JP5432424B2 - ガス拡散電極に有用な修飾炭素材料 - Google Patents

ガス拡散電極に有用な修飾炭素材料 Download PDF

Info

Publication number
JP5432424B2
JP5432424B2 JP2001530134A JP2001530134A JP5432424B2 JP 5432424 B2 JP5432424 B2 JP 5432424B2 JP 2001530134 A JP2001530134 A JP 2001530134A JP 2001530134 A JP2001530134 A JP 2001530134A JP 5432424 B2 JP5432424 B2 JP 5432424B2
Authority
JP
Japan
Prior art keywords
carbon
group
carbon material
organic group
modified carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2001530134A
Other languages
English (en)
Japanese (ja)
Other versions
JP2003515872A (ja
JP2003515872A5 (https=
Inventor
コスバシュ，ローラン
ユ，ユアン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cabot Corp
Original Assignee
Cabot Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cabot Corp filed Critical Cabot Corp
Publication of JP2003515872A publication Critical patent/JP2003515872A/ja
Publication of JP2003515872A5 publication Critical patent/JP2003515872A5/ja
Application granted granted Critical
Publication of JP5432424B2 publication Critical patent/JP5432424B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44—Carbon
    • C09C1/48—Carbon black
    • C09C1/56—Treatment of carbon black ; Purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/96—Carbon-based electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2998—Coated including synthetic resin or polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Inert Electrodes (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Carbon And Carbon Compounds (AREA)
JP2001530134A 1999-10-12 2000-10-10 ガス拡散電極に有用な修飾炭素材料 Expired - Fee Related JP5432424B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/416,088 US6399202B1 (en) 1999-10-12 1999-10-12 Modified carbon products useful in gas diffusion electrodes
US09/416,088 1999-10-12
PCT/US2000/028008 WO2001028015A1 (en) 1999-10-12 2000-10-10 Modified carbon products useful in gas diffusion electrodes

Publications (3)

Publication Number Publication Date
JP2003515872A JP2003515872A (ja) 2003-05-07
JP2003515872A5 JP2003515872A5 (https=) 2007-11-29
JP5432424B2 true JP5432424B2 (ja) 2014-03-05

Family

ID=23648484

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001530134A Expired - Fee Related JP5432424B2 (ja) 1999-10-12 2000-10-10 ガス拡散電極に有用な修飾炭素材料

Country Status (8)

