JP4520743B2 - Ｍｆｉ型の結晶性アルミノシリケートゼオライトを調製する方法 - Google Patents
Ｍｆｉ型の結晶性アルミノシリケートゼオライトを調製する方法 Download PDFInfo
- Publication number
- JP4520743B2 JP4520743B2 JP2003572900A JP2003572900A JP4520743B2 JP 4520743 B2 JP4520743 B2 JP 4520743B2 JP 2003572900 A JP2003572900 A JP 2003572900A JP 2003572900 A JP2003572900 A JP 2003572900A JP 4520743 B2 JP4520743 B2 JP 4520743B2
- Authority
- JP
- Japan
- Prior art keywords
- mixture
- sio
- zeolite
- nucleating agent
- minutes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 89
- 239000010457 zeolite Substances 0.000 title claims description 52
- 229910000323 aluminium silicate Inorganic materials 0.000 title claims description 47
- 229910021536 Zeolite Inorganic materials 0.000 title claims description 42
- 238000000034 method Methods 0.000 title claims description 41
- 239000000203 mixture Substances 0.000 claims description 67
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 41
- 239000002667 nucleating agent Substances 0.000 claims description 38
- 239000000499 gel Substances 0.000 claims description 35
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 29
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 17
- 239000011541 reaction mixture Substances 0.000 claims description 17
- 239000000377 silicon dioxide Substances 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 230000002194 synthesizing effect Effects 0.000 claims description 5
- 230000035484 reaction time Effects 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 26
- -1 poly(alkylene glycol Chemical compound 0.000 abstract description 7
- 229920001400 block copolymer Polymers 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 229920001515 polyalkylene glycol Polymers 0.000 abstract 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 abstract 1
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 1
- 239000007787 solid Substances 0.000 description 23
- 239000011734 sodium Substances 0.000 description 14
- 239000003054 catalyst Substances 0.000 description 11
- 238000003756 stirring Methods 0.000 description 11
- 238000000465 moulding Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 239000002243 precursor Substances 0.000 description 8
- 238000002425 crystallisation Methods 0.000 description 7
- 230000008025 crystallization Effects 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000003208 petroleum Substances 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 229910001388 sodium aluminate Inorganic materials 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000012013 faujasite Substances 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229910001679 gibbsite Inorganic materials 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000004005 microsphere Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000004876 x-ray fluorescence Methods 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- 229910002710 Au-Pd Inorganic materials 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910001680 bayerite Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000002356 laser light scattering Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000011197 physicochemical method Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C01B39/38—Type ZSM-5
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/005—Modified block copolymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/21—Faujasite, e.g. X, Y, CZS-3, ECR-4, Z-14HS, VHP-R
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36066102P | 2002-03-01 | 2002-03-01 | |
| PCT/EP2003/001991 WO2003074423A1 (en) | 2002-03-01 | 2003-02-26 | Preparation of mfi-type crystalline zeolitic aluminosilicate |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005519014A JP2005519014A (ja) | 2005-06-30 |
| JP2005519014A5 JP2005519014A5 (https=) | 2006-08-31 |
| JP4520743B2 true JP4520743B2 (ja) | 2010-08-11 |
Family
ID=27788998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003572900A Expired - Lifetime JP4520743B2 (ja) | 2002-03-01 | 2003-02-26 | Ｍｆｉ型の結晶性アルミノシリケートゼオライトを調製する方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6667023B2 (https=) |
| EP (1) | EP1478596B1 (https=) |
| JP (1) | JP4520743B2 (https=) |
| KR (1) | KR100960438B1 (https=) |
| CN (1) | CN1307101C (https=) |
| AT (1) | ATE317370T1 (https=) |
| BR (1) | BR0308110B1 (https=) |
| CA (1) | CA2477713C (https=) |
| DE (1) | DE60303500T2 (https=) |
| WO (1) | WO2003074423A1 (https=) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6800272B2 (en) * | 2002-03-13 | 2004-10-05 | Council Of Scientific And Industrial Research | Process for the preparation of ZSM-5 catalyst |
| US6964934B2 (en) * | 2002-08-28 | 2005-11-15 | Albemarle Netherlands B.V. | Process for the preparation of doped pentasil-type zeolite using doped seeds |
| US6908603B2 (en) * | 2003-06-02 | 2005-06-21 | Engelhard Corporation | In-situ ZSM-5 synthesis |
| WO2006087337A1 (en) * | 2005-02-15 | 2006-08-24 | Albemarle Netherlands Bv | Nucleating gel, process for its preparation, and its use in the synthesis of mfi-type zeolite |
| EP1707533A1 (en) * | 2005-04-01 | 2006-10-04 | Petroleo Brasileiro S.A. - Petrobras | Nucleating gel, process for its preparation, and its use in the synthesis of MFI-type zeolite |
| BRPI0608355B1 (pt) | 2005-02-17 | 2016-05-24 | Monsanto Technology Llc | processo para oxidação de ácido n-(fosfonometil) iminodiacético ou seu sal e catalisador de oxidação |
| AU2007217054A1 (en) * | 2006-02-17 | 2007-08-30 | Monsanto Technology Llc | Transition metal-containing catalysts and processes for their preparation and use as fuel cell catalysts |
| RU2313486C1 (ru) * | 2006-04-12 | 2007-12-27 | Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") | Синтетический цеолит и способ его получения |
| RU2312063C1 (ru) * | 2006-04-12 | 2007-12-10 | Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") | Синтетический пористый кристаллический материал и способ его получения |
| RU2313488C1 (ru) * | 2006-04-24 | 2007-12-27 | Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") | Синтетический цеолит и способ его получения |
| RU2313487C1 (ru) * | 2006-04-24 | 2007-12-27 | Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") | Высококремнеземный цеолит и способ его получения |
| EP2046850A1 (en) * | 2006-08-03 | 2009-04-15 | Ciba Holding Inc. | Block copolymers of diallyldialkylammonium derivatives |
| CN100582005C (zh) * | 2007-12-11 | 2010-01-20 | 中国铝业股份有限公司 | 导向剂法合成zsm-5分子筛的方法 |
| EP2130586A1 (en) | 2008-06-06 | 2009-12-09 | Total Petrochemicals Research Feluy | Process for making crystalline metallosilicates |
| JP5426983B2 (ja) * | 2009-09-30 | 2014-02-26 | 旭化成ケミカルズ株式会社 | Ｚｓｍ−５型ゼオライトの製造方法 |
| JP5580639B2 (ja) * | 2010-03-31 | 2014-08-27 | 日揮触媒化成株式会社 | 新規ｚｓｍ−５型ゼオライト粒子およびその合成方法 |
| CN103384644B (zh) | 2010-11-23 | 2016-10-26 | 信实工业公司 | 一种mww型沸石的制备方法 |
| CN104556123B (zh) * | 2013-10-23 | 2016-11-16 | 中国石油化工股份有限公司 | 一种原位晶化y型分子筛及其合成方法 |
| CN103708495B (zh) * | 2013-12-27 | 2015-12-09 | 复旦大学 | 纳米棒状颗粒有序组装的zsm-5沸石分子筛的制备方法 |
| KR101644310B1 (ko) * | 2014-02-28 | 2016-08-01 | 노경태 | 알루미노실리케이트 구조체, 그의 제조방법 및 그를 이용한 용도 |
| CN104192859B (zh) * | 2014-08-21 | 2018-02-06 | 陕西延长石油(集团)有限责任公司研究院 | 一种小晶粒zsm‑5分子筛的快速合成法 |
| RU2640236C1 (ru) * | 2017-06-08 | 2017-12-27 | Ирина Игоревна Иванова | Способ получения цеолита mfi |
| KR102227515B1 (ko) * | 2018-12-18 | 2021-03-12 | 주식회사 포스코 | 제올라이트 및 그 제조방법 |
Family Cites Families (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3288770A (en) * | 1962-12-14 | 1966-11-29 | Peninsular Chem Res Inc | Water soluble quaternary ammonium polymers |
| NL149917B (nl) * | 1965-06-09 | 1976-06-15 | Calgon Corp | Werkwijze voor het vervaardigen van elektrisch geleidend papier en vel papier, verkregen volgens deze werkwijze. |
| US3968037A (en) * | 1972-09-01 | 1976-07-06 | Calgon Corporation | Emulsion polymerization of cationic monomers |
| US4156101A (en) * | 1974-03-20 | 1979-05-22 | Dart Industries Inc. | Low molecular weight tert.-alcohols |
| US4166099A (en) | 1974-04-20 | 1979-08-28 | W. R. Grace & Co. | Preparation of zeolites |
| US4235753A (en) * | 1979-03-16 | 1980-11-25 | Engelhard Minerals & Chemicals Corporation | Zeolitized composite bodies and manufacture thereof |
| US4499197A (en) | 1982-03-24 | 1985-02-12 | W. R. Grace & Co. | Co-gel catalyst manufacture |
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| DE3402842A1 (de) | 1984-01-27 | 1985-08-08 | Süd-Chemie AG, 8000 München | Verfahren zur herstellung von kristallinen zeolithischen alumosilicaten |
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-
2003
- 2003-02-19 US US10/370,135 patent/US6667023B2/en not_active Expired - Lifetime
- 2003-02-26 WO PCT/EP2003/001991 patent/WO2003074423A1/en not_active Ceased
- 2003-02-26 BR BRPI0308110-9A patent/BR0308110B1/pt active IP Right Grant
- 2003-02-26 EP EP03708149A patent/EP1478596B1/en not_active Expired - Lifetime
- 2003-02-26 KR KR1020047013523A patent/KR100960438B1/ko not_active Expired - Lifetime
- 2003-02-26 CA CA2477713A patent/CA2477713C/en not_active Expired - Lifetime
- 2003-02-26 DE DE60303500T patent/DE60303500T2/de not_active Expired - Lifetime
- 2003-02-26 CN CNB038050765A patent/CN1307101C/zh not_active Expired - Lifetime
- 2003-02-26 JP JP2003572900A patent/JP4520743B2/ja not_active Expired - Lifetime
- 2003-02-26 AT AT03708149T patent/ATE317370T1/de not_active IP Right Cessation
- 2003-03-21 US US10/509,138 patent/US20050182222A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CA2477713C (en) | 2010-09-21 |
| KR20040093081A (ko) | 2004-11-04 |
| US20030170172A1 (en) | 2003-09-11 |
| US20050182222A1 (en) | 2005-08-18 |
| BR0308110A (pt) | 2005-01-04 |
| DE60303500T2 (de) | 2006-09-28 |
| EP1478596A1 (en) | 2004-11-24 |
| EP1478596B1 (en) | 2006-02-08 |
| JP2005519014A (ja) | 2005-06-30 |
| DE60303500D1 (de) | 2006-04-20 |
| CN1656018A (zh) | 2005-08-17 |
| KR100960438B1 (ko) | 2010-05-28 |
| BR0308110B1 (pt) | 2011-10-04 |
| CN1307101C (zh) | 2007-03-28 |
| WO2003074423A1 (en) | 2003-09-12 |
| CA2477713A1 (en) | 2003-09-12 |
| ATE317370T1 (de) | 2006-02-15 |
| US6667023B2 (en) | 2003-12-23 |
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