JP3011456B2 - Quality improver - Google Patents

Quality improver

Info

Publication number
JP3011456B2
JP3011456B2 JP2339938A JP33993890A JP3011456B2 JP 3011456 B2 JP3011456 B2 JP 3011456B2 JP 2339938 A JP2339938 A JP 2339938A JP 33993890 A JP33993890 A JP 33993890A JP 3011456 B2 JP3011456 B2 JP 3011456B2
Authority
JP
Japan
Prior art keywords
fatty acid
starch
acid ester
quality improver
emulsifier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2339938A
Other languages
Japanese (ja)
Other versions
JPH04207144A (en
Inventor
昌樹 藤村
宏昭 山内
智美 松下
甲三 大宅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kaneka Corp
Original Assignee
Kaneka Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kaneka Corp filed Critical Kaneka Corp
Priority to JP2339938A priority Critical patent/JP3011456B2/en
Publication of JPH04207144A publication Critical patent/JPH04207144A/en
Application granted granted Critical
Publication of JP3011456B2 publication Critical patent/JP3011456B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Confectionery (AREA)
  • Grain Derivatives (AREA)

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、パン等のデンプン質食品をソフトにし、し
かもソフトされ維持され、食感も良好であるものが得ら
れる品質改良剤に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a quality improving agent for softening starchy foods such as bread, which is softened and maintained, and which has good texture. is there.

〔従来の技術〕[Conventional technology]

近年、パンのソフト化が流行し、その流行にしたがっ
て数多くの生地改良素材が開発され、使用されている。
特にグリセリン脂肪酸モノエステルを主体とした乳化剤
を多量に用いて、ソフト化を実現するものが目立ってい
るが、最近の消費者の健康志向ブームと風味への影響に
より、従来使用されているこの種の乳化剤の回避が求め
られているのが現状である。
In recent years, softening of bread has become popular, and many dough improving materials have been developed and used in accordance with the trend.
In particular, those that use a large amount of emulsifiers mainly composed of glycerin fatty acid monoester to realize softening are conspicuous, but due to the recent boom in health-conscious consumers and the effect on flavor, this kind of conventionally used At present, it is required to avoid emulsifiers.

また、各種アミラーゼ剤を用いてパンの老化を防止、
つまり、ソフトさの維持を図っている。そもそもデンプ
ン質食品の老化は、加熱糊化によって糊化したデンプン
中の長鎖α−1,4−グルカンが冷却保存中に再結晶する
ことにより生じる現象であるが、アミラーゼはこの長鎖
α−1,4−グルカンを分解してその再結晶を妨げるの
で、これにより老化を遅延させる効果を発揮するもので
ある。これら酵素剤は前記の乳化剤とは異なり、風味に
大きな変化をもたらさない利点がある。
In addition, we prevent aging of bread using various amylase agents,
That is, the software is maintained. In the first place, aging of starchy foods is a phenomenon that occurs due to recrystallization of long chain α-1,4-glucan in starch gelatinized by heat gelatinization during cold storage, and amylase is a long-chain α- It degrades 1,4-glucan and prevents its recrystallization, thereby exerting an effect of delaying aging. These enzyme agents are different from the above-mentioned emulsifiers and have the advantage that they do not bring about a significant change in flavor.

〔発明が解決しようとする問題点〕[Problems to be solved by the invention]

しかし乍ら、従来の各種アミラーゼ類についてはデン
プンが糊化する以前の、いわゆる生デンプンの状態では
長鎖α−1,4−グルカンの分解は殆ど進行せず、加熱さ
れ糊化した状態になってからのみ作用するので多量に添
加する必要があり、コストの面で高くつく等の問題が生
ずる。
However, the degradation of long-chain α-1,4-glucan hardly progresses in the so-called raw starch state before starch gelatinization of various conventional amylases, resulting in a heated gelatinized state. Since it acts only after the addition, it needs to be added in a large amount, which causes problems such as high cost.

