JP2020164438A - Compound and thermoplastic resin composition and molded article containing the same - Google Patents

Abstract

To provide a compound having a high cost performance capable of imparting significant crystallization accelerating action to a thermoplastic resin even with a small amount of addition, an additive for a thermoplastic resin, an additive composition for a thermoplastic resin containing the same, a thermoplastic resin composition and a molded article.SOLUTION: There is provided a compound having a structure represented by the following general formula (1). In the general formula (1), X represents an alkylene group having 1 to 20 carbon atoms, an arylene group having 6 to 20 carbon atoms, a cycloalkylene group having 3 to 20 carbon atoms or a combination thereof, L1 and L2 represent a straight-chain alkylene group having 2 or 3 carbon atoms, R1 and R2 represent an alkyl group having 1 to 7 carbon atoms or a cycloalkyl group having 3 to 20 carbon atoms.SELECTED DRAWING: None

Description

The present invention relates to a novel compound, an additive for a thermoplastic resin, an additive composition for a thermoplastic resin containing the novel compound, and a thermoplastic resin composition (hereinafter, simply "additive" and "additive composition", respectively). , Also referred to as "resin composition"), and in detail, a compound capable of significantly accelerating the crystallization of a thermoplastic resin with a small amount of compounding, an additive for a thermoplastic resin, and heat containing the compound. The present invention relates to an additive composition for a plastic resin, a thermoplastic resin composition, and a molded product.

Thermoplastic resins such as polyethylene, polypropylene, and polybutene-1 are inexpensive and have excellent properties such as molding processability, hygiene, heat resistance, chemical resistance, mechanical properties, and low specific gravity, so that they are used for building materials, automobile materials, and home appliances. -Widely used for various molded products such as electronic materials, textile materials, packaging materials, agricultural materials, housing materials for home appliances, household goods, medical equipment, food containers, beverage containers, films, sheets and structural parts. ing.

However, in order to enable such a wide range of applications, it is necessary to satisfy the physical properties required for thermoplastic resins. It is known that crystallization of a thermoplastic resin during molding can be controlled by adding a specific compound or composition to the thermoplastic resin. In general, in a thermoplastic resin in which crystallization is promoted, advantages such as shortening of a molding cycle, heat resistance, and improvement of physical properties can be obtained.

Additives that promote the crystallization of thermoplastic resins are generally called "nuclear agents", but the higher the performance, the higher the price, which puts pressure on the profits of thermoplastic resin manufacturers. Therefore, a new nuclear agent with high cost performance is required.

For example, Patent Document 1 proposes a semi-crystalline polyolefin composition containing a di-alkylbis-oxalamide compound.

Japanese Unexamined Patent Publication No. 2013-32521

Patent Document 1 shows that a polyolefin composition in which a di-alkylbis-oxalamide compound is added to a resin containing no nucleating agent raises the crystallization temperature by 4 ° C. or more. However, the amount of the di-alkylbis-oxalamide compound added, which showed the effect, was as large as 0.2 parts by mass with respect to 100 parts by mass of the thermoplastic resin, and its cost performance was not satisfactory.

Therefore, an object of the present invention is a compound having high cost performance, which can impart a remarkable crystallization promoting action to a thermoplastic resin even with a small amount of addition, an additive for a thermoplastic resin, and heat containing the compound. It is an object of the present invention to provide an additive composition for a plastic resin, a thermoplastic resin composition, and a molded product.

As a result of diligent studies to solve the above problems, the present inventors have found that a compound having a novel structure having an amide bond can solve the above problems, and have completed the present invention.

上記一般式（１）中、Ｘは、炭素原子数１〜２０のアルキレン基、炭素原子数６〜２０のアリーレン基、炭素原子数３〜２０のシクロアルキレン基またはこれらの組み合わせを表し、
Ｌ^１およびＬ^２は、それぞれ、炭素原子数２または３の直鎖アルキレン基を表し、
Ｒ^１およびＲ^２は、それぞれ、炭素原子数１〜７のアルキル基または炭素原子数３〜２０のシクロアルキル基を表し、
Ｘで表されるアルキレン基並びにＲ^１およびＲ^２で表されるアルキル基は、直鎖でもよく、分岐を有するものであってもよく、Ｘで表されるアリーレン基、シクロアルキレン基並びにＲ^１およびＲ^２で表されるシクロアルキル基の水素原子は、炭素原子数１〜６のアルキル基、炭素原子数１〜６のアルコキシ基またはハロゲン原子で置換されていてもよい。 That is, the compound of the present invention is characterized by having a structure represented by the following general formula (1).

In the general formula (1), X represents an alkylene group having 1 to 20 carbon atoms, an arylene group having 6 to 20 carbon atoms, a cycloalkylene group having 3 to 20 carbon atoms, or a combination thereof.
L ¹ and L ² represent a linear alkylene group having 2 or 3 carbon atoms, respectively.
R ¹ and R ² represent an alkyl group having 1 to 7 carbon atoms or a cycloalkyl group having 3 to 20 carbon atoms, respectively.
The alkylene group represented by X and the alkyl group represented by R ¹ and R ² may be linear or have a branch, and the arylene group represented by X, the cycloalkylene group and R ¹ may be used. and the hydrogen atoms of the cycloalkyl group represented by R ² is an alkyl group having 1 to 6 carbon atoms, may be substituted by an alkoxy group or a halogen atom having 1 to 6 carbon atoms.

In the compound of the present invention, X in the general formula (1) is -A ^1- L ^3- A ^2- , -L ^4- A ^3- L ^5- (A ^{1 to} A ³ are carbons, respectively. It represents an arylene group having 6 to 20 atoms or a cycloalkylene group having 3 to 20 carbon atoms, and L ^{3 to} L ⁵ represent an alkylene group having 1 to 5 carbon atoms, respectively, and are represented by L ^{3 to} L ⁵ . The alkylene group to be formed may be linear or branched, and the hydrogen atoms of the arylene group and the cycloalkylene group represented by A ^{1 to} A ³ are alkyl groups having 1 to 6 carbon atoms and carbon atoms. It may be substituted with an alkoxy group having 1 to 6 atoms or a halogen atom), and an arylene group having 6 to 20 carbon atoms is preferably selected.

The additive for a thermoplastic resin of the present invention is characterized by containing the compound of the present invention.

The additive composition for a thermoplastic resin of the present invention comprises the additive for a thermoplastic resin of the present invention, a phenolic antioxidant, a phosphorus-based antioxidant, a sulfur-based antioxidant, an ultraviolet absorber, a hindered amine compound, and a nucleus. Contains one or more selected from the group consisting of agents, flame retardants, flame retardants, lubricants, fillers, hydrotalcites, fatty acid metal salts, antioxidants, fluorescent whitening agents, pigments and dyes. It is characterized by that.

The thermoplastic resin composition of the present invention is characterized by containing 0.001 to 10 parts by mass of the additive for a thermoplastic resin of the present invention with respect to 100 parts by mass of the thermoplastic resin.

In the thermoplastic resin composition of the present invention, it is preferable that the thermoplastic resin contains an olefin resin.

The molded article of the present invention is characterized by comprising the thermoplastic resin composition of the present invention.

The compound of the present invention is a novel compound, and can impart an excellent crystallization promoting action to a thermoplastic resin with a small amount of addition. Therefore, according to the present invention, a compound having high cost performance, which can impart a remarkable crystallization promoting action to a thermoplastic resin even with a small amount of addition, an additive for a thermoplastic resin, and heat containing the compound. Additive compositions for plastic resins, thermoplastic resin compositions and molded articles can be provided.

Hereinafter, embodiments of the present invention will be described in detail.

The compound of the present invention is characterized by having a structure represented by the following general formula (1).

Here, X in the general formula (1) represents an alkylene group having 1 to 20 carbon atoms, an arylene group having 6 to 20 carbon atoms, a cycloalkylene group having 3 to 20 carbon atoms, or a combination thereof. ,
L ¹ and L ² represent a linear alkylene group having 2 or 3 carbon atoms, respectively.
R ¹ and R ² represent an alkyl group having 1 to 7 carbon atoms or a cycloalkyl group having 3 to 20 carbon atoms, respectively.
The alkylene group represented by X and the alkyl group represented by R ¹ and R ² may be linear or have a branch, and the arylene group represented by X, the cycloalkylene group and R ¹ may be used. and the hydrogen atoms of the cycloalkyl group represented by R ² is an alkyl group having 1 to 6 carbon atoms, may be substituted by an alkoxy group or a halogen atom having 1 to 6 carbon atoms.

Examples of the alkylene group having 1 to 20 carbon atoms represented by X in the general formula (1) include a linear or branched alkylene group, for example, methylene, methylmethylene, dimethylmethylene, ethylene, propylene, and the like. Examples thereof include isopropylene, butylene, isobutylene, pentylene and heptylene. In the present invention, an alkylene group having 1 to 10 carbon atoms is preferable, and an alkylene group having 1 to 3 carbon atoms is more preferable.

Examples of the arylene group having 6 to 20 carbon atoms represented by X in the general formula (1) include phenylene, 3,4,5-trimethoxyphenylene, 4-tert-butylphenylene, biphenylene, naphthylene, and methyl. Examples thereof include naphthylene, anthracenylene, phenylene and the like, and the hydrogen atom in the arylene group may be substituted with an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or a halogen atom.

Examples of the cycloalkylene group having 3 to 20 carbon atoms represented by X in the general formula (1) include cyclopropylene, cyclopentylene, cyclohexylene, cycloheptyrene, cyclooctylene, cyclononylene, cyclodecylene and the like. , The hydrogen atom in the cycloalkylene group may be substituted with an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or a halogen atom.

Examples of the alkyl group having 1 to 7 carbon atoms represented by R ¹ and R ² in the general formula (1) include a linear or branched alkyl group, for example, methyl, ethyl, propyl, isopropyl, and the like. Examples thereof include butyl, isobutyl, sec-butyl, tert-butyl, heptyl, isoheptyl, hexyl and the like. In the present invention, an alkyl group having 1 to 5 carbon atoms is preferable, and an alkyl group having 2 to 4 carbon atoms is more preferable. Alkyl groups having 8 or more carbon atoms may not be able to obtain the effects of the present invention.

Examples of the cycloalkyl group having 3 to 20 carbon atoms represented by R ¹ and R ² in the general formula (1) include cyclopropyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl, cyclodecyl and the like. The hydrogen atom in the cycloalkyl group may be substituted with an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or a halogen atom.

