JP4715130B2 - 接着剤組成物とそれを用いた積層体 - Google Patents
接着剤組成物とそれを用いた積層体 Download PDFInfo
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- JP4715130B2 JP4715130B2 JP2004242191A JP2004242191A JP4715130B2 JP 4715130 B2 JP4715130 B2 JP 4715130B2 JP 2004242191 A JP2004242191 A JP 2004242191A JP 2004242191 A JP2004242191 A JP 2004242191A JP 4715130 B2 JP4715130 B2 JP 4715130B2
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- crystalline polyester
- polyester
- thermoplastic resin
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Landscapes
- Adhesives Or Adhesive Processes (AREA)
Description
ン(C)を含む接着剤組成物である。
本発明で言う結晶性ポリエステルとは以下のように定義する。まずポリエステル試料を120℃で一時間熱処理を行い、25℃で48時間放置する。次に示差走査型熱量計(DSC)を用いて、その熱処理試料の測定を行う。測定条件は窒素雰囲気下、−100℃〜300℃まで20℃/minで昇温し、次に−100℃まで50℃/minで降温し、続いて−100℃〜300℃まで20℃/minで昇温する。その2度の昇温過程において、どちらかの昇温過程に明確な融点ピークを示すものを結晶性ポリエステルとする。いずれの昇温過程においても結晶融解ピークが見られないものを非晶性ポリエステルとする。
熱可塑性樹脂(B)としては、ポリエチレン、ポリプロピレンなどのポリオレフィン、ポリスチレン、ポリ塩化ビニル、ポリウレタン、シリコン、上記結晶性ポリエステル(A)とは組成が異なるポリエステル、ポリアミドなどから選ばれる1種以上を使用することが好ましい。中でも、接着剤として用いる場合、室温、低温雰囲気下での接着性が要求されることから、熱可塑性樹脂(B)としてはガラス転移点が30℃以下、好ましくは0℃以下さらに好ましくは−40℃以下である。下限は−100℃以上が好ましい。特にJIS K 7215の測定条件における熱可塑性樹脂(B)のショアA硬度としては60〜98であることが好ましい。さらに好ましくは70〜95である。ショアA硬度が60未満であると最終的な樹脂組成物の力学物性が低下し、一方、98以上であると最終的な樹脂組成物が非常に硬くなり、接着性を大幅に低下させてしまう場合がある。一方、ショアA硬度が60〜98の熱可塑性樹脂(B)は、適度に柔軟なであることから結晶性ポリエステル(A)の結晶化進行に伴うひずみエネルギーを効果的に緩和することができ、経時的な接着強度低下を抑制することもできる。
撹拌機、温度計、溜出用冷却管を装備した反応缶内に、テレフタル酸130部、イソフタル酸37部、エチレングリコール124部、酸成分に対し0.04mol%の三酸化アンチモン、最終的な樹脂量に対しNa量が10ppmになるように酢酸ナトリウムを仕込み、180〜240℃の温度において、3時間加圧下でエステル化反応を実施した。エステル化反応終了後、反応系を240℃から260℃に昇温する一方、系内を徐々に減圧していき、60分かけて500Paとした。そして、さらに130Pa以下で2時間重縮合反応を行い、結晶性ポリエステル(A−1)を得た。結晶性ポリエステル(A−1)はNMR分析の結果、テレフタル酸78モル%、イソフタル酸22モル%、エチレングリコール100モル%の組成を有しており、溶融粘度が15000dPa・s、ガラス転移温度70℃、融点190℃であった。
結晶性ポリエステル樹脂(B−2)のは合成例1と同様の手法により得た。ただし、組成を変更させた結晶性ポリエステル(A−2)、(A−3)、(A−4)、(B−1)については、触媒として酸成分の0.06mol%のテトラブチルチタネートを用い、加圧せずに常圧でエステル化反応を実施した。また、共重合成分としてポリテトラメチレングリコールが含まれる場合は、エステル化終了後、酸化防止剤であるイルガノックス1330(チバスペシャリティケミカル社製)を重合終了後の樹脂量に対し0.1wt%となるように添加し、その後重縮合を行った。
結晶性ポリエステル(A−1)100部、エチレン−プロピレン共重合体(住友化学社製 エクセレンEP3721)50部、ダイニオンPTFE(ダイニオン社製)3部を200℃にて二軸スクリュー式押出し機にて混練した。得られた接着剤を50μmの二軸延伸PETフィルムの上に、スクリュー径30mmφ、Tダイ幅200mmの押し出し機(プラ技研製)を用いて、200℃の温度で接着剤厚が30μmとなるように押し出し、接着テープを得た。この接着テープを用いて、下記の評価を行った。
以下同様にして実施例1〜3、比較例1〜6、7を作製し評価を行った。結果を表2に示した。ただし、比較例1は、ポリエステルの融点が200℃を超える場合の比較例であり、特別に260℃で押出しラミネートを行った。
Claims (12)
- 融点が200℃以下の結晶性ポリエステル(A)、熱可塑性樹脂(B)、ポリテトラフルオロエチレン(C)を含み、
前記熱可塑性樹脂(B)が、軟質ポリオレフィン、オレフィン系エラストマーまたはスチレン系エラストマーであり、
前記ポリテトラフルオロエチレン(C)がアクリル系樹脂で改質されているものであり、
かつ以下の(a)〜(c)の全てを満足することを特徴とする接着剤組成物。
(a)融点が200℃以下の結晶性ポリエステル(A)を100重量部とした場合、熱可塑性樹脂(B)を0.5〜110重量部含有する。
(b)融点が200℃以下の結晶性ポリエステル(A)を100重量部とした場合、ポリテトラフルオロエチレン(C)を0.0001〜10重量部含有する。
(c)接着剤組成物の200℃、せん断速度50s-1における溶融粘度が500dPa・s〜50000dPa・sである。 - 結晶性ポリエステル(A)のガラス転移点が30℃以下であることを特徴とする請求項1に記載の接着剤組成物。
- 熱可塑性樹脂(B)のガラス転移点が30℃以下であることを特徴とする請求項1または2に記載の接着剤組成物。
- JIS K 7215の測定条件における熱可塑性樹脂(B)のショアA硬度が60〜98であることを特徴とする請求項1〜3のいずれかに記載の接着剤組成物。
- 前記結晶性ポリエステル(A)のポリオール成分としてポリエーテルグリコールが共重合されていることを特徴とする請求項1〜4のいずれかに記載の接着剤組成物。
- 前記熱可塑性樹脂(B)が、低密度ポリエチレン、超低密度ポリエチレン、エチレンプロピレンエラストマー、エチレン−α−オレフィン共重合体、およびスチレン−ブタジエン−スチレン共重合体の部分水添物または完全水添物のいずれかである請求項1〜5のいずれかに記載の接着剤組成物。
- 熱可塑性樹脂(B)がカルボキシル基および/またはグリシジル基を有することを特徴とする請求項1〜6のいずれかに記載の接着剤組成物。
- さらにエポキシ樹脂(D)を含有することを特徴とする請求項1〜7のいずれかに記載の接着剤組成物。
- 前記結晶性ポリエステル(A)を100重量部とした場合、前記エポキシ樹脂(D)を80重量部以下含有する請求項8に記載の接着剤組成物。
- 請求項1〜9のいずれかに記載の接着剤組成物を用いた積層体。
- 請求項1〜9のいずれかに記載の接着剤組成物を用いたフレキシブルフラットケーブル。
- 請求項1〜9のいずれかに記載の接着剤組成物を用いたフレキシブルプリント配線基板。
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