JP2011122069A - Double-sided adhesive tape for fixing polishing pad - Google Patents

Double-sided adhesive tape for fixing polishing pad Download PDF

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JP2011122069A
JP2011122069A JP2009281168A JP2009281168A JP2011122069A JP 2011122069 A JP2011122069 A JP 2011122069A JP 2009281168 A JP2009281168 A JP 2009281168A JP 2009281168 A JP2009281168 A JP 2009281168A JP 2011122069 A JP2011122069 A JP 2011122069A
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fixing
polishing pad
adhesive layer
pressure
resin
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JP5520026B2 (en
JP2011122069A5 (en
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Rie Matsui
梨絵 松井
Kenji Sakai
賢司 酒井
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Sekisui Chemical Co Ltd
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Sekisui Chemical Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a both-sided adhesive tape for fixing a polishing pad, that can be bonded even to a conventional polishing plate made of a hardly bondable material and can be released with no remaining adhesive. <P>SOLUTION: A double-sided adhesive tape 1 for fixing a polishing pad includes a resin film base 2, a polishing plate-fixing self-adhesive layer 3 stacked integrally on one surface of the base 2, and a polishing pad-fixing adhesive layer 4 stacked integrally on the other surface of the base 2. The self-adhesive constituting the polishing plate-fixing self-adhesive layer 3 includes a base resin containing a styrene-isoprene-styrene-based elastomer, and 50-200 pts.wt. of a petroleum-based tackifying resin and 10-60 pts.wt. of a coumarone-based tackifying resin, each based on 100 pts.wt. of the base resin. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、半導体ウエハ等を研磨する研磨装置の研磨定盤に研磨パッドを固定するために用いられる研磨パッド固定用両面テープに関する。   The present invention relates to a double-sided tape for fixing a polishing pad used for fixing a polishing pad to a polishing surface plate of a polishing apparatus for polishing a semiconductor wafer or the like.

半導体集積回路の高密度化を目的として配線の微細化が進んでいるのに伴い、半導体ウエハや液晶用ガラス基盤などの表面の凹凸をできるだけ平坦化する必要がある。そこで、ケミカルメカニカル研磨法(Chemical Mechanical Polishing:以下、CMP法という)が採用されている。   With the progress of miniaturization of wiring for the purpose of increasing the density of semiconductor integrated circuits, it is necessary to make the surface irregularities of semiconductor wafers and glass substrates for liquid crystals as flat as possible. Therefore, chemical mechanical polishing (CMP) is adopted.

すなわち、上記CMP法では、研磨装置の研磨定盤上に両面テープを用いて研磨パッドを固定し、研磨パッド上に研磨スラリーを滴下しながらウエハ等の研磨面を、研磨パッドをウエハに対して相対的に動かすことによって研磨するようにしている。
上記両面テープは、基材の一方の面に沿って研磨パッドを接着する研磨パッド用接着層が設けられ、基材の他方の面に沿って研磨定盤に接着する研磨定盤用接着層が設けられている。
そして、研磨定盤用接着層は、研磨パッドの交換を容易とするように、再剥離性を備えた粘着剤で形成されている(特許文献1)。
That is, in the CMP method, a polishing pad is fixed on a polishing surface plate of a polishing apparatus using a double-sided tape, and a polishing surface is dropped onto the polishing pad while the polishing slurry is dropped on the polishing pad. It is made to polish by moving relatively.
The double-sided tape is provided with a polishing pad adhesive layer that adheres a polishing pad along one surface of the substrate, and a polishing surface plate adhesive layer that adheres to the polishing surface plate along the other surface of the substrate. Is provided.
The polishing surface plate adhesive layer is formed of an adhesive having removability so as to facilitate replacement of the polishing pad (Patent Document 1).

特開平6−172722号公報JP-A-6-172722

しかし、従来の両面テープの場合、研磨定盤の材質によっては、研磨定盤にうまく接着できないものがあった。
すなわち、研磨装置の研磨定盤としては、ステンレス鋼、鋳鉄、アルミニウム、ポリカーボネートなどの樹脂材料等のいろいろな材質のものがあるが、特に鋳鉄製やポリカーボネート製のものにおいて従来の粘着剤では接着するのが困難な場合が多い。
However, in the case of a conventional double-sided tape, depending on the material of the polishing surface plate, there are some that cannot be adhered well to the polishing surface plate.
In other words, the polishing surface plate of the polishing apparatus includes various materials such as resin materials such as stainless steel, cast iron, aluminum, and polycarbonate, and in particular, those made of cast iron and polycarbonate are bonded with a conventional adhesive. It is often difficult.

本発明は、上記事情に鑑みて、従来接着しがたい材質の研磨定盤であっても、研磨定盤に接着できるとともに、使用後には糊残りがなく剥離することができる研磨パッド固定用両面テープを提供することを目的としている。   In view of the above circumstances, the present invention provides both surfaces for fixing a polishing pad that can be bonded to a polishing platen even if it is a conventional polishing platen that is difficult to bond, and can be peeled off after use without any adhesive residue. The purpose is to provide tape.

上記目的を達成するために、本発明にかかる研磨パッド固定用両面テープ(以下、「本発明の両面テープ」とのみ記す)は、樹脂フィルムからなる基材の一方の面に定盤固定用粘着剤層が積層一体化され、前記基材の他方の面に研磨パッド固定用接着剤層が積層一体化された研磨パッド固定用両面粘着テープであって、定盤固定用粘着剤層を構成する粘着剤が、スチレン−イソプレン−スチレン系エラストマーを含むベース樹脂と、このベース樹脂100重量部に対し、50〜200重量部の石油系粘着付与樹脂と、10〜60重量部のクマロン系粘着付与樹脂とを含むことを特徴としている。   In order to achieve the above object, the double-sided tape for fixing a polishing pad according to the present invention (hereinafter referred to only as “the double-sided tape of the present invention”) is a pressure-sensitive adhesive for fixing a platen on one surface of a substrate made of a resin film. A double-sided pressure-sensitive adhesive tape for fixing a polishing pad in which an adhesive layer is laminated and integrated, and an adhesive layer for fixing a polishing pad is laminated and integrated on the other surface of the base material, and constitutes a pressure-sensitive adhesive layer for fixing a platen A base resin containing a styrene-isoprene-styrene elastomer, 50 to 200 parts by weight of a petroleum-based tackifier resin, and 10 to 60 parts by weight of a coumarone-based tackifier resin with respect to 100 parts by weight of the base resin. It is characterized by including.

