JP2011208147A - Easily adhesive thermoplastic resin film - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an easily adhesive thermoplastic resin film which is excellent in adhesion to a functional layer under high temperature and high humidity conditions.SOLUTION: The easily adhesive thermoplastic resin film which has a coating layer on at least one surface of a thermoplastic resin film. The coating layer contains a polyester resin that does not substantially contain a carboxylic acid group and has a number average molecular weight of not less than 15,000, and a carbodiimide compound as main components.

Description

  The present invention relates to an easily-adhesive thermoplastic resin film excellent in adhesion and moisture and heat resistance. Specifically, it is suitable as a base material for functional films such as hard coat films, antireflection films, light diffusion sheets, prismatic lens sheets, near-infrared shielding films, transparent conductive films, and antiglare films, which are mainly used for displays and the like. The present invention relates to an easily adhesive thermoplastic film.

  In general, a transparent thermoplastic resin made of polyethylene terephthalate (PET), acrylic, polycarbonate (PC), triacetyl cellulose (TAC), polyolefin or the like is used as a base material for a functional film used as a liquid crystal display (LCD) member. A film is used.

  When using the thermoplastic resin film as a base material for various functional films, functional layers corresponding to various applications are laminated. For example, in a liquid crystal display (LCD), a protective film (hard coat layer) that prevents scratches on the surface, an antireflection layer (AR layer) that prevents reflection of external light, and a prism layer that is used to collect and diffuse light And a functional layer such as a light diffusion layer for improving luminance. Among such substrates, particularly polyester films are widely used as substrates for various functional films because they are excellent in transparency, dimensional stability and chemical resistance and are relatively inexpensive.

  In general, in the case of a biaxially oriented thermoplastic film such as a biaxially oriented polyester film or a biaxially oriented polyamide film, the film surface is highly crystallized, so it has good adhesion to various paints, adhesives, inks, etc. There is a disadvantage of being scarce. For this reason, methods for imparting easy adhesion to the biaxially oriented thermoplastic resin film surface by various methods have been proposed.

  For example, by providing a coating layer containing various resins such as polyester, acrylic, polyurethane, and acrylic graft polyester on the surface of the thermoplastic resin film of the base material as the main component of the coating layer, the base film can be easily adhered. The method of giving is generally known. Among these coating methods, an aqueous coating solution containing the resin solution or a dispersion obtained by dispersing the resin in a dispersion medium is coated on a thermoplastic resin film before completion of crystal orientation, and dried. Thereafter, the film is stretched at least in a uniaxial direction and then subjected to heat treatment to complete the orientation of the thermoplastic resin film (so-called in-line coating method), or after the production of the thermoplastic resin film, the film is water-based or solvent-based. A method of drying after applying a coating solution (so-called off-line coating method) has been industrially implemented.

  A display such as an LCD or PDP, or a portable device using a hard coat film as a member is used in various environments regardless of indoors or outdoors. In particular, portable devices may require moisture and heat resistance that can withstand a bathroom, a hot and humid area, and the like. The functional film used for such applications is required to have high adhesion such that delamination does not occur even under high temperature and high humidity. Therefore, in the following patent document, an easy-adhesive thermoplastic resin film imparted with moisture and heat resistance is disclosed by adding a crosslinking agent to the coating solution and forming a crosslinked structure in the coating layer resin when forming the coating layer by the in-line coating method. Has been.

JP 2000-141574 A Japanese Patent No. 3773738 Japanese Patent No. 3900191 JP 2007-253512 A

  Longer life expectancy is expected for home appliances with a display to reduce the global environmental impact. Therefore, it was considered that the functional film used as a member also needs to maintain adhesion for a long time even under high temperature and high humidity. However, the easy-adhesion film as disclosed in the above-mentioned patent document shows good adhesion at first, but a decrease in adhesion strength is inevitable in long-term use under high temperature and high humidity. . Due to such a decrease in adhesion, there is a problem that the initial performance is not maintained for a long time.

  In view of the above-mentioned problems, the present invention has been considered to be an easily-adhesive thermoplastic resin that has been considered to be unavoidable in the past, and that hardly causes deterioration of the coating layer under high temperature and high humidity. A film is provided.

  The adhesiveness under high temperature and high humidity referred to in the present invention is a hard coat layer formed by laminating a hard coat layer, placing it in an environment of 80 ° C., 95% RH, 48 hours, and using a cutter guide with a gap interval of 2 mm. Apply 100 cell-shaped cuts that penetrate the layer to the base film on the hard coat layer surface, and then apply cellophane adhesive tape to the cell-shaped cut surface and rub it with an eraser to ensure complete contact. Means the adhesion when peeled 5 times vigorously, and is an adhesion in a stricter criterion than the evaluation method described in JIS K5600-5-6, which is generally used. It is a problem that the adhesiveness under moisture shows an adhesiveness equivalent to or higher than the initial adhesiveness.

  As a result of intensive studies to solve the above problems, the present inventor has achieved a conventional technique in which adhesion is improved under high temperature and high humidity by using a coating layer containing a polyester resin having a specific molecular weight and a carbodiimide compound. The present inventors have found a fact that overturns common sense and have arrived at the present invention. As described in the above-mentioned patent document, in order to improve the adhesion of the coating layer in the conventional technical common sense, it is mixed with a crosslinking agent and a resin having a functional group capable of reacting with it, and a highly crosslinked structure is formed when the coating layer is formed. It has been considered desirable to form. However, the present invention uses a polyester resin that does not substantially have a carboxylic acid group that is a functional group that reacts with a carbodiimide group, thereby improving adhesion under high temperature and high humidity. It is an easily adhesive film based on the idea.

The above-described problem can be achieved by the following solution means. (1) An easily adhesive thermoplastic resin film having a coating layer on at least one surface of a thermoplastic resin film, wherein the coating layer has a number average molecular weight of 15000 or more and has substantially no carboxylic acid group An easily adhesive thermoplastic resin film comprising a resin and a carbodiimide compound as main components.
(2) The easily adhesive thermoplastic resin film, wherein the polyester resin contains a dicarboxylic acid component represented by the following formula (1) and / or a diol component represented by the following formula (2).
(1) HOOC- (CH ₂ ) _n —COOH (where n is an integer of 4 ≦ n ≦ 10)
(2) HO— (CH ₂ ) _n —OH (where n is an integer of 4 ≦ n ≦ 10)
(3) The easy-adhesive thermoplastic resin film comprising naphthalenedicarboxylic acid as an acid component of the polyester resin.
(4) The easily-adhesive thermoplastic resin film in which the carbodiimide compound is water-soluble and the haze is 2.0% or less. (5) A hard coat layer, light is applied to the coating layer of the easily-adhesive thermoplastic resin film. A laminated thermoplastic resin film obtained by laminating at least one functional layer selected from a diffusion layer, a prismatic lens layer, an electromagnetic wave absorption layer, a near infrared ray blocking layer, and a transparent conductive layer.

