JP5450385B2 - 高い流体遮断特性を有するポリアミド材料 - Google Patents
高い流体遮断特性を有するポリアミド材料 Download PDFInfo
- Publication number
- JP5450385B2 JP5450385B2 JP2010504693A JP2010504693A JP5450385B2 JP 5450385 B2 JP5450385 B2 JP 5450385B2 JP 2010504693 A JP2010504693 A JP 2010504693A JP 2010504693 A JP2010504693 A JP 2010504693A JP 5450385 B2 JP5450385 B2 JP 5450385B2
- Authority
- JP
- Japan
- Prior art keywords
- polyamide
- polyolefin
- composition
- weight
- compatibilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004952 Polyamide Substances 0.000 title claims description 64
- 229920002647 polyamide Polymers 0.000 title claims description 64
- 239000000463 material Substances 0.000 title claims description 26
- 239000012530 fluid Substances 0.000 title claims description 21
- 230000004888 barrier function Effects 0.000 title claims description 8
- 239000000203 mixture Substances 0.000 claims description 55
- 229920000098 polyolefin Polymers 0.000 claims description 41
- 239000011159 matrix material Substances 0.000 claims description 20
- 229920003986 novolac Polymers 0.000 claims description 20
- -1 polyethylene Polymers 0.000 claims description 19
- 125000000524 functional group Chemical group 0.000 claims description 13
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 5
- 238000001746 injection moulding Methods 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 125000003700 epoxy group Chemical group 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 229920001195 polyisoprene Polymers 0.000 claims description 3
- 229920000306 polymethylpentene Polymers 0.000 claims description 3
- 239000011116 polymethylpentene Substances 0.000 claims description 3
- HPNSNYBUADCFDR-UHFFFAOYSA-N chromafenozide Chemical compound CC1=CC(C)=CC(C(=O)N(NC(=O)C=2C(=C3CCCOC3=CC=2)C)C(C)(C)C)=C1 HPNSNYBUADCFDR-UHFFFAOYSA-N 0.000 claims 1
- 239000010410 layer Substances 0.000 description 21
- 229920003023 plastic Polymers 0.000 description 11
- 239000004033 plastic Substances 0.000 description 11
- 229920002292 Nylon 6 Polymers 0.000 description 8
- 229920001903 high density polyethylene Polymers 0.000 description 8
- 230000035699 permeability Effects 0.000 description 8
- 239000004700 high-density polyethylene Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 5
- 229920001169 thermoplastic Polymers 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 229920000299 Nylon 12 Polymers 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 208000016261 weight loss Diseases 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical group O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 229920002302 Nylon 6,6 Polymers 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
- 238000010101 extrusion blow moulding Methods 0.000 description 3
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 3
- 238000006068 polycondensation reaction Methods 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004609 Impact Modifier Substances 0.000 description 2
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 239000004734 Polyphenylene sulfide Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000010102 injection blow moulding Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 150000003951 lactams Chemical class 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229920000069 polyphenylene sulfide Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 239000004953 Aliphatic polyamide Substances 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 241000288673 Chiroptera Species 0.000 description 1
