JP2016528139A - Method of producing ion exchange glass and resulting apparatus - Google Patents

Method of producing ion exchange glass and resulting apparatus Download PDF

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JP2016528139A
JP2016528139A JP2016521881A JP2016521881A JP2016528139A JP 2016528139 A JP2016528139 A JP 2016528139A JP 2016521881 A JP2016521881 A JP 2016521881A JP 2016521881 A JP2016521881 A JP 2016521881A JP 2016528139 A JP2016528139 A JP 2016528139A
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glass
mpa
layer
compressive stress
mol
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JP2016528139A5 (en
JP6538662B2 (en
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マイケル クリアリー,トーマス
マイケル クリアリー,トーマス
グレゴリー クイヤール,ジェイムズ
グレゴリー クイヤール,ジェイムズ
スコット フーテン,ティモシー
スコット フーテン,ティモシー
ジャイン,アヌラーグ
エリザベス マーセラス,ブレンナ
エリザベス マーセラス,ブレンナ
ジョン ムーア,マイケル
ジョン ムーア,マイケル
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コーニング インコーポレイテッド
コーニング インコーポレイテッド
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Priority to PCT/US2014/043619 priority patent/WO2014209861A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10119Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the number, the constitution or treatment of glass sheets having a composition deviating from the basic composition of soda-lime glass, e.g. borosilicate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheet
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10128Treatment of at least one glass sheet
    • B32B17/10137Chemical strengthening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the resin layer, i.e. interlayer
    • B32B17/10743Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the resin layer, i.e. interlayer containing acrylate (co)polymers or salts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the resin layer, i.e. interlayer
    • B32B17/10761Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the resin layer, i.e. interlayer
    • B32B17/1077Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the resin layer, i.e. interlayer containing polyurethane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the resin layer, i.e. interlayer
    • B32B17/10788Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate

Abstract

A laminated structure is disclosed having a first glass layer, a second glass layer, and at least one polymeric interlayer between the first and second glass layers. The first glass layer is composed of a thin chemically strengthened glass having a surface compressive stress between about 250 MPa and about 350 MPa and a layer depth (DOL) of compressive stress greater than about 60 μm. The second glass layer can also be composed of a thin chemically strengthened glass having a surface compressive stress between about 250 MPa and about 350 MPa and a layer depth (DOL) of compressive stress greater than about 60 μm.

Description

Related applications

  This application claims the benefit of priority in US patent application Ser. No. 13/926461 filed Jun. 25, 2013 and US Patent Application No. 13/626958 filed Sep. 26, 2012. The contents are all cited here.

  The embodiments disclosed herein relate to ion exchange glasses, and in particular to methods for producing such glasses with moderate compressive stress, deep depth of the compression layer, and / or desirable central tension characteristics.

  Glass laminates can be used as windows and glazing in architectural applications and in vehicle or transportation applications, including automobiles, rail cars, locomotives and airplanes. Glass laminates can also be used as glass panels in handrails and stairs and as decorative panels or covers for walls, pillars, elevator cars, kitchen appliances and other applications. As used herein, glazed or laminated glass structures are transparent, semi-transparent, translucent or opaque in windows, panels, walls, enclosures, signs or other structures It is a member. Common glazings used in architectural and / or vehicle applications include clear, light-colored laminated glass structures.

  A conventional automotive glazing structure would consist of two layers of 2 mm thick soda lime glass with a polyvinyl butyral (PVB) interlayer. These laminated structures have certain advantages, including low cost and sufficient impact resistance for automotive and other applications. However, due to limited impact resistance and heavy mass, these laminates usually have a higher probability of failure when stones, destructors and other impacts along the road collide and the higher of each vehicle. Insufficient performance characteristics, including low fuel efficiency.

  In applications where strength is important (such as the automotive applications described above), the strength of conventional glasses may be improved by several methods including coating, thermal tempering, and chemical strengthening (ion exchange). Thermal tempering is usually used for thick single glass plates and has the advantage of forming a thick compressed layer to the glass surface, typically 20 to 25% of the total glass thickness. Unfortunately, however, the magnitude of the compressive stress is relatively small, typically less than 100 MPa. Furthermore, thermal tempering becomes increasingly ineffective for relatively thin glasses, such as less than about 2 mm.

  In contrast, ion exchange (IX) techniques can produce high levels of compressive stress on the treated glass as high as about 1000 MPa at the surface and are suitable for ultra-thin glasses. Unfortunately, however, ion exchange is limited to relatively shallow compressed layers, typically on the order of tens of micrometers. High compressive stresses can result in very high blunt impact resistance, which requires the glass to break under certain impact loads to prevent injury, ECE (European Commission for the European Economic Commission) R43 It will not pass certain safety standards for automotive applications such as the Head Form Impact Test. Traditional research and development efforts have focused on controlled or preferential destruction of vehicle laminates at the expense of impact resistance.

In conventional single-step ion exchange processes, long ion exchange steps may be used to achieve deep compressed layer depth (DOL), but in such long periods of time, the selected glass The median tension (CT) increases beyond the friability limit and the glass breaks undesirably. As an example, experiments have shown that Corning® Gorilla® Glass 4 inch × 4 inch (about 10 cm × about 10 cm) × 0.7 mm plates are long single step ion exchange in pure KNO 3. It has been newly discovered that when the process (8 hours at 475 ° C.) is performed, it shows undesirable crushing (energy breakdown into many small pieces) when crushing. In fact, a DOL of about 101 μm was achieved but resulted in a relatively high CT of 65 MPa, which was higher than the desired friability limit (48 MPa) of the target glass plate.

  In addition, it was newly discovered that the external glass scratches of about 75 μm may be caused by the exposure to environmental abrasives such as silica sand and floating debris on the mounted automobile glass (using ion exchange glass). . This depth exceeds the typical depth of the compressed layer (eg, tens of micrometers), which can lead to unexpected breakage of the glass.

  In view of the above, new methods and apparatus are needed to address specific glass applications where moderate compression stress, deep compression layer depth, and / or desirable central tension are important considerations. Has been.