Examples of the alkyl group having 1 to 6 carbon atoms substituting the hydrogen atom in the arylene group, cycloalkylene group and cycloalkyl group include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl and tert-. Butyl, hexyl and the like can be mentioned. Examples of the alkoxy group having 1 to 6 carbon atoms substituting the hydrogen atom in the arylene group, cycloalkylene group and cycloalkyl group include alkoxy corresponding to the alkyl group such as methoxy, ethoxy, propoxy, isopropoxy and butoxy. The group is mentioned. Examples of the halogen atom that replaces the hydrogen atom in the arylene group, cycloalkylene group and cycloalkyl group include fluorine, chlorine, bromine and iodine, but chlorine is particularly preferable in the present invention.

In the compound of the present invention, in particular, X in the general formula (1) is −A ¹ −L ³ −A ² −, −L ⁴ −A ³ −L ⁵ − (A ^{1 to} A ³ are respectively. Representing an arylene group having 6 to 20 carbon atoms or a cycloalkylene group having 3 to 20 carbon atoms, L ^{3 to} L ⁵ represent an alkylene group having 1 to 5 carbon atoms, respectively, and L ^{3 to} L ⁵ The represented alkylene group may have a linear or branched structure, and the hydrogen atoms of the arylene group and the cycloalkylene group represented by A ^{1 to} A ³ are alkyl groups having 1 to 6 carbon atoms. It may be substituted with an alkoxy group or a halogen atom having 1 to 6 carbon atoms), and an arylene group having 6 to 20 carbon atoms is preferably selected.

Examples of the arylene group having 6 to 20 carbon atoms and the cycloalkylene group having 3 to 20 carbon atoms represented by A ^{1 to} A ³ are the same as those described above.

Examples of the alkylene group having 1 to 5 carbon atoms represented by L ^{3 to} L ⁵ include methylene, methyl methylene, dimethyl methylene, ethylene, propylene, isopropylene, butylene, isobutylene, pentylene and the like. In the present invention, among them, an alkylene group having 1 to 3 carbon atoms is preferable.

The compound of the present invention can be easily produced, for example, by reacting a dicarboxylic acid anhydride with an amine. A dicarboxylic acid anhydride selected from succinic anhydride or glutaric anhydride is reacted with an alkylamine or a cycloalkylamine, and further, aryldiamine, cycloalkyldiamine, aryldialkylamine, alkylenedianiline or alkylenebis ( The compound of the present invention can be produced by reacting with cyclohexylamine). The compound of the present invention is characterized in that it has a tetraamide structure.

Examples of the alkylamine include ethylamine, propylamine, butylamine, isobutylamine, sec-butylamine, tert-butylamine, heptylamine, hexylamine and the like. In the present invention, an alkylamine having an alkyl group having 1 to 7 carbon atoms is preferable, and an alkylamine having 3 to 5 carbon atoms is more preferable.

Examples of the cycloalkylamine include cycloalkylamines such as cyclopropylamine, cyclobutylamine, cycloheptylamine, and cyclohexylamine. In the present invention, an amine having a cycloalkyl group having 3 to 20 carbon atoms is preferable, and a cycloalkylamine having a cycloalkyl group having 5 to 9 carbon atoms is more preferable.

Examples of the aryldiamine include 1,4-benzenediamine, 1,3-benzenediamine, naphthalene-1,5-diamine, naphthalene-2,6-diamine and the like.

Examples of the cycloalkyldiamine include 1,4-cyclohexyldiamine and 1,3-cyclohexyldiamine.

Examples of the aryldialkylamine include 1,3-phenylenedimethaneamine, 1,4-phenylenedimethaneamine, 1,3-phenylenediethaneamine, 1,4-phenylenediethaneamine, and 1,3-phenylenediamine. Range Propanamine, 2,2'-naphthalene-1,5-diyl) bis (methaneamine), 2,2'-(naphthalen-1,5-diyl) bis (ethane-1-amine), 2,2'- (Naphthalene-2,6-diyl) bis (methaneamine) and the like can be mentioned.

Examples of the alkylenedianiline include methylene dianiline, ethylene dianiline, propylene dianiline, butyrene aniline, 4,4'-methylenebis (2,6-diethylaniline) and the like.

Examples of the alkylene bis (cyclohexylamine) include 4,4'-methylenebis (cyclohexane-1-amine), 4,4'-ethylenebis (cyclohexane-1-amine), and 4,4'-methylenebis (2,). 6-Methylcyclohexane-1-amine) and the like.

The reaction between the carboxylic acid anhydride and the amine is preferably carried out by using a catalyst such as pyridine, N, N'-dimethylaminopyridine because the yield is improved.

The additive for a thermoplastic resin of the present invention is characterized by containing the compound of the present invention.

Specific examples of the additive of the present invention include the following. However, the present invention is not limited to these compounds.

The additive of the present invention is an additive to be blended with a thermoplastic resin, and can be used in combination with other additives to be blended with a thermoplastic resin. In this case, the additive of the present invention and other additives may be added to the thermoplastic resin separately, or the additive of the present invention and other additives may be mixed to form an additive composition for a thermoplastic resin. It may be used as a thing. The blending amount of the additive of the present invention can be used without particular limitation, but the additive of the present invention is blended in the range of 0.001 to 10 parts by mass with respect to 100 parts by mass of the thermoplastic resin. It is preferable that the amount is in the range of 0.005 part by mass to 1 part by mass. However, when the additive of the present invention is used as a masterbatch containing a high concentration, the blending amount of the additive of the present invention may exceed 10 parts by mass of the upper limit value.

Other additives that can be used in combination with the additives of the present invention are not particularly limited as long as the effects of the additives of the present invention are not significantly impaired or the performance of the obtained resin composition is not significantly impaired. .. Such other additives include additives commonly used in thermoplastic resins, such as phenolic antioxidants, phosphorus antioxidants, sulfur antioxidants, UV absorbers, hindered amine compounds, nuclei. Agents, flame retardants, flame retardants, lubricants, fillers, hydrotalcites, fatty acid metal salts, antistatic agents, optical brighteners, pigments, dyes, etc., and one or more selected from these. Can be used. When the additive of the present invention is blended as an additive exhibiting any of the above functions in combination with another additive having the function, the additive of the present invention and the other additive having the function are used. It is preferable that the total amount of the above is blended so as to be present in an appropriate concentration with respect to the thermoplastic resin.

Examples of the phenolic antioxidant include 2,6-di-tert-butyl-4-ethylphenol, 2-tert-butyl-4,6-dimethylphenol, styrene phenol, and 2,2'-methylenebis (4). -Ethyl-6-tert-butylphenol), 2,2'-thiobis- (6-tert-butyl-4-methylphenol), 2,2'-thiodiethylenebis [3- (3,5-di-tert-) Butyl-4-hydroxyphenyl) propionate], 2-methyl-4,6-bis (octylsulfanylmethyl) phenol, 2,2'-isobutylidenebis (4,6-dimethylphenol), isooctyl-3- (3) , 5-Di-tert-butyl-4-hydroxyphenyl) propionate, N, N'-hexane-1,6-diylbis [3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionamide, 2,2'-Oxamide-bis [ethyl-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate], 2-ethylhexyl-3- (3', 5'-di-tert-butyl) -4'-Hydroxyphenyl) propionate, 2,2'-ethylenebis (4,6-di-tert-butylphenol), 3,5-di-tert-butyl-4-hydroxy-benzenepropanoic acid and C13-15 alkyl , 2,5-Di-tert-amylhydroquinone, a polymer of hindered phenol (ADEKA POLYMER ADDITIVES EUROPE SAS trade name "AO.OH.98"), 2,2'-methylenebis [6- (1) -Methylcyclohexyl) -p-cresol], 2-tert-butyl-6- (3-tert-butyl-2-hydroxy-5-methylbenzyl) -4-methylphenylacrylate, 2- [1- (2-hydroxy) -3,5-di-tert-pentylphenyl) ethyl] -4,6-di-tert-pentylphenyl acrylate, 6- [3- (3-tert-butyl-4-hydroxy-5-methyl) propoxy]- 2,4,8,10-tetra-tert-butylbenz [d, f] [1,3,2] -dioxaphosphobin, hexamethylenebis [3- (3,5-di-tert-butyl-4) -Hydroxyphenyl) propionate, bis [monoethyl (3,5-di-tert-butyl-4-hydroxybenzyl) phosphonate] calcium salt, 5, Reaction product of 7-bis (1,1-dimethylethyl) -3-hydroxy-2 (3H) -benzofuranone and o-xylene, 2,6-di-tert-butyl-4- (4,6-bis) (Octylthio) -1,3,5-triazin-2-ylamino) phenol, DL-a-tocophenol (vitamin E), 2,6-bis (α-methylbenzyl) -4-methylphenol, bis [3, 3-Bis- (4'-hydroxy-3'-tert-butyl-phenyl) butanoic acid] glycol ester, 2,6-di-tert-butyl-p-cresol, 2,6-diphenyl-4-octadeciloxy Phenol, stearyl (3,5-di-tert-butyl-4-hydroxyphenyl) propionate, distearyl (3,5-di-tert-butyl-4-hydroxybenzyl) phosphonate, tridecyl-3,5-tert-butyl -4-Hydroxybenzylthioacetate, thiodiethylenebis [(3,5-di-tert-butyl-4-hydroxyphenyl) propionate], 4,4'-thiobis (6-tert-butyl-m-cresol), 2 -Octylthio-4,6-di (3,5-di-tert-butyl-4-hydroxyphenoxy) -s-triazine, 2,2'-methylenebis (4-methyl-6-tert-butylphenol), bis [3 , 3-Bis (4-hydroxy-3-tert-butylphenyl) butyric acid] glycol ester, 4,4'-butylidenebis (2,6-di-tert-butylphenol), 4,4'-butylidenebis (6- tert-Butyl-3-methylphenol), 2,2'-ethylidenebis (4,6-di-tert-butylphenol), 1,1,3-tris (2-methyl-4-hydroxy-5-tert-butyl) Phenyl) butane, bis [2-tert-butyl-4-methyl-6- (2-hydroxy-3-tert-butyl-5-methylbenzyl) phenyl] terephthalate, 1,3,5-tris (2,6-tris) Dimethyl-3-hydroxy-4-tert-butylbenzyl) isocyanurate, 1,3,5-tris (3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate, 1,3,5-tris ( 3,5-Di-tert-butyl-4-hydroxybenzyl) -2,4,6-trimethylbenzene, 1,3,5-tris [(3,5-di-tert-butyl-4-hydroxyphenyl) ) Propionyloxyethyl] isocyanurate, tetrakis [methylene-3- (3', 5'-di-tert-butyl-4'-hydroxyphenyl) propionate] methane, 2-tert-butyl-4-methyl-6- ( 2-Acryloyloxy-3-tert-butyl-5-methylbenzyl) phenol, 3,9-bis [2- (3-tert-butyl-4-hydroxy-5-methylhydrocinnamoyloxy) -1,1- Dimethylethyl] -2,4,8,10-tetraoxaspiro [5.5] undecane, triethylene glycolbis [β- (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate], stearyl- 3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid amide, palmityl-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid amide, myristyl-3-3 3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid amide, lauryl-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid amide, etc. Examples thereof include 5-dialkyl-4-hydroxyphenyl) propionic acid derivatives.
When the phenolic antioxidant is blended, the blending amount may be adjusted to 0.001 to 5 parts by mass, particularly 0.03 to 3 parts by mass with respect to 100 parts by mass of the thermoplastic resin. preferable.

