JP3436261B2 - 3D or variable print - Google Patents

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a three-dimensional or variable printed matter in which a printed portion is directly provided on the back surface of a lenticular lens, and more particularly to an environmentally friendly three-dimensional or variable printed matter in which a lenticular lens is formed on a non-vinyl chloride sheet base material. It is a thing.

[0002]

2. Description of the Related Art The prior art is disclosed in JP-A-2000-15538.
As disclosed in Japanese Patent Publication No. 0,058, the lens-forming ink is arranged directly in the form of convex stripes on the surface of the sheet-like base material, and each of the ink rows is cured by the action of surface tension and gravity to cure the convex lens-like rows. Disclosed is a manufacturing method for forming a lenticular lens and a stereoscopic or variable printed material in which an image for stereoscopic vision or variable vision is arranged in alignment with any one of the surfaces of the sheet-shaped substrate of the lenticular lens. There is. As a three-dimensional printed matter, a method is known in which a lenticular lens is used to alternately print long and narrow images for the right eye and for the left eye in accordance with the pitch of the lenses, and a parallax is used to make the image look three-dimensional. Also, as a variable printed matter, different elongated images are arranged in order within one pitch of the lenticular lens, and the image that appears varies depending on the viewing angle. This is also well known and will not be described in detail.

As a material for the lenticular lens, a vinyl chloride resin or an acrylic resin has been mainly used because of its excellent workability and moldability, but recently, vinyl chloride resin has been shunned due to environmental problems and the like. . JP 2000-15
Also in JP 5380, a transparent plastic film or sheet made of polyethylene terephthalate (PET), acrylic resin, polypropylene, polyester or the like is mentioned as a sheet-shaped substrate. However, polyethylene terephthalate (PET), polypropylene, polyester and the like have problems that they are unprofitable due to poor moldability or high cost. Therefore, the invention of the above publication considering the manufacturing method may have been reached. However, the conventional method disclosed in Japanese Patent Laid-Open No. 2000-155380 has a problem that it is difficult to obtain an accurate lens design shape because control of the lens shape depends on the surface tension of ink and the action of gravity.

The thermoplastic resin such as polyester, polyamide, polystyrene and polyolefin used as a sheet-like substrate is usually melted to form fibers, films, sheets and the like, but the surface thereof is crystallized. In many cases, the adhesiveness of ink, adhesive, etc. is poor.
Among them, in the case of a film, by the steps of stretching and heat setting,
Due to the high degree of crystal orientation, the level of adhesion is very low, especially in the case of photocurable materials, the adhesion to plastic substrates is generally poor, so lenses or printed patterns (three-dimensional or variable printed images) The adhesiveness to the sheet-shaped substrate was weak, and there was a definite problem of peeling due to bending and bending, which was a barrier to commercialization.

[0005]

SUMMARY OF THE INVENTION In order to solve the above problems, the present invention has good adhesiveness between a lenticular lens and a printed pattern and a thin plate-shaped base material (sheet-shaped base material), and can prevent peeling due to bending and bending. An object of the present invention is to provide a three-dimensional or variable printed matter made of non-vinyl chloride resin that does not have any problem.

[0006]

The invention according to claim 1 provides a transparent primer portion on one surface of a transparent thin plate-like substrate.
Through at least a mark including an image for three-dimensional or variable printing
The transparent thin plate-shaped substrate has a printed portion and is transparent on the opposite surface.
Radical-polymerizable ionizing radiation via a clear primer moiety
A lenticular lens is provided with a line-curable resin,
The transparent primer part has a photopolymerizable unsaturated bond in the molecule.
With a functional group having
And / or an acrylic polymer having an epoxy group.
The three-dimensional or variable printed matter according to claim 1,
It With such a structure, the ink transfer property to the thin plate-shaped substrate of the pattern is stabilized, and the contact surface of the transparent thin plate-shaped substrate and the lenticular lens is firmly adhered, and it may be peeled off even when bending or bending. Disappear. Further, it has adhesiveness to a sheet-like base material made of a thermoplastic resin which has conventionally been poor in adhesiveness such as polyester, polyamide, polystyrene, and polyolefin, and also with respect to a radical-polymerizable ionizing radiation curable resin, they are mutually bonded at the time of curing. By reacting, strong adhesiveness is obtained, and peeling of the lenticular lens and pattern (stereoscopic or variable print image) made of ionizing radiation curable resin such as ultraviolet curable resin is eliminated.