The easily-adhesive thermoplastic resin film of the present invention is excellent in adhesiveness (humidity heat resistance) with the functional layer under high temperature and high humidity. Therefore, as a preferred embodiment, the adhesion at the high temperature and high humidity treatment is equal to or improved from the initial adhesion. As a preferred embodiment of the present invention, when the easy-adhesive thermoplastic resin film of the present invention is used as a substrate for a lens sheet, the adhesion with the lens layer under high temperature and high humidity is good.
Furthermore, in a preferred embodiment of the present invention, optical interference fringes are suppressed and the visibility is excellent.

(Thermoplastic resin film)
The thermoplastic resin constituting the thermoplastic resin film used as a substrate in the present invention is a polyolefin resin such as polyethylene or polypropylene, a polyamide resin such as nylon 6 or nylon 66, polyethylene terephthalate, polybutylene terephthalate, polyethylene-2,6- As naphthalate, polymethylene terephthalate, and copolymer components, for example, diol components such as diethylene glycol, neopentyl glycol, polyalkylene glycol, adipic acid, sebacic acid, phthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, etc. A polyester resin copolymerized with a dicarboxylic acid component or the like can be used. Of these, polyester resins are preferred from the viewpoint of mechanical strength and chemical resistance.

  The polyester resin suitably used in the present invention mainly contains at least one of polyethylene terephthalate, polypropylene terephthalate, polybutylene terephthalate, and polyethylene naphthalate as a constituent component. Among these polyester resins, polyethylene terephthalate is most preferable from the balance between physical properties and cost. Moreover, these polyester films can improve chemical resistance, heat resistance, mechanical strength, etc. by biaxially stretching.

  The biaxially stretched polyester film may be a single layer or a multilayer. Moreover, as long as it exists in the range with the effect of this invention, each of these layers can contain various additives in a polyester resin as needed. Examples of the additive include an antioxidant, a light resistance agent, an antigelling agent, an organic wetting agent, an antistatic agent, an ultraviolet absorber, and a surfactant.

  In addition, in order to improve handling properties such as slipperiness, rollability and blocking resistance of the film, and wear characteristics such as wear resistance and scratch resistance, inert particles may be included in the polyester film. However, when used as a base film for an optical member, it is required to have excellent handling properties while maintaining high transparency. Specifically, when used as a substrate film for an optical member, the total light transmittance of the easily adhesive polyester film is preferably 85% or more, more preferably 87% or more, and even more preferably 88% or more. 89% or more is more preferable, and 90% or more is particularly preferable.

  For high definition, the content of inert particles in the base film is preferably as small as possible. Therefore, it is preferable to make a multilayer structure in which particles are contained only in the surface layer of the film, or to contain fine particles only in the coating layer without substantially containing particles in the film.

  In particular, from the viewpoint of transparency, when an inert particle is practically not contained in the polyester film, an inorganic and / or heat-resistant polymer particle is contained in the aqueous coating solution in order to improve the handleability of the film. It is preferable to form irregularities on the surface of the coating layer.

  Note that “substantially no inert particles” means, for example, in the case of inorganic particles, when the element derived from the particles is quantitatively analyzed by fluorescent X-ray analysis, 50 ppm or less, preferably 10 ppm or less, Preferably, the content is below the detection limit. This means that even if particles are not actively added to the base film, contaminants derived from foreign substances and raw material resin or dirt adhering to the line or equipment in the film manufacturing process will be peeled off and mixed into the film. It is because there is a case to do.

  In addition, from the viewpoint of achieving both high transparency and handling properties, it is also a preferred embodiment to add inert particles only to the surface layer. For example, in the case of a three-layer structure, it is preferable that particles are contained in the outermost layer (A layer in the case of A layer / B layer / A layer), and the center layer (B layer) is substantially free of particles. .

  The type and content of the particles contained in the outermost layer may be inorganic particles or organic particles, and are not particularly limited, but include metal oxidation such as silica, titanium dioxide, talc, and kaolinite. Examples thereof include inorganic particles that are inert to polyesters such as products, calcium carbonate, calcium phosphate, and barium sulfate. Any one of these inert inorganic particles may be used alone, or two or more thereof may be used in combination.

  The particles preferably have an average particle size of 0.1 to 3.5 μm. If the average particle size is less than the lower limit, sufficient handling properties may not be obtained. If the upper limit is exceeded, the transparency may decrease. The content of inorganic particles in the outermost layer is preferably 0.01 to 0.20 mass% with respect to the polyester constituting the outermost layer. If it is less than the lower limit, sufficient handling properties cannot be obtained. When the upper limit is exceeded, the transparency decreases.

  Furthermore, when reflectivity and high concealability are required, a whitening film having a high void content may be used by adding a cavity developer in the base film. In applications where moldability is required, a molding film imparted with moldability by adding a copolymer component as a polyester resin may be used.

  The thickness of the base film used in the present invention is not particularly limited, but can be arbitrarily determined in the range of 30 to 500 μm according to the standard to be used. The upper limit of the thickness of the base film is preferably 350 μm, particularly preferably 250 μm. On the other hand, the lower limit of the film thickness is preferably 50 μm, more preferably 75 μm, and particularly preferably 100 μm. When the film thickness is less than the lower limit, rigidity and mechanical strength tend to be insufficient. On the other hand, when the film thickness exceeds the upper limit, the cost may increase.

(Coating layer)
In the easy-adhesive film of the present invention, it is important to provide a coating layer containing a polyester resin having at least a number average molecular weight of 15000 or more and having substantially no carboxylic acid group and a resin having a carbodiimide group.