- 229920003261 Durez Polymers 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 101000576320 Homo sapiens Max-binding protein MNT Proteins 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229940123973 Oxygen scavenger Drugs 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004954 Polyphthalamide Substances 0.000 description 1
- 229920006121 Polyxylylene adipamide Polymers 0.000 description 1
- 229920003182 Surlyn® Polymers 0.000 description 1
- 239000005035 Surlyn® Substances 0.000 description 1
- 239000004958 Technyl Substances 0.000 description 1
- 229920006096 Technyl® Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229920003231 aliphatic polyamide Polymers 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 229920006020 amorphous polyamide Polymers 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- UBAZGMLMVVQSCD-UHFFFAOYSA-N carbon dioxide;molecular oxygen Chemical compound O=O.O=C=O UBAZGMLMVVQSCD-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 description 1
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000000138 intercalating agent Substances 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920006375 polyphtalamide Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229920006012 semi-aromatic polyamide Polymers 0.000 description 1
- 229920006114 semi-crystalline semi-aromatic polyamide Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 150000003739 xylenols Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
- Y10T428/3175—Next to addition polymer from unsaturated monomer[s]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Description
(a)ポリアミドマトリックス;
(b)ノボラック樹脂;
(c)前記ポリアミドとの相容性を改善するための官能基を含まないポリオレフィン;及び
(d)前記ポリオレフィンと前記ポリアミドとの間の相容化のための添加剤(以下、「相容化剤」と言う)。
C=dc(d−da)/d(dc−da)
(ここで、Cは結晶度、dは測定された密度、daは非晶質相の密度、dcは所定温度における結晶相の密度である。)
・0.94〜0.97g/cm3の範囲の密度;
・450000〜4000000g/モルの範囲の分子量;
・0.1〜25g/10mmの範囲のISO規格1133(190℃、2.16kg)に従って測定したメルトフローインデックス(MFI);
・60〜80%の範囲の結晶度。
・PA−6:RHODIA社から入手したTECHNYL S 40(硫酸中で測定して粘度4);
・高密度ポリエチレン(HDPE):POLIMERI EUROPA社から入手したEraclene BB 76;
・ノボラック:RHEIN CHEMIE社から入手したRhenosin PR 95;
・PA−12:市販のパイプ;
・EVOH:NIPPON GOHSEI社から入手したSoarnol D2908;
・無水マレイン酸をグラフトさせた高密度ポリエチレン(HDPE):Chemtura社から入手したPolybond 3009。
・押出機の温度:230℃
・スクリュー速度:8rpm
・モータートルク:4.7アンペア
・押出出口圧力:2000psi(ポンド/平方インチ)
・真空:−0.2バール
Claims (23)
- ポリアミドマトリックスの流体に対する不透過性を高めるための、ノボラック樹脂、ポリアミドに対する相容性を改善するための官能基を含まないポリオレフィン及び該ポリオレフィンとポリアミドとの間の相容化剤の使用。
- (a)ポリアミドマトリックス;
(b)ノボラック樹脂;
(c)前記ポリアミドに対する相容性を改善するための官能基を含まないポリオレフィン5〜30重量%;
(d)前記ポリオレフィンと前記ポリアミドとの間の相容化剤:
を含むポリアミド組成物の形での、請求項1に記載の使用。 - 前記組成物がノボラック樹脂(b)を0.1〜20重量%含むことを特徴とする、請求項2に記載の使用。
- 前記ポリオレフィン(c)が0.910〜0.97g/cm 3 の範囲の密度を有することを特徴とする、請求項2又は3に記載の使用。
- 前記ポリオレフィン(c)がポリエチレン、ポリプロピレン、ポリイソブチレン、ポリメチルペンテン、ポリイソプレン、並びにそれらのブレンド及び/又はコポリマーを含む群から選択されることを特徴とする、請求項2〜4のいずれかに記載の使用。
- 前記相容化剤(d)が少なくともポリオレフィン鎖とポリアミドに対する相容性を改善するための官能基とを含む化合物であることを特徴とする、請求項2〜5のいずれかに記載の使用。
- 前記官能基が無水マレイン酸、カルボン酸、エステル、アクリル酸、メタクリル酸及びエポキシ基を含む群から選択されることを特徴とする、請求項6に記載の使用。
- 組成物の総重量に対して2〜20重量%の相容化剤(d)を含むことを特徴とする、請求項2〜7のいずれかに記載の使用。
- 前記ポリオレフィン(c)の重量に対して少なくとも30重量%の相容化剤(d)を含むことを特徴とする、請求項2〜7のいずれかに記載の使用。
- (a)ポリアミドマトリックス;
(b)ノボラック樹脂;
(c)前記ポリアミドに対する相容性を改善するための官能基を含まないポリオレフィン5〜30重量%;
(d)前記ポリオレフィンと前記ポリアミドとの間の相容化剤:
を含み、高い流体遮断特性を有するポリアミド組成物であって、流体を入れること又は輸送することが意図される物品の製造に用いるための、前記組成物。 - ノボラック樹脂(b)を0.1〜20重量%含むことを特徴とする、請求項10に記載の組成物。
- 前記ポリオレフィン(c)が0.910〜0.97g/cm3の範囲の密度を有することを特徴とする、請求項10又は11に記載の組成物。
- 前記ポリオレフィン(c)がポリエチレン、ポリプロピレン、ポリイソブチレン、ポリメチルペンテン、ポリイソプレン、並びにそれらのブレンド及び/又はコポリマーを含む群から選択されることを特徴とする、請求項10〜12のいずれかに記載の組成物。
- 前記相容化剤(d)が少なくともポリオレフィン鎖とポリアミドに対する相容性を改善するための官能基とを含む化合物であることを特徴とする、請求項10〜13のいずれかに記載の組成物。
- 前記官能基が無水マレイン酸、カルボン酸、エステル、アクリル酸、メタクリル酸及びエポキシ基を含む群から選択されることを特徴とする、請求項14に記載の組成物。
