JP2716904B2 - Liquid detergent composition for hard surfaces - Google Patents

Liquid detergent composition for hard surfaces

Info

Publication number
JP2716904B2
JP2716904B2 JP4044518A JP4451892A JP2716904B2 JP 2716904 B2 JP2716904 B2 JP 2716904B2 JP 4044518 A JP4044518 A JP 4044518A JP 4451892 A JP4451892 A JP 4451892A JP 2716904 B2 JP2716904 B2 JP 2716904B2
Authority
JP
Japan
Prior art keywords
hard
detergent composition
cleaning composition
composition
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP4044518A
Other languages
Japanese (ja)
Other versions
JPH05239492A (en
Inventor
将万 久保田
卓巳 井上
一訓 佃
正樹 妻鳥
Original Assignee
花王株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 花王株式会社 filed Critical 花王株式会社
Priority to JP4044518A priority Critical patent/JP2716904B2/en
Publication of JPH05239492A publication Critical patent/JPH05239492A/en
Application granted granted Critical
Publication of JP2716904B2 publication Critical patent/JP2716904B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials characterised by their shape or physical properties
    • C11D17/0008Detergent materials characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0026Structured liquid compositions, e.g. liquid crystalline phases, network containing non-Newtonian phase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hard surface cleaning composition having good finish.

[0002]

2. Description of the Related Art In general, when the time required for cleaning a solid surface from contamination to cleaning is long, the adherence to a substrate surface becomes strong, so that cleaning becomes difficult. For example,
Dirt attached to a ventilation fan, a wall around a kitchen, glass, a refrigerator, etc., is oxidized and becomes sticky deteriorated oil when left for a long time. In addition to the area around the kitchen, there are oily stains such as stains and stains that are difficult to wash over the entire house.

[0003] As a detergent for removing such oily stains, for example, as a liquid detergent composition for housing which does not require rinsing, JP-A-2-29498 discloses an anionic surfactant, a terpene solvent and a water-soluble divalent metal. JP-A-3-41200 discloses a liquid detergent composition containing a salt, a hard surface cleaning composition containing an anionic surfactant ammonium salt, ethanolamine and a solvent, and JP-A-3-199297 discloses a A hard surface cleaning composition containing an anionic surfactant ammonium salt, ethanol, n-butoxypropanol, and 2-pentanol and no ethanolamine is disclosed. However, while these compositions have been significantly improved with respect to the retention of wiping streaks, there is a need for further improvements in practice.

[0004]

Means for Solving the Problems In order to solve such a problem, the present inventors diligently studied the relationship between the finish on a hard surface and the state of solids in the cleaning composition remaining on the surface. As a result, it has been found that the finish is different depending on the state of association of a nonvolatile component such as a surfactant on the hard surface, and the present invention has been completed.

That is, the present invention provides (a) at least one molecule in one molecule;
Also have one long-chain branched alkyl or alkenyl group and
Nonionic surfactants having at least three hydroxyl groups
The following general formula (I) R 1 (OR 2 ) x G y (I) wherein R 1 is a linear or branched alkyl having 8 to 18 carbon atoms.
The group or an alkyl phenylene Le group, R 2 is C2-4 Al
G is derived from a reducing sugar having 5 to 6 carbon atoms
Indicates a residue. x has an average value of 0 to 5, and y has
Is 1 to 5, preferably 1.1 to 3. Surface active agent selected from the alkyl glycosides represented by], (b) a volatile or liquid amine compound and (c) a hard surface liquid detergent composition containing water, the water of the detergent composition And when the other volatile components evaporate and the water content in the cleaning composition becomes 10% by weight or less, most or all of the cleaning composition is hexagonal type or lamellar type liquid crystal or An object of the present invention is to provide a hard surface cleaning composition characterized by being a gel.

In the present invention, when the water content in the hard surface cleaning composition is 10% by weight or less,
Observed by the following test method. Put 50g of detergent solution (or its aqueous solution) in a 2cm radius petri dish, 30 ℃, 60%
It is left to stand at RH and air-dried, and the state at each moisture content in the composition at that time is observed with a polarizing microscope. When all or most of the detergent composition presents hexagonal or lamellar liquid crystals or a gel thereof when the water content of the composition is about 10% by weight, the detergent composition is sprayed or applied to a hard surface. After that, even if it is wiped off and air-dried as it is, almost no wiping streaks remain on the hard surface.