Conventionally, it has been considered desirable to positively introduce a crosslinked structure from the viewpoint of improving the heat and moisture resistance of the coating layer. However, in this invention, it discovered that heat-and-moisture resistance improved by making a coating layer into the above structures. Although the mechanism by which the adhesiveness under high temperature and high humidity is improved by such a configuration is not well understood, the present inventor thinks as follows. Since the coating layer of the present invention is substantially free of carboxylic acid groups that are functional groups that react with carbodiimide groups, unreacted carbodiimide groups remain in the coating layer when the coating layer is formed. On the other hand, under high temperature and high humidity, the polyester resin in the coating layer undergoes hydrolysis, the ester bond is broken, and carboxylic acid group terminals are generated. Here, the unreacted carbodiimide group reacts with the generated carboxylic acid terminal to form a crosslink. In other words, it is considered that the deterioration of the coating film strength under high temperature and high humidity can be prevented by self-healing the deterioration of the coating film strength due to hydrolysis.

  According to the above aspect, the present invention can improve the adhesion (humidity heat resistance) with a hard coat layer, a lens layer, and other functional layers under high temperature and high humidity. Further, the configuration of the present invention will be described in detail below.

  The coating layer of the present invention needs to contain a polyester resin. Adhesion can be improved by containing a polyester resin.

  The polyester resin preferably has fewer carboxylic acid groups that are reactive groups with carbodiimide groups. More preferably, it has substantially no carboxylic acid group. Here, having substantially no carboxylic group means that it contains no carboxylic acid group other than the terminal group. As a method for defining a carboxylic acid group, an acid value can be measured. However, the polyester resin having substantially no carboxylic acid group has an acid value of 3 KOHmg / g or less, more preferably 2 KOHmg / g or less. More preferably, it is a polyester resin of 1 KOHmg / g or less.

  The number average molecular weight of the polyester resin needs to be 15000 or more. When the number average molecular weight is low, the terminal carboxylic acid group increases, which may cause a reaction with a carbodiimide group. In addition, the hydrolysis is accelerated, the coating film is not sufficiently repaired, and not only the adhesiveness under high temperature and high humidity is not obtained, but also the adhesiveness with the substrate film is lowered. Further, the number average molecular weight is more preferably 20000 or more, and it is preferably higher as long as it can be produced. However, the number average molecular weight is preferably 60000 or less because the solubility in the coating solution may be reduced as the number average molecular weight increases.

  The polyester resin has acid components such as terephthalic acid, isophthalic acid, phthalic acid, phthalic anhydride, 2,6-naphthalenedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, adipic acid, sebacic acid, trimellitic acid, pyromellitic acid, Examples include dimer acid, 5-sodium sulfoisophthalic acid, 4-sodium sulfonaphthalene-2,7-dicarboxylic acid, and the like. Examples of the diol component include ethylene glycol, propane glycol, 1,4-butanediol, neopentyl glycol, diethylene glycol, 1,6-hexanediol, 1,4-cyclohexanedimethanol, xylene glycol, ethylene oxide adduct of bisphenol A, etc. Is mentioned. When a hard coat layer mainly made of an acrylic resin is provided on the film of the present invention, interference fringes are generated due to the difference in refractive index between the coating layer and the other layer, which may cause a problem in terms of visibility. For this reason, it is preferable to contain naphthalenedicarboxylic acid capable of obtaining a higher refractive index as an acid component because it improves the heat and moisture resistance and the effect of suppressing iris-like colors.

Moreover, from the point of suppression of the iris-like color at the time of providing a hard-coat layer, it may contain the dicarboxylic acid component of following formula (1) and / or the diol component of following formula (2) as a component of a polyester resin. preferable. The dicarboxylic acid component of the following formula (1) and / or the diol component of the following formula (2) in the polyester resin is preferably 10% or more, more preferably 15% or more, and further preferably 20% or more. Further, the dicarboxylic acid component of the following formula (1) and / or the diol component of the following formula (2) in the polyester resin is preferably 70% or less, more preferably 60% or less, and further preferably 50% or less. When exceeding the said upper limit, a coating film may become soft too much and heat-and-moisture resistance may fall. When it is less than the above lower limit, the flexibility of the polyester resin is lowered, the coating film becomes too hard, and the adhesion may be lowered.
(1) HOOC- (CH ₂ ) _n —COOH (where n is an integer of 4 ≦ n ≦ 10)
(2) HO— (CH ₂ ) _n —OH (where n is an integer of 4 ≦ n ≦ 10)

  The polyester resin is based on water or a water-soluble organic solvent (for example, an aqueous solution containing less than 50% by weight of alcohol, alkyl cellosolve, ketone, or ether) or an organic solvent (for example, toluene, ethyl acetate, etc.). Those dissolved or dispersed can be used.

  When the polyester resin is used as an aqueous coating liquid, a water-soluble or water-dispersible polyester resin is used. For such water-solubilization or water-dispersion, a compound containing a sulfonate group or a carboxyl group is used. It is preferable to copolymerize a compound containing an acid base. Therefore, in addition to the dicarboxylic acid component described above, in order to impart water dispersibility to the polyester, it is preferable to use 5-sulfoisophthalic acid or an alkali metal salt thereof in the range of 1 to 10 mol%. Mention may be made of acid, 5-sulfoisophthalic acid, 4-sulfonaphthaleneisophthalic acid-2,7-dicarboxylic acid and 5- (4-sulfophenoxy) isophthalic acid or alkali metal salts thereof.

  In order to set the number average molecular weight of the polyester resin to 15000 or more and to have a glass transition temperature enough to suppress blocking, it is preferable to introduce a branched structure into the polyester resin. However, as the number of branched structures increases, the acid value tends to increase. Therefore, in the polyester resin of the present invention, the molar ratio of the third component having three or more carboxyl groups / one molecule or three or more hydroxyl groups / one molecule is 5.0 mol% or less in the total dicarboxylic acid component. Preferably, it is 1.0 mol% or less more preferably.

  The polyester resin is preferably contained in the coating layer in an amount of 10% by mass to 85% by mass. When high adhesiveness is required, it is more preferably 20% by mass or more and 80% by mass or less. When the content of the polyester resin is large, the adhesiveness under high temperature and high humidity decreases, and conversely, when the content is small, the adhesiveness with the base film decreases.

  In this invention, in order to improve adhesiveness, you may contain other than a polyester resin. Examples of such a resin include an acrylic resin and a urethane resin. Preferably, the carboxylic acid group content is low. More preferably, it does not contain a carboxylic acid group. When there are many carboxylic acid groups, it will react with a carbodiimide group, and the carbodiimide group which reacts with the carboxylic acid group generate | occur | produced from a polyester resin under high temperature and high humidity will reduce.