Examples of phosphorus-based antioxidants include triphenylphosphite, diisooctylphosphite, heptakis (dipropylene glycol) triphosphite, triisodecylphosphite, diphenylisooctylphosphite, diisooctylphenylphosphite, and diphenyl. Tridecylphosphite, triisooctylphosphite, trilaurylphosphite, diphenylphosphite, tris (dipropylene glycol) phosphite, dioleylhydrogenphosphite, trilauryltrithiophosphite, bis (tridecyl) phosphite, tris (Isodecyl) phosphite, tris (tridecyl) phosphite, diphenyldecylphosphite, dinonylphenylbis (nonylphenyl) phosphite, poly (dipropylene glycol) phenylphosphite, tetraphenyldipropylglycoldiphosphite, trisnonyl Phenylphosphite, tris (2,4-di-tert-butylphenyl) phosphite, tris (2,4-di-tert-butyl-5-methylphenyl) phosphite, tris [2-tert-butyl-4- (3-tert-Butyl-4-hydroxy-5-methylphenylthio) -5-methylphenyl] phosphite, tri (decyl) phosphite, octyldiphenylphosphite, di (decyl) monophenylphosphite, distearylpenta Mixture of erythritol and calcium stearate, alkyl (C10) bisphenol A phosphite, tetraphenyl-tetra (tridecyl) pentaerythritol tetraphosphite, bis (2,4-di-tert-butyl-6-methylphenyl) ethylphos Fight, tetra (tridecyl) isopropyridene diphenol diphosphite, tetra (tridecyl) -4,4'-n-butylidenebis (2-tert-butyl-5-methylphenol) diphosphite, hexa (tridecyl) -1,1, 3-Tris (2-methyl-4-hydroxy-5-tert-butylphenyl) butanetriphosphite, tetrakis (2,4-di-tert-butylphenyl) biphenylenediphosphonite, 9,10-dihydro-9-oxa -10-Phosphaphenanthrene-10-oxide, (1-methyl-1-propenyl-3-ylidene) tris (1,1-dimethylethyl) -5-methyl-4,1-phenylene) hexato Redesylphosphite, 2,2'-methylenebis (4,6-di-tert-butylphenyl) -2-ethylhexylphosphite, 2,2'-methylenebis (4,6-di-tert-butylphenyl) -octadecyl Phosphite, 2,2'-ethylidenebis (4,6-di-tert-butylphenyl) fluorophosphite, 4,4'-butylidenebis (3-methyl-6-tert-butylphenylditridecyl) phosphite, tris (2-[(2,4,8,10-tetrakiss-tert-butyldibenzo [d, f] [1,3,2] dioxaphosfepin-6-yl) oxy] ethyl) amine, 3,9 -Bis (4-nonylphenoxy) -2,4,8,10-tetraoxa-3,9-diphosphespiro [5,5] undecane, 2,4,6-tri-tert-butylphenyl-2-butyl -2-Ethyl-1,3-propanediol phosphite, poly 4,4'-isopropyridene diphenol C12-15 alcohol phosphite, bis (diisodecyl) pentaerythritol diphosphite, bis (tridecyl) pentaerythritol diphosphite , Bis (octadecyl) pentaerythritol diphosphite, bis (nonylphenyl) pentaerythritol diphosphite, bis (2,4-di-tert-butylphenyl) pentaerythritol diphosphite, bis (2,4,6-tri) -Tert-Butylphenyl) pentaerythritol diphosphite, bis (2,6-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphite, bis (2,4-dicumylphenyl) pentaerythritol diphosphite And so on.
When the phosphorus-based antioxidant is blended, the blending amount is adjusted to 0.001 to 10 parts by mass, particularly 0.01 to 0.5 parts by mass with respect to 100 parts by mass of the thermoplastic resin. Is preferable.

Examples of the sulfur-based antioxidant include tetrakis [methylene-3- (laurylthio) propionate] methane and bis (methyl-4- [3-n-alkyl (C12 / C14) thiopropionyloxy] 5-tert-butylphenyl. ) Sulfide, ditridecyl-3,3'-thiodipropionate, dilauryl-3,3'-thiodipropionate, dimyristyl-3,3'-thiodipropionate, distearyl-3,3'-thiodipropio Nate, lauryl / stearylthiodipropionate, 4,4'-thiobis (6-tert-butyl-m-cresol), 2,2'-thiobis (6-tert-butyl-p-cresol), distearyl-di Sulfuride can be mentioned.
When the sulfur-based antioxidant is blended, the blending amount is adjusted to 0.001 to 10 parts by mass, particularly 0.01 to 0.5 parts by mass with respect to 100 parts by mass of the thermoplastic resin. Is preferable.

Examples of the ultraviolet absorber include 2-hydroxybenzophenones such as 2,4-dihydroxybenzophenone and 5,5'-methylenebis (2-hydroxy-4-methoxybenzophenone); 2- (2-hydroxy-5-methylphenyl). ) Bentriazole, 2- (2-hydroxy-5-tert-octylphenyl) benzotriazole, 2- (2-hydroxy-3,5-di-tert-butylphenyl) -5-chlorobenzotriazole, 2- (2) -Hydroxy-3-tert-butyl-5-methylphenyl) -5-chlorobenzotriazole, 2- (2-hydroxy-3,5-dikmylphenyl) benzotriazole, 2,2'-methylenebis (4-tert- Octyl-6-benzotriazolylphenol), 2- (2-hydroxy-3-tert-butyl-5-carboxyphenyl) benzotriazole polyethylene glycol ester, 2- [2-hydroxy-3- (2-acryloyloxy) Ethyl) -5-methylphenyl] benzotriazole, 2- [2-hydroxy-3- (2-methacryloyloxyethyl) -5-tert-butylphenyl] benzotriazole, 2- [2-hydroxy-3- (2-) Methacryloyloxyethyl) -5-tert-octylphenyl] benzotriazole, 2- [2-hydroxy-3- (2-methacryloyloxyethyl) -5-tert-butylphenyl] -5-chlorobenzotriazole, 2- [2 -Hydroxy-5- (2-methacryloyloxyethyl) phenyl] benzotriazole, 2- [2-hydroxy-3-tert-butyl-5- (2-methacryloyloxyethyl) phenyl] benzotriazole, 2- [2-hydroxy -3-tert-Amil-5- (2-methacryloyloxyethyl) phenyl] benzotriazole, 2- [2-hydroxy-3-tert-butyl-5- (3-methacryloyloxypropyl) phenyl] -5-chlorobenzo Triazole, 2- [2-hydroxy-4- (2-methacryloyloxymethyl) phenyl] benzotriazole, 2- [2-hydroxy-4- (3-methacryloyloxy-2-hydroxypropyl) phenyl] benzotriazole, 2- [2-Hydroxy-4- (3-methacryloyloxypropyl) phenyl] 2- (2-hydroxyphenyl) benzotriazoles such as benzotriazole; Substituted oxanilides such as phenylsalicylate, resorcinol monobenzoate, 2-ethyl-2'-ethoxyoxanilide, 2-ethoxy-4'-dodecyloxanilide; ethyl-α-cyano-β, β-diphenylacrylate, methyl Cyanoacrylates such as -2-cyano-3-methyl-3- (p-methoxyphenyl) acrylate; 2- (4,6-diphenyl-1,3,5-triazine-2-yl) -5-hexyloxy Phenol, 2- (2-hydroxy-4-octoxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, trioctyl-2,2', 2''-( (1,3,5-triazine-2,4,6-triyl) Tris (3-hydroxybenzene-4-,1-diyl) tripropionate), 2- (4,6-diphenyl-1,3,5 -Triazine-2-yl) -5- [2- (2-ethylhexanoyloxy) ethoxy] phenol, 2,4,6-tris (2-hydroxy-4-hexyloxy-3-methylphenyl) -1, Triazines such as 3,5-triazine, 1,12-bis [2- [4- (4,6-diphenyl-1,3,5-triazine-2-yl) -3-hydroxyphenoxy] ethyl] dodecandioate. Kind: Various metal salts or metal chelate, especially nickel, chromium salts, or chelates and the like.
When blending the ultraviolet absorber, the blending amount may be adjusted to 0.001 to 10 parts by mass, particularly 0.01 to 0.5 parts by mass, with respect to 100 parts by mass of the thermoplastic resin. preferable.

Examples of the hindered amine compound include 2,2,6,6-tetramethyl-4-piperidyl stearate, 1,2,2,6,6-pentamethyl-4-piperidyl stearate, 2,2,6,6- Tetramethyl-4-piperidylbenzoate, bis (2,2,6,6-tetramethyl-4-piperidyl) sebacate, tetrakis (2,2,6,6-tetramethyl-4-piperidyl) -1,2,3 , 4-Butan tetracarboxylate, tetrakis (1,2,2,6,6-pentamethyl-4-piperidyl) -1,2,3,4-butanetetracarboxylate, bis (2,2,6,6- Tetramethyl-4-piperidyl) di (tridecyl) -1,2,3,4-butanetetracarboxylate, bis (1,2,2,6,6-pentamethyl-4-piperidyl) -di (tridecyl)- 1,2,3,4-butanetetracarboxylate, bis (1,2,2,4,4-pentamethyl-4-piperidyl) -2-butyl-2- (3,5-di-tert-butyl-4) -Hydroxybenzyl) malonate, 1- (2-hydroxyethyl) -2,2,6,6-tetramethyl-4-piperidinol / diethyl polycondensate succinate, 1,6-bis (2,2,6) , 6-Tetramethyl-4-piperidylamino) hexane / 2,4-dichloro-6-morpholino-s-triazine polycondensate, 1,6-bis (2,2,6,6-tetramethyl-4-piperidyl) Amino) hexane / 2,4-dichloro-6-tert-octylamino-s-triazine polycondensate, 1,5,8,12-tetrakis [2,4-bis (N-butyl-N- (2,2)) , 6,6-tetramethyl-4-piperidyl) amino) -s-triazine-6-yl] -1,5,8,12-tetraazadodecane, 1,5,8,12-tetrakis [2,4- Bis (N-butyl-N- (1,2,2,6,6-pentamethyl-4-piperidyl) amino) -s-triazine-6-yl] -1,5,8-12-tetraazadodecane, 1, , 6,11-Tris [2,4-bis (N-butyl-N- (2,2,6,6-tetramethyl-4-piperidyl) amino) -s-triazine-6-yl] aminoundecane, 1, , 6,11-Tris [2,4-bis (N-butyl-N- (1,2,2,6,6-pentamethyl-4-piperidyl) amino) -s-triazine-6-yl] aminoundecane, Bis {4- (1-octyloxy-2,2,6,6- Examples thereof include tetramethyl) piperidyl} decandionate and bis {4- (2,2,6,6-tetramethyl-1-undecyloxy) piperidyl} carbonate.
When the hindered amine compound is blended, the blending amount is preferably adjusted to 0.001 to 10 parts by mass, particularly 0.01 to 0.5 parts by mass with respect to 100 parts by mass of the thermoplastic resin. ..

