JP2518505B2 - Diffraction grating spectrometer - Google Patents

Diffraction grating spectrometer

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Publication number
JP2518505B2
JP2518505B2 JP5078672A JP7867293A JP2518505B2 JP 2518505 B2 JP2518505 B2 JP 2518505B2 JP 5078672 A JP5078672 A JP 5078672A JP 7867293 A JP7867293 A JP 7867293A JP 2518505 B2 JP2518505 B2 JP 2518505B2
Authority
JP
Japan
Prior art keywords
diffraction grating
center
concave
light source
distance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP5078672A
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Japanese (ja)
Other versions
JPH06194510A (en
Inventor
英行 野田
雅人 小池
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shimadzu Corp
Original Assignee
Shimadzu Corp
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Filing date
Publication date
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Priority to JP5078672A priority Critical patent/JP2518505B2/en
Publication of JPH06194510A publication Critical patent/JPH06194510A/en
Application granted granted Critical
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Expired - Lifetime legal-status Critical Current

Links

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明はホログラフィック回折格
子を用いた分光器に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a spectrometer using a holographic diffraction grating.

【0002】[0002]

【従来の技術】平面回折格子は従来機械切りで格子溝を
作っており、格子パターンは等間隔直線格子であるが、
この型の回折格子はそれ自身は収差を持っていないが、
リトローマウントの分光器のようにコリメータ素子とテ
レメータ素子に凹面鏡を使ったものでは、凹面鏡に球面
鏡を用い軸外し状態で使うため、これらの凹面鏡によっ
て収差が発生していた。この収差を補正するためには回
折格子の格子パターンを特殊なものにして、回折格子に
コリメータ鏡及びカメラ鏡によって発生する収差を打ち
消すような収差を発生させればよいが、ホログラフイの
利用によってそのような特殊な格子パターンに近い格子
パターンを製作する可能性が出て来た。しかし従来のホ
ログラフィックな回折格子では回折格子のパターンを格
子基板上に形成するための記録光に球面波を用いていた
ため、格子パターンは回転双曲面群と格子基板との交線
群に限定され、収差補正は不充分なものであった。また
瀬谷・波岡マウント分光器のように凹面回折格子を用い
る分光器では回折格子自身に結像作用があるからコリメ
ータ素子やテレメータ素子が不要であり、これらによっ
て生ずる収差はないが、この場合凹面回折格子の結像性
に収差が現れる。この場合にもホログラフィを用いて格
子パターンを製作することによって収差を補正すること
が行われるようになって来たが、この場合にも従来は記
録光に球面波を用いて来たので充分な収差補正ができな
かった。
2. Description of the Related Art A plane diffraction grating has conventionally been formed by mechanical cutting to form a grating groove, and the grating pattern is an evenly spaced linear grating.
This type of grating has no aberrations on its own,
In the case of a concave mirror used as a collimator element and a telemeter element like a Littrow mount spectroscope, a spherical mirror is used as the concave mirror and it is used in an off-axis state, so that aberration is generated by these concave mirrors. In order to correct this aberration, the grating pattern of the diffraction grating may be made special so that the aberration generated by the collimator mirror and the camera mirror is canceled by the diffraction grating. There is a possibility of producing a lattice pattern close to such a special lattice pattern. However, in conventional holographic diffraction gratings, spherical waves are used as the recording light for forming the diffraction grating pattern on the grating substrate, so the grating pattern is limited to the group of intersecting lines between the rotating hyperboloid group and the grating substrate. However, the aberration correction was insufficient. In a spectrograph using a concave diffraction grating such as the Seya / Namioka mount spectroscope, since the diffraction grating itself has an image forming action, a collimator element or a telemeter element is not necessary, and there is no aberration caused by these elements. Aberration appears in the image forming property of the grating. In this case as well, aberrations have come to be corrected by producing a grating pattern by using holography, but in this case as well, since spherical waves have been used for recording light in the past, it is sufficient. Aberration correction was not possible.

【0003】[0003]

【発明が解決しようとする課題】本発明は回折格子分光
器、特に瀬谷・波岡マウント分光器およびリトローマウ
ント分光器において、上述した収差の補正が完全である
ようにしようとするものである。
SUMMARY OF THE INVENTION The present invention is intended to ensure that the above-mentioned aberration correction is complete in a diffraction grating spectroscope, especially a Seya-Namioka mount spectrograph and a Littrow mount spectrograph.

