JP4731357B2 - 化粧シート - Google Patents
化粧シート Download PDFInfo
- Publication number
- JP4731357B2 JP4731357B2 JP2006053526A JP2006053526A JP4731357B2 JP 4731357 B2 JP4731357 B2 JP 4731357B2 JP 2006053526 A JP2006053526 A JP 2006053526A JP 2006053526 A JP2006053526 A JP 2006053526A JP 4731357 B2 JP4731357 B2 JP 4731357B2
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- JP
- Japan
- Prior art keywords
- weight
- parts
- resin
- isocyanate
- aqueous composition
- Prior art date
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- 239000012948 isocyanate Substances 0.000 claims description 94
- 150000002513 isocyanates Chemical class 0.000 claims description 93
- 239000000203 mixture Substances 0.000 claims description 72
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 43
- 229920000728 polyester Polymers 0.000 claims description 38
- 239000000049 pigment Substances 0.000 claims description 19
- 238000010494 dissociation reaction Methods 0.000 claims description 18
- 230000005593 dissociations Effects 0.000 claims description 18
- 239000004606 Fillers/Extenders Substances 0.000 claims description 6
- 238000010030 laminating Methods 0.000 claims description 3
- 239000011342 resin composition Substances 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 79
- 229920005989 resin Polymers 0.000 description 69
- 239000011347 resin Substances 0.000 description 69
- -1 isocyanate compounds Chemical class 0.000 description 38
- 150000001875 compounds Chemical class 0.000 description 27
- 238000012360 testing method Methods 0.000 description 27
- 239000002585 base Substances 0.000 description 23
- 239000003795 chemical substances by application Substances 0.000 description 20
- 239000000463 material Substances 0.000 description 20
- 238000001723 curing Methods 0.000 description 19
- 239000011241 protective layer Substances 0.000 description 19
- 239000000853 adhesive Substances 0.000 description 15
- 238000010438 heat treatment Methods 0.000 description 15
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 15
- 230000001070 adhesive effect Effects 0.000 description 14
- 238000007639 printing Methods 0.000 description 14
- 239000011230 binding agent Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000004744 fabric Substances 0.000 description 12
- 238000004049 embossing Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 11
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- 239000000047 product Substances 0.000 description 9
- 125000006239 protecting group Chemical group 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 239000004743 Polypropylene Substances 0.000 description 8
- 230000000903 blocking effect Effects 0.000 description 8
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- 239000005060 rubber Substances 0.000 description 8
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- 229920005906 polyester polyol Polymers 0.000 description 7
- 239000004925 Acrylic resin Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 239000003086 colorant Substances 0.000 description 5
- 238000003475 lamination Methods 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- 239000005056 polyisocyanate Substances 0.000 description 5
- 229920001228 polyisocyanate Polymers 0.000 description 5
- 150000003077 polyols Chemical class 0.000 description 5
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- 239000004814 polyurethane Substances 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
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- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000012860 organic pigment Substances 0.000 description 4
