JP2010133801A - Method of discriminating quality of ballast filler - Google Patents

Method of discriminating quality of ballast filler Download PDF

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JP2010133801A
JP2010133801A JP2008309079A JP2008309079A JP2010133801A JP 2010133801 A JP2010133801 A JP 2010133801A JP 2008309079 A JP2008309079 A JP 2008309079A JP 2008309079 A JP2008309079 A JP 2008309079A JP 2010133801 A JP2010133801 A JP 2010133801A
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filler
ballast
asphalt
pcb
resin
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JP5022350B2 (en
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Chisato Tsukahara
千幸人 塚原
Akihiro Nozaki
昭宏 野▲崎▼
Noboru Kawamoto
昇 川元
Kensuke Akamizu
研輔 赤水
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Mitsubishi Heavy Industries Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method of discriminating quality of a ballast filler capable of reliably discriminating an asphalt-based filler from the filler of a ballast. <P>SOLUTION: In the method of discriminating quality of the filler of the ballast 14 including a transformer 12, and a capacitor 13 including PCB by the filler 11, an ultrasonic probe 15 is used to discriminate whether the filler inside the ballast is an asphalt-based material from the side of the ballast 14, only the stabilizer made of resin is to be treated in PCB treatment facilities, and the asphalt-based filler is stored separately. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、安定器中のアスファルト充填材を判別する判別方法に関する。   The present invention relates to a discrimination method for discriminating asphalt filler in a ballast.

PCBは、従来からトランスやコンデンサなどの絶縁油として広く使用されてきた経緯があるが、その毒性が強いことにより、PCBを処理する必要がある。このため、PCBを無害化処理する種々の分解方法が提案されている(特許文献1、特許文献2、特許文献3参照)。   Although PCB has been widely used as an insulating oil for transformers, capacitors, and the like, it is necessary to treat PCB due to its strong toxicity. For this reason, various decomposition methods for detoxifying the PCB have been proposed (see Patent Document 1, Patent Document 2, and Patent Document 3).

ここで、前記PCB無害化装置はPCBのみを処理するものであるが、一方のPCBを抜き出したPCB汚染容器等は有機溶剤や界面活性剤等の洗浄液により洗浄処理が施されて、容器の無害化を図っている(特許文献4)。
また、蛍光灯安定器、トランス、コンデンサ等の紙素子のPCB除去を行うために、アルコール洗浄剤として、イソプロピルアルコール(以下「IPA」ともいう。)を用い、除去されたPCBを含むIPAは水熱分解処理装置でPCBを分解することを先に提案した(特許文献5)。
Here, the PCB detoxification device processes only the PCB, but the PCB contaminated container from which one PCB is extracted is subjected to a cleaning process with a cleaning liquid such as an organic solvent or a surfactant, and the container is harmless. (Patent Document 4).
In addition, isopropyl alcohol (hereinafter, also referred to as “IPA”) is used as an alcohol cleaning agent to remove PCB from paper elements such as fluorescent lamp ballasts, transformers, capacitors, etc., and IPA containing the removed PCB is water. It was previously proposed to decompose PCB with a thermal decomposition processing apparatus (Patent Document 5).

特開平11−253795号公報Japanese Patent Laid-Open No. 11-253895 特開平11−253796号公報Japanese Patent Laid-Open No. 11-253796 特開2000−126588号公報JP 2000-126588 A 特開2002−248455号公報JP 2002-248455 A 特開2005−21830号公報JP 2005-21830 A

しかしながら、安定器の充填材の種類(アスファルト)によっては、破砕後の処理工程で、処理能力の低下、機械的能力低下を引き起こす要因となる。
特に、安定器の充填材であるアスファルトが後工程に流れた場合には、その混入の程度にもよるが、洗浄液の汚染がひどくなり、洗浄液の再利用ができないものが発生し、洗浄コストが嵩むという問題もある。
However, depending on the type of filler (asphalt) in the ballast, it may cause a decrease in processing capacity and mechanical capacity in the processing step after crushing.
In particular, when asphalt, which is a stabilizer filler, flows to the subsequent process, depending on the degree of contamination, the cleaning liquid becomes seriously contaminated, and some cleaning liquid cannot be reused. There is also the problem of being bulky.

また、アスファルト型安定器が誤って、後工程に流れた場合には、アスファルトは洗浄に使用する溶剤等にも溶解しやすく、さらに真空加熱炉においても気化して、ガス成分を処理するフィルタの汚染や閉塞等の問題となる。このような閉塞が生じると、PCB処理設備全体の停止を引き起こし、PCB処理が遅延する問題となる。   In addition, if the asphalt type ballast accidentally flows to the subsequent process, the asphalt easily dissolves in the solvent used for cleaning, and further vaporizes in a vacuum heating furnace to process gas components. Problems such as contamination and blockage. When such a blockage occurs, the entire PCB processing facility is stopped, which causes a problem that the PCB processing is delayed.

このため、安定器の充填材を製造年月や型式により人海戦術により判断しているが、汚れやラベル等が剥離している場合や、様々な種類の安定器を瞬時に選別するので、判断漏れがある場合には、処理能力の低下となるので、アスファルト型安定器を処理対象から確実に除外することができる判別手法の構築が切望されている。   For this reason, ballast fillers are judged by human naval tactics according to the date of manufacture and model, but when dirt or labels are peeled off, various types of ballasts are instantly selected, If there is an omission in judgment, the processing capacity will be reduced. Therefore, it is desired to construct a discrimination method that can reliably exclude the asphalt ballast from the processing target.

本発明は、前記問題に鑑み、安定器の充填材からアスファルト系充填材を確実に判定することができる安定器充填材の材質判別方法を提供することを課題とする。   In view of the above problems, an object of the present invention is to provide a ballast filler material discrimination method that can reliably determine an asphalt filler from a ballast filler.

上述した課題を解決するための本発明の第1の発明は、トランスとPCBが含まれたコンデンサとを充填材を用いて内包する安定器の充填材の材質判別方法であって、前記安定器の側面から超音波探触子を用いて超音波を発振し、そのエコー強度の強弱に応じて、安定器内部の充填材がアスファルト系材料であるか否かを判別することを特徴とする安定器充填材の材質判別方法にある。   A first invention of the present invention for solving the above-described problem is a method for determining a material of a filler in a ballast that includes a transformer and a capacitor including a PCB using the filler. Is characterized by oscillating ultrasonic waves using an ultrasonic probe from the side surface and determining whether the filler inside the ballast is an asphalt material according to the strength of the echo intensity. It is in the material discrimination method of the container filler.

第2の発明は、第1の発明において、さらに、安定器の側面から針状探触子を用いて、その挿入の度合いに応じて、内部の充填物がアスファルト系充填材であるか否かを判別することを特徴とする安定器充填材の材質判別方法にある。   According to a second invention, in the first invention, the use of a needle-like probe from the side of the ballast, whether or not the internal filler is an asphalt-type filler depending on the degree of insertion. In the material discrimination method for the ballast filler.

本発明によれば、安定器の側面から超音波探触子を用い、安定器内部の充填材がアスファルト系材料であるか否かを判別するので、アスファルト型安定器を処理対象から確実の除外することができる。   According to the present invention, since the ultrasonic probe is used from the side of the ballast and it is determined whether or not the filler inside the ballast is an asphalt material, the asphalt ballast is surely excluded from the processing target. can do.

以下、この発明につき図面を参照しつつ詳細に説明する。なお、この実施例によりこの発明が限定されるものではない。また、下記実施例における構成要素には、当業者が容易に想定できるもの、あるいは実質的に同一のものが含まれる。   Hereinafter, the present invention will be described in detail with reference to the drawings. Note that the present invention is not limited to the embodiments. In addition, constituent elements in the following embodiments include those that can be easily assumed by those skilled in the art or those that are substantially the same.

