JP4546163B2 - Copper or copper alloy surface treatment agent and soldering method - Google Patents
Copper or copper alloy surface treatment agent and soldering method Download PDFInfo
- Publication number
- JP4546163B2 JP4546163B2 JP2004173115A JP2004173115A JP4546163B2 JP 4546163 B2 JP4546163 B2 JP 4546163B2 JP 2004173115 A JP2004173115 A JP 2004173115A JP 2004173115 A JP2004173115 A JP 2004173115A JP 4546163 B2 JP4546163 B2 JP 4546163B2
- Authority
- JP
- Japan
- Prior art keywords
- chlorophenyl
- bromophenyl
- imidazole
- copper
- solder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims description 37
- 239000010949 copper Substances 0.000 title claims description 36
- 238000000034 method Methods 0.000 title claims description 25
- 239000012756 surface treatment agent Substances 0.000 title claims description 24
- 238000005476 soldering Methods 0.000 title claims description 20
- 229910000881 Cu alloy Inorganic materials 0.000 title claims description 14
- 229910000679 solder Inorganic materials 0.000 claims description 79
- -1 imidazole compound Chemical class 0.000 claims description 35
- 229910052802 copper Inorganic materials 0.000 claims description 34
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 32
- 239000000126 substance Substances 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 238000004381 surface treatment Methods 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 239000004480 active ingredient Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- FHHCKYIBYRNHOZ-UHFFFAOYSA-N 2,5-diphenyl-1h-imidazole Chemical class C=1N=C(C=2C=CC=CC=2)NC=1C1=CC=CC=C1 FHHCKYIBYRNHOZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- LQBJWKCYZGMFEV-UHFFFAOYSA-N lead tin Chemical compound [Sn].[Pb] LQBJWKCYZGMFEV-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 10
- 230000005496 eutectics Effects 0.000 description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- 239000006071 cream Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- WZWWEVCLPKAQTA-UHFFFAOYSA-N 2-bromo-1-(2-chlorophenyl)ethanone Chemical compound ClC1=CC=CC=C1C(=O)CBr WZWWEVCLPKAQTA-UHFFFAOYSA-N 0.000 description 6
- FPYUJUBAXZAQNL-UHFFFAOYSA-N 2-chlorobenzaldehyde Chemical compound ClC1=CC=CC=C1C=O FPYUJUBAXZAQNL-UHFFFAOYSA-N 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- 150000002460 imidazoles Chemical class 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- 238000007739 conversion coating Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- OZOQTOKASOCRJR-UHFFFAOYSA-N 2-(2-chlorophenyl)-5-phenyl-1h-imidazole Chemical compound ClC1=CC=CC=C1C1=NC=C(C=2C=CC=CC=2)N1 OZOQTOKASOCRJR-UHFFFAOYSA-N 0.000 description 3
- XXKGSLIUZMOWKX-UHFFFAOYSA-N 2-(4-chlorophenyl)-5-methyl-4-phenyl-1h-imidazole Chemical compound CC=1NC(C=2C=CC(Cl)=CC=2)=NC=1C1=CC=CC=C1 XXKGSLIUZMOWKX-UHFFFAOYSA-N 0.000 description 3
- RYAFXUYSBDAZBC-UHFFFAOYSA-N 2-(4-chlorophenyl)-5-phenyl-1h-imidazole Chemical compound C1=CC(Cl)=CC=C1C1=NC(C=2C=CC=CC=2)=CN1 RYAFXUYSBDAZBC-UHFFFAOYSA-N 0.000 description 3
- AVPYQKSLYISFPO-HOSYLAQJSA-N 4-chlorobenzaldehyde Chemical group ClC1=CC=C([13CH]=O)C=C1 AVPYQKSLYISFPO-HOSYLAQJSA-N 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Chemical class C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- 239000005749 Copper compound Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Chemical class O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001880 copper compounds Chemical class 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 150000002366 halogen compounds Chemical class 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- BGAXCPSNMHVHJC-UHFFFAOYSA-N phenacyl acetate Chemical compound CC(=O)OCC(=O)C1=CC=CC=C1 BGAXCPSNMHVHJC-UHFFFAOYSA-N 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 150000003505 terpenes Chemical class 0.000 description 3
- 235000007586 terpenes Nutrition 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Chemical class OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 3
- BVQVLAIMHVDZEL-UHFFFAOYSA-N 1-phenyl-1,2-propanedione Chemical compound CC(=O)C(=O)C1=CC=CC=C1 BVQVLAIMHVDZEL-UHFFFAOYSA-N 0.000 description 2
- JBKNZOIIBBKHOR-UHFFFAOYSA-N 2,5-bis(4-chlorophenyl)-1h-imidazole Chemical compound C1=CC(Cl)=CC=C1C1=CNC(C=2C=CC(Cl)=CC=2)=N1 JBKNZOIIBBKHOR-UHFFFAOYSA-N 0.000 description 2
- ASXXGYRRMAYECY-UHFFFAOYSA-N 2-(4-bromophenyl)-5-phenyl-1h-imidazole Chemical compound C1=CC(Br)=CC=C1C1=NC(C=2C=CC=CC=2)=CN1 ASXXGYRRMAYECY-UHFFFAOYSA-N 0.000 description 2
- PWHSTECTUQJALB-UHFFFAOYSA-N 4-(2-bromophenyl)-2-(2-chlorophenyl)-5-methyl-1H-imidazole Chemical compound CC1=C(N=C(N1)C2=CC=CC=C2Cl)C3=CC=CC=C3Br PWHSTECTUQJALB-UHFFFAOYSA-N 0.000 description 2
- LCXDCBBKYDARJZ-UHFFFAOYSA-N 4-(2-bromophenyl)-2-(3-chlorophenyl)-5-methyl-1H-imidazole Chemical compound CC1=C(N=C(N1)C2=CC(=CC=C2)Cl)C3=CC=CC=C3Br LCXDCBBKYDARJZ-UHFFFAOYSA-N 0.000 description 2
- LHLGLIWHKUEJAF-UHFFFAOYSA-N 4-(2-bromophenyl)-2-(4-chlorophenyl)-5-methyl-1H-imidazole Chemical compound CC1=C(N=C(N1)C2=CC=C(C=C2)Cl)C3=CC=CC=C3Br LHLGLIWHKUEJAF-UHFFFAOYSA-N 0.000 description 2
- JEJLPSCPPCHMFT-UHFFFAOYSA-N 4-(3-bromophenyl)-2-(2-chlorophenyl)-5-methyl-1H-imidazole Chemical compound CC1=C(N=C(N1)C2=CC=CC=C2Cl)C3=CC(=CC=C3)Br JEJLPSCPPCHMFT-UHFFFAOYSA-N 0.000 description 2
- ROCCJKWSUCDZKE-UHFFFAOYSA-N 4-(3-bromophenyl)-2-(3-chlorophenyl)-5-methyl-1H-imidazole Chemical compound CC1=C(N=C(N1)C2=CC(=CC=C2)Cl)C3=CC(=CC=C3)Br ROCCJKWSUCDZKE-UHFFFAOYSA-N 0.000 description 2
- OSLRCKLSAOQULL-UHFFFAOYSA-N 4-(3-bromophenyl)-2-(4-chlorophenyl)-5-methyl-1H-imidazole Chemical compound CC1=C(N=C(N1)C2=CC=C(C=C2)Cl)C3=CC(=CC=C3)Br OSLRCKLSAOQULL-UHFFFAOYSA-N 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- SGLZOUCEPBTEMM-UHFFFAOYSA-N 4-(4-bromophenyl)-2-(2-chlorophenyl)-5-methyl-1H-imidazole Chemical compound CC1=C(N=C(N1)C2=CC=CC=C2Cl)C3=CC=C(C=C3)Br SGLZOUCEPBTEMM-UHFFFAOYSA-N 0.000 description 2
- DZKFPZAXICYWRT-UHFFFAOYSA-N 4-(4-bromophenyl)-2-(3-chlorophenyl)-5-methyl-1H-imidazole Chemical compound CC1=C(N=C(N1)C2=CC(=CC=C2)Cl)C3=CC=C(C=C3)Br DZKFPZAXICYWRT-UHFFFAOYSA-N 0.000 description 2
- NIGCKOIGFOCGTM-UHFFFAOYSA-N 4-(4-bromophenyl)-2-(4-chlorophenyl)-5-methyl-1H-imidazole Chemical compound CC1=C(N=C(N1)C2=CC=C(C=C2)Cl)C3=CC=C(C=C3)Br NIGCKOIGFOCGTM-UHFFFAOYSA-N 0.000 description 2
- ZRYZBQLXDKPBDU-UHFFFAOYSA-N 4-bromobenzaldehyde Chemical group BrC1=CC=C(C=O)C=C1 ZRYZBQLXDKPBDU-UHFFFAOYSA-N 0.000 description 2
- AVPYQKSLYISFPO-UHFFFAOYSA-N 4-chlorobenzaldehyde Chemical compound ClC1=CC=C(C=O)C=C1 AVPYQKSLYISFPO-UHFFFAOYSA-N 0.000 description 2
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 description 2
- YSISTYWOUKXOFO-UHFFFAOYSA-N 5-(2-bromophenyl)-2-(2-chlorophenyl)-1H-imidazole Chemical compound C1=CC=C(C(=C1)C2=NC=C(N2)C3=CC=CC=C3Br)Cl YSISTYWOUKXOFO-UHFFFAOYSA-N 0.000 description 2
- BCVVARDVJHDEQJ-UHFFFAOYSA-N 5-(2-bromophenyl)-2-(3-chlorophenyl)-1H-imidazole Chemical compound C1=CC=C(C(=C1)C2=CN=C(N2)C3=CC(=CC=C3)Cl)Br BCVVARDVJHDEQJ-UHFFFAOYSA-N 0.000 description 2
- WWSGFOOUNZDWGF-UHFFFAOYSA-N 5-(2-bromophenyl)-2-(4-chlorophenyl)-1H-imidazole Chemical compound C1=CC=C(C(=C1)C2=CN=C(N2)C3=CC=C(C=C3)Cl)Br WWSGFOOUNZDWGF-UHFFFAOYSA-N 0.000 description 2
- QXZQHLRCAXEYDD-UHFFFAOYSA-N 5-(2-chlorophenyl)-2-phenyl-1H-imidazole Chemical compound C1(=CC=CC=C1)C=1NC=C(N=1)C1=C(C=CC=C1)Cl QXZQHLRCAXEYDD-UHFFFAOYSA-N 0.000 description 2
- VDROHLFCCOANBM-UHFFFAOYSA-N 5-(3-bromophenyl)-2-(2-chlorophenyl)-1H-imidazole Chemical compound C1=CC=C(C(=C1)C2=NC=C(N2)C3=CC(=CC=C3)Br)Cl VDROHLFCCOANBM-UHFFFAOYSA-N 0.000 description 2
- CNTCTCWRTYCQEC-UHFFFAOYSA-N 5-(3-bromophenyl)-2-(3-chlorophenyl)-1H-imidazole Chemical compound C1=CC(=CC(=C1)Cl)C2=NC=C(N2)C3=CC(=CC=C3)Br CNTCTCWRTYCQEC-UHFFFAOYSA-N 0.000 description 2
- PRULYHNZEFCXDV-UHFFFAOYSA-N 5-(3-bromophenyl)-2-(4-chlorophenyl)-1H-imidazole Chemical compound C1=CC(=CC(=C1)Br)C2=CN=C(N2)C3=CC=C(C=C3)Cl PRULYHNZEFCXDV-UHFFFAOYSA-N 0.000 description 2