Country Link
US (1) US6399202B1 (https=)
EP (1) EP1226616A1 (https=)
JP (1) JP5432424B2 (https=)
KR (1) KR100772257B1 (https=)
CN (1) CN1208863C (https=)
AU (1) AU8007500A (https=)
CA (1) CA2387019C (https=)
WO (1) WO2001028015A1 (https=)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6818339B1 (en) * 1999-08-27 2004-11-16 Matsushita Electric Industrial Co., Ltd. Polymer electrolyte type fuel cell
US6280871B1 (en) * 1999-10-12 2001-08-28 Cabot Corporation Gas diffusion electrodes containing modified carbon products
US20030031917A1 (en) * 2000-12-28 2003-02-13 Kenji Katori Gas diffusive electrode, electroconductive ion conductor, their manufacturing method, and electrochemical device
US7541308B2 (en) * 2001-04-11 2009-06-02 Cabot Corporation Fuel cells and other products containing modified carbon products
US20020192537A1 (en) * 2001-06-15 2002-12-19 Xiaoming Ren Metallic layer component for use in a direct oxidation fuel cell
EP1298745B1 (en) * 2001-09-28 2010-04-21 Panasonic Corporation Polymer electrolyte fuel cell
US6926990B2 (en) * 2002-08-29 2005-08-09 Motorola, Inc. Fuel cell having porous electrodes and method for forming same
US6746982B2 (en) * 2001-12-27 2004-06-08 Utc Fuel Cells, Llc Porous carbon body for a fuel cell having an electronically conductive hydrophilic agent
US7144476B2 (en) * 2002-04-12 2006-12-05 Sgl Carbon Ag Carbon fiber electrode substrate for electrochemical cells
US7241334B2 (en) * 2002-05-23 2007-07-10 Columbian Chemicals Company Sulfonated carbonaceous materials
US7390441B2 (en) * 2002-05-23 2008-06-24 Columbian Chemicals Company Sulfonated conducting polymer-grafted carbon material for fuel cell applications
CA2486790A1 (en) 2002-05-23 2003-12-04 Columbian Chemicals Company Sulfonated conducting polymer-grafted carbon material for fuel cell applications
US7459103B2 (en) 2002-05-23 2008-12-02 Columbian Chemicals Company Conducting polymer-grafted carbon material for fuel cell applications
WO2003100883A2 (en) * 2002-05-23 2003-12-04 Columbian Chemicals Company Conducting polymer-grafted carbon material for fuel cell applications
US7195834B2 (en) * 2002-05-23 2007-03-27 Columbian Chemicals Company Metallized conducting polymer-grafted carbon material and method for making
JP2004079420A (ja) * 2002-08-21 2004-03-11 Canon Inc 導電性炭素、これを用いた燃料電池用の電極触媒、燃料電池セルおよび燃料電池
US20040062980A1 (en) * 2002-09-30 2004-04-01 Xiaoming Ren Fluid management component for use in a fuel cell
JP2004265638A (ja) * 2003-02-25 2004-09-24 Ebara Corp 混合伝導カーボンおよび電極
US7348081B2 (en) * 2003-05-30 2008-03-25 Mti Microfuel Cells Inc. Fuel efficient membrane electrode assembly
US20050026012A1 (en) * 2003-07-28 2005-02-03 O'hara Jeanette E. Diffusion media tailored to account for variations in operating humidity and devices incorporating the same
KR100696462B1 (ko) * 2003-09-26 2007-03-19 삼성에스디아이 주식회사 연료전지용 전극 확산층
US7732372B2 (en) * 2003-11-26 2010-06-08 Cabot Corporation Particulate absorbent materials
JP2007535787A (ja) * 2004-03-15 2007-12-06 キャボット　コーポレイション 修飾炭素生成物、燃料電池および類似の装置における修飾炭素生成物の使用、および修飾炭素生成物に関する方法
US20070280876A1 (en) * 2004-03-25 2007-12-06 William Marsh Rice University Functionalization of Carbon Nanotubes in Acidic Media
US20060068987A1 (en) * 2004-09-24 2006-03-30 Srinivas Bollepalli Carbon supported catalyst having reduced water retention
US7282466B2 (en) * 2004-10-04 2007-10-16 The United States Of America As Represented By The Secretary Of The Navy Sulfur-functionalized carbon nanoarchitectures as porous, high-surface-area supports for precious metal catalysts
PL372678A1 (pl) * 2005-02-08 2006-08-21 Politechnika Poznańska Wtórne ogniwo wodór-powietrze
KR100813240B1 (ko) 2005-02-18 2008-03-13 삼성에스디아이 주식회사 유기 전해액 및 이를 채용한 리튬 전지
JP5057261B2 (ja) * 2005-10-25 2012-10-24 東海カーボン株式会社 カーボンブラック水性分散体及びその製造方法
US7554815B2 (en) * 2006-05-31 2009-06-30 Hewlett-Packard Development Company, L.P. Resilient clip for circuit board
EP2099869B1 (en) 2006-10-31 2013-05-01 Sensient Colors Inc. Modified pigments and methods for making and using the same
JP5121290B2 (ja) * 2007-04-17 2013-01-16 新日鐵住金株式会社 固体高分子形燃料電池電極用触媒
EP2201072B1 (en) 2007-08-23 2018-11-14 Sensient Colors LLC Self-dispersed pigments and methods for making and using the same
US8022238B2 (en) * 2009-03-20 2011-09-20 E. I. Du Pont De Nemours And Company Phosphate surfactants
JP2012523479A (ja) 2009-04-07 2012-10-04 センシエント カラーズ エルエルシー 自己分散性粒子並びにその製造方法及び使用方法
JP5940153B2 (ja) * 2011-07-22 2016-06-29 キャボット コーポレイションＣａｂｏｔ Ｃｏｒｐｏｒａｔｉｏｎ 特殊なパーコレーション挙動を有する高抵抗コーティング組成物ならびにそれを含む静電画像現像システムおよびその部品
US20130288006A1 (en) 2012-04-26 2013-10-31 Anna C. Greene Laser-engraveable elements and method of use
WO2014098917A1 (en) * 2012-12-23 2014-06-26 United Technologies Corporation Carbon electrode and method therefor
FR3031917A1 (fr) * 2015-01-22 2016-07-29 Commissariat Energie Atomique Procede de greffage d'un substrat en carbone, et utilisation de ce substrat dans une pile a combustible
CN104730115A (zh) * 2015-02-09 2015-06-24 西南大学 基于仿生蜂窝碳气凝胶材料的新型生物及气体传感器
JP6548954B2 (ja) 2015-05-21 2019-07-24 株式会社東芝 還元触媒及び化学反応装置
CA2985660C (fr) 2015-05-27 2023-03-07 Hydro-Quebec Procede pour la protection de materiaux d'electrode contre l'humidite
CN107640756B (zh) * 2016-12-01 2020-01-07 中国石油化工股份有限公司 多介孔疏水碳气凝胶材料及其制备方法
CN106957095A (zh) * 2017-03-28 2017-07-18 上海大学 用于去除水中铜离子的复合改性活性炭电极及其制备方法
JP2019081667A (ja) * 2017-10-30 2019-05-30 旭化成株式会社 窒素含有炭素材料及びその製造方法、並びにそれを用いた燃料電池電極
JP7029420B2 (ja) * 2019-02-21 2022-03-03 株式会社東芝 二酸化炭素電解セル用電極触媒層、ならびにそれを具備する、電解セルおよび二酸化炭素電解用電解装置
CN110492124B (zh) * 2019-07-17 2020-11-13 珠海冠宇电池股份有限公司 一种高导电性疏水气体扩散层及其制备方法
CN110444769A (zh) * 2019-07-17 2019-11-12 珠海冠宇电池有限公司 一种高导电性超疏水气体扩散层及其制备方法
AU2023223827A1 (en) * 2022-02-28 2024-08-22 Idemitsu Kosan Co.,Ltd. Additive for carbon dioxide reduction catalysts, catalyst layer, cathode, ion exchange membrane-electrode assembly and solid electrolyte electrolysis device
CN119406727B (zh) * 2024-10-18 2025-11-07 武汉理工大学 一种具有亲疏水传输通道的气体扩散层及其制备方法

