JP4008559B2 - Method for manufacturing diaphragm for electroacoustic transducer and diaphragm for electroacoustic transducer - Google Patents

Method for manufacturing diaphragm for electroacoustic transducer and diaphragm for electroacoustic transducer Download PDF

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Publication number
JP4008559B2
JP4008559B2 JP02283498A JP2283498A JP4008559B2 JP 4008559 B2 JP4008559 B2 JP 4008559B2 JP 02283498 A JP02283498 A JP 02283498A JP 2283498 A JP2283498 A JP 2283498A JP 4008559 B2 JP4008559 B2 JP 4008559B2
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JP
Japan
Prior art keywords
diaphragm
resin
electroacoustic transducer
emulsion
manufacturing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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JP02283498A
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Japanese (ja)
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JPH11205893A (en
Inventor
幹康 金井
昭浩 野々垣
隆治 一柳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foster Electric Co Ltd
Toyobo Co Ltd
Original Assignee
Foster Electric Co Ltd
Toyobo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to JP02283498A priority Critical patent/JP4008559B2/en
Publication of JPH11205893A publication Critical patent/JPH11205893A/en
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Publication of JP4008559B2 publication Critical patent/JP4008559B2/en
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Description

【0001】
【発明の属する技術分野】
この発明は音響機器の一種であるスピーカやマイクロホン等の電気音響変換器用振動板の製造方法およびその製造方法によって作製された電気音響変換器用振動板に関する。
【0002】
【従来の技術】
この種の電気音響変換器用振動板に要求される物性としては、比弾性率が大きく、適当な内部損失を有し、機械的疲労が少なく、耐候性に優れている等の点が挙げられる。このような要望に応えるべく従来より種々の金属、セラミックス、合成樹脂、合成繊維、植物セルロース(木材、非木材パルプ)、カーボン繊維、アラミド繊維等の素材が提案され、種々の加工法を用いて加工され使用されてきた。
【0003】
【発明が解決しようとする課題】
その中で、金属やセラミックスは弾性率は大きいものの、密度が高く内部損失が小さいため、高域再生用には使用できるが、軽量高剛性が求められる中低音域や全帯域用には不適当である。また、合成樹脂を用いたものは合成樹脂単体、もしくはベースになる樹脂にフィラー(filler)を混合したもの、他の樹脂とアロイ(alloy)したもの等をシート化し、これを成形加工(主に真空成形)したものや、ペレットにして射出成形機にて射出成形したもの等があるが、これらの樹脂振動板は比弾性率も高く適当な内部損失も持っており、量産時のバラツキも小さいことから比較的優れた性質を有するが、熱に弱く、厚みのコントロールが容易でないため設計上の自由度の小さいことが欠点である。
【0004】
一方、各種植物のセルロース繊維を用いて抄造により得られる紙製振動板は、設計の自由度が高く、適当な内部損失を有しているものの、比弾性率はそれほど大きくなく、この比弾性率を改善するため、各種合成繊維、特にアラミド繊維やカーボン繊維、セラミックス繊維を混合したものが提案され実用化されている。
【0005】
また、植物セルロース繊維との混合ではなく、アラミド繊維のみを用いて織布としたもの、カーボン繊維のみを用いて織布としたものを樹脂含浸し、成形加工した振動板もある。これらの振動板は、高い強度を有し、比弾性率も高い。特に、カーボン繊維の織布によるものは、アラミド繊維のものに比べても高い比弾性率を有している。
【0006】
しかしながら、カーボン繊維は高い比弾性率を有するものの内部損失がそれほど大きくないという欠点がある。また、カーボンの導電性は、スピーカ製造時に絶縁処理の必要があり、コスト面での障害ともなる。
【0007】
また、アラミド繊維は適当な内部損失を有しているが、比弾性率においてはカーボン繊維に及ばない。さらに、植物セルロース繊維を用いた振動板に比べると、アラミド繊維の織布、カーボン繊維の織布ともそれら自体の比重が大きいので、特に、成形時に樹脂が織布の表裏を覆い、目止めも同時に行うタイプのプリプレグを用いた成形方法の場合には、振動板質量が増加し、スピーカの能率低下につながりやすいという欠点がある。
【0008】
本発明はかかる点に鑑みなされたもので、その目的とするところは、上記のような従来の欠点を補うため、弾性率がカーボン繊維と略同等(アラミド繊維の約2倍)で、内部損失も大きく、高強度、高耐熱性を有した有機繊維である、ポリパラフェニレンベンゾビスオキサゾール(PBO)繊維を用いた織布を基材とし、比弾性率、内部損失が大きく、良好な音質が得られ、かつ軽量化、コストダウンをも可能とした電気音響変換器用振動板の製造方法およびその製造方法によって作製された電気音響変換器用振動板を提供することにある。
【0009】
【課題を解決するための手段】
上記目的を達成するため、請求項1記載の電気音響変換器用振動板の製造方法は、引張強度4.0GPa以上、初期引張弾性率140GPa以上のポリパラフェニレン・ベンゾビスオキサゾール繊維からなる織布に、フェノール樹脂もしくはメラミン樹脂からなる熱硬化性樹脂を前記繊布の重量に対し、乾燥重量%で3%以上20%以下含浸し、所定の形状に成形した後、片面にアクリル系エマルジョン、酢酸ビニル系エマルジョン、またはスチレン・ブタジエン系エマルジョンからなるエマルジョン樹脂をコーティングすることを特徴とした。
請求項2記載の電気音響変換器用振動板は、請求項1の製造方法によって作製したことを特徴とした。
【0010】
【発明の実施の形態】
本発明では、引張強度4.0GPa以上、初期引張弾性率140GPa以上であるポリパラフェニレン・ベンゾビスオキサゾール(PBO)繊維からなる織布を、乾燥重量%で、固形分3%以上〜20%以下、好ましくは10%以下の熱硬化性樹脂で含浸し、所定の形状に成形することにより、従来のアラミド繊維の織布からなる振動板と、カーボン繊維の織布からなる振動板の良い所を合わせ持った、比弾性率(音速)が大きく、かつ内部損失の大きい、より理想に近い初期物性を持つ振動板を得るようにしている。
【0011】