- 組成物の総重量に対して2〜20重量%の相容化剤(d)を含むことを特徴とする、請求項10〜15のいずれかに記載の組成物。
- 前記ポリオレフィン(c)の重量に対して少なくとも30重量%の相容化剤(d)を含むことを特徴とする、請求項10〜15のいずれかに記載の組成物。
- ノボラック樹脂、ポリアミドに対する相容性を改善するための官能基を含まないポリオレフィン及び該ポリオレフィンとポリアミドとの間の相容化剤を含む、ポリアミドマトリックスの流体不透過性向上剤。
- 成分がポリアミドマトリックスに一緒に又は別々に添加されることを特徴とする、請求項18に記載の流体不透過性向上剤。
- 請求項10〜17のいずれかに記載の組成物を押出、型成形又は射出成形の内の少なくとも1の加工技術によって成形することによって得られた物品であって、流体を入れること又は輸送することが意図される、前記物品。
- 請求項10〜17のいずれかに記載の組成物から作られた少なくとも1の材料を含む複合物品であって、流体を入れること又は輸送することが意図される、前記複合物品。
- 少なくとも1つの層が請求項10〜17のいずれかに記載の組成物から成る多層物品であることを特徴とする、請求項21に記載の複合物品。
- 少なくとも1つの層が請求項10〜17のいずれかに記載の組成物から成ること、及び少なくとも1つの層がポリオレフィンを含む組成物から得られたことを特徴とする、請求項22に記載の多層複合物品。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0703069 | 2007-04-27 | ||
FR0703069A FR2915484B1 (fr) | 2007-04-27 | 2007-04-27 | Materiau polyamide a proprietes barrieres aux fluides elevees. |
PCT/EP2008/055018 WO2008135401A1 (fr) | 2007-04-27 | 2008-04-24 | Materiau polyamide a proprietes barrieres aux fluides elevees |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010534725A JP2010534725A (ja) | 2010-11-11 |
JP5450385B2 true JP5450385B2 (ja) | 2014-03-26 |
Family
ID=38689175
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010504693A Active JP5450385B2 (ja) | 2007-04-27 | 2008-04-24 | 高い流体遮断特性を有するポリアミド材料 |
Country Status (9)
Country | Link |
---|---|
US (1) | US20100151173A1 (ja) |
EP (1) | EP2139949B1 (ja) |
JP (1) | JP5450385B2 (ja) |
KR (2) | KR20120115557A (ja) |
CN (1) | CN101675112B (ja) |
BR (1) | BRPI0809776B1 (ja) |
CA (1) | CA2685545A1 (ja) |
FR (1) | FR2915484B1 (ja) |
WO (1) | WO2008135401A1 (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2921069B1 (fr) * | 2007-09-18 | 2010-07-30 | Rhodia Operations | Composition polyamide |
FR2960545B1 (fr) * | 2010-05-28 | 2014-11-28 | Rhodia Operations | Polyamide modifie sulfonate aux proprietes barrieres ameliorees |
FR2973731A1 (fr) | 2011-04-11 | 2012-10-12 | Rhodia Operations | Procede de fabrication de reservoirs a proprietes barrieres elevees aux fluides |
FR2974028B1 (fr) * | 2011-04-14 | 2013-04-19 | Arkema France | Structure multicouche comprenant une couche d'un copolyamide particulier et une couche barriere |
CN103665843B (zh) * | 2013-11-26 | 2016-06-22 | 沃太能源南通有限公司 | 一种防渗透的用于复合燃油箱的尼龙材料的制备方法 |
US9494454B2 (en) | 2013-12-06 | 2016-11-15 | Joseph Baumoel | Phase controlled variable angle ultrasonic flow meter |
US9752907B2 (en) | 2015-04-14 | 2017-09-05 | Joseph Baumoel | Phase controlled variable angle ultrasonic flow meter |
WO2018011291A1 (en) * | 2016-07-13 | 2018-01-18 | Rhodia Operations | Method for increasing resistance to halogen-containing oxidizing agents of a polyamide composition |
CN111718578A (zh) * | 2020-06-30 | 2020-09-29 | 重庆科聚孚工程塑料有限责任公司 | 一种乙醇汽油油箱用聚酰胺6复合材料及其制备方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4174358A (en) * | 1975-05-23 | 1979-11-13 | E. I. Du Pont De Nemours And Company | Tough thermoplastic nylon compositions |
JPS6361050A (ja) * | 1986-09-02 | 1988-03-17 | Nissan Motor Co Ltd | プラスチツク成形材料 |
US5049615A (en) * | 1989-12-11 | 1991-09-17 | Hercules Incorporated | Polyindanes as processing aid for engineering thermoplastics |
ES2121924T3 (es) * | 1993-01-07 | 1998-12-16 | Bayer Ag | Masas moldeables de poliamida poco inflamables. |
EP0643105A1 (en) * | 1993-09-01 | 1995-03-15 | MITSUI TOATSU CHEMICALS, Inc. | Polyimide based resin composition |
US5443867A (en) * | 1993-10-25 | 1995-08-22 | E. I. Du Pont De Nemours And Company | Articles incorporating barrier resins |
JPH07150034A (ja) * | 1993-12-02 | 1995-06-13 | Showa Denko Kk | ポリアミド樹脂組成物 |
