JP5105243B2 - Membrane separation activated sludge treatment apparatus and method - Google Patents

Description

  The present invention relates to a membrane separation activated sludge treatment apparatus and method, and more particularly to a membrane separation activated sludge treatment apparatus and method for aerobically treating water to be treated with activated sludge held in an aerobic tank.

FIG. 4 is a diagram showing a schematic configuration of a conventional membrane separation activated sludge treatment apparatus. As illustrated, the membrane separation activated sludge treatment apparatus 100 includes an anoxic tank 101 and an aerobic tank 102 from the upstream side. In the anoxic tank 101, denitrification treatment is performed by denitrifying bacteria in activated sludge under anoxic conditions. In the aerobic tank 102, nitrification is performed by nitrifying bacteria in activated sludge under aerobic conditions. A part of the processing liquid in the aerobic tank 102 is circulated to the anoxic tank 101. Here, the aerobic tank 102 is a single tank, and a membrane unit 104 and a diffuser are attached in the tank. The membrane unit 104 is immersed in the tank, and a coarse bubble diffusing means 106 is installed below the membrane unit 104. Then, coarse bubbles are generated from the coarse bubble diffusing means 106 to clean the activated sludge adhering to the membrane surface of the membrane unit 104 and supply oxygen to the treated water in the aerobic tank 102. In the aerobic tank 102, NH ₄ —N (ammonia nitrogen) is oxidized by nitrifying bacteria to become NO ₃ —N (nitrate nitrogen).

At this time, there is a case where the oxidation of NH ₄ -N is insufficient with only the air flow from the coarse bubble diffusing means 106, and a fine bubble diffusing device 108 is newly installed in the aerobic tank 102. The fine bubble diffusing means 108 can sufficiently oxidize NH ₄ -N by blowing fine bubbles having a specific surface area larger than coarse bubbles into the aerobic tank 102.

As a conventional determination of NH ₄ -N oxidation, a DO sensor is installed in the aerobic tank 102, and the amount of air blown by the fine bubble diffusing means 108 is controlled so that the DO value falls within a certain range. (For example, it is shown in Patent Document 1) Or the amount of air blown by the fine bubble diffusing means that can correspond to the NH ₄ —N concentration in the water to be treated flowing into the aerobic tank from the calculation and experience, regardless of the detection result of the DO sensor. Was set in advance as a fixed value and sludge treatment was performed.

As described above, the membrane separation activated sludge apparatus 100 has a feature that it can be treated in a space-saving manner as compared with the conventional activated sludge treatment apparatus. The reason for this is that the activated sludge in the tank is maintained at a high concentration to increase the ability of the activated sludge to purify the sewage per unit volume.
JP 2005-103381 A

  However, when the activated sludge retained in the aerobic tank is increased in concentration, the following problems occur. First, since the amount of microorganisms that require oxygen increases as the activated sludge concentration increases, the consumption of dissolved oxygen necessary for the reaction increases. In addition, due to the increased concentration of activated sludge, the viscosity of the water to be treated increases, and the bubbles supplied from the air diffuser become coarse, making it difficult for oxygen to dissolve into the water to be treated, and purifying the sewage with respect to the air flow rate. The amount of oxygen acting on As a result, the amount of air blown by the coarse bubble diffusing means is increased, and the driving capability is increased.

Therefore, as an effort to reduce the amount of blast, if the amount of oxygen is insufficient only by blowing from the coarse bubble diffusing means that serves both as the physical cleaning of the membrane unit and the oxygen supply to the activated sludge, High microbubble aeration means have been adopted, but even if the microbubble aeration means is used, the concentration of activated sludge is high and the situation that the supplied oxygen is difficult to dissolve into the treated water remains the same, so the oxygen dissolution efficiency There was a need for a means to improve Also, a control means is required so that the fine bubble diffusing means provided to make up for the shortage of the necessary oxygen amount against the change in NH ₄ -N concentration in the sewage flowing into the aerobic tank does not perform excessive air blowing. there were.

  In order to solve such problems of the prior art, an object of the present invention is to provide a membrane separation activated sludge treatment apparatus and method that can reduce the operation power related to the aeration in the aerobic tank.

