JP2015081206A - Treatment apparatus for cement kiln exhaust gas - Google Patents

Abstract

PROBLEM TO BE SOLVED: To efficiently recover mercury from cement kiln exhaust gas at low cost. SOLUTION: An external heat kiln 2 that heats dust D1 recovered from a cement kiln exhaust gas to volatilize mercury contained in the dust D1 and a gas G1 containing volatile mercury discharged from the external heat kiln 2 are combined with a mercury-containing gas. The filter-type solid-gas separation device 4 is provided with a filter-type solid-gas separation device 4 that separates G2 and mercury-removing dust D3, and an activated carbon adsorption tower 7 that recovers volatile mercury contained in the separated mercury-containing gas G2. Cement kiln exhaust gas treatment device 1 that heats the filter 4b. The retainer 4c that supports the filter 4b can be an electric heater. [Selection diagram] Fig. 1

Description

  The present invention relates to an apparatus for recovering mercury from combustion exhaust gas discharged from a cement kiln.

  Since mercury is contained in natural raw materials such as limestone, which is the main raw material of cement, and recycled resources such as fly ash, the exhaust gas of cement kiln contains a trace amount of metallic mercury (Hg). If mercury in the exhaust gas from the cement kiln increases, it may cause air pollution and may hinder the expansion of the use of recycled resources such as fly ash.

  Therefore, in Patent Document 1, as shown in FIG. 3, the kiln dust D4 containing mercury contained in the cement kiln exhaust gas is added to the hot air furnace 12 for heating the air A2, and the gas G4 discharged from the hot air furnace 12. The bleed duct 13, the cyclone 14 that collects the mercury-containing gas G5 including the kiln dust D4 and separates it into the mercury-containing gas G6 and the mercury removal dust D5, and the mercury-containing gas G6 discharged from the cyclone 14 A bag filter 15 that separates into mercury-containing gas G7 and mercury-removing dust D6, a Jungstrom-type heat exchanger 16 that recovers heat from the mercury-containing gas G7 discharged from the bag filter 15, and a Jungstrom-type heat exchanger 16 Activated carbon adsorption tower 19 for recovering mercury contained in the mercury-containing gas G8 supplied from the fan 17 through the fan 17, and a Jungstrom type Processor 11 of the cement kiln exhaust gas and a supply fan 18 to heat generated by the exchanger 16 to the hot air furnace 12 is described.

JP 2011-88770 A

  According to the processing apparatus described in Patent Document 1, mercury contained in the cement kiln exhaust gas can be efficiently recovered. However, since the kiln dust D4 and the mercury-containing gas G5 are conveyed by the gas G4 obtained by heating the kiln dust D4, a gas amount that is 10 times or more the gas amount necessary for heating is required. Therefore, the efficiency of heat exchange between the mercury-containing gas G7 and the air A3 in the Jungstrom heat exchanger 16 is reduced, and a solid gas separation device such as the extraction duct 13, the cyclone 14 and the bag filter 15, the activated carbon adsorption tower 19 and the like. The related equipment has to be increased in size, and there is a problem that the equipment cost and the operation cost become high.

  Then, this invention is made | formed in view of the problem in the said prior art, Comprising: It aims at recovering mercury efficiently from cement kiln exhaust gas at low cost.

  In order to achieve the above object, a cement kiln exhaust gas treatment apparatus of the present invention comprises a heating device for heating dust recovered from cement kiln exhaust gas to volatilize mercury contained in the dust, and a volatilization discharged from the heating device. A filter-type solid-gas separation device for separating a gas containing mercury into a mercury-containing gas and mercury-removed dust, and a mercury recovery device for recovering volatile mercury contained in the separated mercury-containing gas, the filter type The filter of the solid-gas separator is heated.

  According to the cement kiln exhaust gas treatment apparatus of the present invention, by heating the filter of the filter-type solid-gas separation device, the gas containing volatile mercury discharged from the heating device can be heated also in the solid-gas separation device. it can. As a result, by reducing the amount of gas supplied to the heating device, even if there is a risk that the amount of heat required for volatilization of mercury contained in the dust may be insufficient, the shortage of heat can be compensated for by the solid-gas separation device. Mercury can be efficiently recovered from the exhaust gas.