本発明の両面テープは、基材として樹脂フィルムを用いる。基材として樹脂フィルムを用いることで、定盤固定用粘着剤層及び研磨パッド固定用接着剤層の粘接着力を強化させながら、一方で、使用後に定盤から研磨パットを剥離する際には、定盤に糊残りが生ずることなく容易に研磨パットを剥離することができる。特に、定盤固定用粘着剤層においては、研磨時は粘着力が高く、使用後の剥離時には再剥離性に優れたものとなる。
本発明において、上記基材としては、特に限定されないが、例えば、ポリエステル系樹脂、ポリプロピレン系樹脂等の合成樹脂フィルムが挙げられ、なかでも、平坦であり、厚みのぶれが小さく、一定の強度を有することから、ポリエステル系樹脂フィルムが好適である。
また、基材には、粘接着剤との密着性を上げる為、コロナ処理やプラズマ処理等の表面処理を施したり、ゴム系やポリウレタン樹脂系等の易接着処理を施すことが好ましい。
The double-sided tape of the present invention uses a resin film as a base material. By using a resin film as a base material, while strengthening the adhesive strength of the pressure-sensitive adhesive layer for fixing the surface plate and the adhesive layer for fixing the polishing pad, on the other hand, when peeling the polishing pad from the surface plate after use The polishing pad can be easily peeled off without any adhesive residue on the surface plate. In particular, the pressure-sensitive adhesive layer for fixing the platen has a high adhesive force during polishing and has excellent removability when peeled after use.
In the present invention, the substrate is not particularly limited, and examples thereof include synthetic resin films such as polyester resins and polypropylene resins. Among them, they are flat, have little thickness fluctuation, and have a certain strength. Since it has, a polyester-type resin film is suitable.
Moreover, in order to improve adhesiveness with an adhesive agent, it is preferable to perform surface treatments, such as a corona treatment and a plasma treatment, or easy adhesion processes, such as a rubber system and a polyurethane resin system, to a base material.

また、基材となる合成樹脂フィルムの厚みは、特に限定されないが、12〜300μmが好ましく、20〜250μmがより好ましく、23〜250μmが更に好ましい。
すなわち、基材となる合成樹脂フィルムの厚みが12μm未満であると、得られる研磨パッド固定用両面粘着テープを研磨機の研磨定盤から剥離させる際に基材が破断して綺麗に剥離させることができないことがある。一方、厚みが300μmを超えると、研磨パッドと得られる研磨パッド固定用両面粘着テープとを圧着させる際の圧力の調整が困難となり、研磨パッドと研磨パッド固定用両面粘着テープとの接着強度が低下することがある。
Moreover, although the thickness of the synthetic resin film used as a base material is not specifically limited, 12-300 micrometers is preferable, 20-250 micrometers is more preferable, 23-250 micrometers is still more preferable.
That is, when the thickness of the synthetic resin film as the base material is less than 12 μm, the base material breaks and peels cleanly when the obtained double-sided pressure-sensitive adhesive tape for fixing the polishing pad is peeled off from the polishing surface plate of the polishing machine. May not be possible. On the other hand, when the thickness exceeds 300 μm, it is difficult to adjust the pressure when the polishing pad and the resulting double-sided pressure-sensitive adhesive tape for fixing the polishing pad are pressure-bonded, and the adhesive strength between the polishing pad and the double-sided pressure-sensitive adhesive tape for fixing the polishing pad decreases. There are things to do.

本発明の両面テープは、基材の一方の面に定盤固定用粘着剤層が積層一体化される。
本発明において、定盤固定用粘着剤層を構成する粘着剤のベース樹脂としては、スチレン−イソプレン−スチレン系エラストマーを含んでいれば特に限定されない。
ベース樹脂中のスチレン−イソプレン−スチレン系エラストマーの含有量は、特に限定されないが、ベース樹脂全体の30〜70重量%が好ましい。
すなわち、ベース樹脂中のスチレン−イソプレン−スチレン系エラストマーの含有量が、30重量%未満では、必要とする粘着力発現しない場合があり、70重量%を超えると、相対的に粘着付与樹脂量が少なくなり、粘着力が低下する場合がある。
In the double-sided tape of the present invention, the pressure-sensitive adhesive layer for fixing the platen is laminated and integrated on one surface of the substrate.
In the present invention, the adhesive base resin constituting the surface plate fixing adhesive layer is not particularly limited as long as it contains a styrene-isoprene-styrene elastomer.
The content of the styrene-isoprene-styrene elastomer in the base resin is not particularly limited, but is preferably 30 to 70% by weight of the entire base resin.
That is, if the content of the styrene-isoprene-styrene elastomer in the base resin is less than 30% by weight, the required adhesive strength may not be exhibited. If it exceeds 70% by weight, the amount of tackifying resin is relatively large. It may decrease and the adhesive strength may decrease.

上記ベース樹脂中のスチレン−イソプレン−スチレン系エラストマーのスチレン量は、特に限定されないが、14〜24%であることが好ましく、更に好ましくは15〜18%である。
ベース樹脂中のスチレン−イソプレン−スチレン系エラストマーのスチレン量が14%未満であると、凝集性の弱い粘着剤となり、研磨応力に耐えられなくなる場合があり、24%を超えると、凝集力が高すぎて粘着力が発現しなくなる場合がある。
The amount of styrene of the styrene-isoprene-styrene elastomer in the base resin is not particularly limited, but is preferably 14 to 24%, and more preferably 15 to 18%.
If the amount of styrene of the styrene-isoprene-styrene elastomer in the base resin is less than 14%, it may become an adhesive with weak cohesiveness and may not be able to withstand polishing stress. If it exceeds 24%, the cohesive force is high. In some cases, the adhesive strength may not be exhibited.

上記ベース樹脂中のスチレン−イソプレン−スチレン系エラストマーのジブロック率は、特に限定されないが、25〜70%であることが好ましく、更に好ましくは45〜60%である。ここでジブロックとは、スチレンとイソプレンとからなるジブロックのことをいう。   The diblock ratio of the styrene-isoprene-styrene elastomer in the base resin is not particularly limited, but is preferably 25 to 70%, and more preferably 45 to 60%. Here, the diblock refers to a diblock composed of styrene and isoprene.

スチレン−イソプレン−スチレン系エラストマーのジブロック率が25%未満であると凝集性が高すぎて粘着力が発現しなくなる場合があり、70%を超えると、凝集性の弱い粘着剤となり、研磨応力に耐えられなくなる場合がある。   If the diblock ratio of the styrene-isoprene-styrene elastomer is less than 25%, the cohesiveness may be too high and the adhesive force may not be exhibited. May not be able to withstand.

