JP2016011319A - Local dirt removal product - Google Patents
Local dirt removal product Download PDFInfo
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- JP2016011319A JP2016011319A JP2014131983A JP2014131983A JP2016011319A JP 2016011319 A JP2016011319 A JP 2016011319A JP 2014131983 A JP2014131983 A JP 2014131983A JP 2014131983 A JP2014131983 A JP 2014131983A JP 2016011319 A JP2016011319 A JP 2016011319A
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- acid
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- 239000000203 mixture Substances 0.000 claims abstract description 19
- 238000005507 spraying Methods 0.000 claims abstract description 9
- 238000002347 injection Methods 0.000 claims description 42
- 239000007924 injection Substances 0.000 claims description 42
- 238000004140 cleaning Methods 0.000 claims description 24
- 239000002689 soil Substances 0.000 claims description 18
- 239000004094 surface-active agent Substances 0.000 claims description 13
- 239000003945 anionic surfactant Substances 0.000 claims description 11
- 239000006260 foam Substances 0.000 claims description 8
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- 230000000699 topical effect Effects 0.000 claims description 7
- 239000002280 amphoteric surfactant Substances 0.000 claims description 6
- 238000005187 foaming Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 15
- 239000007921 spray Substances 0.000 abstract description 11
- 238000005406 washing Methods 0.000 abstract description 3
- 230000013872 defecation Effects 0.000 abstract 1
- -1 alkylbenzene sulfonate Chemical class 0.000 description 25
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 125000000217 alkyl group Chemical group 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000003595 mist Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000002519 antifouling agent Substances 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 230000003373 anti-fouling effect Effects 0.000 description 3
- 239000002738 chelating agent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000002550 fecal effect Effects 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
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- 239000011734 sodium Substances 0.000 description 2
- 229940077386 sodium benzenesulfonate Drugs 0.000 description 2
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 2
- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 description 1
- VCVKIIDXVWEWSZ-YFKPBYRVSA-N (2s)-2-[bis(carboxymethyl)amino]pentanedioic acid Chemical compound OC(=O)CC[C@@H](C(O)=O)N(CC(O)=O)CC(O)=O VCVKIIDXVWEWSZ-YFKPBYRVSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 1
- DMQQXDPCRUGSQB-UHFFFAOYSA-N 2-[3-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CCCN(CC(O)=O)CC(O)=O DMQQXDPCRUGSQB-UHFFFAOYSA-N 0.000 description 1
- WYMDDFRYORANCC-UHFFFAOYSA-N 2-[[3-[bis(carboxymethyl)amino]-2-hydroxypropyl]-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)CN(CC(O)=O)CC(O)=O WYMDDFRYORANCC-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- FSVCELGFZIQNCK-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)glycine Chemical compound OCCN(CCO)CC(O)=O FSVCELGFZIQNCK-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- MAEIEVLCKWDQJH-UHFFFAOYSA-N bumetanide Chemical compound CCCCNC1=CC(C(O)=O)=CC(S(N)(=O)=O)=C1OC1=CC=CC=C1 MAEIEVLCKWDQJH-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
- DEFVIWRASFVYLL-UHFFFAOYSA-N ethylene glycol bis(2-aminoethyl)tetraacetic acid Chemical compound OC(=O)CN(CC(O)=O)CCOCCOCCN(CC(O)=O)CC(O)=O DEFVIWRASFVYLL-UHFFFAOYSA-N 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000006479 glucose peptone medium Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 235000021539 instant coffee Nutrition 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Cleaning By Liquid Or Steam (AREA)
- Detergent Compositions (AREA)
Abstract
Description
本発明は、用便後、水洗しても残った便や喫水線に発生したカビやヌメリ汚れを、ブラシ等を使うことなく噴射のみで除去できる局所汚れ除去製品に関するものである。 The present invention relates to a topical soil removal product that can remove mold and slime stains generated on stool and water lines remaining after washing with water without using a brush.