- IDCDIKPZXQGVFW-UHFFFAOYSA-N 5-(4-bromophenyl)-2-(2-chlorophenyl)-1H-imidazole Chemical compound C1=CC=C(C(=C1)C2=NC=C(N2)C3=CC=C(C=C3)Br)Cl IDCDIKPZXQGVFW-UHFFFAOYSA-N 0.000 description 2
- YXXRFOYGINVWST-UHFFFAOYSA-N 5-(4-bromophenyl)-2-(3-chlorophenyl)-1h-imidazole Chemical compound ClC1=CC=CC(C=2NC=C(N=2)C=2C=CC(Br)=CC=2)=C1 YXXRFOYGINVWST-UHFFFAOYSA-N 0.000 description 2
- MMYZCIVKUFDBDZ-UHFFFAOYSA-N 5-(4-bromophenyl)-2-(4-chlorophenyl)-1H-imidazole Chemical compound BrC1=CC=C(C=C1)C=1N=C(NC=1)C1=CC=C(C=C1)Cl MMYZCIVKUFDBDZ-UHFFFAOYSA-N 0.000 description 2
- FDQQAONNYLSJIG-UHFFFAOYSA-N 5-(4-bromophenyl)-2-phenyl-1h-imidazole Chemical compound C1=CC(Br)=CC=C1C1=CN=C(C=2C=CC=CC=2)N1 FDQQAONNYLSJIG-UHFFFAOYSA-N 0.000 description 2
- ZYPUTCALNWHHED-UHFFFAOYSA-N 5-(4-chlorophenyl)-2-phenyl-1h-imidazole Chemical compound C1=CC(Cl)=CC=C1C1=CNC(C=2C=CC=CC=2)=N1 ZYPUTCALNWHHED-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- YZGQDNOIGFBYKF-UHFFFAOYSA-N Ethoxyacetic acid Chemical compound CCOCC(O)=O YZGQDNOIGFBYKF-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical compound CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 2
- QTMDXZNDVAMKGV-UHFFFAOYSA-L copper(ii) bromide Chemical compound [Cu+2].[Br-].[Br-] QTMDXZNDVAMKGV-UHFFFAOYSA-L 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 125000002883 imidazolyl group Chemical group 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 235000002639 sodium chloride Nutrition 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 150000003752 zinc compounds Chemical class 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- 0 *c1c(-c2ccccc2)nc(-c2ccccc2)[n]1 Chemical compound *c1c(-c2ccccc2)nc(-c2ccccc2)[n]1 0.000 description 1
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- FTUYTARZCNUSDA-UHFFFAOYSA-N [2-(4-chlorophenyl)-2-oxoethyl] acetate Chemical group CC(=O)OCC(=O)C1=CC=C(Cl)C=C1 FTUYTARZCNUSDA-UHFFFAOYSA-N 0.000 description 1
- RAOSIAYCXKBGFE-UHFFFAOYSA-K [Cu+3].[O-]P([O-])([O-])=O Chemical compound [Cu+3].[O-]P([O-])([O-])=O RAOSIAYCXKBGFE-UHFFFAOYSA-K 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 229940107816 ammonium iodide Drugs 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229920006272 aromatic hydrocarbon resin Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- LZCZIHQBSCVGRD-UHFFFAOYSA-N benzenecarboximidamide;hydron;chloride Chemical compound [Cl-].NC(=[NH2+])C1=CC=CC=C1 LZCZIHQBSCVGRD-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 229910001956 copper hydroxide Inorganic materials 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- NKNDPYCGAZPOFS-UHFFFAOYSA-M copper(i) bromide Chemical compound Br[Cu] NKNDPYCGAZPOFS-UHFFFAOYSA-M 0.000 description 1
- GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- 229940045803 cuprous chloride Drugs 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 235000011087 fumaric acid Nutrition 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-M hydrosulfide Chemical compound [SH-] RWSOTUBLDIXVET-UHFFFAOYSA-M 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940040102 levulinic acid Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- RMIODHQZRUFFFF-UHFFFAOYSA-N methoxyacetic acid Chemical compound COCC(O)=O RMIODHQZRUFFFF-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- BSCHIACBONPEOB-UHFFFAOYSA-N oxolane;hydrate Chemical compound O.C1CCOC1 BSCHIACBONPEOB-UHFFFAOYSA-N 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 229940107700 pyruvic acid Drugs 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- WEZYFYMYMKUAHY-UHFFFAOYSA-N tert-butyl 2,4-dibenzylpiperazine-1-carboxylate Chemical compound C1C(CC=2C=CC=CC=2)N(C(=O)OC(C)(C)C)CCN1CC1=CC=CC=C1 WEZYFYMYMKUAHY-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229910001174 tin-lead alloy Inorganic materials 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000011746 zinc citrate Substances 0.000 description 1
- 235000006076 zinc citrate Nutrition 0.000 description 1
- 229940068475 zinc citrate Drugs 0.000 description 1
- SRWMQSFFRFWREA-UHFFFAOYSA-M zinc formate Chemical compound [Zn+2].[O-]C=O SRWMQSFFRFWREA-UHFFFAOYSA-M 0.000 description 1
- 239000011576 zinc lactate Substances 0.000 description 1
- 235000000193 zinc lactate Nutrition 0.000 description 1
- 229940050168 zinc lactate Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- ZPEJZWGMHAKWNL-UHFFFAOYSA-L zinc;oxalate Chemical compound [Zn+2].[O-]C(=O)C([O-])=O ZPEJZWGMHAKWNL-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Chemical Treatment Of Metals (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Non-Metallic Protective Coatings For Printed Circuits (AREA)
Description
本発明は、電子部品などをプリント配線板の銅回路部等に無鉛半田を用いて半田付けする際に使用する表面処理剤及び、該表面処理剤を使用する半田付け方法に関するものである。 The present invention relates to a surface treatment agent used when soldering an electronic component or the like to a copper circuit portion or the like of a printed wiring board using lead-free solder, and a soldering method using the surface treatment agent.
近時プリント配線板の実装方法として、実装密度を向上させた表面実装が広く採用されている。このような表面実装方法は、チップ部品をクリーム半田で接合する両面表面実装、チップ部品のクリーム半田による表面実装とディスクリート部品のスルホール実装を組み合わせた混載実装等に分けられる。いずれの実装方法においても、プリント配線板は複数回の半田付けが行われるので、その度に高温に曝されて厳しい熱履歴を受ける。
その結果、プリント配線板の回路部を構成する銅または銅合金の表面は、加熱されることにより酸化皮膜の形成が促進されるので、該回路部表面の半田付け性を良好に保つことができない。
Recently, surface mounting with improved mounting density has been widely adopted as a method for mounting printed wiring boards. Such surface mounting methods can be classified into double-sided surface mounting in which chip components are joined by cream solder, mixed mounting in which surface mounting by chip solder cream soldering and through-hole mounting of discrete components are combined. In any mounting method, since the printed wiring board is soldered a plurality of times, it is exposed to a high temperature each time and receives a severe thermal history.
As a result, the surface of the copper or copper alloy constituting the circuit portion of the printed wiring board is heated to promote the formation of an oxide film, so that the solderability of the surface of the circuit portion cannot be kept good. .
このようなプリント配線板の銅回路部を空気酸化から保護するために、表面処理剤を使用して該回路部表面に化成被膜を形成させる処理が広く行われているが、銅回路部が複数回の熱履歴を受けた後も化成被膜が変成(劣化)することなく銅回路部を保護し、これによって半田付け性を良好なものに保つことが要求されている。 In order to protect the copper circuit portion of such a printed wiring board from air oxidation, a treatment for forming a chemical conversion film on the surface of the circuit portion using a surface treatment agent is widely performed. It is required to protect the copper circuit portion without changing (deteriorating) the chemical conversion film even after receiving the heat history of the times, thereby maintaining good solderability.
従来から電子部品をプリント配線板などに接合する際には、錫−鉛合金の共晶半田が広く使用されていたが、近年その半田合金中に含まれる鉛による人体への有害性が懸念され、鉛を含まない半田を使用することが求められている。
そのために種々の無鉛半田が検討されているが、例えば錫をベース金属として、銀、亜鉛、ビスマス、インジウム、アンチモンや銅などの金属を添加した無鉛半田が提案されている。
Conventionally, tin-lead alloy eutectic solder has been widely used for joining electronic components to printed wiring boards, etc., but in recent years there is concern about the harmfulness of the lead contained in the solder alloy to the human body. There is a need to use solder that does not contain lead.
For this purpose, various lead-free solders have been studied. For example, lead-free solders having a metal such as silver, zinc, bismuth, indium, antimony and copper as a base metal have been proposed.
ところで、従来の錫−鉛系共晶半田は、接合母材、特に銅の表面に対する濡れ性に優れており、銅に対して強固に接合するので、高い信頼性が得られている。
これに対して、無鉛半田は従来の錫−鉛半田に比べると、銅の表面に対する濡れ性が劣っているので、半田付け性が悪く、ボイド発生などの接合不良が生じ、接合強度も低いものであった。
そのため無鉛半田を使用するに当たっては、より半田付け性の良好な半田合金および無鉛半田に適したフラックスの選定が求められているが、銅または銅合金表面の酸化防止のために使用される表面処理剤に対しても、無鉛半田の濡れ性を改善し半田付け性を良好なものとする機能が求められている。
また、無鉛半田の多くは融点が高く、半田付け温度が従来の錫−鉛系共晶半田に比べて20〜50℃程高くなるため、当該表面処理剤に対しは、優れた耐熱性を有する化成被膜を形成させることも望まれている。
By the way, the conventional tin-lead eutectic solder is excellent in the wettability with respect to the joining base material, especially copper surface, and since it joins firmly with respect to copper, high reliability is acquired.