  In the present invention, it is necessary to contain a carbodiimide compound. Examples of the carbodiimide compound include a monocarbodiimide compound and a polycarbodiimide compound.

  Examples of the monocarbodiimide compound include dicyclohexylcarbodiimide, diisopropylcarbodiimide, dimethylcarbodiimide, diisobutylcarbodiimide, dioctylcarbodiimide, t-butylisopropylcarbodiimide, diphenylcarbodiimide, di-t-butylcarbodiimide, and di-β-naphthylcarbodiimide. .

  As the polycarbodiimide compound, those produced by a conventionally known method can be used. For example, it can be produced by synthesizing an isocyanate-terminated polycarbodiimide by a condensation reaction involving decarbonization of diisocyanate.

Examples of the diisocyanate that is a raw material for synthesizing the polycarbodiimide compound include isomers of toluylene diisocyanate, aromatic diisocyanates such as 4,4-diphenylmethane diisocyanate, aromatic aliphatic diisocyanates such as xylylene diisocyanate, isophorone diisocyanate and 4 , 4-dicyclohexylmethane diisocyanate, alicyclic diisocyanates such as 1,3-bis (isocyanatomethyl) cyclohexane, hexamethylene diisocyanate, and aliphatic diisocyanates such as 2,2,4-trimethylhexamethylene diisocyanate. From the problem of yellowing, aromatic aliphatic diisocyanates, alicyclic diisocyanates, and aliphatic diisocyanates are preferred.

The diisocyanate may be used with a molecule controlled to an appropriate degree of polymerization using a compound that reacts with a terminal isocyanate such as monoisocyanate. Examples of monoisocyanates for sealing the ends of polycarbodiimide and controlling the degree of polymerization thereof include phenyl isocyanate, toluylene isocyanate, dimethylphenyl isocyanate, cyclohexyl isocyanate, butyl isocyanate, and naphthyl isocyanate. In addition, a compound having an OH group, NH ₂ group, COOH group, or SO ₃ H group can be used as a terminal blocking agent.

  The condensation reaction involving decarbonization of diisocyanate proceeds in the presence of a carbodiimidization catalyst. Examples of the catalyst include 1-phenyl-2-phospholene-1-oxide, 3-methyl-2-phospholene-1-oxide, 1-ethyl-2-phospholene-1-oxide, and 3-methyl-1-phenyl-2. -Phosphorene-1-oxide, phospholene oxides such as these 3-phospholene isomers and the like can be mentioned, and 3-methyl-1-phenyl-2-phospholene-1-oxide is preferable from the viewpoint of reactivity. The amount of the catalyst used can be a catalyst amount.

  The mono- or polycarbodiimide compound described above is desirably kept in a uniform dispersed state when blended with an aqueous coating material. For this purpose, it is emulsified with an appropriate emulsifier and used as an emulsion, or a polycarbodiimide compound. It is preferable to add a hydrophilic segment in the molecular structure of the compound and mix it with the paint in the form of a self-emulsified product or in the form of a self-dissolved product.

  As a polymerization degree (n) of a polycarbodiimide compound, 2-10 are preferable, More preferably, it is 3-7. When the degree of polymerization is small, the crosslinking reaction rate is deteriorated and the adhesion with the functional layer is lowered. When the degree of polymerization is large, the compatibility with the resin is deteriorated and haze may be increased.

  Examples of the carbodiimide compound used in the present invention include water dispersibility and water solubility. Water solubility is preferred because it is highly compatible with other water-soluble resins and improves the transparency of the coating layer and the crosslinking reaction efficiency.

  In order to make a carbodiimide compound water-soluble, an isocyanate-terminated polycarbodiimide is synthesized by a condensation reaction involving decarbonization of isocyanate, and then a hydrophilic part having a functional group having reactivity with an isocyanate group is added. Can be manufactured.

Examples of hydrophilic sites include (1) quaternary ammonium salts of dialkylamino alcohols and quaternary ammonium salts of dialkylaminoalkylamines, (2) alkyl sulfonates having at least one reactive hydroxyl group, and the like (3) Examples thereof include poly (ethylene oxide) end-capped with an alkoxy group, poly (propylene oxide), a mixture of poly (ethylene oxide) and poly (propylene oxide), and the like. 3-50 are preferable and, as for the repeating unit of ethylene oxide and / or propylene oxide, More preferably, it is 5-35. When the repeating unit is small, the compatibility with the resin is deteriorated and the haze is increased. When the repeating unit is large, the adhesiveness under high temperature and high humidity may be decreased. The carbodiimide compound is (1) cationic, (2) anionic, and (3) nonionic when the above hydrophilic moiety is introduced. Especially, the nonionic property which can be compatible regardless of the ionicity of other water-soluble resin is preferable. Moreover, in order to improve heat-and-moisture resistance, the nonionic property which does not need to introduce | transduce an ionic hydrophilic group is preferable.

  The resin having a carbodiimide group is preferably contained in the coating layer in an amount of 5% by mass to 90% by mass. In particular, when high adhesion is required, such as a hard coat layer and a lens layer, the content is more preferably 10% by mass or more and 70% by mass or less. When the content of the resin having a carbodiimide group is large, the adhesion with the functional layer is lowered. Since the carbodiimide group to be reduced is reduced, the restoration function of the coating film is lowered and the adhesiveness is lowered.

  In the present invention, in order to improve the coating film strength, the coating layer may contain a crosslinking agent different from the resin having a carbodiimide group or a resin having a crosslinking group. Examples of the crosslinking agent include urea, epoxy, melamine, isocyanate, oxazoline, silanol and the like. Moreover, in order to promote a crosslinking reaction, a catalyst etc. are used suitably as needed.

  In the present invention, particles may be contained in the coating layer. Particles are (1) silica, kaolinite, talc, light calcium carbonate, heavy calcium carbonate, zeolite, alumina, barium sulfate, carbon black, zinc oxide, zinc sulfate, zinc carbonate, titanium dioxide, zirconium dioxide, tin oxide, satin Inorganic particles such as white, aluminum silicate, diatomaceous earth, calcium silicate, aluminum hydroxide, hydrous halloysite, magnesium carbonate, magnesium hydroxide, (2) acrylic or methacrylic, vinyl chloride, vinyl acetate, nylon, styrene / Acrylic, styrene / butadiene, polystyrene / acrylic, polystyrene / isoprene, polystyrene / isoprene, methyl methacrylate / butyl methacrylate, melamine, polycarbonate, urea, epoxy, Urethane-based, phenol-based, diallyl phthalate, and organic particles of a polyester or the like.