【0004】[0004]

【課題を解決するための手段】使用する回折格子が分光
器の光学系によって発生する収差を補正するような逆方
向の収差を発生するようにして、分光器の収差を補正す
るもので、回折格子が上述したような収差特性を持った
ものとするため、回折格子をホログラフィック回折格子
とし、露光において使用する光束を点光源からの発散光
束を軸外し凹面鏡で反射させた収差を含んだ光束とし
た。
The diffraction grating to be used is such that aberration of the spectroscope is corrected by causing aberration in the opposite direction to correct the aberration generated by the optical system of the spectroscope. In order to make the grating have the above-mentioned aberration characteristics, the diffraction grating is a holographic diffraction grating, and the light flux used in the exposure is an off-axis of the divergent light flux from the point light source and is reflected by a concave mirror. And

【0005】[0005]

【作用】本発明の対象となっている分光器ではコリメー
タ鏡およびカメラ鏡が軸外しの状態で用いられるので収
差が発生するが、原理的にはこのような収差は回折格子
でそれと逆の収差を発生させることで補正できるであろ
うことが予想される。そのような回折格子をホログラフ
ィックな方法で作るとしても、その露光条件は上述した
ような原理だけから導出することはできない。分光器の
各部配置を一つ決めると、それに対してホログラフィッ
ク露光の最適配置が求められるが、分光器の配置を変え
ると、最適の露光配置も変わるので、両者の配置を変え
て一番良い所を探り当てる必要がある。本発明はそのよ
うにして探り当てられた分光器およびホログラフィック
露光の配置を示すものである。
In the spectroscope to which the present invention is applied, the collimator mirror and the camera mirror are used off-axis, so that an aberration occurs. In principle, however, such an aberration is an aberration opposite to that of the diffraction grating. It is expected that it can be corrected by generating Even if such a diffraction grating is made by a holographic method, the exposure conditions cannot be derived only from the principle described above. If you decide on the layout of each part of the spectroscope, the optimum layout for holographic exposure is required, but if you change the layout of the spectroscope, the optimum layout for exposure also changes. You need to figure out where. The invention shows the arrangement of the spectrograph and the holographic exposure so spotted.

【0006】[0006]

【実施例】この実施例は瀬谷・波岡マウント分光器に関
するものである。この実施例における回折格子は曲率半
径500mmの凹球面で中心における格子ピッチは60
0本/mmであり、これを用いる分光系を第1図に示
す。10が本発明に係る上記凹面回折格子で、6は入射
スリット、7は出射スリットで、入射スリット6から格
子中心0までの距離r=409.8374mm、格子中
心から出射スリットまでの距離r’=410.8190
mm、入射スリットと出射スリットとの格子中心に関す
る角距離θ=69.7083°で、使用波長範囲は10
0〜700nmである。第2図は上記回折格子10の格
子パターン記録時の配置を示す。11が回折格子基板で
曲率半径500mmの凹球面であり、その中心0に立て
た法線をNとする。Nを含む平面内で、同法線Nと角α
=4.77°離れた方向で0点からの距離r=199
9.4mmの所に第1点光源12を置き、法線Nに関
し、点光源12と反対側に角度β=11°だけ離れ、0
点からの距離r’=871.4mmの位置に凹面球面鏡
13の中心0’を置き、0’点から0,0’を結ぶ線よ
り角度2r=16.4°だけ法線N寄りに離れ、0’か
ら距離P=204.9mmの位置に第2点光源14を配
置した。記録光として波長457.93nmのレーザー
光を用いた。なお本発明において各素子間の距離とか素
子の曲率等長さの値は光学系一般の性質としてどれかを
基準とした相対値でよいのである。次の実施例について
も同じである。図は上述回折格子とコマ収差補正を
行った従来のホログラフィック回折格子とを第図に示
す分光器で使い比べたときのスポットダイヤグラム(計
算値)であり各波長において本発明が優れていることが
分かる。
EXAMPLE This example relates to a Seya-Namioka mount spectrometer. The diffraction grating in this embodiment is a concave spherical surface having a radius of curvature of 500 mm and the grating pitch at the center is 60.
The number is 0 / mm, and a spectroscopic system using this is shown in FIG. 10 is the concave diffraction grating according to the present invention, 6 is an entrance slit, 7 is an exit slit, and the distance r from the entrance slit 6 to the grating center 0 is r = 409.8374 mm, and the distance r ′ from the grating center to the exit slit is r ′ = 410.8190
mm, the angular distance θ between the entrance slit and the exit slit with respect to the center of the grating is 69.7083 °, and the usable wavelength range is 10
It is 0 to 700 nm. FIG. 2 shows the arrangement of the diffraction grating 10 at the time of recording the grating pattern. Reference numeral 11 denotes a diffraction grating substrate, which is a concave spherical surface having a radius of curvature of 500 mm, and the normal line standing at the center 0 is N. In the plane containing N, the normal N and the angle α
= Distance from the 0 point in the direction away from 4.77 ° r = 199
The first point light source 12 is placed at a position of 9.4 mm, and with respect to the normal line N, the angle β = 11 ° is provided on the side opposite to the point light source 12, and 0
The center 0'of the concave spherical mirror 13 is placed at a position of distance r '= 871.4 mm from the point, and it is separated from the line connecting the 0'point and 0,0' by an angle 2r = 16.4 ° toward the normal line N, The second point light source 14 was arranged at a position P = 204.9 mm from 0 ′. Laser light having a wavelength of 457.93 nm was used as the recording light. In the present invention, the distance between each element
The value of the curvature equal length of the child is
The relative value used as the reference is sufficient. About the next example
Is also the same. FIG. 3 is a spot diagram (calculated value) when the above diffraction grating and a conventional holographic diffraction grating with coma aberration correction are used and compared in the spectroscope shown in FIG. 1 , and the present invention is excellent at each wavelength. I understand that.

