slackness of the skin and the looseness of the contour that are physically contracted to the state before sagging, and the flexibility of the film is improved. In order to maintain the state for a long time (about 6 to 8 hours), a youthful expression without sagging on the facial skin is maintained for a long time (about 6 to 8 hours). Also, spray cosmetic composition of claims 1 7, because there is no clogging also be used to spray to allow easy makeup way anyone indicated in claim 8.
即ち、請求項8のメイクアップ方法によれば、請求項1から7の化粧組成物をスプレーで顔に吹き付けるだけで容易に顔に生じた皮膚のたるみ等を物理的に補正し、かつ補正後の状態を長時間(約6時間〜8時間)維持することが出来る。従って、請求項8のメイクアップ方法を利用すれば、熟練した知識と化粧技術がなくても、誰もが簡単に若々しい表情を長時間形成することが出来る。 That is, according to the makeup method of claim 8 , the skin sagging or the like easily generated on the face is simply corrected by spraying the cosmetic composition of claims 1 to 7 on the face, and after the correction. This state can be maintained for a long time (about 6 to 8 hours). Therefore, if the makeup method of claim 8 is used, anyone can easily form a youthful expression for a long time without skilled knowledge and makeup techniques.
尚、請求項8のメイクアップ方法によって顔に形成された固着皮膜は、数ミクロン以下の皮膜厚である為に、皮膚に対して違和感などを与えることがない。また、化粧直しなどで使用した場合には、既存のファンデーション類の伸びや仕上がりに影響を与えること無く皮膚のたるみ等を補正できる。さらに、本発明をファンデーション仕上げ後の顔に使用した場合には、ファンデーションの密着を改善して、皮脂による浮きを防止することが出来、化粧を長持ちさせることが出来る。 In addition, since the fixed film formed on the face by the makeup method of claim 8 has a film thickness of several microns or less, it does not give an uncomfortable feeling to the skin. In addition, when used for retouching, it is possible to correct skin sagging and the like without affecting the growth and finish of existing foundations. Furthermore, when this invention is used for the face after foundation finishing, the close_contact | adherence of foundation can be improved, the float by sebum can be prevented, and makeup can be made lasting.
一方、請求項8のメイクアップ方法による顔の固着皮膜は、物理的な摩擦に強く、水分補給によって物理的な収縮力が復元する。即ち、化粧直しなどの化粧スポンジによる塗擦で皮膜が若干破断した場合、皮膜の物理的な収縮力は、一旦低下するものの既存ファンデーション類に含まれる水分あるいは皮膚から蒸散放出される水分(水蒸気)によって天然高分子と水膨潤性無機高分子または水膨潤性無機高分子の組み合わせ、さらにポリエーテル変性シリコンの含有組成物が再皮膜化するため、低下した皮膜の収縮力が復元する。 On the other hand, the fixed film on the face by the makeup method of claim 8 is resistant to physical friction, and the physical contraction force is restored by hydration. In other words, when the film is slightly broken by rubbing with a makeup sponge such as remake, the physical contraction force of the film once decreases, but it is naturally reduced by moisture contained in the existing foundations or moisture (vapor) released from the skin. Since the combination of the polymer and the water-swellable inorganic polymer or the water-swellable inorganic polymer and the composition containing the polyether-modified silicon are re-filmed, the contraction force of the reduced film is restored.
従って、顔の固着皮膜を長時間、例えば皮膜形成後12時間以上持続させたい場合には、皮脂の影響により皮膚と既存ファンデーションとの密着が弱くなりはじめる約6時間〜8時間後に、水分を含んだコットンやティッシュなどで軽く押さえるように水分補給をするか、スプレーで水を噴霧することなどにより持続力を維持することが出来る。また、顔の固着皮膜は、皮膜の上から本発明の化粧組成物を再スプレーすることにより、すでに塗着されていた固着皮膜が化粧組成物中の水分で再皮膜化され、その上に新たな固着皮膜を積層することによって収縮力が増強される。 Therefore, when it is desired to maintain the fixed film on the face for a long period of time, for example, 12 hours or more after the film is formed, it contains water after about 6 to 8 hours, when the adhesion between the skin and the existing foundation starts to weaken due to the effect of sebum. Sustainability can be maintained by hydrating with light cotton or tissue, or spraying with water. In addition, by re-spraying the cosmetic composition of the present invention from above the film, the fixed film on the face is re-filmed with the moisture in the cosmetic composition, and a new film is formed on the film. The laminating force is enhanced by laminating a fixed film.
次に、本発明について詳細に説明する。 Next, the present invention will be described in detail.
本発明のスプレー用化粧組成物は、天然高分子及び水膨潤性無機高分子に加えてポリエーテル変性シリコンを含有する。天然高分子の含有量は、組成物全体に対して0.5〜3.0質量%であり、水膨潤性無機高分子を組成物全体に対して0.5〜3.5質量%となるように含有される。さらに、ポリエーテル変性シリコンの含有量は組成物全体に対して0.5〜3.0質量%である。 The cosmetic composition for spray according to the present invention contains a polyether-modified silicone in addition to a natural polymer and a water-swellable inorganic polymer. The content of the natural polymer is 0.5 to 3.0% by mass with respect to the entire composition, and the water-swellable inorganic polymer is 0.5 to 3.5% by mass with respect to the entire composition. Contained. Furthermore, content of polyether modified silicon is 0.5-3.0 mass% with respect to the whole composition.
本発明のスプレー用化粧組成物に解膠剤を含有させた場合には、天然高分子を組成物全体に対して0〜3.0質量%の範囲で含有させ、水膨潤性無機高分子を組成物全体に対して0.5〜6.0質量%の範囲で含有させ、さらに、ポリエーテル変性シリコンを組成物全体に対して0.5〜5.0質量%の範囲で含有させる。解膠剤には、後述する塩類等を用いることができ、解膠剤の含有量は、水膨潤性無機高分子の総量に対して0.01質量%〜5.0質量%程度とすることが好ましい。その際のポリエーテル変性シリコンは、水膨潤性無機高分子の総量に比例して含有させ、水膨潤性無機高分子:ポリエーテル変性シリコンを80:20〜40:60質量比とすることが好ましく、更に、水膨潤性無機高分子:ポリエーテル変性シリコンを70:30〜60:40とすることがより好ましい。 When a peptizer is contained in the spray cosmetic composition of the present invention, the natural polymer is contained in the range of 0 to 3.0% by mass with respect to the entire composition, and the water-swellable inorganic polymer is added. It is made to contain in 0.5-6.0 mass% with respect to the whole composition, and also polyether modified silicon is contained in 0.5-5.0 mass% with respect to the whole composition. For the peptizer, salts and the like described later can be used, and the content of the peptizer should be about 0.01% by mass to 5.0% by mass with respect to the total amount of the water-swellable inorganic polymer. Is preferred. The polyether-modified silicon at that time is preferably contained in proportion to the total amount of the water-swellable inorganic polymer, and the water-swellable inorganic polymer: polyether-modified silicon is preferably 80:20 to 40:60 mass ratio. Furthermore, it is more preferable that the water-swellable inorganic polymer: polyether-modified silicon is 70:30 to 60:40.
