JP4920188B2 - 軽油基材及び軽油、並びにそれらの製造方法 - Google Patents
軽油基材及び軽油、並びにそれらの製造方法 Download PDFInfo
- Publication number
- JP4920188B2 JP4920188B2 JP2004354259A JP2004354259A JP4920188B2 JP 4920188 B2 JP4920188 B2 JP 4920188B2 JP 2004354259 A JP2004354259 A JP 2004354259A JP 2004354259 A JP2004354259 A JP 2004354259A JP 4920188 B2 JP4920188 B2 JP 4920188B2
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- Prior art keywords
- massppm
- light oil
- oil
- benzo
- hydrorefining
- Prior art date
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Links
- 239000000463 material Substances 0.000 title claims description 35
- 238000004519 manufacturing process Methods 0.000 title claims description 27
- 239000003054 catalyst Substances 0.000 claims description 70
- 150000001875 compounds Chemical class 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 32
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthene Chemical compound C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 claims description 24
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 claims description 24
- 125000003118 aryl group Chemical group 0.000 claims description 23
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 22
- 238000004821 distillation Methods 0.000 claims description 21
- 229910052717 sulfur Inorganic materials 0.000 claims description 21
- DXBHBZVCASKNBY-UHFFFAOYSA-N 1,2-Benz(a)anthracene Chemical compound C1=CC=C2C3=CC4=CC=CC=C4C=C3C=CC2=C1 DXBHBZVCASKNBY-UHFFFAOYSA-N 0.000 claims description 20
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 20
- 239000011593 sulfur Substances 0.000 claims description 20
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims description 16
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 claims description 16
- FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 claims description 12
- GYFAGKUZYNFMBN-UHFFFAOYSA-N Benzo[ghi]perylene Chemical group C1=CC(C2=C34)=CC=C3C=CC=C4C3=CC=CC4=CC=C1C2=C43 GYFAGKUZYNFMBN-UHFFFAOYSA-N 0.000 claims description 12
- HAXBIWFMXWRORI-UHFFFAOYSA-N Benzo[k]fluoranthene Chemical compound C1=CC(C2=CC3=CC=CC=C3C=C22)=C3C2=CC=CC3=C1 HAXBIWFMXWRORI-UHFFFAOYSA-N 0.000 claims description 12
- FTOVXSOBNPWTSH-UHFFFAOYSA-N benzo[b]fluoranthene Chemical compound C12=CC=CC=C1C1=CC3=CC=CC=C3C3=C1C2=CC=C3 FTOVXSOBNPWTSH-UHFFFAOYSA-N 0.000 claims description 12
- WDECIBYCCFPHNR-UHFFFAOYSA-N chrysene Chemical compound C1=CC=CC2=CC=C3C4=CC=CC=C4C=CC3=C21 WDECIBYCCFPHNR-UHFFFAOYSA-N 0.000 claims description 11
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims description 10
- 239000003208 petroleum Substances 0.000 claims description 10
- 229910052750 molybdenum Inorganic materials 0.000 claims description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 7
- CWRYPZZKDGJXCA-UHFFFAOYSA-N acenaphthene Chemical compound C1=CC(CC2)=C3C2=CC=CC3=C1 CWRYPZZKDGJXCA-UHFFFAOYSA-N 0.000 claims description 7
- HXGDTGSAIMULJN-UHFFFAOYSA-N acetnaphthylene Natural products C1=CC(C=C2)=C3C2=CC=CC3=C1 HXGDTGSAIMULJN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000011733 molybdenum Substances 0.000 claims description 7
- LGERRYPEGFPVAJ-UHFFFAOYSA-N 1,12-phenyleneperylene Natural products C1=C2C3=CC=CC=C3C3=CC=C(C=CC=C45)C4=C3C2=C2C5=CC=CC2=C1 LGERRYPEGFPVAJ-UHFFFAOYSA-N 0.000 claims description 6
- SXQBHARYMNFBPS-UHFFFAOYSA-N Indeno[1,2,3-cd]pyrene Chemical compound C=1C(C2=CC=CC=C22)=C3C2=CC=C(C=C2)C3=C3C2=CC=CC3=1 SXQBHARYMNFBPS-UHFFFAOYSA-N 0.000 claims description 6
- 125000004054 acenaphthylenyl group Chemical group C1(=CC2=CC=CC3=CC=CC1=C23)* 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 5
- 239000002283 diesel fuel Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 description 192
- 235000019198 oils Nutrition 0.000 description 190
- 206010064911 Pulmonary arterial hypertension Diseases 0.000 description 45
- 208000020193 Pulmonary artery hypoplasia Diseases 0.000 description 45
- 239000007789 gas Substances 0.000 description 40
- 239000001257 hydrogen Substances 0.000 description 31
- 229910052739 hydrogen Inorganic materials 0.000 description 31
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 30