  In accordance with one or more embodiments described herein, the method and apparatus provide a thin glass article having a surface compression layer from ion exchange techniques that allows scratch and impact resistance. This glass article exhibits a relatively deep compression layer depth (DOL) and becomes resistant to environmental damage. In particular, the compressive stress (CS) at the glass surface is lower than in conventional ion exchange glass, which allows the glass to pass automotive impact safety standards (such as the ECE R43 head impact test) and therefore automotive glass. Suitable for use.

  As an example, one or more embodiments are ion exchange processes for obtaining thin glasses with moderate CS and large DOL, the process comprising (i) an ion exchange step, and (ii) an annealing step May be included.

  According to one or more embodiments, the method and apparatus includes placing a glass plate in a molten salt bath such that ions in the glass plate proximate its surface are exchanged for larger ions from the molten salt bath. Dipping at one or more first temperatures for a first period, thereby (i) initial compressive stress (iCS) at the surface of the glass plate, (ii) initial depth of the compressed layer into the glass plate (IDOL), and (iii) providing a product by performing one or more treatments, including performing an ion exchange process by producing an initial central tension (iCT) in the glass plate and / or Or bring a product. The treatment further includes the step of changing the at least one of initial compressive stress (iCS), initial depth of compressed layer (iDOL), and initial median tension (iCT) after the ion exchange process is completed. The method may further include annealing the glass plate by heating the glass plate to one or more second temperatures over a period of time.

The treatment includes, during the ion exchange process, (i) the molten salt bath comprises KON 3 , (ii) the one or more first temperatures are in the range of about 370-500 ° C., and (Iii) The first period may further provide at least one of being in the range of about 4-24 hours, such as about 8 hours.

  The treatment includes, during the annealing step, (i) the annealing step is performed in an air environment, (ii) the one or more second temperatures are in the range of about 400-550 ° C., and ( iii) may further provide at least one of the second period being in the range of about 0.5-24 hours, such as about 8 hours.

  In the treatment, after the ion exchange process, the initial compressive stress (iCS) exceeds a predetermined value, and after the annealing step, the initial compressive stress (iCS) is equal to or less than the predetermined value. It may further provide a reduction.

  In the treatment, after the ion exchange process, the initial depth (iDOL) of the compressed layer is less than a predetermined value, and after the annealing step, the initial depth (iDOL) of the compressed layer is not less than the predetermined value. Increasing to the final depth (fDOL) of the compression layer may further be provided.

  In the treatment, after the ion exchange process, the initial central tension (iCT) exceeds a predetermined value, and after the annealing step, the initial central tension (iCT) is equal to or less than the predetermined value. It may further provide a reduction.

  The treatment may further provide that the initial compressive stress (iCS) is about 500 MPa or more and the final compressive stress (fCS) is about 400 MPa or less, such as less than about 350 MPa, or less than about 300 MPa. .

  The treatment includes an initial depth (iDOL) of the compressed layer of about 75 μm or less, typically about 40 μm, and a final depth (fDOL) of the compressed layer of about 90 μm or more, or about 80 μm or more. That may provide further.

  The treatment is such that the initial median tension (iCT) is greater than or equal to a selected desired friability limit of the glass plate and the final compressive stress (fCS) is greater than the selected friability of the glass plate. It may further provide that it is below the limit.

  By way of example, an apparatus manufactured using one or more embodiments described herein has been subjected to ion exchange that is (i) less than about 400 MPa, or less than about 350 MPa, or less than about 300 MPa. A compression stress (CS) on the surface of the glass plate, (ii) a depth (DOL) of the compression layer in the glass plate that is about 80 μm or more, or about 90 μm or more, and (iii) It may include a glass plate having a central tension (CT) within the glass plate that is below the selected friability limit.

  Exemplary embodiments can be designed and manufactured with appropriate surface compressive stress levels in the two layers to ensure fracture when evaluated in the ECE R43 head form test, such as “Gorilla” glass A lightweight glass laminate having at least one layer of chemically strengthened glass is provided. Additional embodiments may include two layers of 0.7 mm thick chemically strengthened glass having a surface residual CS of about 250 MPa to about 350 MPa, preferably about 300 MPa, and having a DOL of at least 60 micrometers. These two glass layers can then be joined by an interlayer material such as, but not limited to, a 0.8 mm thick polyvinyl butyral or other polymeric interlayer material.

  Another embodiment provides a laminated structure having a first glass layer, a second glass layer, and at least one polymeric interlayer between the first and second glass layers. The first glass layer can be composed of a thin chemically strengthened glass having a surface compressive stress between about 250 MPa and about 350 MPa and a layer depth (DOL) of compressive stress greater than about 60 μm.

  Yet another embodiment provides a laminated structure having a first glass layer, a second glass layer, and at least one polymeric interlayer between the first and second glass layers. The first glass layer may be composed of a thin chemically strengthened glass having a surface compressive stress between about 250 MPa and about 350 MPa and a layer depth (DOL) of compressive stress greater than about 60 μm. The layer can be composed of a thin chemically strengthened glass having a DOL with a surface compressive stress between about 250 MPa and about 350 MPa and a compressive stress greater than about 60 μm.

  Other aspects, features, and advantages of the embodiments disclosed and discussed herein will become apparent to those skilled in the art from the present description, taken together with the accompanying drawings.

For the purpose of illustration, the presently preferred form is shown in the drawings, but it will be understood that the embodiments disclosed and discussed herein are not limited to the precise arrangements and instrumentalities shown.
A flow diagram illustrating one or more process steps that may be performed in accordance with one or more embodiments disclosed herein. Graph showing changes in one or more features of a glass sheet that has been subjected to one or more of the process steps of FIG. Graph showing changes in compressive stress on the surface of a glass plate that has been subjected to one or more of the process steps of FIG. A graph showing the change in crushing load for several glass plates subjected to one or more of the process steps of FIG. 1 compared to an untreated glass plate Cross-sectional view of some embodiments of the present disclosure Perspective view of additional embodiments of the present disclosure Graph showing residual strength data for some embodiments of the present disclosure

  In the following description, like reference characters refer to like or corresponding parts throughout the several views shown in the drawings. It will also be understood that terms such as “top”, “bottom”, “outside”, “inside”, etc., are words for convenience and should not be construed as limiting terms unless otherwise specified. Moreover, whenever a group is described as including at least one of a plurality of elements and combinations thereof, the groups are listed individually, or in combination with each other. It will also be understood that any number of the elements may include, consist essentially of, or consist of.

  Similarly, whenever a group is described as consisting of at least one of a plurality of elements and combinations thereof, the groups are listed individually, or in combination with each other. It will be understood that any number of elements may be used. Unless otherwise stated, a range of values, when listed, includes both the upper and lower limits of the range. As used herein, a singular noun means “at least one” or “one or more”, unless stated otherwise.

  The following description of the present disclosure is provided as teachings for its realization and its best known embodiments. Those skilled in the art will recognize that many changes can be made to the embodiments described herein while still obtaining the beneficial results of the present disclosure. It will also be apparent that some of the desired benefits of the present disclosure can be obtained by selecting some of the features of the present disclosure without using other features. Accordingly, those skilled in the art will recognize that many modifications and applications of the present disclosure are possible and may even be desirable in certain circumstances and are part of the present disclosure. Accordingly, the following description is provided as illustrative of the principles of the present disclosure and not in limitation thereof.

  Those skilled in the art will appreciate that many modifications to the exemplary embodiments described herein are possible without departing from the spirit and scope of the disclosure. Accordingly, the description is not intended to be limited to the examples given, and should not be construed as such, and is intended to provide all of the protection afforded by the appended claims and their equivalents. A range should be granted. Moreover, some of the features of the present disclosure can be used without correspondingly using other features. Accordingly, the foregoing description of the illustrative or illustrative embodiments is provided for the purpose of illustrating the principles of the present disclosure and not limitation thereof, and may include modifications and substitutions thereof.

  Referring to the drawings wherein like numerals indicate like elements, a flow diagram illustrating one or more process steps that can be performed in accordance with one or more embodiments disclosed herein is shown in FIG. Yes.

  Embodiments herein include comparisons having specific characteristics such as relatively moderate compressive stress (CS), relatively deep compressive layer depth (DOL), and / or moderate central tension (CT). Including the application of one or more new processes to produce a thin glass sheet (about 2 mm or less). The process begins with the preparation of a glass plate that can be ion exchanged (step 100). Details about the nature of the glass plate with respect to ion exchange are discussed later herein. Next, an ion exchange process is performed on the glass plate (step 102), and then an annealing process is performed on the glass plate (step 104).

The ion exchange process 102 may include at least one of the following: (i) exposing the glass plate to a molten salt bath containing KNO 3 , preferably relatively pure KNO 3 , (ii) about 400-500 ° C. One or more first temperatures within a range of, and (iii) a first period within a range of about 4-24 hours, such as about 8 hours. Note that other salt bath compositions are possible and considering such alternatives would be within the level of skill in the art. This ion exchange process comprises (i) an initial compressive stress (iCS) on the surface of the glass plate, (ii) an initial depth of the compressive layer in the glass plate (iDOL), and (iii) an initial median tension in the glass plate ( iCT).

  In general, after the ion exchange process, the initial compressive stress (iCS) is likely to exceed a predetermined (or desired) value, such as about 500 MPa or more, typically reaching 600 MPa or more, and in certain glasses It can even reach 1000 MPa or more under the profile. Alternatively and / or additionally, after the ion exchange process, the initial depth (iDOL) of the compressed layer is about 75 μm or less, or in certain glasses, under certain processing profiles, such as a lower value, etc. Is likely to be smaller than Alternatively and / or additionally, after the ion exchange process, the initial median tension (iCT) may be about 40 MPa or more, or in some glasses, especially about 48 MPa or more, for the selected friability of the glass plate. It is likely that a predetermined (or desired) value will be exceeded, such as exceeding a limit.

  The initial compressive stress (iCS) may exceed a desired value, the initial depth (iDOL) of the compressed layer may be lower than the desired value, and / or the initial median tension (iCT) exceeds the desired value Due to the fact that it may, certain undesirable features may result in the final product produced using this glass sheet. For example, if the initial compressive stress (iCS) exceeds a desired value (eg, reaches 1000 MPa), the glass may not break under certain circumstances. Such may be counterintuitive, but in certain situations, such as automotive glass applications where the glass must break under certain impact loads to prevent injury, it is desirable for the glass plate to break. May be.

  Further, if the initial depth (iDOL) of the compressed layer is less than the desired value, under certain circumstances, the glass sheet may break unexpectedly under undesirable circumstances. In fact, a typical ion exchange process results in an initial depth (iDOL) of the compressed layer of about 70-75 μm or less, which can include scratches, small dents, dents, etc. that can occur in glass plates during use. Will be less than the depth of. For example, our experiments have shown that mounted automotive glass panes (using ion exchange glass) can be exposed to abrasives such as silica sand and floating debris in environments where glass plates are used. It has been discovered that external scratches reaching depths of about 75 μm or more can occur. This depth will be well beyond the typical depth of the compressed layer, which may cause the glass to unexpectedly break into multiple pieces during use.

Finally, if the initial median tension (iCT) exceeds a desired value, such as reaching or exceeding the selected friability limit of the glass, the glass plate unexpectedly falls under undesirable circumstances. It may break. For example, we have experimentally shown that a 4 inch × 4 inch (about 10 cm × about 10 cm) × 0.7 mm plate of “Corning” “Gorilla” Glass is a long single step ion exchange process (475) in pure KNO 3. It has been discovered that when performed at 8 ° C for 8 hours, it exhibits performance characteristics that result in undesired crushing (energy breaking into numerous pieces during crushing). Although a DOL of about 101 μm was achieved, a relatively high CT of 65 MPa occurred, which was higher than the selected friability limit (48 MPa) of the subject glass plate.

  However, according to one or more embodiments, after performing ion exchange on a glass plate, the glass plate is heated to one or more second temperatures over a second period. Thus, the annealing process 104 is performed. For example, the annealing process 104 may include at least one of the following: (i) the process is performed in an air environment; (ii) the one or more second temperatures are about 400-500 ° C. And (iii) the second period is in the range of about 4-24 hours, such as about 8 hours. This annealing process 104 changes at least one of initial compressive stress (iCS), initial depth of compressed layer (iDOL), and initial median tension (iCT).

