JP2016159212A5 - - Google Patents

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JP2016159212A5
JP2016159212A5 JP2015038688A JP2015038688A JP2016159212A5 JP 2016159212 A5 JP2016159212 A5 JP 2016159212A5 JP 2015038688 A JP2015038688 A JP 2015038688A JP 2015038688 A JP2015038688 A JP 2015038688A JP 2016159212 A5 JP2016159212 A5 JP 2016159212A5
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permeate gas
gas
separation membrane
holes
permeate
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JP2015038688A
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JP2016159212A (en
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Priority to JP2015038688A priority Critical patent/JP2016159212A/en
Priority claimed from JP2015038688A external-priority patent/JP2016159212A/en
Priority to PCT/JP2015/082378 priority patent/WO2016136048A1/en
Publication of JP2016159212A publication Critical patent/JP2016159212A/en
Publication of JP2016159212A5 publication Critical patent/JP2016159212A5/ja
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天然ガスまたは油随伴ガスに含まれる非可燃性ガスであるCO等を透過させる複数の平板状の分離膜と、複数のシーリング部材とを備え、
上記分離膜は、平板状に形成され、非透過ガスを通過させるための非透過ガス孔と、上記透過ガスを通過させるための透過ガス孔とを適宜数有し、
上記シーリング部材は、上記分離膜の輪郭形状に沿った環状の外側シール部と、該外側シール部の内側に適宜数の環状の内側シール部を有し、
上記分離膜と上記シーリング部材を交互に重ね合わせて、それぞれ隣合う分離膜とその間のシーリング部材とにより外部に対して隔絶された、非透過ガスが流入・流出する非透過ガス室と、透過ガスが流入・流出する透過ガス室を、上記分離膜の重ね合わせ方向に交互に形成し、
上記非透過ガス室のそれぞれは、その両側の分離膜の上記透過ガス孔間の連絡通路に対して、上記シーリング部材の内側シール部により隔絶され
また、上記透過ガス室のそれぞれは、その両側の分離膜の上記非透過ガス孔間の連絡通路に対して、上記シーリング部材の内側シール部により隔絶され、
もって、上記非透過ガス孔、上記透過ガス孔間の連絡通路および上記非透過ガス室によって非透過ガス流路を形成するとともに、上記透過ガス孔、上記非透過ガス孔間の連絡通路および上記透過ガス室によって透過ガス流路を形成するようにしたことを特徴とする分離器。
A plurality of plate-like separation membranes that allow CO 2 or the like, which is a non-flammable gas contained in natural gas or oil-associated gas, to pass therethrough, and a plurality of sealing members,
The separation membrane is formed in a flat plate shape, and has an appropriate number of non-permeating gas holes for allowing non-permeating gas to pass therethrough and permeating gas holes for allowing the permeating gas to pass therethrough,
The sealing member has an annular outer seal portion along the contour shape of the separation membrane, and an appropriate number of annular inner seal portions inside the outer seal portion,
A non-permeate gas chamber into which the non-permeate gas flows in and out, and the permeate gas, wherein the separation membrane and the sealing member are alternately overlapped and separated from each other by the adjacent separation membranes and the sealing member between them; Permeate gas chambers that flow in and out alternately in the overlapping direction of the separation membrane,
Each of the non-permeate gas chamber, with respect to communication passage between the transmissive gas holes on both sides of the separation membrane, is isolated by an inner sealing portion of the sealing member,
Further, each of the permeate gas chamber, with respect to communication passage between the non-permeate gas holes on both sides of the separation membrane, is isolated by an inner sealing portion of the sealing member,
Accordingly, a non-permeate gas flow path is formed by the non-permeate gas hole , the communication path between the permeate gas holes , and the non-permeate gas chamber, and the permeate gas hole , the communication path between the non-permeate gas holes, and the permeate. A separator characterized in that a permeate gas flow path is formed by a gas chamber.
