JP2022119593A - 発泡スチレン樹脂用難燃剤組成物、難燃性発泡スチレン系樹脂組成物及びその押出発泡成形体 - Google Patents
発泡スチレン樹脂用難燃剤組成物、難燃性発泡スチレン系樹脂組成物及びその押出発泡成形体 Download PDFInfo
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 121
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 119
- 229920005989 resin Polymers 0.000 title claims abstract description 77
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- 238000001125 extrusion Methods 0.000 title abstract description 12
- 238000010097 foam moulding Methods 0.000 title abstract description 10
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 45
- -1 phosphate ester Chemical class 0.000 claims abstract description 45
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 40
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 33
- 239000000194 fatty acid Substances 0.000 claims abstract description 33
- 229930195729 fatty acid Natural products 0.000 claims abstract description 33
- 239000010452 phosphate Substances 0.000 claims abstract description 29
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 26
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- 239000011701 zinc Substances 0.000 claims abstract description 26
- CMQUQOHNANGDOR-UHFFFAOYSA-N 2,3-dibromo-4-(2,4-dibromo-5-hydroxyphenyl)phenol Chemical compound BrC1=C(Br)C(O)=CC=C1C1=CC(O)=C(Br)C=C1Br CMQUQOHNANGDOR-UHFFFAOYSA-N 0.000 claims abstract description 9
- XUMFBUWGVLTWTH-UHFFFAOYSA-N 1,2-dibromo-3-(2,3-dibromo-2-methylpropoxy)-2-methylpropane Chemical compound BrCC(Br)(C)COCC(C)(Br)CBr XUMFBUWGVLTWTH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000006260 foam Substances 0.000 claims description 56
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- 239000002184 metal Substances 0.000 claims description 24
- 150000003839 salts Chemical class 0.000 claims description 19
- LXIZRZRTWSDLKK-UHFFFAOYSA-N 1,3-dibromo-5-[2-[3,5-dibromo-4-(2,3-dibromopropoxy)phenyl]propan-2-yl]-2-(2,3-dibromopropoxy)benzene Chemical compound C=1C(Br)=C(OCC(Br)CBr)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(OCC(Br)CBr)C(Br)=C1 LXIZRZRTWSDLKK-UHFFFAOYSA-N 0.000 claims description 6
- BDFBPPCACYFGFA-UHFFFAOYSA-N 2,4,6-tris(2,4,6-tribromophenoxy)-1,3,5-triazine Chemical compound BrC1=CC(Br)=CC(Br)=C1OC1=NC(OC=2C(=CC(Br)=CC=2Br)Br)=NC(OC=2C(=CC(Br)=CC=2Br)Br)=N1 BDFBPPCACYFGFA-UHFFFAOYSA-N 0.000 claims description 6
- NZUPFZNVGSWLQC-UHFFFAOYSA-N 1,3,5-tris(2,3-dibromopropyl)-1,3,5-triazinane-2,4,6-trione Chemical compound BrCC(Br)CN1C(=O)N(CC(Br)CBr)C(=O)N(CC(Br)CBr)C1=O NZUPFZNVGSWLQC-UHFFFAOYSA-N 0.000 claims description 5
- 239000004593 Epoxy Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 abstract description 8
- 235000021317 phosphate Nutrition 0.000 description 38
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 16
- 230000000694 effects Effects 0.000 description 14
- 239000004088 foaming agent Substances 0.000 description 14
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- 125000001424 substituent group Chemical group 0.000 description 12
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- 238000005187 foaming Methods 0.000 description 9
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 8
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- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000002667 nucleating agent Substances 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 239000003623 enhancer Substances 0.000 description 6