  For example, after the annealing process 104, the initial compressive stress (iCS) has decreased to a final compressive stress (fCS) that is less than or equal to the predetermined value. As an example, the initial compressive stress (iCS) may be about 500 MPa or more, but the final compressive stress (fCS) may be about 400 MPa or less, about 350 MPa or less, or about 300 MPa or less. The goal of the final compressive stress (fCS) is to be a function of the glass thickness since a smaller fCS may be desirable for thicker glass and a larger fCS may be allowed for thinner glass. It should be noted.

  In addition and / or alternatively, after the annealing process 104, the initial depth (iDOL) of the compressed layer is increased to a final depth (fDOL) of the compressed layer that is greater than or equal to the predetermined value. As an example, the initial depth (iDOL) of the compressed layer may be about 75 μm or less, and the final depth (fDOL) of the compressed layer may be about 80 μm or 90 μm or more, such as 100 μm or more.

  Additionally and / or alternatively, after the annealing process 104, the initial median tension (iCT) may be reduced to a final median tension (fCT) that is less than or equal to the predetermined value. As an example, the initial median tension (iCT) may be greater than or equal to the selected friability limit (such as between about 40-48 MPa) of the glass plate, and the final median tension (fCT) is Below the selected friability limit.

In order to explain the above-described characteristics of the glass plate between the pre-annealing condition and the post-annealing condition, reference is made to FIG. This figure is a graph showing changes in potassium profile in a glass plate. The glass plate is a “Corning” “Gorilla” Glass 4 inch × 4 inch (about 10 cm × about 10 cm) × 0.7 mm plate in a KNO 3 molten salt bath at 460 ° C. for 6 hours. Ion exchange was performed, followed by annealing in air at 455 ° C. for 6 hours. The plot marked A shows a simulation of the potassium profile in the glass plate after ion exchange but before the annealing process. The plot with B shows a simulation of the potassium profile in the glass plate after the annealing process. These potassium profiles are shown as diffusion depth expressed in concentration (normalized units) vs. μm. In particular, after the annealing process, the surface concentration has decreased significantly (a corresponding decrease in compressive stress) and the diffusion depth has increased.

To further illustrate the change in the characteristics of the glass plate between the pre-anneal and post-anneal conditions, refer to FIG. This figure is a graph showing changes in the compressive stress (CS) of the surface of several glass plates subjected to different annealing conditions. Each glass plate was formed from “Corning” “Gorilla” Glass to a size of 4 inches × 4 inches (about 10 cm × about 10 cm) × 0.7 mm. Each plate was subjected to ion exchange in a molten salt bath of KNO 3 at 460 ° C. for 6 hours, followed by annealing in air at various temperatures for 6 hours. The various annealing temperatures were 350 ° C, 375 ° C, 400 ° C, and 420 ° C. Each glass plate started with an initial compressive stress (iCS) of about 760 MPa immediately after the ion exchange process. However, during the annealing process, each glass plate exhibited a decrease in compressive stress as a function of time and temperature, resulting in a final compressive stress (fCS) significantly lower than iCS.

To further illustrate the change in the characteristics of the glass plate between the pre-anneal and post-anneal conditions, reference is made to FIG. This figure is a graph showing changes in fracture load for several glass plates subjected to ion exchange and then annealed. Each glass plate was formed from “Corning” “Gorilla” Glass to a size of 4 inches × 4 inches (about 10 cm × about 10 cm) × 0.7 mm. Each plate was subjected to ion exchange in a molten salt bath of KNO 3 at 465 ° C. for 8 hours, followed by annealing in air at 460 ° C. for 5.5 hours. Glass was tested for polished ring-on-ring breaking load. The baseline is shown by the plot labeled A, which shows the fracture characteristics of 10 as-drawn glass plates. Plot A shows an average failure load of 7.144 kg, a standard deviation of 0.4355, an AD value of 0.335, and a P value of 0.430. Twelve glasses were tested after ion exchange but not annealed, with an average breaking load of 111.3 kg, a standard deviation of 8.713, 0.001 as shown in the plot labeled C. It was found to show an AD value of 321 and a P value of 0.482. After ion exchange and annealing, 12 glass plates were tested and, as shown in the plot labeled B, an average failure load of 48.72 kg, a standard deviation of 2.681, an AD value of 1.085, and It was found to show a P value of 0.005.

  According to the general approach to establishing the parameters of the ion exchange process and annealing process, the conditions for each process step include the desired compressive stress (CS) at the glass surface, the desired depth (DOL) of the compressed layer, and the desired Adjusted based on central tension (CT). In the ion exchange process, time and temperature are selected based on known experimental response models for reaching a particular DOL. The annealing process time and temperature are then selected to achieve the desired final values of compressive stress (CS), compressive layer depth (DOL), and median tension (CT). Air annealing processes are generally less expensive than ion exchange processes due to simpler capital equipment and reduced consumable costs, so the time and temperature parameters of ion exchange vs. anneal each will reduce throughput and cost. Can be balanced to optimize.

Example 1
In the first embodiment, a “Corning”, “Gorilla” Glass (code 2318) 4 inch × 4 inch (about 10 cm × about 10 cm) × 0.7 mm glass plate was subjected to 100% at 460 ° C. for 6 hours. Ion exchange in a molten salt bath of KNO 3 was performed, followed by annealing in air at 455 ° C. for 6 hours.

  After ion exchange but before annealing, the glass plate exhibited an initial compressive stress (iCS) of about 620 MPa and an initial depth (iDOL) of the compressed layer of about 71.5 μm. Although this iDOL was lower than would be desirable in the final article, according to the embodiments discussed herein, it was known that the DOL would increase during the annealing process. The temperature of the ion exchange process was chosen to reach the iDOL target in a reasonable time with respect to manufacturing throughput, but was below 480 ° C. to limit degradation of the drug bath. It should be noted that the compressed layer depth (DOL) may be measured from the refractive index of the glass, such as using FSM-6000 or equivalent. The so-called “true DOL” in terms of physical performance, defined as the depth at which internal stress changes from compression to tension, appears to be shallower for most if not all glasses.

