JP2011236926A - Apparatus and method for manufacturing of high pressure tank - Google Patents

Apparatus and method for manufacturing of high pressure tank Download PDF

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JP2011236926A
JP2011236926A JP2010106161A JP2010106161A JP2011236926A JP 2011236926 A JP2011236926 A JP 2011236926A JP 2010106161 A JP2010106161 A JP 2010106161A JP 2010106161 A JP2010106161 A JP 2010106161A JP 2011236926 A JP2011236926 A JP 2011236926A
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liner
pressure tank
manufacturing
fiber
fiber bundle
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Japanese (ja)
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Takeshi Hatta
健 八田
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Toyota Motor Corp
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Toyota Motor Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/08Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
    • B29C70/086Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers and with one or more layers of pure plastics material, e.g. foam layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/08Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
    • B29C70/088Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers and with one or more layers of non-plastics material or non-specified material, e.g. supports
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/32Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core on a rotating mould, former or core
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage

Abstract

PROBLEM TO BE SOLVED: To provide an apparatus for manufacturing of a high pressure tank capable of improving a widening rate of a fiber bundle when fiber is wound around a liner.SOLUTION: The apparatus for manufacturing of the high pressure tank is provided for manufacturing the high pressure tank having a liner and a reinforcement layer composed by winding fiber around an outer surface of the liner, and has a vibration device for vibrating the liner when the fiber is wound around the outer surface of the liner.

Description

本発明は、高圧タンクの製造装置および高圧タンクの製造方法に関する。   The present invention relates to a high-pressure tank manufacturing apparatus and a high-pressure tank manufacturing method.

燃料電池自動車や天然ガス自動車等には、燃料ガスとしての水素ガスや天然ガス等を貯蔵する高圧タンクが搭載される。高圧タンクとして、樹脂製または金属製タンク(ライナ:内容器)の外面に単位密度当りの強度が非常に高い炭素繊維強化プラスチック材(CFRP材)等を巻き付けて補強した高圧タンクが知られている。このような高圧タンクを製造する際、例えばフィラメントワインディング法のように炭素繊維等の繊維束にエポキシ樹脂等の樹脂溶液を含浸させた状態で樹脂製タンクの外面に巻き付けた後、樹脂を硬化させて補強層を形成する方法がある(例えば、特許文献1参照)。   Fuel cell vehicles and natural gas vehicles are equipped with a high-pressure tank for storing hydrogen gas, natural gas, or the like as fuel gas. As a high-pressure tank, a high-pressure tank reinforced by winding a carbon fiber reinforced plastic material (CFRP material) or the like having a very high strength per unit density around the outer surface of a resin or metal tank (liner: inner container) is known. . When manufacturing such a high-pressure tank, the resin is cured after being wound around the outer surface of a resin tank in a state in which a fiber bundle such as carbon fiber is impregnated with a resin solution such as an epoxy resin as in the filament winding method, for example. There is a method of forming a reinforcing layer (see, for example, Patent Document 1).

フィラメントワインディング法で高圧タンクを製造する場合、炭素繊維等の繊維束をできるたけ拡幅した状態(幅を拡げた状態)でライナに巻き付けた方が、高圧タンクの強度等の点で好ましい。   When manufacturing a high-pressure tank by the filament winding method, it is preferable from the viewpoint of the strength of the high-pressure tank that the fiber bundle of carbon fiber or the like is wound around the liner in a widened state (a widened state) as much as possible.

繊維束の拡幅が少ないと、ライナに繊維を巻く際、繊維層間に空隙や繊維折れ等が発生して、タンク強度低下の原因となることがある。また、例えば、ライナに繊維を巻き付ける前に拡幅ローラ等によって繊維東を押し付けて繊維束を拡幅する方法があるが、拡幅率(拡幅前の繊維束の幅に対する拡幅後の繊維束の幅の比率)が充分ではなく(例えば、拡幅率120〜140%程度)、また、ライナに繊維を巻き付ける前に繊維束の幅を拡げても、実際にライナに巻き付けられるまでに張力やガイドローラ等の影響で繊維束の幅が狭まってしまう(例えば、拡幅率100〜130%程度)と、拡幅効果が少なくなる。さらに、拡幅ローラ等によって繊維束を拡幅させる際に繊維の張力を上げ過ぎると繊維の損傷が発生する可能性がある。   If the fiber bundle is not widened, when the fiber is wound around the liner, voids or fiber breakage may occur between the fiber layers, which may cause a decrease in tank strength. In addition, for example, there is a method of widening the fiber bundle by pressing the fiber east with a widening roller or the like before winding the fiber around the liner, but the widening ratio (ratio of the width of the fiber bundle after widening to the width of the fiber bundle before widening) ) Is not sufficient (for example, about 120 to 140% widening ratio), and even if the width of the fiber bundle is widened before the fiber is wound around the liner, the influence of tension, guide rollers, etc. before the fiber is actually wound around the liner. If the width of the fiber bundle becomes narrow (for example, about 100 to 130% widening ratio), the widening effect is reduced. Furthermore, if the fiber tension is increased too much when the fiber bundle is widened by a widening roller or the like, the fiber may be damaged.

