JP5353340B2 - Manufacturing method of press-molded products - Google Patents

Description

The present invention relates to a method for producing a press-molded article, for example, hot press molded product of high strength, low, a method for manufacturing a press molded product for making the warm press molded product of medium strength.

  As part of reducing the weight of automobile bodies, research and development are ongoing to obtain molded products made of thin-walled steel that have the same or higher strength than conventional products. High-strength molded products can be broadly divided into (a) a technology for molding high-strength steel materials such as ultra-high tensile materials into a predetermined shape, and (b) a relatively soft steel material during or during molding. This is performed by a technique for increasing the strength by heat treatment later.

  When a high-strength steel material is formed into a predetermined shape as shown in (a) above, the shape that can be formed is greatly restricted, and a springback inevitably occurs after the forming process, resulting in the dimensions of the molded product. There is a problem that accuracy decreases.

  A so-called hot press molding is known as a technique for heat-treating a soft steel material during the molding process or after the molding process in the above item (b). Hot press molding is a technology that presses a steel material such as a steel plate to a high temperature and then presses it with a cooled die, and the molding and quenching are performed in a single process and constrained by the die. Since it is quenched, it has an excellent feature that a molded product with good dimensional accuracy can be obtained.

  However, in a technique such as hot press forming in which a steel material is heat-treated at the time of molding, a scale (steel oxide) is inevitably formed on the surface of the molded product by the heat treatment. The scale formed on the surface of the molded product is easy to peel off from the base material, causing damage to the press mold, or inducing the peeling of the coating film on the hot press-molded product after coating and the resulting decrease in corrosion resistance. . For this reason, when manufacturing hot press-formed products, the atmosphere during heating is made non-oxidizing to suppress the generation of scale, or shot blasting is performed after hot press forming in an oxidizing atmosphere. It is necessary to sufficiently remove the scale formed on the surface of the molded product, and in any case, the production cost cannot be denied.

  In order to suppress the generation of scale in a hot press-formed product, an invention is disclosed in which hot press forming is performed using a steel material whose surface is coated with plating or the like as a raw material. For example, Patent Document 1 discloses an invention for hot press forming an Al-plated steel sheet as a processing material, and Patent Document 2 discloses an invention for hot press forming a Zn-based or Zn-Al-based plated steel sheet as a processing material. Each is disclosed.

  Since the invention disclosed by patent documents 1 and 2 uses a plated steel sheet as a processing material, certainly the suppression of the generation of scale and the improvement of functions and characteristics derived from the hot press-formed product having a plating film are provided. Be expected.

JP 2000-38640 A JP 2001-353548 A

  In the inventions disclosed in Patent Documents 1 and 2, since a plated steel sheet is used as a processing material, it is possible to suppress the generation of scale, and the functions and characteristics derived from the press-formed product having a plating film. However, an increase in manufacturing cost due to plating is inevitable.

  The situation is the same not only when manufacturing high-strength hot-pressed products but also when manufacturing low- and medium-strength hot-pressed products obtained by heating at a lower temperature than hot press-molding. It is.

The present invention has such has been made in view of the problems the prior art has, by oxidation and the oxidation of the resulting surface to be heated to a high temperature during the hot press forming or warm press forming The above-mentioned various problems that occur can be solved, and plated steel sheets can be formed without any problem as a raw material, thereby enabling high-strength molded products having good dimensional accuracy even for complex shapes. It is an object of the present invention to provide a method for producing a press-molded product capable of mass-producing a press-molded product while sufficiently enjoying the advantages inherent in hot press molding or warm press molding that can be produced at low cost.

  The present inventor has intensively studied to solve the above-mentioned problems, and is not related to hot press forming or warm press forming. For example, the “Iron Heat Treatment Revised 5th Edition” (1995) 239- Attention was paid to the heat treatment method using a salt bath furnace disclosed on page 246. This heat treatment method is generally known as a heat treatment method in which oxides are not easily formed on the surface of the steel material. In addition, it is said that the oxidation rate is less likely to occur and a higher heating rate can be obtained than a heat treatment method in which heating is performed in an electric furnace or a gas furnace. For this reason, the present inventor can perform hot press molding or warm press at a low cost while suppressing the formation of scale on the surface if the steel sheet or the plated steel sheet is heated after being heated using a salt bath furnace. I thought it would be possible to produce molded products.

