JP2942428B2 - Detergent composition - Google Patents

Detergent composition

Info

Publication number
JP2942428B2
JP2942428B2 JP4354223A JP35422392A JP2942428B2 JP 2942428 B2 JP2942428 B2 JP 2942428B2 JP 4354223 A JP4354223 A JP 4354223A JP 35422392 A JP35422392 A JP 35422392A JP 2942428 B2 JP2942428 B2 JP 2942428B2
Authority
JP
Japan
Prior art keywords
skin
cleaning
feeling
present
detergent composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP4354223A
Other languages
Japanese (ja)
Other versions
JPH06179892A (en
Inventor
清子 田中
憲一 杉本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanebo Ltd
Original Assignee
Kanebo Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanebo Ltd filed Critical Kanebo Ltd
Priority to JP4354223A priority Critical patent/JP2942428B2/en
Publication of JPH06179892A publication Critical patent/JPH06179892A/en
Application granted granted Critical
Publication of JP2942428B2 publication Critical patent/JP2942428B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic or non-ionic compounds

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、洗浄剤組成物に関し、
更に詳しくは、特定の球状多孔質シリカを含有し、物理
的(機械的)な洗浄力に優れ、皮膚に対して刺激,損傷
がなく、かつ洗浄後のぬるつきが少なく、さっぱりとし
た洗い上がりを与える使用感に優た洗浄剤組成物に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a detergent composition,
More specifically, it contains a specific spherical porous silica, has excellent physical (mechanical) detergency, has no irritation or damage to the skin, and has less sliminess after washing, and has a refreshing finish. The present invention relates to a detergent composition which is excellent in a feeling of use that gives

【0002】[0002]

【従来の技術】近年、消費者の清潔に対する意識は年々
向上し、清潔は生活上の基本であり、特に洗浄料におい
ては様々な機能や効果が求められている。ボディ洗浄剤
や洗顔料等の洗浄剤に求められる機能を挙げると、ま
ず、洗浄剤としての基本機能である、塵埃や微生物(細
菌)等による外因性の汚れ、皮脂、汗、老廃角質等によ
る内因性の汚れを洗浄除去する機能である。次に、皮膚
は生態のひとつの器官として様々な生理作用を営んでい
るという観点から、皮膚の生理機能を阻害しない、、皮
膚を損傷させないことが求められる。更に、洗浄後の使
用感も重要な機能であり、近年、特に洗浄後において皮
膚のぬるつきがなく、さっぱりとした仕上がり感が強く
求められている。
2. Description of the Related Art In recent years, consumers' awareness of cleanliness has been improving year by year, and cleanliness is a fundamental aspect of daily life. In particular, various functions and effects are required for cleaning materials. The functions required for detergents such as body detergents and facial cleansers are as follows: First, the basic functions of detergents include extrinsic stains such as dust and microorganisms (germs), sebum, sweat, and dead skin cells. It is a function to wash and remove intrinsic dirt. Next, from the viewpoint that the skin performs various physiological actions as one organ of ecology, it is required that the skin does not inhibit the physiological function and does not damage the skin. Furthermore, the feeling of use after washing is also an important function, and in recent years, there has been a strong demand for a refreshing finish with no slimy skin, especially after washing.