JPH10140004A (ja) * | 1996-11-05 | 1998-05-26 | Daicel Huels Ltd | 高分子感温体用樹脂組成物および高分子感温体 |
DE60012470T2 (de) * | 2000-02-07 | 2005-09-15 | Ti Automotive Technology Center Gmbh | Mehrschichtkraftstoffbehälter |
US20050069662A1 (en) * | 2003-05-21 | 2005-03-31 | Cheng Paul P. | Articles made from polyamide resin compositions and having improved fluid permeation barrier properties |
US20050272855A1 (en) * | 2004-03-30 | 2005-12-08 | Andreas Renken | Process for coating vehicle exterior parts made from electrically conductive polyamide resin compositions |
-
2007
- 2007-04-27 FR FR0703069A patent/FR2915484B1/fr not_active Expired - Fee Related
-
2008
- 2008-04-24 US US12/597,083 patent/US20100151173A1/en not_active Abandoned
- 2008-04-24 EP EP08736550.8A patent/EP2139949B1/fr active Active
- 2008-04-24 CN CN200880013773.6A patent/CN101675112B/zh active Active
- 2008-04-24 BR BRPI0809776A patent/BRPI0809776B1/pt active IP Right Grant
- 2008-04-24 CA CA 2685545 patent/CA2685545A1/fr not_active Abandoned
- 2008-04-24 WO PCT/EP2008/055018 patent/WO2008135401A1/fr active Application Filing
- 2008-04-24 KR KR1020127022658A patent/KR20120115557A/ko not_active Application Discontinuation
- 2008-04-24 JP JP2010504693A patent/JP5450385B2/ja active Active
- 2008-04-24 KR KR1020097022314A patent/KR101203026B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
CN101675112B (zh) | 2015-11-25 |
JP2010534725A (ja) | 2010-11-11 |
WO2008135401A1 (fr) | 2008-11-13 |
KR101203026B1 (ko) | 2012-11-20 |
BRPI0809776B1 (pt) | 2018-08-28 |
US20100151173A1 (en) | 2010-06-17 |
BRPI0809776A2 (pt) | 2014-10-07 |
EP2139949A1 (fr) | 2010-01-06 |
FR2915484A1 (fr) | 2008-10-31 |
FR2915484B1 (fr) | 2012-10-12 |
KR20120115557A (ko) | 2012-10-18 |
CA2685545A1 (fr) | 2008-11-13 |
KR20090123979A (ko) | 2009-12-02 |
CN101675112A (zh) | 2010-03-17 |
EP2139949B1 (fr) | 2018-04-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5450385B2 (ja) | 高い流体遮断特性を有するポリアミド材料 | |
KR100855888B1 (ko) | Evoh 층을 포함하는, 2층 이상의 복합체 | |
US8273431B2 (en) | Polyamide resin composition | |
US10016962B2 (en) | Multilayer structure | |
JP6921867B2 (ja) | 樹脂組成物及びその用途 | |
US10364351B2 (en) | Process for the manufacture of tanks having high barrier properties toward fluids | |
US20100282746A1 (en) | Low Organic Vapor Permeation Resin Composition | |
US20230193025A1 (en) | Multilayer structure based on recycled polyamide | |
US8062725B2 (en) | Low organic vapor permeation resin | |
JP6997669B2 (ja) | 複層ペレット、及び容器の製造方法 | |
KR102329828B1 (ko) | 폴리아미드 수지 조성물 및 이로부터 제조된 성형품 | |
AU2012216788B2 (en) | Polyamide resin composition | |
JPH0387254A (ja) | ガスバリヤー性積層体 | |
KR102691586B1 (ko) | 높은 Tg 를 갖는 MXDT/XT 코폴리아미드로 제조된 배리어 구조체 | |
JP6661914B2 (ja) | ポリアミド樹脂組成物、成形品および成形品の製造方法 | |
JP3169280B2 (ja) | バッグインボックス用内容器 | |
JPS62138228A (ja) | 複層中空成形容器の製造法 | |
JPH06190978A (ja) | 積層構造体 | |
JPH09187902A (ja) | 多層成形物 | |
JPH0289643A (ja) | 積層包装材料 | |
TW201425422A (zh) | 聚乙烯系結構體 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20120313 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120417 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20120717 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20120724 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121017 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130709 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20131007 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20131203 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20131225 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5450385 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |