JP2016132655A - Thixotropic composition - Google Patents
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- JP2016132655A JP2016132655A JP2015010393A JP2015010393A JP2016132655A JP 2016132655 A JP2016132655 A JP 2016132655A JP 2015010393 A JP2015010393 A JP 2015010393A JP 2015010393 A JP2015010393 A JP 2015010393A JP 2016132655 A JP2016132655 A JP 2016132655A
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- hypochlorite
- chlorine dioxide
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- 239000000203 mixture Substances 0.000 title claims abstract description 55
- 230000009974 thixotropic effect Effects 0.000 title claims abstract description 29
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002734 clay mineral Substances 0.000 claims abstract description 13
- -1 sodium hypochlorite Chemical compound 0.000 claims abstract description 12
- 239000002243 precursor Substances 0.000 claims abstract description 11
- 239000005708 Sodium hypochlorite Substances 0.000 claims abstract description 10
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229940094522 laponite Drugs 0.000 claims abstract description 9
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 claims abstract description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 7
- 239000004359 castor oil Substances 0.000 claims abstract description 7
- 235000019438 castor oil Nutrition 0.000 claims abstract description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 7
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 54
- 239000004155 Chlorine dioxide Substances 0.000 claims description 27
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 27
- 239000006185 dispersion Substances 0.000 claims description 15
- 239000003381 stabilizer Substances 0.000 claims description 14
- 239000003205 fragrance Substances 0.000 claims description 8
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical group OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims description 7
- 229910001919 chlorite Inorganic materials 0.000 claims description 6
- 229910052619 chlorite group Inorganic materials 0.000 claims description 6
- 230000001954 sterilising effect Effects 0.000 abstract description 9
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 8
- 230000000843 anti-fungal effect Effects 0.000 abstract description 5
- 229940121375 antifungal agent Drugs 0.000 abstract description 5
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 5
- 239000002304 perfume Substances 0.000 abstract description 3
- 238000004332 deodorization Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 abstract description 2
- 229960002218 sodium chlorite Drugs 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 230000002155 anti-virotic effect Effects 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 description 14
- 230000001877 deodorizing effect Effects 0.000 description 8
- 239000007921 spray Substances 0.000 description 6
- 239000004480 active ingredient Substances 0.000 description 4
- 230000000840 anti-viral effect Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000001953 sensory effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- 239000004113 Sepiolite Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910001902 chlorine oxide Inorganic materials 0.000 description 2
- MAYPHUUCLRDEAZ-UHFFFAOYSA-N chlorine peroxide Chemical compound ClOOCl MAYPHUUCLRDEAZ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229910052624 sepiolite Inorganic materials 0.000 description 2
- 235000019355 sepiolite Nutrition 0.000 description 2
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical group O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- NWAPVVCSZCCZCU-UHFFFAOYSA-L magnesium;dichlorite Chemical compound [Mg+2].[O-]Cl=O.[O-]Cl=O NWAPVVCSZCCZCU-UHFFFAOYSA-L 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910000273 nontronite Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- VISKNDGJUCDNMS-UHFFFAOYSA-M potassium;chlorite Chemical compound [K+].[O-]Cl=O VISKNDGJUCDNMS-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910000276 sauconite Inorganic materials 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
本発明は、チクソ性組成物に関する。より詳細に、本発明は、抗菌、除菌、殺菌、抗カビ、抗ウイルス、消臭などに適用可能なチクソ性組成物に関する。 The present invention relates to a thixotropic composition. More specifically, the present invention relates to a thixotropic composition applicable to antibacterial, sterilizing, sterilizing, antifungal, antiviral, deodorizing and the like.