特開2010−019315号公報JP 2010-019315 A

本発明は、ライナへの繊維の巻き付けの際の繊維束の拡幅率を向上することができる高圧タンクの製造装置および高圧タンクの製造方法である。   The present invention is a high-pressure tank manufacturing apparatus and a high-pressure tank manufacturing method capable of improving a fiber bundle widening rate when winding a fiber around a liner.

本発明は、ライナと前記ライナの外面に繊維を巻き付けて構成された補強層とを有する高圧タンクを製造するための高圧タンクの製造装置であって、ライナの外面に繊維を巻き付ける際に前記ライナを振動させる振動手段を有する高圧タンクの製造装置である。   The present invention relates to a high-pressure tank manufacturing apparatus for manufacturing a high-pressure tank having a liner and a reinforcing layer formed by winding fibers on the outer surface of the liner, and the liner is wound when the fibers are wound on the outer surface of the liner. It is a manufacturing apparatus of a high pressure tank which has a vibration means to vibrate.

また、前記高圧タンクの製造装置において、前記振動手段が、前記ライナの回転軸方向に振動させるものであることが好ましい。   In the high-pressure tank manufacturing apparatus, it is preferable that the vibration means vibrate in the direction of the rotation axis of the liner.

また、前記高圧タンクの製造装置において、前記振動手段が、超音波振動発生装置であることが好ましい。   In the high-pressure tank manufacturing apparatus, the vibration means is preferably an ultrasonic vibration generator.

また、本発明は、ライナと前記ライナの外面に繊維を巻き付けて構成された補強層とを有する高圧タンクを製造する高圧タンクの製造方法であって、ライナの外面に繊維を巻き付ける際に前記ライナを振動させる高圧タンクの製造方法である。   The present invention also relates to a method of manufacturing a high-pressure tank having a liner and a reinforcing layer formed by winding fibers on the outer surface of the liner, wherein the liner is wound when the fibers are wound on the outer surface of the liner. It is a manufacturing method of the high-pressure tank which vibrates.

また、前記高圧タンクの製造方法において、前記ライナの回転軸方向に振動させることが好ましい。   Moreover, in the manufacturing method of the said high pressure tank, it is preferable to vibrate in the rotating shaft direction of the said liner.

また、前記高圧タンクの製造方法において、前記振動が、超音波振動であることが好ましい。   In the high pressure tank manufacturing method, the vibration is preferably ultrasonic vibration.

本発明では、ライナの外面に繊維を巻き付ける際にライナを振動させることにより、ライナへの繊維の巻き付けの際の繊維束の拡幅率を向上することができる高圧タンクの製造装置および高圧タンクの製造方法を提供することができる。   In the present invention, the apparatus for manufacturing a high-pressure tank and the manufacture of the high-pressure tank that can improve the fiber bundle widening ratio when the fiber is wound around the liner by vibrating the liner when the fiber is wound around the outer surface of the liner. A method can be provided.

本発明の実施形態に係る高圧タンクの製造装置の一例の全体構成を示す概略図である。It is the schematic which shows the whole structure of an example of the manufacturing apparatus of the high pressure tank which concerns on embodiment of this invention. 本発明の実施形態に係る高圧タンクの製造装置における繊維の巻き付け部分の構成の一例を示す概略図である。It is the schematic which shows an example of a structure of the winding part of the fiber in the manufacturing apparatus of the high pressure tank which concerns on embodiment of this invention. 本発明の実施形態における高圧タンクの製造方法における高圧タンクの軸方向の断面を示す概略図である。It is the schematic which shows the cross section of the axial direction of the high pressure tank in the manufacturing method of the high pressure tank in embodiment of this invention. 本発明の実施形態における繊維束の拡幅の状態を示す概略断面模式図である。It is a schematic cross-sectional schematic diagram which shows the state of the widening of the fiber bundle in embodiment of this invention.