この場合、成形時に樹脂が織布の表裏を覆い、目止めも同時に行うタイプのプリプレグを用いたものに比べ、成形時、少ない樹脂量で形状保持のみを行い、目止めをエマルジョン樹脂による片面コーティングとすることで、樹脂量を軽減することができ、より軽量な振動板を得ることができる。
【0012】
また、熱硬化性樹脂の固形分は上記の通り3%以上〜20%以下としたのは、3%未満では形状保持ができなくなり、また、20%より多いと、成形と同時に目止めまで行うエポキシプリプレグなどのタイプとの質量の差が小さくなり、軽量化の効果が薄れるためである。
【0013】
【実施例】
次に、本発明の実施例を示す。すなわち本発明は、上述のように、上記の物性を有するポリパラフェニレン・ベンゾビスオキサゾール(PBO)繊維を用いた織布を樹脂含浸し、これを成形し、片面コーティングして振動板を作製したもので、その具体的製造手順は以下の通りである。
【0014】
1.ボイド直径が25Å以下のPBO繊維からなる織布を、希釈溶剤、離型剤を所定量添加したフェノール樹脂で含浸し、樹脂量が、乾燥質量で10%となるシートを作製した。熱硬化性樹脂としては、その他メラミン樹脂を用いても良い。
【0015】
2.上記で得られたシートを、所定の形状(この例ではコーン形)の金型を用いて加圧加熱乾燥し、所定の形状を得た。ここでの加圧加熱乾燥条件は、700kg、230℃、10秒とした。
【0016】
3.上記2で得られた成形物の片面(この例では裏面)に、アクリル系エマルジョン樹脂をコートし、乾燥した後、所定の形状に打ち抜いて振動板本体を得た。なお、コーティングする樹脂としては、その他、酢酸ビニル系エマルジョン、またはスチレン・ブタジエン系エマルジョン樹脂でも良い。
【0017】
4.上記3で得られた振動板本体の外周に合成ゴムからなるエッジを取り付け、図1の振動板1を得た。図1において、2はエマルジョン樹脂、3はエッジである。
【0018】
この例では、コーン形状の振動板を作製したが、センターキャップ、ドーム形振動板などの作製も可能である。
【0019】
図2は本発明の周波数に対する音圧特性を示すもので、Aは本発明、Bは従来例であり、本発明では低音域から高音域まで平坦で、かつ高域再生限界が高いものとなっている。
【0020】
【発明の効果】
以上の通り本発明によれば、ポリパラフェニレン・ベンゾビスオキサゾール繊維からなる織布を用い、これに、熱硬化性樹脂を含浸し、所定形状に成形後、エマルジョン樹脂を片面にコーティングして構成したため、この振動板によれば、比弾性率が大きく、さらに内部損失も比較的大きいため、分割振動が起きにくく、低音域から高音域まで平坦で、かつ高域再生限界の高い特性を得ることができる。
【0021】
また、使用する樹脂量を減らすことにより、振動板の軽量化ができ、スピーカの音圧レベルを向上できる。さらに導電性がないため、スピーカ製造時に絶縁処理がいらず、その分、製造コストが安価になる。
【図面の簡単な説明】
【図1】 本発明によって製造された振動板形状の一例を示す。
【図2】 本発明の周波数に対する音圧特性を示す。
【符号の説明】
1 振動板
2 エマルジョン樹脂
3 エッジ
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for manufacturing a diaphragm for an electroacoustic transducer such as a speaker or a microphone, which is a kind of acoustic equipment, and a diaphragm for an electroacoustic transducer manufactured by the manufacturing method .
[0002]
[Prior art]
The physical properties required for this type of electroacoustic transducer diaphragm include a high specific elastic modulus, an appropriate internal loss, little mechanical fatigue, and excellent weather resistance. In order to meet these demands, materials such as various metals, ceramics, synthetic resins, synthetic fibers, vegetable cellulose (wood, non-wood pulp), carbon fibers, aramid fibers, etc. have been proposed and used various processing methods. Processed and used.
[0003]
[Problems to be solved by the invention]
Among them, metals and ceramics have a high elastic modulus, but because of their high density and low internal loss, they can be used for high-frequency reproduction, but are not suitable for mid-low frequencies and all bands where lightweight and high rigidity is required. It is. In addition, for synthetic resin, a synthetic resin alone or a base resin mixed with filler, or an alloy with other resin is made into a sheet, which is molded (mainly Vacuum molded), and pelletized and injection molded with an injection molding machine, etc. These resin diaphragms have a high specific modulus and appropriate internal loss, and have little variation during mass production. Therefore, it has a relatively excellent property, but it is weak to heat and its thickness is not easy to control, so it has a drawback in that the degree of freedom in design is small.
[0004]
On the other hand, a paper diaphragm obtained by papermaking using cellulose fibers of various plants has a high degree of freedom in design and has an appropriate internal loss, but the specific modulus is not so large. In order to improve the above, various synthetic fibers, in particular, aramid fibers, carbon fibers, and ceramic fibers are proposed and put into practical use.
[0005]
There is also a diaphragm in which a woven fabric using only aramid fibers and a woven fabric using only carbon fibers are impregnated with resin, and not molded with plant cellulose fibers. These diaphragms have high strength and high specific elastic modulus. In particular, a carbon fiber woven fabric has a higher specific modulus than that of an aramid fiber.