- 238000006243 chemical reaction Methods 0.000 description 20
- 239000000047 product Substances 0.000 description 20
- 239000002994 raw material Substances 0.000 description 12
- 229910003294 NiMo Inorganic materials 0.000 description 11
- 239000010457 zeolite Substances 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 229910021536 Zeolite Inorganic materials 0.000 description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000006477 desulfuration reaction Methods 0.000 description 6
- 230000023556 desulfurization Effects 0.000 description 6
- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 description 6
- 239000013618 particulate matter Substances 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- LHRCREOYAASXPZ-UHFFFAOYSA-N dibenz[a,h]anthracene Chemical compound C1=CC=C2C(C=C3C=CC=4C(C3=C3)=CC=CC=4)=C3C=CC2=C1 LHRCREOYAASXPZ-UHFFFAOYSA-N 0.000 description 4
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical compound C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- 229910052809 inorganic oxide Inorganic materials 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000395 magnesium oxide Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 150000003464 sulfur compounds Chemical class 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VASZYFIKPKYGNC-UHFFFAOYSA-N 2-[[2-[bis(carboxymethyl)amino]cyclohexyl]-(carboxymethyl)amino]acetic acid;hydrate Chemical compound O.OC(=O)CN(CC(O)=O)C1CCCCC1N(CC(O)=O)CC(O)=O VASZYFIKPKYGNC-UHFFFAOYSA-N 0.000 description 2
- MYAQZIAVOLKEGW-UHFFFAOYSA-N 4,6-dimethyldibenzothiophene Chemical compound S1C2=C(C)C=CC=C2C2=C1C(C)=CC=C2 MYAQZIAVOLKEGW-UHFFFAOYSA-N 0.000 description 2
- NICUQYHIOMMFGV-UHFFFAOYSA-N 4-Methyldibenzothiophene Chemical compound S1C2=CC=CC=C2C2=C1C(C)=CC=C2 NICUQYHIOMMFGV-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- IYYZUPMFVPLQIF-ALWQSETLSA-N dibenzothiophene Chemical group C1=CC=CC=2[34S]C3=C(C=21)C=CC=C3 IYYZUPMFVPLQIF-ALWQSETLSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- VLXBWPOEOIIREY-UHFFFAOYSA-N dimethyl diselenide Natural products C[Se][Se]C VLXBWPOEOIIREY-UHFFFAOYSA-N 0.000 description 2
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000002828 fuel tank Substances 0.000 description 2
- 238000004128 high performance liquid chromatography Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000010734 process oil Substances 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 125000004434 sulfur atom Chemical group 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- DGUACJDPTAAFMP-UHFFFAOYSA-N 1,9-dimethyldibenzo[2,1-b:1',2'-d]thiophene Natural products S1C2=CC=CC(C)=C2C2=C1C=CC=C2C DGUACJDPTAAFMP-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- GBROPGWFBFCKAG-UHFFFAOYSA-N benzochrysene Natural products C1=CC2=C3C=CC=CC3=CC=C2C2=C1C1=CC=CC=C1C=C2 GBROPGWFBFCKAG-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- -1 fatty acid ester Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 210000002196 fr. b Anatomy 0.000 description 1
- 210000003918 fraction a Anatomy 0.000 description 1
- 210000000540 fraction c Anatomy 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 239000002816 fuel additive Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000035485 pulse pressure Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/04—Catalyst added to fuel stream to improve a reaction
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
(PAH測定前処理)
試料の一定量を測り取った後、n−ヘプタンで溶解した溶液をアルミナカートリッジカラムに注入した。次に、アルミナカラムに保持したPAH成分をトルエンで溶出し、溶出したトルエン溶液をトルエンで1mLに定容し、測定溶液とした。
下記の装置及び条件にてPAHの定量を行った。
GC装置: Agilent社製6890N型GC
検出器: Agilent社製5973N型四重極質量分析計
カラム: Agilent社製HP−5MS
液相: 95%ジメチルポリシロキサン−5%ジフェニルポリシロキサン
カラムサイズ: 内径0.25mm×30m、 膜厚=0.25ミクロン
カラムオーブン温度: 70℃(10分保持)→10℃/minで昇温→300℃(17分保持)
注入口温度: 290℃
トランスファーライン温度: 290℃
検出器温度: イオン源温度=230℃、四重極温度=150℃
カラム流量: 0.7mL
キャリアガス: ヘリウム
注入方法: パルスドスプリットレス 注入時パルス圧=25psi(1.5min)
スプリットベントライン: 50mL(1.5min)
SIM条件(定量イオン)
アセナフチレン=152、アセナフテン=154、フルオレン=166、フェナントレン及びアントラセン=178、フルオランテン及びピレン=202、ベンゾ[a]アントラセン及びクリセン=228、ベンゾ[b]フルオランテン, ベンゾ[k]フルオランテン, ベンゾ[a]ピレン=252、ベンゾ[g,h,i]ペリレン, インデノ[1,2,3−c,d]ピレン=276、ジベンゾ[a,h]アントラセン=278.