Nuclear agents include, for example, sodium-2,2'-methylenebis (4,6-di-tert-butylphenyl) phosphate, sodium benzoate, 4-tert-butyl benzoate aluminum salt, sodium adipate and disodium dicyclodi. [2.2.1] Carboxylic acid metal salts such as heptane-2,3-dicarboxylate, dibenzylene sorbitol, bis (methylbenzylene) sorbitol, bis (3,4-dimethylbenzylene) sorbitol, bis (p-ethyl) Polyol derivatives such as benzylene) sorbitol and bis (dimethylbenzylene) sorbitol, N, N', N''-tris [2-methylcyclohexyl] -1,2,3-propanetricarboxamide, N, N', N' Examples thereof include amide compounds such as'-tricyclohexyl-1,3,5-benzenetricarboxamide, N, N'-dicyclohexylnaphthalenedicarboxamide, and 1,3,5-tri (dimethylisopropoylamino) benzene. ..
When the nucleating agent is blended, the blending amount is preferably adjusted to be in the range of 0.005 to 5 parts by mass, particularly 0.01 to 1 part by mass with respect to 100 parts by mass of the thermoplastic resin. ..

Examples of the flame retardant include triphenyl phosphate, tricresyl phosphate, trixylenyl phosphate, cresyldiphenyl phosphate, cresyl-2,6-dixylenyl phosphate, resorcinolbis (diphenyl phosphate), (1-methylethylidene). -4,1-Phenylenetetraphenyldiphosphate, 1,3-phenylenetetrakis (2,6-dimethylphenyl) phosphate, manufactured by ADEKA Co., Ltd. Brand names "Adecastab FP-500", "Adecastab FP-600", "Adecastab FP" -800 "aromatic phosphoric acid ester, phosphonic acid ester such as divinyl phenylphosphonate, diallyl phenylphosphonate, phenylphosphonic acid (1-butenyl), phenyl diphenylphosphinate, methyl diphenylphosphinate, 9,10-dihydro- Phenyl acid esters such as 9-oxa-10-phosphaphenanthrene-10-oxide derivatives, phosphazene compounds such as bis (2-allylphenoxy) phosphazene, dicredylphosphazene, melamine phosphate, melamine pyrophosphate, melamine polyphosphate, polyline Phenyl retardants such as melam acid, ammonium polyphosphate, piperazine phosphate, piperazine pyrophosphate, piperazine polyphosphate, phosphorus-containing vinylbenzyl compounds and red phosphorus, metal hydroxides such as magnesium hydroxide and aluminum hydroxide, brominated Bisphenol A type epoxy resin, brominated phenol novolac type epoxy resin, hexabromobenzene, pentabromotoluene, ethylenebis (pentabromophenyl), ethylenebistetrabromophthalimide, 1,2-dibromo-4- (1,2-dibromo) Ethyl) cyclohexane, tetrabromocyclooctane, hexabromocyclododecane, bis (tribromophenoxy) ethane, brominated polyphenylene ether, brominated polystyrene and 2,4,6-tris (tribromophenoxy) -1,3,5- Examples thereof include triazine, tribromophenylmaleimide, tribromophenyl acrylate, tribromophenyl methacrylate, tetrabromobisphenol A type dimethacrylate, pentabromobenzyl acrylate, and brominated flame retardants such as brominated styrene. These flame retardants are preferably used in combination with a drip inhibitor such as fluororesin and a flame retardant aid such as polyhydric alcohol and hydrotalcite.
When the flame retardant is blended, the blending amount is preferably adjusted to 1 to 100 parts by mass, particularly 10 to 70 parts by mass with respect to 100 parts by mass of the thermoplastic resin.

The lubricant is added for the purpose of imparting slipperiness to the surface of the molded product and enhancing the scratch-preventing effect. Examples of the lubricant include unsaturated fatty acid amides such as oleic acid amide and stearic acid amide; saturated fatty acid amides such as bechenic acid amide and stearic acid amide, butyl stearate, stearyl alcohol, stearic acid monoglyceride, and sorbitan monopalmitite. Examples thereof include sorbitan monostearate, mannitol, stearic acid, hardened castor oil, stearic acid amide, oleic acid amide, and ethylene bisstearic acid amide. One of these may be used alone, or two or more thereof may be used in combination.
When the lubricant is blended, the blending amount is preferably adjusted to 0.01 to 2 parts by mass, particularly 0.03 to 1 part by mass with respect to 100 parts by mass of the thermoplastic resin.

Examples of the filler include talc, mica, calcium carbonate, calcium oxide, calcium hydroxide, magnesium carbonate, magnesium hydroxide, magnesium oxide, magnesium sulfate, aluminum hydroxide, barium sulfate, glass powder, glass fiber, clay, and dolomite. , Silica, Alumina, Potassium Titanium Whisker, Wallastenite, Fibrous Magnesium Oxysulfate and the like, and the particle size (fiber diameter, fiber length and aspect ratio in the fibrous form) can be appropriately selected and used. .. One of these may be used alone, or two or more thereof may be used in combination. Further, as the filler, a surface-treated filler can be used if necessary.
When the filler is blended, the blending amount is preferably 1 to 80 parts by mass, more preferably 3 to 50 parts by mass, and further preferably 5 to 40 parts by mass with respect to 100 parts by mass of the thermoplastic resin.

ここで、一般式（２）中、ｘ１およびｘ２はそれぞれ下記式、
０≦ｘ２／ｘ１＜１０，２≦ｘ１＋ｘ２≦２０
で表される条件を満たす数を表し、ｐは０または正の数を表す。

ここで、一般式（３）中、Ａ^ｑ−は、ｑ価のアニオンを表し、ｐは０または正の数を表す。 Hydrotalcites are complex salt compounds consisting of magnesium, aluminum, hydroxyl groups, carbonate groups and arbitrary crystalline water known as natural products and synthetic products, and magnesium or a part of aluminum is used as an alkali metal or zinc. Examples thereof include those substituted with a metal and those in which a hydroxyl group and a carbonate group are substituted with another anionic group. Specifically, for example, the metal of hydrotalcite represented by the following general formula (2) is replaced with an alkali metal. The replaced one can be mentioned. Further, as the Al-Li-based hydrotalcites, a compound represented by the following general formula (3) can also be used.

Here, in the general formula (2), x1 and x2 are the following formulas, respectively.
0 ≦ x2 / x1 <10,2 ≦ x1 + x2 ≦ 20
Represents a number satisfying the condition represented by, and p represents 0 or a positive number.

Here, in the general formula (3), A ^{q −} represents a q-valent anion, and p represents 0 or a positive number.

Further, the carbonate anion in the above hydrotalcites may be partially replaced with another anion.

Hydrotalcites may be obtained by dehydrating crystalline water, and are higher fatty acids such as stearic acid, higher fatty acid metal salts such as oleic acid alkali metal salts, and organic sulfonic acid metals such as dodecylbenzene sulfonic acid alkali metal salts. It may be coated with a salt, a higher fatty acid amide, a higher fatty acid ester, a wax or the like.

The hydrotalcites may be natural products or synthetic products. Examples of the method for synthesizing this compound include Japanese Patent Publication No. 46-2280, Japanese Patent Publication No. 50-30039, Japanese Patent Publication No. 51-29129, Japanese Patent Publication No. 3-36839, Japanese Patent Application Laid-Open No. 61-174270. Known methods described in Kaihei 5-179052 and the like can be mentioned. Further, the hydrotalcites can be used without being limited by their crystal structure, crystal particles and the like.
When hydrotalcites are blended, the blending amount is preferably adjusted to 0.001 to 5 parts by mass, particularly 0.01 to 3 parts by mass with respect to 100 parts by mass of the thermoplastic resin. ..

上記一般式（４）中、Ｒ^５は、直鎖または分岐状の炭素原子数１２〜２０の脂肪酸を表し、脂肪酸は水酸基で置換されていてもよい。Ｍ^２は、１〜３価の金属原子を表し、２価以上の金属原子はヒドロキシ基を有していてもよく、ｍは、１〜３の整数を表す。 The fatty acid metal salt is preferably a metal salt of lauric acid, myristic acid, palmitic acid, stearic acid, or 12-hydroxystearic acid, and the metal of the fatty acid metal salt is sodium, potassium, lithium, calcium, zinc, barium, etc. Examples thereof include magnesium and hydroxyaluminum, with sodium, lithium and potassium being more preferred. From the viewpoint of heat resistance and the effect of dispersing the additive of the present invention in the resin, the compound represented by the following general formula (4) is preferable.

In the above general formula (4), R ⁵ represents a linear or branched fatty acid having 12 to 20 carbon atoms, and the fatty acid may be substituted with a hydroxyl group. M ² represents a metal atom having a valence of 1 to 3, a metal atom having a valence of 2 or more may have a hydroxy group, and m represents an integer of 1 to 3.

Examples of the antistatic agent include a low molecular weight antistatic agent using a nonionic, anionic, cationic or amphoteric surfactant, and a high molecular weight antistatic agent using a polymer compound. Nonionic surfactants include polyethylene glycol-type nonionic surfactants such as higher alcohol ethylene oxide adducts, fatty acid ethylene oxide adducts, higher alkylamine ethylene oxide adducts, and polypropylene glycol ethylene oxide adducts; fatty acid esters of polyethylene oxide and glycerin. , Pentaerislit fatty acid ester, sorbit or sorbitan fatty acid ester, polyhydric alcohol alkyl ether, polyhydric alcohol type nonionic surfactant such as aliphatic amide of alkanolamine, etc., and examples thereof include anionic surfactants. Is, for example, a carboxylate such as an alkali metal salt of a higher fatty acid; a sulfate ester salt such as a higher alcohol sulfate ester salt, a higher alkyl ether sulfate ester salt, an alkylbenzene sulfonate, an alkyl sulfonate, a paraffin sulfonate, etc. Sulfates; Phosphates such as higher alcohol phosphates and the like can be mentioned, and examples of cationic surfactants include quaternary ammonium salts such as alkyltrimethylammonium salts. Examples of the amphoteric surfactant include amino acid-type amphoteric surfactants such as higher alkylaminopropionate, betaine-type amphoteric surfactants such as higher alkyldimethylbetaine and higher alkyldihydroxyethyl betaine, and the like. Anionic surfactants are preferable, and sulfonates such as alkylbenzene sulfonates, alkyl sulfonates, and paraffin sulfonates are particularly preferable.
When the low molecular weight antistatic agent is blended, the blending amount should be adjusted to 0.1 to 10 parts by mass, particularly 0.5 to 5 parts by mass with respect to 100 parts by mass of the thermoplastic resin. Is preferable.