【0007】これはリトローマウント分光器用について
の実施例で、平面回折格子に関するものである。第4図
は上記実施例を示す。1が平面回折格子基板、2,3が
第1および第2記録光源点で、夫々は同一レーザ(図
外)から発射されたレーザビームを2分割して収束させ
ることにより形成されている。記録光源点2,3から発
散する球面波はそれぞれ第1および第2凹面鏡4,5に
より非球面波として反射され、回折格子基板1上で干渉
縞を形成する。第5図は本発明により作成したホログラ
フィック平面回折格子を用いたリトローマウントの分光
系の一例を示す。分光系の波長領域を200〜800n
m、回折格子12の中心での格子定数を1/1800m
mとし、コリメータ鏡8を単位長の曲率半径をもつ球面
鏡とする。上記回折格子製作の詳細を述べると、記録光
としてレーザ波長441.6nmのレーザ光を用い、露
光系の配置は第4図において pc=0.3986 qc=0.8710 tc=6.188° pd=0.3912 qd=0.8708 td=13.545° である。また凹面鏡4,5の曲率半径R4,R5はR4
=R5=1.000である。分光器の配置は第5図にお
いてr=0.4988D=0.4087,D’=0.4
093,r’=0.4973,θ=4.290°,2K
=2.405°,θ’=5.709°で使用次数−1,
コリメータ鏡8の曲率半径R8はR8=1.000であ
る。したがって、qc,qd、さらに第1および第2
面鏡4,5の曲率半径はコリメータ鏡8の曲率半径に等
しいか、もしくはその近傍にある。上の例では二つの記
録光源2,3に関して、夫々凹面鏡を使用しているが、
この構成には二つの記録光源のうち少なくとも一方につ
いてだけ採用しておけば充分な場合が設計上多い。また
回折格子基板についても平面以外にシリンドリカル面、
球面などを用いることが可能である。上述各実施例に示
された各パラメータの値は、その値の近傍では収差特性
が安定していて、多少の変動によっても、収差特性は殆
ど変わらないものである。
This is an embodiment for a Littrow-mounted spectroscope and relates to a plane diffraction grating. FIG. 4 shows the above embodiment. 1 is a plane diffraction grating substrate, 2 and 3 are
Each of the first and second recording light source points is formed by dividing a laser beam emitted from the same laser (not shown) into two and converging the laser beams. The spherical waves diverging from the recording light source points 2 and 3 are reflected as aspherical waves by the first and second concave mirrors 4 and 5, respectively, and form interference fringes on the diffraction grating substrate 1. FIG. 5 shows an example of a Littrow mount spectroscopic system using a holographic plane diffraction grating prepared according to the present invention. The wavelength range of the spectroscopic system is 200-800n
m, the grating constant at the center of the diffraction grating 12 is 1/1800 m
m, and the collimator mirror 8 is a spherical mirror having a radius of curvature of a unit length. The details of the production of the diffraction grating will be described. A laser beam having a laser wavelength of 441.6 nm is used as a recording beam, and the exposure system is arranged as shown in FIG. 4 by pc = 0.3986 qc = 0.8710 tc = 6.188 ° pd. = 0.3912 qd = 0.8708 td = 13.545 °. Also, the curvature radii R4 and R5 of the concave mirrors 4 and 5 are R4.
= R5 = 1.000. The arrangement of the spectroscope is as shown in FIG. 5, r = 0.4988D = 0.40887, D '= 0.4.
093, r '= 0.4973, θ = 4.290 °, 2K
= 2.405 °, θ ′ = 5.709 °, use order −1,
The radius of curvature R8 of the collimator mirror 8 is R8 = 1.000. Therefore, the radii of curvature of qc, qd and the first and second concave mirrors 4, 5 are equal to or near the radius of curvature of the collimator mirror 8. In the above example, concave mirrors are used for the two recording light sources 2 and 3, respectively.
In many cases, it is sufficient for this configuration to employ at least one of the two recording light sources. Also for the diffraction grating substrate, besides the plane, a cylindrical surface,
It is possible to use a spherical surface or the like. Regarding the value of each parameter shown in each of the above-mentioned examples, the aberration characteristic is stable in the vicinity of the value, and the aberration characteristic hardly changes even if it is changed a little.