〔問題を解決するための手段〕[Means for solving the problem]

このような実情に鑑み、本発明者らは、生デンプン分
解活性を有する酵素としてアスペルギルス(Aspergillu
s)属又はリゾプス(Rhizopus)属由来のグルコアミラ
ーゼを用いて、生デンプンを加熱、糊化していない状態
でも直接酵素的に分解し、ごく少量の添加量で効果的に
パン等のデンプン質食品の老化が抑制できること、さら
にグリセリン脂肪酸モノエステルを主体とした乳化剤を
わずかに併用させることや、他のアミラーゼを併用させ
ることにより飛躍的に老化に防止でき、かつ食感も損な
わないことを見出し、本発明を完成するに至った。
In view of such circumstances, the present inventors have developed Aspergillus (Aspergillus) as an enzyme having raw starch degrading activity.
s) Raw starch is enzymatically decomposed directly using glucoamylase derived from the genus or Rhizopus genus, even in a non-gelatinized state, and starch-based foods such as bread can be effectively produced with a small amount of addition. Aging can be suppressed, furthermore, it is possible to dramatically prevent aging by using a small amount of an emulsifier mainly composed of glycerin fatty acid monoester, or other amylase, and find that the texture is not impaired, The present invention has been completed.

即ち、本発明は、生デンプン(デンプン粒)分解活性
を有する酵素としてアスペルギルス(Aspergillus)属
又はリゾプス(Rhizopus)属由来のグルコアミラーゼを
含有することを特徴とする品質改良剤を内容とするもの
である。
That is, the present invention includes a quality improving agent characterized by containing a glucoamylase derived from the genus Aspergillus or Rhizopus as an enzyme having a raw starch (starch granule) degrading activity. is there.

本発明の品質改良剤の形態としては特に限定されず、
例えば油脂組成物、乳化油脂組成物等の形態が挙げられ
る。
The form of the quality improving agent of the present invention is not particularly limited,
For example, the form of an oil and fat composition, an emulsified oil and fat composition and the like can be mentioned.

本発明で用いられる生デンプン分解活性を有する酵素
としては、アスペルギルス(Aspergillus)属、リゾプ
ス(Rhizopus)属由来のグルコアミラーゼである。
Examples of the enzyme having a raw starch-degrading activity used in the present invention include glucoamylases derived from the genus Aspergillus and the genus Rhizopus.

尚、生デンプン分解活性は下記に示す方法で測定され
る。
The raw starch decomposition activity is measured by the following method.

トウモロコシデンプン20mgを0.1M酢酸緩衝液(pH4.
5)0.2ml、蒸留水1.6mlに懸濁し、これに酵素液0.2mlを
加えて40℃で30分間振盪した後、上清液中の還元糖量を
グルコースを標準にしてSomogyi−Nelson法で測定す
る。
20 mg of corn starch is added to a 0.1 M acetate buffer (pH 4.
5) Suspended in 0.2 ml and 1.6 ml of distilled water, 0.2 ml of the enzyme solution was added thereto, and the mixture was shaken at 40 ° C. for 30 minutes, and the amount of reducing sugar in the supernatant was determined by the Somogyi-Nelson method using glucose as a standard. Measure.

また、デンプン粒分解活性の力価(単位)は、1分間
に1マイクロモルのグルコースに相当する還元力を有す
る還元糖を生ずる酵素量とする。
The titer (unit) of the starch granule degrading activity is the amount of an enzyme that produces a reducing sugar having a reducing power corresponding to 1 micromol of glucose per minute.

生デンプン(デンプン粒)分解活性を有する酵素の配
合量は、品質改良剤1kgに対して5000〜30000単位の範囲
が適当である。上記範囲よりも多量の場合は生地のだれ
やべたつきを生じ、逆に上記範囲よりも少量の場合は意
図した効果が得られない。
The amount of the enzyme having the activity of degrading raw starch (starch granules) is suitably in the range of 5,000 to 30,000 units per kg of the quality improving agent. If the amount is larger than the above range, the fabric will be drooling or sticky, and if the amount is smaller than the above range, the intended effect cannot be obtained.