せん断力をかけ続ければ粘度が減少し続け、静置すると次第に粘度が元に戻る性質、いわゆるチクソ性を有する組成物が種々提案されている。例えば、特許文献１は、次亜塩素酸アルカリ金属塩、アルカリ剤、および無機粘土鉱物を含有する漂白剤組成物を開示している。特許文献２は、次亜塩素酸塩類と塩素酸塩類とを有効成分として含む水溶液にソヂウムモンモリロナイトを配合してなるカビ取り剤組成物を開示している。特許文献３は、次亜塩素酸塩、セピオライト鉱物、苛性ソーダ、アルキルスルホン酸ソーダ、および高アルキルジヒドロキシアルキルアミンオキシドを含有するカビ取り用組成物を開示している。特許文献４は、次亜塩素酸塩、酸化性アルカリ剤、アニオン界面活性剤、両性イオン界面活性剤、およびセピオライト系鉱物を含有する組成物を開示している。これら特許文献１〜４の組成物は漂白やカビ取りに効果があるようである。 Various compositions have been proposed which have a property that the viscosity continues to decrease if the shearing force continues to be applied, and gradually returns to its original value when left standing, so-called thixotropy. For example, Patent Document 1 discloses a bleaching composition containing an alkali metal hypochlorite salt, an alkali agent, and an inorganic clay mineral. Patent Document 2 discloses a fungicide composition obtained by blending sodium montmorillonite with an aqueous solution containing hypochlorite and chlorate as active ingredients. U.S. Patent No. 6,099,077 discloses a mold removal composition containing hypochlorite, sepiolite minerals, caustic soda, sodium alkyl sulfonate, and high alkyldihydroxyalkylamine oxide. Patent Document 4 discloses a composition containing hypochlorite, an oxidizing alkali agent, an anionic surfactant, a zwitterionic surfactant, and a sepiolite-based mineral. These compositions of Patent Documents 1 to 4 seem to be effective for bleaching and mold removal.
ところで、二酸化塩素は、殺菌作用を有する常温気体の物質である。この二酸化塩素を適時に発生させて、洗浄、消臭、抗菌、消毒などに使用することが提案されている。例えば、特許文献５は、亜塩素酸塩、酸供給源、リン酸塩および膨潤性クレイを含有する洗浄薬を開示している。特許文献６は亜塩素酸塩水溶液または安定化二酸化塩素水溶液に、活性化剤として水素塩と、ガス発生調節剤と、吸水性樹脂とを添加してゲル化させて二酸化塩素ガスを持続的に発生させる方法を開示している。特許文献７は、亜塩素酸塩、シリカゲルなどの乾燥剤、およびゼオライトなどの多孔性鉱物を含有する組成物を開示している。 By the way, chlorine dioxide is a normal temperature gaseous substance having a bactericidal action. It has been proposed that this chlorine dioxide be generated in a timely manner and used for cleaning, deodorizing, antibacterial, disinfecting and the like. For example, U.S. Patent No. 6,057,051 discloses a cleaning agent containing chlorite, acid source, phosphate and swellable clay. Patent Document 6 discloses that a hydrogen salt, a gas generation regulator, and a water-absorbing resin are added to an aqueous chlorite solution or a stabilized chlorine dioxide aqueous solution and gelled to continuously generate chlorine dioxide gas. A method of generating is disclosed. Patent Document 7 discloses a composition containing a desiccant such as chlorite, silica gel, and a porous mineral such as zeolite.
本発明の課題は、抗菌、除菌、殺菌、抗カビ、抗ウイルス、消臭などに適用可能なチクソ性組成物を提供することである。 An object of the present invention is to provide a thixotropic composition applicable to antibacterial, sterilization, sterilization, antifungal, antiviral, deodorant and the like.
本課題を解決するために鋭意検討した結果、次のような態様を包含する本発明を完成するに至った。 As a result of intensive studies to solve this problem, the present invention including the following aspects has been completed.
〔１〕 粘土鉱物と、次亜塩素酸塩と、二酸化塩素前駆物質と、水と、を含有するチクソ性組成物。
〔２〕 次亜塩素酸塩が次亜塩素酸ナトリウムである〔１〕に記載の組成物。
〔３〕 二酸化塩素前駆物質が亜塩素酸塩または安定化二酸化塩素である〔１〕または〔２〕に記載の組成物。
〔４〕 粘土鉱物がラポナイトである〔１〕〜〔３〕のいずれかひとつに記載の組成物。
〔５〕 香料をさらに含有する〔１〕〜〔４〕のいずれかひとつに記載の組成物。
〔６〕 分散安定剤をさらに含有する〔１〕〜〔５〕のいずれかひとつに記載の組成物。
〔７〕 分散安定剤がポリオキシエチレン硬化ひまし油である〔６〕に記載の組成物。
[1] A thixotropic composition containing a clay mineral, a hypochlorite, a chlorine dioxide precursor, and water.