上記複数の分離膜は、略矩形状に形成され、両端に位置される分離膜は3つの孔を対角の4角のうち3か所に有し、中間層の分離膜は4つの孔を対角の4角に、その上下端部の左右両端寄りに有し、この4つの孔のうち、一方の対角にある2つの孔を、上記非透過ガスを通過させるための非透過ガス孔とし、他方の対角にある2つの孔を、上記透過ガスを通過させるための透過ガス孔とし、
上記複数のシーリング部材のうち両端に配置されるシーリング部材は、上記分離膜の輪郭形状に沿った環状の外側シール部と、その一角に一つの環状の内側シール部を有し、上記複数のシーリング部材のうち中間層に配置されるシーリング部材は、上記分離膜の輪郭形状に沿った環状の外側シール部と、一方の対角に一対の環状の内側シール部を有し、
上記一対の非透過ガス孔のうち、一方の非透過ガス孔を、上記非透過ガス室に非透過ガスを流入させる非透過ガス流入孔として上記分離膜の一端部に配設するとともに、他方の非透過ガス孔を、上記非透過ガス室から非透過ガスを流出させる非透過ガス流出孔として上記分離膜の他端部に配設し、
他方、該一対の透過ガス孔のうち、その一方の透過ガス孔を、上記透過ガス室に透過ガスを流入させる透過ガス流入孔として上記分離膜の他端部に配設するとともに、その他方の透過ガス孔を、上記透過ガス室から透過ガスを流出させる透過ガス流出孔として上記分離膜の一端部に配設した構成とし、
もって、上記非透過ガス流路および上記透過ガス流路を並列に形成したことを特徴とする請求項1に記載の分離器。
The plurality of separation membranes are formed in a substantially rectangular shape, the separation membranes located at both ends have three holes in three of the four corners of the diagonal, and the separation membrane of the intermediate layer has four holes. Non-permeate gas holes for passing the non-permeate gas through two holes at one diagonal of the four holes at the diagonal four corners near the left and right ends of the upper and lower ends. And the two holes on the other diagonal are permeate gas holes for passing the permeate gas,
Sealing members disposed at both ends of the plurality of sealing members have an annular outer seal portion along the contour shape of the separation membrane, and one annular inner seal portion at one corner thereof, and the plurality of sealing members The sealing member disposed in the intermediate layer of the members has an annular outer seal portion along the outline of the separation membrane, and a pair of annular inner seal portions on one diagonal,
Of the pair of non-permeate gas holes, one of the non-permeate gas holes, while disposed at one end of the separation membrane as non-permeate gas inlet for flowing the non-permeate gas into the non-permeate gas chamber, the other A non-permeate gas hole is disposed at the other end of the separation membrane as a non-permeate gas outflow hole for allowing the non-permeate gas to flow out of the non-permeate gas chamber;
On the other hand, one of the pair of permeate gas holes is disposed at the other end of the separation membrane as a permeate gas inflow hole for allowing permeate gas to flow into the permeate gas chamber. A permeate gas hole is arranged at one end of the separation membrane as a permeate gas outflow hole for allowing the permeate gas to flow out of the permeate gas chamber ,
Therefore, the separator according to claim 1, wherein the non-permeate gas flow path and the permeate gas flow path are formed in parallel .
上記複数の分離膜は、略矩形状に形成され、2つの孔を一端部に形成した一の分離膜と、2つの孔を一側寄りに両端部に形成した二の分離膜を用い、該一および二の分離膜とも一方の孔を、非透過ガスを通過させるための非透過ガス孔とし、他方の孔を、透過ガスを通過させるための透過ガス孔とし、
上記シーリング部材は、上記一および二の分離膜の輪郭形状に沿った環状の外側シール部と、その一角に1つの内側シール部を有し、
隣合う上記一の分離膜と上記二の分離膜の間の空間が上記透過ガス室であるとき、該一の分離膜の上記非透過ガス孔を、該一の分離膜によって一部画成された上記非透過ガス室から非透過ガスを流出させる非透過ガス流出孔として該一の分離膜の他端部に形成するとともに、該一の分離膜の上記透過ガス孔を、該一の分離膜と上記二の分離膜との間の上記透過ガス室から透過ガス孔を流出させる透過ガス流出孔として、該一の分離膜の他端部に形成し、
上記二の分離膜の上記非透過ガス孔を、上記一の分離膜の上記非透過流出孔に合致させて、該二の分離膜と上記三の分離膜との間の上記非透過ガス室に非透過ガスを流入させる非透過ガス流入孔として、該二の分離膜の他端部に形成するとともに、上記二の分離膜の上記透過ガス孔を、上記一の分離膜と該二の分離膜との間の上記透過ガス室に透過ガスを流入させる透過ガス流入孔として該二の分離膜の一端部に形成し、
上記三の分離膜の上記非透過ガス孔を、上記二の分離膜と該三の分離膜との間の上記非透過ガス室から非透過ガスを流出させる非透過ガス流出孔として、該三の分離膜の一端部に形成するとともに、該三の分離膜の上記透過ガス孔を、上記二の分離膜の上記透過ガス流入孔に合致させて、該三の分離膜と四の分離膜との間の上記透過ガス室から透過ガスを流出させる透過ガス流出孔として該三の分離膜の一端部に形成し、
上記四の分離膜の上記非透過ガス孔を、上記三の分離膜の上記非透過ガス流出孔に合致させて、該四の分離膜によって一部画成された上記非透過ガス室に非透過ガスを流入させる非透過ガス流入孔として、該四の分離膜の一端部に形成するとともに、該四の分離膜の上記透過ガス孔を、上記三の分離膜と該四の分離膜との間の上記透過ガス室に透過ガスを流入させる透過ガス流入孔として該四の分離膜の他端部に、上記一の分離膜の上記透過ガス流出孔に対応する位置に形成した構成とし、
もって、上記非透過ガス流路および上記透過ガス流路を直列に形成したことを特徴とする請求項1に記載の分離器。
The plurality of separation membranes are formed in a substantially rectangular shape, using one separation membrane in which two holes are formed at one end, and two separation membranes in which two holes are formed at both ends near one side, In both the first and second separation membranes, one hole is a non-permeating gas hole for allowing a non-permeating gas to pass therethrough, and the other hole is a permeating gas hole for allowing a permeating gas to pass therethrough,
The sealing member has an annular outer seal portion along the contour shape of the one and two separation membranes, and one inner seal portion at one corner thereof.