本発明の品質改良剤は生デンプン(デンプン粒)分解
活性を有しない酵素を更に含有することもできる。ここ
でいう生デンプン分解活性を有しない酵素というのは通
常使用されているアミラーゼ類の大部分であり、具体的
には、α−アミラーゼ、Aspergillus属、麦芽、植物由
来のβ−アミラーゼ、イソアミラーゼ等が挙げられる。
生デンプン(デンプン粒)分解活性を有しないアミラー
ゼ類の配合量は、品質改良剤1kgに対して5000〜20000単
位の範囲が適当である。5000単位未満では、生デンプン
分解活性を有する酵素との併用効果が期待できず、一
方、20000単位を超えると、生地物性に影響を及ぼし、
生地のだれやべたつきを生じる。尚、生デンプン分解活
性を有しない酵素の活性力価(単位)は下記に示す方法
で測定される。
The quality improving agent of the present invention may further contain an enzyme having no activity of degrading raw starch (starch granules). Enzymes having no raw starch-degrading activity as used herein are most of commonly used amylases, specifically, α-amylase, genus Aspergillus, malt, plant-derived β-amylase, isoamylase And the like.
The amount of the amylase having no raw starch (starch granule) decomposing activity is suitably in the range of 5,000 to 20,000 units per 1 kg of the quality improving agent. If it is less than 5000 units, the combined effect with an enzyme having raw starch degrading activity cannot be expected, while if it exceeds 20,000 units, it affects the physical properties of the dough,
Causes dough and stickiness of the dough. The activity titer (unit) of the enzyme having no raw starch degrading activity is measured by the following method.

2%可溶性デンプン液0.25ml、0.1M酢酸緩衝液(pH4.
5)0.25mlを酵素液0.5mlと40℃で30分間反応させ、生じ
た還元糖量をグルコースを標準にしてSomogyi−Nelson
法で測定する。活性力価(単位)は、1分間に1マイク
ロモルのグルコースに相当する還元力を有する還元糖を
生ずる酵素量とする。
0.25 ml of 2% soluble starch solution, 0.1 M acetate buffer (pH 4.
5) 0.25 ml was reacted with 0.5 ml of the enzyme solution at 40 ° C. for 30 minutes, and the amount of reducing sugar generated was determined by using Somogyi-Nelson
It is measured by the method. The activity titer (unit) is the amount of an enzyme that produces a reducing sugar having a reducing power equivalent to 1 micromol of glucose per minute.

更に、本発明の品質改良剤は乳化剤を含有することも
できる。乳化剤としては、グリセリン脂肪酸モノエステ
ル、ポリグリセリン脂肪酸エステル、グリセリン有機酸
脂肪酸エステル、プロピレングリコール脂肪酸エステ
ル、ソルビタン脂肪酸エステル等が好ましく、これらは
1種又は2種以上組み合わせて用いられる。配合量は、
油脂組成物に対して5重量%以下であることが好まし
い。
Further, the quality improving agent of the present invention may contain an emulsifier. As the emulsifier, glycerin fatty acid monoester, polyglycerin fatty acid ester, glycerin organic acid fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester and the like are preferable, and these are used alone or in combination of two or more. The compounding amount is
The content is preferably 5% by weight or less based on the fat or oil composition.

〔実施例〕〔Example〕

次に、実施例(比較例、使用例を含む)を示し、本発
明を更に詳細に説明するが、本発明はこれらの実施例に
限定されるものではない。尚、実施例中、「部」は重量
部を示す。
Next, the present invention will be described in more detail with reference to examples (including comparative examples and usage examples), but the present invention is not limited to these examples. In the examples, "parts" indicates parts by weight.

実施例1〜5 第1表に示す配合の(乳化)油脂組成物を調製した。Examples 1 to 5 (Emulsified) fat and oil compositions having the formulations shown in Table 1 were prepared.

即ち、油脂に乳化剤を加え、加熱溶解し油相とした。
水にクエン酸ナトリウムを加え溶解後、乳化剤を加え分
散し、加熱溶解して水相とした。
That is, an emulsifier was added to fats and oils and dissolved by heating to obtain an oil phase.
After sodium citrate was added to and dissolved in water, an emulsifier was added and dispersed, and the mixture was heated and dissolved to form an aqueous phase.

70℃に保温しつつ油相に水相を徐々に加えて乳化さ
せ、常法により急冷、捏和した。得られた組成物に対
し、同表に示す酵素を少量の水に分散してスラリー化
し、これにソルビトールを混合したものを添加、混合
(後合わせ)し、本発明の品質改良剤(乳化油脂組成
物)を得た。
While maintaining the temperature at 70 ° C., the aqueous phase was gradually added to the oil phase to emulsify, and then rapidly cooled and kneaded by a conventional method. To the obtained composition, the enzymes shown in the same table were dispersed in a small amount of water to form a slurry, and a mixture of sorbitol was added to the slurry, and the mixture was mixed (post-adjusted) to obtain a quality improver (emulsified oil and fat) of the present invention. Composition).