近年、水洗トイレは節水化が進み、当初は大洗浄の１回の水量は２０Ｌあったものが、現在では少ないものでは１回４Ｌ弱まで減量されている。しかし、節水化により水の流れが弱くなり、便器に付着した便が流れず残ってしまうことが起こるようになってきている。また、便器の喫水線には掃除を怠るとカビやヌメリが発生してしまう問題は依然として存在している。 In recent years, flush toilets have been saving water, and the amount of water for one large wash was 20L at the beginning, but now it is reduced to less than 4L for small ones. However, due to water saving, the flow of water is weakened, and stool adhering to the toilet bowl does not flow and remains. In addition, there is still a problem that mold and slime are generated in the toilet waterline if neglected to clean.
汚れの付着を防止するために便器表面に防汚性や、汚れが付着した場合に容易に洗浄できる効果を付与する技術も検討され、例えば、特許文献１及び特許文献２は芳香族スルホン酸系ホルマリン縮合物を含有することを特徴とする親水化処理剤による防汚洗浄方法、防汚剤を開示し、特許文献３では、ポリオキシアルキレンアルキルエーテル及びポリアルキレングリコールを特定比率で含有し、被膜を形成し、硬質表面の洗浄性を向上させる方法を開示している。 In order to prevent the adhesion of dirt, a technique for imparting antifouling properties to the toilet surface and an effect that can be easily washed when dirt is attached has been studied. For example, Patent Document 1 and Patent Document 2 are aromatic sulfonic acid-based. Disclosed is an antifouling cleaning method and an antifouling agent using a hydrophilic treatment agent characterized by containing a formalin condensate. Patent Document 3 contains a polyoxyalkylene alkyl ether and a polyalkylene glycol in a specific ratio, and a coating film. Is disclosed, and a method for improving the cleanability of a hard surface is disclosed.
特許文献１及び特許文献２は、トイレタンク又はトイレタンクの放水タップで防汚剤を溶解させ、水を流した時に防汚剤を便器表面に塗布することにより便の付着を防止するものである。特許文献３は便器表面に塗布し、そのまま乾燥して被膜を形成させるか、被膜形成物質をゲルに配合し、便器のフチ裏にゲルを付着させて、水を流したときに被膜を形成するものである。これらはあらかじめ形成させた被膜により便など汚れの付着を防止又は付着力を弱めるものであるが、付着してしまった汚れを取り除くものではなく、水を流しても取り除けない汚れや喫水線に発生したカビやヌメリはブラシでこすり落とすことになる。しかしながら、ブラシを使用した場合には使用後のブラシ洗浄などが面倒で、より簡単に便器に付着した便などの汚れを取り除く方法が望まれていた。 Patent Document 1 and Patent Document 2 prevent the adhesion of stool by dissolving the antifouling agent with a toilet tank or a drain tap of the toilet tank and applying the antifouling agent to the toilet surface when water is poured. . Patent Document 3 is applied to the toilet surface and dried as it is to form a film, or a film-forming substance is blended in the gel, and the gel is attached to the back of the toilet bowl, and the film is formed when water is poured. Is. These are pre-formed coatings that prevent or reduce the adhesion of dirt such as stool, but do not remove the dirt that has adhered, but have occurred on dirt and waterlines that cannot be removed by running water. Mold and slime will be scraped off with a brush. However, when a brush is used, cleaning of the brush after use is troublesome, and a method of removing dirt such as stool adhering to the toilet bowl more easily has been desired.
そこで、本発明の課題は、用便後水洗しても残った便や汚れや喫水線に発生したカビやヌメリ汚れなどを、ブラシ等を使うことなく簡単に除去できる局所汚れ除去製品を提供することを目的とする。 Therefore, an object of the present invention is to provide a local soil removal product that can easily remove stool, dirt, mold and slime stains generated on the waterline after washing after use, without using a brush or the like. With the goal.