The surfactant (a) used in the present invention can be obtained by the same method as described above when an aqueous solution containing one or more surfactants is naturally dried at room temperature.
When the surfactant concentration is 70% by weight or more and a surfactant is selected such that most or all of the aqueous surfactant solution becomes hexagonal or lamellar liquid crystal or a gel thereof, the condition of the present invention is satisfied. Is easy to obtain a detergent composition satisfying the above. It is possible to provide such a detergent composition (a)
Examples of the surfactant include a 1 mol adduct of pentaerythritol / isostearyl glycidyl ether, a 1 mol adduct of sorbitol / isostearyl glycidyl ether, a 1 mol adduct of mannitol-2-octyldodecyl glycidyl ether, methyl glucoside / iso One molecule of stearyl glycidyl ether, one mole of diglycerin / isostearyl glycidyl ether, at least one long-chain branched alkyl group or alkenyl group and at least three hydroxyl groups in one molecule such as phytantriol. nonionic surfactants, as those of (I) R 1 (oR 2 ) x G y (I) wherein, R 1 represents a linear alkyl group or an alkyl having 8 to 18 carbon atoms branched having a phenyl group, R 2 is an alkylene group having 2 to 4 carbon atoms, G is a reducing having 5-6 carbon atoms It represents a residue derived from. x has an average value of 0 to 5, and y has an average value of 1 to 5, preferably 1.1 to 3. Alkyl glycosidic door Rui mixtures thereof represented by]
It is . (a) The compounding amount of the surfactant is 0.01 to 20% by weight, preferably 0.05 to 10% by weight in the composition. If the amount of the surfactant is less than 0.01% by weight, the surface activity is not sufficient, and if the amount exceeds 20% by weight, no further effect is expected, so the amount exceeding 20% by weight is necessary. And not.

In the present invention, (b) volatile or liquid amine compounds include the following general formulas (II), (III), (IV) and (V)

[0009]

Embedded image

Wherein R 3 , R 6 , R 8 , R 10 , R 12 , R 14 , R
15 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and R 4 , R 5 , R 7 , R 9 , R 11 and R 13 each represent a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or It represents a hydroxyalkyl group having 2 to 3 carbon atoms. ) Is used. Examples of the compound represented by the general formula (II) include ammonia, monoethanolamine, diethanolamine, N-methylpropanol and the like. Examples of the compound represented by the general formula (III) include N- (β-aminoethyl) ethanolamine. General formula (IV)
Examples of the compound represented by are diethylenetriamine and the like. Examples of the compound represented by the general formula (V) include morpholine and N-ethylmorpholine.

The compounding amount of the amine compound in the composition of the present invention is 0.01 to 20% by weight, preferably 0.05 to 10% by weight.
It is. If the compounding amount of the amine compound is less than 0.01% by weight, the cleaning effect is insufficient, and the compounding amount exceeding 20% by weight is not required.

The balance of the composition of the present invention is water.
The hard surface cleaning composition of the present invention includes, as necessary, a normal solvent, a dispersant, a fragrance, and the like, as long as the conditions of the present invention are not impaired, in addition to the surfactant and the amine compound and water. Optional components such as dyes, pigments, preservatives and bactericides can also be added as appropriate. Even in this case, when the water content in the cleaning composition becomes 10% by weight or less, most or all of the cleaning composition may become hexagonal or lamellar liquid crystals or a gel thereof. is necessary.

[0013]

EXAMPLES The present invention will now be described specifically with reference to examples, but the present invention is not limited to these examples.

Example 1 A cleaning agent having the composition shown in Table 1 was prepared, and a window glass at home was washed with the cleaning agent, and the wiping property (finishability) and the detergency were evaluated. In addition, each evaluation was performed by spraying 5 cc of the cleaning liquid with a commercially available sprayer, wiping it off with a dry towel, and performing a sensory evaluation according to the following evaluation criteria. (Evaluation criteria) ・ Finishability ○: Little wiping streak (no need to wipe twice) △: Slight wiping remains ×: Wiping streaks ・ Washing power ○: Dirt is reduced by 80% or more △: Stain is removed by 20 to 50%. X: Stain is hardly removed. As the state of each detergent composition, 50 g of each detergent composition is placed in a petri dish having a radius of 2 cm, and left at 30 ° C. and 60% RH.
Air drying was performed, and the modes shown for each water content at that time are shown in Table 1.