尚、実施例1、2については、以下のように調製し
た。即ち、常温の油脂に対し、同表に示す酵素をごく少
量の水に分散してスラリー化し、これにソルビトールを
混合したものを添加、混合(後合わせ)し、本発明の品
質改良剤(油脂組成物)を得た。
In addition, about Examples 1 and 2, it prepared as follows. That is, the enzyme shown in the same table is dispersed in a very small amount of water and slurried with respect to the oil and fat at room temperature, and a mixture of sorbitol is added thereto and mixed (post-adjusted) to obtain a quality improving agent (oil and fat) of the present invention. Composition).

比較例1、2 比較例1は第1表に示すように油脂をそのまま用い
た。
Comparative Examples 1 and 2 In Comparative Example 1, as shown in Table 1, fats and oils were used as they were.

比較例2は以下のように調製した。 Comparative Example 2 was prepared as follows.

即ち、油脂に乳化剤を加え、加熱溶解し、油相とし
た。
That is, an emulsifier was added to the oil and the mixture was heated and dissolved to obtain an oil phase.

70℃に保温しつつ、油相に水を徐々に加え、乳化さ
せ、常法により急冷、捏和し、乳化油脂組成物を得た。
While keeping the temperature at 70 ° C., water was gradually added to the oil phase to emulsify, quenched and kneaded by an ordinary method to obtain an emulsified oil / fat composition.

使用例 上記実施例1〜5及び比較例1、2で得られた油脂組
成物を用い、第2表に示す配合に基づき70%中種法で食
パンを製造し、パンの評価を行った。
Use Example Using the oil-and-fat compositions obtained in Examples 1 to 5 and Comparative Examples 1 and 2, bread was produced by a 70% sponge method based on the composition shown in Table 2 and the bread was evaluated.

このパンの製造工程は次の通りである。 The manufacturing process of this bread is as follows.

焼成後、パンを20℃で1時間冷却した後、ビニール袋
に入れて密閉し、更に20℃で24時間及び72時間保存し食
パンサンプルとした。
After baking, the bread was cooled at 20 ° C. for 1 hour, then put in a plastic bag and sealed, and further stored at 20 ° C. for 24 hours and 72 hours to obtain a bread sample.

この食パンサンプルについて、官能評価をし、パンの
硬さを測定した。但し、官能評価は24時間保存のサンプ
ルについてのみ行った。尚、パンの硬さの測定は、パン
を2cmの厚さにスライスし、1cmまで圧縮した時の応力を
レオナー〔山電(株)製〕を用いて測定した。得られた
食パンサンプルの評価結果を第3表に示す。
The bread sample was subjected to a sensory evaluation and the bread hardness was measured. However, the sensory evaluation was performed only for the sample stored for 24 hours. The bread hardness was measured by slicing the bread to a thickness of 2 cm and compressing the bread to 1 cm using a Leoner (manufactured by Yamaden Corporation). Table 3 shows the evaluation results of the obtained bread samples.

官能評価: ◎:キメが細かく、マクうすく、非常にソフトで食感
も良い。
Sensory evaluation: :: Fine texture, thin, very soft, good texture.

○:キメが細かく、マクうすく、ソフトで食感も良
い。
:: Fine texture, thin and soft, good texture.

△:キメがやや細かく、マクもややうすい。ソフトさ
はあまりなく、食感もやや悪い。
Δ: The texture is slightly fine, and the Mc is slightly light. There is not much softness and texture is slightly bad.

×:キメはあらく、マクも厚い。ソフトさはなく、食
感悪い。
×: The texture is rough and the mac is thick. No softness and bad texture.

第3表からわかるように本発明の品質改良剤を用いる
ことにより、ソフトでかつソフトさが維持され、食感が
良い等の効果を示す。
As can be seen from Table 3, by using the quality improving agent of the present invention, softness and softness are maintained, and effects such as good texture are exhibited.