本発明は、上記目的を達成するために、以下の構成が優れた効果を奏することを見出したものである。
（１）噴射距離２０cmにおける噴射力が２〜１０ｇ・ｆとなるように設定されたトリガー式噴射装置を用い、前記トリガー式噴射装置より洗浄剤組成物を噴射するようになしたる局所汚れ除去製品。
（２）前記トリガー式噴射装置の噴射距離２０ｃｍにおける噴射パターンが１２０ｍｍ以下であるように設定された（１）記載の局所汚れ除去製品。
（３）前記洗浄剤組成物中に少なくとも界面活性剤を含有する（１）又は（２）に記載の局所汚れ除去製品。
（４）前記界面活性剤が陰イオン界面活性剤、両性界面活性剤、非イオン界面活性剤から選ばれる1種又は2種以上である（３）に記載の局所汚れ除去製品。
（５）更に前記トリガー式噴射装置に霧ノズル及び／又は泡ノズルを付設し、切りかえにより霧噴射及び／又は泡噴射による洗浄もできるようにした（１）乃至（４）のいずれか１に記載の局所汚れ除去製品。
In order to achieve the above object, the present invention has been found that the following configuration has an excellent effect.
(1) Use of a trigger type injection device that is set so that the injection force at an injection distance of 20 cm is 2 to 10 g · f, and removes a local stain that causes the cleaning composition to be injected from the trigger type injection device. Product.
(2) The local soil removal product according to (1), wherein an injection pattern at an injection distance of 20 cm of the trigger type injection device is set to be 120 mm or less.
(3) The topical soil removal product according to (1) or (2), wherein the cleaning composition contains at least a surfactant.
(4) The topical soil removal product according to (3), wherein the surfactant is one or more selected from an anionic surfactant, an amphoteric surfactant, and a nonionic surfactant.
(5) In addition, any one of (1) to (4) may be provided with a mist nozzle and / or a foam nozzle attached to the trigger type injection device so that cleaning can be performed by mist injection and / or foam injection. Topical soil removal product.
本発明の局所汚れ除去製品は噴射距離２０cmにおける噴射力が２〜１０ｇ・ｆとなるように設定されたトリガー式噴射装置を用い、前記トリガー式噴射装置より洗浄剤組成物を噴射することにより、用便後水を流しても取り除けなかった便などの汚れや喫水線に発生したカビやヌメリなどを、ブラシ等を使うことなく噴射するだけで簡単に取り除くことができるので、その実用性は極めて高い。 The local soil removal product of the present invention uses a trigger type injection device that is set so that the injection force at an injection distance of 20 cm is 2 to 10 g · f, and by spraying the cleaning composition from the trigger type injection device, Because it can be easily removed by spraying without using a brush, etc., dirt such as stools that could not be removed even after flushing water after use, and mold and slime generated on the waterline, its practicality is extremely high .
本発明の局所汚れ除去製品で使用されるトリガー式噴射装置は、噴射量が０．５〜３．０ｃｃであって、付着した便等を取り除くには噴射力が２ｇ・ｆ以上が好ましく、より好ましくは５ｇ・ｆ以上である。噴射時の洗浄液の跳ね返りを考えると１０ｇ・ｆ以下が好ましく、より好ましくは８ｇ・ｆ以下である。また、本発明でいう噴射パターンとは、トリガー式噴射装置の噴射部分から２０ｃｍ離れた所に貼り付けた紙の垂直面に向けて1回噴射したときの濡れた部分の最小直径を測定したものである。なお、この濡れた部分とは、噴射の際に十分な噴射が行われる場所をいうもので、噴射の際の飛び散りや液だれ部分は含まない。本発明では噴射パターンが１２０ｍｍ以下のものが好ましく、より好ましくは９０ｍｍ以下で、最も好ましくは６０ｍｍ以下である。更に、本発明製品には別途、噴射パターンが１２０ｍｍより大きい霧ノズル、及び／又は泡ノズルを付設し、ノズルを切りかえることにより、霧噴射や泡噴射による洗浄もできるようにすることも可能である。 The trigger type injection device used in the local soil removal product of the present invention has an injection amount of 0.5 to 3.0 cc, and an injection force of 2 g · f or more is preferable for removing attached stool, etc. Preferably it is 5 g · f or more. Considering the rebound of the cleaning liquid at the time of jetting, it is preferably 10 g · f or less, more preferably 8 g · f or less. In addition, the spray pattern referred to in the present invention is a measurement of the minimum diameter of the wetted part when sprayed once toward the vertical surface of the paper affixed 20 cm away from the spray part of the trigger type spray device. It is. In addition, this wet part means the place where sufficient jetting is performed at the time of jetting, and does not include scattering or dripping part at the time of jetting. In the present invention, the spray pattern is preferably 120 mm or less, more preferably 90 mm or less, and most preferably 60 mm or less. Furthermore, the product of the present invention can be separately provided with a mist nozzle and / or a foam nozzle having a spray pattern larger than 120 mm, and by switching the nozzle, it is possible to perform cleaning by mist spray or foam spray. .