In order to solve the above-mentioned problems, the membrane separation activated sludge treatment apparatus of the present invention is a first aeration means for dividing aerobic tank for treating water to be treated with activated sludge into a plurality of parts and supplying fine bubbles into the tank. A first aerobic tank for aerobically treating the treated water that has flowed in, and a second aeration for supplying the coarse bubbles by flowing in the treated water from the adjacent first aerobic tank And a second aerobic tank comprising a membrane unit for membrane separation of the activated sludge, and the first air diffuser based on a detection value of an NH ₄ -N concentration sensor attached to the first aerobic tank. by adjusting the blowing amount of means, and control means for controlling the NH 4 _-N concentration in the tank of the first aerobic tank to the NH 4 _-N concentration that can be processed by the second aerobic tank It is characterized by that.

In this case, the second aerobic tank may be provided with a circulation line for circulating the nitrification liquid at least upstream of the first aerobic tank .

The membrane separation activated sludge treatment device of the present invention is a membrane separation activated sludge treatment device that aerobically treats water to be treated with activated sludge in an aerobic tank and performs membrane separation, and the aerobic tank is subjected to a plurality of treatments. dividing the tank, the detecting the NH 4 _-N concentration of the treated water flowing into the downstream side of the processing tank in front of the downstream side of the processing tank for aerobic treatment and membrane separation by the activated sludge NH ₄ An upstream processing tank for adjusting the -N concentration is provided.

The membrane separation activated sludge treatment method of the present invention is a membrane separation activated sludge treatment method in which water to be treated is aerobically treated with activated sludge in an aerobic tank and membrane-separated, wherein the aerobic tank is the first preferred. Dividing into an air tank and a second aerobic tank, supplying fine bubbles to the treated water flowing into the tank of the first aerobic tank and aerobically treating, The NH ₄ —N concentration is controlled to the NH ₄ —N concentration capable of treating activated sludge in the second aerobic tank, and the treated water from the first aerobic tank is supplied to the second aerobic tank. Then, the activated sludge is separated into a membrane.

  In this case, the nitrification solution in the second aerobic tank may be circulated at least upstream of the first aerobic tank.

According to the present invention having the above configuration, the aerobic tank is divided into a plurality of tanks, and based on the detection value of the NH ₄ -N concentration detection means of the divided first aerobic tank, The NH ₄ —N concentration is controlled to a NH ₄ —N concentration that can be processed in the second aerobic tank. That is, a treatment tank that detects the NH ₄ -N concentration of the water to be treated and adjusts the NH ₄ -N concentration is provided in the preceding stage of the treatment tank that performs aerobic treatment with activated sludge and membrane separation.

Thereby, in the second aerobic tank into which the water to be treated that is maintained at a predetermined concentration flows, it is possible to make the blowing amount necessary for oxidizing the NH ₄ -N concentration without sending excessive air, The driving power of the entire apparatus can be reduced.

  By circulating the nitrification liquid from the second aerobic tank to at least the upstream side of the first aerobic tank, the activated sludge concentration in the first aerobic tank becomes lower than the activated sludge concentration in the second aerobic tank. Therefore, the first air diffuser for supplying fine bubbles can supply oxygen at a low output, and the driving power required for the air diffuser can be reduced.

  Further, the aerobic tank is divided into two tanks, and the fine bubble diffusing means, the membrane unit and the coarse bubble diffusing means are separately installed in each of the first aerobic tank and the second aerobic tank. For this reason, it becomes easy to repair or maintain equipment that needs to be carried out with the aerobic tank emptied, and the effect increases as the facility scale increases.

An NH ₄ —N concentration sensor is used as the detection means. Since the NH ₄ -N concentration sensor is an ion selective electrode type, the measured value of the NH ₄ -N concentration can be detected quickly. Therefore, the NH ₄ —N concentration in the aerobic tank can be quickly adjusted.