Examples of the polymer-type antistatic agent include ionomer and a block polymer having polyethylene glycol as a hydrophilic portion. Examples of the ionomer include the ionomer described in JP-A-2010-132927. Examples of the polymer having polyethylene glycol as a hydrophilic portion include a polyether ester amide described in JP-A-7-10989, a polymer composed of polyolefin and polyethylene glycol described in US Pat. No. 6,552,131, and JP-A-2016-023254. Examples thereof include the polymer composed of polyester and polyethylene glycol described in the publication.
When the polymer type antistatic agent is blended, the blending amount is 3 to 60 parts by mass, particularly 5 to 25 parts by mass, and particularly 7 to 20 parts by mass with respect to 100 parts by mass of the thermoplastic resin. It is preferable to adjust to.

The fluorescent whitening agent is a compound that absorbs ultraviolet rays of sunlight or artificial light, converts them into visible light of purple to blue and radiates them, thereby promoting the whiteness and bluish tint of the molded product. Examples of the fluorescent whitening agent include benzoxazole compounds C.I. I. Fluorescent Fluorescenter 184; Coumarin-based compound C.I. I. Fluorescent Fluorescent 52; diaminostilbene disulphonic acid-based compound C.I. I. Fluorescent Fluorescenter 24, 85, 71 and the like can be mentioned.
When the fluorescent whitening agent is used, the blending amount is adjusted to 0.00001 to 0.1 parts by mass, particularly 0.00005 to 0.05 parts by mass with respect to 100 parts by mass of the thermoplastic resin. Is preferable.

As the pigment, a commercially available pigment may be used, for example, Pigment Red 1, 2, 3, 9, 10, 17, 22, 23, 31, 38, 41, 48, 49, 88, 90, 97, 112. , 119, 122, 123, 144, 149, 166, 168, 169, 170, 171, 177, 179, 180, 184, 185, 192, 200, 202, 209, 215, 216, 217, 220, 223, 224. , 226, 227, 228, 240, 254; Pigment Orange 13, 31, 34, 36, 38, 43, 46, 48, 49, 51, 52, 55, 59, 60, 61, 62, 64, 65, 71 Pigment Yellow 1,3,12,13,14,16,17,20,24,55,60,73,81,83,86,93,95,97,98,100,109,110,113,114 117, 120, 125, 126, 127, 129, 137, 138, 139, 147, 148, 150, 151, 152, 153, 154, 166, 168, 175, 180, 185; Pigment Green 7, 10, 36 Pigment Blue 15, 15: 1, 15: 2, 15: 3, 15: 4, 15: 5, 15: 6, 22, 24, 29, 56, 60, 61, 62, 64; Pigment Violet 1, 15 , 19, 23, 27, 29, 30, 32, 37, 40, 50 and the like.

Dyes include azo dyes, anthraquinone dyes, indigoid dyes, triarylmethane dyes, xanthene dyes, alizarin dyes, acrydin dyes, stillben dyes, thiazole dyes, naphthol dyes, quinoline dyes, nitro dyes, indamine dyes, oxazine dyes, and phthalocyanine dyes. , Cyanine dyes and the like, and a plurality of these may be mixed and used.

Next, the thermoplastic resin composition of the present invention will be described. The thermoplastic resin composition of the present invention contains 0.001 to 10 parts by mass of the additive of the present invention with respect to 100 parts by mass of the thermoplastic resin. As the thermoplastic resin used in the present invention, a polymer selected from an olefin resin, a styrene resin, a polyester resin, a polyether resin, a polycarbonate resin, a polyamide resin, a polyvinyl alcohol, a halogen-containing resin and the like can be used. preferable. In the thermoplastic resin composition of the present invention, the thermoplastic resin may be one kind or a combination thereof.

Examples of the olefin resin include low-density polyethylene (LDPE), linear low-density polyethylene (L-LDPE), high-density polyethylene (HDPE), isotactic polypropylene, syndiotactic polypropylene, and hemiisotactic polypropylene. Α-Olefin polymers such as cycloolefin polymer, stereoblock polypropylene, poly-3-methyl-1-butene, poly-3-methyl-1-pentene, poly-4-methyl-1-pentene, homopolypropylene, ethylene / Propropylene block or random copolymer, impact copolymer polypropylene, ethylene-methyl methacrylate copolymer, ethylene-methyl acrylate copolymer, ethylene-ethyl acrylate copolymer, ethylene-butyl acrylate copolymer, ethylene-vinyl acetate copolymer An α-olefin copolymer such as a coalescence or an ethylene-vinyl alcohol resin (EVOH) can be used, and an elastomer made of an olefin resin may be used.

When the olefin resin is a copolymer, the content of the polypropylene-derived structural units with respect to all the structural units in the copolymer is preferably 70% by mass or more. In the resin composition of the present invention, two or more of these may be blended and used, a block copolymer may be formed and used as a block polymer type, or the resin may be alloyed. .. Further, it may be a chlorinated product of these olefin resins.

Olefin-based resins include types and presence / absence of polymerization catalysts / co-catalysts, stereoregularity, average molecular weight, molecular weight distribution, presence / absence and ratio of specific molecular weight components, specific gravity, viscosity, solubility in various solvents, elongation, impact strength, etc. Crystalline, X-ray diffraction, unsaturated carboxylic acids (maleic acid, itaconic acid, fumaric acid, etc.) and derivatives thereof (maleic anhydride, maleic acid monoester, maleic acid diester, etc.) and organic peroxides or energy rays. It can be used regardless of the presence or absence of modification / cross-linking treatment by irradiation and a combination of these treatments.

As the elastomer made of an olefin resin, a polyolefin such as polypropylene or polyethylene is used as a hard segment, and a rubber such as ethylene-propylene rubber is used as a soft segment, and the elastomer obtained by blending these or obtained by dynamic cross-linking. Elastomers can be mentioned. Examples of the hard segment include at least one selected from polypropylene homopolymers, polypropylene block copolymers, polypropylene random copolymers, and the like. Examples of the soft segment include ethylene-propylene copolymer (EPM), ethylene-propylene-diene copolymer (EPDM), ethylene-vinyl acetate copolymer (EVA), vinyl acetate homopolymer and the like.

Examples of the styrene resin include vinyl group-containing aromatic hydrocarbons alone, vinyl group-containing aromatic hydrocarbons, and other monomers (for example, maleic anhydride, phenylmaleimide, and (meth) acrylonitrile. Copolymers with (butadiene, (meth) acrylonitrile, etc.) include, for example, polystyrene (PS) resin, impact-resistant polystyrene (HIPS), acrylonitrile-styrene (AS) resin, acrylonitrile-butadiene-styrene (ABS) resin. , Methyl methacrylate-butadiene-styrene (MBS) resin, heat resistant ABS resin, acrylonitrile-acrylate-styrene (ASA) resin, acrylonitrile-acrylic rubber-styrene (AAS) resin, styrene-maleic anhydride (SMA) resin, methacrylate- Styrene (MS) resin, styrene-isoprene-styrene (SIS) resin, acrylonitrile-ethylene propylene rubber-styrene (AES) resin, styrene-butadiene-butylene-styrene (SBBS) resin, methyl methacrylate-acrylonitrile-butadiene-styrene (MABS) ) Styrene-ethylene-butylene-styrene (SEBS) resin, styrene-ethylene-propylene-styrene (SEPS) resin, styrene-ethylene to which a double bond of these butadiene or isoprene is hydrogenated, as well as thermoplastic resins such as resins. Examples thereof include hydrogenated styrene-based elastomer resins such as -propylene (SEP) resin and styrene-ethylene-ethylene-propylene-styrene (SEEPS) resin.

Examples of the polyester-based resin include polyalkylene terephthalates such as polyethylene terephthalate, polybutylene terephthalate, and polycyclohexanedimethylene terephthalate; aromatic polyesters such as polyalkylene naphthalate such as polyethylene naphthalate and polybutylene naphthalate; and polytetramethylene terephthalate. Linear polyesters such as; and degradable aliphatics such as polyhydroxybutyrate, polycaprolactone, polybutylene succinate, polyethylene succinate, polylactic acid, polyapple acid, polyglycolic acid, polydioxane, poly (2-oxetanone). Examples include polyester.

Examples of the polyether resin include polyetherether, polyphenylene ether, polyetherketone, polyetheretherketone, polyetherketoneketone, polyetheretherketoneketone, polyethersulfone, polyetherimide and the like.

Examples of the polycarbonate-based resin include polycarbonate, polycarbonate / ABS resin, polycarbonate / ASA resin, polycarbonate / AES resin, branched polycarbonate, and the like.

Examples of the polyamide-based resin include ε-caprolactam (nylon 6), undecanlactam (nylon 11), lauryllactam (nylon 12), aminocaproic acid, enanthractum, 7-aminoheptanoic acid, 11-aminoundecanoic acid, 9-. Polymers such as aminononanoic acid, α-pyrrolidone, α-piperidone; diamines such as hexamethylenediamine, nonanediamine, nonanemethylenediamine, methylpentadiamine, undecamethylenediamine, dodecamethylenediamine, metaxylenediamine, and adipic acid, sebacic acid. , A copolymer obtained by copolymerizing with a carboxylic acid compound such as dicarboxylic acid such as terephthalic acid, isophthalic acid, dodecandicarboxylic acid and glutaric acid, or a mixture of these polymers or copolymers. .. In addition, aramid resins such as DuPont's product name "Kevlar", DuPont's product name "Nomex", Teijin Limited's product name "Twaron", and "Conex" can be mentioned.

Examples of polyvinyl alcohol include those produced by polymerizing a vinyl ester-based monomer and further saponifying it. Examples of the vinyl ester monomer include vinyl formate, vinyl acetate, vinyl propionate, vinyl valerate, vinyl butyrate, vinyl isobutyrate, vinyl pivalate, vinyl caprate, vinyl laurate, vinyl stearate, vinyl versatic acid, and the like. Examples thereof include aliphatic vinyl esters such as trifluorovinyl acetate and aromatic vinyl esters such as vinyl benzoate, preferably aliphatic vinyl esters having 3 to 20 carbon atoms, and more preferably 4 to 10 carbon atoms. Be done. Vinyl acetate is preferred from an economic point of view. The vinyl ester-based monomer is usually used alone, but two or more kinds may be used if necessary. Further, a copolymer of a vinyl ester-based monomer and another unsaturated monomer may be saponified.