また、本発明の天然高分子は、動物由来天然高分子、植物由来天然高分子、生物由来天然高分子、または微生物由来天然高分子のうち少なくとも一以上から選択されたものである。即ち、本発明の天然高分子は、例えば、ゼラチン、カゼインナトリウム、アルブミン、コラーゲンなどの動物由来天然高分子:アラビアガム、トラガカントガム、ローカストビンガム、アルゲコロイド、デンプン、セルロース誘導体などの植物由来天然高分子:セリシン、キトサンなどの生物由来天然高分子:デキストラン、プルラン、ヒアルロン酸、アセチル化ヒアルロン酸、コンドロイチン、コンドロイチン硫酸などの微生物由来天然高分子のうち少なくとも一以上から選択されたものである。 The natural polymer of the present invention is selected from at least one of animal-derived natural polymers, plant-derived natural polymers, biological-derived natural polymers, or microbial-derived natural polymers. That is, the natural polymer of the present invention includes, for example, animal-derived natural polymers such as gelatin, sodium caseinate, albumin and collagen: plant-derived natural polymers such as gum arabic, gum tragacanth, locust bin gum, alge colloid, starch and cellulose derivatives. : Biologically derived natural polymer such as sericin and chitosan: selected from at least one of microorganism-derived natural polymers such as dextran, pullulan, hyaluronic acid, acetylated hyaluronic acid, chondroitin, and chondroitin sulfate.
尚、動物由来高分子は、カゼインナトリウムまたはアルブミンを選択することが好ましく、植物由来天然高分子は、アルゲコロイドまたはデンプンを選択することが好ましい。また、生物由来天然高分子は、セリシンを選択することが好ましく、微生物由来天然高分子は、アセチル化ヒアルロン酸を選択することが好ましい。尚、中でも最も好ましい高分子は、動物由来高分子のカゼインナトリウムである。カゼインナトリウムは、乳性蛋白質カゼインをアルカリで中和し、ナトリウム塩としたものであり、他の天然高分子に比べて、ケイ酸化合物との安定性がよく、一般的なファンデーション基材や粉体への浸透密着性がよく、皮膚への接着力が強く、強固かつ柔軟な皮膜を形成する。 The animal-derived polymer is preferably sodium caseinate or albumin, and the plant-derived natural polymer is preferably selected from alge colloid or starch. In addition, sericin is preferably selected as the biologically derived natural polymer, and acetylated hyaluronic acid is preferably selected as the microbially derived natural polymer. Of these, the most preferred polymer is animal-derived polymer casein sodium. Casein sodium is a sodium salt obtained by neutralizing the milk protein casein with an alkali, and has better stability with silicate compounds than other natural polymers. It has good penetration adhesion to the body, strong adhesion to the skin, and forms a strong and flexible film.
また、本発明の水膨潤性無機高分子は、天然または合成由来のあらゆるケイ酸化合物を意味する。例えば、シリカ、ベントナイト、ヘクトライト(合成系ラポナイト)、モンモリロナイト、パイデライト、ノントロナイト、サポナイトまたはケイ酸アルミニウムマグネシウムのうち少なくとも一種以上から選択する。これらは、天然物および合成物のいずれであってもよい。尚、本発明の水膨潤性無機高分子は、シリカとヘクトライト(合成ラポナイト)を組み合わせたものが特に好ましく、本発明の化粧組成物に天然高分子を含まない場合、水膨潤性無機高分子は、二酸化ケイ素(シリカ)と合成ケイ酸マグネシウム(ラポナイト)を組み合わせたものが好ましい。 In addition, the water-swellable inorganic polymer of the present invention means any silicate compound derived from nature or synthesis. For example, it is selected from at least one of silica, bentonite, hectorite (synthetic laponite), montmorillonite, piderite, nontronite, saponite, and aluminum magnesium silicate. These may be natural products or synthetic products. The water-swellable inorganic polymer of the present invention is particularly preferably a combination of silica and hectorite (synthetic laponite). When the cosmetic composition of the present invention does not contain a natural polymer, the water-swellable inorganic polymer Is preferably a combination of silicon dioxide (silica) and synthetic magnesium silicate (laponite).
シリカは他のケイ酸化合物に比べて表面積が大きく、水中分散粒子径が極小である為に毛官作用が大きく、乾燥するときに強い収縮力が発生するが、皮膜にならず粉状になる。ヘクトライト(合成ラポナイト)は、皮膜になるものの収縮力は弱い。しかし、シリカとヘクトライト(合成ラポナイト)と天然高分子とポリエーテル変性シリコンを組み合わせて、本実施形態に示す割合で化粧組成物に含有させた場合には、適度な収縮力が長時間持続する柔軟な皮膜ができる。 Silica has a larger surface area than other silicic acid compounds, and its particle size in water is extremely small. . Although hectorite (synthetic laponite) becomes a film, it has a weak contraction force. However, when silica, hectorite (synthetic laponite), natural polymer, and polyether-modified silicon are combined and included in the cosmetic composition at the ratio shown in the present embodiment, an appropriate shrinkage force lasts for a long time. A flexible film can be formed.
また、本発明の水膨潤性無機高分子の平均粒子径は5nm〜1μmとすることが好ましく、例えば二酸化ケイ素の場合には、5nm〜50nmとすることが好ましい。尚、他のケイ酸化合物は、20nm〜1μmが好ましく、比表面積(BET法による)では、50m2/g〜500m2/gとすることが好ましい。これらの水膨潤性無機高分子は、水中で三次元的な網目構造を形成し、ゾル、ゲルの構造を呈しコロイド状となる。 The average particle size of the water-swellable inorganic polymer of the present invention is preferably 5 nm to 1 μm. For example, in the case of silicon dioxide, it is preferably 5 nm to 50 nm. The other silicic acid compound is preferably 20 nm to 1 μm, and the specific surface area (according to the BET method) is preferably 50 m 2 / g to 500 m 2 / g. These water-swellable inorganic polymers form a three-dimensional network structure in water, have a sol-gel structure and are colloidal.