In contrast, lead-free solder is inferior in wettability to the copper surface compared to conventional tin-lead solder, so solderability is poor, bonding defects such as voids occur, and bonding strength is low Met.
Therefore, when using lead-free solder, selection of a solder alloy with better solderability and a flux suitable for lead-free solder is required, but surface treatment used to prevent oxidation of copper or copper alloy surfaces Also for the agent, a function of improving the wettability of the lead-free solder and improving the solderability is required.
In addition, many lead-free solders have a high melting point, and the soldering temperature is about 20 to 50 ° C. higher than that of conventional tin-lead eutectic solders. Therefore, the surface treatment agent has excellent heat resistance. It is also desired to form a conversion coating.
このような表面処理剤の有効成分として、2−アルキルイミダゾール、2−アリールイミダゾール、2−アルキルベンズイミダゾール、2−アリールベンズイミダゾール、2−アラルキルベンズイミダゾール化合物等の数多くのイミダゾール化合物が検討されてきたが、何れのイミダゾール化合物も、錫−鉛系共晶半田用に検討されてきたものであり、無鉛半田を用いて半田付けを行う際に使用した場合には、半田の濡れ性が未だ不十分なものであり、満足すべき半田付け性が得られていない。 Many active imidazole compounds such as 2-alkylimidazole, 2-arylimidazole, 2-alkylbenzimidazole, 2-arylbenzimidazole, and 2-aralkylbenzimidazole compounds have been studied as active ingredients of such surface treatment agents. However, any imidazole compound has been studied for tin-lead eutectic solder, and when used for soldering using lead-free solder, solder wettability is still insufficient. Therefore, satisfactory solderability is not obtained.
例えば、特許文献1〜3には、下記化1の一般式で示されるイミダゾール環の2位と4位にアリール基を有するイミダゾール化合物を有効成分とする表面処理剤が提案され、同文献1〜3の明細書には、使用し得るイミダゾール化合物として、
2−フェニル−4−(4−クロロフェニル)イミダゾール、
2−フェニル−4−(4−ブロモフェニル)イミダゾール、
2−(4−クロロフェニル)−4−フェニルイミダゾール、
2−(4−ブロモフェニル)−4−フェニルイミダゾール、
2−(4−クロロフェニル)−4−(4−クロロフェニル)イミダゾール及び、
2−(4−クロロフェニル)−4−フェニル−5−メチルイミダゾールが例示されているが、これらのイミダゾール化合物を有効成分とする表面処理剤が調製された例は、一切示されていない。
For example, Patent Documents 1 to 3 propose a surface treatment agent containing an imidazole compound having an aryl group at the 2-position and 4-position of the imidazole ring represented by the general formula of Chemical Formula 1 below as an active ingredient. In the specification of 3, as an imidazole compound that can be used,
2-phenyl-4- (4-chlorophenyl) imidazole,
2-phenyl-4- (4-bromophenyl) imidazole,
2- (4-chlorophenyl) -4-phenylimidazole,
2- (4-bromophenyl) -4-phenylimidazole,
2- (4-chlorophenyl) -4- (4-chlorophenyl) imidazole and
Although 2- (4-chlorophenyl) -4-phenyl-5-methylimidazole is exemplified, no examples of the preparation of surface treatment agents containing these imidazole compounds as active ingredients are shown.
また、同文献1〜3に記載された評価試験において使用された半田は、錫−鉛系の共晶半田であり、無鉛半田を使用した場合に半田濡れ性が改善され、半田付け性が良好なものとなる点についても示されていない。 In addition, the solder used in the evaluation tests described in the documents 1 to 3 is a tin-lead eutectic solder. When lead-free solder is used, solder wettability is improved and solderability is good. There is no indication of what would be a problem.
本発明は斯かる事情に鑑みてなされたものであって、無鉛半田を使用して電子部品等をプリント配線板に接合する際に、プリント配線板の回路部等を構成する銅または銅合金の表面と無鉛半田との濡れ性が向上し、半田付け性を良好なものとすることができる表面処理剤を提供することを目的とするものである。
また、本発明の今ひとつの目的は、銅または銅合金の表面を、前記の表面処理剤で処理した後に無鉛半田を使用して半田付けを行う半田付け方法を提供することにある。
The present invention has been made in view of such circumstances, and when bonding electronic components or the like to a printed wiring board using lead-free solder, the copper or copper alloy of the circuit portion or the like of the printed wiring board is formed. An object of the present invention is to provide a surface treating agent that improves the wettability between the surface and lead-free solder and can improve solderability.
Another object of the present invention is to provide a soldering method in which the surface of copper or copper alloy is treated with the surface treatment agent and then soldered using lead-free solder.
本発明者らは、前記の課題を解決するために鋭意検討を重ねた結果、化2の一般式で示される2,4−ジフェニルイミダゾール化合物から選ばれる少なくとも1つのイミダゾール化合物を有効成分として含有させた表面処理剤によって、銅回路部を有するプリント配線板を処理することにより、銅回路部の表面に耐熱性に優れた、即ち無鉛半田の半田付け温度に耐え得る化成被膜を形成させることができ、且つ無鉛半田を使用して半田付けを行うに際して、銅または銅合金の表面に対する無鉛半田の濡れ性を向上させることにより、良好な半田付け性が得られることを認め本発明を完成するに至ったものである。 As a result of intensive studies in order to solve the above-mentioned problems, the present inventors have contained at least one imidazole compound selected from 2,4-diphenylimidazole compounds represented by the general formula of Chemical Formula 2 as an active ingredient. By treating a printed wiring board having a copper circuit portion with the surface treatment agent, a chemical conversion film having excellent heat resistance, that is, capable of withstanding the soldering temperature of lead-free solder can be formed on the surface of the copper circuit portion. In addition, when soldering using lead-free solder, it is recognized that good solderability can be obtained by improving the wettability of lead-free solder to the surface of copper or copper alloy, and the present invention has been completed. It is a thing.
本発明の表面処理剤は、プリント配線板の回路部等を構成する銅または銅合金の表面に、耐熱性に優れた化成被膜を形成させることができると共に、該表面に対する無鉛半田の濡れ性を飛躍的に向上させ、無鉛半田の半田付け性を良好なものとすることができる。
また、本発明の半田付け方法は、有害金属である鉛を含まない半田の使用を可能とするので、環境保護の観点において有用なものである。
The surface treating agent of the present invention can form a chemical conversion film having excellent heat resistance on the surface of copper or copper alloy constituting the circuit portion or the like of a printed wiring board, and also provides the wettability of lead-free solder to the surface. This can dramatically improve the solderability of lead-free solder.
In addition, the soldering method of the present invention is useful from the viewpoint of environmental protection because it enables the use of solder that does not contain lead, which is a harmful metal.
以下、本発明について詳細に説明する。
本発明の実施に適する化2の一般式で示される2,4−ジフェニルイミダゾール化合物は、
(A)2−クロロフェニル−4−フェニルイミダゾール化合物、
(B)2−クロロフェニル−4−クロロフェニルイミダゾール化合物、
(C)2−フェニル−4−クロロフェニルイミダゾール化合物、
(D)2−ブロモフェニル−4−フェニルイミダゾール化合物、
(E)2−ブロモフェニル−4−ブロモフェニルイミダゾール化合物、
(F)2−フェニル−4−ブロモフェニルイミダゾール化合物、
(G)2−クロロフェニル−4−ブロモフェニルイミダゾール化合物及び、
(H)2−ブロモフェニル−4−クロロフェニルイミダゾール化合物である。
Hereinafter, the present invention will be described in detail.
The 2,4-diphenylimidazole compound represented by the general formula (2) suitable for the practice of the present invention is:
(A) 2-chlorophenyl-4-phenylimidazole compound,
(B) 2-chlorophenyl-4-chlorophenylimidazole compound,
(C) 2-phenyl-4-chlorophenylimidazole compound,
(D) 2-bromophenyl-4-phenylimidazole compound,
(E) 2-bromophenyl-4-bromophenylimidazole compound,
(F) 2-phenyl-4-bromophenylimidazole compound,
(G) a 2-chlorophenyl-4-bromophenylimidazole compound and
(H) 2-bromophenyl-4-chlorophenylimidazole compound.
(A)2−クロロフェニル−4−フェニルイミダゾール化合物としては、
2−(2−クロロフェニル)−4−フェニルイミダゾール、
2−(3−クロロフェニル)−4−フェニルイミダゾール、
2−(4−クロロフェニル)−4−フェニルイミダゾール、
2−(2−クロロフェニル)−4−フェニル−5−メチルイミダゾール、
2−(3−クロロフェニル)−4−フェニル−5−メチルイミダゾール及び、
2−(4−クロロフェニル)−4−フェニル−5−メチルイミダゾールが挙げられる。
(A) As a 2-chlorophenyl-4-phenylimidazole compound,
2- (2-chlorophenyl) -4-phenylimidazole,
2- (3-chlorophenyl) -4-phenylimidazole,
2- (4-chlorophenyl) -4-phenylimidazole,
2- (2-chlorophenyl) -4-phenyl-5-methylimidazole,
2- (3-chlorophenyl) -4-phenyl-5-methylimidazole and
2- (4-Chlorophenyl) -4-phenyl-5-methylimidazole is mentioned.