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- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
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- 239000007983 Tris buffer Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
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- 150000004671 saturated fatty acids Chemical class 0.000 description 4
- BHYQWBKCXBXPKM-UHFFFAOYSA-N tris[3-bromo-2,2-bis(bromomethyl)propyl] phosphate Chemical compound BrCC(CBr)(CBr)COP(=O)(OCC(CBr)(CBr)CBr)OCC(CBr)(CBr)CBr BHYQWBKCXBXPKM-UHFFFAOYSA-N 0.000 description 4
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 4
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 3
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- LJKDOMVGKKPJBH-UHFFFAOYSA-N 2-ethylhexyl dihydrogen phosphate Chemical compound CCCCC(CC)COP(O)(O)=O LJKDOMVGKKPJBH-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
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- FDBMBOYIVUGUSL-UHFFFAOYSA-N OP(O)OP(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C(C)(C)C)C)C(C)(C)C Chemical compound OP(O)OP(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C(C)(C)C)C)C(C)(C)C FDBMBOYIVUGUSL-UHFFFAOYSA-N 0.000 description 2
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- MWKGOHCHXBLCSH-UHFFFAOYSA-L [Zn+2].CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O MWKGOHCHXBLCSH-UHFFFAOYSA-L 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
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- 238000000354 decomposition reaction Methods 0.000 description 2
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- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
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- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
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- 125000005843 halogen group Chemical group 0.000 description 2
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- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
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- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
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- 239000002994 raw material Substances 0.000 description 2
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- 125000002256 xylenyl group Chemical group C1(C(C=CC=C1)C)(C)* 0.000 description 2
- 229940098697 zinc laurate Drugs 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- LPEBYPDZMWMCLZ-CVBJKYQLSA-L zinc;(z)-octadec-9-enoate Chemical compound [Zn+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LPEBYPDZMWMCLZ-CVBJKYQLSA-L 0.000 description 2
- FRZSCIVUSFMNBX-UHFFFAOYSA-L zinc;12-hydroxyoctadecanoate Chemical compound [Zn+2].CCCCCCC(O)CCCCCCCCCCC([O-])=O.CCCCCCC(O)CCCCCCCCCCC([O-])=O FRZSCIVUSFMNBX-UHFFFAOYSA-L 0.000 description 2
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 2
- YEYCMBWKTZNPDH-UHFFFAOYSA-N (2,2,6,6-tetramethylpiperidin-4-yl) benzoate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)C1=CC=CC=C1 YEYCMBWKTZNPDH-UHFFFAOYSA-N 0.000 description 1
- OWICEWMBIBPFAH-UHFFFAOYSA-N (3-diphenoxyphosphoryloxyphenyl) diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1)(=O)OC1=CC=CC=C1 OWICEWMBIBPFAH-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