本発明の実施の形態について以下説明する。本実施形態は本発明を実施する一例であって、本発明は本実施形態に限定されるものではない。   Embodiments of the present invention will be described below. This embodiment is an example for carrying out the present invention, and the present invention is not limited to this embodiment.

本発明の実施形態に係る高圧タンクの製造装置の一例の全体構成の概略を図1に示す。また、本実施形態に係る高圧タンクの製造装置における繊維の巻き付け部分の構成の一例の概略を図2に示す。   FIG. 1 shows an outline of an overall configuration of an example of a high-pressure tank manufacturing apparatus according to an embodiment of the present invention. Moreover, the outline of an example of a structure of the winding part of the fiber in the manufacturing apparatus of the high pressure tank which concerns on this embodiment is shown in FIG.

図1に示すように、高圧タンクの製造装置1は、繊維巻き付け装置10を備える。繊維巻き付け装置10は、ライナ22を支持するための回転支持部12を有する。図2に示すように、この回転支持部12には、ライナ22を振動させる振動手段としての振動発生装置14が設置されており、ライナ22に所定の周波数および所定の方向の振動を与えることができる。   As shown in FIG. 1, the high-pressure tank manufacturing apparatus 1 includes a fiber winding device 10. The fiber winding device 10 has a rotation support portion 12 for supporting the liner 22. As shown in FIG. 2, the rotation support unit 12 is provided with a vibration generator 14 as a vibration means for vibrating the liner 22, and can apply vibrations in a predetermined frequency and a predetermined direction to the liner 22. it can.

本実施形態に係る高圧タンクの製造方法および高圧タンクの製造装置1の動作について説明する。   The operation of the high-pressure tank manufacturing method and the high-pressure tank manufacturing apparatus 1 according to this embodiment will be described.

図1,2に示すように、ライナ22は、繊維巻き付け装置10の回転支持部12に設置される。例えば、略円柱状のライナ22は図3に示すようなライナ22の軸を通したシャフト28によって、図2に示すように回転支持部12に支持される。回転支持部12によってライナ22が回転され、図1のボビン16から繰り出された繊維束26がライナ22の外面に巻き付けられる。繊維束26には、例えば、繊維巻き付け装置10の上流側で、エポキシ樹脂等の熱硬化性の樹脂溶液が含浸され、その後、図2に示すように繊維ガイド部18で角度調整されて、ライナ22に巻き付けられる。このとき、繊維束26を巻き付けながら、振動発生装置14によりライナ22自体を振動させる。こうして、ライナ22の外面に繊維束26が拡幅された状態で所定の厚みおよび所定の方向で巻き付けられる。   As shown in FIGS. 1 and 2, the liner 22 is installed on the rotation support portion 12 of the fiber winding device 10. For example, the substantially cylindrical liner 22 is supported by the rotation support portion 12 as shown in FIG. 2 by a shaft 28 that passes through the axis of the liner 22 as shown in FIG. The liner 22 is rotated by the rotation support portion 12, and the fiber bundle 26 fed out from the bobbin 16 of FIG. 1 is wound around the outer surface of the liner 22. The fiber bundle 26 is impregnated with, for example, a thermosetting resin solution such as an epoxy resin on the upstream side of the fiber winding apparatus 10, and then the angle is adjusted by the fiber guide portion 18 as shown in FIG. 22 is wound around. At this time, the liner 22 itself is vibrated by the vibration generator 14 while winding the fiber bundle 26. Thus, the fiber bundle 26 is wound around the outer surface of the liner 22 in a predetermined thickness and in a predetermined direction.

ここで、繊維束を拡幅するとは、例えば図4に示すように、繊維束26を構成する繊維30を拡げて繊維束26を略扁平な状態にすることを意味する。   Here, widening the fiber bundle means, for example, as shown in FIG. 4, the fibers 30 constituting the fiber bundle 26 are expanded to make the fiber bundle 26 substantially flat.