(B)2−クロロフェニル−4−クロロフェニルイミダゾール化合物としては、
2−(2−クロロフェニル)−4−(2−クロロフェニル)イミダゾール、
2−(2−クロロフェニル)−4−(3−クロロフェニル)イミダゾール、
2−(2−クロロフェニル)−4−(4−クロロフェニル)イミダゾール、
2−(3−クロロフェニル)−4−(2−クロロフェニル)イミダゾール、
2−(3−クロロフェニル)−4−(3−クロロフェニル)イミダゾール、
2−(3−クロロフェニル)−4−(4−クロロフェニル)イミダゾール、
2−(4−クロロフェニル)−4−(2−クロロフェニル)イミダゾール、
2−(4−クロロフェニル)−4−(3−クロロフェニル)イミダゾール、
2−(4−クロロフェニル)−4−(4−クロロフェニル)イミダゾール、
2−(2−クロロフェニル)−4−(2−クロロフェニル)−5−メチルイミダゾール、
2−(2−クロロフェニル)−4−(3−クロロフェニル)−5−メチルイミダゾール、
2−(2−クロロフェニル)−4−(4−クロロフェニル)−5−メチルイミダゾール、
2−(3−クロロフェニル)−4−(2−クロロフェニル)−5−メチルイミダゾール、
2−(3−クロロフェニル)−4−(3−クロロフェニル)−5−メチルイミダゾール、
2−(3−クロロフェニル)−4−(4−クロロフェニル)−5−メチルイミダゾール、
2−(4−クロロフェニル)−4−(2−クロロフェニル)−5−メチルイミダゾール、
2−(4−クロロフェニル)−4−(3−クロロフェニル)−5−メチルイミダゾール及び、
2−(4−クロロフェニル)−4−(4−クロロフェニル)−5−メチルイミダゾールが挙げられる。
(B) As 2-chlorophenyl-4-chlorophenylimidazole compound,
2- (2-chlorophenyl) -4- (2-chlorophenyl) imidazole,
2- (2-chlorophenyl) -4- (3-chlorophenyl) imidazole,
2- (2-chlorophenyl) -4- (4-chlorophenyl) imidazole,
2- (3-chlorophenyl) -4- (2-chlorophenyl) imidazole,
2- (3-chlorophenyl) -4- (3-chlorophenyl) imidazole,
2- (3-chlorophenyl) -4- (4-chlorophenyl) imidazole,
2- (4-chlorophenyl) -4- (2-chlorophenyl) imidazole,
2- (4-chlorophenyl) -4- (3-chlorophenyl) imidazole,
2- (4-chlorophenyl) -4- (4-chlorophenyl) imidazole,
2- (2-chlorophenyl) -4- (2-chlorophenyl) -5-methylimidazole,
2- (2-chlorophenyl) -4- (3-chlorophenyl) -5-methylimidazole,
2- (2-chlorophenyl) -4- (4-chlorophenyl) -5-methylimidazole,
2- (3-chlorophenyl) -4- (2-chlorophenyl) -5-methylimidazole,
2- (3-chlorophenyl) -4- (3-chlorophenyl) -5-methylimidazole,
2- (3-chlorophenyl) -4- (4-chlorophenyl) -5-methylimidazole,
2- (4-chlorophenyl) -4- (2-chlorophenyl) -5-methylimidazole,
2- (4-chlorophenyl) -4- (3-chlorophenyl) -5-methylimidazole and
2- (4-Chlorophenyl) -4- (4-chlorophenyl) -5-methylimidazole.
(C)2−フェニル−4−クロロフェニルイミダゾール化合物としては、
2−フェニル−4−(2−クロロフェニル)イミダゾール、
2−フェニル−4−(3−クロロフェニル)イミダゾール、
2−フェニル−4−(4−クロロフェニル)イミダゾール、
2−フェニル−4−(2−クロロフェニル)−5−メチルイミダゾール、
2−フェニル−4−(3−クロロフェニル)−5−イミダゾール及び、
2−フェニル−4−(4−クロロフェニル)−5−イミダゾールが挙げられる。
(C) As a 2-phenyl-4-chlorophenylimidazole compound,
2-phenyl-4- (2-chlorophenyl) imidazole,
2-phenyl-4- (3-chlorophenyl) imidazole,
2-phenyl-4- (4-chlorophenyl) imidazole,
2-phenyl-4- (2-chlorophenyl) -5-methylimidazole,
2-phenyl-4- (3-chlorophenyl) -5-imidazole and
2-phenyl-4- (4-chlorophenyl) -5-imidazole is mentioned.
(D)2−ブロモフェニル−4−フェニルイミダゾール化合物としては、
2−(2−ブロモフェニル)−4−フェニルイミダゾール、
2−(3−ブロモフェニル)−4−フェニルイミダゾール、
2−(4−ブロモフェニル)−4−フェニルイミダゾール、
2−(2−ブロモフェニル)−4−フェニル−5−メチルイミダゾール、
2−(3−ブロモフェニル)−4−フェニル−5−メチルイミダゾール、
2−(4−ブロモフェニル)−4−フェニル−5−メチルイミダゾール、
(D) As 2-bromophenyl-4-phenylimidazole compound,
2- (2-bromophenyl) -4-phenylimidazole,
2- (3-bromophenyl) -4-phenylimidazole,
2- (4-bromophenyl) -4-phenylimidazole,
2- (2-bromophenyl) -4-phenyl-5-methylimidazole,
2- (3-bromophenyl) -4-phenyl-5-methylimidazole,
2- (4-bromophenyl) -4-phenyl-5-methylimidazole,
(E)2−ブロモフェニル−4−ブロモフェニルイミダゾール化合物としては、
2−(2−ブロモフェニル)−4−(2−ブロモフェニル)イミダゾール、
2−(2−ブロモフェニル)−4−(3−ブロモフェニル)イミダゾール、
2−(2−ブロモフェニル)−4−(4−ブロモフェニル)イミダゾール、
2−(3−ブロモフェニル)−4−(2−ブロモフェニル)イミダゾール、
2−(3−ブロモフェニル)−4−(3−ブロモフェニル)イミダゾール、
2−(3−ブロモフェニル)−4−(4−ブロモフェニル)イミダゾール、
2−(4−ブロモフェニル)−4−(2−ブロモフェニル)イミダゾール、
2−(4−ブロモフェニル)−4−(3−ブロモフェニル)イミダゾール、
2−(4−ブロモフェニル)−4−(4−ブロモフェニル)イミダゾール、
2−(2−ブロモフェニル)−4−(2−ブロモフェニル)−5−メチルイミダゾール、
2−(2−ブロモフェニル)−4−(3−ブロモフェニル)−5−メチルイミダゾール、
2−(2−ブロモフェニル)−4−(4−ブロモフェニル)−5−メチルイミダゾール、
2−(3−ブロモフェニル)−4−(2−ブロモフェニル)−5−メチルイミダゾール、
2−(3−ブロモフェニル)−4−(3−ブロモフェニル)−5−メチルイミダゾール、
2−(3−ブロモフェニル)−4−(4−ブロモフェニル)−5−メチルイミダゾール、
2−(4−ブロモフェニル)−4−(2−ブロモフェニル)−5−メチルイミダゾール、
2−(4−ブロモフェニル)−4−(3−ブロモフェニル)−5−メチルイミダゾール及び、
2−(4−ブロモフェニル)−4−(4−ブロモフェニル)−5−メチルイミダゾールが挙げられる。
(E) As 2-bromophenyl-4-bromophenylimidazole compound,
2- (2-bromophenyl) -4- (2-bromophenyl) imidazole,
2- (2-bromophenyl) -4- (3-bromophenyl) imidazole,
2- (2-bromophenyl) -4- (4-bromophenyl) imidazole,
2- (3-bromophenyl) -4- (2-bromophenyl) imidazole,
2- (3-bromophenyl) -4- (3-bromophenyl) imidazole,
2- (3-bromophenyl) -4- (4-bromophenyl) imidazole,
2- (4-bromophenyl) -4- (2-bromophenyl) imidazole,
2- (4-bromophenyl) -4- (3-bromophenyl) imidazole,
2- (4-bromophenyl) -4- (4-bromophenyl) imidazole,
2- (2-bromophenyl) -4- (2-bromophenyl) -5-methylimidazole,
2- (2-bromophenyl) -4- (3-bromophenyl) -5-methylimidazole,
2- (2-bromophenyl) -4- (4-bromophenyl) -5-methylimidazole,
2- (3-bromophenyl) -4- (2-bromophenyl) -5-methylimidazole,
2- (3-bromophenyl) -4- (3-bromophenyl) -5-methylimidazole,
2- (3-bromophenyl) -4- (4-bromophenyl) -5-methylimidazole,
2- (4-bromophenyl) -4- (2-bromophenyl) -5-methylimidazole,
2- (4-bromophenyl) -4- (3-bromophenyl) -5-methylimidazole and
2- (4-Bromophenyl) -4- (4-bromophenyl) -5-methylimidazole.
(F)2−フェニル−4−ブロモフェニルイミダゾール化合物としては、
2−フェニル−4−(2−ブロモフェニル)イミダゾール、
2−フェニル−4−(3−ブロモフェニル)イミダゾール、
2−フェニル−4−(4−ブロモフェニル)イミダゾール、
2−フェニル−4−(2−ブロモフェニル)−5−メチルイミダゾール、
2−フェニル−4−(3−ブロモフェニル)−5−イミダゾール及び、
2−フェニル−4−(4−ブロモフェニル)−5−イミダゾールが挙げられる。
(F) As 2-phenyl-4-bromophenylimidazole compound,
2-phenyl-4- (2-bromophenyl) imidazole,
2-phenyl-4- (3-bromophenyl) imidazole,
2-phenyl-4- (4-bromophenyl) imidazole,
2-phenyl-4- (2-bromophenyl) -5-methylimidazole,
2-phenyl-4- (3-bromophenyl) -5-imidazole and
2-phenyl-4- (4-bromophenyl) -5-imidazole is mentioned.