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- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- RGASRBUYZODJTG-UHFFFAOYSA-N 1,1-bis(2,4-ditert-butylphenyl)-2,2-bis(hydroxymethyl)propane-1,3-diol dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C RGASRBUYZODJTG-UHFFFAOYSA-N 0.000 description 1
- OZHJEQVYCBTHJT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-methylbenzene Chemical compound CC1=C(Br)C(Br)=C(Br)C(Br)=C1Br OZHJEQVYCBTHJT-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
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- VNQNXQYZMPJLQX-UHFFFAOYSA-N 1,3,5-tris[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CN2C(N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C(=O)N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C2=O)=O)=C1 VNQNXQYZMPJLQX-UHFFFAOYSA-N 0.000 description 1
- XYXJKPCGSGVSBO-UHFFFAOYSA-N 1,3,5-tris[(4-tert-butyl-3-hydroxy-2,6-dimethylphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C)=C1CN1C(=O)N(CC=2C(=C(O)C(=CC=2C)C(C)(C)C)C)C(=O)N(CC=2C(=C(O)C(=CC=2C)C(C)(C)C)C)C1=O XYXJKPCGSGVSBO-UHFFFAOYSA-N 0.000 description 1
- CWZVMVIHYSYLSI-UHFFFAOYSA-N 1,3-dibromo-5-[3,5-dibromo-4-(2,3-dibromopropoxy)phenyl]sulfonyl-2-(2,3-dibromopropoxy)benzene Chemical compound C1=C(Br)C(OCC(Br)CBr)=C(Br)C=C1S(=O)(=O)C1=CC(Br)=C(OCC(Br)CBr)C(Br)=C1 CWZVMVIHYSYLSI-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- BHNZEZWIUMJCGF-UHFFFAOYSA-N 1-chloro-1,1-difluoroethane Chemical compound CC(F)(F)Cl BHNZEZWIUMJCGF-UHFFFAOYSA-N 0.000 description 1
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- 238000005260 corrosion Methods 0.000 description 1
- 239000003484 crystal nucleating agent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- UJSSNDKVUQJEGE-UHFFFAOYSA-N dichloro propyl phosphate Chemical compound CCCOP(=O)(OCl)OCl UJSSNDKVUQJEGE-UHFFFAOYSA-N 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 239000001177 diphosphate Substances 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- CAYGQBVSOZLICD-UHFFFAOYSA-N hexabromobenzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1Br CAYGQBVSOZLICD-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ATYSJAJVVFHRKR-UHFFFAOYSA-L magnesium octacosanoate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O ATYSJAJVVFHRKR-UHFFFAOYSA-L 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- BJZBHTNKDCBDNQ-UHFFFAOYSA-L magnesium;dodecanoate Chemical compound [Mg+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O BJZBHTNKDCBDNQ-UHFFFAOYSA-L 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- XESULCZVWZVTFC-UHFFFAOYSA-N n-[(4-ethenylphenyl)methyl]-n-ethylethanamine Chemical compound CCN(CC)CC1=CC=C(C=C)C=C1 XESULCZVWZVTFC-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 1
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical class OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000012321 sodium triacetoxyborohydride Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- LVEOKSIILWWVEO-UHFFFAOYSA-N tetradecyl 3-(3-oxo-3-tetradecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCC LVEOKSIILWWVEO-UHFFFAOYSA-N 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 description 1
- MZHULIWXRDLGRR-UHFFFAOYSA-N tridecyl 3-(3-oxo-3-tridecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCC MZHULIWXRDLGRR-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