なお、回転支持部12に、例えば空気等のガスを供給するガスボンベに通じるガス供給管が接続されて、空気等のガスをガス供給管および回転支持部12を通じてライナ22内に供給して、ライナ22内を加圧状態として繊維を巻き付けてもよい。これにより、繊維束26の巻き付けによりライナ22が変形するのを防止することができる。   For example, a gas supply pipe that communicates with a gas cylinder that supplies a gas such as air is connected to the rotation support unit 12, and a gas such as air is supplied into the liner 22 through the gas supply pipe and the rotation support unit 12. The fiber may be wound with the inside of 22 being in a pressurized state. Thereby, it is possible to prevent the liner 22 from being deformed by winding the fiber bundle 26.

繊維束26の巻き付け工程後、高圧タンク20は、加熱炉等において熱処理される。高圧タンク20は、例えば130℃程度で、10〜15時間程度加熱される。この加熱により、熱硬化性樹脂等が含浸された繊維束26が熱硬化され、図3に示すような補強層24が形成される。その後、高圧タンク20は冷却される。このようにして、ライナ22の外面に補強層24が形成された高圧タンク20が製造される。   After the step of winding the fiber bundle 26, the high-pressure tank 20 is heat-treated in a heating furnace or the like. The high-pressure tank 20 is heated at about 130 ° C. for about 10 to 15 hours, for example. By this heating, the fiber bundle 26 impregnated with the thermosetting resin or the like is thermoset, and a reinforcing layer 24 as shown in FIG. 3 is formed. Thereafter, the high-pressure tank 20 is cooled. In this way, the high-pressure tank 20 in which the reinforcing layer 24 is formed on the outer surface of the liner 22 is manufactured.

このように、繊維束26をライナ22に巻き付けると同時に振動発生装置14によってライナ22の例えば回転軸方向に振動を与えて、ライナ22自体を振動させることにより、繊維束26の拡幅率を向上させることができる。繊維束26をライナ22に巻き付けながら、直接拡幅することで、繊維東26の拡幅率を向上させることができる。したがって、繊維束26を繊維巻き付け装置10の上流側で拡幅ローラ等の拡幅手段により拡幅した状態で巻き付ける場合以上に、拡幅率を向上することができる。   In this way, the fiber bundle 26 is wound around the liner 22 and at the same time, the vibration generator 14 applies vibration in the direction of the rotation axis of the liner 22 to vibrate the liner 22 itself, thereby improving the width expansion rate of the fiber bundle 26. be able to. By directly expanding the fiber bundle 26 while winding the fiber bundle 26 around the liner 22, the expansion ratio of the fiber east 26 can be improved. Therefore, the widening rate can be improved more than when the fiber bundle 26 is wound in the state of being widened by the widening means such as the widening roller on the upstream side of the fiber winding device 10.

また、巻き付ける繊維束26が樹脂を含浸している場合、樹脂の粘度等により拡幅しにくい傾向にあるが、ライナ22に振動を与えることにより、繊維束26がより拡幅しやすくなる。また、ライナ22に振動を与えることによって拡幅させるために、繊維束26の張力を必要以上に上昇させなくてもよいので、繊維の折損等の損傷を防止することができる。   Further, when the fiber bundle 26 to be wound is impregnated with a resin, it tends to be difficult to widen due to the viscosity of the resin or the like, but by applying vibration to the liner 22, the fiber bundle 26 becomes easier to widen. In addition, since the tension of the fiber bundle 26 does not need to be increased more than necessary in order to widen the liner 22 by applying vibration, damage such as fiber breakage can be prevented.

このように、フィラメントワインディング法によりライナ22に繊維束26を巻き付ける際に、繊維束26の拡幅率が向上することにより、繊維層間の空隙や繊維折れ等の発生が抑制され、得られる高圧タンクの強度および疲労強度等が向上し、かつ、良好な品質で、また品質の安定した高圧タンクを製造することができる。また、繊維束26を巻き付けながら拡幅できるため、生産性が低下しない。   As described above, when the fiber bundle 26 is wound around the liner 22 by the filament winding method, the expansion rate of the fiber bundle 26 is improved, so that the generation of voids between the fiber layers, fiber breakage, and the like is suppressed, and the resulting high-pressure tank A high-pressure tank with improved strength and fatigue strength, and good quality and stable quality can be produced. Further, since the fiber bundle 26 can be widened while being wound, productivity does not decrease.