(G)2−クロロフェニル−4−ブロモフェニルイミダゾール化合物としては、
2−(2−クロロフェニル)−4−(2−ブロモフェニル)イミダゾール、
2−(2−クロロフェニル)−4−(3−ブロモフェニル)イミダゾール、
2−(2−クロロフェニル)−4−(4−ブロモフェニル)イミダゾール、
2−(3−クロロフェニル)−4−(2−ブロモフェニル)イミダゾール、
2−(3−クロロフェニル)−4−(3−ブロモフェニル)イミダゾール、
2−(3−クロロフェニル)−4−(4−ブロモフェニル)イミダゾール、
2−(4−クロロフェニル)−4−(2−ブロモフェニル)イミダゾール、
2−(4−クロロフェニル)−4−(3−ブロモフェニル)イミダゾール、
2−(4−クロロフェニル)−4−(4−ブロモフェニル)イミダゾール、
2−(2−クロロフェニル)−4−(2−ブロモフェニル)−5−メチルイミダゾール、
2−(2−クロロフェニル)−4−(3−ブロモフェニル)−5−メチルイミダゾール、
2−(2−クロロフェニル)−4−(4−ブロモフェニル)−5−メチルイミダゾール、
2−(3−クロロフェニル)−4−(2−ブロモフェニル)−5−メチルイミダゾール、
2−(3−クロロフェニル)−4−(3−ブロモフェニル)−5−メチルイミダゾール、
2−(3−クロロフェニル)−4−(4−ブロモフェニル)−5−メチルイミダゾール、
2−(4−クロロフェニル)−4−(2−ブロモフェニル)−5−メチルイミダゾール、
2−(4−クロロフェニル)−4−(3−ブロモフェニル)−5−メチルイミダゾール及び、
2−(4−クロロフェニル)−4−(4−ブロモフェニル)−5−メチルイミダゾールが挙げられる。
(G) As the 2-chlorophenyl-4-bromophenylimidazole compound,
2- (2-chlorophenyl) -4- (2-bromophenyl) imidazole,
2- (2-chlorophenyl) -4- (3-bromophenyl) imidazole,
2- (2-chlorophenyl) -4- (4-bromophenyl) imidazole,
2- (3-chlorophenyl) -4- (2-bromophenyl) imidazole,
2- (3-chlorophenyl) -4- (3-bromophenyl) imidazole,
2- (3-chlorophenyl) -4- (4-bromophenyl) imidazole,
2- (4-chlorophenyl) -4- (2-bromophenyl) imidazole,
2- (4-chlorophenyl) -4- (3-bromophenyl) imidazole,
2- (4-chlorophenyl) -4- (4-bromophenyl) imidazole,
2- (2-chlorophenyl) -4- (2-bromophenyl) -5-methylimidazole,
2- (2-chlorophenyl) -4- (3-bromophenyl) -5-methylimidazole,
2- (2-chlorophenyl) -4- (4-bromophenyl) -5-methylimidazole,
2- (3-chlorophenyl) -4- (2-bromophenyl) -5-methylimidazole,
2- (3-chlorophenyl) -4- (3-bromophenyl) -5-methylimidazole,
2- (3-chlorophenyl) -4- (4-bromophenyl) -5-methylimidazole,
2- (4-chlorophenyl) -4- (2-bromophenyl) -5-methylimidazole,
2- (4-chlorophenyl) -4- (3-bromophenyl) -5-methylimidazole and
2- (4-Chlorophenyl) -4- (4-bromophenyl) -5-methylimidazole.
(H)2−ブロモフェニル−4−クロロフェニルイミダゾール化合物としては、
2−(2−クロロフェニル)−4−(2−ブロモフェニル)イミダゾール、
2−(2−クロロフェニル)−4−(3−ブロモフェニル)イミダゾール、
2−(2−クロロフェニル)−4−(4−ブロモフェニル)イミダゾール、
2−(3−クロロフェニル)−4−(2−ブロモフェニル)イミダゾール、
2−(3−クロロフェニル)−4−(3−ブロモフェニル)イミダゾール、
2−(3−クロロフェニル)−4−(4−ブロモフェニル)イミダゾール、
2−(4−クロロフェニル)−4−(2−ブロモフェニル)イミダゾール、
2−(4−クロロフェニル)−4−(3−ブロモフェニル)イミダゾール、
2−(4−クロロフェニル)−4−(4−ブロモフェニル)イミダゾール、
2−(2−クロロフェニル)−4−(2−ブロモフェニル)−5−メチルイミダゾール、
2−(2−クロロフェニル)−4−(3−ブロモフェニル)−5−メチルイミダゾール、
2−(2−クロロフェニル)−4−(4−ブロモフェニル)−5−メチルイミダゾール、
2−(3−クロロフェニル)−4−(2−ブロモフェニル)−5−メチルイミダゾール、
2−(3−クロロフェニル)−4−(3−ブロモフェニル)−5−メチルイミダゾール、
2−(3−クロロフェニル)−4−(4−ブロモフェニル)−5−メチルイミダゾール、
2−(4−クロロフェニル)−4−(2−ブロモフェニル)−5−メチルイミダゾール、
2−(4−クロロフェニル)−4−(3−ブロモフェニル)−5−メチルイミダゾール及び、
2−(4−クロロフェニル)−4−(4−ブロモフェニル)−5−メチルイミダゾールが挙げられる。
(H) As 2-bromophenyl-4-chlorophenylimidazole compound,
2- (2-chlorophenyl) -4- (2-bromophenyl) imidazole,
2- (2-chlorophenyl) -4- (3-bromophenyl) imidazole,
2- (2-chlorophenyl) -4- (4-bromophenyl) imidazole,
2- (3-chlorophenyl) -4- (2-bromophenyl) imidazole,
2- (3-chlorophenyl) -4- (3-bromophenyl) imidazole,
2- (3-chlorophenyl) -4- (4-bromophenyl) imidazole,
2- (4-chlorophenyl) -4- (2-bromophenyl) imidazole,
2- (4-chlorophenyl) -4- (3-bromophenyl) imidazole,
2- (4-chlorophenyl) -4- (4-bromophenyl) imidazole,
2- (2-chlorophenyl) -4- (2-bromophenyl) -5-methylimidazole,
2- (2-chlorophenyl) -4- (3-bromophenyl) -5-methylimidazole,
2- (2-chlorophenyl) -4- (4-bromophenyl) -5-methylimidazole,
2- (3-chlorophenyl) -4- (2-bromophenyl) -5-methylimidazole,
2- (3-chlorophenyl) -4- (3-bromophenyl) -5-methylimidazole,
2- (3-chlorophenyl) -4- (4-bromophenyl) -5-methylimidazole,
2- (4-chlorophenyl) -4- (2-bromophenyl) -5-methylimidazole,
2- (4-chlorophenyl) -4- (3-bromophenyl) -5-methylimidazole and
2- (4-Chlorophenyl) -4- (4-bromophenyl) -5-methylimidazole.
これらのイミダゾール化合物は、イミダゾール環の2位及び4位にフェニル基が結合した2,4−ジフェニルイミダゾール化合物の基本骨格を有するものであって、2位及び又は4位のフェニル基が1つの塩素原子及び又は臭素原子によって置換されている点に特徴がある。 These imidazole compounds have a basic skeleton of a 2,4-diphenylimidazole compound in which phenyl groups are bonded to the 2-position and 4-position of the imidazole ring, and the 2-position and / or 4-position phenyl groups have one chlorine. It is characterized by being substituted by atoms and / or bromine atoms.
また、これらイミダゾール化合物は、表面処理剤中に、0.01〜10重量%の割合、好ましくは0.1〜5重量%の割合で含有される。イミダゾール化合物の含有割合が0.01重量%より少ないと、銅表面に形成される化成被膜の膜厚が薄くなり、銅表面の酸化を防止することができない。また、10重量%より多い場合には表面処理剤中のイミダゾール化合物が溶け残り、均一な水溶液とすることができない。 These imidazole compounds are contained in the surface treatment agent in a proportion of 0.01 to 10% by weight, preferably in a proportion of 0.1 to 5% by weight. When the content ratio of the imidazole compound is less than 0.01% by weight, the film thickness of the chemical conversion film formed on the copper surface becomes thin, and oxidation of the copper surface cannot be prevented. On the other hand, when the amount is more than 10% by weight, the imidazole compound in the surface treatment agent remains undissolved and a uniform aqueous solution cannot be obtained.
本発明の実施において、イミダゾール化合物を水溶液化するに当たっては、酸として有機酸または無機酸を使用するが、少量の有機溶媒を併用しても良い。この際に使用される代表的な有機酸としては、ギ酸、酢酸、プロピオン酸、酪酸、グリオキシル酸、ピルビン酸、アセト酢酸、レブリン酸、ヘプタン酸、カプリル酸、カプリン酸、ラウリル酸、グリコール酸、グリセリン酸、乳酸、アクリル酸、メトキシ酢酸、エトキシ酢酸、プロポキシ酢酸、ブトキシ酢酸、メトキシプロピオン酸、エトキシプロピオン酸、プロポキシプロピオン酸、ブトキシプロピオン酸、安息香酸、パラニトロ安息香酸、パラトルエンスルホン酸、サリチル酸、ピクリン酸、シュウ酸、コハク酸、マレイン酸、フマール酸、酒石酸、アジピン酸等が挙げられ、無機酸としては、塩酸、リン酸、硫酸、硝酸等が挙げられる。これらの酸は、水溶液に対し0.1〜50重量%の割合、好ましくは1〜30重量%の割合で添加すれば良い。 In practicing the present invention, an organic acid or an inorganic acid is used as an acid for making an imidazole compound into an aqueous solution, but a small amount of an organic solvent may be used in combination. Typical organic acids used in this case include formic acid, acetic acid, propionic acid, butyric acid, glyoxylic acid, pyruvic acid, acetoacetic acid, levulinic acid, heptanoic acid, caprylic acid, capric acid, lauric acid, glycolic acid, Glyceric acid, lactic acid, acrylic acid, methoxyacetic acid, ethoxyacetic acid, propoxyacetic acid, butoxyacetic acid, methoxypropionic acid, ethoxypropionic acid, propoxypropionic acid, butoxypropionic acid, benzoic acid, paranitrobenzoic acid, paratoluenesulfonic acid, salicylic acid, Examples include picric acid, oxalic acid, succinic acid, maleic acid, fumaric acid, tartaric acid, and adipic acid. Examples of inorganic acids include hydrochloric acid, phosphoric acid, sulfuric acid, and nitric acid. These acids may be added in a proportion of 0.1 to 50% by weight, preferably 1 to 30% by weight, based on the aqueous solution.
また、有機溶媒としては、メタノール、エタノール、イソプロピルアルコールなどの低級アルコールあるいはアセトン、N,N−ジメチルホルムアミド、エチレングリコール等の水と自由に混和するものが適している。 As the organic solvent, those which are freely miscible with water such as lower alcohols such as methanol, ethanol and isopropyl alcohol or water such as acetone, N, N-dimethylformamide and ethylene glycol are suitable.
本発明の表面処理剤には、銅または銅合金の表面における化成被膜の形成速度を速めるために銅化合物を添加することができ、また形成された化成被膜の耐熱性を更に向上させるために亜鉛化合物を添加しても良い。
前記銅化合物の代表的なものとしては、酢酸銅、塩化第一銅、塩化第二銅、臭化第一銅、臭化第二銅、ヨウ化銅、水酸化銅、リン酸銅、硫酸銅、硝酸銅等であり、また前記亜鉛化合物の代表的なものとしては、酸化亜鉛、蟻酸亜鉛、酢酸亜鉛、蓚酸亜鉛、乳酸亜鉛、クエン酸亜鉛、硫酸亜鉛、硝酸亜鉛、リン酸亜鉛等が挙げられ、何れも表面処理剤に対して0.01〜10重量%の割合、好ましくは0.02〜5重量%の割合で添加すれば良い。
To the surface treatment agent of the present invention, a copper compound can be added in order to increase the rate of formation of the chemical conversion film on the surface of copper or copper alloy, and zinc can be added to further improve the heat resistance of the formed chemical conversion film. A compound may be added.