  The average particle diameter of the particles is not particularly limited, but from the viewpoint of maintaining the transparency of the film, the average particle diameter of the particles is preferably 1 to 500 nm, and more preferably 1 to 100 nm. The average particle diameter is an average particle diameter measured by using a Coulter Counter (manufactured by Beckman Coulter, Multisizer II type) dispersed in a solvent that does not swell.

  Two or more kinds of particles having different average particle diameters may be used as the particles.

  As content of particle | grains, 0.5 mass% or more and 20 mass% or less are preferable. When the amount is small, sufficient blocking resistance cannot be obtained. Further, scratch resistance is deteriorated. When the amount is large, not only the transparency of the coating layer is deteriorated, but also the coating strength is lowered.

  The coating layer may contain a surfactant for the purpose of improving leveling properties during coating and defoaming the coating solution. The surfactant may be any of cationic, anionic and nonionic surfactants, but is preferably a silicon-based, acetylene glycol-based or fluorine-based surfactant. These surfactants are preferably contained in the coating layer within a range that does not impair the adhesion to the functional layer.

  The easy-adhesive thermoplastic resin film of the present invention preferably has a haze value of 2.0% or less, more preferably 1.5% or less. Such an easily adhesive thermoplastic resin film can be improved in compatibility with other resins by making the resin having a carbodiimide group contained in the coating layer described above water-soluble.

  In order to impart other functionality to the coating layer, various additives may be contained within a range that does not impair the adhesion to the functional layer. Examples of the additive include fluorescent dyes, fluorescent brighteners, plasticizers, ultraviolet absorbers, pigment dispersants, foam suppressors, antifoaming agents, preservatives, and antistatic agents.

  In the present invention, examples of the method of providing the coating layer on the thermoplastic resin film include a method of coating and drying a coating liquid containing a solvent, particles and resin on the polyester film. Examples of the solvent include organic solvents such as toluene, water, and a mixed system of water and a water-soluble organic solvent. Preferably, water alone or a mixture of a water-soluble organic solvent and water is used from the viewpoint of environmental problems. preferable.

  The laminated thermoplastic resin film of the present invention comprises a hard coat layer, a light diffusion layer, a prismatic lens layer, an electromagnetic wave absorption layer, a near-infrared shielding layer, and a transparent conductive layer on at least one surface of the above-mentioned thermoplastic resin film coating layer. It is obtained by at least one selected nobility layer.

  The material used for the functional layer is not particularly limited.

(Manufacture of easy-adhesive thermoplastic resin film)
Although the production method of the easily adhesive thermoplastic resin film of the present invention will be described by taking a polyethylene terephthalate (hereinafter abbreviated as PET) film as an example, it is naturally not limited thereto.

  After sufficiently drying the PET resin in a vacuum, it is supplied to an extruder, melted and extruded at about 280 ° C. from a T-die into a rotating cooling roll into a sheet, cooled and solidified by an electrostatic application method, and unstretched PET. Get a sheet. The unstretched PET sheet may have a single layer structure or a multilayer structure by a coextrusion method. Moreover, it is preferable not to contain an inert particle substantially in PET resin.

  The obtained unstretched PET sheet is stretched 2.5 to 5.0 times in the longitudinal direction with a roll heated to 80 to 120 ° C. to obtain a uniaxially stretched PET film. Furthermore, the edge part of a film is hold | gripped with a clip, it guide | induces to the hot air zone heated at 70-140 degreeC, and is extended | stretched 2.5 to 5.0 times in the width direction. Then, it guide | induces to the heat processing zone of 160-240 degreeC, and heat-processes for 1 to 60 seconds, and completes crystal orientation.

  In an arbitrary stage of the film manufacturing process, a coating solution is applied to at least one surface of the PET film to form the coating layer. There is no particular problem even if the coating layer is formed on both sides of the PET film. The solid content concentration of the resin composition in the coating solution is preferably 2 to 35% by weight, particularly preferably 4 to 15% by weight.

  Any known method can be used as a method for applying the coating solution to the PET film. For example, reverse roll coating method, gravure coating method, kiss coating method, die coater method, roll brush method, spray coating method, air knife coating method, wire bar coating method, pipe doctor method, impregnation coating method, curtain coating method, etc. It is done. These methods are applied alone or in combination.

  In the present invention, the coating layer is formed by coating the coating solution on an unstretched or uniaxially stretched PET film, drying it, stretching in at least a uniaxial direction, and then performing a heat treatment.

In the present invention, the finally obtained coating layer preferably has a thickness of 20 to 350 nm, and the coating amount after drying is preferably 0.02 to 0.5 g / m ² . When the coating amount of the coating layer is less than 0.02 g / m ² , the effect on adhesiveness is almost lost. On the other hand, when the coating amount exceeds 0.5 g / m ² , haze increases.

  The coating layer of the easy-adhesive thermoplastic resin film obtained in the present invention has good adhesion to a hard coat layer, a light diffusion layer, a prismatic lens layer, an electromagnetic wave absorption layer, a near-infrared shielding layer, and a transparent conductive layer. Have By laminating these functional layers mainly for optical use, it is possible to provide a laminated thermoplastic resin film that can maintain an initial function for a long time even under high temperature and high humidity. Also, good adhesive strength can be obtained even for applications other than optical applications. Specifically, adhesion such as photographic photosensitive layer, diazo photosensitive layer, matte layer, magnetic layer, inkjet ink receiving layer, hard coat layer, UV curable resin, thermosetting resin, printing ink and UV ink, dry laminate, extrusion laminate, etc. Examples thereof include vacuum deposition, electron beam deposition, sputtering, ion plating, CVD, plasma polymerization and the like of an agent, a metal or an inorganic substance, or an oxide thereof, and an organic barrier layer.

  EXAMPLES Next, although this invention is demonstrated in detail using an Example and a comparative example, naturally this invention is not limited to a following example. The evaluation method used in the present invention is as follows.

(1) Intrinsic viscosity Based on JIS K7367-5, it measured at 30 degreeC, using the mixed solvent of phenol (60 mass%) and 1,1,2,2-tetrachloroethane (40 mass%) as a solvent.