固定床流通式反応装置に水素化精製触媒HOP−414(NiMo触媒、ART K.K.製)100mLを充填し、水素圧力5.0MPa、10L/hで水素を流通させながら室温から150℃まで昇温し、その後、以下の手順で触媒を予備硫化した。硫化剤(市販軽油に1mass%の二硫化炭素を混合したもの)を水素圧力5.0MPa、水素/オイル比500NL/L、LHSV=2.0h-1、150℃の条件下で2時間通油した。その後、温度以外の条件を一定として硫化剤と水素の供給を継続し、20℃/hで230℃まで昇温して、4時間、230℃で一定とした。その後さらに、17.5℃/hで300℃まで昇温して、4時間、300℃で一定とした。この後、この硫化処理された水素化処理触媒を用いて下記軽油留分A(表1)の水素化精製反応を行った。なお、水素化精製反応は、水素圧力8.0MPa、水素/原料油供給比300NL/L、LHSV=1.2h-1及び反応温度352℃で行った。得られた生成油に含まれる高ユニットリスク化合物の合計量は0massppm、生成油中の硫黄分は1.3massppmであった。また、生成油に含まれる低ユニットリスク化合物の合計量は1.1massppm、ピレン含有量は8.7massppmであった(表2)。
水素圧6.5MPa、水素/原料油供給比350NL/L、LHSV=1.0h-1及び反応温度350℃とした以外は、実施例1と同じ装置・運転手順・原料油・触媒にて水素化精製反応を行った。得られた生成油に含まれる高ユニットリスク化合物の合計量は0massppm、生成油中の硫黄分は3.7massppmであった。また、生成油に含まれる低ユニットリスク化合物の合計量は0.4massppm、ピレン含有量は7.0massppmであった(表2)。
固定床流通式反応装置に水素化精製触媒HOP−467(CoMo触媒、ART K.K.製)を15m3、HOP−414(NiMo触媒、ART K.K.製)45m3を充填した。DMDSを用いて予備硫化した水素化処理触媒を用いて、下記軽油留分B(表1)の水素化精製反応を行った。なお、水素化精製反応は、反応器入口水素圧力6.8MPa、水素/原料油供給比300Nm3/KL、LHSV=1.0h-1、及び触媒重量平均温度350℃で行った。得られた生成油に含まれる高ユニットリスク化合物の合計量は0massppm、生成油中の硫黄分は7.4massppmであった。また、生成油に含まれる低ユニットリスク化合物の合計量は0.1massppm、ピレン含有量は10massppmであった(表2)。
固定床流通式反応装置に水素化精製触媒HOP−467(CoMo触媒、ART K.K.製)を40m3、HOP−414(NiMo触媒、ART K.K.製)20m3を充填した。DMDSを用いて予備硫化した水素化処理触媒を用いて、下記軽油留分C(表1)の水素化精製反応を行った。なお、水素化精製反応は、反応器入口水素圧力5.2MPa、水素/原料油供給比250Nm3/KL、LHSV=2.8h-1及び触媒重量平均温度370℃で行った。得られた生成油に含まれる高ユニットリスク化合物の合計量は0.5massppm、生成油中の硫黄分は38massppmであった。また、生成油に含まれる低ユニットリスク化合物の合計量は0.7massppm、ピレン含有量は9.8massppmであった(表2)。
水素圧5.0MPa、水素/原料油供給比200NL/L、LHSV=4.5h-1、反応器温度345℃とし、原料油を下記軽油留分D(表1)、触媒を水素化精製触媒HOP−467(CoMo触媒、ART K.K.製)100mLとした以外は、実施例1と同じ装置・運転手順にて水素化精製反応を行った。得られた生成油に含まれる高ユニットリスク化合物の合計量は0massppmであったが、生成油中の硫黄分は511massppmであった。また、生成油に含まれる低ユニットリスク化合物の合計量は0massppm、ピレン含有量は2.6massppmであった(表2)。
水素圧5.9MPa、水素/原料油供給比170NL/L、LHSV=0.9h-1、反応器温度345℃とし、原料油を下記軽油留分E(表1)、触媒を水素化精製触媒Z(CoMo触媒、Co:3.5mass%、Mo:15mass%)100mLとした以外は、実施例1と同じ装置・運転手順にて水素化精製反応を行った。得られた生成油に含まれる高ユニットリスク化合物の合計量は0.3massppm、生成油中の硫黄分は7.3massppmであった。また、生成油に含まれる低ユニットリスク化合物の合計量は3.0massppm、ピレン含有量は56massppmであった(表2)。
水素/原料油供給比を200NL/L、反応器温度を355℃とした以外は、比較例3と同じ装置・運転手順にて水素化精製反応を行った。得られた生成油に含まれる高ユニットリスク化合物の合計量は0.9massppm、生成油中の硫黄分は5.8massppmであった。また、生成油に含まれる低ユニットリスク化合物の合計量は1.1massppm、ピレン含有量は66massppmであった(表2)。
Claims (10)
- 全芳香族分が13〜18vol%、2環以上の芳香族分が0.5〜1.5vol%、90容量%留出温度が320〜360℃、硫黄分が10massppm以下であり、
高ユニットリスク化合物としてのベンゾ[a]アントラセン、クリセン、ベンゾ[b]フルオランテン、ベンゾ[k]フルオランテン、ベンゾ[a]ピレン、インデノ[1,2,3−c,d]ピレン及びジベンゾ[a,h]アントラセンの合計量が、0.1massppm未満を0massppmとして積算して0.2massppm以下であることを特徴とする軽油基材。 - 低ユニットリスク化合物としてのアセナフチレン、アセナフテン、フルオレン、アントラセン、フェナントレン、フルオランテン及びベンゾ[g,h,i]ペリレンの合計量が、0.1massppm未満を0massppmとして積算して0.1〜1.5massppmである請求項1に記載の軽油基材。
- ピレン含有量が5〜15massppmである請求項1又は2に記載の軽油基材。
- 活性金属元素として、ニッケル及びモリブデンを含む多孔質体を含む少なくとも1種類の触媒を用いて、芳香族低減処理のされていない石油由来の軽油留分の水素化精製を行うことを特徴とする請求項1〜3のいずれかに記載の軽油基材の製造方法。
- 前記水素化精製をLHSVが0.1〜2.0h-1の条件で行う請求項4に記載の軽油基材の製造方法。
- 全芳香族分が13〜18vol%、2環以上の芳香族分が0.5〜1.5vol%、90容量%留出温度が320〜360℃、硫黄分が10massppm以下であり、
高ユニットリスク化合物としてのベンゾ[a]アントラセン、クリセン、ベンゾ[b]フルオランテン、ベンゾ[k]フルオランテン、ベンゾ[a]ピレン、インデノ[1,2,3−c,d]ピレン及びジベンゾ[a,h]アントラセンの合計量が、0.1massppm未満を0massppmとして積算して0.2massppm以下であることを特徴とする軽油。 - 低ユニットリスク化合物としてのアセナフチレン、アセナフテン、フルオレン、アントラセン、フェナントレン、フルオランテン及びベンゾ[g,h,i]ペリレンの合計量が、0.1massppm未満を0massppmとして積算して0.1〜1.5massppmである請求項6に記載の軽油。
- ピレン含有量が5〜15massppmである請求項6又は7に記載の軽油。
- 活性金属元素として、ニッケル及びモリブデンを含む多孔質体を含む少なくとも1種類の触媒を用いて、芳香族低減処理のされていない石油由来の軽油留分の水素化精製を行うことを特徴とする請求項6〜8のいずれかに記載の軽油の製造方法。
- 前記水素化精製をLHSVが0.1〜2.0h-1の条件で行う請求項9に記載の軽油の製造方法。
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