- CNUJLMSKURPSHE-UHFFFAOYSA-N trioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC CNUJLMSKURPSHE-UHFFFAOYSA-N 0.000 description 1
- KOWVWXQNQNCRRS-UHFFFAOYSA-N tris(2,4-dimethylphenyl) phosphate Chemical compound CC1=CC(C)=CC=C1OP(=O)(OC=1C(=CC(C)=CC=1)C)OC1=CC=C(C)C=C1C KOWVWXQNQNCRRS-UHFFFAOYSA-N 0.000 description 1
- IVJLIUKQYNWCEZ-UHFFFAOYSA-N tris(2-bromophenyl) phosphate Chemical compound BrC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)Br)OC1=CC=CC=C1Br IVJLIUKQYNWCEZ-UHFFFAOYSA-N 0.000 description 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 1
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 description 1
- ILLOBGFGKYTZRO-UHFFFAOYSA-N tris(2-ethylhexyl) phosphite Chemical compound CCCCC(CC)COP(OCC(CC)CCCC)OCC(CC)CCCC ILLOBGFGKYTZRO-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- QEEHNBQLHFJCOV-UHFFFAOYSA-N tris(2-phenylphenyl) phosphate Chemical compound C=1C=CC=C(C=2C=CC=CC=2)C=1OP(OC=1C(=CC=CC=1)C=1C=CC=CC=1)(=O)OC1=CC=CC=C1C1=CC=CC=C1 QEEHNBQLHFJCOV-UHFFFAOYSA-N 0.000 description 1
- LIPMRGQQBZJCTM-UHFFFAOYSA-N tris(2-propan-2-ylphenyl) phosphate Chemical compound CC(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)C)OC1=CC=CC=C1C(C)C LIPMRGQQBZJCTM-UHFFFAOYSA-N 0.000 description 1
- IJOFZIRWMBOMHP-UHFFFAOYSA-N tris(2-propan-2-ylphenyl) phosphite Chemical compound CC(C)C1=CC=CC=C1OP(OC=1C(=CC=CC=1)C(C)C)OC1=CC=CC=C1C(C)C IJOFZIRWMBOMHP-UHFFFAOYSA-N 0.000 description 1
- MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 1
- 239000000326 ultraviolet stabilizing agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001868 water Inorganic materials 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 229940105125 zinc myristate Drugs 0.000 description 1
- 229940012185 zinc palmitate Drugs 0.000 description 1
- 229940057977 zinc stearate Drugs 0.000 description 1
- IJQXGKBNDNQWAT-UHFFFAOYSA-L zinc;docosanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O IJQXGKBNDNQWAT-UHFFFAOYSA-L 0.000 description 1
- GJAPSKMAVXDBIU-UHFFFAOYSA-L zinc;hexadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O GJAPSKMAVXDBIU-UHFFFAOYSA-L 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
- XDWXRAYGALQIFG-UHFFFAOYSA-L zinc;propanoate Chemical compound [Zn+2].CCC([O-])=O.CCC([O-])=O XDWXRAYGALQIFG-UHFFFAOYSA-L 0.000 description 1
- GBFLQPIIIRJQLU-UHFFFAOYSA-L zinc;tetradecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O GBFLQPIIIRJQLU-UHFFFAOYSA-L 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Description
に関する。
項1
少なくとも下記の成分(B1)、成分(C)及び成分(D)、
(B1)テトラブロモビスフェノールA-ビス(2,3-ジブロモ-2-メチルプロピルエーテル)、
(C)脂肪酸亜鉛、及び、
(D)リン酸エステル系化合物
を含み、
前記成分(B1)100質量部あたりの前記成分(C)の含有量が0.1~15質量部であり、
前記成分(B1)100質量部あたりの前記成分(D)の含有量が8~300質量部である、発泡スチレン樹脂用難燃剤組成物。
項2
前記成分(B1)以外に難燃剤として成分(B2)を含有し、
前記成分(B2)は、含臭素難燃剤である、項1に記載の発泡スチレン樹脂用難燃剤組成物。
項3
前記成分(B2)は、テトラブロモビスフェノールA-ビス(2,3-ジブロモプロピルエーテル)、トリス(2,3-ジブロモプロピル)イソシアヌレート、トリス(トリブロモフェノキシ)トリアジン、及び、臭素化エポキシオリゴマーからなる群より選択される少なくとも1種を含む、項1又は2に記載の発泡スチレン樹脂用難燃剤組成物。
項4
前記成分(B1)及び前記成分(B2)の総量に対して、前記成分(B1)の含有割合が10~99質量%である、項2又は3に記載の発泡スチレン樹脂用難燃剤組成物。
項5
さらに下記の成分(E)、
(E)脂肪酸金属塩(ただし、前記(C)成分は除く)
を含む、請求項1~4のいずれか1項に記載の発泡スチレン樹脂用難燃剤組成物。
項6
前記成分(B1)100質量部あたりの前記成分(E)の含有量が1~45質量部である、項5に記載の発泡スチレン樹脂用難燃剤組成物。
項7
項1~6のいずれか1項に記載の発泡スチレン樹脂用難燃剤組成物と、成分(A)スチレン系樹脂とを含む、難燃性発泡スチレン系樹脂組成物。
項8
項7に記載の難燃性発泡スチレン系樹脂組成物の押出発泡成形体。
本発明の発泡スチレン樹脂用難燃剤組成物は、少なくとも下記の成分(B1)、成分(C)及び成分(D)を含む。
(B1)テトラブロモビスフェノールA-ビス(2,3-ジブロモ-2-メチルプロピルエーテル)、
(C)脂肪酸亜鉛、及び、
(D)リン酸エステル系化合物.