  In the cement kiln exhaust gas treatment apparatus, the retainer that supports the filter can be an electric heater, whereby the filter can be heated with a simple configuration.

  The heating device can be an external heat kiln or a U-turn kiln. By using these indirect heating kilns, the amount of gas discharged from the heating device can be reduced, and the related equipment can be downsized. Moreover, it can prevent that a heating medium contains mercury by contact with the dust collect | recovered from cement kiln exhaust gas, and a heating medium, and can simplify an exhaust gas treatment equipment. Moreover, since dust can be heated uniformly, mercury contained in dust can be efficiently volatilized.

  As described above, according to the present invention, it is possible to efficiently recover mercury from cement kiln exhaust gas at low cost.

BRIEF DESCRIPTION OF THE DRAWINGS It is a whole block diagram which shows one Embodiment of the processing apparatus of the cement kiln exhaust gas which concerns on this invention. It is sectional drawing which shows the filter and retainer of a bag filter which comprise the processing apparatus of the cement kiln waste gas of FIG. It is a whole block diagram which shows an example of the processing apparatus of the conventional cement kiln exhaust gas.

  FIG. 1 shows an embodiment of a cement kiln exhaust gas treatment apparatus according to the present invention. This treatment apparatus 1 is supplied with a kiln dust D1 containing mercury and air A1 contained in the cement kiln exhaust gas, and supplies the kiln dust D1. An external heat kiln 2 that is heated and separated into mercury-containing gas G1 and mercury removal dust D2, a hot air furnace 3 that supplies hot air H1 to the external heat kiln 2, and a mercury-containing gas G1 that is discharged from the external heat kiln 2 A bag filter 4 that collects dust and separates into mercury-containing gas G2 and mercury-removed dust D3, a cold air intake unit 5 that introduces cooling air C into the mercury-containing gas G2 discharged from the bag filter 4, and a fan 6 And an activated carbon adsorption tower 7 for recovering mercury from the mercury-containing gas G2 supplied through it.

  An external heat kiln 2 as a heating device is a rotary kiln, and hot air H1 is supplied from a hot stove 3 to a jacket (not shown) surrounding the kiln to heat the inside of the kiln. The hot air H1 from the hot air furnace 3 may be high-temperature air or combustion gas. On the other hand, the kiln dust D <b> 1 is supplied to the external heat kiln 2 and is heated inside the external heat kiln 2.

  A U-turn kiln can be used instead of the external heat kiln 2 as described above. The U-turn kiln includes a cylinder that rotates gently around a horizontal axis and a partition wall having inclined guide vanes, and has an inner cylinder filling rate (hold-up) of 10 to 30% from the conventional 10% or less. The cylinder is downsized by increasing it to 40% to 40%.

  A hot stove 3 as a heating device is provided for blowing hot air H1 into the external heat kiln 2. Kiln dust D1 is heated with hot air H1 to volatilize mercury in kiln dust D1.

  The bag filter 4 has a heat resistance up to about 900 ° C. and includes a filter made of a plurality of rod-shaped ceramic tubes. As shown in FIG. 2, each filter 4b is supported by a gantry 4a by a retainer 4c. . The retainer 4c also has a function as an electric heater, and enables solid-gas separation at a high temperature by heating the filter 4b.

  The bag filter 4 may be a filter in which a plurality of rod-shaped ceramic tubes formed into honeycomb cells are used as a filter, or a filter provided with a sheet-like ceramic filter. Solid-gas separation can be achieved.

  An activated carbon adsorption tower 7 as a mercury recovery device is provided for recovering mercury in the mercury-containing gas G2 introduced by the fan 6. Here, the temperature of the mercury-containing gas G2 is lowered to a temperature at which the gas can be passed through the activated carbon (for example, about 100 ° C.) by the cooling air C introduced from the cold air intake unit 5. As the activated carbon used in the activated carbon adsorption tower 7, it is desirable to select activated carbon that is particularly excellent in mercury recovery ability among commercially available activated carbon. Specifically, activated carbon that has been subjected to sulfur impregnation treatment adjusted for mercury adsorption is suitable.

  Next, operation | movement of the cement kiln exhaust gas processing apparatus 1 which has the said structure is demonstrated, referring FIG.1 and FIG.2.