【0008】[0008]

【発明の効果】本発明による回折格子は従来のホログラ
フィック回折格子に比し、記録光に非球面波を用いたこ
とにより格子パターンを形成したので、分光器を構成す
る光学素子或は回折格子自身を軸外し状態で用いること
により発生する収差の補正が従来のホログラフィック回
折格子に比し一層良好になった。また非球面波を得るの
に凹球面鏡を軸外しで用いると、非球面光学系を用いる
のに非し、回折格子の格子パターン記録用光学系を容易
にきわめて精密に最適設計の諸パラメータに合わせて構
成することができる。
As compared with the conventional holographic diffraction grating, the diffraction grating according to the present invention forms the grating pattern by using the aspherical wave for the recording light, so that the optical element or the diffraction grating constituting the spectroscope is formed. The correction of the aberration generated by using itself in the off-axis state is better than that of the conventional holographic diffraction grating. If a concave spherical mirror is used off-axis to obtain an aspherical wave, it is not necessary to use an aspherical optical system, and the grating pattern recording optical system of the diffraction grating can be adjusted very precisely to the parameters of the optimum design. Can be configured.

【図面の簡単な説明】[Brief description of drawings]

【図1】 本発明の一実施例分光器の平面図、FIG. 1 is a plan view of a spectroscope according to an embodiment of the present invention,

【図2】 同実施例の回折格子の格子パターン記録次の
配置を示す平面図、
FIG. 2 is a plan view showing the arrangement of a grating pattern recorded next to the diffraction grating of the embodiment,

【図3】 同実施例の効果を示すグラフ、FIG. 3 is a graph showing the effect of the same embodiment,

【図4】 本発明の更に他の一実施例の回折格子の格子
パターン記録時の配置を示す平面図、
FIG. 4 is a plan view showing an arrangement of a diffraction grating of another embodiment of the present invention during recording of a grating pattern,

【図5】 同実施例による回折格子を用いた分光器の平
面図。
FIG. 5 is a plan view of a spectroscope using a diffraction grating according to the example.

【符号の説明】[Explanation of symbols]

1 平面回折格子基板 2,3 記録点光源 4,5 凹面鏡 6 入射スリット 7 出射スリット 8 コリメータ鏡 9 出口スリット 10 凹面回折格子 11 凹面回折格子基板 12 平面回折格子 1 plane diffraction grating substrate 2,3 recording point light source 4,5 concave mirror 6 entrance slit 7 exit slit 8 collimator mirror 9 exit slit 10 concave diffraction grating 11 concave diffraction grating substrate 12 plane diffraction grating