- 239000011120 plywood Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 229920005672 polyolefin resin Polymers 0.000 description 4
- 239000002344 surface layer Substances 0.000 description 4
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- 238000004804 winding Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 244000043261 Hevea brasiliensis Species 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
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- 238000013461 design Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010894 electron beam technology Methods 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000007646 gravure printing Methods 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000001023 inorganic pigment Substances 0.000 description 3
- 239000004611 light stabiliser Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 229920003052 natural elastomer Polymers 0.000 description 3
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- 150000007524 organic acids Chemical class 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
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- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- 239000011118 polyvinyl acetate Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
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- VEZUQRBDRNJBJY-UHFFFAOYSA-N cyclohexanone oxime Chemical compound ON=C1CCCCC1 VEZUQRBDRNJBJY-UHFFFAOYSA-N 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
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- 150000002009 diols Chemical class 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 2
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- 150000002334 glycols Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- 229920000554 ionomer Polymers 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 150000003951 lactams Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
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- 230000003472 neutralizing effect Effects 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
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- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
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- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 2
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- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
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- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
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- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
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- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 1
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical group O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- GKZPEYIPJQHPNC-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GKZPEYIPJQHPNC-UHFFFAOYSA-N 0.000 description 1
- KAJBSGLXSREIHP-UHFFFAOYSA-N 2,2-bis[(2-sulfanylacetyl)oxymethyl]butyl 2-sulfanylacetate Chemical compound SCC(=O)OCC(CC)(COC(=O)CS)COC(=O)CS KAJBSGLXSREIHP-UHFFFAOYSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- FTALTLPZDVFJSS-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl prop-2-enoate Chemical compound CCOCCOCCOC(=O)C=C FTALTLPZDVFJSS-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
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Description
(1)基材シートの裏面に水性組成物から形成されるプライマー層を有し、
(2)水性組成物は、ポリエステル系ウレタン樹脂、イソシアネート及び熱解離型ブロックイソシアネートを含有し、
(3)水性組成物は、ポリエステル系ウレタン樹脂100重量部に対して、イソシアネートを21重量部以上28重量部以下含有し、
(4)水性組成物は、ポリエステル系ウレタン樹脂100重量部に対して、熱解離型ブロックイソシアネートを11重量部以上35重量部以下含有する、
ことを特徴とする化粧シート。
(1)ポリエステル系ウレタン樹脂、イソシアネート及び熱解離型ブロックイソシアネートを含有し、
(2)ポリエステル系ウレタン樹脂100重量部に対して、イソシアネートを21重量部以上28重量部以下含有し、
(3)ポリエステル系ウレタン樹脂100重量部に対して、熱解離型ブロックイソシアネートを11重量部以上35重量部以下含有する、
ことを特徴とする水性組成物。
(1)基材シートの裏面に水性組成物から形成されるプライマー層を有し、
(2)水性組成物は、ポリエステル系ウレタン樹脂、イソシアネート及び熱解離型ブロックイソシアネートとを含有し、
(3)水性組成物は、ポリエステル系ウレタン樹脂100重量部に対して、イソシアネートを20重量部以上50重量部未満含有し、
(4)水性組成物は、ポリエステル系ウレタン樹脂100重量部に対して、熱解離型ブロックイソシアネートを11重量部以上65重量部以下含有する、
ことを特徴とする。
本発明で用いる水性組成物は、ポリエステル系ウレタン樹脂、イソシアネート及び熱解離型ブロックイソシアネートを含有する。なお、イソシアネートと熱解離型ブロックイソシアネートとは異なる。イソシアネート(主にイソシアネート化合物)はポリエステル系ウレタン樹脂の硬化に用いる硬化剤である。他方、熱解離型ブロックイソシアネートは、前記イソシアネートの遊離イソシアネート基に化合物(保護基)を結合させたものであり、加熱により解離してイソシアネートを再生する。即ち、熱解離型ブロックイソシアネートは硬化剤の前躯体と言える。このような熱解離型ブロックイソシアネートは、それ自体は水と接触しても失活せず、加熱により保護基が外れてイソシアネートを再生するため、例えば、製造工程における加熱の際にイソシアネートを補充できる。特にシートを加熱軟化させて凹凸模様を圧賦形するエンボス工程は、シートに加える熱温度・熱量が大きく、熱解離型ブロックイソシアネートの保護基を解離させる機会として好ましい。本明細書では、イソシアネートを硬化剤と称して、イソシアネート及び熱解離型ブロックイソシアネート以外の成分を水性組成物の主剤と称する。
ポリエステル系ウレタン樹脂は裏面プライマー層を構成する樹脂成分である。ポリエステル系ウレタン樹脂は、基本的には、ポリエステルポリオールとジイソシアネート化合物との反応生成物からなる。
水性組成物は、ポリエステル系ウレタン樹脂100重量部に対して、イソシアネートを20重量部以上50重量部未満含有する。
(1)脂肪族ポリイソシアネート化合物(例えば、テトラメチレンジイソシアネート、ヘキサメチレンジイソシアネート)、
(2)脂環族ポリイソシアネート化合物(例えば、1,4シクロヘキサジイソシアネート、イソホロンジイソシアネート、1−メチル−2,4−シクロヘキサジイソシアネート、1−メチル−2,6−シクロヘキサジイソシアネート)、
(3)芳香族ポリイソシアネート化合物(例えば、キシリレンジイソシアネート、4,4’−ジフェニルジイソシアネート、2,4−トリレンジイソシアネート、2,6−トリレンジイソシアネート、m−フェニレンジイソシアネート、p−フェニレンジイソシアネート、4,4’−ジフェニルメタンジイソシアネート、1,5−ナフチレンジイソシアネート)、等が挙げられる。
水性組成物は、ポリエステル系ウレタン樹脂100重量部に対して、熱解離型ブロックイソシアネートを11重量部以上65重量部以下含有する。
本発明の化粧シートは、上記(1)〜(4)の要件を具備している限り、層構成は限定されない。即ち、上記水性組成物により形成されたプライマー層が基材シートの裏面に設けられる限り、基材シート表面(おもて面)の層構成は特に限定されない。
基材シートは、その表面(おもて面)には絵柄層等が順次積層される。
絵柄層は、化粧シートに所望の絵柄(意匠)を付与するものであり、絵柄の種類等は限定的ではない。例えば、木目模様、石目模様、砂目模様、タイル貼模様、煉瓦積模様、布目模様、皮絞模様、幾何学図形、文字、記号、抽象模様等が挙げられる。
接着剤層は、絵柄層と透明性樹脂層との間に存在する。接着剤層で使用する接着剤は、絵柄層又は透明性樹脂層を構成する成分等に応じて適宜選択することができる。例えば、ポリウレタン系樹脂、ポリアクリル系樹脂、ポリカーボネート系樹脂、エポキシ系樹脂等を含む接着剤を使用できる。また、反応硬化タイプのほか、ホットメルトタイプ、電離放射線硬化タイプ、紫外線硬化タイプ等の接着剤でもよい。
透明性樹脂層は透明である限り着色されていてもよく、絵柄層が視認できる範囲内で半透明であってもよい。
本発明において、透明性保護層は、最表面層として設けられている。透明性保護層は、透明である限り、着色されていてもよい。
透明性保護層(化粧シートの最表面)は、エンボス加工されていてもよい。さらには、エンボス加工による凹部にインキを充填するワイピング加工を施し、その表面を2液硬化型ウレタン系樹脂で被覆(オーバーコート処理)するのが好ましい。
本発明の化粧板は、本発明の化粧シートと被着材とを積層したものである。具体的には、化粧シートの透明性保護層が最表面層となるように化粧シートを被着材上に積層する。
被着材としては限定的ではない。例えば、木質材料、金属、セラミックス、プラスチックス、ガラス等が挙げられる。本発明化粧シートは、木質材料に好適に適用できる。木質材料としては、具体的には、杉、檜、欅、松、ラワン、チーク、メラピー等の各種素材から作られた突板、木材単板、木材合板、パティクルボード、中密度繊維板(MDF)等が挙げられる。
化粧シートの被着材への積層は、公知の化粧シートの積層と同様にすることができる。例えば、接着剤を用いて化粧シートを被着材上に貼着することにより積層できる。
2 絵柄層
3 接着剤層
4 透明ポリプロピレン系樹脂フィルム(透明性樹脂層)
5 透明性保護層
6 プライマー層
図1に示す層構成の化粧シートを作製した。
印刷原反(作製直後)のシートを巻取り、絵柄層2とプライマー層6とを密着させた。
初期密着試験は、印刷原反を室温で一日放置後、プライマー層6と樹脂フィルム1との密着性を評価するものである。
化粧シートのプライマー層6と合板とを、接着剤「BA10L(中央理化工業株式会社製)」により貼着して化粧板を作製した。接着剤の使用量は8g(wet)/尺とした。
絵柄層2を形成せずに樹脂フィルム1(原反)の裏面にプライマー層6を形成した状態のシートを一旦巻取り、巻取り状態を12時間保持した以外は、前記参考例1と同様にして化粧シートを作製した。
実施例及び比較例において、印刷原反を一旦巻取り、巻取り状態を12時間保持した以外は、前記実施例1と同様にして化粧シートを作製した。
表2の結果のうち、耐ブロッキング性及び初期密着性の観点からは、樹脂成分100重量部に対するイソシアネートの含有量は、下限値を20重量部程度とすることが好ましいことが分かる。
水性組成物に更に熱解離型ブロックイソシアネート(品番「AQB−102」、日本ポリウレタン工業株式会社製、解離温度140℃)を配合した以外は、参考例1と同様にして印刷原反及び化粧シートを作製した。
Claims (5)
- 基材シートの表面上に1又は2以上の層が積層されてなる化粧シートであって、
(1)基材シートの裏面に水性組成物から形成されるプライマー層を有し、
(2)水性組成物は、ポリエステル系ウレタン樹脂、イソシアネート及び熱解離型ブロックイソシアネートを含有し、
(3)水性組成物は、ポリエステル系ウレタン樹脂100重量部に対して、イソシアネートを21重量部以上28重量部以下含有し、
(4)水性組成物は、ポリエステル系ウレタン樹脂100重量部に対して、熱解離型ブロックイソシアネートを11重量部以上35重量部以下含有する、
ことを特徴とする化粧シート。 - 熱解離型ブロックイソシアネートは、解離温度が100〜160℃である、請求項1に記載の化粧シート。
- 水性組成物は、更に体質顔料を含有する、請求項1又は2に記載の化粧シート。
- 請求項1〜3のいずれかに記載の化粧シートと被着材とを積層してなる化粧板。
- 化粧シートの裏面プライマー層の形成に用いられる水性組成物であって、
(1)ポリエステル系ウレタン樹脂、イソシアネート及び熱解離型ブロックイソシアネートを含有し、
(2)ポリエステル系ウレタン樹脂100重量部に対して、イソシアネートを21重量部以上28重量部以下含有し、
(3)ポリエステル系ウレタン樹脂100重量部に対して、熱解離型ブロックイソシアネートを11重量以上35重量部以下含有する、
ことを特徴とする水性組成物。
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