  However, when press forming is performed on a steel plate or plated steel plate heated using a salt bath furnace, the sheet is inevitably pressed with the salt still attached to the surface of the steel plate or plated steel plate. There was a concern that the salt would adhere and the generation of indentation scratches on the surface of the press-formed product due to this.

  In addition, when the hot-pressed product or warm-pressed product is mass-produced by press forming the steel plate or plated steel plate heated using a salt bath furnace, the salt adheres to the press mold and remains attached. It was also expected that the cooling ability of the mold processing material would be reduced by the salt, and it would be difficult to rapidly cool the molded product in the mold, which is a major feature of hot press molding.

The present inventor has intensively studied to solve these new problems in the case of performing press forming after heating a plated steel sheet using a salt bath furnace, and has completed the present invention .

The present invention includes a heating process in which a zinc-based plated steel sheet or an aluminum-plated steel sheet is immersed in a salt bath and heated, and a transporting process in which the zinc-based plated steel sheet or aluminum-plated steel sheet heated by this heating process is transported to a press molding machine, While the temperature of the zinc-based plated steel sheet or aluminum-plated steel sheet transported to the press forming machine by this transporting process is equal to or higher than the quenching temperature of this zinc-based plated steel sheet or aluminum-plated steel sheet, Alternatively, a press process in which an aluminum-plated steel sheet is press-molded to form a molded product, a quenching process in which the molded product molded by this press process is rapidly cooled, and a cleaning medium is sprayed onto the molded product during or after the rapid cooling. And a molded product washing step for removing salt adhering to the molded product. It is a method of manufacturing the less the molded article.

Further, the present invention carries a heating process of heating by immersing the galvanized steel sheet or an aluminum-plated steel sheet into a salt bath, a zinc-based plated steel sheet or an aluminum-plated steel sheet which has been heated by the heating step to press molding machine transport a step, while it is more hardenable temperature of zinc-plated steel sheet or an aluminum-plated steel sheet conveyance zinc-plated steel sheet or an aluminum-plated steel sheet to press molding machine by the conveying step, galvanized by press molding machine Press-molding a steel plate or an aluminum-plated steel plate into a molded product, and quenching the molded product in a state of being restrained by a press mold of a press molding machine, and a cleaning medium in the molded product during or after this rapid cooling And a molded product washing step for removing salt adhering to the molded product by spraying A method for producing a press-molded product characterized.

In these inventions, the viscosity of the molten salt in the salt bath is preferably 30 mPa · s or less.
In the present invention, it is preferable to immerse the zinc-based plated steel sheet or the aluminum-plated steel sheet so as to be substantially perpendicular to the bath surface of the salt bath.

  In these present inventions, further, a mold cleaning for removing salt adhering to the press mold by spraying a cleaning medium on the press mold for performing the press molding at a time later than the bottom dead center in the press molding. Providing a process can prevent the occurrence of indentation scratches on the surface of the press-molded product due to the adhesion of salt to the press mold, and the salt remains attached to the press mold. This is desirable because it can prevent the cooling capacity of the mold material from being lowered. Furthermore, this mold cleaning process is performed after the molded product is lifted up from the mold, and it is possible to maintain the cooling of the workpiece material at a high cooling rate by the mold, which is a major feature of hot press molding. Is desirable.

According to the present invention, even without controlling the pressurized heat atmosphere, brought about by oxidation and the oxidation of the hot press forming or warm unavoidable during press molding to a molded article surface due to being heated to a high temperature As a result, the excellent features of hot press molding or warm press molding that can produce high-strength molded products with good dimensional accuracy at a low cost even for complex shapes While enjoying, mass production of press-molded products is possible. Furthermore, the present invention is capable of are use when the plated steel sheet as a material, since it can be applied to a wide range of materials, hardly even schedule constraints received in terms of production.