また、本発明では、HLB値が5以上のポリエーテル変性シリコンを使用する。具体的には、例えば、ポリオキシエチレン・メチルポリシロキサン共重合体、ポリ(オキシエチレン・オキシプロピレン)メチルポリシロキサン共重合体、ラウリルメチコーンコポリオール、メチルポリシロキサン・セチルメチルポリシロキサン・ポリ(オキシエチレン・オキシプロピレン)メチルポリシロキサン共重合体等のうち少なくとも一種以上から選択する。 In the present invention, polyether-modified silicon having an HLB value of 5 or more is used. Specifically, for example, polyoxyethylene / methylpolysiloxane copolymer, poly (oxyethylene / oxypropylene) methylpolysiloxane copolymer, laurylmethicone copolyol, methylpolysiloxane / cetylmethylpolysiloxane / poly ( It is selected from at least one of oxyethylene / oxypropylene) methylpolysiloxane copolymer and the like.
また、本発明の解膠剤は、塩化ナトリウム、塩化マグネシウム等の金属塩や、ピロリン酸ナトリウム等の塩類等から選択して配合する。尚、本発明の化粧組成物は、天然高分子と水膨潤性無機高分子、または水膨潤性無機高分子の組み合わせに加え、ポリエーテル変性シリコンを必須成分とする他、更に他の成分等を少なくとも一種以上配合してもかまわない。前記他の成分は、化粧品、医薬部外品の成分として用いられるものであれば特に限定されない。本発明に配合できる前記他の成分等を以下に列挙する。 Further, the peptizer of the present invention is selected from a metal salt such as sodium chloride and magnesium chloride, a salt such as sodium pyrophosphate, and the like. The cosmetic composition of the present invention contains, in addition to a combination of a natural polymer and a water-swellable inorganic polymer, or a water-swellable inorganic polymer, a polyether-modified silicone as an essential component, and other components. You may mix | blend at least 1 type or more. The other components are not particularly limited as long as they are used as components for cosmetics and quasi drugs. The other components that can be blended in the present invention are listed below.
即ち、本発明の化粧組成物には、保湿成分として、コラーゲン、ヒアルロン酸、トレハロース、キトサン、グリセリン、ポリエチレングリコール、プロピレングリコール、1・3ブタノール、1,2−ペンタンジオール、キシリトール、エリスリトール、ハチミツ、ソルビトールなどを配合できる。 That is, the cosmetic composition of the present invention contains collagen, hyaluronic acid, trehalose, chitosan, glycerin, polyethylene glycol, propylene glycol, 1,3 butanol, 1,2-pentanediol, xylitol, erythritol, honey, Sorbitol can be blended.
また、本発明の化粧組成物には、細胞賦活成分として、ローヤルゼリーエキス、γ-アミノ酪酸、若しくはε-アミノプロン酸などのアミノ酸類:レチノール、チアミン、リボフラビン、塩酸ピリドキシン、若しくはパントテン酸類などのビタミン類:グリコール酸若しくは乳酸などのα-ヒドロキシ酸類:タンニン、フラボノイド、サポニン、アラントイン、感光素などを配合できる。 In addition, the cosmetic composition of the present invention contains amino acids such as royal jelly extract, γ-aminobutyric acid, or ε-aminoproic acid: vitamins such as retinol, thiamine, riboflavin, pyridoxine hydrochloride, or pantothenic acids as cell activation ingredients. : Α-hydroxy acids such as glycolic acid or lactic acid: tannin, flavonoid, saponin, allantoin, photosensitizer, etc. can be blended.
また、本発明の化粧組成物には、抗シワ成分として、レチノイド(レチノール、レチノイン酸、レチナール等)、カイネチンなどを配合できる。 The cosmetic composition of the present invention can contain retinoids (retinol, retinoic acid, retinal, etc.), kinetin and the like as anti-wrinkle components.
また、本発明の化粧組成物には、美白成分として、パントテン酸、その誘導体、エラグ酸、フィチン酸、ビタミンC、ビタミンA、その誘導体、ビタミンE、プラセンタ、アルブチン、その誘導体を配合できる。 The cosmetic composition of the present invention may contain pantothenic acid, derivatives thereof, ellagic acid, phytic acid, vitamin C, vitamin A, derivatives thereof, vitamin E, placenta, arbutin, and derivatives thereof as whitening ingredients.
また、本発明の化粧組成物には、油脂類として以下のものを配合できる。即ち、セタノール、ステアリルアルコール、ヘキシルデカノール、オクチルデカノール、ラウリルアルコールなどの天然または合成高級アルコールを配合できる。また、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル、オレイン酸オクチルドデシル、コレステロールオレート等のエステル、エーテル類を配合できる。また、綿実油、ゴマ油、サフラワー油、ヒマシ油、オリーブ油、カカオ油、椿油、ヒマワリ油、パーム油、アマ油、シソ油、シア油、サル油、ヤシ油、木ロウ、ホホバ油、アボガド油などの植物油脂を配合できる。また、牛脂、乳脂などの動物油脂を配合できる。また、ミツロウ、ラノリン、カルナウバロウ、キャンデリラロウなどのロウ類を配合できる。また、流動パラフィン、スクワレン、スクワラン、マイクロクリスタリンワックス、セレシンワックス、パラフィンワックス、ワセリンなどの炭化水素類を配合できる。また、ラウリン酸、ミリスチン酸、ステアリン酸、オレイン酸、イソステアリン酸、ベヘニン酸などの天然または合成脂肪酸等を配合できる。また、シリコーン油などを配合できる。 Moreover, the following can be mix | blended with the cosmetic composition of this invention as fats and oils. That is, natural or synthetic higher alcohols such as cetanol, stearyl alcohol, hexyl decanol, octyl decanol, and lauryl alcohol can be blended. Further, esters such as isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, octyldodecyl oleate, cholesterol oleate, and ethers can be blended. Also, cottonseed oil, sesame oil, safflower oil, castor oil, olive oil, cacao oil, cocoon oil, sunflower oil, palm oil, flax oil, perilla oil, shea oil, monkey oil, palm oil, tree wax, jojoba oil, avocado oil, etc. Of vegetable oils and fats. Moreover, animal fats and oils, such as beef tallow and milk fat, can be mix | blended. In addition, waxes such as beeswax, lanolin, carnauba wax, and candelilla wax can be blended. Further, hydrocarbons such as liquid paraffin, squalene, squalane, microcrystalline wax, ceresin wax, paraffin wax, petrolatum and the like can be blended. In addition, natural or synthetic fatty acids such as lauric acid, myristic acid, stearic acid, oleic acid, isostearic acid, and behenic acid can be blended. Moreover, silicone oil etc. can be mix | blended.
