JP2011190232A - 水中油型乳化化粧料 - Google Patents
水中油型乳化化粧料 Download PDFInfo
- Publication number
- JP2011190232A JP2011190232A JP2010060177A JP2010060177A JP2011190232A JP 2011190232 A JP2011190232 A JP 2011190232A JP 2010060177 A JP2010060177 A JP 2010060177A JP 2010060177 A JP2010060177 A JP 2010060177A JP 2011190232 A JP2011190232 A JP 2011190232A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- component
- emulsified cosmetic
- metal oxide
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 31
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 31
- -1 polyoxyethylene Polymers 0.000 claims abstract description 25
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 19
- 239000003921 oil Substances 0.000 claims abstract description 18
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- 229940082509 xanthan gum Drugs 0.000 claims abstract description 16
- 235000010418 carrageenan Nutrition 0.000 claims abstract description 15
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims abstract description 15
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- 239000008346 aqueous phase Substances 0.000 claims description 4
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- 239000000306 component Substances 0.000 abstract 1
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- 230000000052 comparative effect Effects 0.000 description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 10
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- 239000011787 zinc oxide Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
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- 238000009472 formulation Methods 0.000 description 3
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 3
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- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
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- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
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Abstract
【解決手段】内油相中に成分(A)トリエトキシカプリリルシラン被覆金属酸化物を含有し、外水相中に成分(B)キサンタンガムおよびカラギーナン、(C)ポリオキシエチレンの平均付加モル数が80〜100であるポリオキシエチレン硬化ヒマシ油を含有し、且つ全水中油型乳化化粧料中の成分(A)〜(C)の配合量が、成分(A)1〜5重量%、成分(B)0.05〜0.3重量%、成分(C)0.1〜1.0重量%であることにより、高温や経時による変化が少なく、塗布時に肌の上でなめらかにのび、みずみずしく、さっぱりとした使用感である、金属酸化物を含有した水中油型乳化化粧料を提供することができる。
【選択図】なし
Description
この水中油型乳化化粧料を使用しやすい粘度に調節する目的で、あるいは系の安定性を保つ目的で増粘剤が使用されている。この増粘剤は製品使用時の感触に与える影響が大きく、みずみずしく、さっぱりとした使用感を得るためにカルボキシビニルポリマーやアルキル変性カルボキシビニルポリマー等のイオン性水溶性高分子化合物が好まれて使用されている。
更に、添加する粉末粒子を疎水性粉末粒子とした上で、特定のポリエーテル変性シリコーンを用いて、水中油型のエマルションを形成させることにより、疎水性粉末粒子を、その溶出成分を含めて、油相中に長時間止める技術(特許文献3)が開示されているが、高温や経時による変化の安定性は不十分である。
例えば、ι−カラギーナンとキサンタンガム及び/又はローカストビーンガムを併用することで水相を固形化させる技術(特許文献4)等があるが、多糖類を増粘剤として用いた場合、薬剤成分や各種塩類を同時配合した系での安定性は優れるものの、べたつき感がするなど使用性の面においては欠点があった。
なお、本発明において平均一次粒子径とは、一般的に用いられる方法で測定される一次粒子の径を意味するものであるが、具体的には透過型電子顕微鏡写真から、粒子の長軸と短軸の相加平均として求められるものである。
(1)使用感(のびのなめらかさ、みずみずしさ、さっぱり感)
女性専門パネル15人により、使用感に関する評価項目について下記の評価基準に基づき評価を行った。
1.のびのなめらかさ
◎:非常にのびがなめらか。
○:のびがなめらか。
△:ややのびがなめらか。
×:のびが悪い。
2.みずみずしさ
◎:非常にみずみずしい。
○:みずみずしい。
△:ややみずみずしい。
×:みずみずしくない。
3.さっぱり感
◎:非常にさっぱりしている。
○:さっぱりしている
△:ややさっぱりしている。
×:さっぱり感がない。
化粧下地を50℃及び室温でそれぞれ1カ月間放置し、その安定性を外観観察で評価した。
○:外観異常なし。
×:油相が分離している。
A:成分9〜14を80℃に加熱し、成分1〜8を加えてホモミキサーにて均一に分散し、80℃に保温する。
B:成分15〜29をホモミキサーにて均一に混合し、80℃に加熱する。
C:BにAを添加し乳化する。
D:Cを68℃まで冷却し、成分30を添加する。
E:さらに30℃まで冷却し、乳液状の化粧下地を得る。
A:成分5〜10を80℃に加熱し、成分1〜4を加えてホモミキサーにて均一に分散し、80℃に保温する。
B:成分11〜19をホモミキサーにて均一に混合し、80℃に加熱する。
C:BにAを添加し乳化する。
D:Cを68℃まで冷却し、成分20を添加する。
E:さらに30℃まで冷却し、乳液状のファンデーションを得る。
Claims (4)
- 内油相中に成分(A)トリエトキシカプリリルシラン被覆金属酸化物を含有し、外水相中に成分(B)キサンタンガムおよびカラギーナン、(C)ポリオキシエチレン平均付加モル数が80〜100であるポリオキシエチレン硬化ヒマシ油を含有し、且つ全水中油型乳化化粧料中の成分(A)〜(C)の配合量が、成分(A)1〜5重量%、成分(B)0.05〜0.3重量%、成分(C)0.1〜1.0重量%であることを特徴とする水中油型乳化化粧料。
- 成分(C)であるポリオキシエチレン硬化ヒマシ油の、ポリオキシエチレン平均付加モル数が100であることを特徴とする請求項1に記載の水中油型乳化化粧料。
- キサンタンガムとカラギーナンの成分割合が重量比で3:2〜2:3である請求項1又は2に記載の水中油型乳化化粧料。
- メイクアップ化粧料であることを特徴とする請求項1〜3の何れかの項に記載の水中油型乳化化粧料。
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JP2013203716A (ja) * | 2012-03-29 | 2013-10-07 | Kose Corp | 紫外線防御化粧料 |
CN107613950A (zh) * | 2015-05-28 | 2018-01-19 | 堺化学工业株式会社 | 皮脂吸附剂以及含有该皮脂吸附剂的化妆料 |
US20190254947A1 (en) * | 2016-09-27 | 2019-08-22 | Amorepacific Corporation | Film-forming composition for skin or hair coating |
JP2021031475A (ja) * | 2019-08-29 | 2021-03-01 | ポーラ化成工業株式会社 | 水中油型乳化組成物 |
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