Embodiments of the membrane separation activated sludge treatment apparatus and method of the present invention will be described below in detail with reference to the accompanying drawings.
FIG. 1 is a diagram showing a schematic configuration of a membrane separation activated sludge treatment apparatus of the present invention. The activated sludge treatment is mainly performed in the anoxic tank 11 and the aerobic tank 12. The membrane separation activated sludge treatment apparatus 10 of the present invention divides the aerobic tank 12 into a plurality of treatment tanks. In this embodiment, as an example, the aerobic tank 12 is divided into two, and the first aerobic tank 20 and the second aerobic tank 30 are provided. The aerobic tank 12 is divided into two by providing a partition plate 14 between the first aerobic tank 20 and the second aerobic tank 30. The partition plate 14 is one or a plurality of plates that vertically shield the space between the first aerobic tank 20 and the second aerobic tank 30 from the bottom surface toward the water surface, and an opening is formed in a part of the plate. Yes, the water to be treated from the first aerobic tank 20 can flow into the second aerobic tank 30.

  In the first aerobic tank 20 on the upstream side, treated water from the anoxic tank 11 in which denitrification is performed by denitrifying bacteria in activated sludge under anoxic conditions flows. The first aerobic tank 20 includes first aeration means 22 in the tank. The first air diffuser 22 generates fine bubbles in the tank. Since the fine bubbles have a small specific surface area, the oxygen dissolution efficiency for the water to be treated is high. For this reason, it is effective as a supply source of dissolved oxygen to the water to be treated.

  The second aerobic tank 30 on the downstream side is configured such that the water to be treated from the first aerobic tank 20 flows in through the partition plate 14, and the water to be treated from the oxygen-free tank 11 is directly introduced. There is nothing. The second aerobic tank 30 includes a second air diffuser 32 and a membrane unit 34 in the tank. The membrane unit 34 is immersed in the tank. The second air diffuser 32 is attached below the membrane unit 34.

  The second air diffuser 32 generates coarse bubbles in the tank. Coarse bubbles diffused from the second air diffuser 32 generate a cross-flow velocity involving the water to be treated when rising due to buoyancy, and clean the membrane surface of the separation membrane. Moreover, the swirling flow of the water to be treated is generated in the second aerobic tank 30 by the rising of the coarse bubbles, and the mixing and stirring of the activated sludge and the water to be treated is promoted. Also, oxygen in the coarse bubbles comes into contact with the water to be treated and dissolves as dissolved oxygen in the liquid to be treated. Since coarse bubbles have a small specific surface area, oxygen dissolution efficiency with respect to water to be treated is lower than that of fine bubbles.

  The membrane unit 34 has a pipe 35 connected to the secondary side of the separation membrane. A suction pump 36 is attached to the pipe 35. When the suction pump 36 is moved, the secondary side of the separation membrane of the membrane unit 34 becomes negative pressure, and membrane separation between the water to be treated and the activated sludge is performed. The permeated water that has passed through the separation membrane is discharged from the pipe 35 to the outside.

  The second aerobic tank 30 is connected to a circulation line 37. The circulation line 37 is a pipe that circulates the nitrification solution in the second aerobic tank 30 at least upstream of the first aerobic tank 20. The circulation line 37 of a present Example has connected the 2nd aerobic 30 tank and the anoxic tank 11 as an example. A circulation pump 38 is attached to the circulation line 37, and the nitrification liquid in the second aerobic tank 30 is circulated to the anoxic tank 11 through the circulation line 37.

The NH ₄ —N concentration sensor 40 serving as a detection means is provided in the first aerobic tank 20. The NH ₄ —N concentration sensor 40 can use an ion selective electrode type as an example, and is electrically connected to the control means 50 described later. The NH ₄ -N concentration sensor 40 detects the NH ₄ -N concentration in the tank of the first aerobic tank 20 and sends a measured value to the control means 50 described later.

The control means 50 is electrically connected to the NH ₄ -N concentration sensor 40 and the first air diffusion means 22. Control means 50, based on measurements of the _NH 4 -N concentration sensor 40, by adjusting the blowing rate of the first air diffuser unit 22, the _NH 4 -N concentration of the first aerobic tank 20 second aerobic The NH ₄ —N concentration in the tank 30 is controlled to a treatable NH ₄ —N concentration.
Next, the membrane separation activated sludge treatment method of the present invention having the above configuration will be described below.