上記ベース樹脂中のスチレン−イソプレン−スチレン系エラストマーの分子量は、特に限定されないが、重量平均分子量で15万〜25万が好ましい。すなわち、重量平均分子量が15万未満であると、耐熱性が低下する場合があり、重量平均分子量が25万を超えると樹脂や溶剤との相溶性が悪くなる場合がある。ここで重量平均分子量とは、GPC(ゲルパーミエーションクロマトグラフィ)法によりポリスチレン換算分子量として測定されるものをいう。   The molecular weight of the styrene-isoprene-styrene elastomer in the base resin is not particularly limited, but is preferably 150,000 to 250,000 in terms of weight average molecular weight. That is, if the weight average molecular weight is less than 150,000, the heat resistance may decrease, and if the weight average molecular weight exceeds 250,000, the compatibility with the resin or solvent may be deteriorated. Here, the weight average molecular weight refers to that measured as a polystyrene-converted molecular weight by a GPC (gel permeation chromatography) method.

また、本発明において、定盤固定用粘着剤層を構成する粘着剤中には、上記ベース樹脂100重量部に対して50〜200重量部(好ましくは60〜150重量部、更に好ましくは80〜150重量部)の石油樹脂系粘着付与樹脂と、10〜60重量部(好ましくは10〜50重量部、更に好ましくは10〜30重量部)のクマロン樹脂系粘着付与樹脂とが含まれる。
すなわち、ベース樹脂100重量部に対して石油樹脂系粘着付与樹脂の配合量が50重量部未満、あるいは、200重量部を超えると、粘着力が発揮できないという問題がある。
In the present invention, the pressure-sensitive adhesive constituting the surface plate fixing pressure-sensitive adhesive layer is 50 to 200 parts by weight (preferably 60 to 150 parts by weight, more preferably 80 to 150 parts by weight) with respect to 100 parts by weight of the base resin. 150 parts by weight of petroleum resin-based tackifier resin and 10-60 parts by weight (preferably 10-50 parts by weight, more preferably 10-30 parts by weight) of coumarone resin-based tackifier resin.
That is, when the blending amount of the petroleum resin-based tackifying resin is less than 50 parts by weight or more than 200 parts by weight with respect to 100 parts by weight of the base resin, there is a problem that the adhesive force cannot be exhibited.

ベース樹脂100重量部に対してクマロン樹脂系粘着付与樹脂の配合量が10重量部未満であると、凝集力が低くなりすぎて研磨中の研磨応力に耐えられなくなり、すなわち、接着力低下をまねく。一方、クマロン樹脂系粘着付与樹脂の配合量が60重量部を超えると、凝集性が高くなりすぎて粘着力を低下させるという問題がある。   When the blending amount of the coumarone resin-based tackifying resin is less than 10 parts by weight with respect to 100 parts by weight of the base resin, the cohesive force becomes too low to withstand the polishing stress during polishing, that is, the adhesive strength is reduced. . On the other hand, when the blending amount of the coumarone resin-based tackifying resin exceeds 60 parts by weight, there is a problem that the cohesiveness becomes too high and the adhesive strength is lowered.

上記石油樹脂系粘着付与樹脂としては、特に限定されないが、例えば、脂肪族系石油樹脂、脂環族系石油樹脂、芳香族系石油樹脂等が挙げられ、スチレン−イソプレン−スチレン系樹脂との相溶性の観点から脂肪族系石油樹脂が好ましい。
また、上記クマロン樹脂系粘着付与樹脂としては、特に限定されないが、凝集力確保のために軟化点120℃付近のものがよい。
The petroleum resin-based tackifying resin is not particularly limited, and examples thereof include aliphatic petroleum resins, alicyclic petroleum resins, aromatic petroleum resins, and the like, and a phase with a styrene-isoprene-styrene resin. From the viewpoint of solubility, an aliphatic petroleum resin is preferred.
Further, the coumarone resin-based tackifier resin is not particularly limited, but preferably has a softening point near 120 ° C. in order to ensure cohesive strength.

更に、定盤固定用粘着剤層を構成する粘着剤中には、必要に応じて、酸化防止剤(老化防止剤)、上記石油樹脂系粘着付与樹脂及びクマロン樹脂系粘着付与樹脂以外の粘着付与樹脂、有機過酸化物、熱安定剤、光安定剤、紫外線吸収剤等各種の添加剤を配合することができ、スチレン−イソプレン−スチレン系エラストマーの劣化を防ぐために酸化防止剤を配合することが好ましい。   Further, in the pressure-sensitive adhesive constituting the pressure-sensitive adhesive layer for fixing the platen, if necessary, tackifying other than the antioxidant (anti-aging agent), the above petroleum resin-based tackifying resin and the coumarone resin-based tackifying resin. Various additives such as resins, organic peroxides, heat stabilizers, light stabilizers, ultraviolet absorbers can be blended, and antioxidants can be blended to prevent deterioration of the styrene-isoprene-styrene elastomer. preferable.

上記酸化防止剤としては、特に限定されないが、例えば、2,2−メチレンビス(4−メチル−6−t−ブチルフェノール)等のフェノール系酸化防止剤、N−フェニル−N−(1,3−ジメチルブチル)−p−フェニレンジアミン)等のアミン系酸化防止剤、2−メルカプトベンズイミダゾール等のベンズイミダゾール系酸化防止剤等が挙げられる。
酸化防止剤は、少量で効果を発揮し、多すぎる必要はなく、その配合量は、ベース樹脂100重量部に対して2重量部以下でよい。
Although it does not specifically limit as said antioxidant, For example, phenolic antioxidants, such as 2, 2- methylenebis (4-methyl-6-t- butylphenol), N-phenyl-N- (1, 3- dimethyl). Amine-based antioxidants such as butyl) -p-phenylenediamine) and benzimidazole-based antioxidants such as 2-mercaptobenzimidazole.
The antioxidant exhibits an effect in a small amount and does not need to be too much. The amount of the antioxidant may be 2 parts by weight or less with respect to 100 parts by weight of the base resin.

上記石油樹脂系粘着付与樹脂及びクマロン樹脂系粘着付与樹脂以外の粘着付与樹脂としては、例えば、ロジン系樹脂、テルペン系樹脂等の天然物及びその誘導体、スチレン系樹脂、フェノール樹脂、キシレン樹脂等の合成樹脂などが挙げられる。   Examples of the tackifying resin other than the petroleum resin tackifying resin and the coumarone resin tackifying resin include natural products such as rosin resin and terpene resin and derivatives thereof, styrene resin, phenol resin, xylene resin and the like. Examples include synthetic resins.

定盤固定用粘着剤層の厚さは、特に限定されないが、10〜50μmが好ましい。
すなわち、定盤固定用粘着剤層の厚さが10μm未満であると、研磨中に定盤から剥がれが生じる場合があり、粘着剤層の厚さが50μmを超えると、使用後に剥がす時、定盤側に糊残りを生じる場合がある。
The thickness of the pressure-sensitive adhesive layer for fixing the platen is not particularly limited, but is preferably 10 to 50 μm.
That is, if the thickness of the pressure-sensitive adhesive layer for fixing the surface plate is less than 10 μm, peeling may occur from the surface plate during polishing. If the thickness of the pressure-sensitive adhesive layer exceeds 50 μm, the thickness will be constant when peeling after use. There may be a residue of glue on the board side.

一方、本発明の研磨パッド固定用両面粘着テープにおいて、研磨パッド固定用粘着剤層を構成する粘着剤としては、本発明の目的を達成することができる粘着剤であれば、特に限定されないが、感熱型粘着剤や、ホットメルト系粘接着剤が挙げられる。
本発明において、感熱型粘着剤とは、熱圧着後に高い接着力を発揮するものをいう。
上記感熱型粘着剤としては、特に限定されないが、(メタ)アクリル酸ブチルを90重量%以上含有する重合性モノマー混合物中の重合性モノマーを共重合して得られる(メタ)アクリル酸アルキルエステル系共重合体と、該(メタ)アクリル酸アルキルエステル系共重合体の固形分100重量部に対して、テルペンフェノール樹脂を20〜70重量部(より好ましくは、30〜60重量部)含有する感熱型粘着剤が好適である。
上記感熱型粘着剤において、テルペンフェノール樹脂の配合量が20重量部未満であると、感熱型粘着剤として機能しなかったり、粘着力が不足する場合があり、70重量部を超えると、粘着剤層が硬くなってしまい、初期タック性が劣る場合がある。
On the other hand, in the double-sided pressure-sensitive adhesive tape for fixing the polishing pad of the present invention, the pressure-sensitive adhesive constituting the pressure-sensitive adhesive layer for polishing pad fixing is not particularly limited as long as the pressure-sensitive adhesive can achieve the object of the present invention. A heat sensitive adhesive and a hot-melt adhesive are mentioned.
In the present invention, the heat-sensitive pressure-sensitive adhesive means a material that exhibits high adhesive force after thermocompression bonding.
Although it does not specifically limit as said heat-sensitive adhesive, The (meth) acrylic-acid alkylester type | system | group obtained by copolymerizing the polymerizable monomer in the polymerizable monomer mixture containing 90 weight% or more of (meth) acrylic acid butyl is used. Thermosensitive containing 20 to 70 parts by weight (more preferably 30 to 60 parts by weight) of a terpene phenol resin with respect to 100 parts by weight of the solid content of the copolymer and the (meth) acrylic acid alkyl ester copolymer. Mold adhesives are preferred.
In the above heat-sensitive adhesive, if the blending amount of the terpene phenol resin is less than 20 parts by weight, it may not function as a heat-sensitive adhesive or the adhesive strength may be insufficient. If it exceeds 70 parts by weight, the adhesive A layer may become hard and initial tackiness may be inferior.

また、上記テルペンフェノール樹脂としては、本発明の目的を達成できれば、特に限定されず、例えば、ヤスハラケミカル社のYSシリーズ商品名T115やヤスハラケミカル社のYSシリーズ商品名T130などの市販のテルペンフェノール樹脂を用いることができる。   The terpene phenol resin is not particularly limited as long as the object of the present invention can be achieved. For example, a commercially available terpene phenol resin such as YS series trade name T115 of Yashara Chemical Co., Ltd. or YS series trade name T130 of Yashara Chemical Co. is used. be able to.

また、上記感熱型粘着剤には、テルペンフェノール樹脂以外に本発明の目的を阻害しない範囲でその他の粘着付与樹脂を配合しても構わない。
その他の粘着付与樹脂としては、特に限定されないが、フェノール樹脂、ロジン系樹脂、テルペン系樹脂が挙げられ、これらを単独であるいは併せて用いることができる。
Moreover, you may mix | blend other tackifying resin with the said thermosensitive adhesive in the range which does not inhibit the objective of this invention other than a terpene phenol resin.
Other tackifying resins are not particularly limited, and examples thereof include phenol resins, rosin resins, and terpene resins, and these can be used alone or in combination.

〔研磨パッド固定用粘着剤層の粘着力〕
研磨パッド固定用両面粘着テープにおける研磨パッド固定用粘着剤層の180°ピール力は、低いと、研磨工程中にスラリー液に含有された酸やアルカリによって研磨パッド固定用粘着剤層が変質してその粘着力が低下した際に、研磨パッドが研磨パッド固定用両面粘着テープから剥離してしまうことがあるため、20N/25mm以上が好ましく、25N/25mm以上がより好ましい。
ここで、上記研磨パッド固定用両面粘着テープにおける研磨パッド固定用粘着剤層の180°ピール力は、JIS Z0237に準拠して測定するものとする。なお、上記180°ピール力の測定方法において、研磨パッド固定用両面粘着テープからなる試験片を試験板(ステンレス板)に貼着させてから180°ピール力の測定を行うまでに、温度25℃、相対湿度50%の雰囲気中に30分間静置するものとする。
[Adhesive strength of polishing pad fixing adhesive layer]
If the 180 ° peel force of the polishing pad fixing pressure-sensitive adhesive layer in the double-sided pressure-sensitive adhesive tape for polishing pad fixing is low, the polishing pad fixing pressure-sensitive adhesive layer is altered by the acid or alkali contained in the slurry during the polishing process. Since the polishing pad may be peeled off from the double-sided pressure-sensitive adhesive tape for fixing the polishing pad when the adhesive force is reduced, it is preferably 20 N / 25 mm or more, more preferably 25 N / 25 mm or more.
Here, the 180 ° peel force of the pressure-sensitive adhesive layer for fixing the polishing pad in the double-sided pressure-sensitive adhesive tape for fixing the polishing pad is measured according to JIS Z0237. In the above 180 ° peel force measurement method, a temperature of 25 ° C. is required from when a test piece made of a double-sided adhesive tape for fixing a polishing pad is attached to a test plate (stainless steel plate) until 180 ° peel force is measured. Let it stand for 30 minutes in an atmosphere with a relative humidity of 50%.

研磨パッド固定用粘着剤層の厚みは、特に限定されないが、50〜100μmが好ましく、60〜80μmがより好ましい。すなわち、研磨パッド固定用粘着剤層の厚みが薄すぎると、研磨工程中に研磨パッド固定用粘着剤層から研磨パッドが剥離したり、研磨パッドの研磨精度が劣るおそれがある一方、厚いと、研磨工程中に研磨パッド固定用粘着剤層で凝集破壊が発生することがある。   The thickness of the pressure-sensitive adhesive layer for fixing the polishing pad is not particularly limited, but is preferably 50 to 100 μm, and more preferably 60 to 80 μm. That is, if the thickness of the pressure-sensitive adhesive layer for fixing the polishing pad is too thin, the polishing pad may be peeled off from the pressure-sensitive adhesive layer for fixing the polishing pad during the polishing step, or the polishing accuracy of the polishing pad may be deteriorated. During the polishing process, cohesive failure may occur in the pressure-sensitive adhesive layer for fixing the polishing pad.

上記研磨パッド固定用粘着剤層に用いられる粘着剤には、架橋剤を添加してもよい。上記架橋剤としては、特に限定されず、例えば、イソシアネート系架橋剤、アジリジン系架橋剤、エポキシ系架橋剤、金属キレート型架橋剤などが挙げられ、中でも耐熱性及び耐久性等の性能を発現しやすいことからイソシアネート系架橋剤が好ましい。   You may add a crosslinking agent to the adhesive used for the said adhesive pad for polishing pad fixation. The crosslinking agent is not particularly limited and includes, for example, an isocyanate crosslinking agent, an aziridine crosslinking agent, an epoxy crosslinking agent, a metal chelate crosslinking agent, etc. Among them, performance such as heat resistance and durability is expressed. Since it is easy, an isocyanate type crosslinking agent is preferable.

本発明の研磨パッド固定用両面テープには、接着剤層上に離型材が貼着されているのが好ましい。貼着される離型材としては、特に限定されず、例えば、シリコーン樹脂系離型剤や長鎖アルキル基ペンダント型グラフトポリマー系離型剤等により、紙やプラスチックフィルム等の少なくとも片面に離型処理を施して得られる離型紙や離型フィルム等が挙げられる。   In the double-sided tape for fixing the polishing pad of the present invention, it is preferable that a release material is stuck on the adhesive layer. The release material to be attached is not particularly limited, and for example, a release treatment on at least one surface of paper, plastic film, or the like with a silicone resin release agent or a long-chain alkyl group pendant graft polymer release agent. Release paper, release film and the like obtained by applying the above.

本発明の両面テープを用いて固定される研磨パッドの材質としては、特に限定されないが、例えば、硬質ポリウレタンの発泡体、各種ゴムの発泡体、ポリエチレン・ポリプロピレン等のオレフィン系樹脂の発泡体や、更に平均発泡粒径が0.5mm以上のこれらの発泡体のスライス品や、セリウムやシリカなどの砥粒やフィラー、研磨材などをこれらの発泡体に含有させたものが挙げられる。   The material of the polishing pad fixed using the double-sided tape of the present invention is not particularly limited, for example, a hard polyurethane foam, various rubber foams, foams of olefin resins such as polyethylene and polypropylene, Further, sliced products of these foams having an average foamed particle size of 0.5 mm or more, and those obtained by adding abrasive grains such as cerium and silica, fillers, abrasives, etc. to these foams.

本発明の両面テープは、基材として樹脂フィルムを用いることで、定盤固定用粘着剤層及び研磨パッド固定用接着剤層の粘接着力を強化させながら、一方で、使用後に定盤から研磨パットを剥離する際には、定盤に糊残りが生ずることなく容易に研磨パットを剥離することができる。また、定盤固定用粘着剤層を構成する粘着剤が、スチレン−イソプレン−スチレン系エラストマーを主成分とするベース樹脂と、このベース樹脂100重量部に対し、50〜200重量部の石油系粘着付与樹脂と、10〜60重量部のクマロン系粘着付与樹脂とを含むので、研磨定盤に対し、研磨時は充分な粘着力を確保しつつ、使用後の研磨パットの剥離時には、定盤に糊残りが生ずることなく容易に研磨パットを剥離することができる。更に、従来接着しがたい材質の研磨定盤であっても、研磨定盤に充分な粘着力を確保しながら貼着できるとともに、使用後の研磨パットの剥離時には、糊残りがなく剥離することができる。   The double-sided tape of the present invention uses a resin film as a base material to enhance the adhesive force of the adhesive layer for fixing the surface plate and the adhesive layer for fixing the polishing pad, while polishing from the surface plate after use. When the pad is peeled off, the polishing pad can be easily peeled off without any adhesive residue on the surface plate. The pressure-sensitive adhesive constituting the platen-fixing pressure-sensitive adhesive layer is a base resin mainly composed of a styrene-isoprene-styrene elastomer and 50 to 200 parts by weight of a petroleum-based adhesive with respect to 100 parts by weight of the base resin. Since it includes 10 to 60 parts by weight of coumarone-based tackifying resin, the surface plate is used when the polishing pad is peeled off after use while ensuring a sufficient adhesive force when polishing against the polishing surface plate. The polishing pad can be easily peeled off without causing adhesive residue. Furthermore, even if it is a polishing surface plate that is difficult to adhere to the conventional surface, it can be adhered to the polishing surface plate while ensuring sufficient adhesive force, and when removing the polishing pad after use, it should be peeled off without any adhesive residue. Can do.

本発明の両面テープの1つの実施の形態をあらわす断面図である。It is sectional drawing showing one embodiment of the double-sided tape of this invention.

以下に、本発明を、その実施の形態をあらわす図面を参照しつつ詳しく説明する。
図1は、本発明の両面テープの1つの実施の形態をあらわしている。
Hereinafter, the present invention will be described in detail with reference to the drawings showing embodiments thereof.
FIG. 1 shows one embodiment of the double-sided tape of the present invention.

図1に示すように、この両面テープ1は、樹脂フィルムからなる基材2の一方の面に定盤固定用粘着剤層3が積層され、他方の面に研磨パッド固定用接着剤層4が積層されている。また、定盤固定用粘着剤層3及び研磨パッド固定用接着剤層4の表面には、離型シート5がそれぞれ積層されている。
樹脂フィルムからなる基材2は、両面がコロナ放電処理等によって易接着処理された厚さ12〜300μmのポリエチレンテレフタレートフィルムによって形成されている。
As shown in FIG. 1, this double-sided tape 1 has a base plate fixing pressure-sensitive adhesive layer 3 laminated on one surface of a substrate 2 made of a resin film, and a polishing pad fixing adhesive layer 4 on the other surface. Are stacked. A release sheet 5 is laminated on the surface of the pressure-sensitive adhesive layer 3 for fixing the platen and the adhesive layer 4 for fixing the polishing pad.
The base material 2 made of a resin film is formed of a polyethylene terephthalate film having a thickness of 12 to 300 μm whose both surfaces are subjected to easy adhesion treatment by corona discharge treatment or the like.

定盤固定用粘着剤層3は、スチレン−イソプレン−スチレン系エラストマーを主成分とするベース樹脂と、このベース樹脂100重量部に対し、50〜200重量部の石油系粘着付与樹脂と、10〜60重量部のクマロン系粘着付与樹脂とを含む粘着剤で形成されている。
研磨パッド固定用接着剤層4は、アクリル溶剤型粘着剤によって形成されている。
離型シート5は、両面がシリコーン処理されたポリエチレンテレフタレートフィルムによって形成されている。
そして、この両面テープ1は、離型シート5を取り除き、定盤固定用粘着剤層3側を定盤 (図示せず)に、研磨パッド固定用接着剤層4側を研磨パッド(図示せず)にそれぞれ押圧接着されるようになっている。
The pressure-sensitive adhesive layer 3 for fixing the platen is composed of a base resin mainly composed of styrene-isoprene-styrene elastomer, 50 to 200 parts by weight of a petroleum-based tackifying resin with respect to 100 parts by weight of the base resin, It is formed with an adhesive containing 60 parts by weight of coumarone-based tackifying resin.
The polishing pad fixing adhesive layer 4 is formed of an acrylic solvent adhesive.
The release sheet 5 is formed of a polyethylene terephthalate film having both sides treated with silicone.
Then, the double-faced tape 1 removes the release sheet 5, the surface plate fixing adhesive layer 3 side is a surface plate (not shown), and the polishing pad fixing adhesive layer 4 side is a polishing pad (not shown). ) Are pressed and bonded to each other.

また、この両面テープ1は、たとえば、以下のようにして製造することができる。
すなわち、一つの離型シート5の離型性を有する面にスチレン−イソプレン−スチレン系エラストマーを含むベース樹脂と、このベース樹脂100重量部に対し、50〜200重量部の石油系粘着付与樹脂と、10〜60重量部のクマロン系粘着付与樹脂とを含む粘着剤を定盤固定用粘着剤層3の厚さとなるように塗工し乾燥して定盤固定用粘着剤層3形成用シートを作製するとともに、別の離型シート5の離型性を有する面にアクリル溶剤型粘着剤を研磨パッド固定用接着剤層4の厚さとなるように塗工乾燥して研磨パッド固定用接着剤層4形成用シートを作製する。
つぎに、樹脂フィルムからなる基材2の一方の面に定盤固定用粘着剤層3形成用シートの粘着剤層側を押し当て、基材2の他方の面に研磨パッド固定用接着剤層4形成用シートの接着剤層側を押し当て、定盤固定用粘着剤層3及び研磨パッド固定用接着剤層4をそれぞれ樹脂フィルムからなる基材2の各面に転写して積層一体化させることによって得られる。
Moreover, this double-sided tape 1 can be manufactured as follows, for example.
That is, a base resin containing a styrene-isoprene-styrene elastomer on the surface having a releasability of one release sheet 5, and 50 to 200 parts by weight of a petroleum-based tackifying resin with respect to 100 parts by weight of the base resin Then, a pressure-sensitive adhesive layer containing 10 to 60 parts by weight of a coumarone-based tackifying resin is applied to the thickness of the pressure-sensitive adhesive layer 3 for fixing the platen, and dried to form a sheet for forming the pressure-sensitive adhesive layer 3 for fixing the platen. The adhesive layer for polishing pad fixing is prepared by applying and drying an acrylic solvent-type pressure-sensitive adhesive on the surface having the releasability of another release sheet 5 so as to have the thickness of the adhesive layer 4 for fixing the polishing pad. 4 A sheet for forming is prepared.
Next, the pressure-sensitive adhesive layer side of the platen fixing pressure-sensitive adhesive layer 3 forming sheet is pressed against one surface of the base material 2 made of a resin film, and the polishing pad fixing adhesive layer is pressed against the other surface of the base material 2. 4. Press the adhesive layer side of the 4 forming sheet, transfer the surface plate fixing adhesive layer 3 and the polishing pad fixing adhesive layer 4 to each surface of the substrate 2 made of a resin film, and laminate and integrate them. Can be obtained.

以下に、本発明の実施例と比較例とを詳しく説明するが、本発明は、以下の実施例に限定されるものではない。   Examples of the present invention and comparative examples will be described in detail below, but the present invention is not limited to the following examples.

(実施例1)
離型シート(藤森工業社製 離型紙75S−518LA)5に定盤固定用粘着剤層3となる以下に示す配合の粘着剤Aを乾燥後の厚さが40μmとなるように塗工し、100℃のオーブン中で3分間加熱し溶剤を乾燥して離型紙5の一方の面に定盤固定用粘着剤層3を備えた第1の積層体を得た。
厚さ25μmのポリエチレンテレフタレートフィルム(テイジン社製)の両面をコロナ放電処理して基材2を得た。
基材2の一方の面にアクリル酸エステル共重合体(積水化学社製 WHD)100重量部にイソシアネート系架橋剤(日本ポリウレタン社製 コロネートL−55E)を1.5重量部混合したアクリル樹脂系粘着剤を、乾燥後の厚さが80μmとなるように塗工し、100℃のオーブン中で3分間加熱し溶剤を乾燥して、基材2の一方の面に研磨パッド固定用接着層4を備えた第2の積層体を得た。
つぎに、この研磨パッド固定用接着層4の表面に離型シート(藤森工業社製 離型紙75S−518LA)5をラミネートしたのち、先に得られた第1の積層体の定盤固定用粘着剤層3側を第2の積層体の基材2側にラミネートして、両面テープ1を得た。
〔粘着剤A〕
(a)ベース樹脂:100重量部
〔スチレン−イソプレン−スチレン系エラストマー(日本ゼオン社製商品名Quintac3433N,スチレン量16%,ジブロック率56%,平均分子量17万)100重量部〕
(b)石油系粘着付与樹脂:90重量部
〔日本ゼオン社製商品名M100,軟化点100℃〕
(c)クマロン系粘着付与樹脂:30重量部
〔日塗化学社製商品名エスクロンV-120,軟化点120℃〕
Example 1
The release sheet (Fujimori Kogyo Co., Ltd. release paper 75S-518LA) 5 was coated with an adhesive A having the following composition to be the pressure-sensitive adhesive layer 3 for fixing the platen so that the thickness after drying was 40 μm. It heated for 3 minutes in 100 degreeC oven, the solvent was dried, and the 1st laminated body provided with the adhesive layer 3 for surface plate fixing on the one side of the release paper 5 was obtained.
Both sides of a 25 μm thick polyethylene terephthalate film (manufactured by Teijin) were subjected to corona discharge treatment to obtain a substrate 2.
Acrylic resin system in which 1.5 parts by weight of an isocyanate cross-linking agent (Coronate L-55E manufactured by Nippon Polyurethane Co., Ltd.) is mixed with 100 parts by weight of an acrylic ester copolymer (WHD manufactured by Sekisui Chemical Co., Ltd.) on one surface of the substrate 2 The pressure-sensitive adhesive was applied so that the thickness after drying was 80 μm, heated in an oven at 100 ° C. for 3 minutes to dry the solvent, and the adhesive layer 4 for fixing the polishing pad on one surface of the substrate 2. The 2nd laminated body provided with was obtained.
Next, a release sheet (release paper 75S-518LA, manufactured by Fujimori Kogyo Co., Ltd.) 5 is laminated on the surface of the adhesive layer 4 for fixing the polishing pad, and then the first laminate obtained above is used for fixing the surface plate. The double-sided tape 1 was obtained by laminating the agent layer 3 side to the base material 2 side of the second laminate.
[Adhesive A]
(A) Base resin: 100 parts by weight [styrene-isoprene-styrene elastomer (trade name Quintac 3433N, manufactured by Nippon Zeon Co., Ltd., 16% styrene, 56% diblock, average molecular weight 170,000) 100 parts by weight]
(B) Petroleum-based tackifying resin: 90 parts by weight [trade name M100 manufactured by Nippon Zeon Co., Ltd., softening point 100 ° C.]
(C) Coumarone tackifying resin: 30 parts by weight [trade name Escron V-120, softening point 120 ° C., manufactured by Nikko Chemical Co., Ltd.]

(実施例2)
ベース樹脂100重量部に対する石油系粘着付与樹脂の配合量を140重量部、クマロン系粘着付与樹脂の配合量を10重量部とした以外は、粘着剤Aと同様の配合の粘着剤Bを得た。そして、粘着剤Aに代えて粘着剤Bを用いて定盤固定用粘着剤層3を形成した以外は、上記実施例1と同様にして両面テープ1を得た。
(Example 2)
A pressure-sensitive adhesive B having the same composition as pressure-sensitive adhesive A was obtained except that the amount of petroleum-based tackifying resin was 140 parts by weight and the amount of coumarone-based tackifying resin was 10 parts by weight with respect to 100 parts by weight of the base resin. . A double-sided tape 1 was obtained in the same manner as in Example 1 except that the pressure-sensitive adhesive layer 3 was formed using the pressure-sensitive adhesive B instead of the pressure-sensitive adhesive A.

(実施例3)
基材1として厚み60μmのOPP(二軸延伸ポリプロピレンフィルム)を用いた以外は、上記実施例1と同様にして両面テープ1を得た。
(Example 3)
A double-sided tape 1 was obtained in the same manner as in Example 1 except that OPP (biaxially oriented polypropylene film) having a thickness of 60 μm was used as the substrate 1.

(比較例1)
基材1としてレーヨン不織布(日本製紙パピリア社製商品名SPC)を用いた以外は、上記実施例1と同様にして両面テープ1を得た。
(Comparative Example 1)
A double-sided tape 1 was obtained in the same manner as in Example 1 except that a rayon nonwoven fabric (trade name SPC manufactured by Nippon Paper Industries Co., Ltd.) was used as the substrate 1.

(比較例2)
ベース樹脂100重量部に対する石油系粘着付与樹脂の配合量を40重量部とした以外は、粘着剤Aと同様の配合の粘着剤Cを得た。そして、粘着剤Aに代えて粘着剤Cを用いて定盤固定用粘着剤層3を形成した以外は、上記実施例1と同様にして両面テープ1を得た。
(Comparative Example 2)
A pressure-sensitive adhesive C having the same composition as that of pressure-sensitive adhesive A was obtained except that the amount of the petroleum-based tackifying resin was 40 parts by weight with respect to 100 parts by weight of the base resin. A double-sided tape 1 was obtained in the same manner as in Example 1 except that the pressure-sensitive adhesive layer 3 was formed using the pressure-sensitive adhesive C instead of the pressure-sensitive adhesive A.

(比較例3)
ベース樹脂100重量部に対する石油系粘着付与樹脂の配合量を250重量部とした以外は、粘着剤Aと同様の配合の粘着剤Dを得た。そして、粘着剤Aに代えて粘着剤Dを用いて定盤固定用粘着剤層3を形成した以外は、上記実施例1と同様にして両面テープ1を得た。
(Comparative Example 3)
An adhesive D having the same composition as that of the adhesive A was obtained except that the blending amount of the petroleum-based tackifying resin with respect to 100 parts by weight of the base resin was 250 parts by weight. Then, a double-sided tape 1 was obtained in the same manner as in Example 1 except that the pressure-sensitive adhesive layer 3 was formed using the pressure-sensitive adhesive D instead of the pressure-sensitive adhesive A.

(比較例4)
ベース樹脂100重量部に対するクマロン系粘着付与樹脂の配合量を5重量部とした以外は、粘着剤Aと同様の配合の粘着剤Eを得た。そして、粘着剤Aに代えて粘着剤Eを用いて定盤固定用粘着剤層3を形成した以外は、上記実施例1と同様にして両面テープ1を得た。
(Comparative Example 4)
Adhesive E having the same composition as that of Adhesive A was obtained except that the blending amount of the coumarone-based tackifying resin with respect to 100 parts by weight of the base resin was changed to 5 parts by weight. A double-sided tape 1 was obtained in the same manner as in Example 1 except that the pressure-sensitive adhesive layer 3 was formed using the pressure-sensitive adhesive E instead of the pressure-sensitive adhesive A.

(比較例5)
ベース樹脂100重量部に対するクマロン系粘着付与樹脂の配合量を80重量部とした以外は、粘着剤Aと同様の配合の粘着剤Fを得た。そして、粘着剤Aに代えて粘着剤Fを用いて定盤固定用粘着剤層3を形成した以外は、上記実施例1と同様にして両面テープ1を得た。
(Comparative Example 5)
A pressure-sensitive adhesive F having the same composition as that of pressure-sensitive adhesive A was obtained except that the amount of coumarone-based tackifying resin was 80 parts by weight with respect to 100 parts by weight of the base resin. Then, a double-sided tape 1 was obtained in the same manner as in Example 1 except that the pressure-sensitive adhesive layer 3 was formed using the pressure-sensitive adhesive F instead of the pressure-sensitive adhesive A.

上記実施例1〜3及び比較例1〜5で得られた両面テープ1について、ステンレス(SP)製、ポリカーボネート(PC)製、アルマイト製の各研磨定盤への定盤固定用粘着剤層3の粘着性能及び再剥離性について以下のように評価し、その結果を表1に示した。   About the double-sided tape 1 obtained in Examples 1 to 3 and Comparative Examples 1 to 5, the pressure-sensitive adhesive layer 3 for fixing the platen to each polishing platen made of stainless steel (SP), polycarbonate (PC), or anodized. The adhesive performance and re-peelability were evaluated as follows, and the results are shown in Table 1.

〔粘着性能〕
JISZ0237に準拠した90°ピール試験を実施して評価した。
[Adhesion performance]
A 90 ° peel test according to JISZ0237 was carried out for evaluation.

〔再剥離性〕
研磨装置のポリカーボネート製の定盤に両面テープを介して研磨パッドを固定し、被研磨試験体としてのガラス板を、15時間研磨した後、定盤から研磨パッドとともに、両面テープを剥離し、定盤側に糊残りがあるか否かを目視で調べ、糊残りなしが○、糊残りがあれば×、研磨途中で定盤から剥がれたものを××、基材が破壊したものを×××と評価した。
[Removability]
A polishing pad is fixed to a polycarbonate surface plate of a polishing apparatus via a double-sided tape, and after polishing a glass plate as a specimen to be polished for 15 hours, the double-sided tape is peeled off from the surface plate together with the polishing pad. Visually inspect whether there is any adhesive residue on the board side, ○ if there is no adhesive residue, × if there is adhesive residue, XX if it is peeled off from the surface plate during polishing, XX if the substrate is destroyed X was evaluated.

Figure 2011122069
Figure 2011122069

1 両面テープ
2 基材
3 定盤固定用粘着剤層
4 研磨パッド固定用接着剤層
5 離型シート
DESCRIPTION OF SYMBOLS 1 Double-stick tape 2 Base material 3 Adhesive layer 4 for fixing a surface plate Adhesive layer 5 for fixing a polishing pad Release sheet

Claims (4)

樹脂フィルムからなる基材の一方の面に定盤固定用粘着剤層が積層一体化され、前記基材の他方の面に研磨パッド固定用接着剤層が積層一体化された研磨パッド固定用両面粘着テープであって、定盤固定用粘着剤層を構成する粘着剤が、スチレン−イソプレン−スチレン系エラストマーを含むベース樹脂と、
このベース樹脂100重量部に対し、50〜200重量部の石油系粘着付与樹脂と、10〜60重量部のクマロン系粘着付与樹脂とを含むことを特徴とする研磨パッド固定用両面テープ
A polishing pad fixing double-sided surface in which a pressure-sensitive adhesive layer for fixing a surface plate is laminated and integrated on one surface of a base material made of a resin film, and an adhesive layer for fixing a polishing pad is stacked and integrated on the other surface of the base material A base resin containing a styrene-isoprene-styrene elastomer, wherein the pressure-sensitive adhesive is a pressure-sensitive adhesive tape and the pressure-sensitive adhesive layer constituting the surface plate fixing pressure-sensitive adhesive layer;
A double-sided tape for fixing a polishing pad comprising 50 to 200 parts by weight of a petroleum-based tackifying resin and 10 to 60 parts by weight of a coumarone-based tackifying resin with respect to 100 parts by weight of the base resin.
定盤固定用粘着剤層を構成する粘着剤の、ベース樹脂中のスチレン−イソプレン−スチレン系エラストマーのスチレン量が14〜24%である請求項1に記載の研磨パッド固定用両面テープ   2. The double-sided tape for fixing a polishing pad according to claim 1, wherein the styrene content of the styrene-isoprene-styrene elastomer in the base resin of the adhesive constituting the surface plate fixing adhesive layer is 14 to 24%. 定盤固定用粘着剤層を構成する粘着剤の、ベース樹脂中のスチレン−イソプレン−スチレン系エラストマーのジブロック率が25〜70%である請求項1または請求項2に記載の研磨パッド固定用両面テープ。   3. The polishing pad fixing device according to claim 1, wherein a diblock ratio of the styrene-isoprene-styrene elastomer in the base resin of the pressure-sensitive adhesive constituting the surface plate fixing adhesive layer is 25 to 70%. Double-sided tape. 定盤固定用粘着剤層を構成する粘着剤が酸化防止剤を含む請求項1〜請求項3のいずれかに記載の研磨パッド固定用両面テープ。   The double-sided tape for fixing a polishing pad according to any one of claims 1 to 3, wherein the adhesive constituting the adhesive layer for fixing the platen contains an antioxidant.
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WO2012144458A1 (en) * 2011-04-21 2012-10-26 東洋ゴム工業株式会社 Hot-melt adhesive sheet for laminated polishing pad and adhesive-layer-bearing support layer for laminated polishing pad
WO2013065417A1 (en) * 2011-10-31 2013-05-10 東京応化工業株式会社 Adhesive composition for bonding water and supporting body for said wafer, adhesive film, and laminate
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JP2021088614A (en) * 2019-12-02 2021-06-10 東洋インキScホールディングス株式会社 Adhesive for fixing abrasive member and adhesive sheet
JP7318510B2 (en) 2019-12-02 2023-08-01 東洋インキScホールディングス株式会社 Adhesive and Adhesive Sheet for Fixing Abrasive Member
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