(2) Glass transition temperature In accordance with JIS K7121, using a differential scanning calorimeter (Seiko Instruments, DSC6200), 10 mg of a resin sample was heated at a rate of 20 ° C / min over a temperature range of 25 to 300 ° C, and DSC The extrapolated glass transition start temperature obtained from the curve was defined as the glass transition temperature.

(3) Number average molecular weight 0.03 g of resin was dissolved in 10 ml of tetrahydrofuran, and a GPC-LALLS apparatus low-angle light scattering photometer LS-8000 (manufactured by Tosoh Corporation, tetrahydrofuran solvent, reference: polystyrene) was used at a column temperature of 30 ° C. The number average molecular weight was measured using a flow rate of 1 ml / min and a column (showex KF-802, 804, 806 manufactured by Showa Denko KK).

(4) Resin composition The resin is dissolved in deuterated chloroform, and ¹ H-NMR analysis is performed using a nuclear magnetic resonance analyzer (NMR) Gemini-200 manufactured by Varian, and the mol% ratio of each composition is determined from the integral ratio. Were determined.

(5) Acid value 1 g (solid content) of a sample was dissolved in 30 ml of chloroform or dimethylformamide, and titrated with 0.1 N potassium hydroxide ethanol solution using phenolphthalein as an indicator to determine the carboxyl groups per gram of the sample. The amount (mg) of KOH required for neutralization was determined.

(6) Total light transmittance of easy-adhesive polyester film The total light transmittance of the obtained easily-adhesive polyester film was measured using a turbidimeter (Nippon Denshoku, NDH2000) according to JIS K 7105. .

(7) Haze of easy-adhesive polyester film The haze of the obtained easy-adhesive polyester film was measured using a turbidimeter (Nippon Denshoku, NDH2000) based on JIS K7136.

(8) Adhesion 100 square cuts reaching the base film through the photocurable acrylic layer on the hard coat layer surface of the obtained laminated polyester film using a cutter guide with a gap interval of 2 mm. Put on. Next, a cellophane adhesive tape (manufactured by Nichiban Co., Ltd., No. 405; 24 mm width) was attached to the cut surface of the grid and rubbed with an eraser for complete adhesion. Then, after performing the work of peeling the cellophane adhesive tape vertically from the hard coat layer surface of the laminated polyester film once, the number of squares peeled off from the hard coat layer surface of the laminated polyester film was visually counted, and the hard The adhesion between the coating layer and the substrate film was determined. In addition, what peeled partially among squares was also counted as the square which peeled, and was ranked according to the following references | standards.
Adhesiveness (%) = (1−number of peeled squares / 100) × 100
A: 100%, or material breakage of hard coat layer B: 99-90%
Δ: 89-70%
X: 69 to 0%

(9) Moisture and heat resistance The obtained laminated polyester film was allowed to stand in an environment of 80 ° C. and 95% RH for 48 hours in a high-temperature and high-humidity tank. Next, the laminated polyester film was taken out and allowed to stand at room temperature and humidity for 12 hours. Thereafter, contact adhesion between the hard coat layer and the substrate film was determined in the same manner as in (8) above except that the cellophane pressure-sensitive adhesive tape was peeled off from the hard coat layer surface of the laminated polyester film five times. The ranking was based on the criteria.
A: 100%, or material breakage of hard coat layer B: 99-90%
Δ: 89-70%
X: 69 to 0%

(10) Interference spot improvement (iris color)
The obtained laminated polyester film was cut into an area of 10 cm (film width direction) × 15 cm (film longitudinal direction) to prepare a sample film. A black glossy tape (manufactured by Nitto Denko, vinyl tape No. 21; black) was attached to the surface of the obtained sample film opposite to the hard coat layer. This sample film has a hard coat surface as the top surface and a three-wavelength daylight white color (National Palook, FL 15EX-N 15W) as a light source. 60 cm, and an angle of 15 to 45 ° with respect to the perpendicular to the film surface).

The results of visual observation are ranked according to the following criteria. The observation is performed by five people who are familiar with the evaluation, and the highest rank is the evaluation rank. If two ranks have the same number, the center of the rank divided into three is adopted.
○: Almost no iris color is seen △: Slightly iris color is observed ×: Clear iris color is observed

(Polyester resin polymerization)
In a stainless steel autoclave equipped with a stirrer, a thermometer, and a partial reflux condenser, 194.2 parts by weight of dimethyl terephthalate, 184.5 parts by weight of dimethyl isophthalate, 14.8 parts by weight of dimethyl-5-sodium sulfoisophthalate, 233.5 parts by mass of diethylene glycol, 136.6 parts by mass of ethylene glycol, and 0.2 parts by mass of tetra-n-butyl titanate were charged, and a transesterification reaction was performed from 160 ° C. to 220 ° C. over 4 hours. Next, the temperature was raised to 255 ° C., and the pressure of the reaction system was gradually reduced, followed by reaction for 1 hour 30 minutes under a reduced pressure of 30 Pa to obtain a copolymerized polyester resin (A-1). The obtained copolyester resin (A-1) was light yellow and transparent. It was 0.70 dl / g when the reduced viscosity of the obtained copolyester resin (A-1) was measured. The glass transition temperature by DSC was 40 ° C.

In the same manner, copolymer polyester resins (A-2) to (A-5) having different compositions were obtained. Table 1 shows the composition (mole% ratio) and other characteristics measured by ¹ H-NMR for these copolymer polyester resins.

(Adjustment of polyester aqueous dispersion)
30 parts by mass of polyester resin (A-1) and 15 parts by mass of ethylene glycol n-butyl ether were placed in a reactor equipped with a stirrer, a thermometer and a reflux device, and heated and stirred at 110 ° C. to dissolve the resin. After the resin was completely dissolved, 55 parts by mass of water was gradually added to the polyester solution while stirring. After the addition, the solution was cooled to room temperature while stirring to prepare a milky white polyester aqueous dispersion (B-1) having a solid content of 30% by mass. Similarly, using the polyester resins (A-2) to (A-7) instead of the polyester resin (A-1), water dispersions were prepared, and the water dispersions (B-2) to (B- 7).