[2] The composition according to [1], wherein the hypochlorite is sodium hypochlorite.
[3] The composition according to [1] or [2], wherein the chlorine dioxide precursor is chlorite or stabilized chlorine dioxide.
[4] The composition according to any one of [1] to [3], wherein the clay mineral is laponite.
[5] The composition according to any one of [1] to [4], further containing a fragrance.
[6] The composition according to any one of [1] to [5], further containing a dispersion stabilizer.
[7] The composition according to [6], wherein the dispersion stabilizer is polyoxyethylene hydrogenated castor oil.
本発明のチクソ性組成物は、抗菌、除菌、殺菌、抗カビ、抗ウイルス、消臭などに適用可能である。本発明のチクソ性組成物は、せん断を加えている間は粘度が低下し塗布などの作業性が良好である。一方、静置状態においては粘度が高いので垂直面に塗布した場合などでも垂れない。 The thixotropic composition of the present invention is applicable to antibacterial, sterilizing, sterilizing, antifungal, antiviral, deodorizing and the like. The thixotropic composition of the present invention has a low workability during application of shear and good workability such as coating. On the other hand, since it has a high viscosity in a stationary state, it does not drip even when applied to a vertical surface.
本発明のチクソ性組成物は、粘土鉱物と、次亜塩素酸塩と、二酸化塩素前駆物質と、水と、を含有するものである。 The thixotropic composition of the present invention contains a clay mineral, a hypochlorite, a chlorine dioxide precursor, and water.
本発明に用いられる粘土鉱物としては、例えば、ベントナイト、モンモリロナイト、ラポナイト、バイデライト、ヘクトライト、スチブンサイト、ソーコナイト、ノントロナイトなどのスメクタイト系粘土、バーミキュライト、ハロイサイト、膨潤性マイカなどを挙げることができる。これらのうちラポナイトが好ましい。該粘土鉱物は水に分散させたときに増粘効果を及ぼすものである。粘土鉱物の量は、水１００質量部に対して、好ましくは０．５〜１０質量部、より好ましくは１〜８質量部である。 Examples of the clay mineral used in the present invention include smectite clays such as bentonite, montmorillonite, laponite, beidellite, hectorite, stevensite, sauconite, and nontronite, vermiculite, halloysite, and swelling mica. Of these, laponite is preferred. The clay mineral has a thickening effect when dispersed in water. The amount of the clay mineral is preferably 0.5 to 10 parts by mass, more preferably 1 to 8 parts by mass with respect to 100 parts by mass of water.
本発明に用いられる次亜塩素酸塩としては、次亜塩素酸ナトリウム、次亜塩素酸カリウム、次亜塩素酸カルシウムなどを挙げることができる。次亜塩素酸塩は強い酸化力を有し、漂白剤成分や消毒剤成分として知られる物質である。次亜塩素酸塩の量は、水１００質量部に対して、好ましくは０．００１〜５質量部、より好ましくは０．０１〜４質量部である。 Examples of the hypochlorite used in the present invention include sodium hypochlorite, potassium hypochlorite, calcium hypochlorite and the like. Hypochlorite has a strong oxidizing power and is a substance known as a bleach component or a disinfectant component. The amount of hypochlorite is preferably 0.001 to 5 parts by mass, more preferably 0.01 to 4 parts by mass with respect to 100 parts by mass of water.