また、本発明の化粧組成物には、界面活性剤として、ポリオキシエチレン、ミリスチン酸、ステアリン酸、パルミチン酸、ベヘニン酸、イソステアリン酸、オレイン酸、レシチンやベタインなどを配合できる。 Moreover, polyoxyethylene, myristic acid, stearic acid, palmitic acid, behenic acid, isostearic acid, oleic acid, lecithin, betaine, etc. can be mix | blended with the cosmetic composition of this invention as surfactant.
また、本発明の化粧組成物には、植物抽出物として、アロエ、オウゴン、カッコン、クジン、クロレラ、コムギ、コメ、ソウハクヒ、ダイズ、納豆、ウコン、カミツレ、カロット、センブリ、ローズマリー、海藻、納豆、ウイキョウ、クララ(クジン)、オオムギなどを配合できる。 In addition, the cosmetic composition of the present invention includes, as a plant extract, aloe, ougon, kakon, kujin, chlorella, wheat, rice, sakuhakuhi, soybean, natto, turmeric, chamomile, carrot, assembly, rosemary, seaweed, natto , Fennel, Clara, barley, etc.
また、本発明の化粧組成物には、アミノ酸類として、アラニン、セリン、ロイシン、イソロイシン、スレオニン、グリシン、プロリン、ヒドロキシプロリン、グルコサミン、テアニン、これらの誘導体などを配合できる。 Moreover, alanine, serine, leucine, isoleucine, threonine, glycine, proline, hydroxyproline, glucosamine, theanine, these derivatives, etc. can be mix | blended with the cosmetic composition of this invention.
また、本発明の化粧組成物には、抗酸化成分として、トコフェロール、その誘導体、エリソルビン酸、その塩、ブチルヒドロキシアニソール、ジブチルヒドロキシトルエン、亜硫酸水素ナトリウム、フラボノイド、グルタチオン、グルタチオンペルオキシダーゼ、グルタチオン-S-トランスフェラーゼ、カタラーゼ、スーパーオキサイドジスムターゼ、チオレドキシン、タウリン、チオタウリン、ヒポタウリンなどが配合できる。尚、配合する上で特に好ましいのは、トコフェロール及びその誘導体、フラボノイド、チオレドキシン、チオタウリン、ヒポタウリンである。 Further, in the cosmetic composition of the present invention, as an antioxidant component, tocopherol, its derivative, erythorbic acid, its salt, butylhydroxyanisole, dibutylhydroxytoluene, sodium bisulfite, flavonoid, glutathione, glutathione peroxidase, glutathione-S- Transferase, catalase, superoxide dismutase, thioredoxin, taurine, thiotaurine, hypotaurine and the like can be blended. Particularly preferred for blending are tocopherol and its derivatives, flavonoids, thioredoxin, thiotaurine, and hypotaurine.
また、本発明の化粧組成物には、収斂成分として、ミョウバン、クロロヒドロキシアルミニウム、塩化アルミニウム、アラントインアルミニウム塩、硫酸亜鉛若しくは硫酸アルミニウムカリウム、塩化ナトリウム、塩化マグネシウム等の金属塩を配合でき、タンニン酸、クエン酸、乳酸若しくはコハク酸などの有機酸を配合できる。 In addition, the cosmetic composition of the present invention can contain metal salts such as alum, chlorohydroxyaluminum, aluminum chloride, allantoin aluminum salt, zinc sulfate or potassium aluminum sulfate, sodium chloride, magnesium chloride as an astringent component, and tannic acid Organic acids such as citric acid, lactic acid or succinic acid can be blended.
また、本発明の化粧組成物には、抗菌成分として、感光素101号、感光素201号、パラベン、フェノキシエタノールまたは1,2−ペンタンジオールなどを配合できる。 In addition, the cosmetic composition of the present invention may contain photosensitive element 101, photosensitive element 201, paraben, phenoxyethanol, 1,2-pentanediol, or the like as an antibacterial component.
また、本発明の化粧組成物には、色材として、タルク、カオリン、セリサイト、雲母、炭酸カルシウム、二酸化チタン、酸化亜鉛、酸化鉄、黄土、群青などの無機顔料を配合でき、赤色201号〜228号、黄色205号、黄色401号などの有機顔料を配合でき、クロロフィルなどの天然色素を配合できる。 In addition, the cosmetic composition of the present invention can contain inorganic pigments such as talc, kaolin, sericite, mica, calcium carbonate, titanium dioxide, zinc oxide, iron oxide, ocher, ultramarine, etc. as a colorant. Organic pigments such as ˜228, Yellow 205 and Yellow 401 can be blended, and natural pigments such as chlorophyll can be blended.
また、本発明の化粧組成物には、紫外線防止剤として、酸化チタン、オキシベンゾン及びその誘導体、パラメトキシケイ皮酸−2−エチルヘキシル、4−tert−ブチル−4’−メトキシジベンゾイルメタンまたは酸化亜鉛などを配合できる。 In addition, the cosmetic composition of the present invention contains titanium oxide, oxybenzone and derivatives thereof, paramethoxycinnamic acid-2-ethylhexyl, 4-tert-butyl-4′-methoxydibenzoylmethane, or zinc oxide as an ultraviolet inhibitor. Etc. can be blended.
以上に示すように、本発明の天然高分子と水膨潤性無機高分子、または水膨潤性無機高分子の組み合わせにポリエーテル変性シリコンを含有した本発明の化粧組成物は、一般にファンデーション類で使用される粉体や色材、保湿成分などを配合することにより、シミ、くすみ、毛穴、痣などを隠蔽しながら、物理的な引き締め力で若々しい引き締まった表情を演出するメイクアップを可能にする。 As described above, the cosmetic composition of the present invention containing polyether-modified silicon in the combination of the natural polymer of the present invention and the water-swellable inorganic polymer or the water-swellable inorganic polymer is generally used in foundations. By blending powders, coloring materials, moisturizing ingredients, etc., it is possible to make up to create a youthful expression with physical tightening power while concealing spots, dullness, pores, wrinkles, etc. To do.
また、皮膚のたるみや顔輪郭のゆるみ、顔形の変化などには、個人差があり、特に、年齢が増すごとに変化の度合いが大きくなることが知られている。しかし、本発明のメイクアップ方法は、スプレーの噴霧回数に応じて物理的な収縮力や形状変化の度合いを選択することができる点で有益である。 Moreover, there are individual differences in sagging skin, loose facial contours, changes in facial shape, and the like, and it is known that the degree of change increases with age. However, the makeup method of the present invention is advantageous in that the physical contraction force and the degree of shape change can be selected according to the number of sprays.