難燃剤組成物に含まれる成分(B1)は、テトラブロモビスフェノールA-ビス(2,3-ジブロモ-2-メチルプロピルエーテル)であって、難燃剤としての役割を果たす成分である。つまり、成分(B1)は臭素系難燃剤である。
難燃剤組成物は、本発明の効果が阻害されない限り、成分(B1)以外の難燃剤を含むこともでき、この場合、難燃性及び耐熱性が向上することもある。成分(B1)以外の難燃剤として、成分(B1)以外の臭素系難燃剤を挙げることができる。以下、この臭素系難燃剤を「成分(B2)」と略記する。
難燃剤組成物に含まれる成分(C)は、脂肪酸亜鉛である。難燃剤組成物が脂肪酸亜鉛を含むことで、難燃剤組成物は、押出発泡成形体に優れた難燃性及び耐熱性を付与することができ、特に難燃性能を向上させることができる。
{成分(C)の質量/成分(B1)の質量}×100
の値が0.1~15の範囲である。これにより、成分(B1)の難燃剤の効果を高めることができ、優れた難燃性能を発揮することができる。
難燃剤組成物に含まれる成分(D)はリン酸エステル系化合物である。難燃剤組成物が成分(D)を含むことで、成分(B1)等の難燃剤の効果をさらに高めることができ、スチレン系樹脂組成物の発泡成形体の難燃性及び耐熱性を向上させることができる。
{成分(D)の質量/成分(B1)の質量}×100
の値が8~300の範囲である。これにより、成分(B1)の難燃剤の効果を高めることができる。
難燃剤組成物は、さらに下記の成分(E)、
(E)脂肪酸金属塩(ただし、前記(C)成分は除く)
を含むことがきできる。ただし、斯かる(E)脂肪酸金属塩は前記(C)成分以外、つまり、前記脂肪酸亜鉛以外を意味する。要するに、成分(E)において、脂肪酸金属塩の金属は亜鉛以外である。
{成分(E)の質量/成分(B1)の質量}×100
の値が1~45の範囲である。これにより、難燃性能をさらに高めることができ、また、押出発泡成形体に特に優れた耐熱性を付与でき、成形性に優れる押出発泡成形体を得ることができる。
難燃剤組成物は、成分(A)~(D)と必要に応じて含まれる成分(E)以外に、例えば、成分(F)として熱安定剤を含むことができる。なお、難燃剤組成物は成分(F)を含まず、後記するスチレン系樹脂組成物が成分(F)を含むこともできる。熱安定剤は、発泡成形体の熱安定性をさらに向上させることができる。
難燃剤組成物は、成分(A)~(D)以外に、例えば、成分(G)として難燃増強剤を含むことができる。なお、難燃剤組成物は成分(G)を含まず、後記するスチレン系樹脂組成物が成分(G)を含むこともできる。難燃増強剤は、発泡成形体の熱安定性をさらに向上させることができる。
難燃剤脂組成物は、成分(A)~(D)以外に、例えば、成分(I)として発泡核剤を含むことができる。なお、難燃剤組成物は成分(I)を含まず、後記するスチレン系樹脂組成物が成分(I)を含むこともできる。発泡核剤は、スチレン系樹脂組成物の発泡成形体の気泡を形成しやすくし、気泡径の調整も容易になるので発泡成形体の強度等の調節に役立ちやすい。
難燃剤脂組成物は、上記各成分以外にも、本発明の効果を損なわない範囲内で、その他の各種成分を含むことができる。難燃剤脂組成物がその他成分を含む場合、その含有割合は特に限定されず、例えば、前記(B1)、成分(C)及び成分(D)の全質量に対して、50質量%以下とすることができ、好ましくは30質量%以下、より好ましくは10質量%以下、さらに好ましくは1質量%以下である。
本発明の難燃性発泡スチレン系樹脂組成物(スチレン系樹脂組成物)は、前記難燃剤組成物に加えて、さらに成分(A)スチレン系樹脂を含む。つまり、本発明の発泡スチレン樹脂用難燃剤組成物は、成分(A)、成分(B1)、成分(C)及び成分(D)を含む。(A)スチレン系樹脂
(B1)テトラブロモビスフェノールA-ビス(2,3-ジブロモ-2-メチルプロピルエーテル)
(C)脂肪酸亜鉛、及び、
(D)リン酸エステル系化合物