高圧タンク20は、ライナ(内容器)22、補強層(外層)24を含んで構成されている。また、高圧タンク20は、ガス充填・放出口等を備えてもよい。   The high-pressure tank 20 includes a liner (inner container) 22 and a reinforcing layer (outer layer) 24. Further, the high-pressure tank 20 may include a gas filling / releasing port.

ライナ22は、略円柱状等に形成されてなり、例えば高圧水素ガスなどの媒体をその内部に収容するためのものであり、水素ガス等のガスに直接接触する層である。ライナ22の形状、サイズ、厚みは使用目的、仕様等に応じたものを任意に選択することができる。ライナ22の厚みは、例えば、2mm〜4mmの範囲である。   The liner 22 is formed in a substantially cylindrical shape or the like, for example, for accommodating a medium such as high-pressure hydrogen gas therein, and is a layer in direct contact with a gas such as hydrogen gas. The shape, size, and thickness of the liner 22 can be arbitrarily selected according to the purpose of use, specifications, and the like. The liner 22 has a thickness in the range of 2 mm to 4 mm, for example.

ライナ22は、樹脂材料、金属等を含んで構成される。ライナ22を構成する樹脂材料としては、熱可塑性樹脂、熱硬化性樹脂等が挙げられる。熱可塑性樹脂としては、ポリエチレン、ポリプロピレン、ポリ塩化ビニル、ABS樹脂、ポリスチレン、ポリアミド、ポリカーボネート、ポリイミド、フッ素樹脂等が挙げられ、熱硬化性樹脂としては、エポキシ樹脂やポリウレタン等が挙げられる。ライナを構成する金属としては、アルミ合金等の金属が挙げられる。ライナの肉厚やライナを構成する材料の種類は、ライナ22に要求される強度、気密性、成形性等に応じて適宜選択することができる。これらのうち、強度や耐ガス透過性等の点からナイロン等のポリアミド樹脂が好ましい。   The liner 22 includes a resin material, a metal, and the like. Examples of the resin material constituting the liner 22 include a thermoplastic resin and a thermosetting resin. Examples of the thermoplastic resin include polyethylene, polypropylene, polyvinyl chloride, ABS resin, polystyrene, polyamide, polycarbonate, polyimide, and fluorine resin. Examples of the thermosetting resin include epoxy resin and polyurethane. Examples of the metal constituting the liner include metals such as aluminum alloys. The thickness of the liner and the type of material constituting the liner can be appropriately selected according to the strength, hermeticity, moldability, and the like required for the liner 22. Of these, polyamide resins such as nylon are preferable from the viewpoint of strength and gas permeability resistance.

樹脂材料から構成されるライナ22は、例えば、上記樹脂の射出成形により成形される。例えば、金型にポリアミド樹脂等の樹脂を流し込んで、略半円柱体を2つ成型し、それらをレーザ等により溶着して樹脂のライナ22が成形される。この射出成形により、厚みが略均一なライナ22が成形される。   The liner 22 composed of a resin material is molded by, for example, injection molding of the resin. For example, a resin such as a polyamide resin is poured into a mold, two substantially semi-cylindrical bodies are formed, and these are welded by a laser or the like to form a resin liner 22. By this injection molding, the liner 22 having a substantially uniform thickness is formed.

補強層24は、ライナ22の外側を覆うように設けられてライナ22を補強する層であり、例えば、繊維およびマトリックス樹脂を含んで構成される。補強層24を構成する繊維としては、ガラス繊維、炭素繊維、アラミド繊維、金属繊維等が挙げられる。   The reinforcing layer 24 is a layer that is provided so as to cover the outer side of the liner 22 and reinforces the liner 22, and includes, for example, a fiber and a matrix resin. Examples of the fibers constituting the reinforcing layer 24 include glass fibers, carbon fibers, aramid fibers, and metal fibers.