The invention according to claim 2 is the acrylic resin
The polymer has a functional group with a photopolymerizable unsaturated group in the molecule.
It has a range of 0.1 to 40% by weight.
The described three-dimensional or variable printed matter. By setting the content in such a range, a primer having stable and excellent adhesion can be obtained, and a primer having good workability can be obtained. If the functional group is less than 0.1% by weight, it is difficult to obtain a primer having excellent adhesion, and if it exceeds 40% by weight, the primer has tackiness, which is not preferable.

The invention according to claim 3 is the primer described above.
The amount of the functional group having a photopolymerizable unsaturated group in the resin is the total weight of the resin component.
It is 0.01 to 30% by weight based on the amount.
The three-dimensional or variable printed matter according to claim 2. With such a configuration, the acrylic polymer can be mixed with a general resin to expand the selection range of the resin serving as the base of the primer, and thus the selection range of the thin plate-shaped base material. When the amount of the photopolymerizable unsaturated group is less than 0.01% by weight based on the total amount of resin in the primer, it is difficult to obtain a primer having excellent adhesion. If the amount of the photopolymerizable unsaturated group with respect to the total amount of the resin in the primer exceeds 30% by weight, the primer may have tack, which is not preferable.

The invention according to claim 4 is the photopolymerizable polymer.
A functional group having a saturated group is a (meth) acryloyl group.
The three-dimensional or variable printed matter according to claim 1 or 2. With such a structure, when the ionizing radiation-curable resin is irradiated with ionizing radiation to be cured, the primer itself is more preferably radically polymerized.

According to a fifth aspect of the present invention, the active hydrogen is
The functional groups it has are hydroxyl groups, thiol groups, carboxyl groups and
At least one selected from amide groups.
The three-dimensional or variable mark according to any one of claims 1 to 4.
It is a printed matter. With such a constitution, these functional groups serve as a reaction point when the functional group having a photopolymerizable unsaturated bond is introduced and a crosslinking point when the crosslinking agent is used in combination with the primer.

According to a sixth aspect of the present invention, there is provided the transparent ply.
Any of claims 1 to 5 wherein the mer portion contains a cross-linking agent.
The three-dimensional or variable printed matter according to any one of the above. With such a structure, crosslinking of the base polymer of the primer is promoted, the primer cohesive force is increased, and a stronger adhesive force is obtained.

The invention according to claim 7 is the transparent ply.
The thickness of the mer part is 0.01-100 microns
Yes, the thickness of the lenticular lens is 0.01 mm
Claims characterized in that they are between torr and 0.2 mm
The three-dimensional or variable structure according to any one of claims 1 to 6.
It is a printed matter. With such a structure, stable and strong adhesiveness, sufficient performance as a lenticular lens, and suitability in the manufacturing process can be obtained. That is, a three-dimensional or variable printed matter which is flexible and has a transparent thin plate-like base material and a contact surface of a lenticular lens firmly adhered to each other and which is not peeled off even when curved or bent is obtained.

[0013]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below with reference to the drawings. FIG. 1 is an explanatory view showing a cross section of a three-dimensional or variable printed matter of the present invention. Reference numeral 1 is a transparent thin plate-shaped substrate, 2 is a printed portion, 3 is a transparent primer portion, and 4 is a lenticular lens. The transparent thin plate-shaped substrate 1 is, for example, acrylic resin, polyethylene, polypropylene, poly 4
-Polyolefin resins such as methylpentene-1 and polybutene-1, polyester resins such as polyethylene terephthalate and polyethylene naphthalate, polycarbonate resins, polyphenylene sulfide resins,
Examples thereof include polyether sulfone resin, polyethylene sulfide resin, polyphenylene ether resin, styrene resin, polyamide resin, polyimide resin, and cellulose resin such as cellulose acetate. A polyolefin resin is preferable in consideration of environmental problems and flexibility.