例えば、ノンガスタイプ蓄圧式スプレーを使用する場合、皮膚のたるみや顔の輪郭のゆるみが小さい人は、顔の片側1プッシュ(約0.05mL〜0.1mL)〜2プッシュ(0.1mL〜0.2mL)の噴霧回数でよい。また、皮膚のたるみや顔の輪郭のゆるみが大きい人は顔の片側3プッシュ(0.15mL〜0.3mL)〜4プッシュ(0.2mL〜0.4mL)の噴霧回数で良い。 For example, when using a non-gas type accumulator spray, a person with small skin sagging or facial contour looseness may have 1 push (about 0.05 mL to 0.1 mL) to 2 pushes (0.1 mL to 0 mL) on one side of the face. .2 mL) of spraying is sufficient. In addition, the number of sprays of 3 pushes (0.15 mL to 0.3 mL) to 4 pushes (0.2 mL to 0.4 mL) on one side of the face may be sufficient for people with large skin sagging and loose facial contours.
さらに、部分的なたるみのある部位に引き締め補正力を強く施したい場合には、その部位に適度の噴霧量を重ね付けすることが出来るため、自分の顔の皮膚や輪郭の状態、あるいは好みにあった物理的な形状補正力を自身の選択でメイクアップすることが出来る。 In addition, if you want to apply a strong tightening correction force to a part with partial sagging, you can overlay an appropriate amount of spray on that part, so you can adjust your face's skin, contour, or preference. You can make up the correct physical shape correction force by your own choice.
尚、本発明で言う物理的な形状補正、あるいは物理的な引き締め補正力と言う意味は、化粧品業界で永年周知されて来た従来の感覚的な官能では無く、明らかに物理的な変化が見て取れる現象のことをいう。長時間(約6時間〜8時間)持続すると言う事も感覚的に感じるのではなく、この物理的な形状補正が視覚的に持続するという意味である。メイクアップ製品は、本人の感覚的な官能もさることながら、他人から見た目に若々しく綺麗に見える演出ができることが重要である。 The meaning of physical shape correction or physical tightening correction force in the present invention is not a conventional sensory sensation that has been well known in the cosmetics industry for many years, but a clear physical change can be seen. A phenomenon. It does not feel sensual to say that it lasts for a long time (about 6 to 8 hours), but it means that this physical shape correction is visually sustained. It is important for makeup products to be able to produce a youthful and beautiful appearance from the perspective of others, in addition to their own sensory sensations.
以下に本発明の好適な実施例(実施形態)を説明する、尚、本発明はこれらの実施例に限定されるものではない。配合量は質量%である。 Preferred examples (embodiments) of the present invention will be described below, but the present invention is not limited to these examples. A compounding quantity is the mass%.
発明者は、実施例1〜3及び比較例1〜9のスプレー用化粧組成物を表−1の成分含有量(単位:質量%、残りは水とする)により、以下の(1)〜(4)の処方手順で作成した。即ち、(1):カゼインNa(天然高分子)を60℃以上で加温溶解させる。(2):別槽で、シリカとラポナイト(水膨潤性無機高分子)をホモミキサーで加温しながら分散する。(3):(1)を撹拌しながら(2)を混入する。(4):(1)(2)の混合物をよく撹拌しながら、ポリエーテル変性シリコンと1・3BG(ブチレングリコール)を混入して更に撹拌し、攪拌した混合物を冷却して各スプレー用化粧組成物を得た。また、発明者は、実施例4及び比較例10〜12のスプレー用化粧組成物を表−1の成分含有量(単位:質量%、残りは水とする)により、以下の(1)〜(2)の処方手順で作成した。即ち、(1)シリカとラポナイト(水膨潤性無機高分子)、解膠剤としてピロリン酸ナトリウム(比較例10には含有せず)をホモミキサーで加温しながら分散する。(2):(1)を60℃で撹拌しながらポリエーテル変性シリコンと1・3BG(ブチレングリコール)を混入して更に撹拌し、攪拌した混合物を冷却して各スプレー用化粧組成物を得た。そして、発明者は、加齢による皮膚のたるみや輪郭の緩みについて悩みを持つパネラー20名に対し、本発明の実施例1〜4及び比較例1〜12の化粧組成物を使用して評価する試験を行った。 The inventor used the cosmetic compositions for sprays of Examples 1 to 3 and Comparative Examples 1 to 9 according to the component contents shown in Table 1 (unit: mass%, the rest being water), and the following (1) to ( It was prepared by the prescription procedure of 4). That is, (1): Casein Na (natural polymer) is dissolved by heating at 60 ° C. or higher. (2): Disperse silica and laponite (water-swellable inorganic polymer) while heating with a homomixer in a separate tank. (3): (2) is mixed while stirring (1). (4): While thoroughly stirring the mixture of (1) and (2), the polyether-modified silicone and 1.3BG (butylene glycol) are mixed and further stirred, and the stirred mixture is cooled to each cosmetic composition for spraying. I got a thing. In addition, the inventor made the cosmetic compositions for spraying of Example 4 and Comparative Examples 10 to 12 according to the following component (1) to (1) according to the component content of Table-1 (unit: mass%, the rest being water). Prepared by the prescription procedure of 2). That is, (1) silica and laponite (water-swellable inorganic polymer) and sodium pyrophosphate (not included in Comparative Example 10) as a peptizer are dispersed while warming with a homomixer. (2): While stirring (1) at 60 ° C., polyether-modified silicone and 1.3BG (butylene glycol) were mixed and further stirred, and the stirred mixture was cooled to obtain a cosmetic composition for each spray. . And an inventor evaluates using the cosmetic composition of Examples 1-4 of this invention, and Comparative Examples 1-12 with respect to 20 panelists who are worried about the sagging of the skin by the aging, and the looseness of the outline. A test was conducted.
試験は、実施例1〜4及び比較例1〜12のスプレー用化粧組成物を使用した場合における皮膚のたるみの引き締め効果と顔輪郭の引き締め効果を使用直後、3時間経過後及び6時間経過後に評価することによって行った。 In the test, after using the cosmetic compositions for sprays of Examples 1 to 4 and Comparative Examples 1 to 12, the effect of tightening the sagging skin and the effect of tightening the facial contour immediately after use, after 3 hours and after 6 hours This was done by evaluating.
20名のパネラーには、各化粧組成物に関する使用後の印象について、使用直後、3時間経過後及び6時間経過後に点数をつけさせた。点数は、「非常に効果がある」と感じた場合を2点、「効果がある」と感じた場合を1点「変わらない」と感じた場合を0点とした。評価は、各化粧組成物と各経過時点における20名のパネラーの点数の平均点を集計して以下のように行った。 The 20 panelists were given a score for the impression after use for each cosmetic composition immediately after use, after 3 hours and after 6 hours. The score was 2 points when it felt “very effective”, 1 point when it felt “effective”, and 0 point when it felt “not changed”. The evaluation was performed as follows by summing up the average scores of the scores of 20 panelists at each cosmetic composition and at each time point.
[評価基準]
◎ :20名の平均点が2点(満点) →非常に効果がある
○ :20名の平均が1点以上2点未満→効果がある
× :20名の平均が0点以上1点未満→あまり効果が無いものとした。
△ :スプレー噴射口が詰まり連続噴射不可のため試験中断。
[Evaluation criteria]
◎: The average score of 20 people is 2 (full score) → Very effective ○: The average of 20 people is 1 or more and less than 2 points → Effective ×: The average of 20 people is 0 or more and less than 1 point → It was assumed that it was not very effective.
Δ: The test was stopped because the spray nozzle was clogged and continuous injection was not possible.
また、発明者は、実施例1〜4及び比較例1〜12の化粧組成物についてそれぞれスプレー噴射口の目詰りに関する試験を行った。目詰まり試験は、常温保管及び45℃恒温保管状態において各30本ずつ、毎日1回、5プッシュの噴射をし、1ヶ月間で使い切るという噴射継続試験であり、評価基準は以下の通りであり、表−2に結果を示す。 Moreover, the inventor performed the test regarding the clogging of the spray nozzle about the cosmetic composition of Examples 1-4 and Comparative Examples 1-12, respectively. The clogging test is an injection continuation test in which 30 bottles each are stored at room temperature and at 45 ° C constant temperature, each time 5 pushes are injected once a day and used up for a month. The evaluation criteria are as follows. Table 2 shows the results.
[評価基準]
○ :1ヶ月間30本全てに目詰りがなく噴霧状態が良好。
× :30本中いずれか一本でも目詰りが発生し、噴霧不良を起こした場合。
直後不可:数回はスプレー可能だがすぐに詰ってしまう。
○: All 30 bottles are not clogged for one month, and the spray state is good.
X: When any one of the 30 is clogged, resulting in poor spraying.
Immediately impossible: Spraying is possible several times but clogs immediately.
表−1の試験において、実施例1〜3のスプレー用化粧組成物は、天然高分子の含有量が0.5〜3.0質量%であって、水膨潤性無機高分子を組成物全体に対して0.5〜3.5質量%含有する。さらに、ポリエーテル変性シリコンの含有量は組成物全体に対して0.5〜3.0質量%の範囲内で含有する。即ち、実施例1〜3の化粧組成物は、天然高分子を組成物全体に対して0.5〜3.0質量%含有し、水膨潤性無機高分子を組成物全体に対して0.5〜3.5質量%含有するスプレー用化粧組成物であって、ポリエーテル変性シリコンを前記スプレー用化粧組成物全体の0.5〜3.0質量%含有するようにした。表−1の試験において、実施例1〜3の化粧組成物は、皮膚のたるみ引き締め、顔の輪郭の引き締めに優れ、良好であった。一方、実施例4の化粧組成物においては、実施例4は天然高分子を含有させない状態で、組成物全体に対する水膨潤性無機高分子(ヘクトライトとシリカの組み合わせ)の含有量を5.5質量%に増量させると共に、解膠剤としてピロリン酸ナトリウムを0.1質量%含有させた。実施例4の化粧組成物は、穏やかな引き締め感がある柔らかい皮膜を形成して良好であった。 In the test of Table 1, the cosmetic compositions for sprays of Examples 1 to 3 have a natural polymer content of 0.5 to 3.0% by mass, and the water-swellable inorganic polymer is added to the entire composition. 0.5-3.5 mass% is contained with respect to. Furthermore, the content of the polyether-modified silicon is contained in the range of 0.5 to 3.0% by mass with respect to the entire composition. That is, the cosmetic compositions of Examples 1 to 3 contain the natural polymer in an amount of 0.5 to 3.0% by mass with respect to the entire composition, and the water-swellable inorganic polymer in an amount of 0. A cosmetic composition for spraying containing 5 to 3.5% by mass, wherein the polyether-modified silicon is contained in an amount of 0.5 to 3.0% by mass based on the total cosmetic composition for spraying. In the test of Table 1, the cosmetic compositions of Examples 1 to 3 were excellent in sagging skin sagging and tightening the facial contour, and were good. On the other hand, in the cosmetic composition of Example 4, Example 4 has a water-swellable inorganic polymer (combination of hectorite and silica) content of 5.5 with respect to the whole composition in a state where no natural polymer is contained. While increasing the amount to 0.1% by mass, 0.1% by mass of sodium pyrophosphate was added as a peptizer. The cosmetic composition of Example 4 was good by forming a soft film with a gentle tightening feeling.
一方、表−1の試験において、比較例1〜3の化粧組成物は、天然高分子の含有量が0.5〜3.0質量%の範囲内であって、水膨潤性無機高分子が組成物全体に対して0.5〜3.5質量%含有するが、ポリエーテル変性シリコンを含有しない。即ち、比較例1〜3の化粧組成物は、天然高分子を組成物全体に対して1.5〜3.0質量%含有し、水膨潤性無機高分子を組成物全体に対して1.0〜3.0質量%含有するが、ポリエーテル変性シリコンを含有させていない。その結果、比較例1〜3の化粧組成物は、皮膚のたるみ引き締め効果が使用後3時間(比較例1は3時間以内)を経過すると著しく低下し、顔の輪郭の引き締め効果においても、使用後3時間を経過すると著しく低下することが判明し、前記効果の持続性が比較例1〜3よりも顕著に劣ることが判明した。 On the other hand, in the test of Table 1, the cosmetic compositions of Comparative Examples 1 to 3 have a natural polymer content in the range of 0.5 to 3.0% by mass, and the water-swellable inorganic polymer is It is contained in an amount of 0.5 to 3.5% by mass based on the entire composition, but does not contain polyether-modified silicon. That is, the cosmetic compositions of Comparative Examples 1 to 3 contain 1.5 to 3.0% by mass of the natural polymer with respect to the entire composition, and the water-swellable inorganic polymer to 1. 0 to 3.0% by mass is contained, but polyether-modified silicon is not contained. As a result, in the cosmetic compositions of Comparative Examples 1 to 3, the sagging tightening effect of the skin was remarkably lowered after 3 hours after use (Comparative Example 1 was within 3 hours), and the facial contour tightening effect was also used. It was found that after 3 hours had passed, it was significantly reduced, and the sustainability of the effect was significantly inferior to those of Comparative Examples 1 to 3.