【0003】この様な、機能、使用感を改良することを
目的として、洗浄剤においては、スクラブ剤や粘土鉱
物、高分子化合物などを配合した洗浄剤が提案されてい
る。例えば、粒径100〜1000μmの真珠質及び
/または真珠屑を2.5〜20重量%含むスクラブ皮膚
洗浄料(特開昭56−13152号公報)。粘土鉱物
としてモンモリロナイトを配合した洗浄料(特開平1−
190622号公報)。平均粒径が100〜1000
μmで、特定の弾性率をもつ高分子粒子を含む洗浄剤組
成物(特開平2−151693号公報)が開示されてい
る。
[0003] For the purpose of improving such functions and feeling of use, there has been proposed a detergent containing a scrubbing agent, a clay mineral, a polymer compound and the like. For example, a scrub skin cleanser containing 2.5 to 20% by weight of pearl and / or nacre having a particle size of 100 to 1000 μm (JP-A-56-13152). Cleaning agent containing montmorillonite as clay mineral
190622). Average particle size is 100 to 1000
A detergent composition containing polymer particles having a specific elastic modulus of μm (JP-A-2-151693) is disclosed.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、上記の
の洗浄料は粒子が大きく不定形であり、かつ硬質であ
るために皮膚表面を傷める危険性があり皮膚洗浄料とし
ては充分でない。の洗浄料は高級脂肪酸石けん等への
洗浄料へ応用した場合、モンモリロナイトの沈殿が生
じ、また、べたつきがあり使用感も十分ではない。ま
た、の洗浄剤組成物は洗浄効果に優れているもののさ
っぱりとした洗い上がり等の使用感においては効果が不
十分であり、充分満足すべきものには至っていない。
However, the above-mentioned cleansing agent is not sufficient as a skin cleansing agent because the particles are large and irregular in shape and hard, so that the skin surface may be damaged. When the detergent is applied to detergents such as higher fatty acid soaps, precipitation of montmorillonite occurs, and the stickiness is not sufficient and the feeling of use is not sufficient. Further, although the detergent composition is excellent in the cleaning effect, the effect is not sufficient in the usability such as refreshing after washing, and thus the composition is not sufficiently satisfactory.

【0005】この様に、従来の技術では、洗浄性、低刺
激性、使用感(ぬめりがなく、さっぱりとした洗い上が
り)は相容れないものであり、そのいずれかの目的を達
成させるためには、他方の効果を犠牲にしなけれはなら
ないという問題があり、その解決が強く望まれていた。
[0005] As described above, the conventional techniques are incompatible with detergency, hypoallergenicity, and feeling of use (there is no slimming and refreshing washing), and in order to achieve any of the objects, There is a problem that the other effect must be sacrificed, and a solution to this problem has been strongly desired.

【0006】[0006]

【課題を解決するための手段】かかる実情に鑑み、本発
明者等は、前記従来技術の問題点や欠点を改良した洗浄
剤組成物を開発すべく鋭意研究した結果、特定の粒径及
び細孔容積を有する球状多孔質シリカを洗浄剤に配合す
ることにより、高い洗浄効果を有し、皮膚に対して刺
激,損傷を与えることなく、かつ使用感(洗浄後のぬる
つきが少なく、さっぱりとした洗い上がり)に優れた洗
浄剤が得られることを見出し本発明を完成した。
In view of such circumstances, the present inventors have conducted intensive studies to develop a cleaning composition which has improved the problems and disadvantages of the prior art, and as a result, have found that a specific particle size and fineness have been obtained. By incorporating spherical porous silica with a pore volume into the detergent, it has a high cleaning effect, does not cause irritation or damage to the skin, and has a feeling of use (less slimy after cleaning, The present inventors have found that an excellent cleaning agent can be obtained, and completed the present invention.

【0007】すなわち、本発明は、平均粒径が0.1〜
100μmであり、且つ細孔容積が0.5ml/g以上
である球状多孔質シリカを含有することを特徴とする洗
浄剤組成物を提供するものである。
That is, according to the present invention, the average particle size is 0.1 to
It is intended to provide a cleaning composition characterized by containing spherical porous silica having a diameter of 100 μm and a pore volume of 0.5 ml / g or more.

【0008】以下、本発明について詳細に説明する。本
発明で配合される球状多孔質シリカは、化学組成的に、
二酸化ケイ素(SiO2 )であり、白色無臭、化学的に
安定な化合物である。その形状としては球形または真球
状であり、また、球状多孔質シリカの中心部が中空の状
態となっている中空多孔質の球状シリカも本球状多孔質
シリカに含まれる。
Hereinafter, the present invention will be described in detail. The spherical porous silica compounded in the present invention is chemically
Silicon dioxide (SiO 2 ), a white, odorless, chemically stable compound. The spherical porous silica has a spherical shape or a true spherical shape, and a hollow porous spherical silica in which the center of the spherical porous silica is hollow is also included in the present spherical porous silica.