本発明に用いられる二酸化塩素前駆物質は、二酸化塩素ガスを発生し得る物質である。二酸化塩素前駆物質の具体例としては、亜塩素酸ナトリウム、亜塩素酸カリウム、亜塩素酸マグネシウムなどの亜塩素酸塩、安定化二酸化塩素水溶液、純粋中性二酸化塩素水溶液などを挙げることができる。亜塩素酸塩に、次亜塩素酸塩が作用すると二酸化塩素を発生することがある。酸化塩素前駆物質は水溶液で市販されているのでそれを用いることができる。二酸化塩素前駆物質の量は、水１００質量部に対して、好ましくは０．０００５〜５質量部、より好ましくは０．００５〜３質量部である。 The chlorine dioxide precursor used in the present invention is a substance capable of generating chlorine dioxide gas. Specific examples of the chlorine dioxide precursor include chlorites such as sodium chlorite, potassium chlorite, and magnesium chlorite, stabilized aqueous chlorine dioxide, and pure neutral aqueous chlorine dioxide. When hypochlorite acts on chlorite, chlorine dioxide may be generated. Since the chlorine oxide precursor is commercially available in aqueous solution, it can be used. The amount of the chlorine dioxide precursor is preferably 0.0005 to 5 parts by mass, more preferably 0.005 to 3 parts by mass with respect to 100 parts by mass of water.
本発明のチクソ性組成物は、上記以外の成分として、香料や薬草成分（ハーブなど）を含有してもよい。香料としては、水性のものと油性のものとがある。香料または薬草成分の量は、水１００質量部に対して、好ましくは０．０００５〜５質量部、より好ましくは０．００５〜１質量部である。 The thixotropic composition of the present invention may contain a fragrance or a herbal ingredient (herb or the like) as a component other than the above. Perfumes include water-based and oil-based ones. The amount of the fragrance or the herbal ingredient is preferably 0.0005 to 5 parts by mass, more preferably 0.005 to 1 part by mass with respect to 100 parts by mass of water.
本発明のチクソ性組成物は、分散安定剤を含有することができる。特に香料を含有させる場合は分散安定剤を含有させることが好ましい。分散安定剤として、ポリカルボン酸系、ナフタレンスルホン酸ホルマリン縮合系、ポリカルボン酸部分アルキルエステル系、アルキルスルホン酸系、ポリリン酸塩系などのようなアニオン性分散安定剤；ポリアルキレンポリアミン系、四級アンモニウム系、アルキルポリアミン系などのようなカチオン性分散安定剤；ポリエチレングリコール系、ポリエーテル系、高級アルコールアルキレンオキサイド系、多価アルコールエステル系などのようなノニオン性分散安定剤；両性分散安定剤；などを挙げることができる。これらのうち、ノニオン性分散安定剤が好ましく、ポリオキシエチレン硬化ひまし油がより好ましい。分散安定剤の量は、水１００質量部に対して、好ましくは０．００１〜５質量部、より好ましくは０．０１〜２質量部である。分散安定剤の添加によって組成物中の粘土鉱物、香料または油性物質の分散安定性が高まる。 The thixotropic composition of the present invention can contain a dispersion stabilizer. In particular, when a fragrance is contained, it is preferable to contain a dispersion stabilizer. As dispersion stabilizers, anionic dispersion stabilizers such as polycarboxylic acid, naphthalene sulfonic acid formalin condensation, polycarboxylic acid partial alkyl ester, alkyl sulfonic acid, polyphosphate, and the like; polyalkylene polyamine, four Cationic dispersion stabilizers such as quaternary ammonium and alkylpolyamines; Nonionic dispersion stabilizers such as polyethylene glycols, polyethers, higher alcohol alkylene oxides, and polyhydric alcohol esters; Amphoteric dispersion stabilizers And the like. Of these, nonionic dispersion stabilizers are preferred, and polyoxyethylene hydrogenated castor oil is more preferred. The amount of the dispersion stabilizer is preferably 0.001 to 5 parts by mass, more preferably 0.01 to 2 parts by mass with respect to 100 parts by mass of water. Addition of a dispersion stabilizer increases the dispersion stability of the clay mineral, fragrance or oily substance in the composition.
本発明に用いられる水は、特に制限されないが、軟水が好ましく、イオン交換水がより好ましい。組成物中の水の量は、組成物の粘度を所望の範囲にすることのできる範囲であれば特に制限されない。 The water used in the present invention is not particularly limited, but soft water is preferable, and ion exchange water is more preferable. The amount of water in the composition is not particularly limited as long as the viscosity of the composition can be within a desired range.