一方、比較例4と5は、組成物全体に対する天然高分子の含有量が、0.5質量%未満(0.4質量%)である場合と、3.0質量%を超えた(3.1質量%)場合を示す。比較例4は、天然高分子の含有量が少なく、皮膜が弱くなり、たるみなど引き締め効果が発揮できなかった。また、比較例5は、天然高分子の含有量が多く、スプレー噴射口の目詰りのために使用出来なくなった。 On the other hand, in Comparative Examples 4 and 5, the content of the natural polymer relative to the entire composition was less than 0.5% by mass (0.4% by mass) and exceeded 3.0% by mass (3. 1% by mass). In Comparative Example 4, the content of the natural polymer was small, the film became weak, and the tightening effect such as sagging could not be exhibited. In Comparative Example 5, the content of the natural polymer was large, and it became impossible to use due to clogging of the spray nozzle.
比較例6と7は、組成物全体に対する水膨潤性無機高分子(ヘクトライト(ケイ酸塩)+シリカ)の合計含有量が0.5質量%未満(0.4質量%)である場合と、3.5質量%を超えた(3.6質量%)場合を示す。比較例6は、水膨潤性無機高分子の含有量が少なく、収縮力が弱いため、皮膚を補正する固着力が無かった。比較例7は、水膨潤性無機高分子の含有量が多くなり、加えて天然高分子の含有量も多く、水膨潤性無機高分子の含有量と天然高分子の含有量の割りには相対的にポリエーテル変性シリコンの含有量が少なく、粘度の高い、接着力が強く、べたつきが強い組成物となり、スプレー噴射口の目詰りのために使用不可となった。 In Comparative Examples 6 and 7, the total content of the water-swellable inorganic polymer (hectorite (silicate) + silica) with respect to the entire composition is less than 0.5% by mass (0.4% by mass) , 3.5% by mass (3.6% by mass) is shown. In Comparative Example 6, since the content of the water-swellable inorganic polymer was small and the shrinkage force was weak, there was no fixing force for correcting the skin. In Comparative Example 7, the content of the water-swellable inorganic polymer is increased, and in addition, the content of the natural polymer is also large, and relative to the content of the water-swellable inorganic polymer and the content of the natural polymer, In particular, the composition had a low content of polyether-modified silicon, a high viscosity, a strong adhesive force, and a strong stickiness, and became unusable due to clogging of the spray nozzle.
比較例8と9は、組成物全体に対するポリエーテル変性シリコンの含有量が0.5質量%未満(0.4質量%)である場合と、3.0質量%を超えた(3.1質量%)場合を示す。比較例8は、固着形成された皮膜に柔軟性が乏しく、途中で破断して持続力が無く、スプレー噴射口に一定の目詰りが発生した。比較例9は、柔軟性があるものの固着皮膜の収縮力が弱くなるためにたるみなど引き締め効果が極めて低かった。 In Comparative Examples 8 and 9, the content of the polyether-modified silicon relative to the whole composition was less than 0.5% by mass (0.4% by mass), and exceeded 3.0% by mass (3.1% by mass). %) Indicates the case. In Comparative Example 8, the film formed in a fixed manner was poor in flexibility, fractured in the middle and lacked sustainability, and constant clogging occurred in the spray nozzle. Although Comparative Example 9 was flexible, the effect of tightening such as sagging was extremely low because the shrinkage force of the fixing film was weak.
比較例10は、実施例4に対して解膠剤としてのピロリン酸ナトリウムを含有しない化粧組成物を示す。この場合には、ゲル粘度が製造時に急激に増大して製造自体が困難であった。比較例11は、実施例4と比べて水膨潤性無機高分子(ヘクトライトとシリカの組み合わせ)の含有量が6.0質量%を超えた化粧組成物を示す。この場合には、粘度が高くなり、スプレーから噴射されるミストが荒く、顔の一部分に過剰に塗着されて均一の皮膜にならず表情の動きに追随できなくて破断が起き、被膜の持続性に問題が発生した。比較例12は、実施例4と比べてポリエーテル変性シリコンの含有量が5.0質量%を超えた化粧組成物を示す。この場合には、スプレーから均一に噴射され、過剰に塗着されるなどの問題はなかったが皮膜が柔軟すぎて引き締め効果が発揮できなかった。 Comparative Example 10 shows a cosmetic composition that does not contain sodium pyrophosphate as a peptizer for Example 4. In this case, the gel viscosity suddenly increased during production, and the production itself was difficult. Comparative Example 11 shows a cosmetic composition in which the content of the water-swellable inorganic polymer (combination of hectorite and silica) exceeds 6.0% by mass compared to Example 4. In this case, the viscosity becomes high, the mist sprayed from the spray is rough, it is excessively applied to a part of the face, it does not become a uniform film, it cannot follow the movement of facial expressions, breaks, and the film continues There was a problem with sex. Comparative Example 12 shows a cosmetic composition in which the content of polyether-modified silicon exceeds 5.0% by mass as compared with Example 4. In this case, there was no problem of being sprayed uniformly from the spray and being applied excessively, but the film was too flexible to exhibit the tightening effect.
また、表−2におけるスプレー噴射口の目詰り試験において、ポリエーテル変性シリコンを含有した実施例1〜3の化粧用組成物と、ピロリン酸ナトリウムを含有した実施例4の化粧組成物は、常温保管、恒温45℃保管ともに約1ヶ月後の使い切りまで各30本全てに目詰まりも無く噴霧状態も良好であった。しかし、ポリエーテル変性シリコンを含有しない比較例1〜3の組成物は、常温保管において、いずれも試験開始2日後〜10日後までに目詰りや噴霧状態のバラツキを生じるものが続出してその後の継続試験が出来なかった。また、比較例1〜3の化粧組成物は、恒温45℃で保管した場合、試験開始1日後〜5日後までに目詰りや噴霧状態のバラツキが続出したため、その後の継続試験が出来なかった。一方、比較例4,6,9は、スプレー噴射口の目詰りにおいては優れているが皮膚を引き締めて持続させる効果はまったく期待できず、比較例5、7、8においてはスプレー組成物に適さないことが判った。 Moreover, in the clogging test of the spray nozzle in Table 2, the cosmetic compositions of Examples 1 to 3 containing polyether-modified silicon and the cosmetic composition of Example 4 containing sodium pyrophosphate were In both storage and storage at a constant temperature of 45 ° C., all 30 bottles were not clogged and were well sprayed until they were used up after about one month. However, the compositions of Comparative Examples 1 to 3 that do not contain polyether-modified silicon are continuously clogged or sprayed in 2 days to 10 days after the start of the test at room temperature storage. The continuation test was not possible. In addition, when the cosmetic compositions of Comparative Examples 1 to 3 were stored at a constant temperature of 45 ° C., clogging and spraying variations continued from 1 day to 5 days after the start of the test, and thus a subsequent continuous test could not be performed. On the other hand, Comparative Examples 4, 6, and 9 are excellent in clogging the spray nozzle, but cannot be expected to have any effect of tightening and sustaining the skin. In Comparative Examples 5, 7, and 8, they are suitable for the spray composition. I found that there was no.