を含み、必要に応じて、成分(E)である脂肪酸金属塩(ただし、前記(C)成分は除く)を含むこともできる。念のための注記に過ぎないが、前記成分(B1)100質量部あたりの前記成分(C)の含有量が0.1~15質量部であり、前記成分(B1)100質量部あたりの前記成分(D)の含有量が8~300質量部である。
押出発泡工程;スチレン系樹脂組成物を押出機内で溶融混合し、(H)成分としての発泡剤(H)を押出機内に圧入し、次いで、押出機口金から大気中へ押出す工程。
(A)スチレン系樹脂
・GP-PS(PSジャパン社製「PSJポリスチレン G9305」
テトラブロモビスフェノールA-ビス(2,3-ジブロモ-2-メチルプロピルエーテル)(第一工業製薬社製「ピロガード SR-130」)
・B2-1:テトラブロモビスフェノールA-ビス(2,3-ジブロモプロピルエーテル)(第一工業製薬社製「ピロガード SR-720N」)
・B2-2:トリス(2,3-ジブロモプロピル)イソシアヌレート(第一工業製薬社製「ピロガード SR-750」)
・B2-3:トリス(トリブロモフェノキシ)トリアジン(第一工業製薬社製「ピロガード SR-245」)
・B2-4:臭素化エポキシオリゴマー(阪本薬品工業社製「SR-T1000」)
(C)脂肪酸亜鉛
・C-1:ステアリン酸亜鉛(日東化成工業社製「Zn-St」)
・C-2:12-ヒドロキシステアリン酸亜鉛(日東化成工業社製「ZS-6」)
・C-3:モンタン酸亜鉛(日東化成工業社製「ZS-8」)
・C-4:オレイン酸亜鉛
・C-5:ラウリン酸亜鉛(日東化成工業社製「ZS-3」)
(D)リン酸エステル化合物
・D-1:トリフェニルホスフェート(大八化学社製「TPP」)
・D-2:トリクレジルホスフェート(大八化学社製「TCP」)
・D-3:トリクレジルホスファイト(大八化学社製「TXP」)
・D-4:クレジルキシレニルホスフェート(大八化学社製「PX-110」)
・D-5:レゾルシノールビス(ジキシレニルホスフェート)(大八化学社製「PX-200」)
・D-6:トリス(トリブロモネオペンチル)ホスフェート(大八化学社製「CR-900」)
・D-7:トリフェニルホスファイト(大八化学社製「TP-I」)
・D-8:ノンハロゲン系リン酸エステル(大八化学社製「DAIGUARD-1000」)
(E)脂肪酸金属塩
・E-1:ステアリン酸カルシウム(日東化成工業社製「Ca-St」)
・E-2:ステアリン酸マグネシウム(日東化成工業社製「Mg-St」)
・E-3:ステアリン酸アルミニウム(日東化成工業社製「Al-St」)
・E-4:ステアリン酸リチウム(日東化成工業社製「LI-ST」)
・E-5:ステアリン酸ナトリウム(日東化成工業社製「NA-ST」)
・E-6:12-ヒドロキシステアリン酸カルシウム(日東化成工業社製「CS-6」)
・E-7:ラウリン酸カルシウム(日東化成工業社製「CS-3」)
・E-8:ラウリン酸マグネシウム
・E-9:モンタン酸カルシウム(日東化成工業社製「CS-8」)
・E-10:モンタン酸マグネシウム(日東化成工業社製「MS-8」)
(F)熱安定剤
ビス(2,6-ジ-t-ブチル-4-メチルフェニル)ペンタエリスリトールジホスファイト(ADEKA社製「アデカスタブPEP-36」)
(G)難燃増強剤
・G:2,3-ジメチル-2,3-ジフェニルブタン(日油社製「ノフマーBC-90」)
(H)発泡剤
・H-1:イソブタン
・H-2:ジメチルエーテル
・H-3:二酸化炭素
(H)発泡核剤
・タルクMS(日本タルク工業(株)製)
後掲の表1に示す配合割合で発泡剤を除く各成分を、口径65mmの押出機に投入し、機内を200℃に加熱して溶融して可塑化し、混練を続けることで、押出機内でスチレン系樹脂組成物を調製した。押出機は、口径65mmから口径90mmに直列連結した二段押出機を使用した。各成分の配合量は、表1に示すように、成分(A)を100質量部、成分(B1)を0.6質量部、成分(B2)としてB2-1を2.4質量部、成分(C)としてC-1を0.03質量部、成分(D)としてD-1を0.7質量部、成分(E)としてE-1を0.1質量部、成分(F)を0.05質量部とした。