[0015]

[Table 1]

 ──────────────────────────────────────────────────続 き Continuation of front page (72) Inventor Masaki Tsumori 3248-3, Yakushi-ji, Minamikawachi-cho, Kawachi-gun, Tochigi Prefecture 1-7, Green Town 134 Block (56) References JP-A-4-173900 (JP, A)

Claims (1)

    (57) [Claims]
  1. (A) at least one long chain in one molecule;
    A branched alkyl or alkenyl group and at least three waters
    Nonionic surfactant having an acid group and the following general formula
    (I) R 1 (OR 2 ) x G y (I) wherein R 1 is a linear or branched alkyl having 8 to 18 carbon atoms
    The group or an alkyl phenylene Le group, R 2 is C2-4 Al
    G is derived from a reducing sugar having 5 to 6 carbon atoms
    Indicates a residue. x has an average value of 0 to 5, and y has
    Is 1 to 5. Surface active agent selected from the alkyl glycosides represented by], (b) a volatile or liquid amine compound and (c) a hard surface liquid detergent composition containing water, the water of the detergent composition And when the other volatile components evaporate and the water content in the cleaning composition becomes 10% by weight or less, most or all of the cleaning composition is hexagonal type or lamellar type liquid crystal or A cleaning composition for hard surfaces, which is formed into the gel.
JP4044518A 1992-03-02 1992-03-02 Liquid detergent composition for hard surfaces Expired - Fee Related JP2716904B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4044518A JP2716904B2 (en) 1992-03-02 1992-03-02 Liquid detergent composition for hard surfaces

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4044518A JP2716904B2 (en) 1992-03-02 1992-03-02 Liquid detergent composition for hard surfaces

Publications (2)

Publication Number Publication Date
JPH05239492A JPH05239492A (en) 1993-09-17
JP2716904B2 true JP2716904B2 (en) 1998-02-18

Family

ID=12693765

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4044518A Expired - Fee Related JP2716904B2 (en) 1992-03-02 1992-03-02 Liquid detergent composition for hard surfaces

Country Status (1)

Country Link
JP (1) JP2716904B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009227593A (en) * 2008-03-21 2009-10-08 Daicel Chem Ind Ltd Lamellar liquid-crystal type cosmetic composition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2829887B2 (en) * 1990-11-05 1998-12-02 株式会社楽 Detergent composition

Also Published As

Publication number Publication date
JPH05239492A (en) 1993-09-17

Similar Documents

Publication Publication Date Title
JP4323518B2 (en) Cleaning and multifunctional coating compositions containing organosilane quaternary compounds and hydrogen peroxide
US4921629A (en) Heavy duty hard surface liquid detergent
US6821943B2 (en) Hard surface antimicrobial cleaner with residual antimicrobial effect comprising an organosilane
US5102573A (en) Detergent composition
EP0876460B1 (en) Cleaning agent for hard surfaces
CA2007812C (en) Acidic disinfectant all-purpose liquid cleaning composition
TWI246533B (en) Acidic hard-surface antimicrobial cleaner
DE69330305T3 (en) Cleaner for hard surfaces
US3983079A (en) Dishwashing composition
KR930007226B1 (en) Detergent composition
US5929007A (en) Alkaline aqueous hard surface cleaning compositions
US6786223B2 (en) Hard surface cleaners which provide improved fragrance retention properties to hard surfaces
CA2273741C (en) Compositions and processes for a low-foam hard surface cleaner containing an aromatic sulfonate and a sulfosuccinate
DE69827845T2 (en) Cleaning agents for ceramic and porcelain surfaces as well as suitable procedures
US4606850A (en) Hard surface cleaning composition and cleaning method using same
EP1104451B1 (en) Acidic hard surface cleaning and disinfecting compositions
AU700901B2 (en) An aqueous shower rinsing composition and a method for keeping showers clean
EP1349910B1 (en) Alkaline cleaning and sanitizing composition effective for soap scum removal
US4606842A (en) Cleaning composition for glass and similar hard surfaces
CA1056251A (en) Cleaning composition
KR20030088125A (en) Low foaming/defoaming compositions containing alkoxylated quaternary ammonium compounds
KR100581479B1 (en) Cleaning compostion and method of use
US20040142838A1 (en) Detergent composition for dry cleaning
AT393688B (en) Acid, liquid cleaning agent for ceramic plates and method for the production thereof
EP0891412B1 (en) Glass cleaner with adjustable rheology

Legal Events

Date Code Title Description
R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20071107

Year of fee payment: 10

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20081107

Year of fee payment: 11

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20091107

Year of fee payment: 12

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20091107

Year of fee payment: 12

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20101107

Year of fee payment: 13

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111107

Year of fee payment: 14

LAPS Cancellation because of no payment of annual fees