When the water to be treated is supplied to the oxygen-free tank 11, the oxygen-free tank 11 is denitrified by denitrifying bacteria in the activated sludge under oxygen-free conditions.
Next, water to be treated from the oxygen-free tank 11 is supplied to the aerobic tank 12. The aerobic tank 12 of the present invention is divided into two, and the water to be treated from the anoxic tank 11 is first supplied to the first aerobic tank 20. In the first aerobic tank 20, a nitrification reaction is performed by nitrifying bacteria in activated sludge. And the to-be-processed water of the 1st aerobic tank 20 flows over the partition plate 14, and is supplied to the 2nd aerobic tank 30. FIG. In the second aerobic tank 30, a nitrification reaction is performed by the nitrifying bacteria in the activated sludge and membrane separation of the activated sludge by the membrane unit 34 is performed. The permeated water separated by the membrane unit 34 is discharged to the outside through the pipe 35. On the other hand, the activated sludge and a part of the nitrification liquid in the second aerobic tank 30 are circulated to the anoxic tank 11 via the circulation line 37.

  At this time, the activated sludge concentration of the first aerobic tank 20 of the present invention is set lower than the concentration of the second aerobic tank 30. If the activated sludge concentration is set too low, the liquid viscosity of the sludge decreases and the cleaning effect of the separation membrane decreases. Therefore, in the present invention, as an example, the activated sludge concentration ranges of the first aerobic tank and the second aerobic tank are set to 0.2 to 1.7 mg / l and 0.5 to 2.0 mg / l, respectively. Moreover, the ratio between the inflow amount of the water to be treated flowing into the anaerobic tank 11 and the circulation amount of the nitrating liquid circulated from the second aerobic tank to the anaerobic tank 11 is set to 1: 1 to 5. Thereby, in the 1st aerobic tank 20, compared with the 2nd aerobic tank 30, the state in which oxygen is easy to melt | dissolve in to-be-processed water can be formed, and the amount of aeration can be reduced.

  In addition, the density | concentration adjustment of activated sludge can be adjusted with the supply amount of to-be-processed water, the to-be-processed water circulated from the 2nd aerobic tank 30 to the anoxic tank 11, and the circulation amount of activated sludge. For example, when the activated sludge concentration in the first aerobic tank 20 is high, the amount of water to be treated and the activated sludge circulated from the second aerobic tank 30 to the anoxic tank 11 is reduced via the circulation pump 38. As a result, the concentration can be lowered.

In addition, the determination of NH ₄ -N oxidation in the aerobic tank of the present invention is based on the NH ₄ -N concentration. The maximum amount of NH ₄ —N that can be oxidized in the second aerobic tank is determined by factors such as the size of the treatment tank. The NH ₄ —N concentration that can be processed in the second aerobic tank can be obtained by calculation or experience.

Here, the oxygen supplied from the air diffuser is consumed in the aerobic tank for organic matter oxidation, endogenous respiration of activated sludge, NH ₄ -N oxidation, and DO maintenance. Therefore, in the state where the aerobic tank is divided into the first aerobic tank 20 and the second aerobic tank 30 for the purpose of improving oxygen dissolution efficiency, NH ₄ -N that can be oxidized in the second aerobic tank 30 in the subsequent stage is reduced. Even if an attempt is made to control this by providing a DO sensor in the first aerobic tank 20, it is difficult to control because the relationship between NH ₄ -N and DO is not clear.

The method of fixing the blast amount is an effective method because the necessary oxygen amount can be predicted in advance only when the NH ₄ —N amount in the water to be treated flowing into the aerobic tank is constant. However, it is currently difficult to keep the concentration of the treated water supplied constant. Therefore, for example, when the blowing amount is set so as to correspond to the maximum value of the NH ₄ —N concentration in the water to be treated, excessive blowing occurs when the minimum value of the NH ₄ —N concentration flows. Therefore, the driving power is wasted and the optimum air flow control cannot be achieved.

Therefore, in the present invention, the NH ₄ -N concentration sensor 40 is attached to the first aerobic tank to control the NH ₄ -N concentration. More specifically, the the NH 4 _-N in the second aerobic tank 30 by calculating the maximum NH 4 _-N amount that can be oxidized, or empirically set in advance. Here, when the oxygen supply capacity of the second aerobic tank is constant, the remaining amount obtained by subtracting the endogenous respiration of activated sludge from the supply oxygen amount and the oxygen amount consumed for DO maintenance is used for nitrification of NH ₄ -N. The amount of oxygen produced. Therefore, in the present invention, the _NH 4 -N concentration of the oxygen amount is set to a concentration range of 0.1 to 10 mg / l as an example.