【0009】球状多孔質シリカの平均粒径は0.1〜1
00μmの粒子であり、好ましくは、1〜20μmであ
る。0.1μm未満であると充分な使用感が得られず、
100μmを越えると違和感、皮膚への損傷等が発現し
好ましくない。また、球状多孔質シリカの細孔容積は、
0.5ml/g以上であり、好ましくは、1.0ml/
g以上である。0.5ml/gより小さいと、球状多孔
質シリカの比重が増加し、洗浄剤組成物中で分離、沈殿
等が生じ好ましくない。
The average particle size of the spherical porous silica is 0.1-1.
The particle size is 00 μm, preferably 1 to 20 μm. If it is less than 0.1 μm, a sufficient feeling of use cannot be obtained,
If the thickness exceeds 100 μm, uncomfortable feeling, damage to the skin, etc. appear, which is not preferable. The pore volume of the spherical porous silica is
0.5 ml / g or more, preferably 1.0 ml / g
g or more. If it is less than 0.5 ml / g, the specific gravity of the spherical porous silica increases, and separation, sedimentation and the like are undesirably caused in the detergent composition.

【0010】本発明に用いる球状多孔質シリカの配合量
は、実際の適用剤形に応じて適宜選択できるが、当該洗
浄剤組成物における処方成分の全量重量(組成物の重
量)を基準として0.01〜10重量%、好ましくは
0.1〜5重量%である。0.01重量%より少ないと
その所望の効果が発揮されにくく、また、処方系中にお
ける安定性や使用感を考慮すると、10重量%以下が好
ましい。
The amount of the spherical porous silica to be used in the present invention can be appropriately selected according to the actual dosage form. However, the amount of the spherical porous silica may be 0 based on the total weight of the components (the weight of the composition) in the detergent composition. 0.01 to 10% by weight, preferably 0.1 to 5% by weight. If the amount is less than 0.01% by weight, the desired effect is hardly exerted, and considering the stability and feeling in use in the formulation, the amount is preferably 10% by weight or less.

【0011】本発明に用いる球状他孔質シリカは、通常
市販されている公知のものを使用することができ、その
例を挙げれば、商品名 シルデックスH−31,H−3
2,H−51,H−52,H−121,H−122,L
−31,L−51,L−121(旭硝子(株)社製)、
商品名 ゴッドボールB−6C,A−11C,B16
C,B−25C,E−60C,D−11C,E−16
C,E2−C(鈴木油脂(株)社製)等があげられる
が、これらに限定されるものではない。
As the spherical other porous silica used in the present invention, known ones which are generally commercially available can be used, and examples thereof include trade names Sildex H-31 and H-3.
2, H-51, H-52, H-121, H-122, L
-31, L-51, L-121 (manufactured by Asahi Glass Co., Ltd.),
Product name Godball B-6C, A-11C, B16
C, B-25C, E-60C, D-11C, E-16
C, E2-C (manufactured by Suzuki Yushi Co., Ltd.) and the like, but are not limited thereto.

【0012】本発明の洗浄剤組成物に用いる主界面活性
剤は特に限定されないが、例えば、脂肪酸石鹸、カルボ
ン酸型活性剤、アルキル硫酸エステル型活性剤、スルホ
サクシネート型活性剤、タウレート系、アシルサルコシ
ン系、アシル−β−アラニン系等のアシル化アミノ酸型
活性剤、燐酸エステル型活性剤等のアニオン活性剤、ア
ルキルサッカライド類、EO付加型界面活性剤等の非イ
オン界面活性剤等があげられる。その中でも、脂肪酸石
鹸、カルボン酸型活性剤、アシル化アミノ酸型活性剤等
が使用後にぬるつきが少なく、皮膚刺激が少なく好まし
い。
The main surfactant used in the detergent composition of the present invention is not particularly limited. Examples thereof include fatty acid soap, carboxylic acid type activator, alkyl sulfate ester type activator, sulfosuccinate type activator, taurate type, Examples include acylated amino acid surfactants such as acyl sarcosine and acyl-β-alanine surfactants, anionic surfactants such as phosphate ester surfactants, and nonionic surfactants such as alkyl saccharides and EO addition surfactants. Can be Among them, fatty acid soaps, carboxylic acid-type activators, acylated amino acid-type activators, etc. are preferable since they do not get wet after use and cause less skin irritation.

【0013】主界面活性剤の配合量は特に限定されない
が、洗浄料が固形状のとき60〜90%、ペースト状の
とき30〜70%、ゲル状のとき20〜70%、液状の
とき10〜60%配合することが好ましい。
The amount of the main surfactant is not particularly limited, but is 60 to 90% when the detergent is solid, 30 to 70% when it is paste, 20 to 70% when it is gel, and 10 to 70% when it is liquid. It is preferable to mix it by 60%.