An image for a conventional three-dimensional or variable printed matter is printed on the printing portion 2. That is, the elongated images for the right eye and the images for the left eye, which match the pitch of the lenticular lens 4, are alternately printed, and the parallax is used to make the image look solid. In addition, different elongated images are arranged in order in the pitch of the lenticular lens 4, and the image to be viewed changes depending on the viewing angle, and thus the image appears to change. The main body is a three-dimensional or variable printed matter, but normal images, characters, marks, etc. may be partially provided. The printed portion 2 is printed on the transparent thin plate-shaped substrate 1 through the transparent primer portion 3. In order to strengthen the adhesiveness with the primer layer, the ink is preferably an ultraviolet curable ink. White ink may be provided on the printed portion 2. The printing method is not particularly limited as long as the registration accuracy is good, but a lithographic sheet-fed offset printing machine is preferable.

The transparent primer portion 3 is preferably one that strengthens the adhesion between the transparent thin plate-shaped substrate and the radical-polymerizable ionizing radiation curable resin. The transparent primer portion 3 has an acrylic polymer having a functional group having a photopolymerizable unsaturated bond and a functional group having active hydrogen and / or an epoxy group in the molecule (hereinafter referred to as an acrylic polymer P). It is a primer containing. The acrylic polymer P
The functional group having a photopolymerizable unsaturated bond that is introduced into the molecule of is formed into a lenticular lens shape with the radical polymerizable ionizing radiation curable resin on the primer portion 3 and cured by irradiation with ionizing radiation. When it is allowed to do so, it itself undergoes radical polymerization to form a photopolymerizable unsaturated bond and a covalent bond in the ionizing radiation curable resin provided thereon, and the primer portion 3 and the lenticular of the ionizing radiation curable resin are lenticular. It has the function of improving the adhesion to the lens. The functional group having a photopolymerizable unsaturated bond is not particularly limited as long as it has the above-mentioned function, but a (meth) acryloyl group is preferable from the viewpoint of the function.

The functional group having active hydrogen and / or the epoxy group introduced into the molecule of the acrylic polymer P serves as a reaction point when the functional group having a photopolymerizable unsaturated bond is introduced. At the same time, it has a function of improving the adhesion between the transparent thin plate-shaped substrate and the primer portion. When the acrylic polymer P and the cross-linking agent are used in combination, it also functions as a cross-linking point and the adhesiveness can be further improved.
Examples of the functional group having active hydrogen include a hydroxyl group, a thiol group, a carboxyl group, and an acid amide group.

The amount of the functional group having a photopolymerizable unsaturated bond to be introduced into the acrylic polymer P is preferably 0.1 to 40% by weight in view of the reaction surface at the time of introduction and the function of the primer. , More preferably 1 to 30% by weight,
More preferably, it is selected in the range of 2 to 20% by weight.
If the amount introduced is less than 0.1% by weight, it is difficult to obtain an anchor coating agent having excellent adhesion, and the object of the present invention may not be achieved. On the other hand, if it exceeds 40% by weight,
The primer causes tack and is not preferred.

The primer used in the present invention has a functional group having a photopolymerizable unsaturated bond and a functional group having an active hydrogen and / or an epoxy group in the molecule thus obtained. Although it contains the acrylic polymer P, the content of the functional group having a photopolymerizable unsaturated bond in the primer is preferably in the range of 0.01 to 40% by weight. When the content of the functional group deviates from the above range, it may be difficult to obtain a primer having a desired function, and the object of the present invention may not be achieved. The more preferable content of the functional group is in the range of 1 to 30% by weight, and particularly 5 to 20%.
A weight% range is preferred.

As the cross-linking agent optionally blended in the primer portion, for example, polyisocyanate compound, epoxy resin, melamine resin, urea resin, dialdehydes, metal salt or metal chelate compound can be used. A polyisocyanate compound is particularly preferable. Examples of polyisocyanate compounds include tolylene diisocyanate, diphenylmethane diisocyanate, aromatic polyisocyanates such as xylylene diisocyanate, aliphatic polyisocyanates such as hexamethylene diisocyanate, isophorone diisocyanate, alicyclic polyisocyanates such as hydrogenated diphenylmethane diisocyanate. Etc., and their biuret form, isocyanurate form, adduct form, and the like. This crosslinking agent may be used alone or in combination of two or more. The amount of its use depends on the kind of the cross-linking agent, but is usually in the range of 0.01 to 10 parts by weight with respect to 100 parts by weight of the acrylic polymer P.