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57208073A (en) 1981-06-17 1982-12-21 Toshiba Corp Porous catalyst layer of air electrode
DE3411759C1 (de) * 1984-03-30 1985-04-25 Th. Goldschmidt Ag, 4300 Essen An ihrer Oberflaeche durch hydrophile und hydrophobe Gruppen modifizierte Teilchen
US4908198A (en) 1986-06-02 1990-03-13 The Electrosynthesis Company, Inc. Fluorinated carbons and methods of manufacture
US4877694A (en) * 1987-05-18 1989-10-31 Eltech Systems Corporation Gas diffusion electrode
DE3722019A1 (de) 1987-07-03 1989-01-12 Varta Batterie Verfahren zur herstellung einer kunststoffgebundenen gasdiffusionselektrode, die einen manganoxidkatalysator der ueberwiegenden zusammensetzung mno(pfeil abwaerts)2(pfeil abwaerts)o(pfeil abwaerts)3(pfeil abwaerts)* x mn(pfeil abwaerts)5(pfeil abwaerts)o(pfeil abwaerts)8(pfeil abwaerts) enthaelt
US4835074A (en) 1987-09-25 1989-05-30 The Electrosynthesis Company, Inc. Modified carbons and electrochemical cells containing the same
DE68922414T2 (de) 1988-02-05 1995-11-09 Nova Biomedical Corp Enzymelektrode.
JPH03188299A (ja) 1989-12-15 1991-08-16 Tanaka Kikinzoku Kogyo Kk 亜鉛合金電気めっき方法及びそれに使用するガス拡散電極装置
US5232561A (en) 1989-12-15 1993-08-03 Tanaka Kikinzoku Kogyo K.K. Electrolytic method of preparing compounds with a gas permeable electrode
US5302274A (en) 1990-04-16 1994-04-12 Minitech Co. Electrochemical gas sensor cells using three dimensional sensing electrodes
US5846670A (en) 1992-02-21 1998-12-08 Tanaka Kikinzoku Kogyo K.K. Gas diffusion electrode for electrochemical cell and process of preparing same
US5242765A (en) * 1992-06-23 1993-09-07 Luz Electric Fuel Israel Limited Gas diffusion electrodes
GB9301330D0 (en) 1993-01-23 1993-03-17 Johnson Matthey Plc Electrode
US5538608A (en) 1993-09-25 1996-07-23 Tanaka Kikinzoku Kogyo K.K. Bubble collection type gas electrode
BE1008455A3 (nl) 1994-06-07 1996-05-07 Vito Gasdiffusie elektrode met katalysator voor een elektrochemische cel met vast elektrolyt en werkwijze ter vervaardiging van dergelijke elektrode.
US5521020A (en) 1994-10-14 1996-05-28 Bcs Technology, Inc. Method for catalyzing a gas diffusion electrode
IL116379A (en) 1994-12-15 2003-12-10 Cabot Corp Aqueous inks and coatings containing modified carbon products
US5554739A (en) 1994-12-15 1996-09-10 Cabot Corporation Process for preparing carbon materials with diazonium salts and resultant carbon products
US5571311A (en) * 1994-12-15 1996-11-05 Cabot Corporation Ink jet ink formulations containing carbon black products
IL116377A (en) 1994-12-15 2003-05-29 Cabot Corp Reaction of carbon black with diazonium salts, resultant carbon black products and their uses
IL116376A (en) 1994-12-15 2001-03-19 Cabot Corp Aqueous ink jet ink compositions containing modified carbon products
JPH08250117A (ja) * 1995-03-09 1996-09-27 Shin Kobe Electric Mach Co Ltd リチウム二次電池負極用炭素材料及びその製造方法
JPH08283979A (ja) 1995-04-10 1996-10-29 Permelec Electrode Ltd ガス拡散電極とそれを使用する電解方法
PL178802B1 (pl) 1995-08-14 2000-06-30 Elton Aozt Kondensator dwuwarstwowy
JP2000510999A (ja) 1996-05-15 2000-08-22 ハイピリオン カタリシス インターナショナル インコーポレイテッド 電気化学キャパシターにおけるグラファイチックナノファイバー
US5707432A (en) * 1996-06-14 1998-01-13 Cabot Corporation Modified carbon products and inks and coatings containing modified carbon products
US5698016A (en) 1996-06-14 1997-12-16 Cabot Corporation Compositions of modified carbon products and amphiphilic ions and methods of using the same
US6110994A (en) 1996-06-14 2000-08-29 Cabot Corporation Polymeric products containing modified carbon products and methods of making and using the same
US5837045A (en) 1996-06-17 1998-11-17 Cabot Corporation Colored pigment and aqueous compositions containing same
US5783325A (en) * 1996-08-27 1998-07-21 The Research Foundation Of State Of New York Gas diffusion electrodes based on poly(vinylidene fluoride) carbon blends
ES2262311T3 (es) 1998-02-12 2006-11-16 Cabot Corporation Combinaciones polimericas conductoras con material conductor finamente dividido ubicado selectivamente en la fase polimerica continua o en la interfase continua.