1 (a) to 1 (c) are explanatory views schematically showing the press hardening process over time, and FIGS. 1 (c) and 1 (d) schematically show the mold cleaning process. It is explanatory drawing shown. FIG. 2 (a) is a photograph showing the appearance of the hot press-formed product obtained by the first hot press forming, and FIG. 2 (b) is the heat obtained by the fifth hot press forming. It is a photograph which shows the external appearance of a hot press molded product. FIG. 3 is an optical micrograph of the microstructure of the cross section of the obtained hot press-formed product. FIG. 4A is a photograph showing the appearance of a hot press-formed product heated in a natural gas combustion atmosphere furnace, and FIG. 4B shows the appearance of a hot press-formed product heated in a salt bath furnace. It is a photograph. FIG. 5 is a graph showing a heating / cooling curve. FIG. 6 shows three kinds of test pieces of 50 × 70 mm, 50 × 100 mm, and 70 × 100 mm having a plate thickness of 1.6 mm in a salt bath (900 ° C., 920 ° C., 950 ° C.) perpendicular to the bath surface. It is a graph which shows the relationship between the amount of salt take-out (per one side), and a test piece area at the time of being immersed for 4 minutes and pulling up at 500 mm / sec. FIG. 7 is an optical micrograph showing a cross-sectional microstructure of a portion of the warm press-formed product corresponding to the punch bottom of the press die.

Hereinafter, the form for enforcing the manufacturing method of the press-formed product concerning the present invention is explained. In the following explanation, the case where the press-formed product is a hot press-formed product is taken as an example, but the present invention is not limited to the hot press-formed product, and the temperature of the salt bath in which the steel plate is immersed is set. For example, the present invention is similarly applied to a warm press-formed product obtained at 500 to 800 ° C. Further, in the following description, the case where the processed material is a bare steel plate is taken as an example, but the object of the present invention is, for example, various plated steel plates such as a Zn-based plated steel plate, a Zn-Al-based plated steel plate, and further an Al-based plated steel plate. It is applied in respect.

[steel sheet]
In the present embodiment, a steel plate is used as the processing material. The composition of the steel sheet is preferably a composition that can obtain a predetermined hardness after quenching when quenching is intended. For example, C: 0.15% or more and 0.45% or less (in this specification, “%” relating to composition means “mass%” unless otherwise specified), Si: 0.5% or less, Mn: 0 0.5% to 3%, P: 0.01% or less, S: 0.01% or less, Al: 1% or less, N: 0.01% or less, Cr: 0.1% or more and 0.5% or less If necessary, Ti: 0.015% or more and 0.1% or less, Nb: 0.015% or more and 0.1% or less, B: 0.0002% or more and 0.004% or less, the remaining Fe and impurities are contained Illustrated.

  Further, as described later, when cooling while restraining the molded product with a press die, the cooling rate is lower than the cooling rate by water quenching, so quenching is possible even at such a low cooling rate. It is preferable to select the composition.

Moreover, although this invention is especially useful when using a bare steel plate at the point which can suppress scale production | generation at the time of a heating, using for a plated steel plate and a heat resistant coated steel plate is not prevented.
In addition, prior to the heating step described later, in order to remove oils and deposits attached to the surface of the steel plate, it is washed with an alkali, and further, a heating temperature of about 200 ° C. or less in order to remove moisture on the surface of the steel plate. Thus, it is preferable to preheat the steel plate.

[Heating process with salt bath]
After blanking the steel plate into a predetermined shape, the blanked steel plate is immersed in a salt bath and heated. For example, in order to increase the strength by quenching, the steel sheet is immersed in a salt bath housed in a salt bath furnace and heated to a predetermined temperature range of Ar ₃ or higher. The salt bath furnace and the salt to be used may be a well-known and commercially available salt, and those that can obtain a predetermined heating temperature may be appropriately selected and used. Since the heating rate of the steel plate in the salt bath furnace is higher than the heating rate of the steel plate in the gas furnace, for example, the heating process can be shortened.

  The salt (molten salt) used in the salt bath preferably has a viscosity at use temperature of 30 mPa · s or less, and more preferably 10 Pa · s or less. This is because when the viscosity of the salt is high, salt is often taken out, which is disadvantageous in cost. Moreover, it is considered that the lower the viscosity of the salt, the easier it is to level on the blank surface before taking out from the furnace and pressing, and there is an effect of preventing the indentation salt from being pushed in.

  For example, when using at 900 degreeC, Parker Heat Treatment Industry Co., Ltd. H-10 is illustrated, and when using at 700 degreeC, GS540 made by the company is illustrated. These commercial products are those in which sodium chloride, potassium chloride, barium sulfate or the like is blended, and the melting point can be adjusted by the blending ratio of these if necessary. If it is used at a temperature significantly higher than the melting point, salt evaporation increases, which is uneconomical. It is considered that the adhesion of salt to the steel sheet surface not only prevents oxidation of the steel sheet surface but also exhibits a lubricating function between the mold and the blank during pressing.

  When the steel plate is heated in the salt bath and then removed from the salt bath, it is preferable to keep the steel plate as vertical as possible because salt removal is reduced. As a result, there is no accumulation of liquid in the corners and the amount of liquid taken out originally is less than when the molded product is immersed, and the adhesion of salt to the surface of the steel plate and the press mold is reduced, so that the surface of the molded product It is possible to suppress indentation and galling.

  In order to keep the steel plate as vertical as possible when taking it out, multiple through holes for suspension are drilled on one side of the outer edge of the trim line of the steel plate, and a hook for hanging the steel plate is attached to each through hole. For example, the hook is held by an articulated general-purpose robot for handling.

In addition, as needed, you may restrict | squeeze the salt adhering to the surface of a steel plate to the extent which is not removed completely with a heated roll or inert gas.
In addition, when a zinc-based steel plate or an aluminum-plated steel plate is immersed in a salt bath, the temperature of the salt bath is considerably higher than the melting point of the plating film (zinc or aluminum) and it is difficult for oxides to form on the plating surface during heating. Therefore, there is a concern that the plating metal component melts, flows out and reacts in the salt bath. However, for example, even if the alloyed hot-dip galvanized steel sheet is immersed in a salt at about 950 ° C. for several minutes, the outflow of the plating into the salt bath was not recognized, so it is practically problematic to use these plated steel sheets. Absent. In this case, since the zinc oxide layer on the surface of the steel sheet is hardly formed as compared with the case of heating in an atmospheric gas furnace or the like, there is also an advantage that the weldability of the molded product is improved.

[Conveying process]
In order to perform press forming before the temperature of the steel plate taken out from the salt bath falls from the predetermined temperature range, the steel plate is conveyed to the press forming machine before it falls from the predetermined temperature range.

  For example, it is preferable to transport the steel plate to the press molding machine within 20 seconds after taking it out of the salt bath. Further, it is preferable to convey the steel sheet as vertically as possible during conveyance. This is because the salt leveling effect is expected on both sides of the blank. This is because when the steel plate blank plane is conveyed upward, the leveling speed of the salt solution is increased by gravity on the upper surface, whereas the leveling speed is decreased by gravity on the lower surface.

  In order to transport the steel plate in such a manner, for example, the salt bath furnace is disposed as close as possible to the press molding machine, and the pedestal of the articulated general-purpose robot described above includes the salt bath furnace and the press molding machine. It is exemplified that a moving mechanism that can reciprocate between the two is provided.

  If the surface of the steel sheet is inadvertently contacted during the conveyance, salt on the surface of the steel sheet is removed, and scale may be formed in this portion. Therefore, it should be noted that the conveyance is as fast as possible and does not contact the surface of the steel sheet other than the portion that is later removed by trim as much as possible. For example, in the case of using an articulated general-purpose robot having the above-described moving mechanism, it is exemplified that a space around the space where the articulated general-purpose robot moves is surrounded by a safety fence or the like to completely block contact with the outside. Is done.

[Pressing process]
In the pressing process, while the steel sheet conveyed to the press forming machine in the conveying process is in a predetermined temperature range or above the quenchable temperature of the steel sheet, the steel sheet is press formed by the press forming machine to obtain a molded product.

  That is, the steel sheet conveyed to the press mold is press-molded into a molded product having a predetermined shape before falling from a predetermined temperature range. The press molding machine may be a well-known and conventional machine that can be molded into a predetermined shape, and is not limited to a specific type.

  Although salt adheres to the molded product and the mold after press molding, no adverse effects on the appearance of the molded product are observed. On the contrary, when the salt adheres, it functions as a lubricant in press molding, and good press molding can be performed.

[Press quenching process, quenching process]
Fig.1 (a)-FIG.1 (c) are explanatory drawings which show a press hardening process typically and temporally.

  As shown in FIG. 1A to FIG. 1C, in the press quenching process, the temperature of the steel sheet 4 conveyed to the press molding machine 3 including the press dies 1 and 2 is quenched by the conveying process. While the temperature is higher than the possible temperature, the press molding machine 3 press-molds the steel plate 4 to form a molded product 5, and the molded product 5 is rapidly cooled in a state of being restrained by the press molds 1 and 2 of the press molding machine 3. And quench.

That is, in the case of a high-strength hot press molded product, the molded product 5 obtained by press molding is immediately quenched and quenched.
The molded product 5 may be rapidly cooled in a state of being restrained by the press molds 1 and 2 by a press quenching process as shown in FIG. In this case, using a structure in which cooling water flows inside the vicinity of the surfaces of the press dies 1 and 2, in combination with forming the steel plate 4 into the molded product 5 as shown in FIG. A method of quenching immediately after molding, for example, a method of quenching by providing a groove in a mold and flowing a cooling medium (water, oil, etc.) between the molded product 5 and the press molds 1 and 2 through the groove. There is. In the latter case, the salt adhering to the surface of the molded product can be removed with a cooling medium. In addition, the arrow in FIG.1 (c) illustrates the flow of a cooling water.

  On the other hand, in the quenching process, the molded product molded by the pressing process is quenched and quenched. That is, unlike the press quenching process shown in FIGS. 1 (a) to 1 (c), the molded product is taken out from the press mold by the quenching process after the pressing process, and immediately used is water quenching, oil quenching, or the like. It may be. As a result, in addition to securing a generally higher cooling rate, it is possible to remove the salt adhering to the molded product, and therefore when the salt is sufficiently removed, the molded product washing step described later is omitted. You can also.

  Whether the molded product that has been press-molded is quenched and quenched in the press mold, or quenched and quenched after being taken out of the press mold (performance / hardness / toughness) Etc.), dimensional accuracy (influence of shape freezing property at the time of quenching), and equipment cost, etc., may be appropriately selected and determined.

  Therefore, it is preferable that the cooling liquid is rapidly cooled without directly touching the molded product using the mold as described above. In the hot press molding, the cooling rate is lower than when cooling using a liquid such as water or oil. Therefore, it is preferable to set the steel plate components, the plate thickness, the molded product, and the mold shape so that they can be quenched even at such a low cooling rate. On the contrary, since the so-called automatic tempering easily occurs due to the slow cooling rate after the Ms point, it is advantageous for improving the toughness of the hot press-formed product.

[Molded product cleaning process]
In the molded product cleaning process, the salt adhering to the molded product is removed by spraying a cleaning medium onto the molded product during or after quenching in the quenching process or press quenching process.

  That is, the salt adhering to the surface is removed from the molded product after quenching or after quenching in the quenching process or press quenching process by immediately spraying a cleaning medium such as water (hot water). Preferably, it is preferable to wash with a weak acid or alkali after washing with water, and then wash with water again.

  The case where a high-strength molded product is obtained by quenching has been described as an example, but the present invention can also be applied to so-called warm molding in which press molding is performed by heating to a temperature at which hardening by quenching does not occur. is there. For example, when heating to about 450 ° C., a salt having a eutectic composition of lithium chloride-potassium chloride may be used.

In this way, according to the present invention, Te when odor using a fit Kkihagane plate as a workpiece material of the hot press forming or warm pressing, without controlling the heating atmosphere, hot press-forming or warm High strength with good dimensional accuracy even for complex shapes by reliably preventing surface oxidation caused by being heated to high temperature during hot press molding, ensuring lubrication with the mold Can be manufactured at low cost.

[Mold cleaning process]
As described above, there is no adverse effect on the appearance or the like of the molded product after the press molding and the adhesion of the salt to the mold. However, at the time of mass production, there is a concern that a large amount of salt accumulates on the mold due to continuous press molding and adversely affects the appearance of the molded product. Therefore, it is better to clean the mold every press molding.
FIG.1 (c) and FIG.1 (d) are explanatory drawings which show a metal mold | die washing | cleaning process typically. The arrows in FIGS. 1C and 1D illustrate the flow of the cleaning medium.

  In the present invention, since press forming is performed on a steel sheet having salt attached to the surface, salt on the surface of the steel sheet inevitably adheres to the press dies 1 and 2. If the press molding is continued with the salt attached to the press dies 1 and 2, the occurrence of indentation scratches on the surface of the press-molded product due to the adhesion of the salt to the press dies 1 and 2 Or the salt adheres to the press dies 1 and 2, and the cooling capacity of the press dies 1 and 2 is reduced. become unable.

  Therefore, in order to mass-produce hot press-molded products according to the present invention, mold cleaning is performed by spraying a cleaning medium on the press dies 1 and 2 for performing press molding to remove the salt adhering to the press dies 1 and 2. It is desirable to perform the process.

  Since this mold cleaning process is performed by spraying a cleaning medium, the temperature reduction of the steel sheet 5 before the end of press forming is performed after the bottom dead center of the press forming in the press forming shown in FIG. It is desirable to prevent this.

  Further, in order to perform uniform and sufficient cleaning of the press mold, the mold cleaning process is performed after the molded product 5 is lifted up from the press molds 1 and 2 (timing in FIG. 1 (c)). It is desirable to be done.

  Although it is desirable to perform the mold cleaning process every time each press molding, depending on the state of salt adhesion to the press mold, the frequency is such that the adhesion of salt to the press mold is not a problem. As appropriate.

In this way, according to the present invention, to control the heating atmosphere of the steel plate, or hot without performing descaling treatment such as shot blasting to the press-molded product, a high temperature during the hot press forming It is possible to reliably prevent surface oxidation caused by heating and mass-produce high-strength hot press-formed products having good dimensional accuracy even at complicated shapes at low cost. .

Examples of the method for producing a hot press-formed product according to the present invention will be described more specifically with reference to the accompanying drawings.
A test material obtained by cutting a cold-rolled steel sheet having the composition shown in Table 1 (remaining Fe and impurities) and having a plate thickness of 2.0 mm into 90 mm × 190 mm is used as a salt bath (H-10 manufactured by Nippon Parkerizing Co., Ltd.). It was immersed in a temperature of 950 ° C. (viscosity of 3 mPa · s at this time) for 3 minutes in a posture perpendicular to the bath surface and pulled up.

  Thereafter, it was set in a press mold of a press molding machine, and press molded into a molded product having a hat-shaped cross section when about 5 seconds had passed after the pulling. This press die is provided with a cooling water pipe directly inside the die surface, and is cooled by passing cooling water.

After the press molding was completed, it was held in the press mold until it reached 100 ° C. and cooled, the molded product was taken out from the press mold, washed with warm water at 60 ° C., further washed with water and dried.
Such hot press molding was continuously performed without maintaining the press mold.

  FIG. 2 (a) is a photograph showing the appearance of the hot press-formed product obtained by the first hot press forming, and FIG. 2 (b) is the heat obtained by the fifth hot press forming. It is a photograph which shows the external appearance of a hot press molded product. As shown in FIG. 2A and FIG. 2B, from the first hot press-formed product to the fifth hot press-formed product, although traces of light mold galling were observed, The situation was not worse with the fifth and fifth sheets. Therefore, it was considered that this die squeezing occurred for a reason different from the salt adhesion to the press die.

  Further, no die squeezing was observed in any of the sixth hot press-molded products that were subjected to care (# 600 sandpaper polishing finish) in the squeezing portion of the press die and subjected to hot press molding again.

In addition, generation | occurrence | production of the scale which may become a problem practically was not recognized on the surface of any molded article.
FIG. 3 is an optical micrograph of the microstructure of the cross section of the obtained hot press-formed product. As shown in FIG. 3, a martensitic structure was obtained in all cases, and the Vickers hardness was Hv460.

  In addition, although the surface of the hot press-molded product after water washing and drying was slightly discolored in yellow, after the above-mentioned warm water washing, pickling with, for example, about 0.3% hydrochloric acid, and further washing with water It was improved so that there was no problem.

  FIG. 4 (a) is a photograph showing the appearance of a hot press-formed product heated in a natural gas combustion atmosphere furnace (oxygen of about 2 vol%), and FIG. 4 (b) shows this example, that is, a salt bath furnace. It is a photograph which shows the external appearance of the hot press molded product heated by. The surface of the hot press-molded product heated in a salt bath furnace, whereas the hot press-molded product heated in a natural gas combustion furnace has peeling or dropping of the scale formed on the surface (particularly the flange). There was a scale formed.

(Reference example)
A test material having a composition shown in Table 1 and having a sheet thickness of 2.3 mm cut into 70 mm × 150 mm was placed in a salt bath of 20% sodium chloride, 25% potassium chloride, and 55% barium chloride. Dipping for 4 minutes in a posture perpendicular to the bath surface (the viscosity of the salt is 10 mPa · s, the amount of salt taken out (per side) 110 g / m ² ), and immediately after the pulling, 100 × 80 × made of SUS304 at room temperature It was cooled by sandwiching it manually with two 300 mm block molds. When the specimen temperature reached 100 ° C., the specimen was taken out from the mold, washed with water and dried. In addition, this metal mold | die is equipped with a cooling water pipe directly inside the metal mold | die surface, and is cooled by letting a cooling water pass.

  FIG. 5 is a graph showing a heating / cooling curve at this time. For comparison, FIG. 5 shows a heating / cooling curve when a cold-rolled steel plate (70 mm × 100 mm) of the same thickness is heated in a gas furnace (atmosphere atmosphere furnace) and press-formed with a 50 t hydraulic press. Also shown.

  As shown in the graph of FIG. 5, the heating rate when using a salt bath was overwhelmingly higher than the heating rate when using a gas furnace, and the cooling rate was lower and the cooling start temperature. The cooling rate from (about 850 ° C.) to 400 ° C. was about 30 ° C./sec.

This cooling rate is considered to be determined by the amount of salt taken out and the pressure applied in the press.
FIG. 6 shows three kinds of test pieces of 50 × 70 mm, 50 × 100 mm, and 70 × 100 mm having a plate thickness of 1.6 mm on the bath surface in the above-described salt bath (900 ° C., 920 ° C., 950 ° C.). It is a graph which shows the relationship between the amount of salt take-out (per one side) and a test piece area at the time of being immersed for 4 minutes in the attitude | position which becomes a right angle with respect to and raising at 500 mm / sec. The viscosity of the salt at this time was 1 to 7 mPa · s. Takeout amounts of the salt taken out per one side even if the change in temperature of the bath was in the range of 75~95g / m ^2.

  On the other hand, both the above-mentioned specimens having the composition shown in Table 1 and the above-mentioned specimens obtained from the results shown in FIG. 6 had a slight amount of solidified salt on the surface after cooling. However, the surface after washing with water had a slight etched trace, and no scale formation, mold squeezing, indentation, or the like that could cause a practical problem was observed. Further, the solidified salt slightly adhered to the mold.

  When a cross section of the obtained test material was observed, a martensite structure was obtained, and the Vickers hardness of the test material was Hv450. That is, it was confirmed that even the above cooling rate was sufficiently quenched.

  In this way, the steel plate is heated in a salt bath and subjected to hot pressing, whereby die quenching can be performed without generating scale on the surface. At this time, although salt slightly adhered to the molded product and the mold surface, it did not lead to pushing or galling.

Under the same conditions as in Experimental Example 1, a warm press test was performed with salt bath temperatures of 500 ° C., 600, 700 ° C., and 800 ° C.
FIG. 7 is an optical micrograph showing a cross-sectional microstructure of a portion of the warm press-formed product corresponding to the punch bottom of the press die.

  As shown in FIG. 7, the Vickers hardness at the center of the plate thickness of the press-formed product corresponding to the punch bottom was Hv 170, 170, 170, and 260, respectively. 500, 600, and 700 ° C. were ferrite + pearlite structure, and 800 ° C. was ferrite + martensite structure.

In addition, the Vickers hardness of the steel plate before quenching was Hv170, ferrite + pearlite structure.
Also in the case of this warm press, compared with the case of heating at 900 ° C. in Example 1, although the amount of salt carried out increased, abnormal oxidation was not observed on the surface of the warm press-formed product.

  Further, magnesium fluoride or silicon may be appropriately added as an antioxidant in order to suppress decarbonization due to oxides generated by decomposition of molten salt with oxygen or water brought in from the atmosphere or from a blank.

Claims (6)

A heating process in which a zinc-based plated steel sheet or an aluminum-plated steel sheet is immersed in a salt bath and heated;
A conveying step of conveying the zinc-based plated steel sheet or aluminum-plated steel sheet heated by the heating step to a press molding machine;
While the temperature of the zinc-based plated steel sheet or aluminum-plated steel sheet transported to the press-forming machine by the transporting step is equal to or higher than the quenchable temperature of the zinc-based plated steel sheet or aluminum-plated steel sheet, A press process in which a plated steel plate or an aluminum plated steel plate is press-formed into a molded product;
A quenching step of rapidly cooling the molded product formed by the pressing step;
A method of manufacturing a press-molded product, comprising: a molded product cleaning step of removing a salt adhering to the molded product by spraying a cleaning medium on the molded product during or after the rapid cooling. A heating process in which a zinc-based plated steel sheet or an aluminum-plated steel sheet is immersed in a salt bath and heated;
A conveying step of conveying the zinc-based plated steel sheet or aluminum-plated steel sheet heated by the heating step to a press molding machine;
While the temperature of the zinc-based plated steel sheet or aluminum-plated steel sheet transported to the press-forming machine by the transporting step is equal to or higher than the quenchable temperature of the zinc-based plated steel sheet or aluminum-plated steel sheet, A press-quenching process in which a plated steel plate or an aluminum-plated steel plate is press-molded to form a molded product, and the molded product is rapidly cooled in a state of being restrained by a press die of the press molding machine;
A method of manufacturing a press-molded product, comprising: a molded product cleaning step of removing a salt adhering to the molded product by spraying a cleaning medium on the molded product during or after the rapid cooling. The method for producing a press-formed product according to claim 1 or 2 , wherein the viscosity of the molten salt in the salt bath is 30 mPa · s or less. The press-formed product according to any one of claims 1 to 3, wherein the zinc-based steel plate or the aluminum-plated steel plate is immersed so as to be substantially perpendicular to the bath surface of the salt bath. Method. Furthermore, it includes a mold cleaning step of removing salt adhering to the press mold by spraying a cleaning medium on the press mold for performing the press molding at a time after the molding bottom dead center in the press molding. The method for producing a press-formed product according to any one of claims 1 to 4 , wherein the press-molded product is produced. The method for manufacturing a press-molded product according to claim 5 , wherein the mold cleaning step is performed after the molded product is lifted up from the mold.