本発明に用いられる洗浄剤組成物は、通常に使用される洗浄剤組成物であれば、いずれも使用可能である。洗浄剤組成物としては、汚物等の汚れを分散、乳化する界面活性剤や、汚物汚れに含まれる無機塩を分解する酸やキレート剤を配合することにより、汚れを除去しやすくするものが好ましい。 As the cleaning composition used in the present invention, any cleaning composition that is usually used can be used. As the cleaning composition, a surfactant that disperses and emulsifies dirt such as filth, and an acid or chelating agent that decomposes an inorganic salt contained in the filth dirt is preferably added to facilitate removal of the dirt. .
本発明に用いられる洗浄剤組成物には各種の界面活性剤を配合することができる。その界面活性剤としては、通常洗浄に使われるものであればいずれも使用可能で、特に限定されるものではない。洗浄効果の点から、アニオン界面活性剤、非イオン界面活性剤、両性界面活性剤が好ましい。アニオン界面活性剤としては、例えば脂肪酸石けん、アルキルベンゼンスルホン酸塩、直鎖アルキルベンゼンスルホン酸塩、アルキル硫酸塩、アルファオレフィンスルホン酸塩、アルキルリン酸エステル塩、ポリオキシエチレンアルキルエーテル硫酸塩、ポリオキシエチレンアルキルエーテルカルボン酸塩、ポリオキシエチレンアルキルフェニルエーテル硫酸塩、ポリオキシエチレンアルキルエーテルりん酸塩、アルキルスルホコハク酸塩、ポリオキシエチレンアルキルスルホコハク酸塩などが挙げられる。非イオン界面活性剤としては、例えばポリオキシアルキレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレン高級脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ヤシ油脂肪酸ジエタノールアミド、脂肪酸アルカノールアミド、アミンオキシドなどが挙げられる。両性界面活性剤としてはアルキルカルボベタイン、アルキルアミドカルボベタイン、アルキルスルホベタイン、アルキルヒドロキシスルホベタイン、アルキルアミドスルホベタイン、アルキルアミドヒドロキシスルホベタイン等が挙げられる。これらは１種又は２種以上で配合されて使用される。
一般に陶器の便器はマイナスに荷電しているので、防汚を考えると便器に吸着されにくいアニオン界面活性又は非イオン界面活性剤がより好ましく、汚物除去性能を考えるとアニオン界面活性剤が最も好ましい。
なお、本発明に用いられる洗浄剤組成物へのこれらの界面活性剤の配合量については、その使用する界面活性剤の種類などにより適宜変化させることが出来、特に制限はないが、０．１〜１０％の範囲で使用することが出来る。さらに好ましくは、０．３〜５％の範囲で使用することが出来る。
Various detergents can be mix | blended with the cleaning composition used for this invention. Any surfactant can be used as long as it is usually used for cleaning, and is not particularly limited. From the viewpoint of cleaning effect, anionic surfactants, nonionic surfactants, and amphoteric surfactants are preferred. Examples of the anionic surfactant include fatty acid soap, alkylbenzene sulfonate, linear alkylbenzene sulfonate, alkyl sulfate, alpha olefin sulfonate, alkyl phosphate ester salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene Examples thereof include alkyl ether carboxylates, polyoxyethylene alkyl phenyl ether sulfates, polyoxyethylene alkyl ether phosphates, alkyl sulfosuccinates, polyoxyethylene alkyl sulfosuccinates, and the like. Nonionic surfactants include, for example, polyoxyalkylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene higher fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene hydrogenated castor oil, Examples include coconut oil fatty acid diethanolamide, fatty acid alkanolamide, and amine oxide. Examples of amphoteric surfactants include alkyl carbobetaines, alkylamide carbobetaines, alkylsulfobetaines, alkylhydroxysulfobetaines, alkylamide sulfobetaines, alkylamide hydroxysulfobetaines, and the like. These are used alone or in combination of two or more.