【0014】更に、主界面活性剤の他に起泡性向上性や
適度な粘稠性を持たせるためにアミンオキサイド、イミ
ダゾリン型又はベタイン型の両性活性剤を用いることも
好ましい。
Further, in addition to the main surfactant, it is preferable to use an amine oxide, imidazoline-type or betaine-type amphoteric surfactant in order to improve the foaming property and provide an appropriate viscosity.

【0015】また、本発明の洗浄剤組成物は、脂肪酸グ
リコールジエステル等のパール光沢剤、ヒドロキシエチ
ルセルロース等の増粘剤と併用することにより球状多孔
質シリカの分離や凝集を防止しすることができ、長期の
経日安定性を向上させることが可能となる。
The detergent composition of the present invention can prevent the separation and aggregation of spherical porous silica by using in combination with a pearlescent agent such as fatty acid glycol diester and a thickener such as hydroxyethyl cellulose. Thus, long-term stability over time can be improved.

【0016】上記成分の他、洗浄剤に通常用いられる成
分、例えば、湿潤剤、着色料、防腐剤、感触向上剤、香
料、殺菌剤、消炎剤、紫外線吸収剤等を、本発明の効果
を損なわない範囲で用いることができる。
In addition to the above components, components commonly used in detergents, such as wetting agents, coloring agents, preservatives, feel improvers, fragrances, bactericides, anti-inflammatory agents, ultraviolet absorbers, etc., are used to effect the present invention. It can be used within a range that does not impair.

【0017】本発明の洗浄剤組成物は、例えば、全身洗
浄料、固形石鹸、洗顔料等の皮膚洗浄料、食器用洗浄
料、コンタクトレンズ用洗浄料等に幅広く用いることが
できる。
The detergent composition of the present invention can be widely used as, for example, a whole body cleanser, a skin cleanser such as a solid soap and a face wash, a dish cleanser, a contact lens cleanser and the like.

【0018】[0018]

【実施例】次に、実施例を挙げて本発明を詳細に説明す
るが、本発明はこれに限定されるものではない。尚、配
合量は、重量%である。実施例に先立ち、評価方法につ
いて述べる。
Next, the present invention will be described in detail with reference to examples, but the present invention is not limited to these examples. In addition, the compounding amount is weight%. Prior to the examples, an evaluation method will be described.

【0019】(1)洗浄効果の測定 左前腕部の測定部位に、2%カーボンブラックを含む人
工皮脂を塗布し、一定時間乾燥させた後、上部汚れを拭
い、皮溝内に汚れが残るようにした。次に色彩色差計
(ミノルタ社製)を用いて人工皮脂塗布部位の明度(L
2 )を測定し、同時に未塗布部位の明度(L1 )も測定
する。次に、それぞれの洗浄剤で洗浄処理を施した。洗
浄処理後、左前腕部を乾燥させ、再び処理部位の明度
(L3 )を測定する。これらによって得られた明度値よ
り下記の式に入れて洗浄率を求めた。
(1) Measurement of cleaning effect An artificial sebum containing 2% carbon black was applied to the measurement site on the left forearm, dried for a certain period of time, and then the upper dirt was wiped off so that dirt remained in the skin groove. I made it. Next, using a color difference meter (manufactured by Minolta), the lightness (L
2 ) is measured, and at the same time, the brightness (L 1 ) of the uncoated portion is measured. Next, a cleaning treatment was performed with each cleaning agent. After the washing treatment, the left forearm is dried, and the lightness (L 3 ) of the treated part is measured again. The cleaning rate was calculated from the lightness values obtained in these manners according to the following equation.