Examples of other unsaturated monomers include glycidyl (meth) acrylate, glycidyl (meth) allyl ether, 3,4-epoxycyclohexyl (meth) acrylate, allyl glycidyl ether, and other single amounts having a vinyl group and an epoxy group. Body: A monomer having two or more allyl groups such as triallyloxyethylene, diallyl maleate, triallyl cyanurate, triallyl isocyanurate, tetraallyloxyethane, diallyl phthalate, triallyl cyanurate, and triallyl isocyanurate. Allyl ester-based monomers such as allyl acetate, vinyl acetoacetic acid ester, allyl acetoacetate, allyl diacetate acetate; acetoacetoxyalkyl (meth) such as acetoacetoxyethyl (meth) acrylate and acetoacetoxypropyl (meth) acrylate. Acrylic; acetoacetoxyalkyl crotonate such as acetoacetoxyethyl crotonate, acetoacetoxypropyl crotonate; 2-cyanoacetoxyethyl (meth) acrylate; divinylbenzene; ethylene glycol di (meth) acrylate, 1,2-propylene glycol (Meta) acrylate, 1,3-propylene glycol di (meth) acrylate, 1,4-butanediol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, neopentyl glycol di (meth) acrylate, etc. Alkylene glycol (meth) acrylate; trimethylpropantri (meth) acrylate; allyl (meth) acrylate; hydroxy such as 2-hydroxyethyl (meth) acrylate, hydroxypropyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate Alkyl (meth) acrylate (alkyl moiety is C1-C10 alkyl group, preferably C1-C6 alkyl group); nitrile-based monomer such as (meth) acrylonitrile; styrene-based single amount such as styrene and α-methylstyrene. Body; olefins such as ethylene, propylene, 1-butene, isobutene; halogenated olefins such as vinyl chloride, vinylidene chloride, vinyl fluoride, vinylidene fluoride; olefin-based monomers such as ethylene sulfonic acid; 1,3-butadiene , 2-Methyl-1,3-butadiene, 2,3-dimethyl-1,3-butadiene, 2-methyl-1,3-pentadiene, 2-chloro-1,3-butadiene and other diene-based monomers; 3-bu Hydroxy group-containing α-olefins such as ten-1-ol, 4-pentene-1-ol, 5-hexene-1-ol, 2-diol, glycerin monoallyl ether, and derivatives such as acylated products thereof; 1, Hydroxymethylvinylidene diacetates such as 3-diacetoxy-2-methylenepropane, 1,3-dipropionyloxy-2-methylenepropane, 1,3-dibutyronyloxy-2-methylenepropane; itaconic acid, maleic acid, Unsaturated acids such as acrylic acid, salts thereof or mono or dialkyl esters; nitriles such as acrylonitrile, amides such as methacrylamide and diacetoneacrylamide, ethylenesulfonic acid, allylsulfonic acid, metaallylsulfonic acid, 2-acrylamide- Compounds such as olefin sulfonic acid such as 2-methylpropanesulfonic acid or a salt thereof, vinyltriethoxysilane, vinyltrimethoxysilane, vinyltripropoxysilane, vinyltributoxysilane, vinylmethyldimethoxysilane, vinylmethyldiethoxysilane, etc. Vinylalkyldialkoxysilane; γ- (meth) acryloxypropyltrialkoxysilane such as γ- (meth) acryloxipropyltrimethoxysilane, γ- (meth) acryloxipropyltriethoxysilane; γ- (meth) acryloxy Examples thereof include γ- (meth) acryloxypropylalkyldialkoxysilane such as propylmethyldimethoxysilane and γ- (meth) acryloxypropylmethyldiethoxysilane; vinyltris (β-methoxyethoxy) silane and hydroxymethylvinylidene diacetate. Specific examples of hydroxymethylvinylidene diacetate include 1,3-diacetoxy-2-methylenepropane, 1,3-dipropionyloxy-2-methylenepropane, and 1,3-dibutyronyloxy-2-methylenepropane. , 3,4-Dihydroxy-1-butene, 3,4-diasiloxy-1-butene, 3-allyloxy-4-hydroxy-1-butene, 4-acyloxy-3-hydroxy-1-butene, 3,4-diasiloxy -2-Methyl-1-butene, 4,5-dihydroxy-1-pentene, 4,5-diasiloxy-1-pentene, 4,5-dihydroxy-3-methyl-1-pentene, 4,5-diasiloxy-3 -Methyl-1-pentene, 5,6-dihydroxy-1-hexene, 5,6-diasiloxy-1-hexene, glycerin monoallyl ether, 2,3-diacetoxy-1-allyloxypropane, 2-acetoxy-1- Allyloxy-3-hydroxypropane, 3-acetoxy-1-allyloxy-2-hydroxypropane, glycerin monovinyl ether, glycerin monoisopropenyl ether, vinyl ethylene carbonate, 2,2-dimethyl-4-vinyl-1,3-dioxolane, etc. Examples thereof include compounds having the above diol. These can be used alone or in combination of two or more.

Examples of the halogen-containing resin include polyvinyl chloride, polyvinylidene chloride, chlorinated polyethylene, chlorinated polypropylene, polyvinylidene fluoride, rubber chloride, vinyl chloride-vinyl acetate copolymer, vinyl chloride-ethylene copolymer, and vinyl chloride. -Vinylidene chloride copolymer, vinyl chloride-vinylidene chloride-vinyl acetate ternary copolymer, vinyl chloride-acrylic acid ester copolymer, vinyl chloride-maleic acid ester copolymer, vinyl chloride-cyclohexylmaleimide copolymer, etc. Examples thereof include a chlorine-containing resin and a fluorine-containing resin such as an ethylene-tetrafluoroethylene copolymer.

Examples of other polymers include petroleum resin, kumaron resin, polyvinyl acetate, acrylic resin, polymethylmethacrylate, polyvinyl alcohol, polyvinylformal, polyvinylbutyral, polyphenylene sulfide, polyurethane, fibrous resin, and polyimide resin. , Polysulfone, thermoplastic resins such as liquid crystal polymers and blends thereof can be used.

In the resin composition of the present invention, it is preferable to contain an olefin resin because the effect of the present invention is remarkable.

The method of blending the additive of the present invention into the thermoplastic resin is not particularly limited, and is a commonly used method, for example, a method of dry blending a powder or pellet of the thermoplastic resin with the additive of the present invention. A method of preparing a masterbatch containing a high concentration of the additive of the present invention and adding it to a thermoplastic resin, processing the additive of the present invention and other additives into a pellet shape and adding the additive to the thermoplastic resin. The method can be mentioned. Further, the additive of the present invention and other additives may be added to the thermoplastic resin at the same time, or may be added separately.

As a method for processing into a pellet shape, the additive of the present invention, a binder such as a phenolic antioxidant, a polymer compound, a petroleum resin, or any other additive is heated as necessary to obtain a melted binder. It can be produced by mixing in the presence. The processing conditions, processing equipment, etc. are not limited in any way, and well-known general processing methods and processing equipment can be used.

In the resin composition of the present invention, the blending amount of the additive of the present invention with respect to 100 parts by mass of the thermoplastic resin is 0.001 to 10 parts by mass, preferably 0.005 to 1 part by mass, and 0.005 to 5 parts by mass. 0.5 parts by mass is more preferable. If the blending amount is less than 0.001 part by mass, the effect of the present invention may not be obtained, and if it exceeds 10 parts by mass, it becomes difficult to disperse in the thermoplastic resin, and the physical properties and appearance of the molded product may be affected. May have an adverse effect.

The resin composition of the present invention may optionally contain a known additive as long as the effects of the present invention are not significantly impaired. Examples of such known additives include phenol-based antioxidants, phosphorus-based antioxidants, sulfur-based antioxidants, ultraviolet absorbers, hindered amine compounds, nucleating agents, flame retardants, flame retardant aids, lubricants, and the like. Examples thereof include fillers, hydrotalcites, fatty acid metal salts, antistatic agents, fluorescent whitening agents, pigments, dyes and the like. Examples of these additives include those used in the additive composition for thermoplastic resins of the present invention.

Next, the molded article of the present invention will be described. The molded product of the present invention is characterized in that it is formed by molding the thermoplastic resin composition of the present invention. The method for molding the thermoplastic resin composition of the present invention is not particularly limited, and can be molded using a known molding method. For example, to obtain a molded product by using an injection molding method, an extrusion molding method, a blow molding method, a rotary molding method, a vacuum molding method, an inflation molding method, a calendar molding method, a slush molding method, a dip molding method, a foam molding method, or the like. Is possible. Of these, an injection molding method, an extrusion molding method, and a blow molding method are preferable.

Examples of the molded product of the present invention include an injection molded product, a fiber, a flat yarn, a biaxially stretched film, a uniaxially stretched film, a non-stretched film, a sheet, a heat molded product, an extrusion blow molded product, an injection blow molded product, and an injection stretched product. Examples include blow-molded products, deformed extrusion-molded products, and rotary-molded products. Of these, injection-molded products, films, sheets, and thermoformed products are preferable.

Applications of the molded product of the present invention include, for example, various uses such as building materials, agricultural materials, vehicle parts such as automobiles, trains, ships, and aircraft, packaging materials, miscellaneous goods, toys, home appliances, and medical products. Can be mentioned. Specifically, automobile parts such as bumpers, dashboards, instrument panels, battery cases, luggage cases, door panels, door trims, and fender liners; resin parts for home appliances such as refrigerators, washing machines, and vacuum cleaners; tableware, bottles Household products such as caps, buckets, bath products; Resin parts for connection such as connectors; Miscellaneous goods such as toys, storage containers, synthetic paper; Medical packs, injectors, catheters, medical tubes, syringe preparations, infusion bags, reagents Medical molded products such as containers, medicine containers, individual packaging of medicines; building materials such as wall materials, flooring materials, window frames, wallpaper, windows; wire coating materials; agricultural materials such as houses, tunnels, flat yarn mesh bags, etc. Industrial materials such as pallets, pail cans, back grind tapes, LCD protective tapes, pipes, modified silicone polymers for sealing materials; food packaging materials such as wraps, trays, cups, films, bottles, caps, storage containers, 3D Examples thereof include printer materials, separator films for batteries, clothing, woven fabrics, fibers such as non-woven fabrics, and the like. Furthermore, after molding, low-temperature plasma is used for various post-treatment applications, such as medical applications, food packaging applications, and other applications that are sterilized by radiation, or for improving surface properties such as paintability. It can be used for applications where processing is performed. The molded product of the present invention is particularly preferably used for automobile parts, household products, and food packaging materials.