The radical-polymerizing ionizing radiation curable resin for forming the lenticular lens 4 is a resin which is cured by radical polymerization upon irradiation with an actinic ray such as ultraviolet rays or an ionizing radiation such as an electron beam. A UV curable resin having good properties is suitable for practical use.
This radical-polymerizable ionizing radiation-curable resin generally contains a photopolymerizable prepolymer as a basic component and, if desired, further contains a photopolymerizable monomer, a photopolymerizable initiator, and other additives.

As the photopolymerizable prepolymer, for example, polyester acrylate type, epoxy acrylate type,
Examples thereof include urethane acrylate type and polyol acrylate type. Here, as the polyester acrylate prepolymer, for example, by esterifying hydroxy of a polyester oligomer having hydroxyl groups at both ends obtained by condensation of polyvalent carboxylic acid and polyhydric alcohol with (meth) acrylic acid Alternatively, it can be obtained by esterifying the terminal hydroxyl group of an oligomer obtained by adding an alkylene oxide to a polycarboxylic acid with (meth) acrylic acid. The epoxy acrylate prepolymer can be obtained, for example, by reacting (meth) acrylic acid with the oxirane ring of a bisphenol type epoxy resin or novolac type epoxy resin having a relatively low molecular weight to esterify. The urethane acrylate prepolymer can be obtained, for example, by esterifying a polyurethane oligomer obtained by reacting a polyether polyol or polyester polyol with a polyisocyanate with (meth) acrylic acid. Furthermore, the polyol acrylate prepolymer can be obtained by esterifying the hydroxyl groups of the polyether polyol with (meth) acrylic acid.
These photopolymerizable prepolymers may be used alone,
You may use it in combination of 2 or more type.

Examples of the photopolymerizable monomer optionally used include cyclohexyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, lauryl (meth) acrylate, stearyl (meth) acrylate and isobornyl (meth) acrylate. Monofunctional acrylates, 1,4-butanediol di (meth)
Acrylate, 1,6-hexanediol di (meth) acrylate, neopentyl glycol di (meth) acrylate, polyethylene glycol di (meth) acrylate, neopentyl glycol adipate di (meth) acrylate, hydroxypivalic acid neopentyl glycol di (meth) ) Acrylate, dicyclopentanyl di (meth) acrylate, caprolactone modified dicyclopentenyl di (meth) acrylate, ethylene oxide modified phosphoric acid di (meth) acrylate, allylated cyclohexyl di (meth) acrylate, isocyanurate di (meth)
Acrylate, trimethylolpropane tri (meth) acrylate, dipentaerythritol tri (meth) acrylate, propionic acid modified dipentaerythritol tri (meth) acrylate, pentaerythritol tri (meth) acrylate, propylene oxide modified trimethylolpropane tri (meth) acrylate Examples thereof include acrylate, tri (acryloxyethyl) isocyanurate, propionic acid-modified dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) acrylate, and caprolactone-modified dipentaerythritol hexa (meth) acrylate. These photopolymerizable monomers may be used alone or in combination of two or more, and the compounding amount thereof is usually 0 to 40 parts by weight, preferably 100 parts by weight of the photopolymerizable prepolymer. It is selected in the range of 5 to 20 parts by weight.

On the other hand, as the photopolymerization initiator optionally used, for example, benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzoin-n-butyl ether, benzoin isobutyl ether, acetophenone, dimethylaminoacetophenone, 2,2 -Dimethoxy-2-phenylacetophenone, 2,2-diethoxy-2-phenylacetophenone, 2-hydroxy-2-methyl-1-phenylpropan-1-one, 1-hydroxycyclohexylphenylketone, 2-methyl-1- [ 4- (Methylthio) phenyl] -2-morpholino-propane-1-
On, 4- (2-hydroxyethoxy) phenyl-2
(Hydroxy-2-propyl) ketone, benzophenone, p-phenylbenzophenone, 4,4'-diethylaminobenzophenone, dichlorobenzophenone, 2-
Methyl anthraquinone, 2-ethyl anthraquinone, 2
-Tert-butylanthraquinone, 2-aminoanthraquinone, 2-methylthioxanthone, 2-ethylthioxanthone, 2-chlorothioxanthone, 2,4-dimethylthioxanthone, 2,4-diethylthioxanthone, benzyldimethylketal, acetophenonedimethylketal, and the like. To be These may be used alone or in combination of two or more, and the compounding amount thereof is usually in the range of 0.2 to 10 parts by weight with respect to 100 parts by weight of the photopolymerizable prepolymer. To be elected.