Representative examples of the copper compound include copper acetate, cuprous chloride, cupric chloride, cuprous bromide, cupric bromide, copper iodide, copper hydroxide, copper phosphate, copper sulfate. Typical examples of the zinc compound include zinc oxide, zinc formate, zinc acetate, zinc oxalate, zinc lactate, zinc citrate, zinc sulfate, zinc nitrate, zinc phosphate and the like. Any of these may be added in a proportion of 0.01 to 10% by weight, preferably 0.02 to 5% by weight, based on the surface treatment agent.
これらの銅化合物や亜鉛化合物を用いる場合には、有機酸または無機酸の他に、アンモニアあるいはモノエタノールアミン、ジエタノールアミン、トリエタノールアミンなどのアミン類等の緩衝作用を有する物質を添加して溶液のpHを安定にすることが望ましい。 When these copper compounds and zinc compounds are used, in addition to organic or inorganic acids, substances having a buffering action such as ammonia or amines such as monoethanolamine, diethanolamine and triethanolamine are added to the solution. It is desirable to stabilize the pH.
本発明の表面処理剤には、化成被膜の形成速度および該被膜の耐熱性を更に向上させるために、ハロゲン化合物を0.001〜1重量%、好ましくは0.01〜0.1重量%の割合で添加することが望ましい。ハロゲン化合物としては、例えばフッ化ナトリウム、フッ化カリウム、フッ化アンモニウム、塩化ナトリム、塩化カリウム、塩化アンモニウム、臭化ナトリウム、臭化カリウム、臭化アンモニウム、ヨウ化ナトリム、ヨウ化カリウム、ヨウ化アンモニウム等が挙げられる。 The surface treatment agent of the present invention contains 0.001 to 1% by weight of a halogen compound, preferably 0.01 to 0.1% by weight, in order to further improve the formation rate of the conversion coating and the heat resistance of the coating. It is desirable to add in proportions. Examples of the halogen compound include sodium fluoride, potassium fluoride, ammonium fluoride, sodium chloride, potassium chloride, ammonium chloride, sodium bromide, potassium bromide, ammonium bromide, sodium iodide, potassium iodide, ammonium iodide. Etc.
本発明の表面処理剤を用いて銅または銅合金の表面を処理する際の条件としては、表面処理剤の液温を10〜70℃、接触時間を1秒〜10分とすることが適当である。接触方法としては、浸漬、噴霧、塗布等の方法が挙げられる。 As conditions for treating the surface of copper or copper alloy using the surface treating agent of the present invention, it is appropriate that the liquid temperature of the surface treating agent is 10 to 70 ° C. and the contact time is 1 second to 10 minutes. is there. Examples of the contact method include dipping, spraying, and application methods.
また本発明の表面処理を行った後、化成被膜上に熱可塑性樹脂により二重構造を形成し、更に耐熱性を高めることも可能である。
即ち、銅または銅合金の表面上に化成被膜を生成させた後、ロジン、ロジンエステル等のロジン誘導体、テルペン樹脂、テルペンフェノール樹脂等のテルペン樹脂誘導体、芳香族炭化水素樹脂、脂肪族炭化水素樹脂等の炭化水素樹脂やこれらの混合物からなる耐熱性に優れた熱可塑性樹脂を、トルエン、酢酸エチル、イソプロピルアルコール等の溶媒に溶解し、ロールコーター等により化成被膜上に膜厚1〜30μmの厚みになるように均一に塗布して、化成被膜と熱可塑性樹脂の二重構造を形成させれば良い。
Moreover, after performing the surface treatment of this invention, it is also possible to form a double structure with a thermoplastic resin on a chemical conversion film, and to further improve heat resistance.
That is, after forming a chemical conversion film on the surface of copper or copper alloy, rosin derivatives such as rosin and rosin ester, terpene resin derivatives such as terpene resin and terpene phenol resin, aromatic hydrocarbon resin and aliphatic hydrocarbon resin A thermoplastic resin excellent in heat resistance made of a hydrocarbon resin such as a mixture thereof or the like is dissolved in a solvent such as toluene, ethyl acetate, isopropyl alcohol, etc. It is sufficient to apply uniformly to form a double structure of the chemical conversion film and the thermoplastic resin.
本発明の実施に適する代表的な無鉛半田としては、Sn−Ag−Cu系、Sn−Ag−Bi系、Sn−Bi系、Sn−Ag−Bi−In系、Sn−Zn系、Sn−Cu系等の無鉛半田が挙げられる。 Typical lead-free solders suitable for the practice of the present invention include Sn—Ag—Cu, Sn—Ag—Bi, Sn—Bi, Sn—Ag—Bi—In, Sn—Zn, Sn—Cu. Lead-free solders such as those based on this type are included.
また本発明の半田付け方法は、加熱溶融した液体状の半田が入っている半田槽の上を、プリント配線板を流し、電子部品とプリント配線板の接合部に半田付けを行なうフロー法または、予めプリント配線板にペースト状のクリーム半田を回路パターンに合わせて印刷し、そこに電子部品を実装し、プリント配線板を加熱して半田を溶融させ、半田付けを行うリフロー法等に適応し得るものである。 In addition, the soldering method of the present invention is a flow method in which a printed wiring board is flowed over a solder bath containing heated and melted liquid solder, and soldering is performed on the joint between the electronic component and the printed wiring board, or It can be applied to the reflow method, etc., in which paste-like cream solder is printed on the printed wiring board according to the circuit pattern in advance, electronic components are mounted on the printed wiring board, the printed wiring board is heated to melt the solder, and soldering is performed. Is.
以下、本発明を実施例及び比較例によって具体的に説明するが、本発明はこれらに限定されるものではない。
なお、実施例及び比較例で使用したイミダゾール化合物ならびに評価試験方法は次のとおりである。
EXAMPLES Hereinafter, although an Example and a comparative example demonstrate this invention concretely, this invention is not limited to these.
In addition, the imidazole compound used in the Example and the comparative example and the evaluation test method are as follows.
[イミダゾール化合物]
〔参考例1〕
<2−(2−クロロフェニル)−4−フェニルイミダゾール>
2−アセトキシアセトフェノンと、等モルの2−クロロベンズアルデヒドをイソプロピルアルコールに溶解させた溶液に、2.2倍モルの酢酸銅(II)一水和物を20倍モルの25%アンモニア水に溶解させた溶液を水冷下で少量ずつ加え、次いで60℃まで1時間、更に78℃まで3時間かけて昇温した。
反応終了後、反応液を5℃まで冷却し、析出物を濾取して水洗後乾燥して得られた暗緑色粉末状物をメタノールに懸濁させ、0.6倍モルの70%水硫化ナトリウムを加え1時間加熱還流後、冷却、黒色不溶物を濾去した。濾液を減圧乾固し、乾固物をクロロホルムに溶解し、水で洗浄後、クロロホルムを減圧留去し、得られた乾固物をアセトニトリルから再結晶して、乳白色粉末状の2−(2−クロロフェニル)−4−フェニルイミダゾールを得た(収率31%)。
[Imidazole compound]
[Reference Example 1]
<2- (2-Chlorophenyl) -4-phenylimidazole>
In a solution of 2-acetoxyacetophenone and equimolar 2-chlorobenzaldehyde dissolved in isopropyl alcohol, 2.2-fold mol of copper (II) acetate monohydrate was dissolved in 20-fold mol of 25% aqueous ammonia. The resulting solution was added in small portions under water cooling, then heated to 60 ° C. for 1 hour and further to 78 ° C. over 3 hours.
After completion of the reaction, the reaction solution was cooled to 5 ° C., the precipitate was collected by filtration, washed with water and dried, and the resulting dark green powder was suspended in methanol and 0.6-fold mol of 70% hydrosulfide. Sodium was added and the mixture was heated under reflux for 1 hour. The filtrate was dried under reduced pressure, the dried product was dissolved in chloroform, washed with water, chloroform was distilled off under reduced pressure, and the resulting dried product was recrystallized from acetonitrile to give milky white powder 2- (2 -Chlorophenyl) -4-phenylimidazole was obtained (yield 31%).
〔参考例2〕
<2−(3−クロロフェニル)−4−フェニルイミダゾール>
参考例1の2−クロロベンズアルデヒドを3−クロロベンズアルデヒドに代えて、参考例1の方法に準拠して合成した。
[Reference Example 2]
<2- (3-Chlorophenyl) -4-phenylimidazole>
The 2-chlorobenzaldehyde of Reference Example 1 was replaced with 3-chlorobenzaldehyde and synthesized according to the method of Reference Example 1.
〔参考例3〕
<2−(4−クロロフェニル)−4−フェニルイミダゾールの合成法>
参考例1の2−クロロベンズアルデヒドを4−クロロベンズアルデヒドに代えて、参考例1の方法に準拠して合成した。
[Reference Example 3]
<Synthesis Method of 2- (4-Chlorophenyl) -4-phenylimidazole>
The 2-chlorobenzaldehyde of Reference Example 1 was replaced with 4-chlorobenzaldehyde and synthesized according to the method of Reference Example 1.
〔参考例4〕
<2−(4−クロロフェニル)−4−フェニル−5−メチルイミダゾール>
1−フェニル−1,2−プロパンジオンと、等モルの4−クロロベンズアルデヒド及び6倍モルの酢酸アンモニウムを、酢酸中で5時間加熱還流した。反応終了後、大量のアンモニア水に注ぎ、析出した固形物を濾取し水洗後乾燥して、褐色固形物を得た。この固体をアセトニトリルから再結晶して、乳白色粉末状の2−(4−クロロフェニル)−4−フェニル−5−メチルイミダゾールを得た(収率54%)。
[Reference Example 4]
<2- (4-Chlorophenyl) -4-phenyl-5-methylimidazole>
1-Phenyl-1,2-propanedione, equimolar 4-chlorobenzaldehyde and 6-fold molar ammonium acetate were heated to reflux in acetic acid for 5 hours. After completion of the reaction, the mixture was poured into a large amount of aqueous ammonia, and the precipitated solid was collected by filtration, washed with water and dried to obtain a brown solid. This solid was recrystallized from acetonitrile to obtain 2- (4-chlorophenyl) -4-phenyl-5-methylimidazole in the form of milky white powder (yield 54%).