Hereinafter, the present invention will be described in more detail with reference to Production Examples, Examples and Comparative Examples, but the present invention is not limited by the following Production Examples, Examples and the like.

[Manufacturing Example 1]
^{(N 1, N 1 '-} ( ethane-1,2-diyl bis (2,1-phenylene)) bis ^{(N 4} - preparation of cyclohexyl succinamide))
N ^{1, N 1} '- (ethane-1,2-diyl bis (2,1-phenylene)) bis - according to ^{(N 4-cyclohexyl} succinamide), a reaction formula shown below were prepared.

In a nitrogen atmosphere, succinic anhydride (10.1 g, 0.10 mol) and acetone (50 ml) were added to a 100 ml four-necked flask to dissolve succinic anhydride, and cyclohexylamine (10.1 g, 0. 10 mol) was added dropwise. After the dropping, the mixture was stirred at room temperature for 1 hour to react. After completion of the reaction, the mixture was filtered off, the obtained product was washed with acetone, and dried at 80 ° C. for 3 hours using a vacuum dryer to obtain a white powder (18.5 g). As a result of ¹ H-NMR analysis, the obtained white powder was 4- (cyclohexylamino) -4-oxobutanoic acid, and as a result of gas chromatography analysis, it was confirmed that the purity was 99% or more. The results of ¹ H-NMR analysis of the obtained white powder are shown below.

( ¹ Analysis result by ¹ H-NMR (DMSO-d ₆ , 300 MHz))
σ (ppm): 12.03 (s, 1H, COOH), 7.69, 7.67 (d, 1H, -NH-), 3.53-3.45 (m, 1H, -CH-) 2 .42-2.26 (m, 4H, succinic) 1.72-1.05 (m, 10H, cyclohexyl)

Under a nitrogen atmosphere, four-necked flask of 100 ml, 4-(cyclohexylamino) -4-oxobutanoic acid ^{(15.0g, 5.8 × 10 -2 mol} ), 2,2- ethylenedioxy aniline (6.1 g, 2.9 × 10 ^-2 mol), N, N'-dimethylaminopyridine (small amount), and N, N-dimethylformamide (DMF, 100 ml) were added and stirred. After stirring, diisopropylcarbodiimide (7.5 g, 5.9 × ^10-2 mol) was added dropwise. After the dropping, the mixture was stirred at room temperature for 5 hours to react. After completion of the reaction, the mixture was filtered off, the obtained product was washed with water and acetone, and the obtained product was vacuum dried at 70 ° C. for 5 hours to obtain a white powder (12.6 g). As a result of ¹ H-NMR analysis, the obtained white powder was found to be the target product, N ¹ , N ¹ '-(ethane-1,2-diylbis (2,1-phenylene)) bis (N ⁴ -cyclohexylsuccin). As a result of analysis by high performance liquid chromatography, it was confirmed that the purity was 99% or more. The results of ¹ H-NMR analysis of the obtained white powder are shown below.

( ¹ Analysis result by ¹ H-NMR (DMSO-d ₆ , 300 MHz))
σ (ppm): 9.42 (s, 2H, Ph-NH-), 7.77, 7.75 (d, 2H, cyclohexyl-NH-), 7.36-7.25 (m, 8H, Ph) ) 3.52-3.41 (m, 2H, cyclohexyl , -CH -), 2.76 (s, 4H, -Ph-CH 2 -CH 2 -Ph-) 2.61-2.39 (m, 8H, succinic), 1.70-1.04 (m, 20H, succinic, -CH _2- )

[Manufacturing Example 2]
^{(N 1, N 1 '-} ( ethane-1,2-diyl bis (2,1-phenylene)) bis ^{(N 4} - preparation of isobutyl succinamide))
N ^{1, N 1} '- (ethane-1,2-diyl bis (2,1-phenylene)) bis - according to ^{(N 4} isobutyl succinamide), a reaction formula shown below were prepared.

Under a nitrogen atmosphere, succinic anhydride (10.1 g, 0.10 mol) and acetone (50 ml) were added to a 100 ml four-necked flask to dissolve succinic anhydride, and isobutylamine (7.3 g, 0. 10 mol) was added dropwise. After the dropping, the mixture was stirred at room temperature for 1 hour to react. After completion of the reaction, the mixture was separated by filtration, the obtained product was washed with acetone, and dried at 80 ° C. for 3 hours using a vacuum dryer to obtain a white powder (8.8 g). As a result of ¹ H-NMR analysis, the obtained white powder was 4- (isobutylamino) -4-oxobutanoic acid, and as a result of gas chromatography analysis, it was confirmed that the purity was 99% or more. The results of ¹ H-NMR analysis of the obtained white powder are shown below.

( ¹ Analysis result by ¹ H-NMR (DMSO-d ₆ , 300 MHz))
σ (ppm): 12.04 (s, 1H, COOH), 7.80 (s, 1H, -NH-), 2.87-2.84 (dd, 2H, -CH _2- ) 2.33- 2.29 (m, 4H, succinic), 1.67-1.62 (m, 1H, -CH-), 0.83-0.82 (d, 6H, -CH ₃ )

In a nitrogen atmosphere, in a 100 ml four-necked flask, 4- (isobutylamino) -4-oxobutanoic acid (8.0 g, 4.6 × ^10-2 mol), 2,2-ethylenedianiline (4.9 g, 2.3 × ^10-2 mol), N, N'-dimethylaminopyridine (small amount), and dimethylformamide (DMF, 100 ml) were added and stirred. After stirring, it was added dropwise diisopropyl carbodiimide ^{(9.8g, 4.7 × 10 -2 mol} ). After the dropping, the mixture was stirred at room temperature for 5 hours to react. After completion of the reaction, the mixture was filtered off, the obtained product was washed with water and acetone, and dried at 70 ° C. for 5 hours using a vacuum dryer to obtain a white powder (7.0 g). The obtained white powder was analyzed by ¹ H-NMR, and as a result, the target product was N ¹ , N ¹ '-(ethane-1,2-diylbis (2,1-phenylene)) bis (N ⁴ -isobutylsuccin). As a result of analysis by high performance liquid chromatography, it was confirmed that the purity was 99% or more. The results of ¹ H-NMR analysis of the obtained white powder are shown below.

( ¹ Analysis result by ¹ H-NMR (DMSO-d ₆ , 300 MHz))
σ (ppm): 9.39 (s, 2H, -Ph-NH-), 7.87, 7.86, 7.85 (t, 2H, isobutyl-NH-), 7.87-7.08 ( _{m, 8H, Ph) 2.86,2.85,2.83 (} t, 4H, isobutyl, -CH 2 -), 2.76 (s, 4H, -Ph-CH 2 -CH 2 -Ph) 2 .61-2.39 (m, 4H, succinic), 1.69-1.59 (m, 2H, isobutyl, -CH-), 0.84, 0.82 (d, 12H, isobutyl, -CH ₃₎ )

[Manufacturing Example 3]
^{(N 1, N 1 '-} ( ethane-1,2-diyl bis (2,1-phenylene)) bis ^{(N 4} - preparation of butyl succinamide))
In Production Example 1, cyclohexylamine was changed to butylamine (7.31 g, 0.1 mol), but the same procedure was carried out in the same manner as for N ¹ , N ¹ '-(ethane-1,2-diylbis (2,1-). was prepared butyl succinamide) - phenylene)) bis ^{(N 4.}

[Manufacturing Example 4]
^{(N 1, N 1 '-} ( ethane-1,2-diyl bis (2,1-phenylene)) bis ^(N 4 - (production of sec- butyl) succinamide))
In Production Example 1, cyclohexylamine was changed to sec-butylamine (7.31 g, 0.1 mol), and the same procedure was carried out in the same manner as for N ¹ , N ¹ '-(ethane-1,2-diylbis (2,)). 1-phenylene)) bis ^(N 4 - (to produce sec- butyl) succinamide).

[Manufacturing Example 5]
^{(N 1, N 1 '-} ( ethane-1,2-diyl bis (2,1-phenylene)) bis ^(N 4 - (preparation of tert- butyl) succinamide))
In Production Example 1, cyclohexylamine was changed to tert-butylamine (7.31 g, 0.1 mol), but the same procedure was carried out in the same manner as for N ¹ , N ¹ '-(ethane-1,2-diylbis (2,)). 1-phenylene)) bis ^(N 4 - (to produce tert- butyl) succinamide).

[Manufacturing Example 6]
^{(N 1, N 1 '-} ( ethane-1,2-diyl bis (2,1-phenylene)) bis ^(N 4 - (2-preparation of methyl cyclohexyl) succinamide))
In Production Example 1, the same procedure as in Production Example 1 was carried out except that cyclohexylamine was changed to 2-methylcyclohexylamine (11.3 g, 0.10 mol), and N ¹ , N ¹ '-(ethane-1). , 2- diyl bis (2,1-phenylene)) bis - was produced ^(N 4 (2-methylcyclohexyl) succinamide).

[Manufacturing Example 7]
^{(N 1, N 1 '-} ( ethane-1,2-diyl bis (2,1-phenylene)) bis ^{(N 5} - preparation of cyclohexyl glutaric amide))
In Production Example 1, the same procedure as in Production Example 1 was carried out except that succinic anhydride was changed to glutaric anhydride (13.2 g, 0.10 mol), and N ¹ , N ¹ '-(ethane-1,2). - to prepare a cyclohexyl glutaric amide) - diyl bis (2,1-phenylene)) bis ^{(N 5.}

[Manufacturing Example 8]
^{(N 1, N 1 '-} ( ethane-1,2-diyl bis (2,1-phenylene)) bis ^{(N 5} - preparation of isobutyl glutaric amide))
In Production Example 1, the same procedure as in Production Example 1 was carried out except that succinic anhydride was changed to glutaric anhydride (13.2 g, 0.10 mol) and cyclohexylamine was changed to isobutylamine (7.31 g, 0.1 mol). ^{to, N 1,} N 1 '- was produced - (isobutyl glutaric amide ^{N 5)} (ethane-1,2-diyl bis (2,1-phenylene)) bis.

[Manufacturing Example 9]
^{(N 1, N 1 '-} ( ethane-1,2-diyl bis (2,1-phenylene)) bis ^(N 5 - (production of sec- butyl) glutaramide))
In Production Example 1, the same as in Production Example 1 except that succinic anhydride was changed to glutaric anhydride (13.2 g, 0.10 mol) and cyclohexylamine was changed to sec-butylamine (7.31 g, 0.1 mol). N ^{1, N 1} implemented '- was produced - ^((sec-butyl) glutaramido N 5) (ethane-1,2-diyl bis (2,1-phenylene)) bis.