また、補強層24を構成するマトリックス樹脂としては、熱可塑性樹脂、熱硬化性樹脂等が挙げられる。熱可塑性樹脂としては、ポリエチレン、ポリプロピレン、ポリ塩化ビニル、ABS樹脂、ポリスチレン、ポリアミド、ポリカーボネート、ポリイミド、フッ素樹脂等が挙げられ、熱硬化性樹脂としては、エポキシ樹脂やポリウレタン等が挙げられる。これらのうち、強度や接着性等の点からエポキシ樹脂が好ましい。   Moreover, as a matrix resin which comprises the reinforcement layer 24, a thermoplastic resin, a thermosetting resin, etc. are mentioned. Examples of the thermoplastic resin include polyethylene, polypropylene, polyvinyl chloride, ABS resin, polystyrene, polyamide, polycarbonate, polyimide, and fluorine resin. Examples of the thermosetting resin include epoxy resin and polyurethane. Among these, an epoxy resin is preferable from the viewpoint of strength and adhesiveness.

補強層24は、例えば、繊維の繊維束にマトリックス樹脂溶液を含浸させた状態でライナ22の外面に巻き付けた後、樹脂を硬化させて形成することができる。   The reinforcing layer 24 can be formed by, for example, winding the fiber bundle of fibers around the outer surface of the liner 22 in a state where the matrix resin solution is impregnated, and then curing the resin.

補強層24の厚みは、巻き付ける繊維束26の層数等により調整することができ、例えば、20mm〜40mmの範囲である。   The thickness of the reinforcing layer 24 can be adjusted by the number of layers of the fiber bundle 26 to be wound, and is, for example, in the range of 20 mm to 40 mm.

繊維束26は、例えば、上記繊維が10,000〜40,000本程度束ねられたものである。   The fiber bundle 26 is, for example, a bundle of about 10,000 to 40,000 fibers.

振動発生装置14は、回転支持部12に内蔵してもよいし、回転支持部12の外部に設置してもよい。   The vibration generator 14 may be built in the rotation support unit 12 or installed outside the rotation support unit 12.

ライナ22に与える振動については特に制限はないが、例えば、周波数が超音波領域、音波領域等の振動を与えればよい。ライナ22に細かい振動を抑制して与えることができる等の点で超音波振動が好ましい。   Although there is no restriction | limiting in particular about the vibration given to the liner 22, For example, what is necessary is just to give vibrations, such as a frequency, an ultrasonic region, a sound wave region. Ultrasonic vibration is preferable in that fine vibration can be suppressed and applied to the liner 22.

ライナ22に与える振動の方向については特に制限はないが、例えば、繊維を巻き付ける際のライナ22の回転軸方向、あるいはライナ22の回転軸に対して垂直方向等とすればよい。拡幅率がより向上する等の点で、振動方向はライナ22の回転軸方向が好ましい。通常、繊維束26の巻き付け方向は、ライナ22の回転軸に対して垂直方向、または斜め方向であり、いずれの場合もライナ22に与える振動の方向はライナ22の回転軸方向であればよいが、もちろん、ライナ22に与える振動の方向を繊維の巻き付け方向に応じて変更してもよい。   The direction of vibration applied to the liner 22 is not particularly limited, and may be, for example, the rotation axis direction of the liner 22 when the fiber is wound or the direction perpendicular to the rotation axis of the liner 22. The vibration direction is preferably in the direction of the rotation axis of the liner 22 in that the width expansion rate is further improved. Usually, the winding direction of the fiber bundle 26 is a direction perpendicular to the rotation axis of the liner 22 or an oblique direction. In any case, the direction of vibration applied to the liner 22 may be the rotation axis direction of the liner 22. Of course, you may change the direction of the vibration given to the liner 22 according to the winding direction of a fiber.

繊維束26の拡幅率は、拡幅前の繊維束の幅に対する拡幅後の繊維束の幅の比率(%)として定義されるが、本実施形態に係る製造装置および製造方法によってライナ22に振動を与えることにより、例えば、拡幅率として120%以上、150%以上、あるいは200%以上にまで向上させることができる。   The widening rate of the fiber bundle 26 is defined as a ratio (%) of the width of the fiber bundle after widening to the width of the fiber bundle before widening, but the liner 22 is vibrated by the manufacturing apparatus and the manufacturing method according to this embodiment. By giving, for example, the widening ratio can be improved to 120% or more, 150% or more, or 200% or more.