As described above, the NH ₄ —N concentration in the water to be treated flowing into the first aerobic tank 20 varies. In the first aerobic tank 20, the NH ₄ -N concentration sensor 40 detects the NH ₄ -N concentration in the treatment tank. When the NH ₄ -N concentration of the supplied water to be treated increases, the amount of fine bubbles blown by the air diffuser 22 in the first aerobic tank 20 is increased so that the NH ₄ -N concentration is within a set concentration range. It has been lowered to fit. Thus, in the first aerobic tank, the NH ₄ -N concentration can be arbitrarily controlled by the NH ₄ -N sensor and the control mechanism of the amount of air diffused.

The second aerobic tank 30 is supplied with water to be treated whose NH ₄ -N concentration is controlled within a set range even when the NH ₄ -N concentration in the water to be treated varies. For this reason, the NH ₄ —N concentration remaining in the second aerobic tank can be made constant.

FIG. 2 is a graph showing operating conditions of the membrane separation activated sludge treatment apparatus of the present invention. In FIG. 2, the horizontal axis represents the elapsed time (hours) of operation, the left vertical axis represents the NH ₄ -N concentration (mg / l), and the right vertical axis represents the first aerobic tank air flow rate (m ³ / h). Each is shown. Also, plot □ indicates the NH4-N concentration flowing into the first aerobic tank, plot ◯ indicates the NH ₄ -N concentration flowing out from the first aerobic tank, and plot + indicates the air flow rate of the first aerobic tank. Each is shown. As shown in the drawing, in the first aerobic tank of the membrane separation activated sludge treatment apparatus 10, the NH ₄ —N concentration of the water to be treated flowing into the tank is 3 to 5 mg / l. As an example, when the NH ₄ -N concentration in the tank is set to a concentration range of 1.5 to 2.5 mg / l, the NH ₄ -N concentration flowing out from the first aerobic tank 20 exceeds 2.0 mg / l. In this case, the amount of fine bubbles supplied by the first air diffuser 22 is increased. The increase of the fine bubbles is performed until the NH ₄ —N concentration in the tank is lower than 2.0 mg / l. Thereby, the NH ₄ —N concentration of the water to be treated flowing out from the first aerobic tank can be maintained within the set concentration range. Since only the water to be treated within the set concentration range flows into the second aerobic tank, it is not affected by the NH ₄ -N concentration change. The dissolved oxygen concentration required for the activated sludge treatment set in advance in the second aerobic tank can be maintained, and the dissolved oxygen is not insufficient. Therefore, it is possible to process NH ₄ -N with the minimum necessary amount of diffused air.

The NH ₄ -N concentration sensor is provided in the second aerobic tank, measures the NH ₄ -N concentration in the second aerobic tank, and monitors the NH ₄ -N concentration in the second aerobic tank. May be.
FIG. 3 is a view showing a modification of the membrane separation activated sludge treatment apparatus of the present invention. As shown in the figure, the modified membrane separation activated sludge treatment apparatus 10 </ b> A includes a second circulation line 39 that branches in the middle of the first circulation line 37 and is connected to the first aerobic tank 20. Other configurations are the same as those in FIG. 1, and detailed description thereof is omitted. The nitrification solution in the second aerobic tank 30 of the present invention may be circulated at least upstream of the first aerobic tank 20. In the present embodiment, a part of the nitrification liquid in the second aerobic tank 30 is circulated to the anoxic tank 11 and a part of the nitrification liquid is also circulated to the first aerobic tank 20 by the second circulation line 39. ing. At this time, each circulation ratio and activated sludge concentration can be set as follows as an example. The ratio between the inflow amount of the water to be treated flowing into the anaerobic tank 11 and the circulation amount of the nitrification liquid circulated from the second aerobic tank 30 to the anaerobic tank 11 is set to 1: 1 to 5. The ratio between the inflow amount of the water to be treated flowing into the anaerobic tank 11 and the circulation amount of the nitrification liquid to be circulated from the second aerobic tank 30 to the first aerobic tank 20 is set to 1: 0-5. Yes. The activated sludge concentration ranges of the first aerobic tank 20 and the second aerobic tank 30 are set to 0.2 to 1.8 mg / l and 0.5 to 2.0 mg / l, respectively.