【0020】洗浄率(%)=100×(L2 −L3 )/
(L2 −L1
Cleaning rate (%) = 100 × (L 2 −L 3 ) /
(L 2 -L 1)

【0021】(2)皮膚に対する刺激、損傷性の測定 官能パネラー10名について、左下腕部の特定部に対し
て、1.0gのそれぞれの洗浄剤を含んだ少湿スポンジ
にて正確に60秒間洗浄する。次いで洗浄部を乾燥し、
この洗浄処理を1日3回、計15回行った後、各試験部
位を熟練鑑定者により肉眼観察を行い表1の基準によっ
て評価し、官能パネラー10名の結果の得点の平均値を
算出して評価した。
(2) Measurement of irritation and damage to the skin For 10 sensory panelists, a specific portion of the lower left arm was accurately measured for 60 seconds with a low-moisture sponge containing 1.0 g of each cleaning agent. Wash. Next, the washing unit is dried,
After performing this washing treatment three times a day, a total of 15 times, each test site was visually observed by a skilled examiner and evaluated according to the criteria in Table 1, and the average value of the scores of the results of 10 sensory panelists was calculated. Was evaluated.

【0022】[0022]

【表1】 [Table 1]

【0023】(3)使用感の評価 専門美容技術者20名にそれぞれの洗浄剤を使用させ、
洗浄後の皮膚のぬるつきとさっぱり感について表2の基
準によって5点評価で判定させ、平均値を算出して、そ
の平均値を表3の基準により、○、△、×の記号で示し
た。
(3) Evaluation of feeling of use Twenty professional beauty technicians were allowed to use each cleaning agent.
The sliminess and freshness of the skin after washing were evaluated by a five-point evaluation according to the criteria in Table 2, and the average value was calculated. The average value was indicated by the symbols ○, Δ, and × according to the criteria in Table 3. .

【0024】[0024]

【表2】 [Table 2]

【0025】[0025]

【表3】 [Table 3]

【0026】実施例1−3,比較例1−3 表4に常法により調製したボディーシャンプーの処方と
評価結果を示す。表4から明らかなように本発明の実施
例1−3は比較例1−3に比較して、洗浄効果、皮膚刺
激性、使用感(ぬるつき、さっぱり感)の点において優
れていた。
Example 1-3, Comparative Example 1-3 Table 4 shows the formulation and evaluation results of the body shampoo prepared by a conventional method. As is evident from Table 4, Example 1-3 of the present invention was superior to Comparative Example 1-3 in terms of cleaning effect, skin irritation, and feeling of use (sliminess and refreshing feeling).

【0027】[0027]

【表4】 [Table 4]

【0028】実施例4 常法により、以下の組成の石鹸を製造した。 Example 4 A soap having the following composition was produced by a conventional method.

【0029】実施例5 常法により、以下の組成の洗顔フォームを製造した。 Example 5 A facial cleansing foam having the following composition was produced by a conventional method.

【0030】実施例8 常法により、以下の組成のシャワー時に使用する液状ソ
ープを製造した。
Example 8 A liquid soap to be used at the time of shower having the following composition was produced by a conventional method.

【0031】実施例7 常法により、以下の組成のボディシャンプーを製造し
た。
Example 7 A body shampoo having the following composition was produced by a conventional method.

【0032】実施例4〜7の洗浄剤はいずれも洗浄効
果、皮膚刺激性、使用感(ぬるつき、さっぱり感)の点
において良好であった。
All of the cleaning agents of Examples 4 to 7 were good in terms of cleaning effect, skin irritation, and feeling of use (sliminess, refreshing feeling).

【0033】[0033]

【発明の効果】本発明の洗浄剤組成物は、物理的な洗浄
効果に優れ、皮膚表面に対して刺激,損傷を与えること
なく、かつ使用感(皮膚のぬるつきが少なく、さっぱり
とした洗い上がり)に優れた洗浄剤組成物を提供するも
のである。
The cleaning composition of the present invention is excellent in physical cleaning effect, does not cause irritation or damage to the skin surface, and has a feeling of use (lessly slimy to the skin, refreshing washing). The present invention provides a cleaning composition which is excellent in rising.