(Polymerization of water-soluble carbodiimide compounds)
In a flask equipped with a thermometer, nitrogen gas introduction tube, reflux condenser, dropping funnel, and stirrer, 200 parts by mass of isophorone diisocyanate and 4 parts by mass of 3-methyl-1-phenyl-2-phospholene-1-oxide as a carbodiimidization catalyst And stirred at 180 ° C. for 10 hours under a nitrogen atmosphere to obtain an isocyanate-terminated isophorone carbodiimide (degree of polymerization = 5). Next, 111.2 g of the obtained carbodiimide and 80 g of polyethylene glycol monomethyl ether (molecular weight 400) were reacted at 100 ° C. for 24 hours. Water was gradually added thereto at 50 ° C. to obtain a yellow transparent water-soluble carbodiimide compound (C-1) having a solid content of 40% by mass.

(Polymerization of water-soluble carbodiimide compounds)
In a flask equipped with a thermometer, nitrogen gas inlet tube, reflux condenser, dropping funnel, and stirrer, 200 parts by mass of 4,4-dicyclohexylmethane diisocyanate, carbodiimidization catalyst 3-methyl-1-phenyl-2-phospholene-1 4 parts by mass of oxide were added and stirred at 180 ° C. for 8 hours under a nitrogen atmosphere to obtain isocyanate-terminated 4,4-dicyclohexylmethane (degree of polymerization = 2). Subsequently, 69.9 g of the obtained carbodiimide and 80 g of polyethylene glycol monomethyl ether (molecular weight 400) were reacted at 100 ° C. for 24 hours. Water was gradually added thereto at 50 ° C. to obtain a yellow transparent water-soluble carbodiimide compound (C-2) having a solid content of 40% by mass.

(Polymerization of water-soluble carbodiimide compounds)
In a flask equipped with a thermometer, nitrogen gas inlet tube, reflux condenser, dropping funnel, and stirrer, 200 parts by mass of 4,4-dicyclohexylmethane diisocyanate, carbodiimidization catalyst 3-methyl-1-phenyl-2-phospholene-1 4 parts by mass of oxide were added and stirred at 180 ° C. for 30 hours in a nitrogen atmosphere to obtain isocyanate-terminated 4,4-dicyclohexylmethane (degree of polymerization = 10). Next, 244.6 g of the obtained carbodiimide and 150 g of polyethylene glycol monomethyl ether (molecular weight 750) were reacted at 100 ° C. for 24 hours. Water was gradually added thereto at 50 ° C. to obtain a yellow transparent water-soluble carbodiimide compound (C-3) having a solid content of 40% by mass.

(Polymerization of water-dispersible carbodiimide compound)
In a flask equipped with a thermometer, a nitrogen gas introduction tube, a reflux condenser, a dropping funnel, and a stirrer, 200 parts by mass of isophorone diisocyanate, 25 parts by mass of cyclohexyl isocyanate, 3-methyl-1-phenyl-2-phospholene as a carbodiimidization catalyst 2.5 parts by mass of 1-oxide was added and stirred for 30 hours at 180 ° C. in a nitrogen atmosphere to obtain isophorone carbodiimide (degree of polymerization = 10). Next, nonylphenol nonionic surfactant (Sanyo Kasei nonipol) diluted with water to a solid content concentration of 0.5% by mass was gradually added to 100 g of the obtained carbodiimide resin to obtain a water-dispersible carbodiimide having a solid content of 40% by mass. Compound (D) was obtained.

Example 1
(1) Adjustment of coating liquid The following coating agent was mixed and the coating liquid was created. The polyester resin has a number average molecular weight of 20000.
51.00% by mass of water
Isopropanol 30.00% by mass
Polyester water dispersion (B-1) 12.58 mass%
Water-soluble carbodiimide compound (C-1) 4.72% by mass
Particles 1.57% by mass
(Silica sol with an average particle size of 40 nm, solid content concentration of 40% by mass)
0.08% by mass of particles
(Silica sol with an average particle size of 450 nm, solid content concentration of 40% by mass)
Surfactant 0.05% by mass
(Silicon, solid content concentration of 100% by mass)

(2) Production of easy-adhesive polyester film PET film pellets having an intrinsic viscosity of 0.62 dl / g and substantially free of particles as a film raw material polymer are dried at 135 ° C. for 6 hours under a reduced pressure of 133 Pa. did. Thereafter, the sheet was supplied to an extruder, melted and extruded into a sheet at about 280 ° C., and rapidly cooled and solidified on a rotating cooling metal roll maintained at a surface temperature of 20 ° C. to obtain an unstretched PET sheet.

  This unstretched PET sheet was heated to 100 ° C. with a heated roll group and an infrared heater, and then stretched 3.5 times in the longitudinal direction with a roll group having a difference in peripheral speed to obtain a uniaxially stretched PET film.

Subsequently, after apply | coating the said coating liquid on the single side | surface of PET film by the roll coat method, it dried at 80 degreeC for 20 second. The final coating amount (after biaxial stretching) was adjusted so that the coating amount after drying was 0.15 g / m ² . Subsequently, the film was stretched 4.0 times in the width direction at 120 ° C. with a tenter, and heated at 230 ° C. for 0.5 seconds with the length in the width direction fixed, and further at 230 ° C. for 10 seconds. % Relaxation treatment in the width direction was performed to obtain an easily adhesive polyester film having a thickness of 100 μm. The evaluation results are shown in Table 2.

(3) Manufacture of laminated polyester film A coating liquid for forming a hard coat layer having the following composition was applied to the coating layer surface of the above-mentioned easily adhesive polyester film using a # 10 wire bar, dried at 70 ° C. for 1 minute, Was removed. Next, the film coated with the hard coat layer was irradiated with 300 mJ / cm ² ultraviolet rays using a high-pressure mercury lamp to obtain a laminated polyester film having a hard coat layer with a thickness of 5 μm.
Hard coat layer forming coating liquid methyl ethyl ketone 39.00% by mass
Toluene 26.00% by mass
Dipentaerythritol hexaacrylate 22.83 mass%
(Shin-Nakamura Chemical A-DPH)
Polyethylene diacrylate 11.17% by mass
(Shin-Nakamura Chemical A-400)
Photopolymerization initiator 1.00% by mass
(Irgacure 184 manufactured by Ciba Specialty Chemicals)

Comparative Example 1
An easy-adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 1 except that the polyester water dispersion was changed to a polyester water dispersion (B-6) having a molecular weight of 8000.

Comparative Example 2
An easy-adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 1 except that the polyester aqueous dispersion was changed to a polyester aqueous dispersion (B-7) having an acid value of 50 KOHmg / g.