〔参考例5〕
<2−フェニル−4−(2−クロロフェニル)イミダゾール>
ベンズアミジン塩酸塩と、3倍モルの炭酸カリウムのテトラヒドロフラン−水混合液に、加温下、等モルの2−ブロモ−2’−クロロアセトフェノンのテトラヒドロフラン溶液を滴下した。滴下終了後2時間加熱還流した。反応液を減圧乾固し、乾固物を水洗、トルエン洗浄したのち、アセトニトリルより再結晶して、白色の粉末状の2−フェニル−4−(2−クロロフェニル)イミダゾールを得た。(収率65%)
[Reference Example 5]
<2-Phenyl-4- (2-chlorophenyl) imidazole>
To a mixture of benzamidine hydrochloride and 3 moles of potassium carbonate in tetrahydrofuran-water, equimolar 2-bromo-2′-chloroacetophenone in tetrahydrofuran was added dropwise with heating. After completion of dropping, the mixture was heated to reflux for 2 hours. The reaction solution was dried under reduced pressure, and the dried product was washed with water and toluene, and then recrystallized from acetonitrile to obtain 2-phenyl-4- (2-chlorophenyl) imidazole as a white powder. (Yield 65%)
〔参考例6〕
<2−フェニル−4−(3−クロロフェニル)イミダゾール>
参考例5の2−ブロモ−2’−クロロアセトフェノンを2−ブロモ−3’−クロロアセトフェノンに代えて、参考例5の方法に準拠して合成した。
[Reference Example 6]
<2-Phenyl-4- (3-chlorophenyl) imidazole>
The 2-bromo-2′-chloroacetophenone of Reference Example 5 was replaced with 2-bromo-3′-chloroacetophenone and synthesized according to the method of Reference Example 5.
〔参考例7〕
<2−フェニル−4−(4−クロロフェニル)イミダゾール>
参考例5の2−ブロモ−2’−クロロアセトフェノンを2−ブロモ−4’−クロロアセトフェノンに代えて、参考例5の方法に準拠して合成した。
[Reference Example 7]
<2-Phenyl-4- (4-chlorophenyl) imidazole>
The 2-bromo-2′-chloroacetophenone of Reference Example 5 was replaced with 2-bromo-4′-chloroacetophenone and synthesized according to the method of Reference Example 5.
〔参考例8〕
<2−フェニル−4−(4−クロロフェニル)−5−メチルイミダゾール>
参考例5の2−ブロモ−2’−クロロアセトフェノンを2−ブロモ−4’−クロロプロピオフェノンに代えて、参考例5の方法に準拠して合成した。
[Reference Example 8]
<2-Phenyl-4- (4-chlorophenyl) -5-methylimidazole>
The 2-bromo-2′-chloroacetophenone of Reference Example 5 was replaced with 2-bromo-4′-chloropropiophenone and synthesized according to the method of Reference Example 5.
〔参考例9〕
<2−(4−ブロモフェニル)−4−フェニルイミダゾール>
参考例1の2−クロロベンズアルデヒドを4−ブロモベンズアルデヒドに代えて、参考例1の方法に準拠して合成した。
[Reference Example 9]
<2- (4-Bromophenyl) -4-phenylimidazole>
The 2-chlorobenzaldehyde of Reference Example 1 was replaced with 4-bromobenzaldehyde and synthesized according to the method of Reference Example 1.
〔参考例10〕
<2−(4−ブロモフェニル)−4−フェニル−5−メチルイミダゾール>
参考例4の4−クロロベンズアルデヒドを4−ブロモベンズアルデヒドに代えて、参考例4の方法に準拠して合成した。
[Reference Example 10]
<2- (4-Bromophenyl) -4-phenyl-5-methylimidazole>
The 4-chlorobenzaldehyde of Reference Example 4 was replaced with 4-bromobenzaldehyde and synthesized according to the method of Reference Example 4.
〔参考例11〕
<2−フェニル−4−(4−ブロモフェニル)イミダゾール>
参考例5の2−ブロモ−2’−クロロアセトフェノンを2−ブロモ−4’−ブロモアセトフェノンに代えて、参考例5の方法に準拠して合成した。
[Reference Example 11]
<2-Phenyl-4- (4-bromophenyl) imidazole>
The 2-bromo-2′-chloroacetophenone of Reference Example 5 was replaced with 2-bromo-4′-bromoacetophenone and synthesized according to the method of Reference Example 5.
〔参考例12〕
<2−フェニル−4−(4−ブロモフェニル)−5−メチルイミダゾール>
参考例5の2−ブロモ−2’−クロロアセトフェノンを2−ブロモ−4’−ブロモプロピオフェノンに代えて、参考例5の方法に準拠して合成した。
[Reference Example 12]
<2-Phenyl-4- (4-bromophenyl) -5-methylimidazole>
The 2-bromo-2′-chloroacetophenone of Reference Example 5 was replaced with 2-bromo-4′-bromopropiophenone and synthesized according to the method of Reference Example 5.
〔参考例13〕
<2−(4−クロロフェニル)−4−(4−クロロフェニル)イミダゾール>
参考例1の2−クロロベンズアルデヒドを4−クロロベンズアルデヒドに、2−アセトキシアセトフェノンを2−アセトキシ−4’−クロロアセトフェノン代えて、参考例1の方法に準拠して合成した。
[Reference Example 13]
<2- (4-Chlorophenyl) -4- (4-chlorophenyl) imidazole>
The 2-chlorobenzaldehyde of Reference Example 1 was replaced with 4-chlorobenzaldehyde, and 2-acetoxyacetophenone was replaced with 2-acetoxy-4′-chloroacetophenone, and synthesized according to the method of Reference Example 1.
〔参考例14〕
<2−(4−クロロフェニル)−4−(4−クロロフェニル)−5−メチルイミダゾール>
参考例1の2−クロロベンズアルデヒドを4−クロロベンズアルデヒドに、2−アセトキシアセトフェノンを2−アセトキシ−4’−クロロプロピオフェノンに代えて、参考例1の方法に準拠して合成した。
[Reference Example 14]
<2- (4-Chlorophenyl) -4- (4-chlorophenyl) -5-methylimidazole>
The 2-chlorobenzaldehyde of Reference Example 1 was replaced with 4-chlorobenzaldehyde, and 2-acetoxyacetophenone was replaced with 2-acetoxy-4′-chloropropiophenone, and synthesized according to the method of Reference Example 1.
以下のイミダゾール化合物は、特開平7−243053号公報に記載された方法により合成した。
・2,4−ジフェニルイミダゾール
・2,4−ジフェニル−5−メチルイミダゾール
The following imidazole compounds were synthesized by the method described in JP-A-7-243053.
2,4-diphenylimidazole 2,4-diphenyl-5-methylimidazole
[半田上がり性の評価試験]
試験片として、内径0.80mmの銅スルホールを300穴有する120mm(縦)×150mm(横)×1.6mm(厚み)のガラスエポキシ樹脂製のプリント配線板を使用した。この試験片を脱脂、ソフトエッチング及び水洗を行った後、所定の液温に保持した表面処理剤に所定時間浸漬し、次いで水洗、乾燥して銅表面上に厚さ約0.10〜0.50μmの化成被膜を形成させた。
この表面処理を行った試験片について、赤外線リフロー装置(製品名:MULTI−PRO−306、ヴィトロニクス社製)を用いて、ピーク温度が240℃であるリフロー加熱を3回行い、次いで、フロー半田付け装置(コンベア速度:1.0m/分)を用いて半田付けを行った。
なお、使用した半田は、63錫-37鉛(重量%)の組成を有する錫−鉛系共晶半田(商品名:H63A、千住金属工業製)であり、半田付けに際して使用したフラックスはJS−64MSS(弘輝製)である。また、半田温度は240℃とした。
また、前記の表面処理を行った試験片について、錫−鉛系共晶半田の場合と同様にして無鉛半田を使用して半田付けを行った。なお、使用した半田は、96.5錫-3.0銀-0.5銅(重量%)の組成を有する無鉛半田(商品名:H705「エコソルダー」、千住金属工業製)であり、半田付けに際して使用したフラックスはJS−E−09(弘輝製)である。また、リフロー加熱のピーク温度は245℃であり、半田温度も245℃とした。
半田付けを行った試験片について、銅スルーホールの上部ランド部分まで半田が上がった(半田付けされた)スルーホール数を計測し、全スルーホール数(300穴)に対する割合(%)を算出した。
銅の表面に対して半田の濡れ性が大きい程、溶融した半田が銅スルーホール内を浸透し該スルーホールの上部ランド部分まで上がり易くなる。即ち、全スルーホール数に対する上部ランド部分まで半田が上がったスルーホール数の割合が大きい程、銅に対する半田濡れ性が優れ、半田付け性が良好なものと判定される。
[Evaluation test of solderability]
As a test piece, a printed wiring board made of glass epoxy resin of 120 mm (vertical) × 150 mm (horizontal) × 1.6 mm (thickness) having 300 copper through holes with an inner diameter of 0.80 mm was used. The test piece was degreased, soft-etched and washed with water, then immersed in a surface treatment agent maintained at a predetermined liquid temperature for a predetermined time, then washed with water and dried to a thickness of about 0.10 to 0.00 on the copper surface. A 50 μm conversion coating was formed.
About the test piece which performed this surface treatment, the reflow heating whose peak temperature is 240 degreeC was performed 3 times using the infrared reflow apparatus (product name: MULTI-PRO-306, Vitronics company make), then, flow solder Soldering was performed using an attaching device (conveyor speed: 1.0 m / min).
The solder used was tin-lead eutectic solder (trade name: H63A, manufactured by Senju Metal Industry Co., Ltd.) having a composition of 63 tin-37 lead (weight%), and the flux used for soldering was JS- 64MSS (manufactured by Hiroki). The solder temperature was 240 ° C.
Further, the test piece subjected to the surface treatment was soldered using lead-free solder in the same manner as in the case of tin-lead eutectic solder. The solder used is a lead-free solder (trade name: H705 “Eco Solder”, manufactured by Senju Metal Industry Co., Ltd.) having a composition of 96.5 tin-3.0 silver-0.5 copper (% by weight). The flux used for attaching is JS-E-09 (manufactured by Hiroki). The peak temperature of reflow heating was 245 ° C., and the solder temperature was 245 ° C.
For the soldered test piece, the number of through holes in which the solder went up to the upper land portion of the copper through hole (soldered) was measured, and the ratio (%) to the total number of through holes (300 holes) was calculated. .
The higher the solder wettability with respect to the copper surface, the more easily the molten solder penetrates into the copper through hole and rises to the upper land portion of the through hole. That is, it is determined that the higher the ratio of the number of through holes in which the solder has reached the upper land portion with respect to the total number of through holes, the better the solder wettability with respect to copper and the better the solderability.
[半田広がり性の評価試験]
試験片として、50mm(縦)×50mm(横)×1.2mm(厚み)のガラスエポキシ樹脂製のプリント配線板(回路パターンとして、銅箔からなる導体幅0.80mm、長さ20mmの回路部を、1.0mmの間隔にて幅方向に10本形成させたもの)を使用した。この試験片を脱脂、ソフトエッチング及び水洗を行った後、所定の液温に保持した表面処理剤に所定時間浸漬し、次いで水洗、乾燥して銅表面上に厚さ約0.10〜0.50μmの化成被膜を形成させた。
この表面処理を行った試験片について、赤外線リフロー装置(製品名:MULTI−PRO−306、ヴィトロニクス社製)を用いて、ピーク温度が240℃であるリフロー加熱を1回行った。その後、開口径1.2mm、厚み150μmのメタルマスクを使用して銅回路部の中央に錫−鉛系クリーム半田を印刷し、前期条件でリフロー加熱を行い、半田付けを行った。なお、使用した錫−鉛系クリーム半田は63錫-37鉛(重量%)からなる組成の共晶半田(商品名:OZ−63−330F−40−10、千住金属工業製)である。
また、前記の表面処理を行った試験片について、錫−鉛系クリーム半田の場合と同様にして無鉛系クリーム半田を使用して半田付けを行った。なお、使用した無鉛系クリーム半田は、96.5錫-3.0銀-0.5銅(重量%)からなる組成の無鉛半田(商品名:M705−221BM5−42−11、千住金属工業製)である。また、クリーム半田の印刷前および印刷後に行うリフロー加熱は、ピーク温度が245℃になるように設定した。
得られた試験片について、銅回路部上に濡れ広がった半田の長さ(mm)を測定した。
この長さが大きい程、半田濡れ性が優れ、半田付け性が良好なものと判定される。
[Evaluation test of solder spreadability]
As a test piece, a printed wiring board made of glass epoxy resin of 50 mm (vertical) × 50 mm (horizontal) × 1.2 mm (thickness) (as a circuit pattern, a circuit part having a conductor width of 0.80 mm and a length of 20 mm made of copper foil) 10 were formed in the width direction at intervals of 1.0 mm). The test piece was degreased, soft-etched and washed with water, then immersed in a surface treatment agent maintained at a predetermined liquid temperature for a predetermined time, then washed with water and dried to a thickness of about 0.10 to 0.00 on the copper surface. A 50 μm conversion coating was formed.
About the test piece which performed this surface treatment, the reflow heating whose peak temperature is 240 degreeC was performed once using the infrared reflow apparatus (Product name: MULTI-PRO-306, Vitronics company make). After that, using a metal mask having an opening diameter of 1.2 mm and a thickness of 150 μm, tin-lead cream solder was printed at the center of the copper circuit portion, and reflow heating was performed under the previous conditions to perform soldering. The tin-lead cream solder used is a eutectic solder (trade name: OZ-63-330F-40-10, manufactured by Senju Metal Industry Co., Ltd.) composed of 63 tin-37 lead (% by weight).
Moreover, about the test piece which performed the said surface treatment, it soldered using the lead-free cream solder similarly to the case of a tin-lead cream solder. The lead-free cream solder used was a lead-free solder (commercial name: M705-221BM5-42-11, manufactured by Senju Metal Industry Co., Ltd.) composed of 96.5 tin-3.0 silver-0.5 copper (% by weight). ). The reflow heating performed before and after the cream solder printing was set so that the peak temperature was 245 ° C.
About the obtained test piece, the length (mm) of the solder which wet-spreaded on the copper circuit part was measured.
The larger this length, the better the solder wettability and the better the solderability.
〔実施例1〕
イミダゾール化合物として2−(2−クロロフェニル)−4−フェニルイミダゾール、酸として蟻酸、金属塩として酢酸銅及び、ハロゲン化合物として塩化アンモニウムを、表1に記載した組成になるようにイオン交換水に溶解させた後、アンモニア水でpH2.7に調整して表面処理剤を調製した。
次いで、プリント配線板の試験片を40℃に温調した表面処理剤に60秒間浸漬したのち、水洗、乾燥し、半田上がり性及び半田広がり性を測定した。これらの試験結果は表1に示したとおりであった。
[Example 1]
2- (2-Chlorophenyl) -4-phenylimidazole as an imidazole compound, formic acid as an acid, copper acetate as a metal salt, and ammonium chloride as a halogen compound are dissolved in ion-exchanged water so as to have the composition described in Table 1. Thereafter, the surface treatment agent was prepared by adjusting the pH to 2.7 with aqueous ammonia.
Next, the test piece of the printed wiring board was immersed in a surface treatment agent adjusted to 40 ° C. for 60 seconds, washed with water and dried, and the solder finish and solder spreadability were measured. These test results were as shown in Table 1.
〔実施例2〜14、比較例1〜2〕
実施例1と同様にして、表1記載の組成を有する表面処理剤を調製し、表1に記載の処理条件にて表面処理を行った。得られた試験片について、半田上がり性及び半田広がり性を測定した。これらの試験結果は表1に示したとおりであった。
[Examples 2-14, Comparative Examples 1-2]
In the same manner as in Example 1, a surface treatment agent having the composition described in Table 1 was prepared, and the surface treatment was performed under the treatment conditions described in Table 1. About the obtained test piece, solder rising property and solder spreading property were measured. These test results were as shown in Table 1.
表1に示される試験結果を以下に説明する。
本発明の表面処理剤に使用するイミダゾール化合物は、実施例1〜14に示されるとおり、2,4−ジフェニルイミダゾール化合物の基本骨格を有するものであって、2位及び又は4位に結合したフェニル基に1つの塩素原子及び又は臭素原子が置換したものである。また、比較例で使用したイミダゾール化合物は、前記のフェニル基が無置換のものである。
The test results shown in Table 1 will be described below.
The imidazole compound used in the surface treatment agent of the present invention has a basic skeleton of 2,4-diphenylimidazole compound as shown in Examples 1 to 14, and phenyl bonded to the 2-position and / or 4-position. A group is substituted with one chlorine atom and / or bromine atom. Moreover, the imidazole compound used in the comparative example is one in which the phenyl group is unsubstituted.
表1に示される試験結果によれば、錫−鉛系共晶半田を使用して半田付けを行った場合の半田上がり性の数値は、実施例および比較例の試験結果では何れも90〜100%であり、実施例と比較例の間に殆ど差異が認められない。
しかしながら、無鉛半田を使用した場合の半田上がり性の数値は、実施例の場合には90〜100%を達成しているが、比較例の場合には30〜50%程度に留まっており、本発明の表面処理剤を使用して銅表面を処理し、無鉛半田を用いて半田付けを行った場合の半田濡れ性は飛躍的に向上したものと認められる。
According to the test results shown in Table 1, the numerical values of the solderability when soldering using tin-lead eutectic solder are 90 to 100 in the test results of Examples and Comparative Examples. %, And there is almost no difference between the example and the comparative example.
However, the numerical value of solderability when lead-free solder is used achieves 90% to 100% in the case of the example, but remains about 30% to 50% in the case of the comparative example. It is recognized that the solder wettability is remarkably improved when the copper surface is treated with the surface treating agent of the invention and soldered with lead-free solder.
また、錫−鉛系共晶半田を使用した場合の半田広がり性については、実施例の場合が約3.2〜3.6mmであり、比較例の場合は約2.9〜3.1であり、比較例に比べて実施例の場合が顕著に優れているものと認められる。更に、無鉛半田を使用した場合の実施例の試験結果においても、約1.6〜1.7mmに対して、比較例の試験結果では約1.5〜1.6mmとなっており、本発明の表面処理剤を使用して銅表面を処理し、無鉛半田を用いて半田付けを行った場合の半田濡れ性は顕著に向上したものと認められる。 In addition, the solder spreadability when using a tin-lead eutectic solder is about 3.2 to 3.6 mm in the example, and about 2.9 to 3.1 in the comparative example. Yes, it is recognized that the example is remarkably superior to the comparative example. Furthermore, in the test result of the example when lead-free solder is used, the test result of the comparative example is about 1.5 to 1.6 mm as compared to about 1.6 to 1.7 mm. It is recognized that the solder wettability is remarkably improved when the copper surface is treated using the above surface treatment agent and soldering is performed using lead-free solder.
このような効果は、本発明の表面処理剤に使用したイミダゾール化合物が、2,4−ジフェニルイミダゾール化合物の基本骨格を有するものであって、2位及び又は4位に結合したフェニル基に1つの塩素原子及び又は臭素原子が置換したものであることに起因すると考えられる。
Such an effect is that the imidazole compound used in the surface treatment agent of the present invention has a basic skeleton of a 2,4-diphenylimidazole compound, and has one phenyl group bonded to the 2-position and / or 4-position. This is considered to be due to the substitution of a chlorine atom and / or a bromine atom.
Claims (2)
A soldering method, wherein the surface of copper or a copper alloy is treated with the surface treating agent according to claim 1 and then soldered using lead-free solder.
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TW200907107A (en) * | 2007-07-20 | 2009-02-16 | Mec Co Ltd | Surface treating agent |
JP5313044B2 (en) * | 2008-08-08 | 2013-10-09 | 四国化成工業株式会社 | Surface treatment agent for copper or copper alloy and use thereof |
JP5321878B2 (en) * | 2008-09-01 | 2013-10-23 | 四国化成工業株式会社 | Surface treatment agent for copper or copper alloy and use thereof |
JP5260357B2 (en) * | 2008-09-17 | 2013-08-14 | 四国化成工業株式会社 | 2- (2,4-dichlorobenzyl) -4-phenyl-5-alkylimidazole compound |
JP5260208B2 (en) * | 2008-09-22 | 2013-08-14 | 四国化成工業株式会社 | 2- (2,4-Dichlorobenzyl) -4- (halogenated phenyl) imidazole compound |
JP5361316B2 (en) * | 2008-10-02 | 2013-12-04 | 株式会社タムラ製作所 | Surface treatment agent, printed circuit board, and manufacturing method thereof |
JP5615227B2 (en) * | 2011-05-23 | 2014-10-29 | 四国化成工業株式会社 | Surface treatment agent for copper or copper alloy and use thereof |
JP5615233B2 (en) * | 2011-06-20 | 2014-10-29 | 四国化成工業株式会社 | Surface treatment agent for copper or copper alloy and use thereof |
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US11090289B2 (en) | 2017-01-24 | 2021-08-17 | University Of Virginia Patent Foundation | Compositions and methods for blocking sodium channels |
CN115043779B (en) * | 2022-06-14 | 2024-06-25 | 广东金柏化学有限公司 | 2, 4-Diphenyl imidazole compound and preparation method and application thereof |
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