In general, pottery toilet bowls are negatively charged. Therefore, an anionic surfactant or a nonionic surfactant that is difficult to be adsorbed on the toilet bowl is more preferable in view of antifouling, and an anionic surfactant is most preferable in view of dirt removal performance.
The amount of these surfactants to be added to the cleaning composition used in the present invention can be appropriately changed depending on the type of the surfactant used and is not particularly limited. It can be used in the range of -10%. More preferably, it can be used in the range of 0.3 to 5%.
本発明の洗浄剤組成物には、汚れに含まれる無機塩を分解するために、更に無機酸、有機酸及びキレート剤から選ばれる１種又は２種以上を配合することが好ましい。無機酸としては、塩酸、硫酸、硝酸、スルファミン酸、リン酸等が挙げられ、有機酸としては、酢酸、クエン酸、グリコール酸、リンゴ酸、酒石酸、乳酸等が挙げられ、キレート剤としては、エチレンジアミンテトラ酢酸、ニトリロトリ酢酸、ジエチレントリアミンペンタ酢酸、ヒドロキシエチルエチレンジアミントリ酢酸、トリエチレンテトラアミンヘキサ酢酸、１，３−プロパンジアミンテトラ酢酸、１，３−ジアミノ−２−ヒドロキシプロパンテトラ酢酸、ヒドロキシエチルイミノジ酢酸、ジヒドロキシエチルグリシン、グリコールエーテルジアミンテトラ酢酸、Ｌ−グルタミン酸ジ酢酸、ヒドロキシエチリデンジホスホン酸、アミノトリ（メチレンホスホン酸）、エチレンジアミンテトラ（メチレンホスホン酸）、ジエチレントリアミンペンタ（メチレンホスホン酸）及びこれらの塩等が挙げられる。噴射時の飛沫による金属などに対する腐食等を考えると、有機酸及び／又はキレート剤を配合することがより好ましい。 In order to decompose the inorganic salt contained in the soil, the cleaning composition of the present invention preferably further contains one or more selected from inorganic acids, organic acids and chelating agents. Examples of the inorganic acid include hydrochloric acid, sulfuric acid, nitric acid, sulfamic acid, phosphoric acid, and the like. Examples of the organic acid include acetic acid, citric acid, glycolic acid, malic acid, tartaric acid, lactic acid, and the like. Ethylenediaminetetraacetic acid, nitrilotriacetic acid, diethylenetriaminepentaacetic acid, hydroxyethylethylenediaminetriacetic acid, triethylenetetraaminehexaacetic acid, 1,3-propanediaminetetraacetic acid, 1,3-diamino-2-hydroxypropanetetraacetic acid, hydroxyethyliminodi Acetic acid, dihydroxyethylglycine, glycol ether diamine tetraacetic acid, L-glutamic acid diacetic acid, hydroxyethylidene diphosphonic acid, aminotri (methylenephosphonic acid), ethylenediaminetetra (methylenephosphonic acid), diethylenetria Npenta (methylenephosphonic acid) and salts thereof. In consideration of corrosion of the metal or the like caused by splashes at the time of jetting, it is more preferable to add an organic acid and / or a chelating agent.
本発明の洗浄剤組成物には、更にｐＨ調整剤、防錆剤、水溶性溶剤、防汚剤、抗菌・除菌剤、増粘剤、消臭剤、香料等を適宜配合することができる。 The cleaning composition of the present invention may further contain a pH adjuster, a rust preventive agent, a water-soluble solvent, an antifouling agent, an antibacterial / bacteria-removing agent, a thickener, a deodorant, a fragrance and the like as appropriate. .
次に、具体的実施例に基づいて、本発明の局所汚れ除去製品をさらに詳細に説明する。 Next, based on specific examples, the topical soil removal product of the present invention will be described in more detail.