本実施形態に係る製造装置および製造方法において、ライナ22に繊維束26を巻き付ける前に、拡幅ローラ等の拡幅手段を設けて、拡幅ローラ等に繊維束26を押し付けて予めある程度拡幅しておいてもよい。   In the manufacturing apparatus and manufacturing method according to the present embodiment, before the fiber bundle 26 is wound around the liner 22, widening means such as a widening roller is provided, and the fiber bundle 26 is pressed against the widening roller or the like to widen to some extent in advance. Also good.

本実施形態に係る高圧タンク20は、例えば、移動体に搭載され、内部に高圧ガスを貯蔵する高圧タンクである。また、高圧タンク20は、据え置き型の高圧タンクであってもよい。   The high-pressure tank 20 according to the present embodiment is, for example, a high-pressure tank that is mounted on a moving body and stores high-pressure gas therein. The high pressure tank 20 may be a stationary high pressure tank.

ここで、移動体としては、二輪の車両、バスや乗用車等の四輪以上の自動車のほか、電車、船舶、航空機、ロボットなどが挙げられ、特に燃料電池車両である。高圧ガスとしては、水素ガスや圧縮天然ガスなどが挙げられる。   Here, examples of the moving body include two-wheeled vehicles, automobiles having four or more wheels such as buses and passenger cars, trains, ships, airplanes, robots, and the like, and particularly fuel cell vehicles. Examples of the high pressure gas include hydrogen gas and compressed natural gas.

本実施形態に係る高圧タンクの製造装置および高圧タンクの製造方法により得られる繊維束は、樹脂溶液を含浸させて硬化した繊維強化プラスチック材(FRP材)等として、各種素材の強化材等に用いることができる。例えば、炭素繊維の場合、炭素繊維の繊維束にエポキシ樹脂等の樹脂溶液を含浸させた炭素繊維強化プラスチック材(CFRP材)として、高圧タンク、自動車用シャフト、航空機の胴体、部品等の補強材として用いることができる。   The fiber bundle obtained by the high-pressure tank manufacturing apparatus and the high-pressure tank manufacturing method according to the present embodiment is used as a reinforcing material for various materials as a fiber reinforced plastic material (FRP material) that has been impregnated with a resin solution and cured. be able to. For example, in the case of carbon fiber, a carbon fiber reinforced plastic material (CFRP material) in which a fiber bundle of carbon fiber is impregnated with a resin solution such as an epoxy resin is used as a reinforcing material for a high-pressure tank, an automobile shaft, an aircraft fuselage, parts, etc. Can be used as

以下、実施例および比較例を挙げ、本発明をより具体的に詳細に説明するが、本発明は、以下の実施例に限定されるものではない。   Hereinafter, although an example and a comparative example are given and the present invention is explained more concretely in detail, the present invention is not limited to the following examples.

(実施例1)
図1に示すような高圧タンクの製造装置を使用して、炭素繊維束の拡幅を行った。振動発生装置として超音波振動発生装置を用いた。樹脂ライナを回転させて、超音波振動発生装置によって樹脂ライナの回転軸方向に超音波振動を与えながら、炭素繊維の繊維束(繊維約24,000本がエポキシ樹脂により束ねられたもの)を樹脂ライナに巻き付けた。炭素繊維の拡幅率を測定したところ、150%であった。
Example 1
The carbon fiber bundle was widened using a high-pressure tank manufacturing apparatus as shown in FIG. An ultrasonic vibration generator was used as the vibration generator. While rotating the resin liner and applying ultrasonic vibration in the direction of the rotation axis of the resin liner by an ultrasonic vibration generator, a fiber bundle of carbon fibers (about 24,000 fibers bundled with epoxy resin) is resinized. Wound around the liner. When the expansion ratio of the carbon fiber was measured, it was 150%.

(比較例1)
炭素繊維の巻き付け時に超音波振動を与えなかった以外は実施例1と同様にして炭素繊維の繊維束を樹脂ライナに巻き付けた。炭素繊維の拡幅率を測定したところ、110%であり、実施例1より低かった。
(Comparative Example 1)
A fiber bundle of carbon fibers was wound around a resin liner in the same manner as in Example 1 except that no ultrasonic vibration was applied when the carbon fibers were wound. When the carbon fiber widening ratio was measured, it was 110%, which was lower than Example 1.