Comparative Example 3
An easily adhesive polyester film and a laminated polyester film were prepared in the same manner as in Example 1 except that the water-soluble carbodiimide compound (C-1) was changed to an epoxy compound (Denacol EX-521, solid content concentration 100%, manufactured by Nagase ChemteX Corporation). Obtained.

Comparative Example 4
An easily-adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 1 except that the water-soluble carbodiimide compound (C-1) was changed to a melamine compound (Bicamine M-3 solid content concentration 60%, manufactured by DIC). .

Example 2
An easily adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 1 except that the polyester water dispersion was changed to a polyester water dispersion (B-2) having a molecular weight of 15000.

Example 3
An easily adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 1 except that the polyester water dispersion was changed to a polyester water dispersion (B-3) having a molecular weight of 23000.

Example 4
An easily adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 1 except that the polyester water dispersion was changed to a polyester water dispersion (B-4) having a molecular weight of 46000.

Example 5
An easy-adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 1 except that the polyester water dispersion was changed to a polyester water dispersion (B-5) having a molecular weight of 50000.

Example 6
An easy-adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 1 except that the coating solution was changed to the following.
Water 52.35% by mass
Isopropanol 30.00% by mass
Polyester water dispersion (B-1) 1.80 mass%
Water-soluble carbodiimide compound (C-1) 14.15 mass%
Particles 1.57% by mass
(Silica sol with an average particle size of 40 nm, solid content concentration of 40% by mass)
0.08% by mass of particles
(Silica sol with an average particle size of 450 nm, solid content concentration of 40% by mass)
Surfactant 0.05% by mass
(Silicon, solid content concentration of 100% by mass)

Example 7
An easy-adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 1 except that the coating solution was changed to the following.
Water 52.24% by mass
Isopropanol 30.00% by mass
Polyester water dispersion (B-1) 2.70 mass%
Water-soluble carbodiimide compound (C-1) 13.36 mass%
Particles 1.57% by mass
(Silica sol with an average particle size of 40 nm, solid content concentration of 40% by mass)
0.08% by mass of particles
(Silica sol with an average particle size of 450 nm, solid content concentration of 40% by mass)
Surfactant 0.05% by mass
(Silicon, solid content concentration of 100% by mass)

Example 8
An easy-adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 1 except that the coating solution was changed to the following.
50.55% by weight of water
Isopropanol 30.00% by mass
Polyester water dispersion (B-1) 16.17 mass%
Water-soluble carbodiimide compound (C-1) 1.57% by mass
Particles 1.57% by mass
(Silica sol with an average particle size of 40 nm, solid content concentration of 40% by mass)
0.08% by mass of particles
(Silica sol with an average particle size of 450 nm, solid content concentration of 40% by mass)
Surfactant 0.05% by mass
(Silicon, solid content concentration of 100% by mass)

Example 9
An easy-adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 1 except that the coating solution was changed to the following.
Water 50.44% by mass
Isopropanol 30.00% by mass
Polyester water dispersion (B-1) 17.07 mass%
Water-soluble carbodiimide compound (C-1) 0.79 mass%
Particles 1.57% by mass
(Silica sol with an average particle size of 40 nm, solid content concentration of 40% by mass)
0.08% by mass of particles
(Silica sol with an average particle size of 450 nm, solid content concentration of 40% by mass)
Surfactant 0.05% by mass
(Silicon, solid content concentration of 100% by mass)

Example 10
An easy-adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 1 except that the water-soluble carbodiimide compound (C-1) was changed to the water-dispersible carbodiimide compound (D).

Example 11
An easily-adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 4 except that the water-soluble carbodiimide compound (C-1) was changed to the water-soluble carbodiimide compound (C-2).

Example 12
An easily adhesive polyester film and a laminated polyester film were obtained in the same manner as in Example 4 except that the water-soluble carbodiimide compound (C-1) was changed to the water-soluble carbodiimide compound (C-3).

  The easy-adhesive polyester film of the present invention is excellent in adhesion with a functional layer and adhesion under high temperature and high humidity (moisture and heat resistance). Therefore, it is mainly used for displays and the like, and a hard coat film and antireflection using the film. It is suitable as a base film for functional films such as films, light diffusion sheets, prismatic lens sheets, near-infrared shielding films, transparent conductive films, and antiglare films.

Claims (9)

An easily adhesive thermoplastic resin film having a coating layer on at least one surface of the thermoplastic resin film,
The thermoplastic resin film is a polyester film;
The coating layer is composed mainly of a polyester resin having a number average molecular weight of 15000 or more and substantially having no carboxylic acid group, and a carbodiimide compound,
The resin in the coating layer is only the polyester resin,
Easy-adhesive thermoplastic film. The easily adhesive thermoplastic resin film according to claim 1, wherein the polyester resin contains a dicarboxylic acid component represented by the following formula (1) and / or a diol component represented by the following formula (2). .
(1) HOOC- (CH ₂ ) _n —COOH (where n is an integer of 4 ≦ n ≦ 10)
(2) HO— (CH ₂ ) _n —OH (where n is an integer of 4 ≦ n ≦ 10)   The easy-adhesive thermoplastic resin film according to claim 1, wherein naphthalenedicarboxylic acid is included as an acid component of the polyester resin.   The easily adhesive thermoplastic resin film according to claim 1, wherein the carbodiimide compound is water-soluble and has a haze of 2.0% or less.   The easily adhesive thermoplastic resin film according to any one of claims 1 to 4, wherein the carbodiimide compound is polycarbodiimide, and the degree of polymerization thereof is 2 to 10.   Content in the coating layer of the said carbodiimide compound is 5-90 mass%, The easily adhesive thermoplastic resin film in any one of Claims 1-5.   The easily adhesive thermoplastic resin film according to claim 1, wherein the polyester film is a polyethylene terephthalate film.   The coating layer is further selected from the group consisting of particles, fluorescent dyes, optical brighteners, plasticizers, UV absorbers, pigment dispersants, foam suppressors, antifoaming agents, preservatives, and antistatic agents. The easily adhesive thermoplastic resin film in any one of Claims 1-7 containing 1 or more types of additives.   From the hard coat layer, the light diffusion layer, the prismatic lens layer, the electromagnetic wave absorbing layer, the near infrared ray blocking layer, and the transparent conductive layer to the coating layer of the easily adhesive thermoplastic resin film according to any one of claims 1 to 8. A laminated thermoplastic resin film obtained by laminating at least one selected functional layer.