  After ion exchange but before annealing, the glass plate exhibits an initial compressive stress (iCS) that is lower than desired in the final product and lower than would be achieved in a glass plate ion exchanged to a shallower iDOL. It was. However, this iCS was still significant, i.e. about 620 MPa in this example. As mentioned above, the temperature of the ion exchange process has been chosen to reach the iDOL target, but such a choice also affects iCS, so such a choice can set process parameters. It should be noted that this may be a matter for consideration.

After ion exchange but before annealing, the glass plate exhibited a relatively high median tension (iCT), which was higher than desired in the final article. However, it has been found that CT will decrease during the annealing process. iCT was about 56 MPa in this example. At such a high CT (beyond the selected friability limit of the glass), if the flaw penetrates the DOL, the glass will break due to the stored energy from the CT. It has been shown that above a certain minimum CT, the number of pieces of broken glass is proportional to CT 4 and thus a high CT would be undesirable. The critical CT for breaking into multiple pieces varies with the thickness of the glass. Experiments have shown that a 0.7 mm thick glass plate of Code 2318 glass does not break into a large number of small pieces from a single sharp flaw at CT below 48 MPa. As mentioned above, the temperature of the ion exchange process has been chosen to reach the iDOL target, but such a choice also affects iCT, and thus such a choice can set process parameters. It should be noted that this may be a matter for consideration.

In particular, central tension (CT) is a dominant factor in determining failure behavior. CT is often approximated as CT = (CS * DOL) / (L-2 * DOL), where L is the glass thickness. This approximation becomes increasingly inaccurate as the DOL increases and the concentration profile gradually changes during the annealing process. A more accurate measure of the median tension (CT) is the internal stress required for the total stress in the part to be zero.

  As described above, the post ion exchange annealing process serves to increase iDOL while lowering iCS and iCT. After 6 hours of annealing at 455 ° C., the final compressive stress (fCS) was about 227 MPa, the final depth of the compressed layer (fDOL) was about 100 μm, and the final central tension (fCT) was 42 MPa. The annealing process time was equal to the ion exchange period to balance manufacturing throughput requirements. The temperature was selected to achieve a final depth (fDOL) of the compressed layer of about 100 μm and a final median tension (fCT) of less than about 48 MPa. The specific temperature may be estimated by simulation or trial and error. The final compressive stress (fCS) remains higher than that of untreated or thermally tempered glass, and the resulting fDOL is that of flaws typically found in certain applications such as automotive glass. It was bigger than the depth. Therefore, if the number penetrates fDOL, a low fCT should prevent undesired breakage of the glass, which can obstruct vision or cause glass fragments to scatter. The reduction in fCS reduces the load at which the glass breaks to the desired level.

Example 2
In a second example, 100% KNO 3 melted at 420 ° C. for 9.5 hours on several glass plates of “Corning” “Gorilla” Glass (code 2318) 1100 × 500 mm × 0.7 mm. Ion exchange in a salt bath was performed. This produced an initial compressive stress (iCS) of about 630 MPa and an initial depth (iDOL) of the compressed layer of about 57 μm on each glass plate. Two of the glass plates were not annealed and were bonded together using PVB. Ten of the glass plates were annealed in air at 420 ° C. for 10 hours, and the 10 plate pairs were bonded together using PVB. This annealing resulted in a final compressive stress (fCS) of about 290 MPa and a final depth (fDOL) of the compressed layer of about 92 μm in each glass plate.

  Each laminated structure was subjected to an automobile impact safety standard test, that is, an ECE (United Nations European Economic Commission) R43 head impact test. This test involves dropping a 10 Kg wooden head from a height of 1.5 meters onto each laminated structure. In order to pass this test, the laminated structure must flex and fracture and exhibit a number of circular cracks centered about the point of impact. Due to the high strength (high iCS) of the laminated structure that was not subjected to the annealing process, this structure failed to break within limits during testing. However, each of the five laminated structures subjected to the annealing process was crushed within specified limits and passed regulatory tests.

  The process described herein can form a thin glass article with a surface compression layer, allowing for high residual strength and impact resistance over untempered glass. The final compressive stress (fCS) at the glass surface is lower than in conventional ion exchange, so the glass can pass the maximum strength and friability limits in applications where this is desirable. However, the glass also maintains a deep final depth (fDOL) of the compression layer, making the glass resistant to environmental damage.

  The process described here will be suitable for a wide range of applications. One particularly interesting application is automotive glazing, which can produce glass that can pass automotive impact safety standards. Other uses will be identified by those skilled in the art.

  FIG. 5 is a cross-sectional view of some embodiments of the present disclosure. FIG. 6 is a perspective view of an additional embodiment of the present disclosure. Referring to FIGS. 5 and 6, an exemplary embodiment can include two layers of chemically strengthened glass, eg, “Gorilla” Glass, that has been heat treated, ion exchanged, and annealed as described above. Exemplary embodiments can have a surface compressive or compressive stress of about 300 MPa and a DOL greater than about 60 micrometers. In a preferred embodiment, the laminate 10 comprises a glass outer layer 12 having a thickness of 1.0 mm or less and having a residual surface CS level of about 250 MPa to about 350 MPa with a DOL greater than 60 micrometers. it can. In another embodiment, the CS level of the outer layer 12 is preferably about 300 MPa. The laminated plate 10 includes a polymer interlayer 14 and an inner glass layer 16 having a residual surface CS level of about 250 MPa to about 350 MPa at a DOL of more than 60 micrometers, also having a thickness of 1.0 mm or less. It also has. In another embodiment, the CS level of the inner layer 16 is preferably about 300 MPa. In one embodiment, the interlayer 14 can have a thickness of about 0.8 mm. Exemplary interlayer 14 may include, but is not limited to, polyvinyl butyral or other suitable polymeric material. In additional embodiments, either the outer layer 12 and / or the surface of the inner layer 16 can be acid etched to improve durability against external impact events. For example, in one embodiment, the first surface 13 of the outer layer 12 is acid etched and / or another surface 17 of the inner layer is acid etched. In another embodiment, the second surface 15 of the outer layer is acid etched and / or another surface 19 of the inner layer is acid etched. Thus, such an embodiment can provide a laminated structure that is substantially lighter than conventional laminated structures and that meets regulatory impact requirements.