When the space between the adjacent the one of the separation membrane and the second separation membrane is the permeate gas chamber, the non-permeate gas holes of the one of the separation membrane, made a part image by said first separation membrane And forming the non-permeate gas outflow hole from the non-permeate gas chamber as the non-permeate gas outflow hole at the other end of the one separation membrane. As a permeate gas outflow hole for allowing the permeate gas hole to flow out of the permeate gas chamber between the first separation membrane and the second separation membrane,
The non-permeating gas hole of the second separation membrane is matched with the non-permeating outflow hole of the one separation membrane, and the non-permeating gas chamber between the second separation membrane and the third separation membrane is formed. A non-permeate gas inflow hole through which the non-permeate gas flows is formed at the other end of the two separation membranes, and the permeate gas hole of the second separation membrane is formed by the one separation membrane and the second separation membrane. Formed at one end of the two separation membranes as a permeate gas inflow hole for allowing permeate gas to flow into the permeate gas chamber between
The non-permeating gas holes of the three separation membranes are used as non-permeating gas outflow holes for allowing non-permeating gas to flow out from the non-permeating gas chamber between the two separation membranes and the three separation membranes. Formed at one end of the separation membrane, and the permeation gas holes of the three separation membranes are matched with the permeation gas inflow holes of the second separation membrane, so that the three separation membranes and the four separation membranes Formed at one end of the three separation membranes as a permeate gas outflow hole for allowing the permeate gas to flow out from the permeate gas chamber between,
The non-permeating gas holes of the four separation membranes are matched with the non-permeating gas outflow holes of the three separation membranes, and are impermeable to the non-permeating gas chamber partially defined by the four separation membranes. A non-permeate gas inflow hole through which gas flows is formed at one end of the four separation membranes, and the permeate gas hole of the four separation membranes is formed between the three separation membranes and the four separation membranes. As a permeate gas inflow hole for allowing permeate gas to flow into the permeate gas chamber, the other end of the four separation membranes is formed at a position corresponding to the permeate gas outflow hole of the one separation membrane,
Accordingly, the separator according to claim 1, wherein the non-permeate gas flow path and the permeate gas flow path are formed in series .
上記複数の分離膜は、略矩形状に形成され、4つの孔を対角の4角に有し、The plurality of separation membranes are formed in a substantially rectangular shape, and have four holes at diagonal four corners,
上記複数のシーリング部材は、上記分離膜の輪郭形状に沿った環状の外側シール部と、その対角の一角に一つの環状の内側シール部を有するとともに、その対角の反対の角に、上記複数の分離膜において不要となる孔を封じるための円盤状シール部を有することを特徴とする請求項2または3に記載の分離器。  The plurality of sealing members have an annular outer seal portion along the contour shape of the separation membrane, and one annular inner seal portion at one corner thereof, and at the opposite corner to the above-mentioned 4. The separator according to claim 2, further comprising a disk-shaped seal portion for sealing unnecessary holes in the plurality of separation membranes.
上記複数の分離膜および上記複数のシーリング部材を重ね合わせ方向に圧縮する態様で、耐圧プレートをこの重ね合わせ方向両端に設置した構成とし、ことを特徴とする請求項1〜4のいずれかに記載の分離器。 5. The pressure-resistant plates are installed at both ends in the overlapping direction in a mode in which the plurality of separation membranes and the plurality of sealing members are compressed in the overlapping direction, and the structure according to claim 1, Separator. 上記分離膜は、その表面に凹凸を形成したことを特徴とする請求項1〜5のいずれかに記載の分離器。 The separator according to any one of claims 1 to 5, wherein the separation membrane has irregularities formed on a surface thereof. 上記分離膜の面のうち、一方の面には凹凸のストライプを形成し、他方の面には、該一方の面のストライプの形成方向とは異なる方向に凹凸のストライプを形成したことを特徴とする請求項1〜6のいずれかに記載の分離器。 Among the surfaces of the separation membrane, a concave / convex stripe is formed on one surface, and a concave / convex stripe is formed on the other surface in a direction different from the stripe formation direction of the one surface. The separator according to any one of claims 1 to 6 .
JP2015038688A 2015-02-27 2015-02-27 Separator Pending JP2016159212A (en)

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JP2015038688A JP2016159212A (en) 2015-02-27 2015-02-27 Separator
PCT/JP2015/082378 WO2016136048A1 (en) 2015-02-27 2015-11-18 Separator

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KR101910296B1 (en) 2017-11-17 2018-10-22 한국에너지기술연구원 Ceramic Oxygen membrane module using metal frame
EP4026609A1 (en) * 2019-09-03 2022-07-13 Kyushu University, National University Corporation Porous membrane, production method therefor, separation membrane, layered module, and gas permeation module

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