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 瀬谷・波岡マウント分光器において、凹
球面の回折格子基板を用い、同基板とほゞ同じ曲率半径
をもつ凹面鏡に対して軸外し位置に点光源を配置して回
折格子基板面に干渉パターンを形成させて作られたホロ
グラフィック凹面回折格子を用い、この凹面回折格子の
曲率半径を基準としてこれを相対値で500としたと
き、分光器において、入射スリットから回折格子中心ま
での距離rおよび回折格子中心から出射スリットまでの
距離r’を夫々約410、両スリット位置が回折格子中
心に対して張る角θを約69.7°とし、上記ホログラ
フィック回折格子の露光条件を下記のようにしたことを
特徴とする回折格子分光器。 記 面回折格子の曲率半径を基準としてこれを500としたとき、相対値で r : 回折格子基板中心と第1点光源間の距離約2.00×10 r’: 回折格子基板中心と凹面鏡中心間の距離約871 p : 凹面鏡中心と第2点光源間の距離約205 α : 回折格子基板中心法線と第1点光源が回折格子基板中心に対して張角約4.77° β : 回折格子基板中心法線と凹面鏡中心が回折格子基板中心に対して張る 角約11° γ : 回折格子基板中心と第2点光源とが凹面鏡中心に対して張る角約8. 2° 露光波長 457.93nm
1. In a Seya-Namioka mount spectrometer, a diffraction grating substrate having a concave spherical surface is used, and a point light source is arranged at an off-axis position with respect to a concave mirror having substantially the same radius of curvature as that of the diffraction grating substrate surface. Using a holographic concave diffraction grating made by forming an interference pattern on the, and setting this as a relative value of 500 with respect to the radius of curvature of this concave diffraction grating, the spectroscope measures from the entrance slit to the diffraction grating center. The distance r and the distance r ′ from the center of the diffraction grating to the exit slit are respectively about 410, the angle θ formed by the positions of both slits with respect to the center of the diffraction grating is about 69.7 °, and the exposure conditions of the holographic diffraction grating are as follows. A diffraction grating spectroscope characterized in that When this was used as a 500 on the basis of the curvature radius of the serial concave surface diffraction grating, r by a relative value: the distance of about 2.00 × 10 3 r between the diffraction grating substrate center and the first point light source ': the diffraction grating substrate center distance of about 871 p between the concave mirror centers: distance of about 205 between the concave center and the second point light source alpha: Zhang Ru angle about 4.77 ° relative to the grating substrate center normal line and the first point light source grating substrate center β: The angle between the normal to the center of the diffraction grating substrate and the center of the concave mirror is about 11 ° γ: The angle between the center of the diffraction grating substrate and the center of the second point light source is about 8 from the concave mirror 2 ° exposure wavelength 457.93nm
【請求項2】 リトローマウント分光器であって、使用
する回折格子が平面回折格子であり、コリメータ鏡の曲
率半径を基準にしてこれを1とするとき、分光器につい
てのパラメータ D,D’:回折格子中心とコリメータ鏡との距離約0.41 θ :回折格子中心と入スリットがコリメータ鏡中心に対して張る角約4. 3° θ’ :回折格子中心と出口スリットがコリメータ鏡中心に対して張る角約5 .7° K :回折格子中心への入射光と反射光とのなす角約1.2° であり、上記回折格子のホログラフィック露光条件pc,pd:回折格子基板中心と第1,第2凹面鏡間の各距離 約0.4 qc,qd:第1点光源第1凹面鏡間および第2点光源第2凹面鏡間の各距離 約0.87 τc: 第1点光源と第1凹面鏡中心法線が同凹面鏡中心にたいして張る角 約6.2° τd: 第2点光源と第2凹面鏡中心法線が同凹面鏡中心に対して張る角 約13.5° 露光波長 441.6nm であることを特徴とする回折格子分光器
2. A Littrow mount spectroscope, wherein the diffraction grating used is a plane diffraction grating, and when the radius of curvature of the collimator mirror is taken as 1 and the spectroscopic parameters are D and D. ': Distance between the center of the diffraction grating and the collimator mirror about 0.41 θ: Angle between the center of the diffraction grating and the center of the collimator mirror about 4. 3 ° θ ': Angle formed by the center of the diffraction grating and the center of the exit slit with respect to the center of the collimator mirror . 7 ° K: The angle between the incident light and the reflected light at the center of the diffraction grating is about 1.2 ° , and the holographic exposure condition of the diffraction grating is pc, pd: the center of the diffraction grating substrate and the first and second Distance between concave mirrors : about 0.4 qc, qd: First point light source Distance between first concave mirror and second point light source Second distance between concave mirrors : about 0.87 τc: First point light source and center line of first concave mirror Is about 6.2 ° τd about the center of the concave mirror: The second point light source and the center line of the second concave mirror are about 13.5 ° about the center of the concave mirror and the exposure wavelength is 441.6 nm. Diffraction grating spectrometer
JP5078672A 1985-04-11 1993-03-13 Diffraction grating spectrometer Expired - Lifetime JP2518505B2 (en)

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US10900832B2 (en) 2016-06-06 2021-01-26 Shimadzu Corporation Diffraction grating and spectral device

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KR20020013061A (en) * 2000-08-10 2002-02-20 조기환 Method for Determinating spectrum using multslit and mult channel spectrograph using the same
CN100434945C (en) * 2006-07-07 2008-11-19 中国科学院长春光学精密机械与物理研究所 IV type concave holographic grating production process
US8773659B2 (en) * 2012-01-13 2014-07-08 Roper Scientific Inc. Anastigmatic imaging spectrograph

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10900832B2 (en) 2016-06-06 2021-01-26 Shimadzu Corporation Diffraction grating and spectral device

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