Also Published As

Publication number Publication date
CN1208863C (zh) 2005-06-29
JP2003515872A (ja) 2003-05-07
US6399202B1 (en) 2002-06-04
CA2387019A1 (en) 2001-04-19
AU8007500A (en) 2001-04-23
KR20020048961A (ko) 2002-06-24
EP1226616A1 (en) 2002-07-31
WO2001028015A1 (en) 2001-04-19
CN1379917A (zh) 2002-11-13
KR100772257B1 (ko) 2007-11-01
CA2387019C (en) 2010-09-21

Similar Documents

Publication Publication Date Title
JP5432424B2 (ja) ガス拡散電極に有用な修飾炭素材料
US6280871B1 (en) Gas diffusion electrodes containing modified carbon products
JP4361738B2 (ja) 修飾炭素生成物を含む燃料電池及び他の生成物
EP0603175B1 (en) High utilization supported catalytic metal-containing gas-diffusion electrode, process for making it, and cells utilizing it
JP7368853B2 (ja) 多機能電極添加剤
US20030022055A1 (en) Fuel cells and other products containing modified carbon products
JP2003523056A (ja) 耐腐食性がほとんど無い炭素系成分を含むアノード構造
KR102303179B1 (ko) 전지 캐소드, 전지 캐소드 촉매층용 조성물 및 전지
JP7228942B1 (ja) 燃料電池用電極材料、並びにこれを使用した燃料電池用電極、膜電極接合体及び固体高分子形燃料電池
US4382904A (en) Electrode backing layer and method of preparing
CA1163768A (en) Electrode backing layer and method of preparing
AU8752291A (en) High utilization supported catalytic metal-containing gas-diffusion electrode, process for making it, and cells utilizing it

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20071010

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20071010

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20110414

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110426

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110726

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20120327

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20120627

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20130305

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20130704

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20130722

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130924

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20131031

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20131126

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20131206

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

Ref document number: 5432424

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees