JP3880320B2 - Underwear made from lightweight heat-insulated knitted fabric - Google Patents

Underwear made from lightweight heat-insulated knitted fabric Download PDF

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Publication number
JP3880320B2
JP3880320B2 JP2001031996A JP2001031996A JP3880320B2 JP 3880320 B2 JP3880320 B2 JP 3880320B2 JP 2001031996 A JP2001031996 A JP 2001031996A JP 2001031996 A JP2001031996 A JP 2001031996A JP 3880320 B2 JP3880320 B2 JP 3880320B2
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Japan
Prior art keywords
knitted fabric
yarn
lightweight heat
heat
surface layer
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Expired - Lifetime
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JP2001031996A
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Japanese (ja)
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JP2002235264A5 (en
JP2002235264A (en
Inventor
剛 添田
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Teijin Frontier Co Ltd
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Teijin Fibers Ltd
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Priority to JP2001031996A priority Critical patent/JP3880320B2/en
Application filed by Teijin Fibers Ltd filed Critical Teijin Fibers Ltd
Priority to EP02711434A priority patent/EP1359238B1/en
Priority to CNA028078802A priority patent/CN1501996A/en
Priority to DE60219284T priority patent/DE60219284T2/en
Priority to KR1020037010367A priority patent/KR100821114B1/en
Priority to US10/467,085 priority patent/US20040060328A1/en
Priority to PCT/JP2002/001109 priority patent/WO2002063082A1/en
Publication of JP2002235264A publication Critical patent/JP2002235264A/en
Publication of JP2002235264A5 publication Critical patent/JP2002235264A5/ja
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/02Moisture-responsive characteristics
    • D10B2401/021Moisture-responsive characteristics hydrophobic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/02Moisture-responsive characteristics
    • D10B2401/022Moisture-responsive characteristics hydrophylic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2403/00Details of fabric structure established in the fabric forming process
    • D10B2403/01Surface features
    • D10B2403/011Dissimilar front and back faces
    • D10B2403/0114Dissimilar front and back faces with one or more yarns appearing predominantly on one face, e.g. plated or paralleled yarns
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2403/00Details of fabric structure established in the fabric forming process
    • D10B2403/02Cross-sectional features
    • D10B2403/021Lofty fabric with equidistantly spaced front and back plies, e.g. spacer fabrics
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/02Underwear

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Knitting Of Fabric (AREA)
  • Undergarments, Swaddling Clothes, Handkerchiefs Or Underwear Materials (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は、表裏の地組織を結接糸でタックした三層構造編地に関し、さらに詳しくは、軽量性があり、保温性に優れた編地に関するものである。用途としては、高い保温性を必要とする肌着などに好適に使用される。
【0002】
【従来の技術】
一般に、表裏の地組織を結接糸でタックした三層構造編地は、軽量で嵩高性や保温性に優れるとともに、汎用性のある外観から、スポーツ衣料用途のトレーニングウェアーや子供、婦人用のカジュアル商品など広く用いられている。しかし、肌着用途では直接肌に接触するため、さらに一層の軽量性と保温性が求められるのが現状である。
【0003】
また、従来の肌着編物としては綿などの天然繊維もしくは天然繊維と合成繊維、再生繊維、半合成繊維などとを組み合わせて丸編機でフライスあるいは天竺組織に編成されたものが主として使用されている。これらの従来の肌着編物では、さらに一層の保温性が求められているため、これまでは表面あるいは裏面を起毛したり、遠赤外線や近赤外線を吸収する物質を練りこんだ繊維、あるいは空気中の湿度を吸収することにより発熱する繊維等の機能繊維を使用することで優れた保温性が確保されていた。しかるに起毛では厚みが極端に増したり、また、これまでの機能繊維を使用した組織ではさらに保温性を上げるために組織上厚みを増す必要があり、その結果重量増となる欠点があった。
【0004】
【発明が解決しようとする課題】
本発明の目的は、上記従来技術の有する問題点を解消し、厚さが薄く軽量であるにもかかわらず、高い保温性を有する軽量保温編地を提供することにある。
【0005】
【課題を解決するための手段】
上記目的を達成するため、本発明の軽量保温編地を用いてなる肌着衣料は次の構成を有する。
1.表面層と裏面層とを結接糸でタックしてなる三層構造編地において、該結接糸が中空糸で構成されており、かつ編地の厚さが0.5〜1.2mm、目付けが80〜200g/m 2 であり、かつ保温性αが18%以上であることを特徴とする軽量保温編地を用いてなる肌着衣料。
2.該結接糸が総繊度が20〜170デシテックス、単糸の繊度が1〜10デシテックス、単糸の中空率が10〜55%のポリエステルマルチフィラメント糸である上記1記載の軽量保温編地を用いてなる肌着衣料。
3.結接糸で形成される中間層の目付けが25〜60g/m 2 である上記1または上記2に記載の軽量保温編地を用いてなる肌着衣料
4.表面層が主として総繊度20〜170デシテックス、単糸繊度0.1〜20デシテックスのポリエステルウーリー糸で形成されている上記1〜3のいずれか1項に記載の軽量保温編地を用いてなる肌着衣料
5.裏面層が主として天然繊維、合成繊維、再生繊維、半合成繊維の群より選択された少なくとも1種の繊維である上記1〜4のいずれか1項に記載の軽量保温編地を用いてなる肌着衣料
6.編地が丸編である上記1〜5のいずれか1項に記載の軽量保温編地を用いてなる肌着衣料
【0006】
【発明の実施の形態】
以下、本発明の軽量保温編地を詳細に説明する。
【0007】
本発明の軽量保温裏地は、表面層と裏面層とを結接糸でタックしてなる三層構造編地であって該結接糸が中空糸で構成されていることを特徴とする。ここで、表面層は着用の際に外気側に位置する面であり、裏面層は保温する側に位置する面である。該表面層と裏面層は結接糸でタックされ、三層構造編地が形成される。
【0008】
図1は、本発明の軽量保温編地の一例を示す側面図であり、表面層1と裏面層2とが結接糸3でタックされており、結接糸3は中空糸で構成される。
【0009】
本発明の軽量保温編地の結接糸は保温性と風合いの点で総繊度が20〜170デシテックス、単糸の繊度が1〜10デシテックス、単糸の中空率が10〜55%のマルチフィラメント糸であることがのぞましい。また、結接糸の素材は通常、衣料用に用いられる繊維であり、特に限定されるものではないが、上記の中空率を得るためにポリエステル繊維が好適である。
【0010】
また、本発明の軽量保温裏地の表面層は保温性の点でウーリー糸、紡績糸、空気交絡糸、異収縮混繊糸などの嵩高糸で形成されることがこのましく、とくに風合いを良くすると同時に結接糸が表面層から飛び出すのを防ぐために総繊度が20〜170デシテックス、単糸繊度0.1〜20デシテックスのポリエステルウーリー糸で形成されることがのぞましい。
【0011】
さらに、本発明の軽量保温編地の裏面層を形成する繊維は、着用上の快適性を得ると同時に結接糸が裏面層から飛び出すのを防ぐために120〜20番手の天然繊維、合成繊維、再生繊維、半合成繊維のうちのいずれか、もしくはこれらを組み合わせた繊維であることがのぞましい。
【0012】
本発明の軽量保温編地においては、保温性と軽量性とを両立させるという点から、厚さが0.5〜1.2mmであり、かつ目付けが80〜200g/m2であることがのぞましく、より一層軽量保温効果を高めるためには、結接糸で形成される中間層の目付けが25〜60g/m2であることがのぞましい。
【0013】
さらに、下記に定義する保温性αが18%以上であることがよりのぞましい。保温性α:
20℃の雰囲気温度中で10cm四方の65℃の熱源上に測定サンプルを置いた場合の消費電力W1(ワット)と、同じ熱源で測定サンプルを置かない場合の消費電力W0(ワット)とから下式に基づいて算出する。
保温性α=(W0−W1)/W0×100(%)
【0014】
本発明の軽量保温編地を製造するには、例えば、丸編機のシリンダー側及びダイヤル側から、表面層を形成する繊維と裏面層を形成する繊維をそれぞれ供給して、結接糸でタックしながら編成すればよい。
【0015】
【実施例】
以下、本発明を実施例をあげて詳細に説明するが、本発明はこれらによって限定されるものではない。
【0016】
[実施例1]
丸編23Gダブル機を用いて、本発明である三層構造の軽量保温編地を編成した。表面層には56デシテックス36フィラメントのポリエチレンテレフタレートウーリー糸、裏面層には60番手の綿糸を使用し、結接糸には40デシテックス12フィラメントのポリエチレンテレフタレート中空糸(中空率35%)を使用した。表裏の地組織を結接糸でタックしながら、図2に示す組織図の三層構造編地を得た。
【0017】
得られた編地は、軽量性、保温性に優れ、表面タッチの柔かい編地であった。また、結接糸が表面層や裏面層から飛び出すこともなく品位も良好であった。
表1に、評価測定結果を示す。
【0018】
[比較例1]
丸編23Gダブル機を用い、図2に示す組織図に従って表面層には56デシテックス36フィラメントのポリエチレンテレフタレートウーリー糸、裏面層には60番手の綿糸を使用し、結接糸には本発明に使用する中空糸と同じ見掛け繊度をもつ56デシテックス24フィラメントのポリエチレンテレフタレート糸(通常の非中空糸)を使用して三層編地を編成した。
【0019】
得られた編地は、品位は良好であるものの保温性が不十分であった。
表1に、評価測定結果を示す。
【0020】
[比較例2]
丸編機を用い、40番手の綿糸を使用してフライス組織で編地を編成した。
得られた編地は保温性が不良であった。
表1に、評価測定結果を示す。
【0021】
【表1】

Figure 0003880320
【0022】
【発明の効果】
本発明の軽量保温編地は、保温性に優れ、かつ、軽量であるために、肌着など高い保温性を必要とする用途に利用することができる。
【図面の簡単な説明】
【図1】本発明の軽量保温編地の一例を示す側面図である。
【図2】本発明の軽量保温編地の組織図の一例である。
【符号の説明】
1 表面層
2 裏面層
3 結接糸[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a three-layer structure knitted fabric in which the front and back ground structures are tucked with a binding yarn, and more particularly to a knitted fabric having light weight and excellent heat retention. As a use, it is used suitably for the underwear etc. which require high heat retention.
[0002]
[Prior art]
In general, a three-layered knitted fabric that is tucked with a binding yarn on the front and back fabrics is lightweight and has excellent bulkiness and heat retention properties, as well as versatile appearances, for sportswear training wear and children and women's use. It is widely used for casual goods. However, since it is in direct contact with the skin for use as an undergarment, further lightness and heat retention are required.
[0003]
Further, as a conventional underwear knitted fabric, a natural fiber such as cotton or a combination of natural fiber and synthetic fiber, regenerated fiber, semi-synthetic fiber, etc., which is knitted in a circular knitting machine into a milling or tense structure is mainly used. . In these conventional underwear knitted fabrics, there is a need for further heat retention, so far, the front or back surface is raised, the fiber kneaded with a substance that absorbs far infrared rays or near infrared rays, or in the air Excellent heat retention was ensured by using functional fibers such as fibers that generate heat by absorbing humidity. However, there is a drawback that the thickness of the raised hair is extremely increased, and in the tissue using the functional fiber so far, it is necessary to increase the thickness on the tissue in order to further increase the heat retaining property, resulting in an increase in weight.
[0004]
[Problems to be solved by the invention]
An object of the present invention is to provide a lightweight heat-insulating knitted fabric having high heat-retaining properties in spite of the fact that the above-mentioned conventional techniques are solved and the thickness is thin and light.
[0005]
[Means for Solving the Problems]
In order to achieve the above object, an undergarment using the lightweight heat-insulated knitted fabric of the present invention has the following configuration.
1. In a three-layer structure knitted fabric formed by tacking the front surface layer and the back surface layer with a binding yarn, the binding yarn is constituted by a hollow yarn, and the thickness of the knitted fabric is 0.5 to 1.2 mm, A skin apparel comprising a lightweight heat-insulating knitted fabric, having a basis weight of 80 to 200 g / m 2 and a heat-retaining property α of 18% or more .
2. The lightweight heat-insulated knitted fabric according to 1 above, wherein the binding yarn is a polyester multifilament yarn having a total fineness of 20 to 170 dtex, a single yarn fineness of 1 to 10 dtex, and a single yarn hollow ratio of 10 to 55%. Skin clothing.
3. 3. A skin apparel comprising the lightweight heat-insulated knitted fabric according to 1 or 2 above, wherein the basis weight of the intermediate layer formed of the binding yarn is 25 to 60 g / m 2 .
4). The underwear which uses the lightweight heat-insulating knitted fabric of any one of said 1-3 whose surface layer is mainly formed with the polyester wooly yarn of the total fineness of 20-170 dtex and the single yarn fineness of 0.1-20 dtex. Clothing .
5). The underwear which uses the lightweight heat insulation knitted fabric of any one of said 1-4 whose back surface layer is at least 1 sort (s) of fibers mainly selected from the group of natural fiber, synthetic fiber, regenerated fiber, and semi-synthetic fiber. Clothing .
6). The underwear which uses the lightweight heat insulation knitted fabric of any one of said 1-5 whose knitted fabric is a circular knitting .
[0006]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, the lightweight heat insulating knitted fabric of the present invention will be described in detail.
[0007]
The lightweight heat-insulating lining of the present invention is a three-layer structure knitted fabric in which a surface layer and a back surface layer are tacked with a binding yarn, and the binding yarn is composed of a hollow fiber. Here, the surface layer is a surface located on the outside air side when worn, and the back surface layer is a surface located on the side to be kept warm. The front surface layer and the back surface layer are tacked with a binding yarn to form a three-layer structure knitted fabric.
[0008]
FIG. 1 is a side view showing an example of a lightweight heat-insulating knitted fabric of the present invention, in which a surface layer 1 and a back layer 2 are tucked with a binding yarn 3, and the binding yarn 3 is constituted by a hollow fiber. .
[0009]
The binding yarn of the lightweight heat-insulated knitted fabric of the present invention is a multifilament having a total fineness of 20 to 170 dtex, a single yarn fineness of 1 to 10 dtex, and a single yarn hollowness of 10 to 55% in terms of heat retention and texture. I want to be a thread. The material of the binding yarn is usually a fiber used for clothing and is not particularly limited, but a polyester fiber is suitable for obtaining the above-described hollowness.
[0010]
In addition, the surface layer of the lightweight heat-insulating lining of the present invention is preferably formed of bulky yarns such as woolly yarns, spun yarns, air entangled yarns, and different shrinkage mixed yarns from the standpoint of heat insulation, and particularly has a good texture. At the same time, in order to prevent the binding yarn from jumping out of the surface layer, it is preferable to form the polyester wooly yarn having a total fineness of 20 to 170 dtex and a single yarn fineness of 0.1 to 20 dtex.
[0011]
Furthermore, the fibers forming the back layer of the lightweight heat-insulated knitted fabric of the present invention are 120 to 20th natural fibers, synthetic fibers, in order to obtain comfort on wearing and at the same time prevent the binding yarn from jumping out from the back layer. It is preferable that the fiber is one of recycled fiber, semi-synthetic fiber, or a combination of these.
[0012]
In the lightweight heat-insulated knitted fabric of the present invention, the thickness is 0.5 to 1.2 mm and the basis weight is 80 to 200 g / m 2 from the viewpoint of achieving both heat retention and light weight. In order to further enhance the light weight heat retaining effect, it is preferable that the basis weight of the intermediate layer formed of the binding yarn is 25 to 60 g / m 2 .
[0013]
Furthermore, it is more preferable that the heat retention α defined below is 18% or more. Thermal insulation α:
From the power consumption W1 (watt) when the measurement sample is placed on a 10 cm square 65 ° C heat source in an ambient temperature of 20 ° C and the power consumption W0 (watt) when the measurement sample is not placed with the same heat source Calculate based on the formula.
Thermal insulation α = (W0−W1) / W0 × 100 (%)
[0014]
In order to manufacture the lightweight heat-insulated knitted fabric of the present invention, for example, the fiber forming the surface layer and the fiber forming the back layer are respectively supplied from the cylinder side and the dial side of the circular knitting machine, and tacked with the binding yarn. You can organize while doing.
[0015]
【Example】
EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated in detail, this invention is not limited by these.
[0016]
[Example 1]
Using a circular knitting 23G double machine, a lightweight heat insulating knitted fabric having a three-layer structure according to the present invention was knitted. A 56 dtex 36 filament polyethylene terephthalate wooly yarn was used for the surface layer, a 60th cotton yarn was used for the back layer, and a 40 dtex 12 filament polyethylene terephthalate hollow fiber (hollow rate 35%) was used for the binding yarn. While tucking the front and back ground structures with the connecting yarn, a three-layer structure knitted fabric having the structure chart shown in FIG.
[0017]
The obtained knitted fabric was excellent in lightness and heat retention, and was a soft knitted fabric with a surface touch. Further, the binding yarn did not jump out from the front surface layer and the back surface layer, and the quality was good.
Table 1 shows the evaluation measurement results.
[0018]
[Comparative Example 1]
Using a circular knitting 23G double machine, according to the organization chart shown in FIG. 2, the front layer uses 56 dtex 36 filament polyethylene terephthalate wooly yarn, the back layer uses 60th cotton yarn, and the binding yarn is used in the present invention. A three-layer knitted fabric was knitted using a 56 dtex 24-filament polyethylene terephthalate yarn (ordinary non-hollow yarn) having the same apparent fineness as the hollow yarn.
[0019]
Although the obtained knitted fabric had good quality, its heat retention was insufficient.
Table 1 shows the evaluation measurement results.
[0020]
[Comparative Example 2]
Using a circular knitting machine, a knitted fabric was knitted with a milling structure using 40th cotton yarn.
The obtained knitted fabric had poor heat retention.
Table 1 shows the evaluation measurement results.
[0021]
[Table 1]
Figure 0003880320
[0022]
【The invention's effect】
Since the lightweight heat-insulated knitted fabric of the present invention is excellent in heat-retaining properties and lightweight, it can be used for applications that require high heat-retaining properties such as underwear.
[Brief description of the drawings]
FIG. 1 is a side view showing an example of a lightweight heat-insulating knitted fabric of the present invention.
FIG. 2 is an example of an organization chart of a lightweight heat-insulating knitted fabric of the present invention.
[Explanation of symbols]
1 Surface layer 2 Back layer 3 Knotting yarn

Claims (6)

表面層と裏面層とを結接糸でタックしてなる三層構造編地において、該結接糸が中空糸で構成されており、かつ編地の厚さが0.5〜1.2mm、目付けが80〜200g/m 2 であり、かつ保温性αが18%以上であることを特徴とする軽量保温編地を用いてなる肌着衣料。In a three-layer structure knitted fabric formed by tacking the front surface layer and the back surface layer with a binding yarn, the binding yarn is constituted by a hollow yarn, and the thickness of the knitted fabric is 0.5 to 1.2 mm, A skin apparel comprising a lightweight heat-insulating knitted fabric, having a basis weight of 80 to 200 g / m 2 and a heat-retaining property α of 18% or more . 該結接糸が総繊度が20〜170デシテックス、単糸の繊度が1〜10デシテックス、単糸の中空率が10〜55%のポリエステルマルチフィラメント糸である請求項1記載の軽量保温編地を用いてなる肌着衣料。  The lightweight heat-insulating knitted fabric according to claim 1, wherein the binding yarn is a polyester multifilament yarn having a total fineness of 20 to 170 dtex, a single yarn fineness of 1 to 10 dtex, and a single yarn hollow ratio of 10 to 55%. Used underwear clothing. 結接糸で形成される中間層の目付けが25〜60g/m 2 である請求項1または請求項2に記載の軽量保温編地を用いてなる肌着衣料 The skin apparel using the lightweight heat-insulated knitted fabric according to claim 1 or 2 , wherein the basis weight of the intermediate layer formed of the binding yarn is 25 to 60 g / m2 . 表面層が主として総繊度20〜170デシテックス、単糸繊度0.1〜20デシテックスのポリエステルウーリー糸で形成されている請求項1〜3のいずれか1項に記載の軽量保温編地を用いてなる肌着衣料 The surface layer is formed by using the lightweight heat-insulating knitted fabric according to any one of claims 1 to 3, wherein the surface layer is mainly formed of a polyester wooly yarn having a total fineness of 20 to 170 dtex and a single yarn fineness of 0.1 to 20 dtex. Underwear clothing . 裏面層が主として天然繊維、合成繊維、再生繊維、半合成繊維の群より選択された少なくとも1種の繊維である請求項1〜4のいずれか1項に記載の軽量保温編地を用いてなる肌着衣料 The backside layer is at least one type of fiber selected mainly from the group of natural fibers, synthetic fibers, regenerated fibers, and semi-synthetic fibers. The lightweight heat-insulating knitted fabric according to any one of claims 1 to 4. Underwear clothing . 編地が丸編である請求項1〜5のいずれか1項に記載の軽量保温編地を用いてなる肌着衣料 The garment is a circular knitting, A skin apparel formed using the lightweight heat-insulating knitted fabric according to any one of claims 1 to 5 .
JP2001031996A 2001-02-08 2001-02-08 Underwear made from lightweight heat-insulated knitted fabric Expired - Lifetime JP3880320B2 (en)

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JP2001031996A JP3880320B2 (en) 2001-02-08 2001-02-08 Underwear made from lightweight heat-insulated knitted fabric
CNA028078802A CN1501996A (en) 2001-02-08 2002-02-08 Knitted fabric with triple knitted layer structure
DE60219284T DE60219284T2 (en) 2001-02-08 2002-02-08 THREE-POINTED MESHWARE
KR1020037010367A KR100821114B1 (en) 2001-02-08 2002-02-08 3-layer structure knit fabric
EP02711434A EP1359238B1 (en) 2001-02-08 2002-02-08 Three-layer knitted fabric
US10/467,085 US20040060328A1 (en) 2001-02-08 2002-02-08 Three-layer knitting fabric
PCT/JP2002/001109 WO2002063082A1 (en) 2001-02-08 2002-02-08 Three-layer knitting fabric

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CN1501996A (en) 2004-06-02
DE60219284D1 (en) 2007-05-16
DE60219284T2 (en) 2008-01-03
KR100821114B1 (en) 2008-04-11
JP2002235264A (en) 2002-08-23
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US20040060328A1 (en) 2004-04-01

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