1 高圧タンクの製造装置、10 繊維巻き付け装置、12 回転支持部、14 振動発生装置、16 ボビン、18 繊維ガイド部、20 高圧タンク、22 ライナ(内容器)、24 補強層(外層)、26 繊維束、28 シャフト、30 繊維。 DESCRIPTION OF SYMBOLS 1 High pressure tank manufacturing apparatus, 10 Fiber winding apparatus, 12 Rotation support part, 14 Vibration generator, 16 Bobbin, 18 Fiber guide part, 20 High pressure tank, 22 Liner (inner container), 24 Reinforcement layer (outer layer), 26 Fiber Bundle, 28 shafts, 30 fibers.

Claims (6)

ライナと前記ライナの外面に繊維を巻き付けて構成された補強層とを有する高圧タンクを製造するための高圧タンクの製造装置であって、
ライナの外面に繊維を巻き付ける際に前記ライナを振動させる振動手段を有することを特徴とする高圧タンクの製造装置。
An apparatus for manufacturing a high-pressure tank for manufacturing a high-pressure tank having a liner and a reinforcing layer formed by winding fibers around the outer surface of the liner,
An apparatus for manufacturing a high-pressure tank, comprising: a vibrating means for vibrating the liner when a fiber is wound around the outer surface of the liner.
請求項1に記載の高圧タンクの製造装置であって、
前記振動手段が、前記ライナの回転軸方向に振動させるものであることを特徴とする高圧タンクの製造装置。
The high-pressure tank manufacturing apparatus according to claim 1,
The high-pressure tank manufacturing apparatus, wherein the vibration means vibrates in the direction of the rotation axis of the liner.
請求項1または2に記載の高圧タンクの製造装置であって、
前記振動手段が、超音波振動発生装置であることを特徴とする高圧タンクの製造装置。
An apparatus for manufacturing a high-pressure tank according to claim 1 or 2,
The apparatus for producing a high-pressure tank, wherein the vibration means is an ultrasonic vibration generator.
ライナと前記ライナの外面に繊維を巻き付けて構成された補強層とを有する高圧タンクを製造する高圧タンクの製造方法であって、
ライナの外面に繊維を巻き付ける際に前記ライナを振動させることを特徴とする高圧タンクの製造方法。
A method of manufacturing a high-pressure tank, which manufactures a high-pressure tank having a liner and a reinforcing layer formed by winding fibers around the outer surface of the liner,
A method of manufacturing a high-pressure tank, wherein the liner is vibrated when a fiber is wound around an outer surface of the liner.
請求項4に記載の高圧タンクの製造方法であって、
前記ライナの回転軸方向に振動させることを特徴とする高圧タンクの製造方法。
It is a manufacturing method of the high-pressure tank according to claim 4,
A method of manufacturing a high-pressure tank, wherein the liner is vibrated in the direction of the rotation axis.
請求項4または5に記載の高圧タンクの製造方法であって、
前記振動が、超音波振動であることを特徴とする高圧タンクの製造方法。
It is a manufacturing method of the high-pressure tank according to claim 4 or 5,
The method for manufacturing a high-pressure tank, wherein the vibration is ultrasonic vibration.
JP2010106161A 2010-05-06 2010-05-06 Apparatus and method for manufacturing of high pressure tank Pending JP2011236926A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103375678A (en) * 2012-04-26 2013-10-30 中冶南方工程技术有限公司 Novel storage device of mobile cables of gas holder
DE102014208830A1 (en) * 2014-05-12 2015-11-12 Bayerische Motoren Werke Aktiengesellschaft Pressure vessel with wet-rolled CFRP

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103375678A (en) * 2012-04-26 2013-10-30 中冶南方工程技术有限公司 Novel storage device of mobile cables of gas holder
DE102014208830A1 (en) * 2014-05-12 2015-11-12 Bayerische Motoren Werke Aktiengesellschaft Pressure vessel with wet-rolled CFRP
WO2015172913A1 (en) * 2014-05-12 2015-11-19 Bayerische Motoren Werke Aktiengesellschaft Pressure vessel having wet-wrapped carbon-fiber-reinforced plastic
CN105980763A (en) * 2014-05-12 2016-09-28 宝马股份公司 Pressure vessel having wet-wrapped carbon-fiber-reinforced plastic
US10260678B2 (en) 2014-05-12 2019-04-16 Bayerische Motoren Werke Aktiengesellschaft Pressure vessel having wet-wrapped carbon-fiber-reinforced plastic

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