本発明による実施例に係る安定器充填材の材質判別方法について、図面を参照して説明する。
図1は、実施例1に係る安定器充填材の材質判別を行う超音波探触子を設置した状態を示す概略図である。図2は、エコー強度測定結果を示す模式図である。
図1に示すように、本実施例に係る安定器充填材の材質判別方法は、トランス12とPCBが含まれたコンデンサ13とを充填材11を用いて内包する安定器14の充填材の材質判別方法であって、安定器14の側面から超音波探触子15を用い、安定器内部の充填材がアスファルト系材料であるか否かを判別するものである。
図1中、符号16は安定器14の側面に塗布されたグリース、17a、17bは結線である。
A material discrimination method for a ballast filler according to an embodiment of the present invention will be described with reference to the drawings.
FIG. 1 is a schematic diagram illustrating a state in which an ultrasonic probe that performs material discrimination of a ballast filler according to the first embodiment is installed. FIG. 2 is a schematic diagram showing the result of echo intensity measurement.
As shown in FIG. 1, the material determination method of the ballast filler according to the present embodiment is the material of the filler of the ballast 14 including the transformer 12 and the capacitor 13 including the PCB using the filler 11. This is a determination method, in which an ultrasonic probe 15 is used from the side of the ballast 14 to determine whether or not the filler inside the ballast is an asphalt material.
In FIG. 1, reference numeral 16 denotes grease applied to the side surface of the ballast 14, and 17a and 17b are wire connections.

図1に示すように、本実施例においては、前記超音波探触子15を安定器14の側面にグリース16を介して、接触させており、超音波探触子15の内部に設けられた送信用振動子から超音波を発振し、その際のエコーを受信し、該エコー強度の強弱を計測するようにしている。   As shown in FIG. 1, in this embodiment, the ultrasonic probe 15 is brought into contact with the side surface of the ballast 14 via grease 16 and is provided inside the ultrasonic probe 15. An ultrasonic wave is oscillated from the transmitting vibrator, an echo at that time is received, and the strength of the echo intensity is measured.

充填材の材質が硬い方は、エコー強度が速いものとなり、これに対し、材質が柔らかい方は、エコー強度が遅いものとなる。ここで、超音波の音速としては、特に限定されるものではないが、例えば5000m/sとした。   The harder the filler material, the faster the echo intensity, whereas the softer the material, the slower the echo intensity. Here, the sound speed of the ultrasonic wave is not particularly limited, but is set to, for example, 5000 m / s.

図2にアスファルト型安定器14Aと樹脂型安定器14Bとのエコー強度測定結果を示す。図2中、時間T0〜T4は図1に示す安定器をエコーが通過する地点に対応する。
ここで、アスファルト型安定器14Aで使用されるアスファルト系充填材は、常温において、粘度状態であり、その状態で安定器内に充填している。
よって、アスファルト系充填材は柔軟であるので、図2に示すように、エコー強度は弱い(低い)ものとなる。
FIG. 2 shows the echo intensity measurement results of the asphalt ballast 14A and the resin ballast 14B. In FIG. 2, times T 0 to T 4 correspond to points where the echo passes through the ballast shown in FIG.
Here, the asphalt-based filler used in the asphalt-type ballast 14A is in a viscous state at room temperature, and is filled in the ballast in that state.
Therefore, since the asphalt filler is flexible, the echo intensity is weak (low) as shown in FIG.

これに対し、樹脂型安定器14Bで使用される樹脂系充填材は、例えばポリエステル樹脂と砂とを4:6の割合で混合し、常温では流動性(例えば水飴状態)であるが、安定器内部に充填された後、所定期間の経過後に硬化している。
よって、樹脂系充填材は硬いものとなるので、図2に示すように、エコー強度は強い(高い)ものとなる。
On the other hand, the resin filler used in the resin type ballast 14B is, for example, a polyester resin and sand mixed at a ratio of 4: 6, and is fluid (eg, in a water tank state) at room temperature. After filling the inside, it is cured after a predetermined period.
Therefore, since the resin filler is hard, the echo intensity is strong (high) as shown in FIG.

そして、図2に示すように、超音波探触子15からのエコー強度が硬いものか柔らかいものかを判断することで、充填材の材質の種類を判断することができることが判明した。   Then, as shown in FIG. 2, it has been found that the type of filler material can be determined by determining whether the echo intensity from the ultrasound probe 15 is hard or soft.

よって、エコー強度の閾値を設定し、閾値以上か以下かで、樹脂系充填材かアスファルト系充填材かを判別することができる。   Therefore, the threshold value of the echo intensity is set, and it can be determined whether the resin-based filler or the asphalt-based filler is greater than or less than the threshold.

本発明による実施例に係る安定器充填材の材質判別方法について、図面を参照して説明する。
図3−1〜3−3は、実施例2に係る安定器充填材の材質判別を行う説明図である。
図3−1〜3−3に示すように、本実施例に係る安定器充填材の材質判別方法は、トランス12とPCBが含まれたコンデンサ13とを充填材11を用いて内包する安定器14の充填材の材質の判別方法であって、安定器11の側面から針状の探触子33を用いて、その挿入の度合いに応じて、内部の充填物がアスファルト系充填材であるか否かを判別するものである。
A material discrimination method for a ballast filler according to an embodiment of the present invention will be described with reference to the drawings.
FIGS. 3A to 3C are explanatory diagrams for determining the material of the ballast filler according to the second embodiment.
As shown in FIGS. 3-1 to 3-3, the ballast filler material discrimination method according to the present embodiment includes a transformer 12 and a capacitor 13 including a PCB using a filler 11. 14 is a method for discriminating the material of the filler, and whether the inner filler is an asphalt filler according to the degree of insertion using the needle-like probe 33 from the side surface of the ballast 11. This is to determine whether or not.

具体的には、図3−1に示すように、先ず判別する安定器14の側面から穿孔機31を用いて、例えば2〜3mm程度の開口部32とする。その後、例えば直径が1mm程度の針状探触子33を用いて、開口部32から挿入する。   Specifically, as shown in FIG. 3A, the opening 32 having a size of, for example, about 2 to 3 mm is used from the side surface of the ballast 14 to be discriminated by using a punching machine 31. Thereafter, the needle-like probe 33 having a diameter of about 1 mm is inserted through the opening 32, for example.

そして、図3−2に示すように、アスファルト型安定器14Aであれば、内部の充填材が柔軟であるので、針状探触子33が挿入されることとなる。   And as shown to FIGS. 3-2, if it is an asphalt type stabilizer 14A, since an internal filler is flexible, the needle-shaped probe 33 will be inserted.

これに対し、図3−3に示すように、樹脂型安定器14Bであれば、内部が硬いので、針状探触子33の挿入が阻止される。   On the other hand, as shown in FIG. 3C, if the resin-type ballast 14B is used, the inside is hard, so that the insertion of the needle-like probe 33 is prevented.

よって、針状探触子33の挿入の相違により、樹脂系充填材かアスファルト系充填材かを判別することができる。
なお、この判別方法によりアスファルト型安定器14Aと判別された場合には、開口部32を塞いで、別途保管処理することとなる。
Therefore, it is possible to determine whether the filler is the resin filler or the asphalt filler based on the difference in insertion of the needle-like probe 33.
In addition, when it discriminate | determines from the asphalt type stabilizer 14A by this discrimination | determination method, the opening part 32 will be plugged up and it will store separately.

また、この判別方法は、実施例1により判別できない場合に、用いるようにすることが処理効率の点から好適である。   Also, this determination method is preferably used from the viewpoint of processing efficiency when it cannot be determined by the first embodiment.

この安定器充填材の材質判別方法を仕分け部に用いたPCB処理システムの一例を図4に示す。
図4に示すように、本実施例に係るPCB処理システム100は、例えばPCBを含む安定器101の充填材の材質の種類(アスファルト系充填材又は樹脂系充填材)を仕分けする仕分け部102と、アスファルト型安定器14Aが仕分けされ除かれ、分別された樹脂型安定器14Bを破砕・分別処理する破砕・分別部103と、分別処理された分別品(素子104a、非鉄部材104b、鉄部材104c等)をそれぞれ予備洗浄する予備洗浄部105と、予備洗浄された素子104aから紙素子106と樹脂フィルム107とを分離する分離部108と、分離された紙素子106を有機溶剤(ヘキサン)で一次洗浄し、その後イソプロピルアルコールで二次洗浄する一次・二次洗浄部109と、洗浄後のイソプロピルアルコールが含まれる紙素子からイソプロピルアルコールを除去し、洗浄液を判定するIPA除去装置10Aとを具備するものである。
図中、符号110は一次・二次洗浄部109に供給されるPCB洗浄液、111はPCB洗浄廃液、112は非鉄部材104bやフィルム107を真空・高温状態で加熱してPCBを除去する真空加熱部、113は一次・二次洗浄部109で処理された鉄をアルカリ洗浄するアルカリ洗浄部、114は真空加熱処理やアルカリ洗浄処理の後の部材中のPCBの有無を判断して、PCBが基準値以下であることを判定する卒業判定部、115は卒業判定された鉄、銅、アルミニウム等の卒業判定品、116は各処理部でのガス成分117中の微粒子等を浄化する排気処理部、118はさらにガス成分を浄化する活性炭フィルタ部を各々図示する。
An example of a PCB processing system using this ballast filler material discrimination method in the sorting section is shown in FIG.
As shown in FIG. 4, the PCB processing system 100 according to the present embodiment includes a sorting unit 102 that sorts the type of filler (asphalt filler or resin filler) of the ballast 101 including PCB, for example. The asphalt type ballast 14A is sorted and removed, and the divided resin type ballast 14B is crushed and separated, and the separated product (element 104a, non-ferrous member 104b, iron member 104c). Etc.), a separation unit 108 for separating the paper element 106 and the resin film 107 from the pre-cleaned element 104a, and the separated paper element 106 with an organic solvent (hexane). Primary / secondary cleaning unit 109 that performs cleaning and then secondary cleaning with isopropyl alcohol and isopropyl alcohol after cleaning are included. Isopropyl alcohol was removed from the element, and comprising a IPA removing apparatus 10A determines the cleaning liquid.
In the figure, reference numeral 110 denotes a PCB cleaning solution supplied to the primary / secondary cleaning unit 109, 111 denotes a PCB cleaning waste solution, and 112 denotes a vacuum heating unit for removing the PCB by heating the non-ferrous member 104b and the film 107 in a vacuum / high temperature state. , 113 is an alkaline cleaning unit that performs alkaline cleaning of iron processed by the primary / secondary cleaning unit 109, 114 is the presence or absence of PCB in the member after the vacuum heating process or alkaline cleaning process, and the PCB is a reference value A graduation judgment unit 115 for judging that the following is satisfied, 115 is a graduation judgment product such as iron, copper, and aluminum that has been judged for graduation, 116 is an exhaust processing unit for purifying particulates in the gas component 117 in each processing unit, 118 Fig. 2 further shows activated carbon filter parts for purifying gas components.

本実施例では、仕分け部102において、実施例1又は2いずれか一方又は両方の判別法により判別することで、樹脂型安定器14Bのみが、PCB処理設備内での処理の対象となり、安定して処理することができることとなる。
また、一次破砕によりコンデンサから漏れ出たPCBが二次的に充填材に付着した部材は洗浄処理又は真空加熱処理により処理されるが、本実施例では、樹脂製の充填材のみの場合となるので、従来のようにアスファルトによる阻害がないので、安定した操業が可能となる。
In the present embodiment, in the sorting unit 102, only the resin-type ballast 14B becomes a target of processing in the PCB processing facility by the determination by the determination method of either one or both of the first and second embodiments, or both. Can be processed.
In addition, the member where the PCB leaked from the capacitor due to the primary crushing is secondarily attached to the filler is processed by the cleaning process or the vacuum heating process, but in this embodiment, only the resin filler is used. Therefore, since there is no inhibition by asphalt as in the prior art, stable operation is possible.

なお、前記仕分け部102においてアスファルト型安定器14Aが仕分けされ除かれたものは、別途厳重に保管されることとなる。   In addition, what the asphalt type ballast 14A is sorted and removed in the sorting unit 102 is stored strictly separately.

以上のように、本発明に係る安定器充填材の材質判別方法によれば、処理の阻害となるアスファルト型安定器を確実に判別することができるので、PCB処理設備における判別に用いて適している。   As described above, according to the material determination method for ballast fillers according to the present invention, it is possible to reliably determine an asphalt type ballast that hinders processing, so that it is suitable for use in determination in a PCB processing facility. Yes.

実施例1に係る安定器充填材の材質判別を行う超音波探触子を設置した状態を示す概略図である。It is the schematic which shows the state which installed the ultrasonic probe which performs material discrimination | determination of the ballast filler concerning Example 1. FIG. エコー強度測定結果を示す模式図である。It is a schematic diagram which shows an echo intensity | strength measurement result. 実施例2に係る安定器充填材の材質判別を行う説明図である。It is explanatory drawing which performs material discrimination | determination of the ballast filler concerning Example 2. FIG. 実施例2に係る安定器充填材の材質判別を行う説明図である。It is explanatory drawing which performs material discrimination | determination of the ballast filler concerning Example 2. FIG. 実施例2に係る安定器充填材の材質判別を行う説明図である。It is explanatory drawing which performs material discrimination | determination of the ballast filler concerning Example 2. FIG. 実施例3に係るPCB処理システムの概略図である。FIG. 10 is a schematic diagram of a PCB processing system according to a third embodiment.

符号の説明Explanation of symbols

11 充填材
12 トランス
13 コンデンサ
14 安定器
15 超音波探触子
11 Filler 12 Transformer 13 Capacitor 14 Ballast 15 Ultrasonic Probe

Claims (2)

トランスとPCBが含まれたコンデンサとを充填材を用いて内包する安定器の充填材の材質判別方法であって、
前記安定器の側面から超音波探触子を用いて超音波を発振し、そのエコー強度の強弱に応じて、安定器内部の充填材がアスファルト系材料であるか否かを判別することを特徴とする安定器充填材の材質判別方法。
A method for determining a material of a filler of a ballast that includes a transformer and a capacitor including PCB using the filler,
The ultrasonic wave is oscillated from the side of the ballast using an ultrasonic probe, and it is determined whether or not the filler inside the ballast is an asphalt material according to the strength of the echo intensity. The material discrimination method of the ballast filler.
請求項1において、
さらに、安定器の側面から針状探触子を用いて、その挿入の度合いに応じて、内部の充填物がアスファルト系充填材であるか否かを判別することを特徴とする安定器充填材の材質判別方法。
In claim 1,
Furthermore, using a needle-like probe from the side surface of the ballast, it is determined whether or not the inner packing is an asphalt-type packing material according to the degree of insertion. Material discrimination method.
JP2008309079A 2008-12-03 2008-12-03 Method for distinguishing ballast filler material Expired - Fee Related JP5022350B2 (en)

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US9340441B2 (en) 2009-07-08 2016-05-17 Saudi Arabian Oil Company Wastewater treatment system including irradiation of primary solids

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JPS63186141A (en) * 1987-01-28 1988-08-01 Fujimori Kogyo Kk Inspecting method for package contents using ultrasonic wave
JPH03255333A (en) * 1990-03-03 1991-11-14 Cosmo Toreede & Service:Kk Automatic penetration measuring apparatus
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Publication number Priority date Publication date Assignee Title
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