[0006]
However, although carbon fiber has a high specific modulus, it has a drawback that internal loss is not so large. In addition, the conductivity of carbon needs to be insulated during speaker production, which is an obstacle in terms of cost.
[0007]
Aramid fibers have an appropriate internal loss, but the specific elastic modulus does not reach that of carbon fibers. Furthermore, compared to diaphragms using plant cellulose fibers, both woven fabrics of aramid fibers and woven fabrics of carbon fibers have a higher specific gravity. In particular, the resin covers the front and back of the woven fabric during molding. In the case of a molding method using a prepreg of the type that is performed simultaneously, there is a drawback that the mass of the diaphragm increases and the efficiency of the speaker tends to decrease.
[0008]
The present invention has been made in view of the above points. The purpose of the present invention is to compensate for the above-mentioned conventional drawbacks, and the elastic modulus is substantially the same as that of carbon fibers (about twice that of aramid fibers), and internal loss. Large woven fabric using polyparaphenylene benzobisoxazole (PBO) fiber, which is an organic fiber having high strength and high heat resistance, and has a large specific elastic modulus, large internal loss, and good sound quality. An object of the present invention is to provide a method for manufacturing an electroacoustic transducer diaphragm that is obtained and can be reduced in weight and cost, and an electroacoustic transducer diaphragm manufactured by the manufacturing method .
[0009]
[Means for Solving the Problems]
In order to achieve the above object, the method for manufacturing a diaphragm for an electroacoustic transducer according to claim 1 is applied to a woven fabric made of polyparaphenylene benzobisoxazole fibers having a tensile strength of 4.0 GPa or more and an initial tensile elastic modulus of 140 GPa or more. , Impregnated with a thermosetting resin made of phenolic resin or melamine resin in a dry weight percentage of 3% or more and 20% or less with respect to the weight of the fabric , molded into a predetermined shape, and then an acrylic emulsion or vinyl acetate type on one side It is characterized by coating an emulsion resin comprising an emulsion or a styrene / butadiene emulsion .
The diaphragm for an electroacoustic transducer according to claim 2 is manufactured by the manufacturing method according to claim 1.
[0010]
DETAILED DESCRIPTION OF THE INVENTION
In the present invention, a woven fabric made of polyparaphenylene benzobisoxazole (PBO) fibers having a tensile strength of 4.0 GPa or more and an initial tensile modulus of 140 GPa or more is dry weight%, and the solid content is 3% to 20%. Preferably, a diaphragm made of a woven fabric of aramid fiber and a diaphragm made of a woven fabric of carbon fiber are good by impregnating with a thermosetting resin of 10% or less and molding into a predetermined shape. In addition, a diaphragm having a higher specific elastic modulus (sound speed) and a larger internal loss and having near-ideal initial physical properties is obtained.
[0011]
In this case, compared to the type using a prepreg of the type in which the resin covers the front and back of the woven fabric at the time of molding, and the sealing is performed at the same time, only the shape is maintained at the time of molding, and the sealing is applied on one side with emulsion resin By doing so, the amount of resin can be reduced, and a lighter diaphragm can be obtained.
[0012]
Further, the solid content of the thermosetting resin is 3% to 20% as described above. If it is less than 3%, the shape cannot be maintained. This is because the difference in mass with a type such as an epoxy prepreg is reduced, and the effect of reducing the weight is reduced.
[0013]
【Example】
Next, examples of the present invention will be described. That is, in the present invention, as described above, a woven fabric using the polyparaphenylene benzobisoxazole (PBO) fiber having the above-mentioned physical properties is impregnated with resin, molded, and coated on one side to produce a diaphragm. The specific manufacturing procedure is as follows.
[0014]
1. A woven fabric made of PBO fibers having a void diameter of 25 mm or less was impregnated with a phenol resin to which a predetermined amount of a diluent solvent and a release agent were added, and a sheet having a resin amount of 10% by dry mass was produced. As the thermosetting resin, other melamine resins may be used.
[0015]
2. The sheet obtained above was dried under pressure using a mold having a predetermined shape (in this example, a cone shape) to obtain a predetermined shape. The pressure heating and drying conditions here were 700 kg, 230 ° C., and 10 seconds.
[0016]
3. One side (the back side in this example) of the molded product obtained in 2 above was coated with an acrylic emulsion resin, dried, and then punched into a predetermined shape to obtain a diaphragm main body. The resin to be coated may be vinyl acetate emulsion or styrene / butadiene emulsion resin.
[0017]
4). An edge made of synthetic rubber was attached to the outer periphery of the diaphragm main body obtained in the above 3 to obtain the diaphragm 1 of FIG. In FIG. 1, 2 is an emulsion resin and 3 is an edge.
[0018]
In this example, a cone-shaped diaphragm is manufactured, but a center cap, a dome-shaped diaphragm, and the like can also be manufactured.
[0019]
FIG. 2 shows the sound pressure characteristics with respect to the frequency of the present invention. A is the present invention, B is a conventional example, and the present invention is flat from the low range to the high range and has a high high range reproduction limit. ing.
[0020]
【The invention's effect】
As described above, according to the present invention, a woven fabric made of polyparaphenylene benzobisoxazole fibers is used, impregnated with a thermosetting resin, molded into a predetermined shape, and then coated with an emulsion resin on one side. Therefore, according to this diaphragm, since the specific elastic modulus is large and the internal loss is also relatively large, it is difficult for divided vibration to occur, and it is flat from the low range to the high range, and has a characteristic with a high high range reproduction limit. Can do.
[0021]
Further, by reducing the amount of resin used, the diaphragm can be reduced in weight and the sound pressure level of the speaker can be improved. Furthermore, since there is no electrical conductivity, no insulation treatment is required when manufacturing the speaker, and the manufacturing cost is reduced accordingly.
[Brief description of the drawings]
FIG. 1 shows an example of a diaphragm shape manufactured according to the present invention.
FIG. 2 shows sound pressure characteristics with respect to frequency according to the present invention.
[Explanation of symbols]
1 Diaphragm 2 Emulsion resin 3 Edge

Claims (2)

引張強度4.0GPa以上、初期引張弾性率140GPa以上のポリパラフェニレン・ベンゾビスオキサゾール繊維からなる織布に、フェノール樹脂もしくはメラミン樹脂からなる熱硬化性樹脂を前記繊布の重量に対し、乾燥重量%で3%以上20%以下含浸し、所定の形状に成形した後、片面にアクリル系エマルジョン、酢酸ビニル系エマルジョン、またはスチレン・ブタジエン系エマルジョンからなるエマルジョン樹脂をコーティングすることを特徴とする電気音響変換器用振動板の製造方法A thermosetting resin made of a phenol resin or a melamine resin is dried on a woven fabric made of polyparaphenylene benzobisoxazole fibers having a tensile strength of 4.0 GPa or more and an initial tensile elastic modulus of 140 GPa or more, based on the weight of the fabric. Electroacoustic conversion characterized in that it is impregnated with 3% or more and 20% or less and molded into a predetermined shape and then coated on one side with an emulsion resin comprising an acrylic emulsion, a vinyl acetate emulsion, or a styrene / butadiene emulsion. A method for manufacturing a mechanical diaphragm. 上記請求項1の製造方法によって作製したことを特徴とする電気音響変換器用振動板。 The characterized in that it is produced by the process according to claim 1 electric acoustic converter diaphragm.
JP02283498A 1998-01-19 1998-01-19 Method for manufacturing diaphragm for electroacoustic transducer and diaphragm for electroacoustic transducer Expired - Lifetime JP4008559B2 (en)

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JP02283498A JP4008559B2 (en) 1998-01-19 1998-01-19 Method for manufacturing diaphragm for electroacoustic transducer and diaphragm for electroacoustic transducer

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JP4008559B2 true JP4008559B2 (en) 2007-11-14

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JP3522615B2 (en) * 1999-12-15 2004-04-26 株式会社ケンウッド Woven fabric for speaker diaphragm, diaphragm for speaker and speaker
JP7263358B2 (en) * 2018-07-27 2023-04-24 ヤマハ株式会社 Speaker diaphragm and method for manufacturing speaker diaphragm

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