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.6,DB名) C11D 3/12 - 3/14 C11D 7/20 A61K 7/50 WPI/L(QUESTEL)────────────────────────────────────────────────── ─── Continued on the front page (58) Fields surveyed (Int. Cl. 6 , DB name) C11D 3/12-3/14 C11D 7/20 A61K 7/50 WPI / L (QUESTEL)

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 平均粒径が0.1〜100μmであり、
且つ細孔容積が0.5ml/g以上である球状多孔質シ
リカを含有することを特徴とする洗浄剤組成物。
An average particle diameter is 0.1 to 100 μm,
A detergent composition comprising spherical porous silica having a pore volume of 0.5 ml / g or more.
JP4354223A 1992-12-14 1992-12-14 Detergent composition Expired - Lifetime JP2942428B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4354223A JP2942428B2 (en) 1992-12-14 1992-12-14 Detergent composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4354223A JP2942428B2 (en) 1992-12-14 1992-12-14 Detergent composition

Publications (2)

Publication Number Publication Date
JPH06179892A JPH06179892A (en) 1994-06-28
JP2942428B2 true JP2942428B2 (en) 1999-08-30

Family

ID=18436110

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4354223A Expired - Lifetime JP2942428B2 (en) 1992-12-14 1992-12-14 Detergent composition

Country Status (1)

Country Link
JP (1) JP2942428B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005034862A3 (en) * 2003-10-03 2007-03-22 Procter & Gamble Topical composition

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2170851T3 (en) * 1995-03-14 2002-08-16 Procter & Gamble SILICE AMORFA DISPERSES AS A WATER OIL STABILIZER FOR COMPOSITION CLEANSING LIQUID FOR SKIN.
JPWO2004069210A1 (en) * 2003-02-05 2006-05-25 三好化成株式会社 Skin cosmetics
JP4798969B2 (en) * 2003-06-27 2011-10-19 ライオン株式会社 Cleaning composition
PL1750662T3 (en) 2004-05-07 2017-09-29 Deb Ip Limited Foamed cleanser with suspended particles, a method of producing same, and a dispenser therefore
WO2011111828A1 (en) * 2010-03-11 2011-09-15 ライオン株式会社 Cosmetic composition
JP5919156B2 (en) * 2012-09-27 2016-05-18 株式会社マンダム Skin cleanser composition and skin cleanser
EP3777826A4 (en) 2018-03-27 2022-01-19 Sumitomo Seika Chemicals Co., Ltd. Water-absorbing exfoliator, method for producing same, and cosmetic
US20220025307A1 (en) * 2018-12-28 2022-01-27 Kao Corporation Wiping detergent composition for textile products
JP7348332B2 (en) * 2022-02-21 2023-09-20 牛乳石鹸共進社株式会社 Solid cleaning composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005034862A3 (en) * 2003-10-03 2007-03-22 Procter & Gamble Topical composition

Also Published As

Publication number Publication date
JPH06179892A (en) 1994-06-28

Similar Documents

Publication Publication Date Title
JP4142272B2 (en) Cleansing cosmetic composition
JP2942428B2 (en) Detergent composition
EP1051964B1 (en) Gommage cosmetic composition
JP5700770B2 (en) Skin cleanser composition
JP2006083140A (en) Skin-cleansing agent composition
JP3265772B2 (en) Detergent composition
JPH01287017A (en) Low-irritant washing agent composition
JP2588870B2 (en) Detergent composition
JPH01502023A (en) soap-based cosmetics
JP2005336068A (en) Skin detergent composition
JP2834381B2 (en) Detergent composition
JP2001115191A (en) Detergent
JPH06305951A (en) Detergent composition
JP2558094B2 (en) Hypoallergenic detergent composition
JP2002212060A (en) Detergent composition
JP3114361B2 (en) Detergent composition
JP3114370B2 (en) Detergent composition
JP4550234B2 (en) Skin cleanser composition
JP2001247448A (en) Detergent composition for skin
JP3464030B2 (en) Skin cleanser
JPH0867622A (en) Skin cleaning agent
JP3130373B2 (en) Detergent composition
JPH07126124A (en) Skin-cleansing agent
JP3486445B2 (en) Makeup cleaning fee
JPH06116133A (en) Skin detergent composition

Legal Events

Date Code Title Description
S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

R371 Transfer withdrawn

Free format text: JAPANESE INTERMEDIATE CODE: R371

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080618

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090618

Year of fee payment: 10

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090618

Year of fee payment: 10

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100618

Year of fee payment: 11

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100618

Year of fee payment: 11

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110618

Year of fee payment: 12

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110618

Year of fee payment: 12

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120618

Year of fee payment: 13

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120618

Year of fee payment: 13

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130618

Year of fee payment: 14

EXPY Cancellation because of completion of term
FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130618

Year of fee payment: 14