〔発明の効果〕〔The invention's effect〕

叙上の通り、本発明の品質改良剤は、パン、菓子、麺
等のデンン質食品をソフトにし、しかもソフトさが維持
され、食感も良い等の効果を奏する。
As described above, the quality improving agent of the present invention has effects such as softening dentic foods such as bread, confectionery, and noodles, maintaining the softness, and improving the texture.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI A23L 1/16 A23L 1/16 (56)参考文献 特開 昭62−79745(JP,A) (58)調査した分野(Int.Cl.7,DB名) A21D 2/00 A21D 8/00 A23L 1/00 A23G 3/00 ──────────────────────────────────────────────────続 き Continued on front page (51) Int.Cl. 7 Identification code FI A23L 1/16 A23L 1/16 (56) References JP-A-62-79745 (JP, A) (58) Fields investigated (Int. .Cl. 7 , DB name) A21D 2/00 A21D 8/00 A23L 1/00 A23G 3/00

Claims (5)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】生デンプン(デンプン粒)分解活性を有す
る酵素としてアスペルギルス(Aspergillus)属又はリ
ゾプス(Rhizopus)属由来のグルコアミラーゼを含有す
ることを特徴とする品質改良剤。
1. A quality improving agent characterized by containing a glucoamylase derived from the genus Aspergillus or Rhizopus as an enzyme having an activity of degrading raw starch (starch granules).
【請求項2】更に生デンプン(デンプン粒)分解活性を
有しないアミラーゼ類を含有してなる請求項1記載の品
質改良剤。
2. The quality improver according to claim 1, further comprising an amylase having no activity of degrading raw starch (starch granules).
【請求項3】更に乳化剤を含有してなる請求項1又は2
記載の品質改良剤。
3. The method according to claim 1, further comprising an emulsifier.
A quality improver as described.
【請求項4】乳化剤がグリセリン脂肪酸モノエステル、
ポリグリセリン脂肪酸エステル、グリセリン有機酸脂肪
酸エステル、プロピレングリコール脂肪酸エステル、ソ
ルビタン脂肪酸エステルから選ばれた1種又は2種以上
の化合物である請求項3記載の品質改良剤。
4. An emulsifier comprising glycerin fatty acid monoester,
The quality improver according to claim 3, which is one or more compounds selected from polyglycerin fatty acid ester, glycerin organic acid fatty acid ester, propylene glycol fatty acid ester, and sorbitan fatty acid ester.
【請求項5】乳化剤の添加量が油脂組成物に対して5重
量%以下である請求項3又は4記載の品質改良剤。
5. The quality improver according to claim 3, wherein the amount of the emulsifier added is 5% by weight or less based on the fat or oil composition.
JP2339938A 1990-11-30 1990-11-30 Quality improver Expired - Lifetime JP3011456B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2339938A JP3011456B2 (en) 1990-11-30 1990-11-30 Quality improver

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2339938A JP3011456B2 (en) 1990-11-30 1990-11-30 Quality improver

Publications (2)

Publication Number Publication Date
JPH04207144A JPH04207144A (en) 1992-07-29
JP3011456B2 true JP3011456B2 (en) 2000-02-21

Family

ID=18332181

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2339938A Expired - Lifetime JP3011456B2 (en) 1990-11-30 1990-11-30 Quality improver

Country Status (1)

Country Link
JP (1) JP3011456B2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69830119T2 (en) * 1997-10-31 2006-02-23 Amano Enzyme Inc., Nagoya Dough composition and its preparation
JP4289833B2 (en) * 2002-06-03 2009-07-01 株式会社Adeka Rice flour dough baked food, rice flour dough and mixed flour therefor
JP2008187946A (en) * 2007-02-02 2008-08-21 Kyokomachi:Kk Wet rice confectionery and method for producing the same
DK2579727T3 (en) * 2010-06-11 2018-11-26 Novozymes As Enzymatic milk correction
JP5729723B2 (en) * 2011-09-30 2015-06-03 日清オイリオグループ株式会社 Pastry dough and pastry food
JP6080151B2 (en) * 2012-06-21 2017-02-15 株式会社Adeka Dough
EP3166412B1 (en) * 2014-07-08 2022-04-20 Caravan Ingredients Inc. Sugar-producing and texture-improving bakery methods and products formed therefrom
JP6735868B2 (en) * 2014-07-08 2020-08-05 キャラヴァン イングリーディエンツ インク. Bakery process for producing sugar and improving texture and products formed therefrom

Also Published As

Publication number Publication date
JPH04207144A (en) 1992-07-29

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