If desired, various additives, such as a photopolymerization accelerator, may be added to the radically polymerizable ionizing radiation curable resin.
A polymerization inhibitor, a cross-linking agent, an adhesion improver, a leveling agent, a thixotropic agent, a coupling agent, a plasticizer, an antifoaming agent, a filler, a solvent, a colorant and the like can be appropriately added.

The three-dimensional or variable printed matter of the present invention has a coat layer obtained by applying the above-mentioned primer on at least one surface of the transparent thin plate-like substrate, and the thickness of the coat layer is: It is usually in the range of 0.01 to 100 micrometers. If the thickness is less than 0.01 micrometer, the function as a primer portion (layer) may not be sufficiently exhibited, and if it exceeds 100 micrometer, cohesive failure may occur and the adhesion may be deteriorated. Considering the function as a primer layer and the adhesiveness, the preferable film thickness of this coat layer is in the range of 0.1 to 10 μm, particularly 0.5 to 5 μm.

The thickness of the lenticular lens provided on the transparent thin plate-shaped substrate via the primer is usually in the range of 0.01 to 0.2 mm. If the thickness is less than 0.01, the function as a lens is insufficient, and if it is 0.2 mm or more, the flexibility of the product is impaired, a defect occurs in the manufacturing process, and the application of the product becomes narrow. The thickness of the transparent thin plate-like substrate is generally 10
~ 2,000 micrometer, preferably 10
0-1,000 micrometer, more preferably 15
It is selected in the range of 0 to 600 micrometer.

[0027]

Embodiments of the present invention will now be described in detail with reference to the drawings, but the present invention is not limited to these embodiments. The three-dimensional or variable printed matter 5 of FIG. 1 was produced in the process shown in FIG. (Adjustment of primer and coating on thin plate-shaped transparent substrate) Commercially available polyester resin "Byron 2 manufactured by Toyobo Co., Ltd."
[0SS] resin content concentration of 30% by weight, the synthesized acrylic copolymer P is blended so that the content of methacryloyl group becomes 5% by weight based on the total amount of the resin, and isocyanurate trimer as a crosslinking agent. Was added together with a solvent to prepare a primer having a resin content of 20% by weight. The above-mentioned primer was coated on both sides of a polypropylene sheet having a thickness of 300 μm (FIG. 2 (a)) whose surface was subjected to corona discharge treatment so that the thickness after drying would be 1 μm. A transparent substrate was obtained. (Figure 2 (b))

(Molding of Lenticular Lens) A lenticular lens was molded on a thin plate-shaped transparent substrate whose both surfaces were coated with a primer by a molding machine having a schematic structure shown in FIG. Reference numeral 6 is a plate cylinder having the shape of a lenticular lens, and FIG. A cylindrical cylinder having a rotation axis, on the front side of which concave portions in the shape of a lenticular lens are arranged on the circumference in the axial direction. 7
Is a transparent base material coated with a primer on both sides, 8 is a transparent base material having a lenticular lens formed thereon, 9 is an ultraviolet source, 10 is an ultraviolet curable resin tank, 11 is a nip roll, 12, 13, 14 Is a guide roll. While unwinding, the ultraviolet curable resin is supplied from the tank 10 between the transparent base material sandwiched between the plate cylinder 6 and the nip roll 11 and the plate cylinder 6, and the ultraviolet curable resin is transferred to the plate cylinder 6 and the transparent base material. While existing between the two, the ultraviolet ray was irradiated from the side opposite to the side where the resin was supplied to the transparent substrate to cure the ultraviolet ray curable resin, and the lenticular lens was molded and wound. (Fig. 2
(C)) In this example, the material is wound up, but may be cut into sheets and laminated.

(Backside pattern printing) The lenticular lens was cut to a specified size, and a three-dimensional plate-making image was subjected to four-color printing and white backside processing by using a UV curable ink in an ordinary offset sheet-fed printing machine. . (FIG. 2D) In this way, a polypropylene-based three-dimensional printed material was obtained.

[0030]

The invention according to claim 1 is a thin plate having a pattern.
Transparent thin plate with stable ink transfer to the substrate
Of contact between the base material, lenticular lens and printed pattern
Is firmly bonded and does not peel off even when bent or bent.
Become. In addition, polyester, polyamides, polystyrene
Thermoplastic resin with poor adhesion, such as resins and polyolefins
The sheet-like base material made of fat has adhesiveness and
At the time of curing, even for cal-polymerizable ionizing radiation curable resin
By reacting with each other, strong adhesiveness is obtained,
Wrench made of ionizing radiation curable resin such as UV curable
Peeling off of a curular lens or design (three-dimensional or variable print image)
Disappears.

The invention according to claim 2 provides stable adhesion.
Of excellent primer and good workability
It

The invention according to claim 3 is the acrylic resin
The polymer is mixed with ordinary resin to form a base for the primer.
Wider selection range of resin to expand selection range of thin plate base material
be able to.

The invention according to claim 4 is the one for curing with ionizing radiation.
When curing the mold resin by irradiating it with ionizing radiation,
-Itself is more preferable as a function of radical polymerization.

The invention according to claim 5 is a hydroxyl group and a thiol group.
Group, carboxyl group and amide group are
When it becomes a reaction point when introducing a functional group having a saturated bond,
In addition, it serves as a crosslinking point when the crosslinking agent is used in combination with the primer.

The invention according to claim 6 is a primer primer.
Promotes cross-linking of base polymer and increases primer cohesion.
Therefore, a stronger adhesive force can be obtained.

The invention described in claim 7 is stable and strong.
Adhesiveness and sufficient performance as a lenticular lens
Compatibility in the manufacturing process is obtained. That is, flexibi
A transparent, transparent thin substrate and lenticular
Surface and the contact surface with the printed pattern are firmly adhered, causing
You can get three-dimensional or variable prints that will not come off
It

[Brief description of drawings]

FIG. 1 is an explanatory sectional view showing an embodiment of a three-dimensional or variable printed material of the present invention.

FIG. 2 is a step (a) of the three-dimensional or variable printed matter of the present invention,
It is sectional explanatory drawing which shows (B), (C), and (D).

FIG. 3 is a front explanatory view of a plate cylinder used for molding the lenticular lens of the present invention.

FIG. 4 is an explanatory view showing an embodiment of an apparatus used for forming a lenticular lens of the present invention.

[Explanation of symbols]

DESCRIPTION OF SYMBOLS 1 ... Transparent thin plate-shaped substrate 2 ... Printed part 3 ... Transparent primer part 4 ... Lenticular lens 5 ... Three-dimensional or variable printed matter 6 ... Plate cylinder having the shape of a lenticular lens
7 ... Winding of transparent base material coated with primer on one side 8
... Winding of transparent substrate with lenticular lens formed 9
... UV source 10 ... UV curable resin tank 11 ... Nip roll 12, 13, 14 ... Guide roll

Claims (7)

(57) [Claims] 1. A transparent ply on one surface of a transparent thin substrate.
Image for at least three-dimensional or variable printing through the mer part
Having a printed portion including, on the opposite side of the transparent thin substrate.
The surface of the radical-polymerizable
Lenticular lens with ionizing radiation curable resin
The transparent primer portion is provided with a photopolymerizable
Having a functional group with a saturated bond and having active hydrogen
Acrylic polymer having functional group and / or epoxy group
A three-dimensional or variable printed matter including :. 2. The acrylic polymer is photopolymerized in the molecule.
The functional group having a polyunsaturated group in the range of 0.1 to 40% by weight
The three-dimensional or variable printed matter according to claim 1, which has. 3. The photopolymerizable unsaturated group in the primer is also included.
The amount of the functional group is 0.01 to 30 based on the total weight of the resin component.
3% or 3% according to claim 1 or claim 2 which is% by weight
Strange printed matter. 4. The functional group having the photopolymerizable unsaturated group is
And a) acryloyl group.
Three-dimensional or variable printed matter. 5. The functional group having active hydrogen is a hydroxyl group or thiol.
Selected from carboxylic, carboxylic and amide groups
It is at least 1 sort (s), Claim 1 thru / or Claim 4 any one
Three-dimensional or variable printed matter. 6. A contract in which the transparent primer portion contains a cross-linking agent.
The three-dimensional or acceptable shape according to any one of claims 1 to 5.
Strange printed matter. 7. The transparent primer portion has a thickness of 0.01.
~ 100 micrometer, lenticular
Thickness of 0.01 mm to 0.2 mm
7. Any of claims 1 to 6 characterized in that
The three-dimensional or variable printed matter according to any one of the above.