  The kiln dust D1 and the air A1 are simultaneously supplied to the external heat kiln 2. Further, hot air H1 is supplied from the hot air furnace 3 to the external heat kiln 2, and the kiln dust D1 is indirectly heated to 380 to 500 ° C. by the hot air H1 to volatilize mercury contained in the kiln dust D1. The mercury-containing gas G1 discharged from the external heat kiln 2 is supplied to the bag filter 4, and the mercury removal dust D2 is used as a cement raw material or the like. The hot air H2 after heating the kiln dust D1 is discharged into the atmosphere after appropriate exhaust gas treatment.

  In the bag filter 4, the mercury-containing gas G1 is separated into the mercury-containing gas G2 and the mercury removal dust D3, and the mercury removal dust D3 is recovered and used as a cement raw material or the like. At this time, the retainer 4c of the bag filter 4 is energized to heat the filter 4b to compensate for the shortage of heat required for volatilization of mercury contained in the kiln dust D1. The mercury-containing gas G <b> 2 at 350 to 450 ° C. is cooled to about 100 ° C. by the cooling air C taken from the cold air intake unit 5 and supplied to the activated carbon adsorption tower 7 through the fan 6. Mercury in the mercury-containing gas G2 is recovered in the activated carbon adsorption tower 7, and the exhaust gas G3 after recovery is appropriately exhausted and then released to the atmosphere.

  As described above, in the present embodiment, the amount of gas supplied to the kiln (the amount of heat supplied) is reduced using the external heat kiln 2 or the U-turn kiln, so that mercury is regenerated in the dust collected by the filter 4b. Even in the case of adhering, heating the filter 4b of the bag filter 4 heats and vaporizes the mercury while the dust is adhering to the filter 4b, so that the shortage of heat can be compensated for at low cost. Mercury can be efficiently recovered from the cement kiln exhaust gas.

  In the above-described embodiment, the external heat kiln 2 or the like is used as a heating device. However, any other type of kiln can be used as long as it can heat the kiln dust D1 and volatilize mercury contained in the kiln dust D1. Alternatively, a direct heating type heating device may be used.

  Further, the heat source for heating the filter 4b of the bag filter 4 may be other than the retainer 4c functioning as an electric heater, and can be variously changed depending on the structure of the bag filter 4.

  Furthermore, although the air A1 is supplied to the external heat kiln 2, the exhaust gas from the clinker cooler attached to the cement kiln may be supplied to the external heat kiln 2 and used for indirect heating of the kiln dust D1.

  Further, although the activated carbon adsorption tower 7 is used as the mercury recovery device, a device using activated coke or a gas adsorption device for adsorbing and removing mercury with an adsorbent can also be used.

  Further, the mercury-containing gas G2 is cooled by the cooling air C from the cold air intake section 5, but the temperature is lowered while heat is recovered from the mercury-containing gas G2 by passing the mercury-containing gas G2 through the heat exchanger. You can also.

DESCRIPTION OF SYMBOLS 1 Cement kiln exhaust gas processing apparatus 2 External heat kiln 3 Hot air furnace 4 Bag filter 4a Mounting frame 4b Filter 4c Retainer 5 Cold wind intake part 6 Fan 7 Activated carbon adsorption tower A1 Air C Cooling air D1 Kiln dust D2, D3 Mercury removal dust G1, G2 Mercury Contained gas G3 Exhaust gas H1-H2 Hot air

Claims (3)

A heating device that heats the dust recovered from the cement kiln exhaust gas and volatilizes mercury contained in the dust;
A filter-type solid-gas separation device that separates gas containing volatile mercury discharged from the heating device into mercury-containing gas and mercury-removed dust;
A mercury recovery device for recovering volatile mercury contained in the separated mercury-containing gas,
A cement kiln exhaust gas treatment apparatus, wherein the filter of the filter-type solid-gas separation device is heated.   2. The cement kiln exhaust gas treatment apparatus according to claim 1, wherein the retainer that supports the filter is an electric heater.   The cement kiln exhaust gas treatment apparatus according to claim 1 or 2, wherein the heating device is an external heat kiln or a U-turn kiln.