以下に評価方法について記載する。
（汚物除去試験）
１０×１０ｃｍ白色タイル（ＭＬＰ−１００、（株）ＬＩＸＩＬ製）を１５分以上水に浸漬後、表面の水をふき取り、タイルの中心に直径２ｃｍの円を書く。この円の中心に、直径５ｍｍ、厚さ０．５ｍｍの大きさで、インスタントコーヒー（味の素ゼネラルフーズ（株） ＭＡＸＩＭ）１５ｇと精製水５ｇとをよく混合して作製したモデル汚れを付着させる。タイルを垂直に立て、タイル面から３０°の角度で２０ｃｍの距離から噴射し、モデル汚れが円から出るまでの回数を３回計測し平均値を算出し、以下の評価基準で評価した。
◎：噴射２０回未満で除去
○：噴射５０回未満で除去
△：噴射５０〜１００回で除去
×：１００回噴射しても除去できない
（カビ汚れ除去試験）
１００倍希釈したグルコースペプトン培地４００ｍＬを１０００ｍＬのガラスビーカーに入れ、ＪＩＳ Ｚ ２９１１の方法で作製したＣｌａｄｏｓｐｏｒｉｕｍ ｃｌａｄｏｓｐｏｒｉｏｉｄｅｓのカビ分散液を０．４ｍＬ加える。次いで、１０×１０ｃｍの白色タイル（ＭＬＰ−１００、（株）ＬＩＸＩＬ製）を一部浸漬するように設置し、２５℃で７日間培養してタイル喫水線にカビを発生させる。このカビ発生タイルを垂直に立て、タイル面から３０°の角度で２０ｃｍの距離からカビ汚れに噴射し、以下の基準で評価を行った。
○：噴射回数５０回以内でカビ汚れを落とすことができる
×：噴射回数５０回でカビ汚れを落とすことができない
（液の跳ね返り試験）
実際のトイレの便器に汚物試験で使用したモデル汚れを付着させ、モデル汚れを除去するときの液の跳ね返りを以下の基準で評価した。
◎：跳ね返りはまったくない
○：跳ね返りはない
△：跳ね返りがわずかにある
×：跳ね返りが明らかにある
（噴射パターン測定）
２０ｃｍ離れた所に貼り付けた紙の垂直面に向けて1回噴射したときの濡れた部分の最小直径を測定した。ただし、最小直径には、飛び散りや液だれ部分は含まない。
The evaluation method is described below.
(Soil removal test)
After dipping a 10 × 10 cm white tile (MLP-100, manufactured by LIXIL Co., Ltd.) in water for 15 minutes or more, wipe off the surface water and write a circle with a diameter of 2 cm at the center of the tile. At the center of this circle, a model soil having a diameter of 5 mm and a thickness of 0.5 mm and a mixture of 15 g of instant coffee (Ajinomoto General Foods Co., Ltd. MAXIM) and 5 g of purified water is adhered. Tiles were set up vertically, sprayed from a distance of 20 cm at an angle of 30 ° from the tile surface, the number of times until the model dirt came out of the circle was measured three times, an average value was calculated, and evaluated according to the following evaluation criteria.
A: Removed with less than 20 injections ○: Removed with less than 50 injections Δ: Removed with 50 to 100 injections ×: Cannot be removed even after 100 injections (mold stain removal test)
400 mL of 100-fold diluted glucose peptone medium is placed in a 1000 mL glass beaker, and 0.4 mL of a mold dispersion of Cladospodium cladosporoides prepared by the method of JIS Z 2911 is added. Next, a 10 × 10 cm white tile (MLP-100, manufactured by LIXIL Corporation) is placed so as to be partially immersed, and cultured at 25 ° C. for 7 days to generate mold on the tile draft. This mold generating tile was set up vertically, sprayed on mold stain from a distance of 20 cm at an angle of 30 ° from the tile surface, and evaluation was performed according to the following criteria.
○: Mold dirt can be removed within 50 injections ×: Mold dirt cannot be removed after 50 injections (liquid rebound test)
The model dirt used in the filth test was attached to an actual toilet bowl, and the splash of liquid when removing the model dirt was evaluated according to the following criteria.
◎: No rebound ○: No rebound △: There is a slight rebound ×: Rebound is clear (measurement of injection pattern)
The minimum diameter of the wet part was measured when it was sprayed once toward the vertical surface of the paper affixed 20 cm away. However, the minimum diameter does not include splashing or dripping.
（２）キャニヨン製 T-95（ノズルタイプ：スタンダード／ジェット）
（３）吉野工業所製 YT87（ノズルタイプ：泡／直）
（４）キャニヨン製 ＣＨＳ−２ＡＮ（ノズルタイプ：ジェット〜霧）
（５）キャニヨン製 ＣＨＳ−５Ａ（ノズルタイプ：ジェット〜霧）
（６）キャニヨン製 T-95（ノズルタイプ：スタンダード、直径６mmフォーマー付き）
(2) Canyon T-95 (Nozzle type: Standard / Jet)
(3) YT87 manufactured by Yoshino Kogyo (nozzle type: foam / straight)
(4) CHS-2AN made by Canyon (nozzle type: jet to fog)
(5) Canyon CHS-5A (nozzle type: jet to fog)
(6) Canyon T-95 (Nozzle type: Standard, with 6mm diameter former)
表１は水のみを噴射したときの各トリガー式噴射装置の汚物除去試験結果、カビ汚れ除去試験及び跳ね返り試験結果について示したものである。比較例１は噴射力が１．０ｇ・ｆであることから、１００回の噴射によっても汚物及び喫水線のカビ汚れを除去することはできなかった。一方、２．０ｇ・ｆ以上の噴射力がある実施例１〜５は良好な汚物除去効果及び喫水線のカビ汚れ除去効果が得られ、液の跳ね返りもなかった。 Table 1 shows the filth removal test results, the mold stain removal test, and the rebound test results of each trigger type spray device when only water is injected. Since Comparative Example 1 has an injection force of 1.0 g · f, filth and mold stains on the waterline could not be removed even after 100 injections. On the other hand, Examples 1 to 5 having an injection force of 2.0 g · f or more obtained a good filth removal effect and mold stain removal effect on the waterline, and there was no rebound of the liquid.
＊２
アニオン界面活性剤（１） 直鎖アルキル（Ｃ１０−Ｃ１４）ベンゼンスルホン酸ナトリウム
アニオン界面活性剤（２） アルキル（Ｃ１４−Ｃ１８）スルホン酸ナトリウム
アニオン界面活性剤（３） ポリオキシエチレン（２）アルキル（Ｃ１２−Ｃ１４）エーテル硫酸エステルナトリウム
両性界面活性剤（１） ラウリン酸アミドプロピルジメチルアミノ酢酸ベタイン
両性界面活性剤（２） ラウリルジメチルアミノ酢酸ベタイン
ノニオン界面活性剤（１） ポリオキシエチレン（９）ラウリルエーテル
ノニオン界面活性剤（２） ラウリルジメチルアミンオキシド
Anionic surfactant (1) Linear alkyl (C 10 -C 14 ) Sodium benzenesulfonate anionic surfactant (2) Alkyl (C 14 -C 18 ) Sodium sulfonate anionic surfactant (3) Polyoxyethylene ( 2) alkyl (C 12 -C 14 ) ether sulfate sodium amphoteric surfactant (1) lauric acid amidopropyldimethylaminoacetic acid betaine amphoteric surfactant (2) lauryldimethylaminoacetic acid betaine nonionic surfactant (1) polyoxy Ethylene (9) Lauryl ether nonionic surfactant (2) Lauryl dimethylamine oxide
表２には各種界面活性剤を配合した洗浄剤組成物を噴射したときの汚物除去試験結果を示している。界面活性剤を配合していない実施例３は、汚物を除去するのに１３回噴射するのに対して、アニオン界面活性剤である実施例６〜８は、噴射回数が６〜８回、両性界面活性剤を配合した実施例９，１０は、噴射回数が８〜１０、そして、ノニオン界面活性剤を配合した実施例１１，１２は、噴射回数が１０〜１１回となり、界面活性剤を配合することにより、汚物除去効果が高まることが判った。 Table 2 shows the filth removal test results when the cleaning composition containing various surfactants was sprayed. In Example 3 where the surfactant is not blended, 13 times of spraying are performed to remove the filth, whereas in Examples 6 to 8 which are anionic surfactants, the number of sprays is 6 to 8 times. In Examples 9 and 10 containing a surfactant, the number of injections was 8 to 10, and in Examples 11 and 12 containing a nonionic surfactant, the number of injections was 10 to 11 and the surfactant was added. As a result, it was found that the effect of removing filth is enhanced.
（実地試験）
表３に示した実施例及び比較例となる洗浄剤組成物を充填した局所汚れ除去製品を作製し、実際のトイレで便の除去試験を行い、以下の基準で評価した。
◎：噴射5回以内で便汚れが落ちた
○：噴射１０回以内で便汚れが落ちた
×：１０回以上噴射しても落とせない
(Field test)
A local soil removal product filled with the cleaning composition as Examples and Comparative Examples shown in Table 3 was prepared, and a fecal removal test was performed in an actual toilet, and evaluated according to the following criteria.
◎: Stool stain was removed within 5 injections ○: Stool stain was removed within 10 injections ×: Cannot be removed even after 10 or more injections
（２）キャニヨン製 T-95（スタンダード／ジェット）
（３）吉野工業所製 YT87（泡／直）
（４）キャニヨン製 T-95（スタンダード、直径６mmフォーマー付き）
*4 エチレンジアミン四酢酸二ナトリウム
*5 エチレンジアミン四酢酸四ナトリウム
*6 直鎖アルキル（Ｃ１０−Ｃ１４）ベンゼンスルホン酸ナトリウム
*7 ポリオキシエチレン（２）アルキル（Ｃ１２−Ｃ１４）エーテル硫酸エステルナトリウム
*8 アルキル（Ｃ１４−Ｃ１８）スルホン酸ナトリウム
(2) Canyon T-95 (Standard / Jet)
(3) YT87 (foam / straight) manufactured by Yoshino Industry
(4) Canyon T-95 (standard, with 6mm diameter former)
* 4 Disodium ethylenediaminetetraacetate
* 5 Ethylenediaminetetraacetic acid tetrasodium salt
* 6 Linear alkyl (C 10 -C 14 ) sodium benzenesulfonate
* 7 Polyoxyethylene (2) alkyl (C 12 -C 14) ether sulfate ester
* 8 alkyl (C 14 -C 18) sulfonate, sodium
表３に示した通り、噴射力２〜１０ｇ・ｆの実施例１３〜１７は良好な便の除去効果が認められ、その中で、洗浄剤組成物にアニオン界面活性剤を配合し、噴射パターンが６０ｍｍ以下の実施例１４、１５及び１７は更に良好な便の除去効果が認められた。一方、噴射力０．９ｇ・ｆの比較例２は便の汚れを除去できなかった。 As shown in Table 3, Examples 13 to 17 having a jetting power of 2 to 10 g · f showed a good fecal removal effect. Among them, an anionic surfactant was added to the cleaning composition, and a jetting pattern was obtained. In Examples 14, 15 and 17 having a diameter of 60 mm or less, a better stool removal effect was observed. On the other hand, Comparative Example 2 having an injection force of 0.9 g · f could not remove stool stains.
本発明はトイレ用洗浄剤に利用可能であり、用便後の便器に付着した便を除去する効果及び喫水線のカビやヌメリ汚れ除去効果を付与する。本発明の、噴射力２ｇ・ｆ以上のトリガー式噴射装置により、特定の界面活性剤を有する洗浄剤組成物を噴射することで、用便時に付着した便及び喫水線に発生したカビやヌメリのような局所汚れに優れた除去効果を示すとともに、噴射ノズルの切り替えによっては霧や泡噴射洗浄も兼ね備えるトイレ用洗浄剤を提供することができる。 INDUSTRIAL APPLICABILITY The present invention can be used for a toilet cleaning agent, and provides an effect of removing stool adhering to a toilet after use and a water line mold and slime dirt removal effect. By using the trigger type injection device of the present invention having an injection force of 2 g · f or more, a detergent composition having a specific surfactant is injected, so that the stool adhered to the stool and mold or slime generated on the waterline It is possible to provide a toilet cleaning agent that exhibits an excellent removal effect against various local stains and also has mist and foam jet cleaning depending on the switching of the jet nozzle.
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