尚、比較例10は、製造自体が困難を極めたために、試験ができなかった。比較例11は、開始1日後から目詰りや噴霧状態のバラツキが続出したため、その後の継続試験が出来なかった。比較例12は、スプレー噴射口の目詰り防止においては優れているが皮膚を引き締めて持続させる効果はまったく期待できず、スプレー組成物に適さないことが判った。従って、実施例1〜4の化粧組成物は、スプレー噴射口の目詰まりも無く、かつ持続して使用できる点において比較例1〜3、比較例4〜9、比較例10〜12よりも顕著に優れることが判明した。 Note that Comparative Example 10 could not be tested because the production itself was extremely difficult. In Comparative Example 11, since subsequent clogging and spray state variation continued one day after the start, a subsequent continuation test could not be performed. Comparative Example 12 was excellent in preventing clogging of the spray nozzle, but was not expected to have an effect of tightening and maintaining the skin at all, and was found to be unsuitable for a spray composition. Therefore, the cosmetic compositions of Examples 1 to 4 are more conspicuous than Comparative Examples 1 to 3, Comparative Examples 4 to 9, and Comparative Examples 10 to 12 in that the spray composition is not clogged and can be used continuously. It turned out to be excellent.
即ち、上記表−1及び表−2の試験結果により、本発明の化粧組成物における必須成分の好適な含有量は、実施例1〜3に示すピロリン酸ナトリウム等の解膠剤を含まない場合において、天然高分子が0.5〜3.0質量%(更に好適な含有量は、実施例1及び2に示す1.5〜3.0質量%)、水膨潤性無機高分子(ケイ酸塩+シリカ)が0.5〜3.5質量%(更に好適な合計含有量は、実施例1〜3に示す1.0〜3.0質量%)、ポリエーテル変性シリコンが0.5〜3.0質量%(更に好適な含有量は、実施例1〜3に示す0.5〜1.0質量%)と言える。一方、本発明の化粧組成物における必須成分の好適な含有量は、実施例4の解膠剤(ピロリン酸ナトリウム)を含む場合において、天然高分子が0〜3.0質量%、水膨潤性無機高分子(ケイ酸塩+シリカ)が0.5〜6.0質量%、ポリエーテル変性シリコンが0.5〜5.0質量%、ピロリン酸ナトリウムが水膨潤性無機高分子の総量に対して0.01質量%〜5.0質量%程度と言える。また、最も好適な含有量は、3時間から6時間経過後の結果が最も良い表−1の実施例4(天然高分子が3.0質量%、水膨潤性無機高分子(ケイ酸塩+シリカ)が5.5質量%、ポリエーテル変性シリコンが3.0質量%、ピロリン酸ナトリウムが水膨潤性無機高分子の総量に対して0.1質量%)に示す含有量であるといえる。 That is, according to the test results in Tables 1 and 2 above, the preferred content of the essential components in the cosmetic composition of the present invention does not include a peptizer such as sodium pyrophosphate shown in Examples 1 to 3. , The natural polymer is 0.5 to 3.0% by mass (the more preferable content is 1.5 to 3.0% by mass shown in Examples 1 and 2), the water-swellable inorganic polymer (silicic acid) Salt + silica) is 0.5 to 3.5% by mass (a more preferable total content is 1.0 to 3.0% by mass shown in Examples 1 to 3 ), and polyether-modified silicon is 0.5 to 3.5% by mass. It can be said that the content is 3.0% by mass (more preferable content is 0.5 to 1.0% by mass shown in Examples 1 to 3 ). On the other hand, the preferred content of the essential component in the cosmetic composition of the present invention is 0 to 3.0% by mass of the natural polymer when the peptizer (sodium pyrophosphate) of Example 4 is included, and water swellability. 0.5-6.0% by mass of inorganic polymer (silicate + silica), 0.5-5.0% by mass of polyether-modified silicon, and sodium pyrophosphate based on the total amount of water-swellable inorganic polymer It can be said that it is about 0.01 mass%-5.0 mass%. In addition, the most preferable content is the result of Example 4 in Table 1 with the best results after 3 to 6 hours (3.0% by mass of natural polymer, water-swellable inorganic polymer (silicate + (Silica) is 5.5% by mass, polyether-modified silicon is 3.0% by mass, and sodium pyrophosphate is 0.1% by mass based on the total amount of the water-swellable inorganic polymer.
尚、本発明のスプレー用化粧組成物とこれを利用したスプレーによるメイクアップ方法によれば、従来の視覚的効果を利用した塗りファンデーションの塗り方でしわなどを隠すメイクアップ方法では不可能であった、加齢によって生じた皮膚のたるみや顔の輪郭の緩みを従来のファンデーションを使用した上からでも非接触のスプレー噴霧による方法で塗布することができ、顔の皮膚を引き締めることでたるみや皮膚の凹凸などを隠すメイクアップが可能であり、若々しい頃のように引き締まった顔の表情を演出することが可能である。尚、本発明は、顔のみならず、首筋や顎の下、手指などにも使用できる。 In addition, according to the cosmetic composition for spray of the present invention and the makeup method using a spray using the same, it is impossible with the conventional makeup method that hides wrinkles and the like by applying the foundation using a visual effect. In addition, it is possible to apply the sagging of the skin caused by aging and the loosening of the contour of the face even by using a conventional foundation by the method of non-contact spray spraying, and sagging and skin by tightening the facial skin It is possible to make up makeup that hides the unevenness of the face, and to produce a tight facial expression as youthful. The present invention can be used not only on the face but also on the neck, chin, fingers, and the like.
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