表1、表2、表3及び表4に示すように各成分の種類と配合量を変更したこと以外は実施例1と同様の方法で押出発泡成形体を得た。
後掲の表5に示すように各成分の種類と配合量を変更したこと以外は実施例1と同様の方法で押出発泡成形体を得た。
<難燃性>
JISK-7201に従って酸素指数を測定し、下記判断基準に基づいて難燃性能を評価した。
◎:酸素指数が30.0以上であり、特に優れた難燃性を有していた。
〇:酸素指数が29.0以上30.0未満であり、優れた難燃性を有していた。
×:酸素指数が29.0未満であり、優れた難燃性を有していなかった。
各実施例及び比較例で得られた発泡成形体の黄変度合い(YI:イエローインデックス)から、発泡成形体の耐熱性を評価した。具体的に、試験中の押出発泡成形体をカッターでスライスしてボードとし、2軸ロールで圧縮した後粉砕機で粗砕した。粗砕物をラボプラストミルに投入し、200℃で溶融混練後すぐ取り出して冷却プレスにて3.2mm厚の板状に成形した。このように得られた板状成形品を220℃の熱プレスにて40分加熱後、冷却プレスにて冷却した。冷却後の板状成形品を塩化メチレンに10質量%となるように溶解させ、溶解液を0.45μmのフィルターに通し濾過した後の溶解液を耐熱試験サンプルとした。該サンプルのYI値を、分光色差計(日本電色工業(株)製SE-6000)を用いた透過法にて測定し、下記判断基準に基づいて耐熱性能を評価した。
◎:YI値が10以下であり、特に優れた耐熱性を有していた。
〇:YI値が10を超え、15以下であり、優れた耐熱性を有していた。
×:YI値が15を超え、優れた耐熱性を有していなかった。
各実施例及び比較例で得られた発泡成形体の成形性については、下記判断基準に基づいて評価した。
〇:発泡体表面にボイド、突起物、異物及び変色はいずれも見られず、平滑で外観良好であった。
×:発泡体表面にボイド、突起物、異物及び変色の少なくともが一つが存在し、平滑さも外観も悪いものであった。
Claims (8)
- 少なくとも下記の成分(B1)、成分(C)及び成分(D)、
(B1)テトラブロモビスフェノールA-ビス(2,3-ジブロモ-2-メチルプロピルエーテル)、
(C)脂肪酸亜鉛、及び、
(D)リン酸エステル系化合物
を含み、
前記成分(B1)100質量部あたりの前記成分(C)の含有量が0.1~15質量部であり、
前記成分(B1)100質量部あたりの前記成分(D)の含有量が8~300質量部である、発泡スチレン樹脂用難燃剤組成物。 - 前記成分(B1)以外に難燃剤として成分(B2)を含有し、
前記成分(B2)は、含臭素難燃剤である、請求項1に記載の発泡スチレン樹脂用難燃剤組成物。 - 前記成分(B2)は、テトラブロモビスフェノールA-ビス(2,3-ジブロモプロピルエーテル)、トリス(2,3-ジブロモプロピル)イソシアヌレート、トリス(トリブロモフェノキシ)トリアジン、及び、臭素化エポキシオリゴマーからなる群より選択される少なくとも1種を含む、請求項1又は2に記載の発泡スチレン樹脂用難燃剤組成物。
- 前記成分(B1)及び前記成分(B2)の総量に対して、前記成分(B1)の含有割合が10~99質量%である、請求項2又は3に記載の発泡スチレン樹脂用難燃剤組成物。
- さらに下記の成分(E)、
(E)脂肪酸金属塩(ただし、前記(C)成分は除く)
を含む、請求項1~4のいずれか1項に記載の発泡スチレン樹脂用難燃剤組成物。 - 前記成分(B1)100質量部あたりの前記成分(E)の含有量が1~45質量部である、請求項5に記載の発泡スチレン樹脂用難燃剤組成物。
- 請求項1~6のいずれか1項に記載の発泡スチレン樹脂用難燃剤組成物と、成分(A)スチレン系樹脂とを含む、難燃性発泡スチレン系樹脂組成物。
- 請求項7に記載の難燃性発泡スチレン系樹脂組成物の押出発泡成形体。
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