本発明のチクソ性組成物は、その調製法によって特に制限されない。例えば、酸化塩素前駆物質の水溶液に、次亜塩素酸塩、および粘土鉱物、ならびに必要に応じて香料および界面活性剤を添加し、さらに粘度調整のために水を加えることによって得ることができる。本発明においては、粘土鉱物が組成物中に均一に分散してコロイドを形成するようにすることが好ましい。 The thixotropic composition of the present invention is not particularly limited by its preparation method. For example, it can be obtained by adding hypochlorite, clay minerals, and, if necessary, perfumes and surfactants to an aqueous solution of a chlorine oxide precursor, and further adding water for viscosity adjustment. In the present invention, it is preferable that the clay mineral is uniformly dispersed in the composition to form a colloid.
本発明のチクソ性組成物は、スプレーに入れて噴霧することができる。スプレーとして、トリガー式、手動ポンプ式、電動ポンプ式、高圧ガス式、空気圧式、蓄圧式、ベンチュリ式などを用いることができる。また、本発明のチクソ性組成物は、刷毛塗り、ヘラ塗りなどをすることもできる。対象物に塗布した後、組成物の粘度が増大し対象物から塗膜が垂れにくくなる。 The thixotropic composition of the present invention can be sprayed in a spray. As the spray, a trigger type, a manual pump type, an electric pump type, a high pressure gas type, a pneumatic type, a pressure accumulation type, a venturi type, or the like can be used. Further, the thixotropic composition of the present invention can be applied with a brush or a spatula. After application to the object, the viscosity of the composition increases and the coating film is less likely to sag from the object.
以下、本発明を実施例により具体的に説明するが、これらにより本発明の範囲が限定されるものではない。 EXAMPLES Hereinafter, the present invention will be specifically described with reference to examples, but the scope of the present invention is not limited by these examples.
実施例１
安定化二酸化塩素水溶液（二酸化塩素５００００ｐｐｍ、デュポン社製）３質量部、１２％次亜塩素酸ナトリウム水溶液２質量部、ラポナイトＸＬＧ（ＢＹＫ社製）７質量部、およびイオン交換水８８質量部を混ぜ合わせて、チクソ性組成物を得た。トリガー式スプレーにチクソ性組成物を入れた。生ごみにチクソ性組成物をスプレー散布した。評価者１０名で官能試験を行った。評価者１０名中１０名は、消臭効果ありの判定をした。
Example 1
3 parts by mass of stabilized chlorine dioxide aqueous solution (chlorine dioxide 50000 ppm, manufactured by DuPont), 2 parts by mass of 12% sodium hypochlorite aqueous solution, 7 parts by mass of Laponite XLG (by BYK), and 88 parts by mass of ion-exchanged water In combination, a thixotropic composition was obtained. The thixotropic composition was placed in a trigger spray. The thixotropic composition was sprayed on the garbage. A sensory test was conducted by 10 evaluators. Ten of the 10 evaluators made a determination that there was a deodorizing effect.
実施例２
安定化二酸化塩素水溶液（二酸化塩素５００００ｐｐｍ、デュポン社製）０．２質量部、１２％次亜塩素酸ナトリウム水溶液０．５質量部、ラポナイトＸＬＧ（ＢＹＫ社製）３質量部、ポリオキシエチレン硬化ひまし油０．５質量部、フローラル香料０．３質量部、およびイオン交換水９５．５質量部を混ぜ合わせて、チクソ性組成物を得た。トリガー式スプレーにチクソ性組成物を入れた。生ごみにチクソ性組成物を噴霧散布した。評価者１０名で官能試験を行った。評価者１０名中８名は、消臭効果ありの判定をした。
Example 2
Stabilized chlorine dioxide aqueous solution (chlorine dioxide 50000 ppm, manufactured by DuPont) 0.2 parts by mass, 12% sodium hypochlorite aqueous solution 0.5 parts by mass, Laponite XLG (by BYK) 3 parts by mass, polyoxyethylene hydrogenated castor oil 0.5 parts by mass, 0.3 parts by mass of a floral fragrance, and 95.5 parts by mass of ion-exchanged water were mixed to obtain a thixotropic composition. The thixotropic composition was placed in a trigger spray. The thixotropic composition was sprayed on the garbage. A sensory test was conducted by 10 evaluators. Eight out of 10 evaluators made a determination that there was a deodorizing effect.
比較例１
１２％次亜塩素酸ナトリウム水溶液０．５質量部、ラポナイトＸＬＧ（ＢＹＫ社製）３質量部、ポリオキシエチレン硬化ひまし油０．５質量部、フローラル香料０．３質量部、およびイオン交換水９５．７質量部を混ぜ合わせて、チクソ性組成物を得た。トリガー式スプレーにチクソ性組成物を入れた。生ごみにチクソ性組成物を噴霧散布した。評価者１０名で官能試験を行った。評価者１０名中３名は、消臭効果ありの判定をした。
Comparative Example 1
0.5% by weight of 12% aqueous sodium hypochlorite solution, 3 parts by weight of Laponite XLG (manufactured by BYK), 0.5 part by weight of polyoxyethylene hydrogenated castor oil, 0.3 part by weight of floral flavor, 7 parts by mass were mixed to obtain a thixotropic composition. The thixotropic composition was placed in a trigger spray. The thixotropic composition was sprayed on the garbage. A sensory test was conducted by 10 evaluators. Three out of 10 evaluators made a determination that there was a deodorizing effect.
比較例２
安定化二酸化塩素水溶液（二酸化塩素５００００ｐｐｍ、デュポン社製）０．２質量部、ラポナイトＸＬＧ（ＢＹＫ社製）３質量部、ポリオキシエチレン硬化ひまし油０．５質量部、フローラル香料０．３質量部、およびイオン交換水９６質量部を混ぜ合わせて、チクソ性組成物を得た。トリガー式スプレーにチクソ性組成物を入れた。生ごみにチクソ性組成物を噴霧散布した。評価者１０名で官能試験を行った。評価者１０名中４名は、消臭効果ありの判定をした。
Comparative Example 2
Stabilized aqueous chlorine dioxide solution (chlorine dioxide 50000 ppm, manufactured by DuPont) 0.2 parts by mass, 3 parts by mass of Laponite XLG (manufactured by BYK), 0.5 parts by mass of polyoxyethylene hydrogenated castor oil, 0.3 parts by mass of floral fragrance, And 96 parts by mass of ion-exchanged water were mixed to obtain a thixotropic composition. The thixotropic composition was placed in a trigger spray. The thixotropic composition was sprayed on the garbage. A sensory test was conducted by 10 evaluators. Four out of 10 evaluators made a determination that there was a deodorizing effect.
以上の結果が示すとおり、活性成分として次亜塩素酸ナトリウム水溶液のみを含有する組成物、および活性成分として安定化二酸化塩素水溶液のみを含有する組成物に対して、活性成分として次亜塩素酸ナトリウム水溶液と安定化二酸化塩素水溶液とを含有する本発明のチクソ性組成物は、優れた消臭効果を有する。さらに、次亜塩素酸ナトリウム水溶液と安定化二酸化塩素水溶液との相乗作用で、消臭だけでなく、抗菌、除菌、殺菌、抗カビ、抗ウイルスなどにおいても高い効果を有する。 As the above results show, the composition containing only sodium hypochlorite aqueous solution as the active ingredient, and the composition containing only stabilized chlorine dioxide aqueous solution as the active ingredient, sodium hypochlorite as the active ingredient The thixotropic composition of the present invention containing an aqueous solution and a stabilized chlorine dioxide aqueous solution has an excellent deodorizing effect. Furthermore, the synergistic action of the sodium hypochlorite aqueous solution and the stabilized chlorine dioxide aqueous solution has a high effect not only in deodorization but also in antibacterial, sterilization, sterilization, antifungal, antiviral and the like.
Claims (7)
次亜塩素酸塩と、
二酸化塩素前駆物質と、
水と、
を含有するチクソ性組成物。 Clay minerals,
Hypochlorite,
A chlorine dioxide precursor,
water and,
A thixotropic composition.
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