  According to the membrane separation activated sludge treatment apparatus 10 </ b> A of such a modification, a concentration difference can be provided in the activated sludge concentration between the first aerobic tank 20 and the second aerobic tank 30. Compared to the second aerobic tank 30, the first aerobic tank 20 can form a state in which oxygen is easily dissolved in the water to be treated, and the amount of aeration can be reduced.

It is a figure which shows the structure outline of the membrane separation activated sludge processing apparatus of this invention. It is a graph which shows the driving | running conditions of the membrane separation activated sludge processing apparatus of this invention. It is a figure which shows the modification of the membrane separation activated sludge processing apparatus of this invention. It is a figure which shows the structure outline of the conventional membrane separation activated sludge processing apparatus.

Explanation of symbols

DESCRIPTION OF SYMBOLS 10 ......... Membrane separation activated sludge processing apparatus, 11 ......... Anoxic tank, 12 ......... Aerobic tank, 14 ......... Partition plate, 20 ......... First aerobic tank, 22 ......... First Air diffuser, 30 ......... Second aerobic tank, 32 ......... Second air diffuser, 34 ......... Membrane unit, 35 ......... Piping, 36 ......... Suction pump, 37 ......... Circulation line , 38 ......... circulating pump, 39 ......... second circulation line, 40 ......... _NH 4 -N concentration sensor 50 ......... control unit, 100 ......... membrane separation activated sludge treatment apparatus, 101 ...... ... anoxic tank, 102 ... aerobic tank, 104 ... ... membrane unit, 106 ... coarse air bubble diffuser, 108 ... fine bubble diffuser.

Claims (5)

The aerobic tank for treating the water to be treated with activated sludge is divided into a plurality of parts, a first air diffuser for supplying fine bubbles into the tank is attached, and a first aerobic treatment is performed for the water to be treated. An air tank,
A second aerobic tank comprising second aeration means for supplying the coarse bubbles, and a membrane unit for membrane separation of the activated sludge;
Based on the detection value of the NH ₄ -N concentration sensor attached to the first aerobic tank, the amount of air blown by the first aeration unit is adjusted to adjust the NH ₄ -N in the tank of the first aerobic tank. and control means for controlling the concentration of the NH 4 _-N concentration that can be processed by the second aerobic tank,
A membrane separation activated sludge treatment apparatus characterized by comprising:   The membrane separation activated sludge treatment apparatus according to claim 1, wherein the second aerobic tank is provided with a circulation line for circulating the nitrification liquid at least upstream of the first aerobic tank. A membrane separation activated sludge treatment device for aerobically treating water to be treated with activated sludge in an aerobic tank,
Dividing the aerobic tank into a plurality of processing tanks;
The NH ₄ -N concentration is adjusted by detecting the NH ₄ -N concentration of the water to be treated flowing into the downstream treatment tank upstream of the aerobic treatment with the activated sludge and the downstream treatment tank for membrane separation. A membrane separation activated sludge treatment apparatus, characterized in that an upstream treatment tank is provided. A membrane separation activated sludge treatment method for aerobically treating water to be treated with activated sludge in an aerobic tank and separating the membrane,
Dividing the aerobic tank into a first aerobic tank and a second aerobic tank;
While supplying microbubbles to the water to be treated flowing into the tank of the first aerobic tank to treat aerobically, the NH ₄ -N concentration of the first aerobic tank is set to the second aerobic tank. Control to NH ₄ -N concentration that can be treated with
A membrane separation activated sludge treatment method, wherein the treated water from the first aerobic tank is supplied to the second aerobic tank and the activated sludge is subjected to membrane separation. The membrane separation activated sludge treatment method according to claim 4 , wherein the nitrification solution in the second aerobic tank is circulated at least upstream of the first aerobic tank.

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