  In another embodiment of the present disclosure, at least one layer of thin but high strength glass can be used to construct an exemplary laminated structure. In such embodiments, chemically tempered glass, such as “Gorilla” Glass, can be used for the glass outer layer 12 and / or inner layer 16 of the exemplary laminate 10. In another embodiment, the inner glass layer 16 can be conventional soda-lime glass, annealed glass, or the like. Exemplary thicknesses of outer layer 12 and / or inner layer 16 can range from 0.55 mm to 1.5 mm to 2.0 mm or more. In addition, the thicknesses of the outer layer 12 and the inner layer 16 can be different in the laminate 10. An exemplary glass layer is a fusion draw method, as described in U.S. Pat. Nos. 7,666,511, 4,483,700, and 5,674,790, all of which are hereby incorporated by reference. Such a sheet-drawn glass can be manufactured by chemically strengthening. Thus, the exemplary glass layers 12 and 16 can have a deep DOL of CS and can exhibit high bending strength, scratch resistance and impact resistance. Exemplary embodiments can include acid-etched or flame-treated surfaces to increase impact resistance, and the strength of such surfaces reduces the size and extent of scratches on these surfaces. Increase by letting If etched immediately prior to lamination, the enhanced benefit of etching or flame treatment can be maintained on the surface bonded to the interlayer.

  One embodiment of the present disclosure relates to a laminated structure having a first glass layer, a second glass layer, and at least one polymer interlayer in between the first and second glass layers. This first glass layer can be composed of a thin chemically strengthened glass having a surface compressive stress between about 250 MPa and about 350 MPa and a CS layer depth (DOL) greater than about 60 μm. In another embodiment, the second glass layer comprises a thin chemically strengthened glass having a surface compressive stress between about 250 MPa and about 350 MPa and a CS layer depth (DOL) greater than about 60 μm. Can do. The preferred surface compressive stress of the first and / or second glass layer may be about 300 MPa. In some embodiments, the thickness of the first and / or second glass layer is 1.5 mm or less, 1.0 mm or less, 0.7 mm or less, 0.5 mm The following thicknesses may be in the range of about 0.5 mm to about 1.0 mm, about 0.5 mm to about 0.7 mm. Of course, the thickness and / or composition of the first and second glass layers can be different from each other. In addition, the surface of the first glass layer opposite to the intermediate film may be acid-etched, and the surface of the second glass layer adjacent to the intermediate film may be acid-etched. Exemplary polymeric interlayers include, but are not limited to, polyvinyl butyral (PVB), polycarbonate, sound insulation PVB, ethylene vinyl acetate (EVA), thermoplastic polyurethane (TPU), ionomers, thermoplastic materials, and combinations thereof Including materials such as.

  Another embodiment of the present disclosure is directed to a laminated structure having a first glass layer, a second glass layer, and at least one polymeric intermediate film intermediate the first and second glass layers. The first and second glass layers can be composed of a thin chemically strengthened glass having a surface compressive stress between about 250 MPa and about 350 MPa and a compressed layer depth (DOL) greater than about 60 μm. The preferred surface compressive stress of the first and / or second glass layer may be about 300 MPa. In some embodiments, the thickness of the first and / or second glass layer is 1.5 mm or less, 1.0 mm or less, 0.7 mm or less, 0.5 mm The following thicknesses may be in the range of about 0.5 mm to about 1.0 mm, about 0.5 mm to about 0.7 mm. Of course, the thicknesses of the first and second glass layers may be different from each other. In addition, the surface of the first glass layer opposite to the intermediate film may be acid-etched, and the surface of the second glass layer adjacent to the intermediate film may be acid-etched. In another embodiment, the surface of the first glass layer in contact with the intermediate film may be acid-etched, and the surface of the second glass layer opposite to the intermediate film may be acid-etched. There is no problem. Exemplary polymeric interlayers include, but are not limited to, polyvinyl butyral (PVB), polycarbonate, sound insulation PVB, ethylene vinyl acetate (EVA), thermoplastic polyurethane (TPU), ionomers, thermoplastic materials, and combinations thereof Including materials such as.

  Due to concerns regarding the damage level of crash damage to automobile occupants, automotive glass sheet products are required to be relatively susceptible to breakage. For example, in ECE R43 Amendment 2, when an impact is applied to the laminate from an internal object (due to the head of the occupant in collision), the laminate dissipates energy during the event, causing injury to the occupant. There is a requirement that it should be crushed to minimize the fear of This requirement generally avoids the direct use of high strength glass as both layers of the laminated structure. A book with one or more layers of chemically strengthened glass having a residual surface compressive stress of about 250 MPa to about 350 MPa, preferably about 300 MPa, with a glass thickness of about 0.7 mm for each layer by extensive head testing. It has been found that the exemplary laminated structure according to the disclosed embodiments always meets the requirements of these tests.

  With continued reference to FIG. 6, an outer glass layer 12 having a thickness of 1.0 mm or less, a DOL greater than about 60 micrometers, and a residual surface CS level of about 250 MPa to about 350 MPa, a polymer interlayer 14, And implementation of another exemplary laminated structure 10 having a glass inner layer 16 having a residual surface CS level of about 250 MPa to about 350 MPa with a DOL greater than about 60 micrometers and a DOL greater than about 60 micrometers. The form of is shown. As shown, the laminated structure 10 can be flat or formed into a three-dimensional shape by bending the molded glass into a windshield or other glass structure used in vehicles. .

  FIG. 7 is a graph illustrating residual strength data for some embodiments of the present disclosure. Referring to FIG. 7, there is a box plot of residual strength data measured with a single layer ring-on-ring of glass after scratching with a Knoop indenter at various loads (3N, 5N, 7N and 10N). ing. This graph provides an explanation of the benefits of extending the depth of the compression layer by using the exemplary post ion exchange and annealing process to create a final residual stress profile in the glass layer described above. FIG. 7 provides a plot of the residual strength (measured by ring-on-ring) of glass scratched by a diamond-knoop indenter at various load levels (3N, 5N, 7N and 10N). A typical ion-exchanged “Gorilla” Glass with a residual surface stress level of approximately CS = 700 and DOL = 45 μm cannot withstand 10 N scratch, while post-ion exchange with CS = 300 and DOL = 70 μm The glass withstood such damage. Thus, embodiments of the present disclosure are more than in conventional products to achieve mass reduction while maintaining the desired controlled crushing behavior when impacted from the inside of the vehicle. Even a thin glass layer could be used.

Further Details on Ion Exchange—Glass Composition As noted above, the conditions for the ion exchange glass and annealing steps are the desired compressive stress (CS) on the glass surface, the desired depth of the compressed layer (DOL), and the desired Adjusted to achieve central tension (CT). While all such features are important, the ion exchange process is specifically directed to the depth (DOL) of the compressed layer.

This ion exchange step is performed by immersing the glass plate in a molten salt bath for a predetermined period of time, during which the ions in or near the surface in the glass plate are removed from the salt bath, for example. Exchanged for larger ions. As an example, the molten salt bath may contain KNO 3 , the temperature of the molten salt bath may be in the range of about 400-500 ° C., and the predetermined period is in the range of about 4-24 hours, preferably about May be between 4-10 hours. As larger ions are incorporated into the glass, the plate is strengthened by the formation of compressive stresses in areas near the surface. In order to balance this compressive stress, a corresponding tensile stress is produced in the central region of the glass plate.

As yet another example, sodium ions in the glass plate may be replaced by potassium ions from the molten salt bath, but other alkali metal ions with larger atomic radii, such as rubidium or cesium, may be Smaller alkali metal ions may be substituted. According to certain embodiments, smaller alkali metal ions in the glass plate may be replaced by Ag + ions. Similarly, other alkali metal salts such as, but not limited to, sulfates and halides may be used in the ion exchange process.

  Replacing smaller ions with larger ions at a temperature below that at which the glass network can relax results in an ion distribution that results in a stress profile across the surface of the glass plate. Due to the larger volume of ions entering, compressive stress (CS) occurs on the surface of the glass and tension (central tension, or CT) occurs in the central region of the glass. This compressive stress is related to the median tension by the following approximate relation:

Where t is the total thickness of the glass plate and DOL is the exchange depth, also referred to as the depth of the compression layer.

  Any number of specific glass compositions may be used to produce the glass plate. For example, ion-exchangeable glasses suitable for use in the embodiments described herein include alkali aluminosilicate glass or alkali aluminoborosilicate glass, but other glass compositions are also contemplated. As used herein, “ion exchangeable” means that a glass can exchange cations located at or near the surface of the glass with cations of the same valence that are larger or smaller in size. To do.

For example, a suitable glass composition includes SiO 2 , B 2 O 3 and Na 2 O, where (SiO 2 + B 2 O 3 ) ≧ 66 mol% and Na 2 O ≧ 9 mol%. In certain embodiments, the glass plate comprises at least 6% by weight aluminum oxide. In yet another embodiment, the glass plate comprises one or more alkaline earth oxides such that the alkaline earth oxide content is at least 5% by weight. Suitable glass compositions further include at least one of K 2 O, MgO, and CaO in some embodiments. In a special embodiment, the glass comprises 61-75 mol% SiO 2 , 7-15 mol% Al 2 O 3 , 0-12 mol% B 2 O 3 , 9-21 mol% Na 2 O. , 0-4 mol% of K 2 O, no problem include 0-7 mol% of MgO, and 0-3 mol% of CaO.

The glass composition of a further example suitable for forming a hybrid glass laminate, 60-70 mol% of SiO 2, having 6 to 14 mol% of Al 2 O 3, 0 to 15 mol% of B 2 O 3, 0 to 15 mol% of Li 2 O, 0 to 20 mol% of Na 2 O, 0 mol% of K 2 O, 0 to 8 mol% of MgO, 0 mol% of CaO, 0 to 5 mol% ZrO 2 , 0-1 mol% SnO 2 , 0-1 mol% CeO 2 , less than 50 ppm As 2 O 3 , and less than 50 ppm Sb 2 O 3 , where 12 mol% ≦ (Li 2 O + Na 2 O + K 2 O) ≦ 20 mol%, and 0 mol% ≦ (MgO + CaO) ≦ 10 mol%.

Furthermore glass composition of another example, 63.5 to 66.5 mol% of SiO 2, 8 to 12 mol% of Al 2 O 3, 0 to 3 mol% of B 2 O 3, 0 to 5 mol % of Li 2 O, 8 to 18 mol% of Na 2 O, 0 to 5 mol% of K 2 O, 1 to 7 mol% of MgO, 0 to 2.5 mol% of CaO, from 0 to 3 mol% ZrO 2 , 0.05-0.25 mol% SnO 2 , 0.05-0.5 mol% CeO 2 , less than 50 ppm As 2 O 3 , and less than 50 ppm Sb 2 O 3 , wherein 14 mol% ≦ (Li 2 O + Na 2 O + K 2 O) ≦ 18 mol%, and 2 mol% ≦ (MgO + CaO) ≦ 7 mol%.

In another embodiment, the alkali aluminosilicate glass is 61 to 75 mol% of SiO 2, 7 to 15 mol% of Al 2 O 3, 0 to 12 mol% of B 2 O 3, 9 to 21 mol% of Na 2 O, 0 to 4 mol% of K 2 O, 0 to 7 mol% of MgO, and containing 0-3 mole% of CaO, it consists essentially of, or consisting of.

In particular embodiments, the alkali aluminosilicate glass comprises alumina, at least one alkali metal, and in some embodiments, greater than 50 mole percent SiO 2 , in other embodiments, at least 58 mole percent. SiO 2 , and in yet another embodiment, at least 60 mol% SiO 2 , where the ratio (Al 2 O 3 + B 2 O 3 ) / Σ modifier> 1, The components are expressed in mole percent and the modifier is an alkali metal oxide. This glass is, in a special embodiment, 58-72 mol% SiO 2 , 9-17 mol% Al 2 O 3 , 2-12 mol% B 2 O 3 , 8-16 mol% Na 2. O, and it includes a 0-4 mole% of K 2 O, substantially made from, or made, the ratio (Al 2 O 3 + B 2 O 3) / Σ modifier> 1.

In yet another embodiment, the alkali aluminosilicate glass substrate, 60 to 70 mol% of SiO 2, having 6 to 14 mol% of Al 2 O 3, 0 to 15 mol% of B 2 O 3, 0 to 15 mol% of Li 2 O, 0 to 20 mol% of Na 2 O, 0 mol% of K 2 O, 0 to 8 mol% of MgO, 0 mol% of CaO, 0 to 5 mol% of ZrO 2 , comprising 0-1 mol% SnO 2 , 0-1 mol% CeO 2 , less than 50 ppm As 2 O 3 , and less than 50 ppm Sb 2 O 3 , consisting essentially of or consisting of 12 mol% ≦ Li 2 O + Na 2 O + K 2 O ≦ 20 mol%, and 0 mol% ≦ MgO + CaO ≦ 10 mol%.

In yet another embodiment, the alkali aluminosilicate glass is 64 to 68 mol% of SiO 2, 12 to 16 mol% of Na 2 O, 8 to 12 mol% of Al 2 O 3, 0 to 3 mole% of B 2 O 3, 2 to 5 mol% of K 2 O, 4 to 6 mole% of MgO, and includes a 0-5 mole% of CaO, essentially made from, or made, where 66 mol % ≦ SiO 2 + B 2 O 3 + CaO ≦ 69 mol%, Na 2 O + K 2 O + B 2 O 3 + MgO + CaO + SrO> 10 mol%, 5 mol% ≦ MgO + CaO + SrO ≦ 8 mol%, (Na 2 O + B 2 O 3 ) ≦ Al 2 O 3 ≦ 2 mol%, 2 mol% ≦ Na 2 O ≦ Al 2 O 3 ≦ 6 mol%, and 4 mol% ≦ (Na 2 O + K 2 O) ≦ Al 2 O 3 ≦ 10 mol%.

Advantages One or more advantages of the above-described embodiments may include one or more of the following: improved residual strength and impact resistance compared to untempered glass; conventional heat of glass Relatively high compressive stress and higher compatibility with thin glass compared to mechanical tempering; relatively deep compressed layer depth compared to standard single-step ion exchange techniques; and reduced cycle time and Significantly lower cost to achieve a relatively deep DOL compared to traditional single-step ion exchange processes due to less expensive capital equipment requirements. For example, a new ion exchange process in a mixed alkaline bath (eg 50% KNO 3 + 50% NaNO 3 ) achieves lower processing costs. In particular, a sodium-containing bath can be used to achieve a lower CS, but the diffusion rate is correspondingly reduced, thus significantly increasing the time to reach a relatively deep DOL.

  While this description may contain many details, these should not be considered as limiting the scope, but rather as a description of features that may be specific to a particular embodiment. Certain features that have been described so far in the context of individual embodiments may be implemented in combination in one embodiment. Conversely, various features that are described in the context of one embodiment may be implemented separately in some embodiments or in any suitable subcombination. Moreover, while a feature may have been previously described as functioning in a particular embodiment and may even be recited in the claims per se, one or more features from a combination of claims are: In some cases, it may be deleted from the combination, and the claim combination may relate to a sub-combination or a sub-combination variant.

  Similarly, operations are shown in the drawings in a particular order, which is to ensure that such operations are performed in the particular or illustrated sequence shown, or to achieve the desired result. It should not be understood to require that all of the illustrated operations be performed. In certain circumstances, parallel work and parallel processing may be advantageous.

  Various methods for manufacturing ion exchange glass and the resulting device have been described, as illustrated by the various configurations and embodiments shown in the figures.

  While preferred embodiments of the present disclosure have been described, the described embodiments are for illustrative purposes only, and the scope of the present invention is, when the full scope of equivalents is allowed, It should be understood that it is to be defined only by the appended claims, and that many modifications and changes will naturally occur to those skilled in the art upon reading that.

10 Laminated plate or laminated structure 12 Outer layer 14 Intermediate film 16 Inner layer

Claims (10)

  1. In the laminated structure,
    A first glass layer,
    A second glass layer, and at least one polymer intermediate film intermediate the first and second glass layers;
    Have
    A laminated structure, wherein the first glass layer is composed of chemically strengthened glass having a surface compressive stress between about 250 MPa and about 350 MPa and a layer depth (DOL) of compressive stress greater than about 60 μm.
  2.   The laminated structure of claim 1, wherein the second glass layer is comprised of chemically strengthened glass having a surface compressive stress between about 250 MPa and about 350 MPa and a DOL with a compressive stress greater than about 60 μm.
  3.   The laminated structure according to claim 1, wherein the surface compressive stress of the first glass layer is about 300 MPa.
  4.   The thickness of the first and second glass layers is 1.5 mm or less, 1.0 mm or less, 0.7 mm or less, 0.5 mm or less, about 0.5 mm. The laminated structure of claim 1 selected from the group consisting of a thickness in the range of from about 1.0 mm to about 1.0 mm, and a thickness of from about 0.5 mm to about 0.7 mm.
  5.   The laminated structure according to claim 1, wherein the first and second glass layers have different thicknesses.
  6.   The laminated structure according to claim 1, wherein the compositions of the first and second glass layers are different.
  7.   The laminated structure according to claim 1, wherein a surface of the first glass layer adjacent to the intermediate film is acid-etched.
  8.   The laminated structure according to claim 1, wherein a surface of the second glass layer opposite to the intermediate film is acid-etched.
  9.   The polymer interlayer is selected from the group consisting of polyvinyl butyral (PVB), polycarbonate, sound insulation PVB, ethylene vinyl acetate (EVA), thermoplastic polyurethane (TPU), ionomer, thermoplastic material, and combinations thereof. The laminated structure according to claim 1, comprising:
  10.   The laminated structure of claim 1, wherein the first or second glass layer has a median tension (CT) less than a predetermined friability limit.
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