[Manufacturing Example 10]
(Manufacture of N ¹ , N ¹ '-(1,3-phenylene bis (methylene)) bis (N ⁵ -cyclohexylsuccinamide))
Production Example 1, 2,2-ethylenedioxy aniline 1,3-phenylene methanamine was changed to ^{(3.13g, 2.3 × 10 -2 mol} ), was performed in the same manner as described in Example 1 , N ¹ , N ¹ '-(1,3-phenylene bis (methylene)) bis (N ⁵ -cyclohexylsuccinamide) was produced.

[Manufacturing Example 11]
(Manufacture of N ¹ , N ¹ '-(1,3-phenylene bis (methylene)) bis (N ⁵ -cyclohexylglutalamide))
Production Example 1, 2,2-ethylenedioxy aniline 1,3-phenylene methanamine ^{(3.13g, 2.3 × 10 -2 mol} ) , the succinic anhydride glutaric anhydride (13.2 g, 0 N ¹ , N ¹ '-(1,3-phenylene bis (methylene)) bis (N ⁵ -cyclohexylglutaramide) was produced in the same manner as in Production Example 1 except that it was changed to .10 mol).

[Manufacturing Example 12]
(Manufacture of N ¹ , N ¹ '-(1,3-phenylene bis (methylene)) bis (N ^5- (sec-butyl) glutaramide))
In Production Example 1, cyclohexylamine was added to sec-butylamine (7.31 g, 0.1 mol), succinic anhydride was added to glutaric anhydride (13.2 g, 0.10 mol), and 2,2-ethylenedianiline was added. 1,3-phenylene methanamine was changed to ^{(3.13g, 2.3 × 10 -2 mol} ), was performed in the same manner as in example ^{1, N 1, N 1 '} - (1,3- Phenylene bis (methylene)) bis (N ^5- (sec-butyl) glutaramide) was produced.

[Manufacturing Example 13]
^{(N 1, N 1 '-} ( methylenebis (2,6-diethyl-4,1-phenylene)) bis ^{(N 5} - preparation of isobutyl glutaric amide))
In Production Example 1, succinic anhydride was added to glutaric anhydride (13.2 g, 0.10 mol), cyclohexylamine to isobutylamine (7.31 g, 0.1 mol), and 2,2-ethylene dianiline. 4,4'-methylenebis (2,6-diethyl) was changed to ^{(7.14g, 2.3 × 10 -2 mol} ), was performed in the same manner as in example ^{1, N 1, N 1 '} - It was prepared - (isobutyl glutaric amide ^{N 5)} (methylenebis (2,6-diethyl-4,1-phenylene)) bis.

[Manufacturing Example 14]
(Manufacture of N ¹ , N ¹ '-(methylene bis (2,6-diethyl-4,1-phenylene)) bis (N ^5- (sec-butyl) glutaramide))
Production Example 1, 2,2-ethylene dianiline, 4,4'-methylenebis ^{(2,6-diethyl) (7.14g, 2.3 × 10 -2} mol) , the glutaric anhydride succinic anhydride The procedure was carried out in the same manner as in Production Example 1 except that cyclohexylamine was changed to (13.2 g, 0.10 mol) and cyclohexylamine was changed to sec-butylamine (7.31 g, 0.1 mol), and N ¹ , N ¹ '. -(Methylenebis (2,6-diethyl-4,1-phenylene)) bis (N ^5- (sec-butyl) glutarumamide) was produced.

[Manufacturing Example 15]
^{(N 1, N 1 '-} (1,4- phenylene) bis ^{(N 5} - preparation of isobutyl succinamide))
Production Example 1, a cyclohexylamine isobutylamine (7.31 g, 0.1 mol), 2,2-ethylenedioxy aniline benzene-1,4-diamine ^{(2.49g, 2.3 × 10 -2 mol} ) N ¹ , N ¹ '-(1,4-phenylene) bis (N ⁵ -isobutylsuccinamide) was produced in the same manner as in Production Example 1 except that the mixture was changed to.

[Manufacturing Example 16]
(Manufacture of N ¹ , N ¹ '-(1,4-phenylene) bis (N ^5- (tert-butyl) succinamide))
Production Example 1, a cyclohexylamine tert- butylamine (7.31 g, 0.1 mol) in 2,2-ethylenedioxy aniline benzene-1,4-diamine (2.49g, 2.3 × ¹⁰ -2 mol except that the) is performed in the same manner as in example ^{1, N 1, N 1 '} - was prepared succinamide) - ((tert-butyl 1,4-phenylene) bis ^(N 5).

[Manufacturing Example 17]
^{(N 1, N 1 '-} (1,4- phenylene) bis ^{(N 5} - preparation of cyclohexyl succinamide))
Production Example 1, 2,2-ethylenedioxy aniline benzene-1,4-diamine was changed to ^{(2.49g, 2.3 × 10 -2 mol} ), was performed in the same manner as in Example 1, N ¹ , N ¹ '-(1,4-phenylene) bis (N ⁵ -cyclohexylsuccinamide) was produced.

[Manufacturing Example 18]
(Manufacture of N ¹ , N ¹ '-(naphthalene-1,5-diyl) bis (N ⁵ -isobutylsuccinamide))
Production Example 1, a cyclohexylamine isobutylamine (7.31 g, 0.1 mol), 2,2-ethylenedioxy aniline naphthalene-1,5-diamine ^{(3.64g, 2.3 × 10 -2 mol} ) N ¹ , N ¹ '-(naphthalene-1,5-diyl) bis (N ⁵ -isobutylsuccinamide) was produced in the same manner as in Production Example 1 except that it was changed to.

[Manufacturing Example 19]
(Manufacture of N ¹ , N ¹ '-(naphthalene-1,5-diyl) bis (N ^5- (tert-butyl) succinamide))
Production Example 1, a cyclohexylamine tert- butylamine (7.31 g, 0.1 mol) in 2,2-ethylenedioxy aniline naphthalene-1,5-diamine (3.64g, 2.3 × ¹⁰ -2 mol N ¹ , N ¹ '-(naphthalene-1,5-diyl) bis (N ^5- (tert-butyl) succinamide) was produced in the same manner as in Production Example 1 except that the mixture was changed to.

[Examples 1-1 to 1-19, Comparative Examples 1-1 to 1-27]
Phenolic antioxidant (tetrakis [methylene-3- (3', 5'-tert-butyl-)) based on 100 parts by mass of homopolypoly (melt flow rate 8 g / 10 min; ISO standard 1133 compliant 2.16 kg x 230 ° C). 4'-Hydroxyphenyl) propionate] methane) 0.05 parts by mass, phosphorus-based antioxidant (tris (2,4-di-tert-butylphenyl) phosphite) 0.1 parts by mass, calcium stearate 0.05 parts The test compounds shown in Tables 1 to 5 were blended in an amount of 0.02 parts by mass, blended by hand for 3 minutes, charged into a twin-screw extruder, and melted at 230 ° C. Granulated with. Comparative Example 1-27 was granulated in the same procedure as in Example 1-1 except that the test compound was not blended. The granulated pellets were dried at 80 ° C. for 8 hours and then evaluated under the following conditions. The test compounds shown in Tables 1 and 2 represent functional groups corresponding to each symbol in the compounds represented by the general formula (1), and * indicates that the functional groups are represented by the general formula (1). Represents the position of binding to the carbon atom of the carbonyl group or the nitrogen atom of the amide group of the compound.

<Crystallization temperature Tc [° C]>
Using the obtained pellets, the crystallization temperature (Tc) was measured using a differential scanning calorimetry device (apparatus; diamond manufactured by PerkinElmer). The measuring method is as follows: the temperature is raised from room temperature to 230 ° C. at a rate of 50 ° C./min, held for 20 minutes, cooled to 50 ° C. at -10 ° C./min, then held for 5 minutes, and then kept at 230 ° C. The temperature was raised to. In the obtained chart, the temperature at which the endothermic reaction peaked was defined as the crystallization temperature Tc (° C.). In addition, ΔTc [° C.] in the table represents the difference from the crystallization temperature of Comparative Example 1-27 in which the test compound was not blended.

From the above, it was confirmed that the additive of the present invention can remarkably promote the crystallization of the thermoplastic resin composition even when blended in a small amount, and the effect of the nucleating agent is remarkable.

Claims (7)

A compound having a structure represented by the following general formula (1).

In the general formula (1), X represents an alkylene group having 1 to 20 carbon atoms, an arylene group having 6 to 20 carbon atoms, a cycloalkylene group having 3 to 20 carbon atoms, or a combination thereof.
L ¹ and L ² represent a linear alkylene group having 2 or 3 carbon atoms, respectively.
R ¹ and R ² represent an alkyl group having 1 to 7 carbon atoms or a cycloalkyl group having 3 to 20 carbon atoms, respectively.
The alkylene group represented by X and the alkyl group represented by R ¹ and R ² may be linear or have a branch, and the arylene group represented by X, the cycloalkylene group and R ¹ may be used. and the hydrogen atoms of the cycloalkyl group represented by R ² is an alkyl group having 1 to 6 carbon atoms, may be substituted by an alkoxy group or a halogen atom having 1 to 6 carbon atoms. X in the general formula (1) is −A ¹ −L ³ −A ² −, −L ⁴ −A ³ −L ⁵ − (A ^{1 to} A ³ are arylenes having 6 to 20 carbon atoms, respectively. represents a group or a cycloalkylene group having a carbon number of 3 to ^20, L 3 ~L ⁵ each represent an alkylene group having 1 to 5 carbon ^atoms, alkylene group represented by L 3 ~L ⁵ is a straight It may have a chain or a branch, and the hydrogen atoms of the arylene group and the cycloalkylene group represented by A ^{1 to} A ³ are an alkyl group having 1 to 6 carbon atoms and an alkoxy having 1 to 6 carbon atoms. The compound according to claim 1, which is selected from an arylene group having 6 to 20 carbon atoms (which may be substituted with a group or a halogen atom). An additive for a thermoplastic resin, which comprises the compound according to claim 1 or 2. The additive for thermoplastic resin according to claim 3, a phenol-based antioxidant, a phosphorus-based antioxidant, a sulfur-based antioxidant, an ultraviolet absorber, a hindered amine compound, a nucleating agent, a flame retardant, a flame retardant aid, and a lubricant. , Hydrotalcites, fatty acid metal salts, antistatic agents, fluorescent whitening agents, one or more selected from the group consisting of pigments and dyes, and additives for thermoplastic resins. Composition. A thermoplastic resin composition comprising 0.001 to 10 parts by mass of the additive for a thermoplastic resin according to claim 3 with respect to 100 parts by mass of the thermoplastic resin. The thermoplastic resin composition according to claim 5, wherein the thermoplastic resin contains an olefin resin. A molded product comprising the thermoplastic resin composition according to claim 5 or 6.